Gold Processing: Cyanide Leach Process
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From Base Metals and Back – Isamills and Their Advantages in African Base Metal Operations
The Southern African Institute of Mining and Metallurgy Base Metals Conference 2013 H. de Waal, K. Barns, and J. Monama From base metals and back – IsaMills and their advantages in African base metal operations H. de Waal, K. Barns, and J. Monama Xstrata IsaMill™ technology was developed from Netzsch Feinmahltechnik GmbH stirred milling technology in the early 1990s to bring about a step change in grinding efficiency that was required to make Xstrata’s fine-grained lead/zinc orebodies economic to process. From small-scale machines suited to ultrafine grinding, the IsaMill™ has developed into technology that is able to treat much larger tonnages, in coarser applications, while still achieving high energy efficiency, suited for coarser more standard regrind and mainstream grinding applications. The unique design of the IsaMillTM, combining high power intensity and effective internal classification, achieves high energy efficiency and tight product distribution which can be effectively scaled from laboratory scale to full-sized models. The use of fine ceramic media also leads to significant benefits in downstream flotation and leaching operations. These benefits are key drivers for the adoption of the technology into processing a diverse range of minerals worldwide, and offer major opportunities for power reduction and improved metallurgy for the African base metal operations. Keywords: IsaMill, regrind, energy efficiency, inert grinding. Introduction The development of the IsaMillTM, by MIM (now GlencoreXstrata) and Netzsch Feinmahltechnik GmbH, was initiated to enable the development of the fine-grained ore deposits at Mt Isa and McArthur River in Northern Australia. To liberate the valuable minerals and so produce a saleable concentrate this ultrafine-grained ore needed to be ground to a P80 of 7 μm. -
Some Problems and Potentials of the Study of Cupellation
Some problems and potentials of the study of cupellation remains: the case of post-medieval Montbéliard, France Marcos Martinon-Torres, Nicolas Thomas, Thilo Rehren, Aude Mongiatti To cite this version: Marcos Martinon-Torres, Nicolas Thomas, Thilo Rehren, Aude Mongiatti. Some problems and po- tentials of the study of cupellation remains: the case of post-medieval Montbéliard, France. Archeo- sciences, revue d’Archéométrie, G.M.P.C.A./Presses universitaires de Rennes, 2008, pp.59-70. halshs- 00599974 HAL Id: halshs-00599974 https://halshs.archives-ouvertes.fr/halshs-00599974 Submitted on 19 Jun 2011 HAL is a multi-disciplinary open access L’archive ouverte pluridisciplinaire HAL, est archive for the deposit and dissemination of sci- destinée au dépôt et à la diffusion de documents entific research documents, whether they are pub- scientifiques de niveau recherche, publiés ou non, lished or not. The documents may come from émanant des établissements d’enseignement et de teaching and research institutions in France or recherche français ou étrangers, des laboratoires abroad, or from public or private research centers. publics ou privés. Some problems and potentials of the study of cupellation remains: the case of early modern Montbéliard, France Problèmes et perspectives à partir de l’étude des vestiges archéologiques issus de la coupellation : l’exemple du site de Montbéliard (France) Marcos Martinón-Torres*, Nicolas Thomas**, Thilo Rehren*, and Aude Mongiatti* Abstract: Bone-ash cupels are increasingly identified in medieval and later archaeological contexts related to the refining of noble metals in alchemy, assaying, jewellery or coin minting. These small finds may provide information on metal refining activities, the technical knowledge of different craftspeople, and the versatility of laboratory practices, which often differed from the standard protocols recorded in metallurgical treatises. -
S Ndlovu (PDF)
