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WO 2014/153570 A9 25 September 2014 (25.09.2014) P O P C T (12) INTERNATIONAL APPLICATION PUBLISHED UNDER THE PATENT COOPERATION TREATY (PCT) CORRECTED VERSION (19) World Intellectual Property Organization I International Bureau (10) International Publication Number (43) International Publication Date WO 2014/153570 A9 25 September 2014 (25.09.2014) P O P C T (51) International Patent Classification: (74) Agents: HERSHKOVITZ, Abraham et al; Hershkovitz CIOB 49/12 (2006.01) & Associates PLLC, 2845 Duke Street, Alexandria, VA 223 14 (US). (21) International Application Number: PCT/US20 14/038290 (81) Designated States (unless otherwise indicated, for every kind of national protection available): AE, AG, AL, AM, (22) Date: International Filing AO, AT, AU, AZ, BA, BB, BG, BH, BN, BR, BW, BY, 15 May 2014 (15.05.2014) BZ, CA, CH, CL, CN, CO, CR, CU, CZ, DE, DK, DM, (25) Filing Language: English DO, DZ, EC, EE, EG, ES, FI, GB, GD, GE, GH, GM, GT, HN, HR, HU, ID, IL, IN, IR, IS, JP, KE, KG, KN, KP, KR, (26) Publication Language: English KZ, LA, LC, LK, LR, LS, LT, LU, LY, MA, MD, ME, (30) Priority Data: MG, MK, MN, MW, MX, MY, MZ, NA, NG, NI, NO, NZ, 61/801,491 15 March 2013 (15.03.2013) US OM, PA, PE, PG, PH, PL, PT, QA, RO, RS, RU, RW, SA, SC, SD, SE, SG, SK, SL, SM, ST, SV, SY, TH, TJ, TM, (71) Applicant: TRANSTAR GROUP, LTD [— /CN]; China TN, TR, TT, TZ, UA, UG, US, UZ, VC, VN, ZA, ZM, Overseas Building, Room A, 7F, 139 Hennessy Road, ZW. Wanchai, Hong Kong (CN). (84) Designated States (unless otherwise indicated, for every (72) Inventors; and kind of regional protection available): ARIPO (BW, GH, (71) Applicants : KALPAN, Allen [US/US]; Post Office Box GM, KE, LR, LS, MW, MZ, NA, RW, SD, SL, SZ, TZ, 191344, Miami Beach, FL 33 119-1344 (US). BRADLEY, UG, ZM, ZW), Eurasian (AM, AZ, BY, KG, KZ, RU, TJ, Randall [US/US]; Post Office Box 22903, Ft. Lauderdale, TM), European (AL, AT, BE, BG, CH, CY, CZ, DE, DK, FL 33335 (US). EE, ES, FI, FR, GB, GR, HR, HU, IE, IS, IT, LT, LU, LV, MC, MK, MT, NL, NO, PL, PT, RO, RS, SE, SI, SK, SM, [Continued on nextpage] (54) Title: NEW AND IMPROVED SYSTEM FOR PROCESSING VARIOUS CHEMICALS AND MATERIALS (57) Abstract: Eco-friendly systems, methods and processes/processing (EF- SMP) or an integrated Matrix encompasses stand-alone and/or interconnec ted modules for completely self-sustained, closed-loop, emission- free pro cessing of mutiple source feedstock that can include pretreatment, with pois - oning materials isolated during pretreatment being further recycled to provide useful materials such as, for example, separated metals, carbon and fullerenes for production of nano materials, sulfur, water, sulfuric acid, gas, heat and carbon dioxide for energy production, and production of refined petroleum, at a highly-reduced cost over the best state-of-the-art refining methods/systems that meets new emissions standards as well as optimizes production output with new ultra-speed cycle times. By-products from the petroleum refining process which were previously discarded also now are re cycled as renewable sources of energy (water, waste oil and rubber/coal de rived pyrolyic (pyro lysis) oil, carbon gases and process gases), or recyclable resources, such as metals and precious metals, oxides, minerals, etc., can be obtained. < © 5 w o 2014/153570 A 9 1I II II I III IIII II I ll l ll II II II III III II TR), OAPI (BF, BJ, CF, CG, CI, CM, GA, GN, GQ, GW, (88) Date of publication of the international search report: KM, ML, MR, NE, SN, TD, TG). 1 February 2015 Published: (48) Date of publication of this corrected version: 6 August 2015 — with international search report (Art. 21(3)) — with information concerning request for restoration of (15) Information about Correction: the right of priority in respect of one or more priority see Notice of 6 August 20 15 claims (Rules 26bis.3 and 48.2(b)(vii)) NEW AND IMPROVED SYSTEM FOR PROCESSING VARIOUS CHEMICALS AND MATERIALS Field of the Invention The present invention relates to a matrix strategy of an all-encompassing or selective integrating of the petrochemical, metals, pharmaceutical, energy and power industry's processes and technologies for optimum energy and operational efficiency, new profitable product diversification and compliant cycled closed looped emissions free processing. The novel matrix strategy comprises the integration of cost effective, renewable hydrocarbon feedstocks such as coal, spent oil, terminated/expired/spent tires and batteries, heavy and/or light varieties of crude oil, spent and secondary metals refining, and internally generated liquid, supercritical phase fluids and drying process, solid and gaseous wastes streams. The novel matrix strategy can be located at major consuming market locations being typically interconnected through a direct system of