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Safety Data Sheet SAFETY DATA SHEET Revision Date 22-Jan-2021 Revision Number 2 SECTION 1: IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING 1.1. Product identifier Product Description: Hafnium(IV) chloride Cat No. : 45612 Synonyms Hafnium tetrachloride. CAS-No 13499-05-3 Molecular Formula Hf Cl4 Reach Registration Number - 1.2. Relevant identified uses of the substance or mixture and uses advised against Recommended Use Laboratory chemicals. Uses advised against No Information available 1.3. Details of the supplier of the safety data sheet Company Thermo Fisher (Kandel) GmbH . Erlenbachweg 2 76870 Kandel Germany Tel: +49 (0) 721 84007 280 Fax: +49 (0) 721 84007 300 E-mail address [email protected] www.alfa.com Product safety Tel + +049 (0) 7275 988687-0 1.4. Emergency telephone number Carechem 24: +44 (0) 1235 239 670 (Multi-language emergency number) Poison Information Center Mainz www.giftinfo.uni-mainz.de Telephone: +49(0)6131/19240 Exclusively for customers in Austria: Poison Information Center (VIZ) Emergency call 0-24 clock: +43 1 406 43 43 Office hours: Monday to Friday, 8am to 4pm, tel: +43 1 406 68 98 SECTION 2: HAZARDS IDENTIFICATION 2.1. Classification of the substance or mixture CLP Classification - Regulation (EC) No 1272/2008 Physical hazards Based on available data, the classification criteria are not met ______________________________________________________________________________________________ ALFAA45612 Page 1 / 10 SAFETY DATA SHEET Hafnium(IV) chloride Revision Date 22-Jan-2021 ______________________________________________________________________________________________ Health hazards Skin Corrosion/Irritation Category 1 B (H314) Serious Eye Damage/Eye Irritation Category 1 (H318) Environmental hazards Based on available data, the classification criteria are not met Full text of Hazard Statements: see section 16 2.2. Label elements Signal Word Danger Hazard Statements H314 - Causes severe skin burns and eye damage EUH029 - Contact with water liberates toxic gas Precautionary Statements P301 + P330 + P331 - IF SWALLOWED: rinse mouth. Do NOT induce vomiting P280 - Wear eye protection/ face protection P305 + P351 + P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing P310 - Immediately call a POISON CENTER or doctor/physician P402 + P404 - Store in a dry place. Store in a closed container 2.3. Other hazards In accordance with Annex XIII of the REACH Regulation, inorganic substances do not require assessment SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS 3.1. Substances Component CAS-No EC-No. Weight % CLP Classification - Regulation (EC) No 1272/2008 Hafnium chloride (HfCl4), (T-4)- 13499-05-3 EEC No. 236-826-5 99 Skin Corr. 1B (H314) (EUH029) Reach Registration Number - ______________________________________________________________________________________________ ALFAA45612 Page 2 / 10 SAFETY DATA SHEET Hafnium(IV) chloride Revision Date 22-Jan-2021 ______________________________________________________________________________________________ Full text of Hazard Statements: see section 16 SECTION 4: FIRST AID MEASURES 4.1. Description of first aid measures Eye Contact Immediate medical attention is required. Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Skin Contact Wash off immediately with soap and plenty of water while removing all contaminated clothes and shoes. Immediate medical attention is required. Ingestion Do NOT induce vomiting. Call a physician immediately. Inhalation Remove from exposure, lie down. Remove to fresh air. If breathing is difficult, give oxygen. If not breathing, give artificial respiration. Immediate medical attention is required. Self-Protection of the First Aider Ensure that medical personnel are aware of the material(s) involved, take precautions to protect themselves and prevent spread of contamination. 4.2. Most important symptoms and effects, both acute and delayed Causes burns by all exposure routes. Product is a corrosive material. Use of gastric lavage or emesis is contraindicated. Possible perforation of stomach or esophagus should be investigated: Ingestion causes severe swelling, severe damage to the delicate tissue and danger of perforation 4.3. Indication of any immediate medical attention and special treatment needed Notes to Physician Treat symptomatically. SECTION 5: FIREFIGHTING MEASURES 5.1. Extinguishing media Suitable Extinguishing Media Carbon dioxide (CO 2). Dry chemical. Chemical foam. Extinguishing media which must not be used for safety reasons No information available. 