Time Resolved Diffuse X Ray Scattering
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SwissFEL X-ray Free Electron Laser 21 Poster # 18 ! # ! " # " # $ $ %# !" ! @ # )# * ' +! ( # &"' ( , * * )# &"' ' +!- ( . )# / )# , !( ,+!-#/ ,+ ( &'( ) ) * % +%, " +9 52 (# (# )# ' A 56 % , A B5 A B5 " )# , C B5 + 4 * $ 4$ 153 ! 555 ,* C B56 @*( * 0!0 !566C $ 4 0 5652 # # $ 26 - &/; # . ! " A 56 $ B26 / - " " 9 # D 9 # D 97 # D ,* # D $ # D - , C =66 / + 866 0$-+ 1234$ 5 E 5656 758+9 ! 5666 # &";% !# : , # $ #0 ( )# ( % & # , 153 ; $ '<= ==5>5??? ! 123 ; $ ,<2 2=82682656 22 Hard X-ray Instrumentation Workshops 2011 Poster # 19 ^ĞƌŝĂů&ĞŵƚŽƐĞĐŽŶĚƌLJƐƚĂůůŽŐƌĂƉŚLJ Ăƚ^ǁŝƐƐ&>yͲZĂLJ&ƌĞĞůĞĐƚƌŽŶ>ĂƐĞƌ &ƌĂŶĐĞƐĐŽ^ƚĞůůĂƚŽϭ͕<ĂƌŽůEĂƐƐϮ͕^ĂƓĂĂũƚϯ͕ĂƌůĂůĞŵĂŶϭ͕ĂŶŝĞůĞWŽŶƚĞϭ͕ŶĚƌĞǁs͘DĂƌƚŝŶϭ͕dŚŽŵĂƐ͘tŚŝƚĞϭ͕ŶƚŽŶĂƌƚLJϭ͕,ĞŶƌLJE͘ŚĂƉŵĂŶϭ͕Ϯ ϭĞŶƚĞƌĨŽƌ&ƌĞĞͲůĞĐƚƌŽŶ>ĂƐĞƌ^ĐŝĞŶĐĞ͕^z͕EŽƚŬĞƐƚƌĂƐƐĞϴϱ͕ϮϮϲϬϳ,ĂŵďƵƌŐ͕'ĞƌŵĂŶLJ ϮhŶŝǀĞƌƐŝƚLJŽĨ,ĂŵďƵƌŐ͕>ƵƌƵƉĞƌŚĂƵƐƐĞĞϭϰϵ͕ϮϮϳϲϭ,ĂŵďƵƌŐ͕'ĞƌŵĂŶLJ ϯWŚŽƚŽŶ^ĐŝĞŶĐĞ͕^z͕EŽƚŬĞƐƚƌĂƐƐĞϴϱ͕ϮϮϲϬϳ,ĂŵďƵƌŐ͕'ĞƌŵĂŶLJ tŚLJƐĞƌŝĂůĐƌLJƐƚĂůůŽŐƌĂƉŚLJĂƚ^ǁŝƐƐ&>͍ džƉĞƌŝŵĞŶƚĂůůĂLJŽƵƚ ͻ DŝĐƌŽĐƌLJƐƚĂůƐ ĂƌĞŵŽƌĞĞĂƐŝůLJŽďƚĂŝŶĞĚƚŚĂŶŵĂĐƌŽƐĐŽƉŝĐ ^ŝŶŐůĞ ĐƌLJƐƚĂů yͲƌĂLJ ĚŝĨĨƌĂĐƚŝŽŶ ƐŶĂƉƐŚŽƚƐ ŽŶĞƐ͘ ĐĂŶďĞĐŽůůĞĐƚĞĚĨƌŽŵĂƐƚƌĞĂŵŽĨĐƌLJƐƚĂůƐ ͻ /Ŷ ǀŝǀŽ ĐƌLJƐƚĂůƐ ĂůůŽǁ ƚŽ ŚĂǀĞ ƉƌŽƚĞŝŶƐ ŝŶ ƉŚLJƐŝŽůŽŐŝĐĂů ƵƐŝŶŐ ĨĞŵƚŽƐĞĐŽŶĚ ƉƵůƐĞƐ ĨƌŽŵ Ă ŚĂƌĚ yͲ ĐŽŶĚŝƚŝŽŶƐ;ŝŶĐůƵĚŝŶŐƉŽƐƚͲƚƌĂŶƐůĂƚŝŽŶĂůŵŽĚŝĨŝĐĂƚŝŽŶƐͿϭ͘ ƌĂLJ&ƌĞĞůĞĐƚƌŽŶ>ĂƐĞƌ;&>Ϳϯ dŚĞƐĞ ĐƌLJƐƚĂůƐ ĂƌĞ ƚŽŽ ƐŵĂůů ĨŽƌ ĐŽŶǀĞŶƚŝŽŶĂů ĂŶĂůLJƐĞƐ͘ ͻ dŝŵĞͲƌĞƐŽůǀĞĚƐƚƵĚŝĞƐŽĨ ŝƌƌĞǀĞƌƐŝďůĞ ƉƌŽĐĞƐƐĞƐ ƉŽƐƐŝďůĞ͕ ŝĨĨƌĂĐƚŝŽŶ ĨƌŽŵ ƵůƚƌĂͲƐŚŽƌƚ ƉƵůƐĞƐ ĐĂŶ ďĞ ďLJƐƚŽƉͲĨůŽǁŵŝdžŝŶŐŽƌƉŚŽƚŽŝŶŝƚŝĂƚŝŽŶ͘ ĐŽůůĞĐƚĞĚďĞĨŽƌĞƐŝŐŶŝĨŝĐĂŶƚĐŚĂŶŐĞƐŽĐĐƵƌ ͻ DĞĂƐƵƌĞŵĞŶƚƐ ĂƌĞ ĐĂƌƌŝĞĚ ŽƵƚ Ăƚ ƌŽŽŵ ƚĞŵƉĞƌĂƚƵƌĞ͕ ƚŽƚŚĞƐĂŵƉůĞϰ ĂǀŽŝĚŝŶŐƚŚĞŶĞĞĚĨŽƌĐƌLJŽŐĞŶŝĐƚĞŵƉĞƌĂƚƵƌĞƐǁŚŝĐŚĚŝƐƚŽƌƚ ƐƚƌƵĐƚƵƌĞƐϮ͘ dŝŵĞͲƌĞƐŽůǀĞĚ ƐƚƌƵĐƚƵƌĂů ƐƚƵĚŝĞƐ ŽĨ ͻ ^ĞƌŝĂů ĐƌLJƐƚĂůůŽŐƌĂƉŚLJ ĂůůŽǁƐ ŚŝŐŚĞƌ ƚŚƌŽƵŐŚƉƵƚ ŽĨ ŝƌƌĞǀĞƌƐŝďůĞƌĞĂĐƚŝŽŶĚLJŶĂŵŝĐƐŝŶďŝŽůŽŐŝĐĂů ƐƚƌƵĐƚƵƌĞƐĂŶĚƉŽƚĞŶƚŝĂůůLJĂůŽǁĞƌĐŽŶƐƵŵƉƚŝŽŶ ŽĨŵĂƚĞƌŝĂů ƐLJƐƚĞŵƐ ŝƐ ƉŽƐƐŝďůĞ͗ ŽƉƚŝĐĂů ƉƵŵƉ ůĂƐĞƌƐ ƚŚĂŶĐŽŶǀĞŶƚŝŽŶĂůƚĞĐŚŶŝƋƵĞƐ͘ ƐLJŶĐŚƌŽŶŝnjĞĚƚŽ&>ƉƵůƐĞƐŚĂǀĞďĞĞŶƵƐĞĚ ƚ ϭϬϬ ,nj͕ Ă ĐŽŵƉůĞƚĞ ĚĂƚĂƐĞƚ ĐĂŶ ďĞ ĂĐƋƵŝƌĞĚ ŝŶ Ϯϱ ƚŽŽďƚĂŝŶyͲƌĂLJĚŝĨĨƌĂĐƚŝŽŶ ƐŶĂƉƐŚŽƚƐĨƌŽŵ ŵŝŶƵƚĞƐ;ĂƚϭϬϭϭ ηͬŵůĂŶĚϭϱйŚŝƚƌĂƚĞͿ͕ǁŝƚŚŶŽĚĞĂĚͲƚŝŵĞ ƚŚĞ ĞdžĐŝƚĞĚ ƐƚĂƚĞƐ ŽĨ ƉƌŽƚĞŝŶƐ ŝŶ ϱ ĨŽƌƐĂŵƉůĞĐŚĂŶŐĞ͘ ŵŝĐƌŽĐƌLJƐƚĂůƐ ͘ ϭZ͘<ŽŽƉŵĂŶŶĞƚĂů͘ Ͳ ^ƵďŵŝƚƚĞĚ;ϮϬϭϭͿ͖Ϯ:͘^͘&ƌĂƐĞƌĞƚĂů͘ ʹ WE^ϭϬϴ͕ϯϵ ;ϮϬϭϭͿ͖ϯ,͘E͘ŚĂƉŵĂŶĞƚĂů͘ Ͳ 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ϱϬϬђŵ ƌLJƐƚ&>ʹ ĂƚĂĂŶĂůLJƐŝƐ ƐƵƐƉĞŶƐŝŽŶ &>ĚĞǀĞůŽƉĞĚƐŽĨƚǁĂƌĞƚŚĂƚŝŶĚĞdžĞƐ͕ŝŶƚĞŐƌĂƚĞƐĂŶĚŵĞƌŐĞƐϴ ƐĞƌŝĂů ϯϬŶŵƚŚŝĐŬǁŝŶĚŽǁƐƐĞƉĂƌĂƚĞĚďLJϱϬϬђŵ ĐƌLJƐƚĂůůŽŐƌĂƉŚLJĚĂƚĂ ϭϬϭϬĐŵϮ ĐŚŝƉǁŽƵůĚŐŝǀĞĂďŽƵƚϭϬϰ ƐŝŶŐůĞĐƌLJƐƚĂůŚŝƚƐ ϲ͘ĞWŽŶƚĞĞƚĂů͘ Ͳ :͘WŚLJƐ͘ϰϭ͕ϭϵϱϱϬϱ;ϮϬϬϴͿ ϳd͘͘tŚŝƚĞĞƚĂů͘ʹ ƐƵďŵŝƚƚĞĚ͖ϴZ͘͘<ŝƌŝĂŶĞƚĂů͘ ĐƚĂƌLJƐƚϲϳ͕ϭϯϭ;ϮϬϭϭͿ >>^ZĞƐƵůƚƐ ŽŶǀĞƌŐĞŶƚĞĂŵʹ ,ŝŐŚĂŶĚǁŝĚƚŚ ĂŵĂŐĞ ^ŝŵƵůĂƚŝŽŶƐŽŶW^/ƐŚŽǁƚŚĂƚĨĞǁĞƌƉĂƚƚĞƌŶƐĂƌĞ ƐŝŶŐůĞ ĐƌLJƐƚĂů ƌĞƋƵŝƌĞĚ ǁŚĞŶ ƵƐŝŶŐ Ă ĐŽŶǀĞƌŐĞŶƚ ďĞĂŵ Žƌ ŚŝŐŚĞƌ ƉĂƚƚĞƌŶ ĂĐƋƵŝƌĞĚ ďĂŶĚǁŝĚƚŚ ^ŝŵƵůĂƚĞĚĚĂŵĂŐĞ Ăƚ>>^ϯ ŝŶƚŚĞĐĞŶƚĞƌ ŽĨĂϳϬϬŶŵ W^/ĐƌLJƐƚĂů ^ŝŵƵůĂƚŝŽŶƐĂƌĞĚŽŶĞƵƐŝŶŐĂƉůĂƐŵĂĐŽĚĞϵ ;ĐƌĞƚŝŶͿ͕ ĂŶĚĚŝƐƉůĂĐĞŵĞŶƚƐĂƌĞĐĂůĐƵůĂƚĞĚďĂƐĞĚŽŶĚŝĨĨƵƐŝŽŶŝŶ ŶĂůLJƐŝƐŽĨ>>^ĞdžƉĞƌŝŵĞŶƚĂů ĂǁĞĂŬůLJŝŽŶŝnjĞĚƉůĂƐŵĂϰ ϯ ƌĞƐƵůƚƐ ŽŶWŚŽƚŽƐLJƐƚĞŵ/;W^/Ϳ ZĂĚŝĂƚŝŽŶĚĂŵĂŐĞǁŝůůŶŽƚďĞĂŶŝƐƐƵĞĂƚ^ǁŝƐƐ&> ƐŚŽǁƐƚŚĂƚĂďŽƵƚϭϬϰ ƉĂƚƚĞƌŶƐĂƌĞƌĞƋƵŝƌĞĚ ϵ͘ĂůĞŵĂŶĞƚĂů͘:͘DŽĚ͘KƉƚ͘ϱϴ;ϮϬϭϭͿ ĞƚĞĐƚŽƌZĞƋƵŝƌĞŵĞŶƚƐ ,ŝŐŚƌĞƐŽůƵƚŝŽŶ͗ϮϬϰϴdžϮϬϰϴƉŝdžĞůƐŽƌŵŽƌĞ͘tŽƌŬŝŶŐĚŝƐƚĂŶĐĞŽĨĂďŽƵƚϳ ĐŵĨŽƌĂ WĂƌĂŵĞƚĞƌ ZĞƋƵŝƌĞŵĞŶƚ DŽƚŝǀĂƚŝŽŶ ϭϬĐŵǁŝĚĞĚĞƚĞĐƚŽƌ;ϱϬђŵƉŝdžĞůƐͿǁŽƌŬƐǁĞůů;Ϯ 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;dƵŶĞĂďůĞŽǀĞƌϯϬϬŶŵфʄфϳϬϬŶŵ͕ƉƵůƐĞĞŶĞƌŐLJϱͲϭϬђ:͕ƉƵůƐĞůĞŶŐƚŚϭͲϭϬϬŶƐͿ WƵůƐĞůĞŶŐƚŚ ŝĂŐŶŽƐƚŝĐZĞƋƵŝƌĞŵĞŶƚƐ ^ƚĂďŝůŝƚLJ ϭй ĚĞƐƚƌƵĐƚŝŽŶ͛ yͲƌĂLJ/ŶƚĞŶƐŝƚLJ ;WƵůƐĞĞŶĞƌŐLJŝŶŵ:͕ƉĞƌƐŝŶŐůĞƐŚŽƚͿ WƵůƐĞĂƌƌŝǀĂůƚŝŵĞ ĨƐ Ͳ Ͳ yͲƌĂLJŶĞƌŐLJͬ^ƉĞĐƚƌƵŵ ;yͲƌĂLJĞŶĞƌŐLJĂŶĚďĂŶĚǁŝĚƚŚƐƉƌĞĂĚ͕ŝŶĞs͕ƉĞƌƐŝŶŐůĞƐŚŽƚͿ WƵůƐĞĚƵƌĂƚŝŽŶ;yͲƌĂLJƉƵůƐĞĚƵƌĂƚŝŽŶŝŶĨƐ͕ƉĞƌƐŚŽƚͿ SwissFEL X-ray Free Electron Laser 23 Poster # 20 Probing magnetic phase transitions S.O.Mariager, P.Beaud, A.Caviezel, S.Grübel, J.Johnson, G.Ingold FEMTO group, SLS, Paul Scherrer Institut, 5232 Villigen, Switzerland. U.Staub, V.Scagnoli RESOXS team, SLS, Paul Scherrer Institut, 5232 Villigen, Switzerland. S.L.Johnson Institute for Quantum Electronics , Swiss Federal Institute of Technology (ETH), Zürich, Switzerland. L. Le Guyader, F. Nolting, C. Quitmann SLS, Paul Scherrer Institut, 5232 Villigen, Switzerland. Motivation Exploiting the coherence $SRVVLEOHPHWKRGIRUVWXG\LQJGRPDLQG\QDPLFV Structural and magnetic dynamics &RKHUHQWVFDWWHULQJ ;UD\SKRWRQFRUUHODWLRQVSHFWURVFRS\ ⋅ :HKDYHVWXGLHGWKHDOOR\)H5KDWWKH)(072VOLFLQJVRXUFH$W7a 'RQHZLWK SKVQRZ±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esonant magnetic x-ray diffraction Non-resonant magnetic x-ray diffraction 7KHZHDNPDJQHWLFVFDWWHULQJFDQEHVLJQLILFDQWO\HQKDQFHG a DWDEVRUSWLRQHGJHV )RUVWXG\LQJPDJQHWLFRUGHUFRPELQHGZLWKVWUXFWXUDOPRGXODWLRQV6SLQDQG +DUG[UD\VXLWDEOHIRU.HGJHVRIWUDQVLWLRQPHWDOVDQG/HGJHVRIIDQGGUDUHHDUWKHOHPHQWV RUELWDORUGHUFDQEHGHFRXSOHG 5HTXLUHVWXQDEOHHQHUJ\ORZEDQGZLGWKDQGTXLFNHQHUJ\VFDQV )DUIURPDEVRUSWLRQHGJHV,≈ _) 4δU ± L (PF ) _ 2QHDGYDQWDJHFRPSDUHGWRVRIW[UD\VLVDFFHVVWRDODUJHYROXPHLQUHFLSURFDOVSDFH δ 0 +HUH) 4δU IRU4 + DQGδU .HGJHPDJQHWLFFLUFXODUGLFKURLVP KDVEHHQUHSRUWHG δ ,QWKHFODVVLFDOH[DPSOH1L2 ) ) a⋅GRDEOHDW6ZLVV)(/ &LUFXODUSRODUL]DWLRQSRVVLEOHZLWKSKDVHUHWDUGHUV7UDQVPLVVLRQa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uture end station Parameter Unit Requirement Motivation/remarks 6DPSOHPDQLSXODWRU IRUJUDFLQJLQFLGHQFHGLIIUDFWLRQ keV 2-12 Select edges for resonant diffraction Energy &RPSOHWHJRQLRPHWHU KH[DSRGRUHTXLYDOHQWVWDJH Stability eV <1 Monochromator needed. 6DPSOHURWDWLRQDURXQGVXUIDFHQRUPDODQGIRULQFLGHQFHDQJOH <1 Monochormator needed 6XIILFLHQWWUDQVODWLRQVWRSRVLWLRQVDPSOH Bandwidth Stability % bw <10 6DPSOHHQYLURQPHQW 7HPSHUDWXUHFRQWURO± . Beam position Stability μm <1 For laser overlap and gracing incidence. 0DJQHWLFILHOG3HUPDQHQWPDJQHWV7LQIOH[LEOH6&PDJQHWV!7ELJVHWXS μm <5 Gracing incidence diffraction requires horizontal Beam size &KDOOHQJH6HFXUHDFFHVVIRUSXPSODVHU focus. &KDOOHQJH6HFXUHFRKHUHQFHRI[UD\EHDP 108-1012