Descriptive and Geoenvironmental Model for Cobalt-Copper-Gold Deposits in Metasedimentary Rocks
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PGM Associations in Copper-Rich Sulphide Ore of the Oktyabr Deposit, Talnakh Deposit Group, Russia Olga A. Yakovleva1, Sergey M. Kozyrev1 and Oleg I. Oleshkevich2 1Institute Gipronickel JS, St. Petersburg, Russia 2Mining and Metallurgical Company “Noril’sk Nickel” JS, Noril’sk, Russia e-mail: [email protected] The PGM assemblages of the Cu-rich 6%; the Ni content ranges 0.8 to 1.3%, and the ratio sulphide ores occurring in the western exocontact Cu/S = 0.1-0.2. zone of the Talnakh intrusion and the Kharaelakh Pyrrhotite-chalcopyrite ore occurs at the massive orebody have been studied. Eleven ore top of ore horizons. The ore-mineral content ranges samples, weighing 20 to 200 kg, were processed 50 to 60%, and pyrrhotite amount is <15%. The ore using gravity and flotation-gravity techniques. As a grades 1.1 to 1.3% Ni, and the ratio Cu/S = 0.35- result, the gravity concentrates were obtained from 0.7. the ores and flotation products. In the gravity Chalcopyrite ore occurs at the top and on concentrates, more than 20,000 PGM grains were the flanks of the orebodies. The concentration of found and identified, using light microscopy and sulphides ranges 50 to 60%, and pyrrhotite amount EPMA. The textural and chemical characteristics of is <1%; the Ni content ranges 1.3 to 3.4%, and the PGM were documented, as well as the PGM ratio Cu/S = 0.8-0.9. distribution in different size fractions. Also, the The ore types are distinctly distinguished balance of Pt, Pd and Au distribution in ores and by the PGE content which directly depends on the process products and the PGM mass portions in chalcopyrite quantity, but not on the total sulphide various ore types were calculated. -
LOW TEMPERATURE HYDROTHERMAL COPPER, NICKEL, and COBALT ARSENIDE and SULFIDE ORE FORMATION Nicholas Allin
Montana Tech Library Digital Commons @ Montana Tech Graduate Theses & Non-Theses Student Scholarship Spring 2019 EXPERIMENTAL INVESTIGATION OF THE THERMOCHEMICAL REDUCTION OF ARSENITE AND SULFATE: LOW TEMPERATURE HYDROTHERMAL COPPER, NICKEL, AND COBALT ARSENIDE AND SULFIDE ORE FORMATION Nicholas Allin Follow this and additional works at: https://digitalcommons.mtech.edu/grad_rsch Part of the Geotechnical Engineering Commons EXPERIMENTAL INVESTIGATION OF THE THERMOCHEMICAL REDUCTION OF ARSENITE AND SULFATE: LOW TEMPERATURE HYDROTHERMAL COPPER, NICKEL, AND COBALT ARSENIDE AND SULFIDE ORE FORMATION by Nicholas C. Allin A thesis submitted in partial fulfillment of the requirements for the degree of Masters in Geoscience: Geology Option Montana Technological University 2019 ii Abstract Experiments were conducted to determine the relative rates of reduction of aqueous sulfate and aqueous arsenite (As(OH)3,aq) using foils of copper, nickel, or cobalt as the reductant, at temperatures of 150ºC to 300ºC. At the highest temperature of 300°C, very limited sulfate reduction was observed with cobalt foil, but sulfate was reduced to sulfide by copper foil (precipitation of Cu2S (chalcocite)) and partly reduced by nickel foil (precipitation of NiS2 (vaesite) + NiSO4·xH2O). In the 300ºC arsenite reduction experiments, Cu3As (domeykite), Ni5As2, or CoAs (langisite) formed. In experiments where both sulfate and arsenite were present, some produced minerals were sulfarsenides, which contained both sulfide and arsenide, i.e. cobaltite (CoAsS). These experiments also produced large (~10 µm along longest axis) euhedral crystals of metal-sulfide that were either imbedded or grown upon a matrix of fine-grained metal-arsenides, or, in the case of cobalt, metal-sulfarsenide. Some experimental results did not show clear mineral formation, but instead demonstrated metal-arsenic alloying at the foil edges. -
Washington State Minerals Checklist
