TSCA New Chemicals Notices Received May, 2020

Total Page:16

File Type:pdf, Size:1020Kb

TSCA New Chemicals Notices Received May, 2020 TSCA New Chemicals Notices Received file:///W:/OneEPA/Newchems/pubs/5d2-IMD/PMN-SNUN-MCAN-T... TSCA New Chemicals Notices Received May, 2020 Received Case No. Version Manufacturer Use Chemical Substance Date (S) A lubricating agent SN-19-0004A 4 06/04/2019 CBI used in the production of (G) Pitch coke automotive disc brakes Molecular SN-19-0005A 2 05/28/2019 (G) Conductive ink (S) Functionalized multiwall carbon nanotubes Rebar Design (G) Carboxylic acids, unsaturated, polymers with disubstituted amine, alkanediol, substituted alkylpropanoic acid, alkanedioic P-16-0442A 4 06/26/2019 CBI (G) Polymer for coatings acid and substituted isocyanatocycloalkane, compds with alkylamine (G) Carboxylic acids, unsaturated, hydrogenated polymers with disubstituted amine, alkanediol, substituted alkylpropanoic P-16-0443A 4 06/26/2019 CBI (G) Polymer for coatings acid, alkanedioic acid and substituted isocyanatocycloalkane, compds with alkylamine P-16-0444A 4 06/26/2019 CBI (G) Polymer for coatings (G) Amine salted polyurethane (G) Carboxylic acids, unsaturated, hydrogenated polymers with substituted alkanediamine, alkanediol, substituted P-16-0445A 4 06/26/2019 CBI (G) Polymer for coatings alkylpropanoic acid, alkanedioic acid and substituted isocyanatocycloalkane, compds with alkylamine P-17-0007A 5 06/13/2019 CBI (S) Intermediate (G) Dialkyl 7,10-dioxa, dithiahexadeca diene (G) Substituted carboxylic acid, polymer with 2,4-diisocyanato- 1-methylbenzene, hexanedioic acid, alpha-hydro-omega- (G) Adhesive for open P-17-0239A 6 06/11/2019 CBI hydroxypoly[oxy(methyl-1,2-ethanediyl)], 1,1'-methylenebis[4- non-descriptive use isocyanatobenzene], 2,2'-oxybis[ethanol], 1,1'-oxybis[2- propanol] and 1,2-propanediol (G) 2-Propenoic acid, alkyl -, polymers with alkyl acrylate and P-17-0299A 3 06/06/2019 CBI (G) Paint additive polyethylene glycol methacrylate alkyl ether P-17-0345A 2 06/07/2019 CBI (G) Resin intermediate (G) Polyurethane, methacrylate blocked (G) Alkyl oil, polymer with 1,4-cyclohexanedimethanol, P-17-0389A 6 06/24/2019 CBI (G) Polymer precursor dehydrated Alkyl oil, hydrogentated rosin, phthalic anhydride and trimethylolpropane P-18-0009A 5 06/24/2019 CBI (G) Lubricant additive (G) Phosphonic acid, dimethyl ester, polymer with alkyl diols P-18-0044A 3 06/24/2019 CBI (G) Intermediate species (G) Fatty acids P-18-0045A 3 06/24/2019 CBI (G) Application coating (G) Fatty acids, alkyl esters (G) Raw material in (G) Alkane, diisocyanato-, homopolymer, alkyl dihydrogen P-18-0050 1 11/16/2017 CBI industrial coatings phosphate- and polyalkylene glycol mono-alkyl ether- (G) Alkyl methacrylates, polymer with alkyl acrylates, styrene (G) Industrial coating P-18-0061A 3 06/24/2019 CBI hydroxyalkyl acrylates, novalac epoxy and epoxy modified hardners acrylic salt with organic amines (G) 2-Alkenoic acid, 2-alkyl-, 2-alkyl ester, polymer with alkyl 2-alkenoate, 2-substitutedalkyl 2-alkenoate and P-18-0078A 4 06/26/2019 CBI (G) Paint 2-substitutedalkyl 2-alkyl-2-alkenoate, tert alkylperoxoate initiated Polymer (G) Alkylamide, polymer with alkylamine, formaldehyde, and P-18-0122A 6 06/04/2019 (G) Paper additive Ventures, Inc. polycyanamide, alkyl acid salt. NOLTEX (G) Reagent in coating P-18-0125A 2 06/18/2019 (G) Oxoalkylcarboxylic acid, sodium salt L.L.C. material (G) Polymer composite P-18-0197A 2 06/21/2019 CBI (G) Metal, alkylcarboxylate oxo complexes additive (G) Polymer composite P-18-0207A 3 06/21/2019 CBI (G) Metal, oxo alkylcarboxylate complexes additive P-18-0239A 3 06/26/2019 CBI (G) Reactant in coating (G) N-alkyl propanamide P-18-0240A 3 06/26/2019 CBI (G) Reactant in coating (G) N-alkyl acetamide 1 of 66 6/22/2020, 9:04 AM TSCA New Chemicals Notices Received file:///W:/OneEPA/Newchems/pubs/5d2-IMD/PMN-SNUN-MCAN-T... Received Case No. Version Manufacturer Use Chemical Substance Date (G) Fatty acids, polymers with alkanoic acid and substituted Allnex USA (S) Binder for wood P-18-0260A 4 06/04/2019 carbomonocycle, peroxide-initiated, polymers with alkanoic Inc. stains acid esters and substituted carbomonocycle, ammonium salts (G) Mixed alkyl esters-, polymer with N1-(2-aminoethyl)- l,2- P-18-0263A 2 06/17/2019 CBI (G) Solution additive ethanediamine, aziridine, N-acetyl derivs., acetates (salts) (G) Mixed alkyl esters-, polymer with N1-(2-aminoethyl)- l,2- P-18-0263A 3 06/26/2019 CBI (G) Solution additive ethanediamine, aziridine, N-acetyl derivs., acetates (salts) (S) Chemical P-18-0274A 6 06/19/2019 CBI (G) Heterocycle fluoroalkyl sulfonyl Intermediate P-18-0274A 6 06/19/2019 CBI (G) Additive (G) Heterocycle fluoroalkyl sulfonyl (S) Use as an ingredient in the manufacture of consumer cleaning P-18-0295 1 08/30/2018 CBI products. In these (S) 1,3-Butanediol, (3R)- products, the notified chemical is not destroyed nor further reacted. (S) Use as monomer in the manufacture of resins for use in paint and P-18-0295 1 08/30/2018 CBI coating products. (S) 1,3-Butanediol, (3R)- Notified substance will not be present in the cured coating. (S) Use as a monomer in the manufacture of plastic products. In this process the notified substance is reacted with one or more other compounds to become part of a P-18-0295 1 08/30/2018 CBI polymer. Depending on (S) 1,3-Butanediol, (3R)- the reactants involved, the final polymer can be a resin used to make molded plastic products or the final polymer can be a shorter polymer used as a plasticizer. Kuraray (G) Raw material for P-18-0323A 3 06/18/2019 (S) 2-Propenoic acid, 2-methyl-, 3-methyl-3-buten-1-yl ester America, Inc. polymer manufacturing (G) Formaldehyde, polymer with phenol and heteroatom- P-18-0372A 4 06/11/2019 Hexion Inc (G) Polyol. substituted heteromonocycle, reaction products with 1,3- dioxolan-2-one and 4-methyl-1,3-dioxolan-2-one (S) Reactive modifier for Carbon, Fiber bonding, (G) Formaldehyde, polymer with phenol and heteroatom- Friction, Coated P-18-0372A 4 06/11/2019 Hexion Inc substituted heteromonocycle, reaction products with 1,3- abrasives, Glass Inserts, dioxolan-2-one and 4-methyl-1,3-dioxolan-2-one Refractory, and Bonded abrasives. (S) Reactive polyol for (G) Formaldehyde, polymer with phenol and heteroatom- Sealants, Adhesives, 1 P-18-0372A 4 06/11/2019 Hexion Inc substituted heteromonocycle, reaction products with 1,3- part coatings, 2 part dioxolan-2-one and 4-methyl-1,3-dioxolan-2-one coatings, and composites. (G) Formaldehyde, polymer with phenol and heteroatom- P-18-0372A 3 05/31/2019 Hexion Inc (G) Polyol. substituted heteromonocycle, reaction products with 1,3- dioxolan-2-one and 4-methyl-1,3-dioxolan-2-one (S) Reactive modifier for (G) Formaldehyde, polymer with phenol and heteroatom- Carbon, Fiber bonding, P-18-0372A 3 05/31/2019 Hexion Inc substituted heteromonocycle, reaction products with 1,3- Friction, Coated dioxolan-2-one and 4-methyl-1,3-dioxolan-2-one 2 of 66 6/22/2020, 9:04 AM TSCA New Chemicals Notices Received file:///W:/OneEPA/Newchems/pubs/5d2-IMD/PMN-SNUN-MCAN-T... Received Case No. Version Manufacturer Use Chemical Substance Date abrasives, Glass Inserts, Refractory, and Bonded abrasives. (S) Reactive polyol for (G) Formaldehyde, polymer with phenol and heteroatom- Sealants, Adhesives, 1 P-18-0372A 3 05/31/2019 Hexion Inc substituted heteromonocycle, reaction products with 1,3- part coatings, 2 part dioxolan-2-one and 4-methyl-1,3-dioxolan-2-one coatings, and composites. (G) Formaldehyde, polymer with 2-methyloxirane, oxirane, P-18-0373A 4 06/11/2019 Hexion Inc (G) Polyol phenol and heteroatom-substituted heteromonocycle (G) Formaldehyde, polymer with 2-methyloxirane, oxirane, P-18-0373A 3 05/31/2019 Hexion Inc (G) Polyol phenol and heteroatom-substituted heteromonocycle (G) Hydroxyalkyl carboxylic acid, polymer with alkylamine, P-19-0021A 3 06/26/2019 CBI (G) Pigment ink alkylene carbonate, alkanediol, isocyanate, compd. with alkylamine (G) Hydroxyalkyl carboxylic acid, polymer with alkylamine, P-19-0022A 3 06/26/2019 CBI (G) Pigment ink alkyl carbonate, alkanediol, isocyanate, compd. with alkylamine (S) Hot Mix Asphalt Application: The PMN compound will be used as asphalt additive for hot mix (HMA) as well as cold mix (CMA) asphalt applications. The PMN substance chemically reacts with the surface of (S) 1-Octadecanaminium, N,N-dimethyl- the aggregate and Sales and N-[3-(trimethoxysilyl)propyl]-, chloride (1:1) , reaction changes surface P-19-0024A 4 06/12/2019 Distribution products with water, Trimethoxy(propyl) silane, characteristics of Services, Inc. Trimethoxy(methyl)silane, Tetraethyl orthosilicate and ethane- aggregate from 1,2-diol hydrophilic to hydrophobic. This change provides stronger bonding between asphalt and aggregates and reduces the potential for stripping away asphalt binder from an aggregate due to water. (S) Waterproofing Application: The PMN substance is expected to be used in waterproofing of building materials, including cementitious material, masonry, concrete, plaster, bricks, etc. It is initially intended to be used at a maximum (S) 1-Octadecanaminium, N,N-dimethyl- Sales and of 5 sites by trained N-[3-(trimethoxysilyl)propyl]-, chloride (1:1) , reaction P-19-0024A 4 06/12/2019 Distribution commercial applicators. products with water, Trimethoxy(propyl) silane, Services, Inc. The PMN substance is Trimethoxy(methyl)silane, Tetraethyl orthosilicate and ethane- modification of a 1,2-diol quaternary silane compound by a hydrolysis reaction with other silanes to make it an oligomeric compound. These quaternary silane products have been manufactured and marketed for 3 of 66 6/22/2020, 9:04 AM TSCA New Chemicals Notices Received file:///W:/OneEPA/Newchems/pubs/5d2-IMD/PMN-SNUN-MCAN-T... Received Case No. Version Manufacturer Use Chemical Substance Date waterproofing uses for over 35 years. The solution of PMN substance in water is applied as a waterproofing sealer for building materials by spray application.,(S) Asphalt Emulsion Application: The PMN substance is water soluble and can be used as an asphalt emulsion in road construction.
