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T. Don Tilley's Publications Titanium-Germoxy Precursor Route to Germanium-Modified Epoxidation Catalysts with 387. Enhanced Activity. P. J. Cordeiro, P. Guillo, C. S. Spanjers, J. W. Chang, M. E. Fasulo, R. M. Rioux and T. D. Tilley, ACS Catal. 2013, 3, 2269. Photocatalytic Water Oxidation by Very Small Cobalt Domains on a Silica Surface. H. S. 386. Ahn, J. Yano and T. D. Tilley, Energy Environ. Sci. 2013, 6, 3080. Platinum-Catalyzed C-C Activation Induced by C-H Activation. M. Bowring, R. G. 385. Bergman and T. D. Tilley, J. Am. Chem. Soc. 2013, 135, 13121. Structural and mechanistic investigation of a cationic hydrogen-substituted ruthenium 384. silylene catalyst for alkene hydrosilation. M. Fasulo, M. C. Lipke and T. D. Tilley, Chem. Sci. 2013, 4, 3882. Water Oxidation Catalysis via Immobilization of the Dimanganese Complex [Mn2(μ- 383. O)2Cl(μ-O2CCH3)(bpy)2(H2O)](NO3)2 onto Silica. E. M. W. Rumberger, H. S. Ahn, A. T. Bell and T. D. Tilley, Dalton Trans. 2013, 42, 12238. The Osmium-Silicon Triple Bond: Synthesis and Reactivity of an Osmium Silylyne 382. Complex. P. G. Hayes, Z. Xu, C. Beddie, J. M. Keith, M. B. Hall and T. D. Tilley, J. Am. Chem. Soc. 2013, 135, 11780. Silane-Isocyanide Coupling Involving 1,1-Insertion of XylNC into the Si-H Bond of a σ- 381. Silane Ligand. M. C. Lipke and T. D. Tilley, J. Am. Chem. Soc. 2013, 135, 10298. A Remote Lewis Acid Trigger Dramatically Accelerates Biaryl Reductive Elimination from 380. a Platinum Complex. A. Liberman-Martin, R. G. Bergman and T. D. Tilley, J. Am. Chem. Soc. 2013, 135, 9612. Multiple Si–H Bond Activations by tBu2PCH2CH2PtBu2 and tBu2PCH2PtBu2 379. Di(phosphine) Complexes of Rhodium and Iridium. M. E. Fasulo, E. Calimano, J. M. Buchanan and T. D. Tilley, Organometallics 2013, 32, 1016. Synthesis and Characterization of Tantalum Silsesquioxane Complexes. P. Guillo, M. E. 378. Fasulo, M. I. Lipschutz and T. D. Tilley, Dalton Trans. 2013, 42, 1991. Hydrolysis of 3-carboxy-6,8-difluoro-7-hydroxycoumarin (Pacific BlueTM) succinimidyl 377. ester under acidic and basic conditions. A. M. Stockton, M. F. Mora, M. L. Cable, T. C. Davenport, T. D. Tilley and P. A. Willis, Dyes Pigments 2013, 96, 148. Electrocatalytic Water Oxidation at Neutral pH by a Nanostructured Co(PO3)2 Anode. H. 376. S. Ahn and T. D. Tilley, Adv. Func. Mater. 2013, 23, 227. Stabilization of ArSiH4– and SiH62– Anions in Diruthenium Si—H σ-Complexes. M. C. 375. Lipke and T. D. Tilley, Angew. Chem. Int. Ed. 2012, 51, 11115. Stoichiometric Reaction Chemistry of Cationic Ruthenium Silylene Complexes toward 374. Polar and Non-polar Organic Substrates. M. Fasulo and T. D. Tilley, Organometallics 2012, 31, 5049. Synthesis and Reactivity of Cationic Ruthenium Germylene Complexes 373. [Cp*(PiPr3)RuH2(=GeRR')]+. M. Fasulo and T. D. Tilley, Chem. Comm. 2012, 48, 7690. Synthesis and Reactivity of a Conveniently Prepared Two-Coordinate Bis(amido) Nickel(II) 372. Complex. M. Lipschutz and T. D. Tilley, Chem. Comm. 2012, 48, 7146. 371. Preparation and Physical Properties of Early-Late Heterobimetallic Compounds Featuring Ir–M Bonds (M = Ti, Zr, Hf). J. J. Curley, R. G. Bergman and T. D. Tilley, Dalton Trans. 