Division of Geology and Earth Resources MS 47007; Olympia, WA 98504-7007 Washington State 360-902-1450; 360-902-1785 fax E-mail: [email protected] Website: http://www.dnr.wa.gov/geology Minerals Checklist Note: Mineral names in parentheses are the preferred species names. Compiled by Raymond Lasmanis o Acanthite o Arsenopalladinite o Bustamite o Clinohumite o Enstatite o Harmotome o Actinolite o Arsenopyrite o Bytownite o Clinoptilolite o Epidesmine (Stilbite) o Hastingsite o Adularia o Arsenosulvanite (Plagioclase) o Clinozoisite o Epidote o Hausmannite (Orthoclase) o Arsenpolybasite o Cairngorm (Quartz) o Cobaltite o Epistilbite o Hedenbergite o Aegirine o Astrophyllite o Calamine o Cochromite o Epsomite o Hedleyite o Aenigmatite o Atacamite (Hemimorphite) o Coffinite o Erionite o Hematite o Aeschynite o Atokite o Calaverite o Columbite o Erythrite o Hemimorphite o Agardite-Y o Augite o Calciohilairite (Ferrocolumbite) o Euchroite o Hercynite o Agate (Quartz) o Aurostibite o Calcite, see also o Conichalcite o Euxenite o Hessite o Aguilarite o Austinite Manganocalcite o Connellite o Euxenite-Y o Heulandite o Aktashite o Onyx o Copiapite o o Autunite o Fairchildite Hexahydrite o Alabandite o Caledonite o Copper o o Awaruite o Famatinite Hibschite o Albite o Cancrinite o Copper-zinc o o Axinite group o Fayalite Hillebrandite o Algodonite o Carnelian (Quartz) o Coquandite o o Azurite o Feldspar group Hisingerite o Allanite o Cassiterite o Cordierite o o Barite o Ferberite Hongshiite o Allanite-Ce o Catapleiite o Corrensite o o Bastnäsite -
Geochemistry, Mineralogy and Microbiology of Cobalt in Mining-Affected Environments
minerals Article Geochemistry, Mineralogy and Microbiology of Cobalt in Mining-Affected Environments Gabriel Ziwa 1,2,*, Rich Crane 1,2 and Karen A. Hudson-Edwards 1,2 1 Environment and Sustainability Institute, University of Exeter, Penryn TR10 9FE, UK; [email protected] (R.C.); [email protected] (K.A.H.-E.) 2 Camborne School of Mines, University of Exeter, Penryn TR10 9FE, UK * Correspondence: [email protected] Abstract: Cobalt is recognised by the European Commission as a “Critical Raw Material” due to its irreplaceable functionality in many types of modern technology, combined with its current high-risk status associated with its supply. Despite such importance, there remain major knowledge gaps with regard to the geochemistry, mineralogy, and microbiology of cobalt-bearing environments, particu- larly those associated with ore deposits and subsequent mining operations. In such environments, high concentrations of Co (up to 34,400 mg/L in mine water, 14,165 mg/kg in tailings, 21,134 mg/kg in soils, and 18,434 mg/kg in stream sediments) have been documented. Co is contained in ore and mine waste in a wide variety of primary (e.g., cobaltite, carrolite, and erythrite) and secondary (e.g., erythrite, heterogenite) minerals. When exposed to low pH conditions, a number of such minerals are 2+ known to undergo dissolution, typically forming Co (aq). At circumneutral pH, such aqueous Co can then become immobilised by co-precipitation and/or sorption onto Fe and Mn(oxyhydr)oxides. This paper brings together contemporary knowledge on such Co cycling across different mining environments. -
Cobalt Mineral Ecology
American Mineralogist, Volume 102, pages 108–116, 2017 Cobalt mineral ecology ROBERT M. HAZEN1,*, GRETHE HYSTAD2, JOSHUA J. GOLDEN3, DANIEL R. HUMMER1, CHAO LIU1, ROBERT T. DOWNS3, SHAUNNA M. MORRISON3, JOLYON RALPH4, AND EDWARD S. GREW5 1Geophysical Laboratory, Carnegie Institution, 5251 Broad Branch Road NW, Washington, D.C. 20015, U.S.A. 2Department of Mathematics, Computer Science, and Statistics, Purdue University Northwest, Hammond, Indiana 46323, U.S.A. 3Department of Geosciences, University of Arizona, 1040 East 4th Street, Tucson, Arizona 85721-0077, U.S.A. 4Mindat.org, 128 Mullards Close, Mitcham, Surrey CR4 4FD, U.K. 5School of Earth and Climate Sciences, University of Maine, Orono, Maine 04469, U.S.A. ABSTRACT Minerals containing cobalt as an essential element display systematic trends in their diversity and distribution. We employ data for 66 approved Co mineral species (as tabulated by the official mineral list of the International Mineralogical Association, http://rruff.info/ima, as of 1 March 2016), represent- ing 3554 mineral species-locality pairs (www.mindat.org and other sources, as of 1 March 2016). We find that cobalt-containing mineral species, for which 20% are known at only one locality and more than half are known from five or fewer localities, conform to a Large Number of Rare Events (LNRE) distribution. Our model predicts that at least 81 Co minerals exist in Earth’s crust today, indicating that at least 15 species have yet to be discovered—a minimum estimate because it assumes that new minerals will be found only using the same methods as in the past. Numerous additional cobalt miner- als likely await discovery using micro-analytical methods. -