Extraction of Gold Then, Now and the Future Prof Sehliselo Ndlovu DST/NRF SARChI: Hydrometallurgy and Sustainable Development University of the Witwatersrand, Johannesburg Building a Robust Minerals Industry 3 – 4 July 2017, Cresta Lodge, Harare University of the Witwatersrand Johannesburg Founded Oct. 1896: School of Mines Approx. 37 000 Students 5 Faculties, 33 Schools, 3610 Courses >160 000 Degrees Conferred since 1922 55% Female Students 10 National Centres of Excellence Home to the Bidvest Football Club( Current PSL league Champions) Evolution in Gold Processing Past Technologies • Amalgamation • Panning Current Technologies • Cyanide leaching • Processing of Emerging and Future refractory ores Technologies • Bio-oxidation • Ionic liquids • Alternative leaching • Ultrasonic leaching reagents • Corn starch?? Past Technologies Used in Ancient Times History of gold extends back at least 6,000 years. Egypt and Mesopotamia around 4000 BC. Gravity Separation: Gold Panning Gold concentrated by washing lighter river sands with water Leaves dense gold particles Alternative- wash gold-bearing sand and gravel over a woollen fleece Traps heavier gold dust that would sink into the wool fibres. Advantages • Simplicity Disadvantages • Labour intensive Gravity Separation: Sluicing • Water is channelled to flow through a sluice-box. • Sluice-box is essentially a man-made channel with riffles (barriers) at the bottom. • Riffles create dead-zones in the water current which allows gold to drop out of suspension. Sluicing and panning results in the direct recovery of small gold nuggets and flakes. Gold Parting: Salt Cementation Process • Invented to remove Ag from Au-Ag mixtures around 6th century BC. Mix: argentiferous gold foil, common salt, brick dust or burnt clay and urine in a sealed container. -
Metal Extraction Processes for Electronic Waste and Existing Industrial Routes: a Review and Australian Perspective
Resources 2014, 3, 152-179; doi:10.3390/resources3010152 OPEN ACCESS resources ISSN 2079-9276 www.mdpi.com/journal/resources Review Metal Extraction Processes for Electronic Waste and Existing Industrial Routes: A Review and Australian Perspective Abdul Khaliq, Muhammad Akbar Rhamdhani *, Geoffrey Brooks and Syed Masood Faculty of Science, Engineering and Technology, Swinburne University of Technology, Hawthorn, VIC 3122, Australia; E-Mails: [email protected] (A.K.); [email protected] (G.B.); [email protected] (S.M.) * Author to whom correspondence should be addressed; E-Mail: [email protected]; Tel.: +61-3-9214-8528; Fax: +61-3-9214-8264. Received: 11 December 2013; in revised form: 24 January 2014 / Accepted: 5 February 2014 / Published: 19 February 2014 Abstract: The useful life of electrical and electronic equipment (EEE) has been shortened as a consequence of the advancement in technology and change in consumer patterns. This has resulted in the generation of large quantities of electronic waste (e-waste) that needs to be managed. The handling of e-waste including combustion in incinerators, disposing in landfill or exporting overseas is no longer permitted due to environmental pollution and global legislations. Additionally, the presence of precious metals (PMs) makes e-waste recycling attractive economically. In this paper, current metallurgical processes for the extraction of metals from e-waste, including existing industrial routes, are reviewed. In the first part of this paper, the definition, composition and classifications of e-wastes are described. In the second part, separation of metals from e-waste using mechanical processing, hydrometallurgical and pyrometallurgical routes are critically analyzed. -
Cip and Cil Circuit Modelling
SGS MINERALS SERVICES – T3 SGS 1338 02-2014 CIP AND CIL CIRCUIT MODELLING The SGS carbon-in-pulp (CIP) / carbon- in-leach (CIL) modelling package is used to estimate the performance of a full-scale CIP or CIL plant and to derive the optimum design criteria based on the results of small scale experiments. It is a powerful design tool that uses the results from standard leach and adsorption tests (bottle roll tests) to generate kinetic data that are fitted to leaching and carbon adsorbtion rate equations (Figure 2). The rate data and mass balance equations are then applied to the SGS model to calculate the concentrations of gold in solution, on the carbon and in the ore for each stage of a multi-stage leach- adsorbtion circuit. The model allows for the generation of multiple operating scenarios, where • the number of leach and adsorption