Titanium-Germoxy Precursor Route to Germanium-Modified Epoxidation Catalysts with 387. Enhanced Activity. P. J. Cordeiro, P. Guillo, C. S. Spanjers, J. W. Chang, M. E. Fasulo, R. M. Rioux and T. D. Tilley, ACS Catal. 2013, 3, 2269. Photocatalytic Water Oxidation by Very Small Cobalt Domains on a Silica Surface. H. S. 386. Ahn, J. Yano and T. D. Tilley, Energy Environ. Sci. 2013, 6, 3080. Platinum-Catalyzed C-C Activation Induced by C-H Activation. M. Bowring, R. G. 385. Bergman and T. D. Tilley, J. Am. Chem. Soc. 2013, 135, 13121. Structural and mechanistic investigation of a cationic hydrogen-substituted ruthenium 384. silylene catalyst for alkene hydrosilation. M. Fasulo, M. C. Lipke and T. D. Tilley, Chem. Sci. 2013, 4, 3882. Water Oxidation Catalysis via Immobilization of the Dimanganese Complex [Mn2(μ- 383. O)2Cl(μ-O2CCH3)(bpy)2(H2O)](NO3)2 onto Silica. E. M. W. Rumberger, H. S. Ahn, A. T. Bell and T. D. Tilley, Dalton Trans. 2013, 42, 12238. The Osmium-Silicon Triple Bond: Synthesis and Reactivity of an Osmium Silylyne 382. Complex. P. G. Hayes, Z. Xu, C. Beddie, J. M. Keith, M. B. Hall and T. D. Tilley, J. Am. Chem. Soc. 2013, 135, 11780. Silane-Isocyanide Coupling Involving 1,1-Insertion of XylNC into the Si-H Bond of a σ- 381. Silane Ligand. M. C. Lipke and T. D. Tilley, J. Am. Chem. Soc. 2013, 135, 10298. A Remote Lewis Acid Trigger Dramatically Accelerates Biaryl Reductive Elimination from 380. a Platinum Complex. A. Liberman-Martin, R. G. Bergman and T. D. Tilley, J. Am. Chem. Soc. 2013, 135, 9612. Multiple Si–H Bond Activations by tBu2PCH2CH2PtBu2 and tBu2PCH2PtBu2 379. Di(phosphine) Complexes of Rhodium and Iridium. M. E. Fasulo, E. Calimano, J. M. Buchanan and T. D. Tilley, Organometallics 2013, 32, 1016. Synthesis and Characterization of Tantalum Silsesquioxane Complexes. P. Guillo, M. E. 378. Fasulo, M. I. Lipschutz and T. D. Tilley, Dalton Trans. 2013, 42, 1991. Hydrolysis of 3-carboxy-6,8-difluoro-7-hydroxycoumarin (Pacific BlueTM) succinimidyl 377. ester under acidic and basic conditions. A. M. Stockton, M. F. Mora, M. L. Cable, T. C. Davenport, T. D. Tilley and P. A. Willis, Dyes Pigments 2013, 96, 148. Electrocatalytic Water Oxidation at Neutral pH by a Nanostructured Co(PO3)2 Anode. H. 376. S. Ahn and T. D. Tilley, Adv. Func. Mater. 2013, 23, 227.

Stabilization of ArSiH4– and SiH62– Anions in Diruthenium Si—H σ-Complexes. M. C. 375. Lipke and T. D. Tilley, Angew. Chem. Int. Ed. 2012, 51, 11115. Stoichiometric Reaction Chemistry of Cationic Ruthenium Silylene Complexes toward 374. Polar and Non-polar Organic Substrates. M. Fasulo and T. D. Tilley, Organometallics 2012, 31, 5049. Synthesis and Reactivity of Cationic Ruthenium Germylene Complexes 373. [Cp*(PiPr3)RuH2(=GeRR')]+. M. Fasulo and T. D. Tilley, Chem. Comm. 2012, 48, 7690. Synthesis and Reactivity of a Conveniently Prepared Two-Coordinate Bis(amido) Nickel(II) 372. Complex. M. Lipschutz and T. D. Tilley, Chem. Comm. 2012, 48, 7146. 371. Preparation and Physical Properties of Early-Late Heterobimetallic Compounds Featuring Ir–M Bonds (M = Ti, Zr, Hf). J. J. Curley, R. G. Bergman and T. D. Tilley, Dalton Trans. 2012, 42, 192. Epoxidation catalysts derived from introduction of titanium centers onto the surface of 370. mesporporous aluminophosphate: Comparisons with analogous catalysts based on mesoporous silica. L. Raboin, J. Yano and T. D. Tilley, J. Catal. 2012, 285, 168. Isolation, observation, and computational modeling of proposed intermediates in catalytic 369. proton reductions with the hydrogenase mimic Fe2(CO)6S2C6H4. R. J. Wright, W. Zhang, X. Yang, M. Fasulo and T. D. Tilley, Dalton Trans. 2012, 41, 73.

Dinucleating Naphthyridine-Based Ligand for Assembly of Bridged Dicopper(I) Centers: 368. Three-Center Two-Electron Bonding Involving an Acetonitrile Donor. T. C. Davenport and T. D. Tilley, Angew. Chem. Int. Ed. 2011, 50, 12205. Mechanism of the Decomposition of Aqueous Hydrogen Peroxide over Heterogeneous TiSBA15 and TS-1 Selective Oxidation Catalysts: Insights from Spectroscopic and Density 367. Functional Theory Studies. C. W. Yoon, K. F. Hirsekorn, M. L. Neidig, X. Yang and T. D. Tilley, ACS Catal. 2011, 1, 1665. Cp*(PiPr3)RuOTf: A Reagent for Access to Ruthenium Silylene Complexes. M. E. Fasulo, 366. P. B. Glaser and T. D. Tilley, Organometallics 2011, 30, 5524. Inverse Rectification in Donor-Acceptor Molecular Heterojunctions. S. K. Yee, J. Sun, P. 365. Darancet, T. D. Tilley, A. Majumdar, J. B. Neaton and R. A. Segalman, ACS Nano 2011, 5, 9256. Comparison of Cobalt-based Nanoparticles as Electrocatalysts for Water Oxidation. N. H. 364. Chou, P. N. Ross, A. T. Bell and T. D. Tilley, ChemSusChem 2011, 4, 1566. High Electrophilicity at Silicon in η3-Silane s-Complexes: Lewis Base Adducts of a Silane 363. Ligand, Featuring Octahedral Silicon and Three Ru-H-Si Interactions. M. C. Lipke and T. D. Tilley, J. Am. Chem. Soc. 2011, 133, 16374. Highly Dispersed Pd-SBA15 Materials from Tris(tert-butoxy)siloxy Complexes of Pd(II). 362. Y. S. Choi, E. G. Moschetta, J. T. Miller, M. Fasulo, M. J. McMurdo, R. M. Rioux and T. D. Tilley, ACS Catal. 2011, 1, 1166. Assembly of Macrocycles by Zirconocene-Mediated, Reversible Carbon-Carbon Bond 361. Formation. V. Gessner, J. Tannaci, A. Miller and T. D. Tilley. Acc. Chem. Res. 2011, 44, 435. Terminal Hafnium Phosphinidene Complexes and Phosphinidene Ligand Exchange. R. 360. Waterman and T. D. Tilley, Chem. Sciences 2011, 2, 1320. Enhancement of Epoxidation Efficiencies for Ta-SBA15 Catalysts. The Influence of 359. Modification with –EMe3 (E = Si, Ge, Sn) Groups. P. J. Cordeiro and T. D. Tilley, Langmuir 2011, 27, 6295. Enhancement of the Catalytic Activity of Titanium-Based Terminal Olefin Epoxidation 358. Catalysts via Surface Modification with Functionalized Protic Molecules. P. J. Cordeiro and T. D. Tilley, ACS Catal. 2011, 1, 455. Transition metal complexes of the novel hexadentate ligand 1,4-bis(di(N-methylimidazol-2- 357. yl)methyl)phthalazine. S. Roggan, C. Limberg, C. Knispel and T. D. Tilley. Dalton Trans. 2011, 40, 4315. Disambiguation of Metal and Bronsted Acid Catalyzed Pathways for Hydroarylation with a 356. Platinum(II) Catalyst. M. Bowring, R. G. Bergman and T. D. Tilley, Organometallics 2011, 30, 1295. Diphenylanthracene Macrocycles from Reductive Zirconocene Coupling: On the Edge of 355. Steric Overload. V. H. Gessner and T. D. Tilley, Org. Lett. 2011, 13, 1154. Interligand H…Si Interactions in Tungsten Silyl Trihydride Complexes. M. E. Fasulo and 354. T. D. Tilley. J. Organomet. Chem. 2011, 696, 1325. Disulfide Passivation of the Ge(100)-2 × 1 Surface. J. S. Kachian, J. Tannaci, R. J. Wright, 353. T. D. Tilley and S. F. Bent, Langmuir 2011, 27, 179.

Active and Efficient Hydrosilylation of Carbonyl Compounds with the Simple Iron-Based 352. Catalyst Fe[N(SiMe3)2]2. J. Yang and T. D. Tilley, Angew. Chem. Int. Ed. 2010, 52, 10186. Unusual Ruthenium Hydride Complexes Supported by the [N(2-PPh2-4-Me-C6H3)2] 351. Pincer Ligand M. E. Fasulo and T. D. Tilley, Inorg. Chim. Acta 2010, 364, 246. (special issue to commemorate the 70th birthday of Prof. Arnold L. Rheingold). Nickel Complexes with Bis(8-Quinolyl)silyl Ligands. An Unusual Ni3Si2 Cluster 350. Containing Six-Coordinate Silicon. J. Yang, I. D. Rosal, M. Fasulo, P. Sangtrirutnugul, L. Maron and T. D. Tilley, Organometallics 2010, 29, 5544. (MeQn2SiH)Fe[N(SiMe3)2]2 (Qn = 8-Quinolyl): An Unusual δ-Agostic Iron Complex 349. Containing an η1-SiH Interaction. J. Yang, M. Fasulo and T. D. Tilley, New J. Chem. 2010, 34, 2528. Synthesis and reactivity of rhodium and iridium alkene, alkyl and silyl complexes supported 348. by a phenyl-substituted pincer ligand. E. Calimano and T. D. Tilley, Dalton Trans. 2010, 39, 9250. Synthesis and Electronic Properties of Extended, Fused-Ring Aromatic Systems Containing 347. Multiple Pentalene Units. Z. Levi and T. D. Tilley, J. Am. Chem. Soc. 2010, 132, 11012. Reactions of Cationic PNP-Supported Iridium Silylene Complexes with Polar Organic 346. Substrates. E. Calimano and T. D. Tilley, Organometallics 2010, 29, 1680. Synthesis and Characterization of Fluorinated Heterofluorene-Containing Donor-Acceptor 345. Systems. K. Geramita, Y. Tao, R. A. Segalman and T. D. Tilley. J. Org. Chem. 2010, 75, 1871. Facile Interconversion of Cp2(Cl)Hf-SnH3 and Cp2(Cl)Hf(μ-H)SnH2: DFT Investigations 344. of Hafnocene Stannyl Complexes as Masked Stannylenes. J. Guihaumé, C. Raynaud, O. Eisenstein, L. Perrin, L. Maron and T. D. Tilley. Angew. Chem. Int. Ed. 2010, 49, 1816. Nucleophilic Attack of Amides onto Coordinated Ethylene in Platinum Complexes 343. Supported by a Chelating Pyridyl-Pyrrolide Ligand: Azaplatinacyclobutane and Vinylamine Complexes. J. L. McBee and T. D. Tilley. Organometallics 2010, 29, 184.