Cosalite Pb2bi2s5 C 2001-2005 Mineral Data Publishing, Version 1 Crystal Data: Orthorhombic
Cosalite Pb2Bi2S5 c 2001-2005 Mineral Data Publishing, version 1 Crystal Data: Orthorhombic. Point Group: 2/m 2/m 2/m. Prismatic crystals elongated k [001], to 8 cm; flexible capillary fibers; commonly massive in aggregates of radiating prismatic, fibrous, or feathery forms. Physical Properties: Cleavage: Very rare. Fracture: Uneven. Tenacity: Fibers are flexible. Hardness = 2.5–3 VHN = n.d. D(meas.) = 6.86–6.99 D(calc.) = 7.12 Optical Properties: Opaque. Color: Lead-gray to steel-gray to silver-white; in polished section, white, with only a trace of cream. Streak: Black. Luster: Metallic. Pleochroism: Weak. Anisotropism: Weak, but distinct in oil. R1–R2: (400) 48.2–51.4, (420) 47.0–50.3, (440) 45.9–49.5, (460) 44.9–48.7, (480) 43.9–47.9, (500) 43.0–47.1, (520) 42.2–46.4, (540) 41.6–45.9, (560) 41.1–45.5, (580) 40.8–45.3, (600) 40.5–45.2, (620) 40.4–45.2, (640) 40.2–45.2, (660) 40.1–45.2, (680) 40.1–45.2, (700) 40.0–45.1 Cell Data: Space Group: P bnm. a = 19.09 b = 23.87 c = 4.055 Z = 8 X-ray Powder Pattern: Hagidaira mine, Gumma Prefecture, Japan. 3.44 (100), 2.81 (30), 3.37 (23), 2.96 (22), 1.911 (17), 2.13 (15), 3.72 (14) Chemistry: (1) (2) (3) Pb 38.68 39.55 41.75 Cu 2.02 2.71 Fe 0.25 Bi 42.38 40.21 42.10 S 16.59 17.20 16.15 rem. -
Joint Meeting
Joint Meeting 19. Jahrestagung der Deutschen Gesellschaft für Kristallographie 89. Jahrestagung der Deutschen Mineralogischen Gesellschaft Jahrestagung der Österreichischen Mineralogischen Gesellschaft (MinPet 2011) 20.-24. September 2011 Salzburg Referate Oldenbourg Verlag – München Inhaltsverzeichnis Plenarvorträge ............................................................................................................................................................ 1 Goldschmidt Lecture .................................................................................................................................................. 3 Vorträge MS 1: Crystallography at High Pressure/Temperature ................................................................................................. 4 MS 2: Functional Materials I ........................................................................................................................................ 7 MS 3: Metamorphic and Magmatic Processes I ......................................................................................................... 11 MS 4: Computational Crystallography ....................................................................................................................... 14 MS 5: Synchrotron- and Neutron Diffraction ............................................................................................................. 17 MS 6: Functional Materials II and Ionic Conductors ................................................................................................ -
Petrography and Geochemistry of Metasedimentary Rocks from the Taku Schist in Kelantan, North-East Peninsular Malaysia