stages can be varied, • the carbon concentration per tank can be adjusted, • the carbon loading and final barren solutions can be manipulated, • and carbon advance and elution rates adjusted. PHILOSOPHY The SGS CIP/CIL model is based on a model developed by Fleming and Nicol • Robust predictions of steady state as (1984). The philosophy then was to strive APPLICATIONS well as transient carbon adsorption for simplicity and user-friendliness, rather behaviour from simple laboratory The SGS CIP/CIL model can be used for than precision through complexity. This batch tests, feasibility or production stage projects. is still true today in SGS‘ CIP and CIL • Economic sensitivity analyses of It is a cost effective way to determine modelling package. -
Principles of Extractive Metallurgy Lectures Note
PRINCIPLES OF EXTRACTIVE METALLURGY B.TECH, 3RD SEMESTER LECTURES NOTE BY SAGAR NAYAK DR. KALI CHARAN SABAT DEPARTMENT OF METALLURGICAL AND MATERIALS ENGINEERING PARALA MAHARAJA ENGINEERING COLLEGE, BERHAMPUR DISCLAIMER This document does not claim any originality and cannot be used as a substitute for prescribed textbooks. The information presented here is merely a collection by the author for their respective teaching assignments as an additional tool for the teaching-learning process. Various sources as mentioned at the reference of the document as well as freely available material from internet were consulted for preparing this document. The ownership of the information lies with the respective author or institutions. Further, this document is not intended to be used for commercial purpose and the faculty is not accountable for any issues, legal or otherwise, arising out of use of this document. The committee faculty members make no representations or warranties with respect to the accuracy or completeness of the contents of this document and specifically disclaim any implied warranties of merchantability or fitness for a particular purpose. BPUT SYLLABUS PRINCIPLES OF EXTRACTIVE METALLURGY (3-1-0) MODULE I (14 HOURS) Unit processes in Pyro metallurgy: Calcination and roasting, sintering, smelting, converting, reduction, smelting-reduction, Metallothermic and hydrogen reduction; distillation and other physical and chemical refining methods: Fire refining, Zone refining, Liquation and Cupellation. Small problems related to pyro metallurgy. MODULE II (14 HOURS) Unit processes in Hydrometallurgy: Leaching practice: In situ leaching, Dump and heap leaching, Percolation leaching, Agitation leaching, Purification of leach liquor, Kinetics of Leaching; Bio- leaching: Recovery of metals from Leach liquor by Solvent Extraction, Ion exchange , Precipitation and Cementation process. -
Table of Contents
Table of Contents Preface ........................................... xi Chapter 1. Physical Extraction Operations .................... 1 1.1. Solid-solid and solid-fluid separation operations .............. 1 1.1.1. Flotation ................................... 1 1.1.2. Settling under gravity ........................... 3 1.1.3. Centrifugation ................................ 3 1.1.4. Filtration ................................... 4 1.2. Separation operations of the components of a fluid phase ........ 5 1.2.1. Condensation ................................ 5 1.2.2. Vacuum distillation ............................. 5 1.2.3. Liquation ................................... 6 1.2.4. Distillation .................................. 8 1.2.5. Extractive distillation ........................... 11 1.3. Bibliography ................................... 12 Chapter 2. Hydrometallurgical Operations .................... 15 2.1. Leaching and precipitation operations .................... 15 2.1.1. Leaching and precipitation reactors ................... 15 2.1.2. Continuous stirred tank reactor (CSTR) ................ 18 2.1.3. Models of leaching and precipitation operations ........... 20 2.1.4. Particle-size distribution (PSD) functions ............... 21 2.2. Reactor models based on particle residence time distribution functions ........................................ 24 2.2.1. Performance equations for a single CSTR ............... 24 2.2.2. Performance equations for multistage CSTRs ............. 28 2.3. Reactor models based on the population balance -