Recommended publications
  • United States Patent (19) 11) 4,128,586 Ratcliffe 45) Dec
    United States Patent (19) 11) 4,128,586 Ratcliffe 45) Dec. 5, 1978 (54) CATALYTICREDUCTION OF AROMATIC 2,792,422 5/1957 Harris et al...................... 260/609 D SULFONYL HALDES WITH HYDROGEN 2,820,780 1/1958 Gutcho et al. ....................... 260/12 SULFDE TO YELD AROMATIC THOLS 2,986,581 5/1961 Levy et al. ........................... 260/608 3,994,980 1 1/1976 Kubicek .......................... 260/609 D. (75) Inventor: Charles T. Ratcliffe, Morristown, N.J. FOREIGN PATENT DOCUMENTS (73) Assignee: Allied Chemical Corporation, Morris 461101 4/1975 U.S.S.R.............................. 260/609 D Township, Morris County, N.J. Primary Examiner-Lewis Gotts Appl. No.: 881,952 Assistant Examiner-Molly C. Eakin 21 Attorney, Agent, or Firm-Horst M. Kasper 22) Filed: Feb. 27, 1978 (57) ABSTRACT 51 Int. Cl’............................................ CO7C 149/28 52) U.S. C. ................. 260/609 D; 260/302 S; A process for reducing aromatic sulfonyl halides with 260/302 F, 260/308 R; 260/608; 544/315; hydrogen sulfide. Hydrogen sulfide is contacted with 544/408; 548/337; 548/346; 546/290; 546/179; sulfonyl halides preferably in the presence of a solvent 54.6/139 and of a catalyst. The reaction forms thiols and pro 58) Field of Search ............. 260/609 D, 608, 294.8 R ceeds in the range of between about 50' and 300' C. There is little formation of disulfide and no cleavage of 56) References Cited the thiol group. U.S. PATENT DOCUMENTS 2,402,641 6/1946 Lazler et al. ......................... 260/609 20 Claims, No Drawings 4,128,586 1.
    [Show full text]
  • Chip Incompatibility Filters
    ChIP Incompatibility Filters Filter Name Type Description includes carboxylic acid halides and >1 acyl halide and related SMARTS derivatives like chloroformates, carbamoyl- , imidoyl halides, etc. >1 aldehyde SMARTS R no heteroatom no isocyanate, ketene, etc. >1 alkyl bromide / iodide SMARTS no acyl halide or related or vinyl halide >1 amine aromatic primary SMARTS aromatic carbon bound to N, N not charged >1 amines (aromatic/aliphatic, primary no amide, enamine, etc., no heteroatom SMARTS or secondary) bound to N, N not charged no amide, enamine, etc, no heteroatom >1 amines nucleophilic (aliphatic SMARTS bound to N, no aromatic carbon bound to primary or secondary) N, N not charged >1 aryl bromide / iodide SMARTS any aryl bromide / iodide >1 aryl halide SMARTS any aryl halide any boronic acid derivative, aromatic or >1 boronic acid derivative SMARTS aliphatic >1 carbonyl acid SMARTS any carboxylic or carbamic acid, etc. >1 carboxylic acid anhydrides SMARTS carbon must be bound to carbonyl no heteroatom bound to carbonyl or >1 carboxylic acid ester SMARTS oxygen, no acid, no anydride, etc >1 isocyanate / isothiocyanate SMARTS no restrictions to nitrogen substituents R no heteroatom, no isocyanate, ketene, >1 ketone or aldehyde SMARTS etc. >1 NH any SMARTS R can be anything >1 thioamide and related (any) SMARTS any substitution >1 thiol and related (nucleophic) SMARTS any SH or negative S >2 NH any SMARTS R can be anything acidic compounds I combination sulfonyl acids and carboxylic acids anhydrides, bicarbonates, thio and imino acyl anhydrides and derivatives SMARTS derivatives, etc. includes carboxylic acid halides and acyl halide and related SMARTS derivatives like chloroformates, carbamoyl- , imidoyl halides, etc.