Journal of Applied Geology, vol. 5(2), 2020, pp. 124–140 DOI: http://dx.doi.org/10.22146/jag.61183 Petrography and Geochemistry of Metasedimentary Rocks from the Taku Schist in Kelantan, North-East Peninsular Malaysia Muhammad Irman Khalif Ahmad Aminuddin1,2, Nugroho Imam Setiawan*1, I Wayan Warmada1, Kamar Shah Ariffin2, and Kotaro Yonezu3 1Department of Geological Engineering, Faculty of Engineering, Universitas Gadjah Mada, Yogyakarta, Indonesia 2School of Materials and Mineral Resources Engineering, Universiti Sains Malaysia, Nibong Tebal, Penang 14300, Malaysia 3Department of Earth Resources Engineering, Kyushu University, 819-0395, Fukuoka, Japan ABSTRACT. The Taku Schist, located in north-east Peninsular Malaysia, is characterized by its North-South oriented elongated body. It forms part of the Indosinian orogenic build-up generated by the convergence of the Sibumasu continental block and Sukhothai Arc. Pet- rographic analyses of the metasedimentary rocks sourced from the Taku Schist revealed that the formation was attributable to greenschist’s metamorphism into amphibolite fa- cies, which could be observed near the Triassic and Cretaceous intrusions of the Kema- hang Granite. The evolution process of the rocks could be linked with the interactions between a contact and regional metamorphisms. The resulting of XRF and ICP-MS geo- chemical analyses upon the assessment disclosed that the metasedimentary rocks of Taku Schist were made up of greywacke and shale, grouped into the quartzose sedimentary protolith, and belonged to the Continental Island Arc (CIA). It reflects the Taku Schist’s episodic contractions, wherein they would lead to the Sibumasu sedimentary cover along with both an accretionary wedge and the genetically-correlated Bentong-Raub mélange to different greenschist. -
Palaeozoic Collision Between the North and South China Blocks, Triassic Intracontinental Tectonics, and the Problem of the Ultra
Palaeozoic collision between the North and South China Blocks, Triassic intracontinental tectonics, and the problem of the ultrahigh-pressure metamorphism Michel Faure, Wei Lin, Patrick Monié, Sébastien Meffre To cite this version: Michel Faure, Wei Lin, Patrick Monié, Sébastien Meffre. Palaeozoic collision between the North and South China Blocks, Triassic intracontinental tectonics, and the problem of the ultrahigh- pressure metamorphism. Comptes Rendus Géoscience, Elsevier Masson, 2008, 340, pp.139-150. 10.1016/j.crte.2007.10.007. insu-00191534 HAL Id: insu-00191534 https://hal-insu.archives-ouvertes.fr/insu-00191534 Submitted on 8 Jan 2008 HAL is a multi-disciplinary open access L’archive ouverte pluridisciplinaire HAL, est archive for the deposit and dissemination of sci- destinée au dépôt et à la diffusion de documents entific research documents, whether they are pub- scientifiques de niveau recherche, publiés ou non, lished or not. The documents may come from émanant des établissements d’enseignement et de teaching and research institutions in France or recherche français ou étrangers, des laboratoires abroad, or from public or private research centers. publics ou privés. Comptes Rendus Geoscience Palaeozoic collision between the North and South China blocks, Triassic intracontinental tectonics, and the problem of the ultrahigh-pressure metamorphism Collision paléozoïque entre les blocs de Chine du Nord et du Sud, tectonique intracontinentale triasique et le problème du métamorphisme de ultra-haute pression Michel Faure a, , Wei -
Cobalt Resources in Europe and the Potential for New Discoveries
Ore Geology Reviews 130 (2021) 103915 Contents lists available at ScienceDirect Ore Geology Reviews journal homepage: www.elsevier.com/locate/oregeorev Cobalt resources in Europe and the potential for new discoveries S. Horn a,b,*, A.G. Gunn a, E. Petavratzi a, R.A. Shaw a, P. Eilu c, T. Torm¨ anen¨ d, T. Bjerkgård e, J. S. Sandstad e, E. Jonsson f,g, S. Kountourelis h, F. Wall b a British Geological Survey, Nicker Hill, Keyworth, Nottingham NG12 5GG, United Kingdom b Camborne School of Mines, University of Exeter, Penryn Campus, Penryn TR10 9FE, United Kingdom c Geological Survey of Finland, PO Box 96, FI-02151 Espoo, Finland d Geological Survey of Finland, PO Box 77, FI-96101 Rovaniemi, Finland e Geological Survey of Norway, Postal Box 6315 Torgarden, NO-7491 Trondheim, Norway f Geological Survey of Sweden, Box 670, SE-751 28 Uppsala, Sweden g Department of Earth Sciences, Uppsala University, Villavagen¨ 16, SE-752 36 Uppsala, Sweden h G.M.M.S.A. LARCO, Northern Greece Mines, Mesopotamia, Kastoria 52050, Greece ARTICLE INFO ABSTRACT Keywords: Global demand for cobalt is increasing rapidly as we transition to a low-carbon economy. In order to ensure Cobalt secure and sustainable supplies of this critical metal there is considerable interest in Europe in understanding the Nickel availability of cobalt from indigenous resources. This study reviews information on cobalt resources in Europe Copper and evaluates the potential for additional discoveries. Europe Based on published information and a survey of national mineral resource agencies, 509 cobalt-bearing de Resources UNFC posits and occurrences have been identified in 25 countries in Europe. -