land, sea and air access media both nationally and internationally. Direct transcontinental pipeline access is an added advantage. The matrix strategy is capable of being adapted for operation at remote subterranean, oceanic and terrestrial locations. The invention strategy can utilize domestic and foreign sourcing of feedstock and can provide a broad spectrum of production diversification. As a bonus, present government funding, land provisions, tax and other incentives can reduce startup costs, for such operations have been deemed independently or matrix collectively clean energy, renewable energy, green energy classified and carbon trading credit and carbon transfer worthy. Cutting edge technology including, inter alia: 1) rapid cycle time, 2) no fugitive emissions; 3) a closed loop system; 4) water manufacture self-sufficiency; 5) utilization of novel super reactor technology; 6) cross industry technology applications; and 7) a safer technology; 8) negative carbon emission footprint; and 9) carbon credit exchange and trading; 10) a vertically integrated feedstock; 11) power self-sufficiency; and 12) coal material extraction including coal fines, charcoal, coal ash, actinides and coal combustion gases/fumes. Summary of the Invention The present integrated matrix encompasses interconnected modules including a starting feedstock module where feedstock from various sources is received and stored and/or directly routed to modules of the matrix system for processing. The matrix system can be comprised of pretreatment process modules from which an upstream feed can be pre-purified and then sent to the petroleum refining module with poisoning materials separated from the feedstock during pretreatment then being further recycled to provide useful materials such as, for example, separated metals, carbon and fullerenes for production of nano materials, sulfur, water, sulfuric acid, gas, heat and carbon dioxide for energy production. As a consequence of the matrix system, method and apparatus, by-products from the petroleum refining process which were previously discarded now can be recycled as a renewable source of energy (water, waste oil and rubber/coal derived pyrolyic (pyrolysis) oil, carbon gases and process gases) or recyclable resources such as metals and precious metals, oxides, minerals and others to the various modules of the present integrated matrix to provide useful end products. The matrix allows for the production of refined petroleum at a cost considerably below that of even the best current state- of-the-art presently used in petroleum refineries. The matrix system and method can minimize capital outlay in either retrofit or new build expenditures and can meet the new eminent emissions standards, optimize production output with new ultra-speed cycle times, and effectively vertically integrate feedstocks, expand on and or add profitable new product lines as well as significantly reduce existing technology upgrading and retrofit expenditures, operating costs, maintenance and repair downtime and process cycle time. The general concept of the present system, method and apparatus is shown in block diagram form in Figure 1. A feed matrix module is the module in which feed is received, stored and introduced into the processing matrix modules and the refinery matrix module. The feed can include: 1) oil pipeline feed; la) Crude Oil, lb) Peat in various liquid forms, lc) Shale Oil, Id) Oil Sands, Id) Tar Sands, le) waste industrial and utility company transformer oil 2) waste (spent) automotive oil; 3) terminated spent tires; 4) spent batteries in various forms and construction; 5) coal and ; 6) carbon black. Waste (spent) oil is processed to remove impurities, including, inter alia, minerals, chemical additives, solvents, metals, carbon, grit, chlorine, sulfur, volatile organics, moisture, acids, ash, oxidants, PCBs, actinides, unspent fuel and other like contaminants. The pretreated material is sent to the refinery to be reprocessed in the refinery to petroleum, and to other modules such as, for example, advanced Nano, to provide composites, carbon fiber or ceramic materials, and other modules to provide fuels, lubricants or electrical and thermal energy products. By-products from the refining process can be recycled through matrix modules to provide further products. Products from the present matrix system and process include, inter alia, 1) motor oil; 2) gasoline; 3) diesel and JP-4; 3b) JP fuels, 4) kerosene; 5) greases and lubricants; 6) LPG, propane, hydrogen, naphtha, nitrogen; 7) butane; 8) feedstock; 9) metals including precious metals; 10) metal oxides; 11) sulfuric acid and sulfur; 12) waxes; 13) ceramics; 14) activated carbon; fluff (from tires and used as component for growing nano tubes) 15) carbon black; 16) asphalt; 17) ammonia;
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