Spatial Resolution of a Type II Heterojunction in a Single Bipolar Molecule. C. G. Tao, J. 342. B. Sun, X. W. Zhang, R. Yamachika, D. Wegner, Y. Bahri, G. Samsonidze, S. G. Louie, T. D. Tilley, R. A. Segalman and M. F. Crommie. Nano Lett. 2009, 9, 3963. 341. N-Heterocyclic Carbene-Stabilized Gold Nanoparticles and their Assembly into 3D Superlattices. J. Vignolle and T. D. Tilley. Chem. Comm. 2009, 7230. The Nature of Transport Variations in Molecular Heterojunction Electronics. J. A. Malen, 340. P. Doak, K. Baheti, T. D. Tilley, A. Majumdar and R. A. Segalman. Nano Lett. 2009, 9, 3406. Synthesis, Structure and Reactivity of Neutral Hydrogen-Substituted Ruthenium Silylene 339. and Germylene Complexes. P. G. Hayes, R. Waterman, P. B. Glaser and T. D. Tilley. Organometallics 2009, 28, 5082. Synthesis and Reactivity of Iridium and Rhodium Silyl Complexes Supported by a 338. Bipyridine Ligand. J. L. McBee and T. D. Tilley. Organometallics 2009, 28, 5072. High Oxidation State Rhodium and Iridium Bis(silyl)dihydride Complexes Supported by a 337. Chelating Pyridyl-Pyrrolide Ligand. J. L. McBee, J. Escalada and T. D. Tilley. J. Am. Chem. Soc. 2009, 131, 12703. Germylene and Silylene Complexes of Molybdenum via E-H (E = Ge, Si) Bond 336. Activations. Steric Influences on Intramolecular MoH···E Interactions. A. Shinohara, J. L. McBee and T. D. Tilley. Inorg. Chem. 2009, 48, 8081. Size-Dependent Activity of Co3O4 Anodes for Alkaline Water Electrolysis. A. J. Esswein, 335. M. J. McMurdo, P. N. Ross, A. T. Bell and T. D. Tilley. J. Phys. Chem. C 2009, 113, 15068. Diiron Proton Reduction Catalysts Possessing Electron-rich and Electron-poor 334. Naphthalene-1,8-dithiolate Ligands. R. J. Wright, C. Lim and T. D. Tilley. Chem. Eur. J. 2009, 15, 8518. Synthesis and Structure of PNP-Supported Iridium Silyl and Silylene Complexes: Catalytic 333. Hydrosilation of Alkenes. E. Calimano and T. D. Tilley. J. Am. Chem. Soc. 2009, 131, 11161. Five-Coordinate Dihydridosilyl Platinum(IV) Complexes Supported by a Chelating 332. Monoanionic Nitrogen-Based Ligand. J. L. McBee and T. D. Tilley. Organometallics 2009, 28, 3947. Bond Activations of PhSiH3 by Cp2SmH: A Mechanistic Investigation by the DFT 331. Method. L. Perrin, L. Maron, O. Eisenstein and T. D. Tilley. Organometallics 2009, 28, 3767. Octa- and Nonamethylfluorenyl Complexes of Zr(IV): Reactive Hydride Derivatives and 330. Reversible Hydrogen Migration between the Metal and the Fluorenyl Ligand. P. Bazinet and T. D. Tilley. Organometallics 2009, 28, 2285. Perfluoropentaphenylborole: A New Approach to Lewis Acidic, Electron-Deficient 329. Compounds. K. Huynh, J. Vignolle and T. D. Tilley. Angew. Chem. Intl. Ed. 2009, 48, 2835. Mesityl Alkyne Substituents for Control of Regiochemistry and Reversibility in Zirconocene Couplings: New Synthetic Strategies for Unsymmetrical 328. Zirconacyclopentadienes and Conjugated Polymers. A. D. Miller, J. F. Tannaci, S. A. Johnson, H. Lee, J. L. McBee and T. D. Tilley. J. Am. Chem. Soc. 2009, 131, 4917. A Hydrogen-Substituted Osmium Stannylene Complex: Isomerization to a 327. Metallostannylene Complex via an Unusual α-Hydrogen Migration from Tin to Osmium. P. G. Hayes, C. W. Gribble, R. Waterman and T. D. Tilley. J. Am. Chem. Soc. 2009, 131, 4606. Identifying the Length Dependence of Orbital Alignment and Contact Coupling in 326. Molecular Heterojunctions. J. A. Malen, P. Doak, K. Baheti, T. D. Tilley, R. A. Segalman and A. Majumdar. Nano Lett. 2009, 9, 1164. Zirconocene-Mediated Macrocyclizations of Diynes Containing Di-o-Methylphenylene 325. Spacers. A. D. Miller, J. L. McBee and T. D. Tilley. J. Org. Chem. 2009, 74, 2880. Versatile Synthesis of Pentalene Derivatives via the Pd-Catalyzed Homocoupling of 324. Haloenynes. Z. U. Levi and T. D. Tilley. J. Am. Chem. Soc. 2009, 131, 2796. Unsymmetrical Zirconacyclopentadienes from Isolated Zirconacyclopropenes with 1- 323. Alkynylphosphine Ligands. A. D. Miller, S. A. Johnson, K. A. Tupper, J. L. McBee and T. D. Tilley. Organometallics 2009, 28, 1252. 2,7-Substituted Hexafluoroheterofluorenes as Potential Building Blocks for Electron 322. Transporting Materials. K. Geramita, J. McBee and T. D. Tilley. J. Org. Chem. 2009, 74, 820. Functionalized Silicone Nanospheres: Synthesis, Transition Metal Immobilization, and 321. Catalytic Applications. C. A. Bradley, M. J. McMurdo, B. D. Yuhas and T. D. Tilley. Chem. Mater., 2009, 21, 174. Stereoselective macrocyclization through zirconocene-mediated coupling of achiral 320. dialkynes. J. F. Tannaci, I. H. Kratter, E. A. Rider, J. McBee, A. D. Miller and T. D. Tilley. Chem. Commun. 2009, 233.

Mechanistic Studies of Hydroamination of Norbornene with Electrophilic Platinum 319. Complexes: The Role of Proton Transfer. J. L. McBee, A. T. Bell and T. D. Tilley. J. Am. Chem. Soc. 2008, 130, 16562. Synthesis and characterization of 2,7-bis(pentafluorophenylethynyl)hexafluoro- 318. heterofluorenes: New materials with high electron affinities. K. Geramita, J. McBee, Y. Tao, R. A. Segalman and T. D. Tilley. Chem. Commun. 2008, 5107. Site-Isolated Pt-SBA15 Materials from Tris(tert-butoxy)siloxy Complexes of Pt(II) and 317. Pt(IV). D. A. Ruddy, J. Jarupatrakorn, R. M. Rioux, J. T. Miller, J. L. McBee, M. J. McMurdo, K. A. Tupper and T. D. Tilley. Chem. Mater. 2008, 20, 6517. Paramagnetic Vanadium Silyl Complexes: Synthesis, Structure and Reactivity. A. 316. Shinohara, J. McBee, R. Waterman and T. D. Tilley. Organometallics 2008, 27, 5717. 9,10-Disubstituted Octafluoroanthracene Derivatives via Palladium-Catalyzed Cross- 315. Coupling. J. F. Tannaci, M. Noji, J. McBee and T. D. Tilley. J. Org. Chem. 2008, 73, 7895. Kinetics and Mechanism of Olefin Epoxidation with Aqueous H2O2 and a Highly Selective 314. Surface-Modified TaSBA15 Heterogeneous Catalyst. D. A. Ruddy and T. D. Tilley. J. Am. Chem. Soc. 2008, 130, 11088. Alkene Hydrosilation by a Cationic Hydrogen–Substituted Iridium Silylene Complex. E. 313. Calimano and T. D. Tilley. J. Am. Chem. Soc. 2008, 130, 9226. The Influence of Surface Modification on the Epoxidation Selectivity and Mechanism of 312. TiSBA15 and TaSBA15 Catalysts with Aqueous Hydrogen Peroxide. D. A. Ruddy, R. L. Brutchey and T. D. Tilley. Topics in Catalysis 2008, 48, 99. Mechanism of Reversible Alkyne Coupling at Zirconocene: Ancillary Ligand Effects. A. D. 311. Miller, J. L. McBee and T. D. Tilley. J. Am. Chem. Soc. 2008, 130, 4992. DFT Investigation of the Catalytic Hydromethylation of Olefins by Scandocenes. 2. 310. Influence of the ansa Ligand on Propene and Isobutylene Hydromethylation. N. Barros, O. Eisenstein, L. Maron and T. D. Tilley. Organometallics 2008, 27, 2252. Alkyl and Hydrido Pt(IV) Complexes Supported by a Bis(8-quinolyl)methylsilyl Ligand. P. 309. Sangtrirutnugul and T. D. Tilley. Organometallics 2008, 27, 2223. Octa- and Nonamethylfluorenyl Complexes of Zr(II), Zr(IV), and Hf(IV). Investigation of 308. Steric and Electronic Effects. P. Bazinet and T. D. Tilley. Organometallics 2008, 27, 1267. 1,2-Phosphinoboranes as Amphoteric Ligands in Nickel-Methyl Complexes. A. Fischbach, 307. P. R. Bazinet, R. Waterman, and T. D. Tilley. Organometallics 2008, 27, 1135. Probing the Chemistry of Molecular Heterojunctions Using Thermoelectricity. K. Baheti, J. 306. A. Malen, P. Doak, P. Reddy, S.-Y. Jang, T. D. Tilley, A. Majumdar, and R. Segalman. Nano Lett. 2008, 8, 715.

Selective, Catalytic Cyclohexene Oxidation using Titanium-Functionalized Silicone 305. Nanospheres. C. A. Bradley, M. J. Meredith and T. D. Tilley. J. Phys. Chem. C. 2007, 111, 17570. Silyl Derivatives of [Bis(8-quinolyl)methylsilyl]iridium(III) Complexes: Catalytic 304. Redistribution of Arylsilanes and Dehydrogenative Arene Silylation. P. Sangtrirutnugul and T. Don Tilley. Organometallics 2007, 26, 5557. Highly Selective Olefin Epoxidation with Aqueous H2O2 over Surface-Modified TaSBA15 303. Prepared via the TMP Method. D. A. Ruddy and T. D. Tilley. Chem. Comm. 2007, 3350. Synthetic Development and Chemical Reactivity of Transition-Metal Silylene Complexes. 302. R. Waterman, P. G. Hayes and T. D. Tilley. Acc. Chem. Res. 2007, 40, 712. 9,10-Dichlorooctafluoroanthracene as a Building Block for n-Type Organic 301. Semiconductors. J. F. Tannaci, M. Noji, J. McBee and T. Don Tilley. J. Org. Chem. 2007, 72, 5567. Reverse Micelle Synthesis of Rhodium Nanoparticles. J. D. Hoefelmeyer, H. Liu, G. A. 300. Somorjai and T. D. Tilley. J. Coll. Int. Sci. 2007, 309, 86. Charge-Transfer Interaction of Poly(vinylpyrrolidone) with Platinum and Rhodium 299. Nanoparticles. Y. Borodko, S. M. Humphrey, T. D. Tilley, H. Frei and G. A. Somorjai. J. Phys. Chem. C. 2007, 111, 6288. Rhodium Nanoparticles from Cluster Seeds: Control of Size and Shape by Precursor 298. Addition Rate. S. M. Humphrey, M. E. Grass, S. E. Habas, K. Niesz, G. A. Somorjai and T. D. Tilley. Nano Lett. 2007, 7, 785. Photoinduced β-Hydrogen Elimination and Radical Formation with CpW(CO)3(CH2CH3): Ultrafast IR and DFT Studies. E. A. Glascoe, M. F. Kling, J. E. Shanoski, R. A. DiStasio, 297. Jr., C. K. Payne, B. V. Mork, T. D. Tilley and C. B. Harris. Organometallics 2007, 26, 1424.

296. Antimony-Antimony Bond Formation by Reductive Elimination from a Hafnium Bis(stibido) Complex. R. Waterman and T. D. Tilley. Inorg. Chem. 2006, 45, 9625. DFT Investigation of the Catalytic Hydromethylation of α-Olefins by Metallocenes. 1. 295. Differences between Scandium and Lutetium in Propene Hydromethylation. N. Barros, O. Eisenstein, L. Maron and T. D. Tilley. Organometallics 2006, 25, 5699. Selective Homo- and Heterodehydrocouplings of Phosphines Catalyzed by Rhodium 294. Phosphido Complexes. L.-B. Han and T. D. Tilley. J. Am. Chem. Soc. 2006, 128, 13698. Synthesis, Characterization and Reactivity of Tetramethylphospholyl Complexes of 293. Scandium. F.-G. Fontaine, K. A. Tupper and T. D. Tilley. J. Organomet. Chem. 2006, 691, 4595. Terminal stibinidene ligands. Generation of CpCp*Hf=Sb(dmp) and trapping reactions with 292. PMe3 and 3-butyne. R. Waterman and T. D. Tilley. Chem. Commun. 2006, 4030. Stoichiometric and Catalytic Reactions Involving Si-H Bond Activations by Rh and Ir 291. Complexes Containing a Pyridylindolide Ligand. D. Karshtedt, A. T. Bell and T. D. Tilley. Organometallics 2006, 25, 4471. Octa- and Nonamethylfluorene and an Electron-Rich Permethylfluorenyl Ruthenocene 290. Derivative. P. Bazinet, K. A. Tupper and T. D. Tilley. Organometallics 2006, 25, 4286. Synthesis of Polysilanyl Magnesium Compounds. W. Gaderbauer, M. Zirngast, J. 289. Baumgartner, C. Marschner and T. D. Tilley. Organometallics 2006, 25, 2599. Synthesis and Characterization of Perfluoroaryl-Substituted Siloles and Thiophenes: A 288. Series of Electron-Deficient Blue Light-Emitting Materials. K. Geramita, J. McBee, Y. Shen. N. S. Radu and T. D. Tilley. Chem. Mater. 2006, 18, 3261. Single Source Molecular Precursors to Niobia-Silica and Niobium Phosphate Materials. C. 287. G. Lugmair and T. D. Tilley. Monatshefte für Chemie 2006, 137, 557 (special issue to commemorate the 60th birthday of Prof. Ulrich Schubert). Catalytic Antimony-Antimony Bond Formation through Stibinidene Elimination from 286. Zirconocene and Hafnocene Complexes. R. Waterman and T. D. Tilley. Angew. Chem. Intl. Ed. 2006, 45, 2926. Stoichiometric and Catalytic Arene Activations by Pt Complexes Containing a Bidentate 285. Monoanionic Nitrogen-Based Ligand. D. Karshtedt, J. L. McBee, A. T. Bell and T. D. Tilley. Organometallics 2006, 25, 1801. Rhodium Complexes Containing a Tridentate Bis(8-quinolyl)methylsilyl Ligand: Synthesis 284. and Reactivity. P. Sangtrirutnugul, M. Stradiotto, and T. D. Tilley. Organometallics 2006, 25, 1607. Thermolytic Molecular Precursor Route to Site-Isolated Vanadia-Silica Materials and their 283. Catalytic Performance in Methane Partial Oxidation. D. A. Ruddy, N. L. Ohler, A. T. Bell, and T. D. Tilley. J. Catal. 2006, 238, 277. Hydrogen-Substituted Osmium Silylene Complexes: Effect of Charge Localization on 282. Catalytic Hydrosilation P. G. Hayes, C. Beddie, M. B. Hall, R. Waterman and T. D. Tilley. J. Am. Chem. Soc. 2006, 128, 428.

