The Influence of Heavy Metals and Organic Matter on Hexavalent
View metadata, citation and similar papers at core.ac.uk brought to you by CORE provided by Archivio della ricerca- Università di Roma La Sapienza 289 A publication of CHEMICAL ENGINEERING TRANSACTIONS VOL. 47, 2016 The Italian Association of Chemical Engineering Online at www.aidic.it/cet Guest Editors: Angelo Chianese, Luca Di Palma, Elisabetta Petrucci, Marco Stoller Copyright © 2016, AIDIC Servizi S.r.l., ISBN 978-88-95608-38-9; ISSN 2283-9216 DOI: 10.3303/CET1647049 The Influence of Heavy Metals and Organic Matter on Hexavalent Chromium Reduction by Nano Zero Valent Iron in Soil Mouhamadou Thierno Gueyea, Luca Di Palmab, Gunel Allahverdeyevac, Irene b b b b Bavasso , Elisabetta Petrucci , Marco Stoller , Giorgio Vilardi a Université Cheikh Anta Diop de Dakar (UCAD), Dakar Fann, Senegal b Sapienza Università di Roma, Dipartimento di Ingegneria Chimica Materiali Ambiente, via Eudossiana 18, 00184 Roma c Baku State University, 23 Khalilov St., Baku, Azerbaijan During the last decades great attention has been payed at evaluating the feasibility of Cr(VI) reduction in soil 0 by nano zero valent iron (nZVI). An inhibitory effect on the Cr(VI) reduction by Fe nanoparticles is generally shown in the presence of high level of heavy metals and natural organic matter in soil. Heavy metals in the environment can react with nZVI by redox reactions, precipitation/dissolution reactions, and adsorption/desorption phenomena. As a result of the presence of metals as Ni, Pb, a decrease in the rate of Cr(VI) reduction was observed. Hence, in the present study, experimental tests of Cr(VI) reduction by nZVI in the presence of selected heavy metals, such as nickel and lead, and in the presence of high level of organic matter, are presented and discussed.
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