2012, 42, 192. Epoxidation catalysts derived from introduction of titanium centers onto the surface of 370. mesporporous aluminophosphate: Comparisons with analogous catalysts based on mesoporous silica. L. Raboin, J. Yano and T. D. Tilley, J. Catal. 2012, 285, 168. Isolation, observation, and computational modeling of proposed intermediates in catalytic 369. proton reductions with the hydrogenase mimic Fe2(CO)6S2C6H4. R. J. Wright, W. Zhang, X. Yang, M. Fasulo and T. D. Tilley, Dalton Trans. 2012, 41, 73. Dinucleating Naphthyridine-Based Ligand for Assembly of Bridged Dicopper(I) Centers: 368. Three-Center Two-Electron Bonding Involving an Acetonitrile Donor. T. C. Davenport and T. D. Tilley, Angew. Chem. Int. Ed. 2011, 50, 12205. Mechanism of the Decomposition of Aqueous Hydrogen Peroxide over Heterogeneous TiSBA15 and TS-1 Selective Oxidation Catalysts: Insights from Spectroscopic and Density 367. Functional Theory Studies. C. W. Yoon, K. F. Hirsekorn, M. L. Neidig, X. Yang and T. D. Tilley, ACS Catal. 2011, 1, 1665. Cp*(PiPr3)RuOTf: A Reagent for Access to Ruthenium Silylene Complexes. M. E. Fasulo, 366. P. B. Glaser and T. D. Tilley, Organometallics 2011, 30, 5524. Inverse Rectification in Donor-Acceptor Molecular Heterojunctions. S. K. Yee, J. Sun, P. 365. Darancet, T. D. Tilley, A. Majumdar, J. B. Neaton and R. A. Segalman, ACS Nano 2011, 5, 9256. Comparison of Cobalt-based Nanoparticles as Electrocatalysts for Water Oxidation. N. H. 364. Chou, P. N. Ross, A. T. Bell and T. D. Tilley, ChemSusChem 2011, 4, 1566. High Electrophilicity at Silicon in η3-Silane s-Complexes: Lewis Base Adducts of a Silane 363. Ligand, Featuring Octahedral Silicon and Three Ru-H-Si Interactions. M. C. Lipke and T. D. Tilley, J. Am. Chem. Soc. 2011, 133, 16374. Highly Dispersed Pd-SBA15 Materials from Tris(tert-butoxy)siloxy Complexes of Pd(II). 362. Y. S. Choi, E. G. Moschetta, J. T. Miller, M. Fasulo, M. J. McMurdo, R. M. Rioux and T. D. Tilley, ACS Catal. 2011, 1, 1166. Assembly of Macrocycles by Zirconocene-Mediated, Reversible Carbon-Carbon Bond 361. Formation. V. Gessner, J. Tannaci, A. Miller and T. D. Tilley. Acc. Chem. Res. 2011, 44, 435. Terminal Hafnium Phosphinidene Complexes and Phosphinidene Ligand Exchange. R. 360. Waterman and T. D. Tilley, Chem. Sciences 2011, 2, 1320. Enhancement of Epoxidation Efficiencies for Ta-SBA15 Catalysts. The Influence of 359. Modification with –EMe3 (E = Si, Ge, Sn) Groups. P. J. Cordeiro and T. D. Tilley, Langmuir 2011, 27, 6295. Enhancement of the Catalytic Activity of Titanium-Based Terminal Olefin Epoxidation 358. Catalysts via Surface Modification with Functionalized Protic Molecules. P. J. Cordeiro and T. D. Tilley, ACS Catal. 2011, 1, 455. Transition metal complexes of the novel hexadentate ligand 1,4-bis(di(N-methylimidazol-2- 357. yl)methyl)phthalazine. S. Roggan, C. Limberg, C. Knispel and T. D. Tilley. Dalton Trans. 2011, 40, 4315. Disambiguation of Metal and Bronsted Acid Catalyzed Pathways for Hydroarylation with a 356. Platinum(II) Catalyst. M. Bowring, R. G. Bergman and T. D. Tilley, Organometallics 2011, 30, 1295. Diphenylanthracene Macrocycles from Reductive Zirconocene Coupling: On the Edge of 355. Steric Overload. V. H. Gessner and T. D. Tilley, Org. Lett. 2011, 13, 1154. Interligand H…Si Interactions in Tungsten Silyl Trihydride Complexes. M. E. Fasulo and 354. T. D. Tilley. J. Organomet. Chem. 2011, 696, 