Synthesis, Structure, and α-Elimination Chemistry of Hafnocene Triarylstannyl 281. Complexes. N. R. Neale and T. D. Tilley. J. Am. Chem. Soc. 2005, 127, 14745. Synthesis and Characterization of Et2NM{OB[OSi(OtBu)3]2}3 (M = Zr, Hf) Molecular Precursors to Zr/B/Si/O and Hf/B/Si/O Materials. K. L. Fujdala and T. D. Tilley. Z. Anorg. 280. Allg. Chem. 2005, 631, 2619 (special issue to commemorate the 70th birthday of Prof. Herbert Roesky). Influence of Surface Modification of Ti-SBA15 Catalysts on the Epoxidation Mechanism 279. for Cyclohexene with Aqueous Hydrogen Peroxide. R. L. Brutchey, D. A. Ruddy, L. K. Andersen and T. D. Tilley. Langmuir 2005, 21, 9576. Transition Metals in Organosilicon Chemistry. In Organosilicon Chemistry VI - From 278. Molecules to Materials, N. Auner and J. Weis, Eds.; Wiley-VCH: Weinheim, Germany, 2005. T. D. Tilley, pp 382-391. Tailored Oxide Materials via Thermolytic Molecular Precursor (TMP) Methods. In Topics in Organometallic Chemistry 16: Surface and Interfacial Organometallic Chemistry and 277. Catalysis, C. Copéret and B. Chaudret, Eds.; Springer-Verlag: Heidelberg, 2005. K. L. Fujdala, R. L. Brutchey and T. D. Tilley, pp 69-115. Platinum-Based Catalysts for the Hydroamination of Olefins with Sulfonamides and 276. Weakly Basic Anilines. D. Karshtedt, A. T. Bell and T. D. Tilley. J. Am. Chem. Soc. 2005, 127, 12640. Control of Selectivity in the Hydromethylation of Olefins via Ligand Modification in 275. Scandocene Catalysts. F.-G. Fontaine and T. D. Tilley. Organometallics 2005, 24, 4340. New Fe/SiO2 Materials Prepared Using Diiron Molecular Precursors: Synthesis, 274. Characterization and Catalysis. A. W. Holland, G. Li, A. M. Shahin, G. J. Long, A. T. Bell and T. D. Tilley. J. Catal. 2005, 235, 150. Partial oxidation of methanol over highly dispersed vanadia supported on silica SBA-15. C. 273. Hess, I. J. Drake, J. D. Hoefelmeyer, T. D. Tilley and A. T. Bell. Catal. Lett. 2005, 105, 1. A dimeric molecular precursor [(tBuO)2Ti{μ-O2Si[OSi(OtBu)3]2}]2 to Ti(IV)/SiO2 272. catalysts for selective cyclohexene epoxidation. R. L. Brutchey, B. V. Mork, D. J. Sirbuly, P. Yang and T. D. Tilley. J. Molec. Catal. 2005, 238, 1. Liquid phase oxidation of alkylaromatics by an H-atom transfer mechanism with a new 271. heterogeneous CoSBA15 catalyst. R. L. Brutchey, I. J. Drake, A. T. Bell and T. D. Tilley. Chem. Commun. 2005, 3736. Synthesis and characterization of scandium complexes with reduced ligands. Crystal 270. structures of Cp*ScI2, [Cp*ScI(bpy)]2, and [Cp*ScCl(bpy)]2 K. A. Tupper and T. D. Tilley. J. Organomet. Chem. 2005, 690, 1689. Dimethyl carbonate production via the oxidative carbonylation of methanol over Cu/SiO2 269. catalysts prepared via molecular precursor grafting and chemical vapor deposition approaches. I. J. Drake, K. L. Fujdala, A. T. Bell and T. D. Tilley. J. Catal. 2005, 230, 14. Synthesis and Characterization of MoO[OSi(OtBu)3]4 and MoO2[OSi(OtBu)3]2 (M = Mo, W): Models for Isolated Oxo-Molybdenum and –Tungsten Sites on Silica and Precursors to 268. Molybdenum- and Tungsta-Silica Materials. J. Jarupatrakorn, M. P. Coles and T. D. Tilley. Chem. Mater. 2005, 17, 1818. Radial Anisotropic Growth of Rhodium Nanoparticles. J. D. Hoefelmeyer, K. Niesz, G. A. 267. Somorjai and T. D. Tilley. Nano Lett. 2005, 5, 435. 266. Synthesis and Characterization of Scandium Silyl Complexes of the Type Cp*2ScSiHRR'. α-Bond Metathesis Reactions and Catalytic Dehydrogenative Silation of Hydrocarbons. A. D. Sadow and T. D. Tilley. J. Am. Chem. Soc. 2005, 127, 643. Thermolytic Conversion of a Bis(alkoxy)tris(siloxy)tantalum(V) Single-Source Molecular 265. Precursor to Catalytic Tantala-Silica Materials. R. L. Brutchey, C. G. Lugmair, L. O. Schebaum and T. D. Tilley. J. Catal. 2005, 229, 72.

Effects of additives on the activity and selectivity of supported vanadia catalysts for the 264. oxidative dehydrogenation of propane. H. X. Dai, L. Chen, T. D. Tilley, E. Iglesia and A. T. Bell. Studies in Surface Science and Catalysis 2004, 147, 679. Synthesis and Reactivity of Ti(III) Tris(tert-butoxy)siloxy Complexes. C. G. Lugmair and 263. T. D. Tilley. Zeitschrift für Naturforschung 2004, 59b, 1540 (special issue to commemorate the 70th birthday of Prof. Hubert Schmidbaur). Synthesis and Reactivity of Silyl and Silylene Ligands in the Coordination Sphere of the 14- 262. Electron Fragment Cp*(iPr3P)Os+. P. B. Glaser and T. D. Tilley. Organometallics 2004, 23, 5799. Effects of Precursor Composition on the Local Structure of Cu Dispersed on Mesoporous 261. Silica: A Detailed X-ray Absorption Spectroscopy Study. I. J. Drake, K. L. Fujdala, S. Baxamusa, A. T. Bell and T. D. Tilley. J. Phys. Chem. B 2004, 108, 18421. C-H Bond Activation by Iridium and Rhodium Complexes: Catalytic Hydrogen-Deuterium Exchange and C-C Bond-Forming Reactions. In Activation and Functionalization of C-H 260. Bonds, ACS Symposium Series 885, K. I. Goldberg and A. S. Goldman, Eds.; American Chemical Society, Washington, 2004. S. R. Klei, K. L. Tan, J. T. Golden, C. M. Yung, R. K. Thalji, K. A. Ahrendt, J. A. Ellman, T. D. Tilley, and R. G. Bergman, Chap. 2, p. 46. Unusual Ar-H/Rh-H JHH NMR Coupling in Complexes of Rhodium(III): Experimental Evidence and Theoretical Support for an η1-Arene Structure. J. R. Krumper, M. Gerisch, A. 259. Magistrato, U. Röthlisberger, R. G. Bergman and T. D. Tilley. J. Am. Chem. Soc. 2004, 126, 12492. Atomic Level Control Over Surface Species via a Molecular Precursor Approach: Isolated 258. Cu(I) Sites and Cu Nanoparticles Supported on Mesoporous Silica. K. L. Fujdala, I. J. Drake, A. T. Bell and T. D. Tilley. J. Am. Chem. Soc. 2004, 126, 10864. Pt-Ag Catalyst System for Hydroarylations with Unactivated Arenes and Olefins. D. 257. Karshtedt, A. T. Bell and T. D. Tilley. Organometallics 2004, 23, 4169. Silylene Hydride Complexes of Molybdenum with Silicon-Hydrogen Interactions. Neutron 256. Structure of (η5-C5Me5)(Me2PCH2CH2PMe2)Mo(H)(SiEt2). B. V. Mork, T. D. Tilley, A. J. Schultz and J. A. Cowan. J. Am. Chem. Soc. 2004, 126, 10428. Synthesis and Characterization of {(diene)Rh[µ-OSi(OtBu)3]}2, a Model for Silica-Bound 255. Rhodium. J. Jarupatrakorn and T. D. Tilley. Dalton Trans. 2004, 2808. Reactions of hafnocene stannyl complexes with stannanes: implications for the mechanism 254. of the metal-catalyzed dehydropolymerization of secondary stannanes. N. R. Neale and T. D. Tilley. Tetrahedron 2004, 60, 7247. Oxidative Dehydrogenation of Propane over Vanadia Based Catalysts Supported on High- 253. Surface-Area Mesoporous MgAl2O4. O. R. Evans, A. T. Bell and T. D. Tilley. J. Catal. 2004, 226, 292. Spectroscopic Characterization of Highly Dispersed Vanadia Supported on SBA-15 Silica. 252. C. Hess, J. D. Hoefelmeyer and T. D. Tilley. J. Phys. Chem. B 2004, 108, 9703. Synthesis and Reactivity of Tris(imido) Rhenium Complexes Containing Rhenium-Main 251. Group Element Bonds. Silicon-Carbon Bond Activations of PhSiH3 by Silyl Complexes. J. Gavenonis and T. D. Tilley. Inorg. Chem. 2004, 43, 4353. The [(η5-C5Me5)(2,2'-bipyridine)Ru]- Anion, and its Use in the Synthesis of Alkyl, Gallyl, 250. and Stannyl Complexes of Ruthenium. B. V. Mork, A. McMillan, H. Yuen and T. D. Tilley. Organometallics 2004, 23, 2855. Coordination Chemistry and Reactivity of New Zwitterionic Rhodium and Iridium Complexes Featuring the Tripodal Phosphine Ligand [PhB(CH2PiPr2)3]-. Activation of H- 249. H, Si-H, and Ligand B-C Bonds. L. Turculet, J. D. Feldman and T. D. Tilley. Organometallics 2004, 23, 2488. Synthons for Coordinatively Unsaturated Complexes of Tungsten, and their Use for the 248. Synthesis of High Oxidation-State Silylene Complexes. B. V. Mork and T. D. Tilley. J. Am. Chem. Soc. 2004, 126, 4375. Dimolybdenum(III) Complexes of -OSi(OtBu)3, -O2P(OtBu)2 and -OB[OSi(OtBu)3]2 as 247. Single-Source Molecular Precursors to Molybdenum-Containing, Multi-Component Oxide Materials. K. L. Fujdala and T. D. Tilley. Chem. Mater. 2004, 16, 1035. Probing the Structure of the Silylene Complex (Cy3P)2Pt=SiMes2. UV-Vis and 246. Preresonance Raman Investigations. S. S. Bukalov, I. A. Garbuzova, L. A. Leites, J. D. Feldman and T. D. Tilley. Spectrochim. Acta Part A 2004, 60, 801. Synthesis and Reactivity of d0 Alkyl, Silyl, and Hydride Complexes of Titanium and 245. Zirconium Featuring an Aryl-Substituted Tripodal Triamide Ligand Derived from cis-cis- 1,3,5-Triaminocyclohexane. L. Turculet and T. D. Tilley. Organometallics 2004, 23, 1542. Synthesis, Structure, and Reactivity of Osmium Silyl and Silylene Complexes 244. Cp*(Me3P)2OsSiR2X and [Cp*(Me3P)2OsSiR2][B(C6F5)4] (R= Me, iPr; X = Cl, OTf). P. B. Glaser, P. W. Wanandi and T. D. Tilley. Organometallics 2004, 23, 693. Synthesis and reactivity of bis(heptamethylindenyl)yttrium (Ind*2Y) complexes containing 243. alkyl and hydride ligands: crystal structure of Ind*2YCl(THF). J. Gavenonis and T. D. Tilley. J. Organomet. Chem. 2004, 689, 870. Activated Boron Nitride Derived From Activated Carbon. W.Q. Han, R. Brutchey, T. D. 242. Tilley and A. Zettl. Nano Lett., 2004, 4, 173. Synthesis and Reactivity of Alkyl, Hydride, and Silyl Derivatives of the (Terphenyl)imido Fragments Cp*(ArMesN=)Ta (Cp* = η5-C5Me5; ArMes = 2,6-(2,4,6-Me3C6H2)2C6H3) 241. and Cp*(ArTripN=)Ta (ArTrip = 2,6-(2,4,6-iPr3C6H2)2C6H3). J. Gavenonis and T. D. Tilley. Organometallics 2004, 23, 31.

