IAC Research Report 2020 Final ALL
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A MESSAGE FROM THE DIRECTORS Dear Friends of the PRISM Imaging and Analysis Center, The PRISM Imaging and Analysis Center (IAC) offers high-end, state-of-the-art instrumentation and expertise for characterization of hard, soft, and biological materials to stimulate research and education at Princeton University and beyond. The IAC houses and operates a full range of instruments employing visible photons, electrons, ions, X-rays, and scanning probe microscopy for the physical examination and analysis of complex materials. With 25 years of continuous support from Princeton University, as well as the National Science Foundation, the Air Force Office of Scientific Research, the Office of Naval Research, the State of New Jersey, Industrial Companies, etc., the IAC has become the largest central facility at Princeton and a world-leader in advanced materials characterization. A central mission of the IAC is the education, research, and training of students at Princeton University. The IAC supports more than ten regular courses annually. The award-winning course, MSE505-Characterization of Materials is conducted at the IAC for both graduate and undergraduate students. The IAC also offers a full range of training courses, which involve direct experimental demonstrations and hands-on instruction ranging from basic sample preparation, to the operation of high-end electron microscopes. The IAC's short courses have drawn over 3,500 student enrollments. Additionally, over 700 industrial scientists from more than 120 companies and 40 institutions have utilized instruments in the IAC. Our efforts have helped build bridges between Princeton and Industry that have fostered many innovations and new product developments. Recent IAC internal users include over 300 students and researchers from more than 90 research groups. The IAC supports ~230 current research contracts worth a total of ~$440M. In the IAC, undergraduate students are provided with the opportunity to operate various electron microscopes during class and later utilize these instruments in research for their senior thesis. The research experience provided by the IAC has helped students win many national awards including the Fannie and John Hertz Foundation Fellowship, Rhode Scholarship, the Barry M. Goldwater National Scholarship, Fulbright Scholarship, National Science Foundation Fellowship, etc. In this report, we highlight many recent research projects conducted by our internal users, which were enabled by the IAC’s facilities and expertise. These topics cover a wide range of scientific disciplines, reflecting the great diversity in research conducted at Princeton. We hope this report will encourage learning from our students and stimulate research and education in the years to come. Thank you for your continued support and please enjoy learning about the IAC and the exciting research being carried out here at Princeton University. Nan Yao, Director of the Imaging and Analysis Center Craig B. Arnold, Director of PRISM 1 2 PRISM Imaging and Analysis Center (IAC) IAC Background: Started in 1993 with one person, one microscope, and today it has grown to have seven staff and become a world-leading microscopy facility for the physical and life sciences. 3 IAC team members: IAC faculty users from Princeton: Architecture Chemical & Biological Eng. Chemistry Forrest Meggers Bruce E. Koel Andrew Bocarsly Celeste Nelson Bob Cava Civil & Environmental Eng. Lynn Loo Erik Sorensen Catherine Peters Michele Sarazen Greg Scholes Claire White Pierre-Thomas Brun Haw Yang Ian Bourg Rick Register Jeff Schwartz Zhiyong (Jason) Ren Robert Prud'homme Leslie M. Schoop Rodney Priestley Mohammad Seyedsayamdost Computer Science Paul Chirik Sebastian Seung Ecology and Evolutionary Biology Tom Muir Sarah Kocher Library-Rare Books & Special Electrical Engineering Collections Andrew Houck Geosciences Alan Stahl Antoine Kahn Adam Maloof Barry Rand Bess Ward Mechanical and Aerospace Eng. Claire Gmachl Blair Schoene Craig Arnold James Sturm Tullis Onstott Daniel Steingart Jeff Thompson Satish Myneni Edgar Choueiri Nathalie De Leon Thomas Duffy Howard Stone Paul Prucnal Jeremy Kasdin Steve Chou Physics Yiguang Ju Steve Lyon Ali Yazdani Chris Tully Plasma Physics Molecular Biology Frank Calaprice Mojtaba Safabakhsh Alexei Korennykh Jason Petta Yevgeny Raitses Bonnie Bassler Joshua Shaevitz Fred Hughson Phuan Ong PRISM Martin Jonikas Sanfeng Wu Nan Yao Nieng Yan Zahid Hasan Sabine Petry Zemer Gitai 4 IAC outside users from industry and other universities: Secondary electron image showing surface morphology of SmCoS2 material collected using a field-emission environmental scanning electron microscope operated at 20 keV. Field of view: 80 μm. (Image courtesy of Gerald Poirier and Nan Yao) Acknowledgement: The Imaging and Analysis Center acknowledges partial support from the National Science Foundation through the Princeton University Materials Research Science and Engineering Center (PCCM), DMR-2011750. 