5.2. Special hazards arising from the substance or mixture Thermal decomposition can lead to release of irritating gases and vapors. Hazardous Combustion Products Hydrogen chloride gas. 5.3. Advice for firefighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear. SECTION 6: ACCIDENTAL RELEASE MEASURES 6.1. Personal precautions, protective equipment and emergency procedures ______________________________________________________________________________________________ ALFAA45612 Page 3 / 10 SAFETY DATA SHEET Hafnium(IV) chloride Revision Date 22-Jan-2021 ______________________________________________________________________________________________ Ensure adequate ventilation. 6.2. Environmental precautions See Section 12 for additional Ecological Information. 6.3. Methods and material for containment and cleaning up Sweep up and shovel into suitable containers for disposal. Do not let this chemical enter the environment. 6.4. Reference to other sections Refer to protective measures listed in Sections 8 and 13. SECTION 7: HANDLING AND STORAGE 7.1. Precautions for safe handling Do not breathe dust. Do not get in eyes, on skin, or on clothing. Do not ingest. If swallowed then seek immediate medical assistance. Handle product only in closed system or provide appropriate exhaust ventilation. Hygiene Measures Handle in accordance with good industrial hygiene and safety practice. Keep away from food, drink and animal feeding stuffs. Do not eat, drink or smoke when using this product. Remove and wash contaminated clothing and gloves, including the inside, before re-use. Wash hands before breaks and after work. 7.2. Conditions for safe storage, including any incompatibilities Keep in a dry, cool and well-ventilated place. Keep container tightly closed. Corrosives area. Keep under nitrogen. Technical Rules for Hazardous Substances (TRGS) 510 Storage Class (LGK) Storage Class/LGK 8B (Germany) 7.3. Specific end use(s) Use in laboratories SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION 8.1. Control parameters Exposure limits List source(s): Component European Union The United Kingdom France Belgium Spain Hafnium chloride TWA / VLA-ED: 0.5 (HfCl4), (T-4)- mg/m3 (8 horas) Component Italy Germany Portugal The Netherlands Finland Hafnium chloride TWA: 0.5 mg/m3 8 horas (HfCl4), (T-4)- Component Austria Denmark Switzerland Poland Norway Hafnium chloride MAK-TMW: 0.5 mg/m3 8 (HfCl4), (T-4)- Stunden ______________________________________________________________________________________________ ALFAA45612 Page 4 / 10 SAFETY DATA SHEET Hafnium(IV) chloride Revision Date 22-Jan-2021 ______________________________________________________________________________________________ Biological limit values This product, as supplied, does not contain any hazardous materials with biological limits established by the region specific regulatory bodies Monitoring methods BS EN 14042:2003 Title Identifier: Workplace atmospheres. Guide for the application and use of procedures for the assessment of exposure to chemical and biological agents. MDHS14/3 General methods for sampling and gravimetric analysis of respirable and inhalable dust Derived No Effect Level (DNEL) No information available Route of exposure Acute effects (local) Acute effects Chronic effects Chronic effects (systemic) (local) (systemic) Oral Dermal Inhalation Predicted No Effect Concentration No information available. (PNEC) 8.2. Exposure controls Engineering Measures Ensure adequate ventilation, especially in confined areas. Ensure that eyewash stations and safety showers are close to the workstation location. Wherever possible, engineering control measures such as the isolation or enclosure of the process, the introduction of process or equipment changes to minimise release or contact, and the use of properly designed ventilation systems, should be adopted to control hazardous materials at source Personal protective equipment Eye Protection Goggles (European standard - EN 166) Hand Protection Protective gloves Glove material Breakthrough time Glove thickness EU standard Glove comments Natural rubber See manufacturers - EN 374 (minimum requirement) Nitrile rubber recommendations Neoprene PVC Skin and body protection Wear appropriate protective gloves and clothing to prevent skin exposure Inspect gloves before use. observe the instructions regarding permeability and breakthrough time which are provided by the supplier of the gloves. (Refer to manufacturer/supplier for information) gloves are suitable for the task: Chemical compatability, Dexterity, Operational conditions, User susceptibility, e.g. sensitisation effects, also take into consideration the specific local conditions under which the product is used, such as the danger of cuts, abrasion. gloves with care avoiding skin contamination. Respiratory Protection When workers are facing
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