Catalytic Hydrosilylation of Alkenes by a Ruthenium Silylene Complex. Evidence for a 240. New Hydrosilylation Mechanism.P. B. Glaser and T. D. Tilley. J. Am. Chem. Soc. 2003, 125, 13640. Monomeric Rhodium(II) Catalysts for the Preparation of Aziridines and Enantioselective 239. Formation of Cyclopropanes from Ethyl Diazoacetate at Room Temperature. J. R. Krumper, M. Gerisch, J. M. Suh, R. G. Bergman and T. D. Tilley. J. Org. Chem. 2003, 68, 9705. Coordinatively and Electronically Unsaturated Zwitterionic Iron Silyl Complexes Featuring 238. the Tripodal Phosphine Ligand [PhB(CH2PiPr2)3]-. L. Turculet, J. D. Feldman and T. D. Tilley. Organometallics 2003, 22, 4627. Synthesis and study of platinum silylene complexes of the type (R3P)2Pt=SiMes2 (Mes = 237. 2,4,6-trimethylphenyl). J. D. Feldman, G. P. Mitchell, J.-O. Nolte and T. D. Tilley. Can. J. Chem. 2003, 81, 1127. Tailoring Properties of Silicon-Containing Oxide Catalysts via the Thermolytic Molecular Precursor Route. In Organosilicon Chemistry V - From Molecules to Materials, N. Auner 236. and J. Weis, Eds.; K. L. Fujdala and T. D. Tilley; Wiley-VCH, Weinheim, Germany, p. 379-388. Cationic Hafnium Silyl Complexes and their Enhanced Reactivity in σ-Bond Metathesis 235. Processes with Si-H and C-H Bonds. A. D. Sadow and T. D. Tilley. J. Am. Chem. Soc. 2003, 125, 9462. Enhanced Reactivity of Cationic Hafnocene Complexes towards σ-Bond Metathesis 234. Reactions. Si–H and Si–C Bond Activations in Stoichiometric and Catalytic Organosilane Conversions. A. D. Sadow and T. D. Tilley. Organometallics 2003, 22, 3577. Synthesis and Study of Heterobimetallic Complexes Supported by a Ferrocene-Based 233. Bisphosphine-Diamine Ligand. D. Karshtedt, A. T. Bell and T. D. Tilley. Organometallics 2003, 22, 2855. Homogeneous Catalysis with Methane. A Strategy for the Hydromethylation of Olefins 232. Based on the Nondegenerate Exchange of Alkyl Groups and σ-Bond Metathesis at Scandium. A. D. Sadow and T. D. Tilley. J. Am. Chem. Soc. 2003, 125, 7971. Thermolytic Molecular Precursor Routes to Cr/Si/Al/O and Cr/Si/Zr/O Catalysts for the 231. Oxidative Dehydrogenation and Dehydrogenation of Propane. K. L. Fujdala and T. D. Tilley. J. Catal. 2003, 218, 123. Design and synthesis of heterogeneous catalysts: the thermolytic molecular precursor 230. approach. K. L. Fujdala and T. D. Tilley. J. Catal. 2003, 216, 265. Regioselective Coupling of Pentafluorophenyl Substituted Alkynes: Mechanistic Insight into the Zirconocene Coupling of Alkynes and a Facile Route to Conjugated Polymers 229. Bearing Electron-Withdrawing Pentafluorophenyl Substituents. S. A. Johnson, F.-Q. Liu, M. C. Suh, S. Zürcher, M. Haufe, S. S. H. Mao and T. D. Tilley. J. Am. Chem. Soc. 2003, 125, 4199. Rhodium(III) and Rhodium(II) Complexes of Novel Bis(Oxazoline) Pincer Ligands. M. 228. Gerisch, J. R. Krumper, R. G. Bergman and T. D. Tilley. Organometallics 2003, 22, 47. Nonaqueous, Molecular Precursor Route to Hybrid Inorganic/Organic Zirconia-Silica 227. Materials Containing Covalently Linked Organic Bridges. R. L. Brutchey and T. D. Tilley. Chem. Mater. 2003, 15, 1040. Synthesis of chelating, C2-symmetric bis(silylamido) complexes of zirconium, and their 226. activities as olefin polymerization catalysts. T. I. Gountchev and T. D. Tilley. Inorg. Chim. Acta 2003, 345, 81. Catalytic Functionalization of Hydrocarbons via σ-Bond Metathesis 225. Chemistry: Dehydrosilylation of Methane with a Scandium Catalyst. A. D. Sadow and T. D. Tilley. Angew. Chem. Int. Ed. 2003, 42, 803. Tris(tert-butoxy)siloxy Derivatives of Boron, Including the Boronous Acid HOB[OSi(OtBu)3]2 and the Metal (Siloxy)boryloxide Complex 224. Cp2Zr(Me)OB[OSi(OtBu)3]2. A Remarkable Crystal Structure with 18 Independent Molecules in its Asymmetric Unit. K. L. Fujdala, A. G. Oliver, F. J. Hollander and T. D. Tilley. Inorg. Chem. 2003, 42, 1140. Multiple Bonding Between Silicon and Molybdenum: A Transition Metal Complex with 223. Considerable Silylyne Character. B. V. Mork and T. D. Tilley. Angew. Chem. Int. Ed. 2003, 42, 357. Convenient, Zirconocene-Coupling Routes to Germole- and Thiophene-Containing 222. Macrocycles with Triangular Geometries. J. R. Nitschke and T. D. Tilley. J. Organomet. Chem. 2003, 666, 15.

Iridium(III) and Rhodium(III) Complexes Bearing Chelating Cyclopentadienyl-Phosphine 221. Ligands as C-H Activation Catalysts for the Deuteration of Hydrocarbons in D2O. S. R. Klei, T. D. Tilley and R. G. Bergman. Organometallics 2002, 21, 4905. Tantalum Alkyl and Silyl Complexes of the Bulky (Terphenyl)imido Ligand [2,6-(2,4,6- Me3C6H2)2C6H3N=]2- ([Ar*N=]2-). Generation and Reactivity of [(Ar*N=)(Ar*NH)Ta– 220. (H)(OSO2CF3)], which Reversibly Transfers Hydride to an Aromatic Ring of the Arylamide Ligand. J. Gavenonis and T. D. Tilley. Organometallics 2002, 21, 5549. Coordinatively and electronically unsaturated tris(trimethylsilyl)silyl complexes of 219. manganese and iron. R. H. Heyn and T. D. Tilley. Inorg. Chim. Acta 2002, 341, 91. Stoichiometric and Catalytic Behavior of Cationic Silyl and Silylene Complexes. S. R. 218. Klei, T. D. Tilley and R. G. Bergman. Organometallics 2002, 21, 4648. Synthesis, Characterization, and Catalytic Performance of Single-Site Iron(III) Centers on 217. the Surface of SBA-15 Silica. C. Nozaki, C. G. Lugmair, A. T. Bell and T. D. Tilley. J. Am. Chem. Soc. 2002, 124, 13194. Activations of Silanes with [PhB(CH2PPh2)3]Ir(H)(η3-C8H13). Formation of Iridium 216. Silylene Complexes via the Extrusion of Silylenes from Secondary Silanes R2SiH2. J. D. Feldman, J. C. Peters and T. D. Tilley. Organometallics 2002, 21, 4065. Structural and Chemical Properties of Zwitterionic Iridium Complexes Featuring the 215. Tripodal Phosphine Ligand [PhB(CH2PPh2)3]-. J. D. Feldman, J. C. Peters and T. D. Tilley. Organometallics 2002, 21, 4050. Zirconium Amide, Halide, and Alkyl Complexes Supported by Tripodal Amido Ligands 214. Derived from cic,cis-1,3,5-Triaminocyclohexane. L. Turculet and T. D. Tilley. Organometallics 2002, 21, 3961. Reactions of Cp*(PMe3)Ir(Me)OTf with Silanes: Role of Base-Free Silylene Complexes in 213. Rearrangements of the Resulting Silicon-Based Ligands. S. R. Klei, T. Don Tilley and R. G. Bergman. Organometallics 2002, 21, 3376. Neutral and Anionic Silyl Hydride Derivatives of the Tantalum Imido Fragment Cp*(DippN=)Ta (Cp* = η5-C5Me5; Dipp = 2,6-iPr2C6H3). Reactive σ-Bonds and 212. Intramolecular C-H Bond Activations Involving the Silyl Ligands. U. Burckhardt, G. L. Casty, J. Gavenonis and T. D. Tilley. Organometallics 2002, 21, 3108. 211. Reversible Intramolecular Hydride Transfer between Tantalum and an Aromatic Ring. An η5-Cyclohexadienyl Complex as a Masked Hydride. J. Gavenonis and T. D. Tilley. J. Am. Chem. Soc. 2002, 124, 8536. Silica-Supported, Single-Site Titanium Catalysts for Olefin Epoxidation. A Molecular 210. Precursor Strategy for Control of Catalyst Structure. J. Jarupatrakorn and T. D. Tilley. J. Am. Chem. Soc. 2002, 124, 8380. Activation of Arene C-H Bonds by a Cationic Hafnium Silyl Complex Possessing an α- 209. Agostic Si-H Interaction. A. D. Sadow and T. D. Tilley. J. Am. Chem. Soc. 2002, 124, 6814. Synthesis and Reactivity of η5-Germacyclopentadienyl Complexes of Iron. W. P. Freeman, 208. J. M. Dysard, T. D. Tilley and A. L. Rheingold. Organometallics 2002, 21, 1734. A New Mechanism for Metal-Catalyzed Stannane Dehydrocoupling Based on α-H- 207. Elimination in a Hafnium Hydrostannyl Complex. N. R. Neale and T. D. Tilley. J. Am. Chem. Soc. 2002, 124, 3802. New Vanadium Tris(tert-butoxy)siloxy Complexes and Their Thermolytic Conversions to 206. Vanadia-Silica Materials. K. L. Fujdala and T. D. Tilley. Chem. Mater. 2002, 14, 1376. Iridium-Catalyzed H/D Exchange into Organic Compounds in Water. S. R. Klei, J. T. 205. Golden, T. D. Tilley, and R. G. Bergman. J. Am. Chem. Soc. 2002, 124, 2092. Hafnium imido complexes containing silyl ligands. I. Castillo and T. D. Tilley. J. 204. Organomet. Chem. 2002, 643-644, 431. New Tris(tert-butoxy)siloxy Complexes of Aluminum and Their Transformation to 203. Homogeneous Aluminosilicate Materials via Low Temperature Thermolytic Pathways. C. G. Lugmair, K. L. Fujdala and T. D. Tilley. Chem. Mater. 2002, 14, 888. Order-Disorder Phase Transition in Poly(di-n-butylstannane) Observed by UV-Vis and 202. Raman Spectroscopy. S. S. Bukalov, L. A. Leites, V. Lu and T. D. Tilley. Macromolecules 2002, 35, 1757. Oxidative Dehydrogenation of Propane over Vanadia-Magnesia Catalysts Prepared by 201. Thermolysis of OV(OtBu)3 in the Presence of Nanocrystalline MgO. C. Pak, A. T. Bell and T. D. Tilley. J. Catal. 2002, 206, 49. Coordination of 2,2'-Bipyridyl and 1,10-Phenanthroline to Substituted Ytterbocenes: An 200. Experimental Investigation of Spin Coupling in Lanthanide Complexes. M. Schultz, J. M. Boncella, D. J. Berg, T. D. Tilley and R. A. Andersen. Organometallics 2002, 21, 460. Zirconocene-Mediated, High-Yielding Macrocyclizations of Silyl-Terminated Diynes. L. 199. L. Schafer, J. R. Nitschke, S. S. H. Mao, F.-Q. Liu, G. Harder, M. Haufe and T. D. Tilley. Chem. Eur. J. 2002, 8, 74. Molecular Design and Synthesis of Heterogeneous and Single-Site, Supported Catalysts. T. 198. D. Tilley. J. Molec. Catal. A: Chem. 2002, 182-183, 17.