Recovery of Gold and Iron from Cyanide Tailings with a Combined Direct Reduction Roasting and Leaching Process
metals Article Recovery of Gold and Iron from Cyanide Tailings with a Combined Direct Reduction Roasting and Leaching Process Pingfeng Fu 1,2,* ID , Zhenyu Li 1, Jie Feng 1 and Zhenzhong Bian 1 1 School of Civil and Resources Engineering, University of Science and Technology Beijing, Beijing 100083, China; [email protected] (Z.L.); [email protected] (J.F.); [email protected] (Z.B.) 2 Key Laboratory of High-Efficient Mining and Safety of Metal Mines, Ministry of Education, Beijing 100083, China * Correspondence: [email protected]; Tel.: +86-10-6233-2902 Received: 25 June 2018; Accepted: 19 July 2018; Published: 21 July 2018 Abstract: Cyanide tailings are the hazardous waste discharged after gold cyanidation leaching. The recovery of gold and iron from cyanide tailings was investigated with a combined direct reduction roasting and leaching process. The effects of reduction temperature, coal dosage and CaO dosage on gold enrichment into Au-Fe alloy (FexAu1−x) were studied in direct reduction roasting. Gold containing iron powders, i.e., Au-Fe alloy, had the gold grade of 8.23 g/t with a recovery of 97.46%. After separating gold and iron in iron powders with sulfuric acid leaching, ferrous sulfate in the leachate was crystallized to prepare FeSO4·7H2O with a yield of 222.42% to cyanide tailings. Gold enriched in acid-leaching residue with gold grade of 216.58 g/t was extracted into pregnant solution. The total gold recovery of the whole process reached as high as 94.23%. The tailings generated in the magnetic separation of roasted products, with a yield of 51.33% to cyanide tailings, had no toxic cyanide any more. -
Metal Leaching in Mine-Waste Materials and Two Schemes for Classification of Potential Environmental Effects of Mine-Waste Piles
Metal Leaching in Mine-Waste Materials and Two Schemes for Classification of Potential Environmental Effects of Mine-Waste Piles By David L. Fey and George A. Desborough Chapter D4 of Integrated Investigations of Environmental Effects of Historical Mining in the Basin and Boulder Mining Districts, Boulder River Watershed, Jefferson County, Montana Edited by David A. Nimick, Stanley E. Church, and Susan E. Finger Professional Paper 1652–D4 U.S. Department of the Interior U.S. Geological Survey ffrontChD4new.inddrontChD4new.indd ccxxxviixxxvii 33/14/2005/14/2005 66:07:29:07:29 PPMM Contents Abstract ...................................................................................................................................................... 139 Introduction ............................................................................................................................................... 139 Purpose and Scope ......................................................................................................................... 140 Sample Collection and Preparation ....................................................................................................... 140 Bulk Surface Samples ..................................................................................................................... 140 Two-Inch Diameter Vertical Core .................................................................................................. 140 Location of Mine-Waste Sites ............................................................................................................... -
Treatment and Microscopy of Gold
TREATMENT AND MICROSCOPY OF GOLD AND BASE METAL ORES. (Script with Sketches & Tables) Short Course by R. W. Lehne April 2006 www.isogyre.com Geneva University, Department of Mineralogy CONTENTS (Script) page 1. Gold ores and their metallurgical treatment 2 1.1 Gravity processes 2 1.2 Amalgamation 2 1.3 Flotation and subsequent processes 2 1.4 Leaching processes 3 1.5 Gold extraction processes 4 1.6 Cyanide leaching vs. thio-compound leaching 5 2. Microscopy of gold ores and treatment products 5 2.1 Tasks and problems of microscopical investigations 5 2.2 Microscopy of selected gold ores and products 6 (practical exercises) 3. Base metal ores and their beneficiation 7 3.1 Flotation 7 3.2 Development of the flotation process 7 