Primary Minerals of the Jáchymov Ore District
Journal of the Czech Geological Society 48/34(2003) 19 Primary minerals of the Jáchymov ore district Primární minerály jáchymovského rudního revíru (237 figs, 160 tabs) PETR ONDRU1 FRANTIEK VESELOVSKÝ1 ANANDA GABAOVÁ1 JAN HLOUEK2 VLADIMÍR REIN3 IVAN VAVØÍN1 ROMAN SKÁLA1 JIØÍ SEJKORA4 MILAN DRÁBEK1 1 Czech Geological Survey, Klárov 3, CZ-118 21 Prague 1 2 U Roháèových kasáren 24, CZ-100 00 Prague 10 3 Institute of Rock Structure and Mechanics, V Holeovièkách 41, CZ-182 09, Prague 8 4 National Museum, Václavské námìstí 68, CZ-115 79, Prague 1 One hundred and seventeen primary mineral species are described and/or referenced. Approximately seventy primary minerals were known from the district before the present study. All known reliable data on the individual minerals from Jáchymov are presented. New and more complete X-ray powder diffraction data for argentopyrite, sternbergite, and an unusual (Co,Fe)-rammelsbergite are presented. The follow- ing chapters describe some unknown minerals, erroneously quoted minerals and imperfectly identified minerals. The present work increases the number of all identified, described and/or referenced minerals in the Jáchymov ore district to 384. Key words: primary minerals, XRD, microprobe, unit-cell parameters, Jáchymov. History of mineralogical research of the Jáchymov Chemical analyses ore district Polished sections were first studied under the micro- A systematic study of Jáchymov minerals commenced scope for the identification of minerals and definition early after World War II, during the period of 19471950. of their relations. Suitable sections were selected for This work was aimed at supporting uranium exploitation. electron microprobe (EMP) study and analyses, and in- However, due to the general political situation and the teresting domains were marked. -
Mineralogy of Cu-Ni-PGE Ore and Sequence of Events in the Copper Cliff South Mine, Sudbury, Ontario
Mineralogy of Cu-Ni-PGE ore and Sequence of Events in the Copper Cliff South Mine, Sudbury, Ontario Zsuzsanna Magyarosi, David H. Watkinson, and Peter C. Jones Department of Earth Sciences, Carleton University, 1125 Colonel By Drive, Ottawa, Ontario, Canada K1S 5B6 e-mail: [email protected] The Sudbury Structure is the largest Cu- country rocks are Copper Cliff rhyolite and Ni-PGE producer in the world. It is an impact McKim metasediments. structure in rocks of the Superior Province to the The 800 and 810 ore bodies are the two North and the Southern Province to the South. major deposits in the Copper Cliff South mine, The Sudbury Igneous Complex is subdivided located at the opposite contacts of the quartz into Main Mass and offset dikes (radial and diorite dike with metapelite of McKim concentric): the Main Mass is composed of the Formation. In several places the two ore bodies Contact Sublayer, norite, quartz gabbro and are connected through the center of the dike or granophyre, from bottom to top. The offset there is another ore body parallel to the contact dikes, composed of quartz diorite, intruded along of quartz diorite and country rocks. The primary fracture zones in highly brecciated areas created magmatic minerals in the quartz diorite in by the meteorite impact (Hawley, 1962). The Copper Cliff South include plagioclase, quartz, Copper Cliff Offset, the host of 15 % of the amphibole and biotite. The quartz diorite is sulfide ore (Cochrane, 1984), is one of the radial weakly to strongly altered in the whole area, with offset dikes in the South Range of the Sudbury increasing degree of alteration toward the Structure.