Organolutetium Complexes in σ-Bond Metathesis Reactions Involving Silicon. Catalysts 197. for the Hydrogenolysis of Si-C Bonds. I. Castillo and T. D. Tilley. Organometallics 2001, 20, 5598. Reactions of Zirconacyclopentadienes with Nitrosobenzene. Characterization of 196. Zirconacycle Intermediates and Formation of N-Phenylpyrroles. M. Nakamoto and T. D. Tilley. Organometallics 2001, 20, 5515. Generation and Reactivity of {(Ethane-1,2-diyl)bis[diisopropylphosphine-κP]}-{[2,4,6- tri(tert-butyl)phenyl]phosphino-κP}rhodium ([Rh{PH(tBu3C6H2)}(iPr2PCH2CH2PiPr2)]): Catalytic C−P Bond Formation via 195. Intramolecular C−H/P−H Dehydrogenative Cross-Coupling. M. Stradiotto, K. L. Fujdala and T. D. Tilley. Helv. Chim. Acta 2001, 84, 2958 (memorial issue for Professor Luigi Venanzi). Carbosilane Dendrimers as Nanoscopic Building Blocks for Hybrid Organic-Inorganic 194. Materials and Catalyst Supports. J. W. Kriesel and T. D. Tilley. Adv. Mater. 2001, 13, 1645. Mechanistic Aspects of Samarium-Mediated σ-Bond Activations of Arene C-H and 193. Arylsilane Si-C Bonds. I. Castillo and T. D. Tilley. J. Am. Chem. Soc. 2001, 123, 10526. Enhanced Reactivity of Cationic vs. Neutral Hafnocene Complexes in Stoichiometric and 192. Catalytic σ-Bond Metathesis Reactions Involving Si-H and Si-C Bonds. A. Sadow and T. D. Tilley. Organometallics 2001, 20, 4457. Efficient, High-Yield Route to Long, Functionalized p-Paraphenylene Oligomers 191. Containing Perfluorinated Segments, and Their Cyclodimerizations by Zirconocene Coupling. J. R. Nitschke and T. D. Tilley. J. Am. Chem. Soc. 2001, 123, 10183. Block Copolymer Assisted Synthesis of Mesoporous, Multicomponent Oxides by Non- 190. hydrolytic, Thermolytic Decomposition of Molecular Precursors in Nonpolar Media. J. W. Kriesel, M. S. Sander and T. Don Tilley. Chem. Mater. 2001, 13, 3554. An Efficient, Single-Source Molecular Precursor to Silicoaluminophosphates. K. L. Fujdala 189. and T. D. Tilley. J. Am. Chem. Soc. 2001, 123, 10133. High Oxidation-State (Formally d0) Tungsten Silylene Complexes via Double Si-H Bond 188. Activation. B. V. Mork and T. D. Tilley. J. Am. Chem. Soc. 2001, 123, 9702. Synthesis and Chemistry of the 16-Electron Osmium Complex (η5-C5Me5)(iPr3P)OsBr. P. 187. B. Glaser and T. D. Tilley. Eur. J. Inorg. Chem. 2001, 2747. Synthesis, Structure and Hydrosilylation Catalysis of a Chiral A-Frame Rhodium(I) Dimer 186. with Cis-Diphosphite Ligands. S. Ini, A. G. Oliver, T. D. Tilley and R. G. Bergman. Organometallics 2001, 20, 3839. An Observable Silene/Silylene Rearrangement in a Cationic Iridium Complex. S. R. Klei, 185. R. G. Bergman and T. D. Tilley. Organometallics 2001, 20, 3220. Intramolecular Rearrangements on Ultrafast Timescales: Femtosecond Infrared Studies of 184. Ring Slip in (η1-C5Cl5)Mn(CO)5. C. K. Payne, P. T. Snee, H. Yang, K. T. Kotz, L. L. Schafer, T. D. Tilley and C. B. Harris. J. Am. Chem. Soc. 2001, 123, 7425. Novel Bis(oxazoline) Pincer Ligands: Formation of Mononuclear Rhodium(II) 183. Complexes. M. Gerisch, J. R. Krumper, R. G. Bergman and T. D. Tilley. J. Am. Chem. Soc. 2001, 123, 5818. Iridium(III) complexes of the new tridentate bis(8-quinolyl)silyl (NSiN) ligand. M. 182. Stradiotto, K. L. Fujdala and T. D. Tilley. Chem. Commun. 2001, 1200. Thermolytic Transformation of Tris(alkoxy)siloxychromium(IV) Single-Source Molecular 181. Precursors to Catalytic Chromia-Silica Materials. K. L. Fujdala and T. D. Tilley. Chem. Mater. 2001, 13, 1817. 180. Novel Templating Effect in the Macrocyclization of Functionalized Diynes via Zirconocene Coupling. J. R. Nitschke and T. D. Tilley. Angew. Chem., Int. Ed. Engl. 2001, 40, 2142. Efficient Diastereoselective Syntheses of Chiral Macrocycles via Zirconocene- 179. Coupling. Synthetic Control of Size and Geometry. L. L. Schafer and T. D. Tilley. J. Am. Chem. Soc. 2001, 123, 2683. Silabenzene and Disilabenzene Complexes of Ruthenium. J. M. Dysard, T. D. Tilley and T. 178. K. Woo. Organometallics 2001, 20, 1195. A new molecular precursor for magnesia-silica materials. J. W. Kriesel and T. Don 177. Tilley. J. Mater. Chem. 2001, 11, 1081. General Route to Homogeneous, Mesoporous, Multicomponent Oxides Based on the 176. Thermolytic Transformation of Molecular Precursors in Nonpolar Media. J. W. Kriesel, M. S. Sander and T. Don Tilley. Adv. Mater. 2001, 13, 331.

Synthesis of Sm-SiH3 Complexes via σ-Bond Metathesis of the Si-C bond of 175. Phenylsilane. I. Castillo and T. D. Tilley. Organometallics 2000, 19, 4733. Synthesis and Reactivity of Pentamethylcyclopentadienyl Ruthenium Complexes of the 174. Stable Neutral Silylene Si(tBuNCH=CHNtBu). J. M. Dysard and T. D. Tilley. Organometallics 2000, 19, 4726. Tantalum-Mediated Substitution at Germanium: A Germolyl-to-Germole Transformation 173. Leading to η4-C4Me4GeMeCl Complexes. J. M. Dysard and T. D. Tilley. Organometallics 2000, 19, 4720. New Zirconocene-Coupling Route to Large, Functionalized Macrocycles. J. R. Nitschke, S. 172. Zürcher and T. D. Tilley. J. Am. Chem. Soc. 2000, 122, 10345. Ditantalum Hydride Complexes with Bridging (2,6-iPr2C6H3)NSiHPh Silanimine Ligands Resulting from PhSiH3-Imido Ligand Coupling. A Combined Spectroscopic and 171. Theoretical Investigation. U. Burckhardt, G. L. Casty, T. D. Tilley, T. K. Woo and U. Rothlisberger. Organometallics 2000, 19, 3830. Thermolytic Molecular Precursor Route to Active and Selective Vanadia-Zirconia Catalysts 170. for the Oxidative Dehydrogenation of Propane. J. L. Male, H. G. Niessen, A. T. Bell, and T. D. Tilley. J. Catal. 2000, 194, 431. Poly(2,5-diphenylgermole): Incorporation of a Germole Ring into a Conjugated 169. Polymer. B. L. Lucht, M. A. Buretea, and T. D. Tilley. Organometallics 2000, 19, 3469. Hafnium-Rhodium and Hafnium-Iridium Heterobimetallic Complexes Featuring the 168. Bridging Germole Dianion Ligand [GeC4Me4]2-. J. M. Dysard and T. D. Tilley. Organometallics 2000, 19, 2671. An Efficient, Modular Synthetic Route to Oligomers Based on Zirconocene- Coupling. Properties for Phenylene-Thiophene-1-Oxide and Phenylene-Thiophene-1,1- 167. Dioxide Chains. M. C. Suh, B. Jiang and T. D. Tilley. Angew. Chem. Int. Ed. Engl. 2000, 39, 2870. The first structurally characterised oligosilylmagnesium compound. J. D. Farwell, M. F. 166. Lappert, C. Marschner, C. Strissel and T. D. Tilley. J. Organomet. Chem. 2000, 603, 185. Synthesis and Chemical Functionalization of High Surface Area Dendrimer-Based Xerogels 165. and Their use as New Catalyst Supports. J. W. Kriesel and T. D. Tilley. Chem. Mater. 2000, 12, 1171. Synthesis and Reactivity of η5-Silolyl, η5-Germolyl and η5-Germole Dianion Complexes 164. of Zirconium and Hafnium. J. M. Dysard and T. D. Tilley. J. Am. Chem. Soc. 2000, 122, 3097. Poly(diaryl)stannanes: Influence of Substituents on the σ-σ* Transition Energy. V. Y. Lu 163. and T. D. Tilley. Macromolecules 2000, 33, 2403. Synthesis of Novel Conjugated Polymers for Potential LED Applications. B. Jiang and T. 162. D. Tilley. Polym. Prepr., (Am. Chem. Soc. Div. Polym. Chem.) 2000, 41(1), 829. Hybrid Organic-Inorganic Gels Based on Dendrimeric Building Blocks: High Surface Area 161. Xerogels as Catalyst Supports. J. W. Kriesel and T. D. Tilley. Polym. Prepr., (Am. Chem. Soc. Div. Polym. Chem.) 2000, 41(1), 566. Versatile Zirconocene-Coupling Pathway to Conjugated Polymers with a Range of 160. Structural and Electronic Properties. T. D. Tilley and B. Jiang. Polym. Prepr., (Am. Chem. Soc. Div. Polym. Chem.) 2000, 41(1), 418. Synthesis and Structure of the (Tetrahydroxy)oligosiloxane [(tBuO)3SiOSi(OH)2]2O. R. 159. Rulkens, M. P. Coles, and T. D. Tilley. Dalton Trans. 2000, 627. The Mechanism of Silicon-Hydrogen and Carbon-Hydrogen Bond Activation by Iridium(III): Production of a Silylene Complex, and the First Direct Observation of 158. Ir(III)/Ir(V) C-H Bond Oxidative Addition and Reductive Elimination. S. R. Klei, T. D. Tilley, and R. G. Bergman. J. Am. Chem. Soc. 2000, 122, 1816. Reactivity of an Osmium Silylene Complex towards Chlorocarbons. Promotion of Metal 157. Redox Chemistry by a Silylene Ligand, and Relevance to the Mechanism of the Direct Process. P. W. Wanandi, P. B. Glaser, and T. D. Tilley. J. Am. Chem. Soc. 2000, 122, 972. Titania-Silica Materials from the Molecular Precursor Ti[OSi(OtBu)3]4: Selective 156. Epoxidation Catalysts. M. P. Coles, C. G. Lugmair, K. W. Terry, and T. D. Tilley. Chem. Mater. 2000, 12, 122.

Hydrosilylation Catalysis by C2-Symmetric Bis(silylamido) Complexes of Yttrium. T. I. 155. Gountchev and T. D. Tilley. Organometallics 1999, 18, 5661. Silylene Extrusion from a Silane. Direct Conversion of Mes2SiH2 to an Iridium Silylene 154. Dihydride. J. C. Peters, J. D. Feldman, and T. D. Tilley. J. Am. Chem. Soc. 1999 121, 9871. General, Efficient Route to Thiophene-1-Oxides and Well-Defined, Mixed Thiophene- 153. Thiophene-1-Oxide Oligomers. B. Jiang and T. D. Tilley. J. Am. Chem. Soc. 1999, 121, 9744. Vanadyl tert-Butoxy Orthosilicate, OV[OSi(OtBu)3]3: A Model for Isolated Vanadyl Sites on Silica and a Precursor to Vanadia-Silica Xerogels. R. Rulkens, J. L. Male, K. W. Terry, 152. B. Olthof, A. Khodakov, A. T. Bell, E. Iglesia, and T. D. Tilley. Chem. Mater. 1999, 11, 2966. Yttrium Complexes of the Chelating, C2-Symmetric, Bis(silylamido)biphenyl Ligand 151. [DADMB]2- {=[6,6'-Me2-(C6H3)2](2,2'-NSiMe2tBu)2}2-. T. I. Gountchev and T. D. Tilley. Organometallics 1999, 18, 2896. Carbonylation Chemistry of the Tantalum Silyl Hydride Cp*(2,6-iPr2C6H3N=)– 150. Ta[Si(SiMe3)3]H: The Unexpected Formation of a Ta(V) Carbonyl Complex and the Complete Reduction of CO. U. Burckhardt and T. D. Tilley. J. Am. Chem. Soc. 1999, 121, 6328. Di(tert-butyl)phosphate Complexes of Aluminum. Precursors to Aluminum Phosphate 149. Xerogels and Thin Films. C. G. Lugmair, T. D. Tilley, and A. L. Rheingold. Chem. Mater. 1999, 11, 1615. Strained, Ring Tilted Dicarbon-bridged [2]Ferrocenophanes and Ferrocene Revisited: 57Fe Mössbauer Spectroscopic Study of Bonding, Hyperfine Interactions, and Lattice 148. Dynamics. R. H. Herber, K. Temple, I. Manners, M. Buretea, T. D. Tilley. Inorg. Chim. Acta 1999, 287, 152. Dendrimers as Building Blocks for Nanostructured Materials: Micro- and Mesoporosity in 147. Dendrimer-Based Xerogels. J. Kriesel and T. D. Tilley. Chem. Mater. 1999, 11, 1190.

Synthesis and Study of Ruthenium Silylene Complexes of the Type [(η5- 146. C5Me5)(Me3P)2Ru=SiR2]+. S. K. Grumbine, G. P. Mitchell, D. A. Straus, T. D. Tilley, and A. L. Rheingold. Organometallics 1998, 17, 5607. Synthesis of Highly Charged Organometallic Dendrimers and their Characterization by Electrospray Mass Spectrometry and Single Crystal X-ray Diffraction. J. W. Kriesel, S. 145. König, M. A. Freitas, A. G. Marshall, J. A. Leary, and T. D. Tilley. J. Am. Chem. Soc. 1998, 120, 12207. Layered Zincophosphate Materials Prepared from a Molecular Zinc Di(tert-butyl)phosphate 144. Complex in Organic Solvents. C. G. Lugmair and T. D. Tilley. Inorg. Chem. 1998, 37, 6304. Isolation and Characterization of Neutral Platinum Silylene Complexes of the Type 143. (R3P)2Pt=SiMes2 (Mes = 2,4,6-Trimethylphenyl). J. Feldman, G. P. Mitchell, J.-O. Nolte, and T. D. Tilley. J. Am. Chem. Soc. 1998, 120, 11184. A Molecular Precursor Route to Active and Selective Vanadia-Silica-Zirconia 142. Heterogeneous Catalysts for the Oxidative Dehydrogenation of Propane. R. Rulkens and T. D. Tilley. J. Am. Chem. Soc. 1998, 120, 9959. Generation of a Silylene Complex via the 1,2-Migration of Hydrogen from Silicon to 141. Platinum. G. P. Mitchell and T. D. Tilley. Angew. Chem. Int. Ed. Engl. 1998, 37, 2524. Zirconocene-Coupling Routes to Conjugated Polymers: Soluble 140. Poly(arylenedienylene)s. B. L. Lucht and T. D. Tilley. Chem. Commun. 1998, 1645. η5-Silolyl and η5-Germolyl Complexes of d0 Hafnium. Structural Characterization of an 139. η5-Silolyl Complex. J. M. Dysard and T. D. Tilley. J. Am. Chem. Soc. 1998, 120, 8245. Reversible 1,2-Migration of Hydrogen between Platinum and Silicon via Intermediate 138. Silylene Complexes. G. P. Mitchell and T. D. Tilley. J. Am. Chem. Soc. 1998, 120, 7635. Hydrogen Migrations in Rhodium Silyl Complexes: Silylene Intermediates vs. Oxidative 137. Addition/Reductive Elimination. G. P. Mitchell and T. D. Tilley. Organometallics 1998, 17, 2912. A Zirconocene-Coupling Route to Substituted Poly(p-phenylenedienylene)s: Bandgap 136. Tuning via Conformational Control. B. L. Lucht, S. S. H. Mao, and T. D. Tilley. J. Am. Chem. Soc. 1998, 120, 4354. 135. Bipyridine-Containing Cyclophanes via Zirconocene-Coupling. J. Nitschke and T. D. Tilley. J. Org. Chem. 1998, 63, 3673. A Simple, Efficient Route to Cage Compounds via Zirconocene-Coupling. F.-Q. Liu, G. 134. Harder, and T. D. Tilley. J. Am. Chem. Soc. 1998, 120, 3271. Di-tert-buyl Phosphate Complexes of Titanium. C. G. Lugmair and T. D. Tilley. Inorg. 133. Chem. 1998, 37, 1821. Alkoxy(siloxy) complexes of tin, lead, and bismuth. K. W. Terry, K. Su, T. D. Tilley and 132. A. L. Rheingold. Polyhedron 1998, 17, 891. Hydrolysis of Zirconium and Hafnium Siloxide Complexes. Isolation and Characterization 131. of Intermediate Aqua Complexes M[OSi(OtBu)3]4(H2O)n (M = Zr, Hf; n = 1, 2). C. G. Lugmair and T. D. Tilley. Inorg. Chem. 1998, 37, 764. Efficient Zirconocene-Coupling of Silicon-Substituted Diynes to Polymers and 130. Macrocycles. S. S. H. Mao, F.-Q. Liu and T. D. Tilley. J. Am. Chem. Soc. 1998, 120, 1193. A coordination network based on d0 transition-metal centers: synthesis and structure of the 129. [4,2]-connected layered compound [(TiCl4)2Si(p-C6H4CN)4]•1.5C7H8. F.-Q. Liu and T. D. Tilley. J. Chem. Soc., Chem. Commun. 1998, 103.