    [Show full text]
  • "Fluorine Compounds, Organic," In: Ullmann's Encyclopedia Of
    Article No : a11_349 Fluorine Compounds, Organic GU¨ NTER SIEGEMUND, Hoechst Aktiengesellschaft, Frankfurt, Federal Republic of Germany WERNER SCHWERTFEGER, Hoechst Aktiengesellschaft, Frankfurt, Federal Republic of Germany ANDREW FEIRING, E. I. DuPont de Nemours & Co., Wilmington, Delaware, United States BRUCE SMART, E. I. DuPont de Nemours & Co., Wilmington, Delaware, United States FRED BEHR, Minnesota Mining and Manufacturing Company, St. Paul, Minnesota, United States HERWARD VOGEL, Minnesota Mining and Manufacturing Company, St. Paul, Minnesota, United States BLAINE MCKUSICK, E. I. DuPont de Nemours & Co., Wilmington, Delaware, United States 1. Introduction....................... 444 8. Fluorinated Carboxylic Acids and 2. Production Processes ................ 445 Fluorinated Alkanesulfonic Acids ...... 470 2.1. Substitution of Hydrogen............. 445 8.1. Fluorinated Carboxylic Acids ......... 470 2.2. Halogen – Fluorine Exchange ......... 446 8.1.1. Fluorinated Acetic Acids .............. 470 2.3. Synthesis from Fluorinated Synthons ... 447 8.1.2. Long-Chain Perfluorocarboxylic Acids .... 470 2.4. Addition of Hydrogen Fluoride to 8.1.3. Fluorinated Dicarboxylic Acids ......... 472 Unsaturated Bonds ................. 447 8.1.4. Tetrafluoroethylene – Perfluorovinyl Ether 2.5. Miscellaneous Methods .............. 447 Copolymers with Carboxylic Acid Groups . 472 2.6. Purification and Analysis ............. 447 8.2. Fluorinated Alkanesulfonic Acids ...... 472 3. Fluorinated Alkanes................. 448 8.2.1. Perfluoroalkanesulfonic Acids
    [Show full text]
  • Process for the Preparation of Substituted N-\Aryl
    Europaisches Patentamt European Patent Office © Publication number: 0 537 611 A1 Office europeen des brevets EUROPEAN PATENT APPLICATION © Application number: 92117123.7 int. Ci.5; C07D 487/04, A01 N 43/90, //(C07D487/04,249:00,239:00) @ Date of filing: 07.10.92 © Priority: 08.10.91 US 772990 © Applicant: DOWELANCO 9002 Purdue Road @ Date of publication of application: Indianapolis, Indiana 46268-1 189(US) 21.04.93 Bulletin 93/16 @ Inventor: Johnson, Timothy C. © Designated Contracting States: 1047 Orange Street AT BE CH DE DK ES FR GB IT LI NL Concord, California 9451 8(US) Inventor: Nasutavicus, Wilmonte A. 1700 Reliez Valley Road Lafayette, California 94549(US) © Representative: Huber, Bernhard, Dipl.-Chem. et al Patentanwalte H. Weickmann, Dr. K. Fincke F.A. Weickmann, B. Huber Dr. H. Liska, Dr. J. Prechtel Kopernikusstrasse 9 Postfach 86 08 20 W-8000 Munchen 86 (DE) © Process for the preparation of substituted N-(aryl)-1,2,4-triazolopyrimidine-2-sulfonamides. © The preparation of N-(aryl)-1 ,2,4-triazolopyrimidine-2-sulfonamides of formula (V) by the coupling of substi- tuted 1 ,2,4-triazolopyrimidine-2-sulfonyl halides of formula (VI) with aryl amines of substantially reduced nucleophilic reactivity is facilitated by conducting the reaction in the presence of a pyridine base and a catalytic amount of dimethyl sulfoxide. CO 00 Rank Xerox (UK) Business Services (3. 10/3.5x/3.0. 1) EP 0 537 61 1 A1 EP 0 537 61 1 A1 The present invention concerns a process for the preparation of N-(aryl)-1 ,2,4-triazolopyrimidine-2- sulfonamides by the coupling of aryl amines with substituted 1 ,2,4-triazolopyrimidine-2-sulfonyl halides.
    [Show full text]
  • Synthesis and Characterization of Functionalized Poly(Arylene Ether Sulfone)S Using Click Chemistry
    Wright State University CORE Scholar Browse all Theses and Dissertations Theses and Dissertations 2016 Synthesis and Characterization of Functionalized Poly(arylene ether sulfone)s using Click Chemistry Kavitha Neithikunta Wright State University Follow this and additional works at: https://corescholar.libraries.wright.edu/etd_all Part of the Chemistry Commons Repository Citation Neithikunta, Kavitha, "Synthesis and Characterization of Functionalized Poly(arylene ether sulfone)s using Click Chemistry" (2016). Browse all Theses and Dissertations. 1650. https://corescholar.libraries.wright.edu/etd_all/1650 This Thesis is brought to you for free and open access by the Theses and Dissertations at CORE Scholar. It has been accepted for inclusion in Browse all Theses and Dissertations by an authorized administrator of CORE Scholar. For more information, please contact [email protected]. SYNTHESIS AND CHARACTERIZATION OF FUNCTIONALIZED POLY (ARYLENE ETHER SULFONE)S USING CLICK CHEMSITRY A thesis submitted in partial fulfilment of the requirements for the degree of Master of Science By Kavitha Neithikunta B.sc Osmania University, 2010 2016 Wright State University WRIGHT STATE UNIVERSITY GRADUATE SCHOOL August 26, 2016 I HEREBY RECOMMEND THAT THE THESIS PREPARED UNDER MYSUPERVISION BY Kavitha Neithikunta ENTITLED Synthesis and Characterization of Functionalized Poly(arylene ether sulfone)s using Click chemistry BE ACCEPTED IN PARTIAL FULFILLMENT OF THE REQUIREMENTS FOR THE DEGREE OF Master of Science __________________________ Eric Fossum, Ph.D. Thesis Advisor ___________________________ David Grossie, Ph.D. Chair, Department of Chemistry Committee on Final Examination ____________________________ Eric Fossum, Ph.D. _____________________________ Daniel M. Ketcha, Ph.D. _____________________________ William A. Feld, Ph.D. _______________________________ Robert E. W. Fyffe, Ph.D Vice President for Research and Dean of the Graduate School ABSTRACT Neithikunta, Kavitha M.S., Department of Chemistry, Wright State University, 2016.