3.3 Principles and mechanisms of flotation 7 3.4 Column flotation 9 3.5 Hydrometallurgy 10 4. Microscopy of base metal ores and milling products 10 4.1 Specific tasks of microscopical investigations 11 4.2 Microscopy of selected base metal ores and milling products 13 (practical exercises) 5. Selected bibliography 14 (Sketches & Tables) Different ways of gold concentration 15 Gravity concentration of gold (Agricola) 16 Gravity concentration of gold (“Long Tom”) 17 Shaking table 18 Humphreys spiral concentrator 19 Amalgamating mills (Mexican “arrastra”, Chilean “trapiche”) 20 Pressure oxidation flowsheet 21 Chemical reactions of gold leaching and cementation 22 Cyanide solubilities of selected minerals 23 Heap leaching flowsheet 24 Carbon in pulp process 25 Complexing of gold by thio-compounds 26 Relation gold content / amount of particles in polished section 27 www.isogyre.com Economically important copper minerals 28 Common zinc minerals 29 Selection of flotation reagents 30 Design and function of a flotation cell 31 Column cell flotation 32 Flowsheet of a simple flotation process 33 Flowsheet of a selective Pb-Zn flotation 34 Locking textures 35 2 1. -
Xstrata Technology Update Edition 13 – April 2012 Building Plants That Work
xstrata technology update Edition 13 – April 2012 Building plants that work You have to get a lot of things it takes another operator to get them right to build a plant that works. right. Someone who has lived through the problems, had to do the maintenance, operated during a midnight power Of course the big picture must be right – doing the right project, in the right place, failure, cleaned up the spill. Someone at the right time. who has “closed the loop” on previous designs; lived with previous decisions After that, the devil is in the detail. You and improved them, over and over. need a sound design, good execution, good commissioning, and ongoing This is why Xstrata Technology provides support after commissioning. You need a technology “package”. Just as a car to operate and maintain your plant in is more than an engine, technology is the long run, long after the construction more than a single piece of equipment. company has left. That’s when all the Technology is a system. All the elements “little” details become important – how of the system have to work with each easy is it to operate, how good is the other and with the people in the plant. maintenance access, what happens in We want our cars designed by people a power failure, where are the spillage who love cars and driving. So should points and how do we clean them our plants be designed by people with up? Are the instruments reliable and experience and passion to make each is the process control strategy robust one work better than the last. -
Production of Gold
Production of Gold Background A feasibility study on the production of gold at a fictitious mine (Moapa mine) in Elko County, Nevada is to be performed. The mine is capable of producing 325,800 tons of high-grade ore per year for 8 years. The deposit contains 0.12 ounces of gold per ton of high-grade ore and can be acquired at a cost of $10 per ton of ore (cost of mining ore at site). A sodium cyanide process is used to extract the gold from the ore, and various other processing techniques are used to produce 99.9% pure gold bullion from the ore. The results of the feasibility study show that the ore can be processed by agitation leaching, which is preferred over heap leaching due to the low recovery associated with the heap leaching technology. The problem is to find the break-even price of gold for this mining operation. The process is currently unprofitable with a gold price around $300 per ounce. Process Description Unit 100 – Size Reduction of Ore The BFD of the overall process is shown in Figure 1. The PFD for Unit 100, shown in Figure 2, is designed to reduce 41.5 tons/hr of gold ore from a feed range of 2- 5” to 160 microns. The mined ore is fed using a Grizzly Feeder, F-101, into a Jaw Crusher, J-101, where 80% of the ore is crushed to 1.75” or smaller. The remaining 20% are recycled back into F-101 (not shown on PFD). The ore is then sent to Screen S-101 where the ore that does not pass through the first deck is sent to the Standard Cone Crusher SC-101.