Structure and Reactivity of Chelating Imido-Amido Complexes of Tantalum. Mechanistic 128. Studies on the Addition of Silanes to Ta-N Multiple Bonds. T. I. Gountchev and T. D. Tilley. J. Am. Chem. Soc. 1997, 119, 12831. Reversible Cycloaddition of Isocyanates to Ruthenium Silylene Complexes. G. P. Mitchell 127. and T. D. Tilley. J. Am. Chem. Soc. 1997, 119, 11236. Zirconocene Molecular Zippers: Implements for Construction of Well-Defined Polymers and Macrocycles. In Modular Chemistry, NATO ASI Series C: Vol. 499,J. Michl, Ed.; 126. Kluwer Academic Publisher: Dordrecht, The Netherlands, 1997. S. S. H. Mao and T. D. Tilley, pp 623-635. Coordination Networks Based on Tetrahedral Silane Building Blocks: Influence of the 125. Anion on Structures Adopted by Ag+-Si(p-C6H4CN)4 Arrays. F.-Q. Liu and T. D. Tilley. Inorg. Chem. 1997, 36, 5090. Synthesis and Reactivity of d0 Bis(imido) Silyl and Germyl Complexes of Molybdenum 124. and Tungsten. G. L. Casty, T. D. Tilley, G. A. P. Yap and A. L. Rheingold. Organometallics 1997, 16, 4746. Tris(tert-butoxy)siloxy Complexes as Single-Source Precursors to Homogeneous Zirconia- 123. and Hafnia-Silica Materials. An Alternative to the Sol-Gel Method. K. W. Terry, C. G. Lugmair and T. D. Tilley. J. Am. Chem. Soc. 1997, 119, 9745. Osmium Alkyl and Silyl Derivatives with Cyclopentadienyl(phosphine) and 122. Pentamethylcyclopentadienyl(phosphine) Ligand Sets. P. W. Wanandi and T. D. Tilley. Organometallics 1997, 16, 4299. A Versatile, Transition Metal-Mediated Route to Blue-Light Emitting Polymers with 121. Chemically Tunable Luminescent Properties. S. S. H. Mao and T. D. Tilley. Macromolecules 1997, 30, 5566. Zirconium Bent Sandwich Complex of a Dicarbahexaborate Ligand: [Li(THF)3]{[η5- 120. C2B4H4(SiMe3)2](η5-C5Me5)ZrCl2. S. S. H. Mao, T. D. Tilley, A. L. Rheingold, and N. S. Hosmane. J. Organomet. Chem. 1997, 533, 257. Poly(ferrocenylenevinylene) from Ring Opening Metathesis Polymerization of ansa- 119. (Vinylene)ferrocene. M. A. Buretea and T. D. Tilley. Organometallics 1997, 16, 1507. Molecular Routes to Metal Oxides and Metal Silicates. Synthesis and Thermal Decomposition Studies of Eclipsed Mo2[O2Si(OtBu)2]3 and 118. W2(NHMe2)2[O2Si(OtBu)2]2-[OSi(OH)(OtBu)2]2. K. Su and T. D. Tilley. Chem. Mater. 1997, 9, 588. Zinc Di(tert-butyl)phosphate Complexes as Precursors to Zinc Phosphates. Manipulation of 117. Zincophosphate Structures. C. G. Lugmair, T. D. Tilley, and A. L. Rheingold. Chem. Mater. 1997, 9, 339. Synthesis and Reactivity of 16-Electron Hafnocene Silyl Hydride Complexes. G. L. Casty, 116. C. G. Lugmair, N. S. Radu, T. D. Tilley, J. F. Walzer, and D. Zargarian. Organometallics 1997, 16, 8.

Tris(trimethylstannyl)silyl Complexes of Ruthenium and Platinum. R. H. Heyn and T. D. 115. Tilley. Main Group Chem. 1996, 1, 415. Samarium-Mediated Redistribution of Silanes and formation of Trinuclear Samarium- 114. Silicon Clusters. N. S. Radu, F. J. Hollander, T. D. Tilley, and A. L. Rheingold. J. Chem. Soc., Chem. Commun. 1996, 2459. Synthesis and Study of Cyclic π-Systems Containing Silicon and Germanium. The 113. Question of Aromaticity in Cyclopentadienyl Analogues. W. P. Freeman, T. D. Tilley, L. M. Liable-Sands, and A. L. Rheingold. J. Am. Chem. Soc. 1996, 118, 10457. Cross-Conjugated Polymers via Condensation of a Zirconocene Alkynyl(benzyne) 112. Derivative Generated by Thermolysis of Cp2ZrMe(C6H4C≡CSiMe3). S. S. H. Mao and T. D. Tilley. J. Organomet. Chem. 1996, 521, 425. Polymers with Linked Macrocyclic Rings in the Main Chain. Zirconocene Coupling of 1,8- 111. Cyclotetradecadiyne. S. S. H. Mao and T. D. Tilley. Macromolecules 1996, 29, 6362. Low Band-Gap, σ-Conjugated Polymers: Poly(diarylstannanes). V. Lu and T. D. Tilley. 110. Macromolecules 1996, 29, 5763. Bis(triisopropylsilyl)-o-phenylenediamido Complexes of Tanatalum. X-ray Structure of 109. (η5-C5Me5)[o-C6H4(NSiiPr3)2]TaCl2. K. Aoyagi, P. K. Gantzel, and T. D. Tilley. Polyhedron 1996, 15, 4299. Migrations in a Polysilyl Complex of Rhodium. Trapping of an Apparent Silylene 108. Intermediate and Observation of Reversible Si-Si Bond Reductive Elimination. G. P. Mitchell and T. D. Tilley. Organometallics 1996, 15, 3477. Neutral Lanthanide Silyl Complexes via σ-Bond Metathesis Reactions. N. S. Radu, T. D. 107. Tilley, and A. L. Rheingold. J. Organomet. Chem. 1996, 516, 41. Silolyl Anions and Silole Dianions: X-ray Structure of [K(18-Crown-6)+]2[C4Me4Si2- 106. ]. W. P. Freeman, T. D. Tilley, G. A. P. Yap, and A. L. Rheingold. Angew. Chem. Int. Ed. Engl. 1996, 35, 882. Zirconocene Coupling of 1,8-Cyclotetradecadiyne to Polymers Containing Macrocyclic 105. Rings in the Main Chain. S. S. H. Mao and T. D. Tilley. Polym. Prepr., (Am. Chem. Soc. Div. Polym. Chem.) 1996, 37(1), 443. 104. Molecular and Polymer Precursor Routes to Manganese-Doped Zinc Orthosilicate Phosphors. K. Su, T. D. Tilley, and M. J. Sailor. J. Am. Chem. Soc. 1996, 118, 3459. Bis(triisopropylsilyl)-o-phenylenediamido Complexes of Titanium and 103. Zirconium: Investigation of a New Ancillary Ligand. K. Aoyagi, P. K. Gantzel, K. Kalai, and T. D. Tilley. Organometallics 1996, 15, 923. Cuprous Tris(tert-butoxy)siloxy Complexes and their Thermolytic Conversion to Copper- 102. Silica and Copper Oxide-Silica Nanocomposites. K. W. Terry, C. G. Lugmair, P. K. Gantzel, and T. D. Tilley. Chem. Mater. 1996, 8, 274.

Polysilyl Group Isomerization via Migrations in Rhodium and Iridium Derivatives 101. (Me3P)3MSi(SiMe3)3. G. P. Mitchell, T. D. Tilley, G. P. A. Yap, and A. L. Rheingold. Organometallics 1995, 14, 5472. Metal-Catalyzed Dehydropolymerization of Secondary Stannanes to High Molecular 100. Weight Polystannanes. T. Imori, V. Lu, H. Cai and T. D. Tilley. J. Am. Chem. Soc. 1995, 117, 9931. Synthesis and Structure of a Free Germacyclopentadienide Anion: [Li(12-Crown- 99. 4)2]+[C4Me4GeSi(SiMe3)3]-. W. P. Freeman, T. D. Tilley, F. P. Arnold, A. L. Rheingold and P. K. Gantzel. Angew. Chem., Int. Ed. Engl. 1995, 34, 1887. Efficient, Zirconocene-Mediated Cyclotrimerization and Cyclotetramerization of 98. Me3SiC≡CC6H4C6H4C≡CSiMe3 to Unsaturated Macrocycles. S. S. H. Mao and T. Don Tilley. J. Am. Chem. Soc. 1995, 117, 7031. Autocatalytic Mechanism for σ-Bond Metathesis Reactions of (η5- 97. C5Me5)2SmCH(SiMe3)2 with Silicon-Hydrogen Bonds. N. S. Radu and T. D. Tilley. J. Am. Chem. Soc. 1995, 117, 5863. New Route to Unsaturated Organosilicon Polymers and Macrocycles Based on 96. Zirconocene-Coupling of 1,4-MeC≡C(Me2Si)C6H4(SiMe2)C≡CMe. S. S. H. Mao and T. Don Tilley. J. Am. Chem. Soc. 1995, 117, 5365. Isolation of the First d0 Metalloxy Ketene Complexes via Double Insertion of Carbon 95. Monoxide into Thorium-Silicon Bonds. N. S. Radu, M. P. Engeler, C. P. Gerlach, and T. D. Tilley. J. Am. Chem. Soc. 1995, 117, 3621. Synthetic, Structural, and Reactivity Studies with New Group 4 Transition-Metal Silyl 94. Complexes. T. Imori, R. H. Heyn, T. D. Tilley, and A. L. Rheingold. J. Organomet. Chem. 1995, 493, 83. Synthesis, Structure and Dynamic Studies on Base-Stabilized Silylene Complexes [(η5- 93. C5Me5)(PMe3)2RuSiX2(NCMe)+]. S. K. Grumbine, D. A. Straus, T. D. Tilley, and A. L. Rheingold. Polyhedron 1995, 14, 127.

Synthesis and Characterization of Transition Metal Silylene and Silylyne Complexes In 92. Progress in Organosilicon Chemistry, B. Marciniec and J. Chojnowski, Eds.; Gordon and Breach Science Publishers: Langhorne, PA, 1994. S. K. Grumbine and T. D. Tilley, p 133. The Influence of Catalyst Structure on the Dehydropolymerization of Phenylsilane. T. Imori 91. and T. D. Tilley. Polyhedron 1994, 13, 2231. 90. Stable Silacyclopentadienyl Complexes of Ruthenium: (η5-C5Me5)Ru[η5-Me4C4Si- Si(SiMe3)3] and X-ray Structure of its Protonated Form. W. P. Freeman, T. D. Tilley, and A. L. Rheingold. J. Am. Chem. Soc. 1994, 116, 8428. Transition Metal-Mediated Redistribution at Silicon: A Bimolecular Mechanism Involving 89. Silylene Complexes. S. K. Grumbine and T. D. Tilley. J. Am. Chem. Soc. 1994, 116, 6951. Base-Free Silylene Complexes Without π-Donor Stabilization. Molecular Structure of 88. [Cp*(PMe3)2Ru=SiMe2][B(C6F5)4]. S. K. Grumbine, T. D. Tilley, F. P. Arnold, and A. L. Rheingold. J. Am. Chem. Soc. 1994, 116, 5495. Lanthanide-Tungsten Heterobimetallic Complexes via σ-Bond Metathesis. N. S. Radu, P. K. 87. Gantzel, and T. D. Tilley. J. Chem. Soc., Chem. Commun. 1994, 1175. Sigma-Bond Metathesis Reactions Involving Lanthanide-Silicon and Lanthanide-Hydrogen 86. Bonds. N. S. Radu and T. D. Tilley. Phosphorus, Sulfur, and Silicon 1994, 87, 209. New Chemistry for Reactive Transition-Metal-Silicon Bonds In Organosilicon Chemistry: 85. From Molecules to Materials, N. Auner and J. Weis, Eds.; VCH Publishers: New York, 1994. T. D. Tilley, p 225.

A Stable η5-Germacyclopentadienyl Complex: (η5-C5Me5)Ru[η5- 84. C4Me4GeSi(SiMe3)3]. W. P. Freeman, T. D. Tilley, A. L. Rheingold and R. L. Ostrander. Angew. Chem. Int. Ed. Engl. 1993, 32, 1744. High Molecular Weight Polystannanes via Dehydropolymerization of Di(n- 83. butyl)stannane. T. Imori and T. D. Tilley. J. Chem. Soc., Chem. Commun. 1993, 1607. Disilanylenearylene Oligomers and Polymers from Dehydropolymerization of 1,4- 82. RH2SiC6H4SiH2R (R = Methyl, Ethyl, and Hexyl). T. Imori, H.-G. Woo, J. F. Walzer and T. D. Tilley. Chem. Mater. 1993, 5, 1487. A Fischer-Type Silylene Complex of Platinum: [trans-(Cy3P)2(H)Pt=Si(SEt)2]BPh4. S. D. 81. Grumbine, T. D. Tilley, A. L. Rheingold, and F. P. Arnold. J. Am. Chem. Soc. 1993, 115, 7884. Chromium(II) and Chromium(III) Tri-tert-butoxysiloxy Complexes. K. W. Terry, P. K. 80. Gantzel and T. D. Tilley. Inorg. Chem. 1993, 32, 5402. Synthesis and Study of the Ruthenium Silene Complexes (η5-C5Me5)(PR3)RuH(η2- 79. CH2=SiR'2) (R = iPr, Cy; R' = Me, Ph). B. K. Campion, R. H. Heyn, T. D. Tilley and A. L. Rheingold. J. Am. Chem. Soc. 1993, 115, 5527. Synthesis and Reactions of Silyl and Germyl Derivatives of Scandocene. Structure of 78. Cp2Sc[Si(SiMe3)3](THF). B. K. Campion, R. H. Heyn and T. D. Tilley. Organometallics 1993, 12, 2584. Synthesis and Structure of a Transition Metal-Substituted Silylene Complex, 77. (CO)4OsSi(STol-p)[Ru(η5-C5Me5)(PMe3)2]. S. D. Grumbine, T. D. Tilley and A. L. Rheingold. J. Am. Chem. Soc. 1993, 115, 358. The Coordination Polymerization of Silanes to Polysilanes by a σ-Bond Metathesis 76. Mechanism. Implications for Linear Chain Growth. T. D. Tilley. Acc. Chem. Res. 1993, 26, 22.

75. Low-Temperature Pyrolytic Transformations of Tri-tert-butoxysiloxy Derivatives of Aluminum to Aluminosilicate Materials. K. W. Terry, P. K. Ganzel and T. D. Tilley. Chem. Mater. 1992, 4, 1290. Silylene-Bridged Ruthenium Dimers via Reactions of [(η5-C5Me5)Ru(μ-OMe)]2 with 74. Silanes. Structure of {[(η5-C5Me5)Ru]2(μ-SiPhOMe)(μ-OMe)(μ-H)]}. B. K. Campion, R. H. Heyn and T. D. Tilley. Organometallics 1992, 11, 3918. Synthesis and Characterization of the Neutral Lanthanide Silyl Complexes (η5- 73. C5Me5)2LnSiH(SiMe3)2 (Ln = Nd, Sm). N. S. Radu, T. D. Tilley and A. L. Rheingold. J. Am. Chem. Soc. 1992, 114, 8293. Transition Metal-Catalyzed Routes to Polysilane Polymers In Ultrastructure Processing of 72. Advanced Materials, D. R. Uhlmann and D. R. Ulrich, Eds.; Wiley: New York, 1992. H.-G. Woo and T. D. Tilley. Chap 56, p. 651-665. Ruthenium(IV) Silyl Hydride Complexes via Reaction of Silanes with 16-Electron (η5- C5Me5)Ru(PPri3)X (X = Cl, CH2SiHPh2, SiMePh2) Complexes. Hydride Migrations to an 71. η2-Silene Ligand. B. K. Campion, R. H. Heyn and T. D. Tilley. J. Chem. Soc., Chem. Commun. 1992, 1201. A σ-Bond Metathesis Mechanism for Dehydropolymerization of Silanes to Polysilanes by 70. d0 Metal Catalysts. H.-G. Woo, J. F. Walzer and T. D. Tilley. J. Am. Chem. Soc. 1992, 114, 7047. σ-Bond Metathesis Reactions for d0 Metal-Silicon Bonds that Produce Zirconocene and 69. Hafnocene Hydrosilyl Complexes. H.-G. Woo, R. H. Heyn, and T. D. Tilley. J. Am. Chem. Soc.1992, 114, 5698. Synthesis, Characterization and Reactivity of Triphenylsilyl, Triphenylgermyl, and 68. Triphenylstannyl Derivatives of Zirconium and Hafnium. H.-G. Woo, W. P. Freeman and T. D. Tilley. Organometallics 1992, 11, 2198. Synthesis and Structure of [(η5-C5Me5)Ru(μ-NHPh)]2, an Electron-Deficient Ruthenium 67. Amide Complex. R. E. Blake, Jr., R. H. Heyn and T. D. Tilley. Polyhedron 1992, 11, 709. Design of Catalysts for the Dehydropolymerization of Silanes to Polysilanes. T. D. Tilley, 66. N. S. Radu, J. F. Walzer and H.-G. Woo. Polym. Prepr., (Am. Chem. Soc. Div. Polym. Chem.) 1992, 33, 1237. Platinum-Mediated Reactions of Hydrosilanes. Isolation of a Complex with Bridging 65. Disilene and Silylene Ligands. R. H. Heyn and T. D. Tilley. J. Am. Chem. Soc. 1992, 114, 1917. Transition-Metal Complexes Containing Donor-Stabilized Silylyne Ligands. Reductive 64. Dimerization to a Silylene Complex. S. D. Grumbine, R. K. Chadha and T. D. Tilley. J. Am. Chem. Soc. 1992, 114, 1518.

Dehydropolymerization of Bis- and Tris(silyl)arenes to Highly Cross-Linked 63. Disilanylenearylene Polymers, Catalyzed by [(η5-C5H5)(η5-C5Me5)ZrH2]2. H.-G. Woo, J. F. Walzer and T. D. Tilley. Macromolecules 1991, 24, 6863. Trialkoxysiloxy Complexes as Precursors to MO2·4SiO2 (M = Ti, Zr, Hf) Materials. K. W. 62. Terry and T. D. Tilley. Chem. Mater. 1991, 3, 1001. Transition-Metal Silyl Derivatives. In The Silicon-Heteroatom Bond, S. Patai and Z. 61. Rappoport, Eds.; Wiley: New York, 1991. T. D. Tilley. Chaps 9 and 10, pp. 245 and 309. Reactions of the Ruthenium Silylene Derivative [(η5-C5Me5)(PMe3)2RuSiPh2- 60. (NCMe)]BPh4 with Alcohols, Ketones, and Acetic Acid. C. Zhang, S. D. Grumbine and T. D. Tilley. Polyhedron 1991, 10, 1173. Transition-Metal Complexes of Reactive Silicon Intermediates. In Frontiers of Organosilicon Chemistry, A. R. Bassindale and P. P. Gaspar, Eds.; The Royal Society of 59. Chemistry, Thomas Graham House: Cambridge, 1991. T. D. Tilley, B. K. Campion, S. D. Grumbine, D. A. Straus and R. H. Heyn, p. 295. Catalytic Dehydrogenative Polymerization of Silanes to Polysilanes by Zirconocene and Hafnocene Catalysts. A New Polymerization Mechanism. In Inorganic and Organometallic 58. Oligomers and Polymers, Proceedings of the 33rd IUPAC Symposium on Macromolecules, J. F. Harrod, R. M. Laine, Eds.; Kluwer Publishers, Amsterdam, Netherlands, 1991. T. D. Tilley and H.-G. Woo, p 3. Approaches to High Molecular Weight Polysilanes via Dehydrogenative Coupling of 57. Silanes. J. F. Walzer, H.-G. Woo and T. D. Tilley. Polym. Prepr., (Am. Chem. Soc. Div. Polym. Chem.) 1991, 32, 441. Structure of trans-{Pt[P(c-C6H11)3]2(H)(NCCH3)}[BPh4]. R. H. Heyn, S. D. Grumbine 56. and T. D. Tilley. Acta Cryst. Sect. C 1991, C47, 313.

Silicon-Based Ligands. In 1991 McGraw-Hill Yearbook of Science and Technology; 55. McGraw-Hill: New York, 1990. T. D. Tilley. pp. 80-83. Carbon Dioxide Activation by a Transition Metal-Silicon Bond. Formation of 54. Silanecarboxylate Complexes [Cp2Sc(μ-O2CSiR3)]2. B. K. Campion, R. H. Heyn and T. D. Tilley. Inorg. Chem. 1990, 29, 4355. Base-Free Silylene Complexes [(η5-C5Me5)(PMe3)2Ru=Si(SR)2]BPh4 (R = Et, p- 53. MeC6H4). D. A. Straus, S. D. Grumbine and T. D. Tilley. J. Am. Chem. Soc. 1990, 112, 7801. Preparation and Properties of Tris(trimethylstannyl)silyl Complexes of Chromium, 52. Molybdenum, and Tungsten. X-ray Structure of [NEt4][(CO)5WSi(SnMe3)3]. R. H. Heyn and T. D. Tilley. Inorg. Chem. 1990, 29, 4051. Insertion of Nitriles and Pyridine into the Zr-Si Bond of (η5-C5H5)(η5- 51. C5Me5)Zr[Si(SiMe3)3]Me. H.-G. Woo and T. D. Tilley. J. Organomet. Chem. 1990, 393, C6. Dehydrogenative Polymerization of Silanes by Sigma-Bond Metathesis. T. D. Tilley and H.- 50. G. Woo. Polym. Prepr., (Am. Chem. Soc. Div. Polym. Chem.) 1990, 31, 228. Bis[bis(trimethylsilyl)amido]bis(diethyl ether)ytterbium and (Diethyl ether)bis(η5- 49. pentamethylcyclopentadienyl)ytterbium. T. D. Tilley, J. M. Boncella, D. J. Berg, C. J. Burns and R. A. Andersen. Inorg. Synth. 1990, 27, 146. Trialkoxysiloxy Complexes of Nickel. Crystal and Molecular Structures of Na3(μ3- 48. I){Ni[μ3-OSi(OtBu)3]3I}0.5THF·0.5C5H12 and {(η3-C3H5)Ni[μ2-OSi(OtBu)3]}2. A. K. McMullen, T. D. Tilley, A. L. Rheingold and S. J. Geib. Inorg. Chem. 1990, 29, 2228. A Stable η2-Silene Complex of Iridium: (η5-C5Me5)(PMe3)Ir(η2-CH2=SiPh2). B. K. 47. Campion, R. H. Heyn and T. D. Tilley. J. Am. Chem. Soc. 1990, 112, 4079. 46. Mechanistic Aspects of Transition-Metal Catalyzed Dehydrogenative Silane Coupling Reactions. T. D. Tilley. Comments Inorg. Chem. 1990, 10, 37. Silyl and Diphenylsilylene Derivatives of (η5-C5Me5)(PMe3)2Ru. Evidence for the Base- Free Silylene Complex [(η5-C5Me5)(PMe3)2Ru=SiPh2]+. D. Straus, C. Zhang, G. E. 45. Quimbita, S. D. Grumbine, R. H. Heyn, T. D. Tilley, A. L. Rheingold and S. J. Geib. J. Am. Chem. Soc. 1990, 112, 2673. Reactions of Alkynes with Coordinatively Unsaturated (η5-C5Me5)Ru Derivatives. X-ray Crystal Structures of (η5-C5Me5)Cl2Ru(η2:η4-μ2-C4H4)Ru(η5-C5Me5) and (η5- 44. C5Me5)3Ru3(μ2-Cl)2(μ3-Cl)(η2-μ2-HC≡CSiMe3). B. K. Campion, R. H. Heyn and T. D. Tilley. Organometallics 1990, 9, 1106. Reactivity of a Sc-Si Bond Toward CO and CN(2,6-Me2C6H3). Generation and Reactivity 43. of an Apparent Silene Intermediate Resulting From Isocyanide Coupling at Scandium. B. K. Campion, R. H. Heyn and T. D. Tilley. J. Am. Chem. Soc. 1990, 112, 2011.