    [Show full text]
  • Development of Nucleophile Assisting Leaving Groups (Nalgs)
    DEVELOPMENT OF NUCLEOPHILE ASSISTING LEAVING GROUPS (NALGS) AND NEW STEREOSELECTIVE REACTIONS USING TITANIUM(IV) REAGENTS by Deboprosad Mondal A Dissertation Submitted to the Faculty of The Charles E. Schmidt College of Science in Partial Fulfillment of the Requirements for the Degree of Doctor of Philosophy Florida Atlantic University Boca Raton, Florida December 2010 ACKNOWLEDGEMENTS I would like to thank my advisor, Dr. Salvatore D. Lepore, for his excellent guidance throughout my PhD. Dr. Lepore has opened for me a door to the art and science of chemical synthesis and methodology development. His talent, passion and motivation in synthesis and his kind personality have always inspired me to improve myself; I am grateful for his encouragement, patience and financial support. I want to thank my committee professors Predrag Cudic, Stanislaw Wnuk and Guodong Sui for their time and insightful advice on my research. I would also like to express my gratitude towards all the past and current members of the Lepore Research Group, especially Change He, Pradip, Ravi and Songye for their help and friendship throughout my PhD. Finally, I thank Drs. Anjan Bhunia and Maximilian Silvestri for their guidance during first year of my PhD. Now I wish to express my thanks to all my friends who have continually inspired me. I am deeply indebted to my parents, especially my father who was my ‘Guru’, my inspiration; my dada for his affection and love; maa-bapi, bhai, kaka for their unconditional love, support and inspiration. Finally, my wife Pinki, I am really proud of her for her love, inspiration and support.
    [Show full text]
  • Process for Polymerizing Acrylonitrile
    HH HI H HH I H HI H HI H HI II HI H HI II HI II HI H HI II HI HI H H HI I HI European Patent Office Office europeen des brevets EP 0 872 493 A2 EUROPEAN PATENT APPLICATION (43) Date of publication: (51) |nt CI.6: C08F 20/44 21.10.1998 Bulletin 1998/43 (21) Application number: 98302755.8 (22) Date of filing: 08.04.1998 (84) Designated Contracting States: (72) Inventor: Percec, Virgil AT BE CH CY DE DK ES Fl FR GB GR IE IT LI LU Chagrin Falls, Ohio 44022 (US) MC NL PT SE Designated Extension States: (74) Representative: Hoey, Shona AL LT LV MK RO SI BP International Limited Patents and Agreements Division (30) Priority: 14.04.1997 US 843259 Chertsey Road Sunbury-on-Thames, Middlesex TW16 7LN (GB) (71) Applicant: Case Western Reserve University Cleveland, Ohio 44106 (US) (54) Process for polymerizing acrylonitrile (57) This invention relates to a process for polymer- substituted halopropionitriles in the form of monoad- ising acrylonitrile, comprising: (A) forming a polymeris- ducts derived from sulfonyl halides and acrylonitrile, or able mixture comprising acrylonitrile monomer, solvent monoadducts derived from substituted sulfonyl halides and a metal catalyst; (B) contacting said mixture with an and monomers other than acrylonitrile; and (C) polymer- initiator, said initiator being selected from the group con- ising said acrylonitrile monomer to form a polymer com- sisting of sulfonyl halides, halopropionitriles, substituted prised of acrylonitrile. In one embodiment, the polymer- halopropionitriles in the form of monoadducts derived isable mixture in step (A) further comprises at least one from sulfonyl halides and acrylonitrile, monoadducts de- polymerisable comonomer other than acrylonitrile, and rived from substituted sulfonyl halides and monomers the polymer formed during step (C) is a copolymer or a other than acrylonitrile; or polymers containing end multicomponent copolymer comprised of acrylonitrile groups derived from sulfonyl halides, halopropionitriles, and said at least one other polymerisable comonomer.