5 IAC new instrumentation highlights: (1) Titan Themis Double Cs-corrected Scanning/Transmission Electron Microscope (2) Titan Krios G3 Cryo-Transmission Electron Microscope 6 Table of Contents School of Architecture .............................................................................................................................. 14 Teitelbaum, et al. Membrane-assisted radiant cooling for expanding thermal comfort zones globally without air conditioning ............................................................................................................................................ 15 Department of Chemical and Biological Engineering ........................................................................... 16 Markwalter, et al. Polymeric Nanocarrier Formulations of Biologics Using Inverse Flash NanoPrecipitation .................. 17 Nerger, et al. Microextrusion Printing Cell-Laden Networks of Type I Collagen with Patterned Fiber Alignment and Geometry ................................................................................................................................................ 18 Sezen-Edmonds, et al. Humidity and Strain Rate Determine the Extent of Phase Shift in the Piezoresistive Response of PEDOT:PSS ............................................................................................................................................ 19 Yang, et al. Nitrogen-plasma treated hafnium oxyhydroxide as an efficient acid-stable electrocatalyst for hydrogen evolution and oxidation reactions ........................................................................................................... 20 Buzi, et al. Deuterium and helium ion irradiation of nanograined tungsten and tungsten–titanium alloys .............. 21 Zhao, et al. Extending the Photovoltaic Response of Perovskite Solar Cells into the Near-Infrared with a Narrow- Bandgap Organic Semiconductor ........................................................................................................... 22 Hamill, et al. Influence of Solvent Coordination on Hybrid Organic−Inorganic Perovskite Formation ...................... 23 Hamill, et al. Acid-Catalyzed Reactions Activate DMSO as a Reagent in Perovskite Precursor Inks......................... 24 Hamill, et al. Sulfur-Donor Solvents Strongly Coordinate Pb2+ in Hybrid Organic−Inorganic Perovskite Precursor Solutions ................................................................................................................................................. 25 Khlyabich, et al. Precursor Solution Annealing Forms Cubic-Phase Perovskite and Improves Humidity Resistance of Solar Cells ............................................................................................................................................... 26 Khlyabich, et al. Crystalline Intermediates and Their Transformation Kinetics during the Formation of Methylammonium Lead Halide Perovskite Thin Films .......................................................................... 27 Zhao, et al. A hole-transport material that also passivates perovskite surface defects for solar cells with improved efficiency and stability ............................................................................................................................ 28 Zhao, et al. Accessing Highly Oriented Two-Dimensional Perovskite Films via Solvent-Vapor Annealing for Efficient and Stable Solar Cells .............................................................................................................. 29 7 Department of Chemistry ......................................................................................................................... 30 Ferrenti, et al. Change in Magnetic Properties upon Chemical Exfoliation of FeOCl ................................................... 31 Guerra, et al. Single-Particle Dynamic Light Scattering: Shapes of Individual Nanoparticles .................................... 32 Lei, et al. Charge Density Waves and Magnetism in Topological Semimetal Candidates GdSbxTe2−x−δ ............... 33 Lei, et al. High mobility in a van der Waals layered antiferromagnetic metal ....................................................... 34 Song, et al. Soft Chemical Synthesis of HxCrS2: An Antiferromagnetic Material with Alternating Amorphous and Crystalline Layers ................................................................................................................................... 35 DelPo, et al. Polariton Transitions in Femtosecond Transient Absorption Studies