Preparation and Characterization of the Monomeric Copper(II) Siloxide Complex 42. Cu[OSi(OCMe3)3]2(pyr)2. A. K. McMullen, T. D. Tilley, A. L. Rheingold and S. J. Geib. Inorg. Chem. 1989, 28, 3772. Dehydrogenative Polymerization of Silanes to Polysilanes by Zirconocene and Hafnocene 41. Catalysts. A New Polymerization Mechanism. H.-G. Woo and T. D. Tilley. J. Am. Chem. Soc. 1989, 111, 8043. Insertion of Ethylene into Zr-Si and Hf-Si Bonds. J. Arnold, M. P. Engeler, F. H. Elsner, R. 40. H. Heyn and T. D. Tilley. Organometallics 1989, 8, 2284. Trityl Tetraphenylborate as a Reagent in Organometallic Chemistry. D. A. Straus, C. Zhang 39. and T. D. Tilley. J. Organomet. Chem. 1989, 369, C13. Alkoxy and Aryloxy Derivatives of (Pentamethylcyclopentadienyl)ruthenium. X-ray Crystal Structures of [(η5-C5Me5)Ru(μ-OMe)]2, [(η5-C5Me5)(CO)Ru(μ-OEt)]2, and (η5- 38. C5Me5)Ru(η5-2,6-tBu2C6H3O), and Molecular Orbital Analysis of [(η5-C5H5)Ru(μ- OMe)]2. S. D. Loren, B. K. Campion, R. H. Heyn, T. D. Tilley, B. E. Bursten and K. W. Luth. J. Am. Chem. Soc. 1989, 111, 4712. Tris(trimethylsilyl)silyl Derivatives of Tri(tert-butoxy)zirconium and -Hafnium. X-ray 37. Crystal Structure of (Me3CO)3ZrSi(SiMe3)3. R. H. Heyn and T. D. Tilley. Inorg. Chem. 1989, 28, 1768. σ-Bond Metathesis Reactions of Si-H and M-Si Bonds. New Routes to d0 Metal Silyl 36. Complexes. H.-G. Woo and T. D. Tilley. J. Am. Chem. Soc. 1989, 111, 3757. Dimesitylsilyl Derivatives of Zirconium. D. M. Roddick, R. H. Heyn and T. D. 35. Tilley. Organometallics 1989, 8, 324. Carbonylation Chemistry of the Tantalum Silyl (η5-C5Me5)Cl3TaSiMe3. Synthesis, Characterization, and Reaction Chemistry of (η5-C5Me5)Cl3Ta(η2-COSiMe3) and 34. Derivatives. J. Arnold, T. D. Tilley, A. L. Rheingold, S. J. Geib and A. M. Arif. J. Am. Chem. Soc. 1989, 111, 149. Transition-Metal Silyl Derivatives. In The Chemistry of Organic Silicon Compounds, S. 33. Patai and Z. Rappoport, Eds.; Wiley: New York, 1989. T. D. Tilley. Chap 24, p. 1415.

Reactions of (η5-C5H5)(η5-C5Me5)Zr[Si(SiMe3)3]X (X = Cl, Me) Complexes with Carbon Monoxide and the Isocyanide 2,6-Me2C6H3NC. Crystal Structure of (η5-C5H5)(η5- 32. C5Me5)Zr[η2-C(N-2,6-Me2C6H3)Si(SiMe3)3]Cl. F. H. Elsner, T. D. Tilley, A. L. Rheingold and S. J. Geib. J. Organomet. Chem. 1988, 358, 169. Preparation, Isolation and Characterization of Transition-Metal η2-Silene Complexes. X-ray 31. Crystal Structure of (η5-C5Me5)[P(i-Pr)3]Ru(H)(η2-CH2SiPh2). B. K. Campion, R. H. Heyn and T. D. Tilley. J. Am. Chem. Soc. 1988, 110, 7558. Preparation and Characterization of Tris(trimethylsilyl)silyl and Tris(trimethylsilyl)germyl Derivatives of Zirconium and Hafnium. X-ray Crystal Structures of (η5- 30. C5Me5)Cl2HfSi(SiMe3)3 and (η5-C5Me5)Cl2HfGe(SiMe3)3. J. Arnold, D. M. Roddick, T. D. Tilley, A. L. Rheingold and S. J. Geib. Inorg. Chem. 1988, 27, 3510. Surface Modification of Matrix Materials for Oxidation-Resistant Carbon-Carbon Composites. In Ultrastructure Processing of Advanced Ceramics, J. A. Mackenzie and D. R. 29. Ulrich, Eds.; Wiley: New York, 1988. H. Streckert, F. Montgomery, T. D. Tilley, B. K. Campion and R. H. Heyn. Chap 79, p. 963. Reaction of an Early Transition-Metal η2-Silaacyl Complex with Pyridine. Diastereoselectivity in the Formation of a (2-Pyridyl)(silyl)methoxy Ligand. J. 28. Arnold, H.-G. Woo, T. D. Tilley, A. L. Rheingold and S. J. Geib. Organometallics 1988, 7, 2045. Preparation and Reactivity of 16-Electron Half-Sandwich Ruthenium Complexes; X-ray 27. Crystal Structure of (η5-C5Me5)Ru(PiPr3)Cl. B. K. Campion, R. H. Heyn and T. D. Tilley. J. Chem. Soc., Chem. Commun. 1988, 278. Preparation of the First Stable Formylsilane, (Me3Si)3SiCHO, from a Zirconium η2-Silaacyl 26. Complex. F. H. Elsner, H.-G. Woo and T. D. Tilley. J. Am. Chem. Soc. 1988, 110, 313.

Preparation, Characterization and X-ray Crystal Structure of an Acetonitrile-Complexed 25. Ruthenium Silylene. D. A. Straus, T. D. Tilley, A. L. Rheingold and S. J. Geib. J. Am. Chem. Soc. 1987, 109, 5872. An Arbuzov-like Reaction in the Trimethylphosphite-η2-Silaacyl Adduct (η5- 24. C5Me5)Cl3Ta{η2-OC(SiMe3)[P(OMe)3]}. J. Arnold, T. D. Tilley, A. L. Rheingold and S. J. Geib. Inorg. Chem. 1987, 26, 2556. Preparation and Characterization of Tris(trimethylsilyl)silyl Derivatives of Zinc, Cadmium 23. and Mercury. X-ray Crystal Structure of Zn[Si(SiMe3)3]2. J. Arnold, T. D. Tilley, A. L. Rheingold and S. J. Geib. Inorg. Chem. 1987, 26, 2106. Formation of the Novel Benzophenone Sila-acylhydrazonato Complex (η5- C5Me5)Cl3Ta[OC(SiMe3)NNCPh2] Following Addition of Diphenyldiazomethane to an η2- 22. Sila-acyl Ligand. J. Arnold, T. D. Tilley, A. L. Rheingold and S. J. Geib. J. Chem. Soc., Chem. Commun. 1987, 793. Insertion of Organic Carbonyls into the Tantalum-Silicon Bond of (η5- C5Me5)Cl3TaSiMe3. Preparation and Characterization of the α-Silylalkoxides (η5- 21. C5Me5)Cl3TaOCRR'SiMe3. J. Arnold and T. D. Tilley. J. Am. Chem. Soc. 1987, 109, 3318. 20. Reactions of Carbon Monoxide with Trimethylsilyl and Tris(trimethylsilyl)silyl Derivatives of Group 4 Metals. Synthesis, Characterization, and Reactivity of Silaacyl Complexes. B. K. Campion, J. Falk and T. D. Tilley. J. Am. Chem. Soc. 1987, 109, 2049. Preparation and Reaction Chemistry of Trimethylsilyl Derivatives of Niobium. Redox Chemistry of (η5-C5H5)2Nb(SiMe3)Cl and X-ray Structures of (η5-C5H5)2Nb(SiMe3)(η2- 19. C2H4) and [(η5-C5H5)2Nb(CH2SiMe3)Cl]PF6. J. Arnold, T. D. Tilley, A. L. Rheingold and S. J. Geib. Organometallics 1987, 6, 473. Coordinatively Unsaturated Tris(trimethylsilyl)silyl Complexes of Chromium, Manganese 18. and Iron. D. M. Roddick, T. D. Tilley, A. L. Rheingold and S. J. Geib. J. Am. Chem. Soc. 1987, 109, 945.

Preparation and Reaction Chemistry of Trimethylsilyl Derivatives of Tantalum. X-ray 17. Structures of d0 (η5-C5Me5)Ta(SiMe3)Cl3 and d1 (η5-C5Me5)Ta(SiMe3)(PMe3)Cl2. J. Arnold, D. N. Shina, T. D. Tilley and A. M. Arif. Organometallics 1986, 5, 2037. Tetrahedral Lewis Base Adducts of an Acyl. Preparation and X-ray Structure of the Pyridine 16. Adduct (η5-C5Me5)Cl3Ta[η2-OC(SiMe3)(NC5H5)]. J. Arnold, T. D. Tilley and A. L. Rheingold. J. Am. Chem. Soc. 1986, 108, 5355.

Ether Cleavage Following Insertion of Carbon Monoxide into the Tantalum-Silicon Bond of 15. (η5-C5Me5)Ta(SiMe3)Cl3. J. Arnold and T. D. Tilley. J. Am. Chem. Soc. 1985, 107, 6409. Trimethylsilyl Derivatives of Bis(cyclopentadienyl)zirconium and -hafnium. Crystal 14. Structure of (η5-C5H5)2Zr(SiMe3)(S2CNEt2). T. D. Tilley. Organometallics 1985, 4, 1452. Insertion of Carbon Monoxide into a Transition-Metal-Silicon Bond. X-ray Structure of the 13. Silaacyl (η5-C5H5)2Zr(η2-COSiMe3)Cl. T. D. Tilley. J. Am. Chem. Soc. 1985, 107, 4084.

Divalent Lanthanide Chemistry. Preparation and Crystal Structures of Sodium Tris[bis(trimethylsilyl)amido]europate(II) and Sodium Tris[bis(trimethylsilyl)amido]- 12. ytterbate(II), NaM[N(SiMe3)2]3. T. D. Tilley, R. A. Andersen and A. Zalkin. Inorg. Chem. 1984, 23, 2271. Reaction of M(C5Me5)2(OEt2), M = Eu or Yb, with Phenylacetylene; Formation of Mixed- 11. Valence Yb3(C5Me5)4(μ-C≡CPh)4 and Eu2(C5Me5)2(μ-C≡CPh)2(tetrahydrofuran)4. J. M. Boncella, T. D. Tilley and R. A. Andersen. J. Chem. Soc., Chem. Commun. 1984, 710. Halide, Hydride and Alkyl Derivatives of (Pentamethylcyclopentadienyl)bis(trimethyl- 10. phosphine)ruthenium. T. D. Tilley, R. H. Grubbs and J. E. Bercaw. Organometallics 1984, 3, 274.

Tertiary Phosphine Complexes of the f-Block Metals. Preparation of Pentamethyl- cyclopentadienyl-Tertiary Phosphine Complexes of Ytterbium(II), Ytterbium(III) and 9. Europium(II). Crystal Structure of Yb(Me5C5)2Cl(Me2PCH2PMe2). T. D. Tilley, R. A. Andersen and A. Zalkin. Inorg. Chem. 1983, 22, 856.

Bis(pentamethylcyclopentadienyl)bis(pyridine)ytterbium(II). T. D. Tilley, R. A. Andersen, B. 8. Spencer and A. Zalkin. Inorg. Chem. 1982, 21, 2647. Bis(pentamethylcyclopentadienyl)carboxylato and -dithiocarbamato Derivatives of Neodymium(III) and Ytterbium(III). Crystal Structure of Bis(pentamethylcyclopentadienyl)- 7. (diethyldithiocarbamato)ytterbium(III). T. D. Tilley, R. A. Andersen, A. Zalkin and D. H. Templeton. Inorg. Chem. 1982, 21, 2644. Tertiary Phosphine Complexes of the f-Block Metals. Crystal Structure of 6. Yb[N(SiMe3)2]2(Me2PCH2CH2PMe2): Evidence for a Ytterbium-γ-Carbon Interaction. T. D. Tilley, R. A. Andersen and A. Zalkin. J. Am. Chem. Soc. 1982, 104, 3725. Preparation and Crystal Structure of Bis[bis(pentamethylcyclopentadienyl)ytterbium(III)] Undecacarbonyltriferrate, [(C5Me5)2Yb]2[Fe3(CO)11]: A Compound with Four Isocarbonyl 5. (Fe-CO-Yb) Interactions. T. D. Tilley and R. A. Andersen. J. Am. Chem. Soc. 1982, 104, 1772.

Preparation and Crystal Structure of μ-Carbonyl-OC-bis(pentamethylcyclopentadienyl)- 4. (tetrahydrofuran)ytterbium(III)tricarbonylcobalt(I); A Yb-OC-Co Linkage. T. D. Tilley and R. A. Andersen. J. Chem. Soc., Chem. Commun. 1981, 985. Pentamethylcyclopentadienyl Derivatives of the Trivalent Lanthanide Elements Neodymium, 3. Samarium and Ytterbium. T. D. Tilley and R. A. Andersen. Inorg. Chem. 1981, 20, 3267. Divalent Lanthanide Chemistry. Preparation of Some Four- and Six-Coordinate Bis[(trimethylsilyl)amido] Complexes of Europium(II). Crystal Structure of Bis[bis- 2. (trimethylsilyl)amido]bis(1,2-dimethoxyethane)europium(II). T. D. Tilley, A. Zalkin, R. A. Andersen and D. H. Templeton. Inorg. Chem. 1981, 20, 551.

Divalent Lanthanide Chemistry. Bis(pentamethylcyclopentadienyl)europium(II) and - ytterbium(II) Derivatives: Crystal Structure of Bis(pentamethylcyclopentadienyl)(tetrahy- 1. drofuran)ytterbium(II)-Hemitoluene at 176 K. T. D. Tilley, R. A. Andersen, B. Spencer, H. Ruben, A. Zalkin and D. H. Templeton. Inorg. Chem. 1980, 19, 2999.