    [Show full text]
  • Polyfluoroarenesulfonyl Chlorides Are Usually Obtained by Reactions Of
    1 TRANSFORMATIONS OF POLYFLUOROARENESULFONYL HALIDES WITH ALKENES, POLYFLUOROARENETHIOLS AND ALKALI METAL HALIDES * Roman A. Bredikhin , Alexander M. Maksimov and Vyacheslav E. Platonov N.N. Vorozhtsov Novosibirsk Institute of Organic Chemistry of the Siberian Branch of Russian Academy of Sciences 630090, Academician Lavrentev Ave., 9, Novosibirsk, Russian Federation E-mail: [email protected] Abstract: The reactions of polyfluoroarenesulfonyl chlorides or bromides with polyfluoroarenethiols gave mixtures of polyfluorinated diaryl disulfides, whereas replacement of fluorine atom at the 4-position of aromatic ring of C6F5SO2F occured. The reactions of polyfluoroarenesulfonyl chlorides or bromides with some n-nucleophiles such as alkali metal halides probably proceed with electron transfer. The reactions of polyfluoroarenesulfonyl bromides with alkenes such as hexene-1 or allyl chloride provided the corresponding adducts in high yields, while the conversion of polyfluoroarenesulfonyl chlorides at the same conditions was poor and C6F5SO2F was unreactive. The reaction of polyfluoroarenesulfonyl bromides with allyl bromide resulted in allyl polyfluoroaryl sulfones. The formation of the products in reactions of polyfluoroareneslfonyl bromdes with alkenes apparently occurs with participation of polyfluoroarenesulfonyl radicals. Keywords: polyfluoroaromatic compounds, sulfonyl bromide, sulfonyl chloride, alkenes, radical addition, allyl polyfluoroaryl sulfone, thiols, metal halides, electron transfer, diaryl disulfide INTRODUCTION Non-fluorinated
    [Show full text]
  • A Process for Preparing an Acyl Halide Or Sulfonyl Halide
    ~™ llll III II II III II III I II II III (19) J European Patent Office Office europeen des brevets (1 1 ) EP0 751 131 A1 (12) EUROPEAN PATENT APPLICATION (43) Date of publication: (51) Int. CI.6: C07D 233/18, C07C 51/60, 02.01.1997 Bulletin 1997/01 C07C 303/02, C07B 41/1 0 (21) Application number: 96108936.4 (22) Date of filing: 04.06.1996 (84) Designated Contracting States: • Hayashi, Hidetoshi DE FR IT NL Ohmuta-shi, Fukuoka-ken, 836 (JP) • Mizuta, Hideki (30) Priority: 20.06.1995 JP 152826/95 Ohmuta-shi, Fukuoka-ken, 837 (JP) (71) Applicant: MITSUI TOATSU CHEMICALS, Inc. (74) Representative: Strehl Schubel-Hopf Groening & Chiyoda-Ku Tokyo 1 00 (JP) Partner Maximilianstrasse 54 (72) Inventors: 80538 Munchen (DE) • Nagata, Teruyuki Ohmuta-shi, Fukuoka-ken, 836 (JP) (54) A process for preparing an acyl halide or sulfonyl halide (57) A preparation process of acyl halide or sulfonyl halide which comprises reacting corresponding carboxylic acid or sulfonic acid with a haloiminium salt represented by the general formula (1): R'-N -R2 X ( 1 ) XCrU/n wherein R1 and R2 are same or different lower alkyl groups, X is a halogen atom, and n is an integer of 2 or 3. CO LO o Q_ LU Printed by Rank Xerox (UK) Business Services 2.13.10/3.4 EP0 751 131 A1 Description 1 . Field of the Invention 5 The present invention relates to a preparation process of acyl halide or sulfonyl halide. 2. Description of the Related Art In recent years, acyl halide has become important in industry as an intermediate for preparing heat resistant resin, 10 medicines and agricultural chemicals.