1325. Disulfide Passivation of the Ge(100)-2 × 1 Surface. J. S. Kachian, J. Tannaci, R. J. Wright, 353. T. D. Tilley and S. F. Bent, Langmuir 2011, 27, 179. Active and Efficient Hydrosilylation of Carbonyl Compounds with the Simple Iron-Based 352. Catalyst Fe[N(SiMe3)2]2. J. Yang and T. D. Tilley, Angew. Chem. Int. Ed. 2010, 52, 10186. Unusual Ruthenium Hydride Complexes Supported by the [N(2-PPh2-4-Me-C6H3)2] 351. Pincer Ligand M. E. Fasulo and T. D. Tilley, Inorg. Chim. Acta 2010, 364, 246. (special issue to commemorate the 70th birthday of Prof. Arnold L. Rheingold). Nickel Complexes with Bis(8-Quinolyl)silyl Ligands. An Unusual Ni3Si2 Cluster 350. Containing Six-Coordinate Silicon. J. Yang, I. D. Rosal, M. Fasulo, P. Sangtrirutnugul, L. Maron and T. D. Tilley, Organometallics 2010, 29, 5544. (MeQn2SiH)Fe[N(SiMe3)2]2 (Qn = 8-Quinolyl): An Unusual δ-Agostic Iron Complex 349. Containing an η1-SiH Interaction. J. Yang, M. Fasulo and T. D. Tilley, New J. Chem. 2010, 34, 2528. Synthesis and reactivity of rhodium and iridium alkene, alkyl and silyl complexes supported 348. by a phenyl-substituted pincer ligand. E. Calimano and T. D. Tilley, Dalton Trans. 2010, 39, 9250. Synthesis and Electronic Properties of Extended, Fused-Ring Aromatic Systems Containing 347. Multiple Pentalene Units. Z. Levi and T. D. Tilley, J. Am. Chem. Soc. 2010, 132, 11012. Reactions of Cationic PNP-Supported Iridium Silylene Complexes with Polar Organic 346. Substrates. E. Calimano and T. D. Tilley, Organometallics 2010, 29, 1680. Synthesis and Characterization of Fluorinated Heterofluorene-Containing Donor-Acceptor 345. Systems. K. Geramita, Y. Tao, R. A. Segalman and T. D. Tilley. J. Org. Chem. 2010, 75, 1871. Facile Interconversion of Cp2(Cl)Hf-SnH3 and Cp2(Cl)Hf(μ-H)SnH2: DFT Investigations 344. of Hafnocene Stannyl Complexes as Masked Stannylenes. J. Guihaumé, C. Raynaud, O. Eisenstein, L. Perrin, L. Maron and T. D. Tilley. Angew. Chem. Int. Ed. 2010, 49, 1816. Nucleophilic Attack of Amides onto Coordinated Ethylene in Platinum Complexes 343. Supported by a Chelating Pyridyl-Pyrrolide Ligand: Azaplatinacyclobutane and Vinylamine Complexes. J. L. McBee and T. D. Tilley. Organometallics 2010, 29, 184. Spatial Resolution of a Type II Heterojunction in a Single Bipolar Molecule. C. G. Tao, J. 342. B. Sun, X. W. Zhang, R. Yamachika, D. Wegner, Y. Bahri, G. Samsonidze, S. G. Louie, T. D. Tilley, R. A. Segalman and M. F. Crommie. Nano Lett. 2009, 9, 3963. 341. N-Heterocyclic Carbene-Stabilized Gold Nanoparticles and their Assembly into 3D Superlattices. J. Vignolle and T. D. Tilley. Chem. Comm. 2009, 7230. The Nature of Transport Variations in Molecular Heterojunction Electronics. J. A. Malen, 340. P. Doak, K. Baheti, T. D. Tilley, A. Majumdar and R. A. Segalman. Nano Lett. 2009, 9, 3406. Synthesis, Structure and Reactivity of Neutral Hydrogen-Substituted Ruthenium Silylene 339. and Germylene Complexes. P. G. Hayes, R. Waterman, P. B. Glaser and T. D. Tilley. Organometallics 2009, 28, 5082. Synthesis and Reactivity of Iridium and Rhodium Silyl Complexes Supported by a 338. Bipyridine Ligand. J. L. McBee and T. D. Tilley. Organometallics 2009, 28, 5072. High Oxidation State Rhodium and Iridium Bis(silyl)dihydride Complexes Supported by a 337.
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