for Plug and Abandonment

© Wild Well Control, Inc. Tyler James . Mechanical Engineer . Cement Specialist

CSI Technologies . Cement Experts . Research Laboratory . Field Scale Testing

ControlSEAL Resin

2 1 1 / 5 / 2 0 1 9 What is Properties & ControlSEAL Advantages

3 1 1 / 5 / 2 0 1 9 Mechanical Properties

Tensile Strength Compressive Strength

4000 9000 3500 8000 3000 7000 6000 2500 5000 2000 PSI PSI 4000 1500 3000 1000 2000 500 1000 0 0 ControlSEAL Cement ControlSEAL Cement

4 1 1 / 5 / 2 0 1 9 5 1 1 / 5 / 2 0 1 9 Solids Free

6 1 1 / 5 / 2 0 1 9 Tensile Strength in Calcium Bromide 4000

3500

3000

2500

2000 PSI

1500

1000

500

0

7 1 1 / 5 / 2 0 1 9 8 1 1 / 5 / 2 0 1 9 Bonding Brittle Immiscible in water

Flexible Solids Free Incompatible with Water Resin

Thermal Degradation Chemical Degradation Chemically Inert

Tg Shrinkage High Compressive Strength What is Resin Synthetic Resin Thermosetting

Some are thermosetting plastics in which the term "resin" is loosely applied to the reactant or product

A plastic that is irreversibly cured from a liquid…. changes the resin into an infusible, insoluble polymer network.

10 1 1 / 5 / 2 0 1 9 Resin “”

. . Furan . Phenolic . Polyester 1. Base polymer 2. Reactive sites 3. Curing agents

11 1 1 / 5 / 2 0 1 9 Resin as a Durable Barrier Fluid Properties Set Mechanical Properties - Contamination - Chemical Stability - Placement Technique - Thermal Stability - Handling Time - Shrinkage - Viscosity - Adhesion - Glass Transition Temperature - Strength (Tensile and Compressive) - Young’s Modulus / Poission’s Ratio - Resilience

12 1 1 / 5 / 2 0 1 9 Durable Barriers

13 1 1 / 5 / 2 0 1 9 BARRIER LIFE TIMELINE nt Temperature Pressure Fatigue Damage l Seal laceme Initia BarrierP ure Test Press

American Oxford Dictionary 14 1 1 / 5 / 2 0 1 9 1. Fatigue - Stress Variation 2. Plug Profile Change - Plastic Deformation - Shrinkage 3. Thermal Degradation 4. Corrosion - Chemical Attack

15 1 1 / 5 / 2 0 1 9 Stress Variation / Fatigue

Cement Yield Point

. Yield Point s . Young’s Modulus Stres

Young’s Modulus

Strain

16 1 1 / 5 / 2 0 1 9 Plug Profile Change Hydrostatic Pressure Plastic Deformation . At stresses below yield point Shrinkage . Post set (after pressure test) Adhesion Friction

Creep Modulus or Relaxation Modulus Stress in plug o Adhesion strength o Shrinkage (during set) o Well parameters Formation Pressure Shrinkage (Post set)

17 1 1 / 5 / 2 0 1 9 Thermal Degradation / Corrosion (Chemical Attack) Baseline Bottom Baseline Middle

. Polymer stiffness Baseline Top - Structure Aromatic Bottom - Bonding Aromatic Middle

Tensile Strength in Aromatic Hydrocarbon Aromatic Top 4000KIPs Non-Aromatic Bottom 3500 3000 Non-Aromatic Middle 2500 Non-Aromatic Top 2000 PSI Cement 1500 Brine Bottom ControlSEAL 1000 Brine Middle 500 0 Brine Top Inch

18 1 1 / 5 / 2 0 1 9 Critical Properties for Durable Barriers

How To Measure? . Young’s Modulus . Yield Point . Adhesion Strength . Shrinkage (during set) . Well Parameters . Creep Modulus or Relaxation Modulus . Shrinkage (after set)

19 1 1 / 5 / 2 0 1 9 Thank you

Decomworld: Resin Makes Debut

Decomworld: JIP Resin Delivers Knockout Blow Over Cement

Please contact us at: [email protected]

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