    [Show full text]
  • Patent Document US 08058429
    I 1111111111111111 11111 1111111111 111111111111111 1111111111111111 IIII IIII IIII US008058429B2 c12) United States Patent (IO) Patent No.: US 8,058,429 B2 Landis et al. (45) Date of Patent: Nov. 15, 2011 (54) DIAZAPHOSPHACYCLE TRANSITION Ben-Arroya, B., et al., "Addition of borane-protected secondary METAL COMPLEXES phosphines to imines. A route to protected mono-N-substituted-a­ arninophosphines," Tetrahedron Letters, vol. 41, pp. 6143-6147 (2000), published by Pergamon Press Ltd., Oxford, Great Britain. (75) Inventors: Clark R. Landis, Madison, WI (US); Burk, M. J., et al., "Ci-Symmetric Bis(phospholanes) and Their use Wiechang Jin, Madison, WI (US); in Highly Enantioselective Hydrogenation Reactions," J Am. Chem. Jonathan S. Owen, Pasadena, CA (US); Soc., vol. 113, pp. 8518-8519 (1991), published by American Chemi­ Thomas P. Clark, Madison, WI (US) cal Society, Washington, D.C. Burk, M. J., et al., "New Electron-Rich Chiral Phosphines for Asym­ metric Catalysis," Organometallics, vol. 9, pp. 2653-2655 (1990), (73) Assignee: Wisconsin Alumni Research published by the American Chemical Society, Washington, D.C. Foundation, Madison, WI (US) Clark et al, "Highly Active, Regioselective, and Enantioselective Hydroformylation with Rh Catalysts Ligated by Bis-3,4- ( *) Notice: Subject to any disclaimer, the term ofthis diazaphospholanes," J Am. Chem. Soc., 2005, 127, pp. 5040-5042; patent is extended or adjusted under 35 published by American Chemical Society. Clark, T. P. et al., "Resolved Chiral 3,4-Diazaphospholanes and Their U.S.C. 154(b) by O days. Application to Catalytic Asymmetric Allylic Alkylation," J Am. Chem. Soc., vol. 125, pp. 11792-11793 (2003); published by Ameri­ (21) Appl.
    [Show full text]
  • Class 562 Organic Compounds -- Part of the Class 532-570 Series 562 - 1
    CLASS 562 ORGANIC COMPOUNDS -- PART OF THE CLASS 532-570 SERIES 562 - 1 562 ORGANIC COMPOUNDS -- PART OF THE CLASS 532-570 SERIES MOC NOTES 8 .Phosphorus acids or salts This Class 562 is... This Class 562 is considered to be an thereof (i.e., compounds integral part of Class 260 (see the Class having -XH, wherein X is 260 schedule for the position of this chalcogen, attached directly Class in schedule hierarchy). This Class to phosphorus by nonionic retains all pertinent definitions and bonding and wherein the class lines of Class 260. hydrogen may be replaced by a This Class 562 is... substituted or unsubstituted ammonium or by a group IA or IIA light metal) 9 ..Sulfur attached directly to the ORGANIC COMPOUNDS (CLASS 532, phosphorus by nonionic bonding SUBCLASS 1) 10 ..Nitrogen attached directly to 1 .Persulphonic acids or salts the phosphorus by nonionic thereof (i.e., compounds bonding having the -S(=O)(=O) O-OH group, wherein the hydrogen 11 ..Nitrogen attached indirectly to may be replaced by a group IA the phosphorus by nonionic or IIA light metal, or by bonding substituted or unsubstituted 12 ...Plural phosphori attached ammonium) indirectly to each other by 2 .Percarboxylic acids or salts nonionic bonding thereof (i.e., compounds 13 ....Plural phosphori bonded having the -C(=O)-O OH group, directly to the same carbon wherein the hydrogen may be 14 ....Additional nitrogen attached replaced by a group IA or IIA indirectly to the phosphorus light metal, or by substituted by nonionic bonding or unsubstituted ammonium) 15 ...The nitrogen
    [Show full text]
  • CASREACT User Guide
    CASREACT® User Guide September 2016 Copyright © 2016 American Chemical Society All rights reserved Table of Contents Chapter 1: Overview of CASREACT ........................................................................................ 4 Content ............................................................................................................................ 4 Sources ............................................................................................................................ 4 Reaction Information ...................................................................................................... 4 Document Information .................................................................................................... 5 LCASREACT ................................................................................................................. 5 Getting Started in CASREACT ....................................................................................... 5 Database Summary Sheet ............................................................................................... 5 Search and Display Fields ............................................................................................... 5 Reaction Information ...................................................................................................... 6 Reaction Map .................................................................................................................. 7 Multistep Reaction Map .................................................................................................
    [Show full text]