Refrigerant Report 21
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REFRIGERANT REPO RT 21 A-501-21 EN BITZER Kühlmaschinenbau GmbH Peter-Schaufler-Platz 1 // 71065 Sindelfingen // Germany Tel +49 7031 932-0 // Fax +49 7031 932-147 [email protected] // www.bitzer.de Subject to change // 80050206 // 09.2020 A-501-21_EN_Cover.indd Alle Seiten 15.09.20 09:05 Refrigerant Report Contents Page Essential revisions/supplements vs. 20th edition Refrigerant development and legal situation 3 Alternative refrigerants – overview 4 Environmental aspects 6 Global Warming and TEWI Factor 6 Eco-Efficiency 7 HCFC refrigerants 8 R22 as transitional refrigerant 8 HFC refrigerants 9 R134a as a substitute for R12 and R22 9 Alternatives to R134a 11 Refrigerant blends 13 Substitutes for R22 in refrigeration systems 17 R404A and R507A as substitutes for R22 and R502 17 R407A, R407B, R407F, R407H and R422A as substitutes for R22 and R502 18 Substitutes for R22 in air conditioning systems and heat pumps 20 R407C as substitute for R22 // R410A as substitute for R22 20 R417A, R417B, R422D, R438A and R427A as substitutes for R22 22 R32 as substitute for R22 23 "Low GWP" HFOs and HFO/HFC blends as alternatives to HFCs 24 Aspects on the development 24 R134a alternatives 24 Substitutes for R404A/R507A and R410A 25 Further development projects 26 Halogen free (natural) refrigerants 28 NH 3 (Ammonia) as alternative refrigerant 28 R723 (NH 3/DME) as an alternative to NH 3 29 R290 (Propane) as alternative refrigerant // Propylene (R1270) as an alternative to Propane 30 Carbon dioxide R744 (CO 2) as an alternative refrigerant and secondary fluid 33 Refrigerants for special applications 37 Lubricants for compressors 41 Refrigerant properties 42 Application ranges 44 Overview lubricants 45 to the BITZER to the digital Refrigerant Ruler App Android iOS Refrigerant Report This edition supersedes all previous issues. Refrigerant development and legal situation Stratospheric ozone depletion as well as at- than direct (CO 2-equivalent) emissions The so-called "TEWI" factor ( Total Equiva - mospheric greenhouse effect due to refriger - caused by HFC refrigerants, refrigerants lent Warming Impact) has been introduced. ant emissions have led to drastic changes in with high global warming potential (GWP) Meanwhile, another, more extensive the refrigeration and air conditioning tech- will in the future be subject to use restrictions assessment method has been developed nology since the beginning of the 1990s. or bans. This will affect primarily R404A and considering "Eco-Efficiency". Hereby, both R507A, for which alternatives with lower ecological (such as TEWI) and economical This is especially true for the area of com - GWP are already being offered. However, in criteria are taken into account (further mercial refrigeration and air conditioning order to achieve the legal objectives, substi - explanations see page 7). systems with their wide range of applica - tutes for further refrigerants and increased Therefore it is possible that the assessment tions. In former years the main refrigerants use of naturally occurring substances (N H , 3 of refrigerants with regard to the environment used for these systems were ozone deplet - CO , hydrocarbons) will become necessary. ing types, namely R12, R22 and R502; for 2 can differ according to the place of installa - special applications R114, R12B1, R13B1, This requires comprehensive testing of tion and drive method. these refrigerants, suitable oils and adjusted R13 and R503 were used. Upon closer evaluation of substitutes for the systems. Therefore a close co-operation originally used CFC and HCFC as well as The use of these substances is no longer exists with scientific institutions, the refriger - for HFCs with higher GWP, the options with allowed in industrialised countries, but the ation and oil industries, component manu - single-substance refrigerants are very limit - use of R22 has been extended through tran - facturers as well as a number of innovative ed. This includes e.g. R134a, which will be sitional periods. However, the European refrigeration and air conditioning companies. Union also commited to an early phase-out usable for quite some time based on its for R22, which was enforced in several A large number of development tasks have comparatively low GWP. Similarly, the stages (see page 8). The main reason for been completed. Suitable compressors for hydro-fluoro-olefins (HFO) R1234yf and this early ban of R22 contrary to the inter- alternative refrigerants are available. R1234ze(E) with a GWP < 10, which are also exempted from the F-Gas regulation. national agreement is the ozone depletion Besides the development projects, BITZER potential although it is only small. actively supports legal regulations and self Direct alternatives (based on fluorinated Since 2010, phase-out regulations became commitments concerning the responsible hydrocarbons) for almost all refrigerants of effective in other countries as well, for use of refrigerants as well as measures to higher volumetric refrigerating capacity and instance in the USA. increase system and components’ efficiency. pressure level than R134a can (mainly) only be "formulated" as blends. However, taking This implies enormous consequences for The following report deals with potential into account thermodynamic properties, the whole refrigeration and air conditioning measures of a short to medium-term change flammability, toxicity and global warming sector. BITZER therefore committed itself to towards technologies with reduced environ - potential, the list of potential candidates is taking a leading role in the research and mental impact in medium and large size very limited. Blends of reduced GWP in- development of environmentally friendly sys - commercial and industrial refrigeration, air clude in addition to R134a, R1234yf and tem designs. conditioning and heat pump systems. R1234ze(E) primarily the refrigerants R32, Furthermore, the experiences so far and the After the chlorine-free (ODP = 0) HFC refriger - R125 and R152a. ants R134a, R404A, R407C, R507A and resulting consequences for plant technology R410A have become widely established for are discussed. Besides halogenated refrigerants, Ammonia many years in commercial refrigeration, air (NH 3) and hydrocarbons are considered as substitutes as well. The use for commercial conditioning and heat pump systems, new ? ? ? challenges have come up. They concern pri - applications, however, is limited by strict marily the greenhouse effect: The aim is a safety requirements. Several studies confirm that vapour com - clear reduction of direct emissions caused Carbon dioxide (CO ) becomes more impor - pression refrigeration systems normally 2 by refrigerant losses and indirect emissions tant as an alternative refrigerant and sec - used commercially are far superior in effi - by particularly efficient system technology. ondary fluid, too. Due to its specific charac - ciency to all other processes down to a cold teristics, however, there are restrictions to a In this area, applicable legal regulations are space temperature of around -40°C. already in force, such as the EU F-Gas general application. The selection of an alternative refrigerant Regulation No. 517/2014 (BITZER brochure The following illustrations show a structural and the system design receives special sig - A-510) and a series of regulations already survey of the alternative refrigerants and a nificance, however. Besides the request for ratified or in preparation as part of the EU summary of the single or blended substance s substances without ozone depletion poten - Ecodesign Directive (BITZER brochure which are now available. After that the indi - tial (ODP = 0) especially the energy de- A-530). Similar regulations are also in vidual subjects are discussed. preparation or already implemented in Aus - mand of a system is seen as an essential tralia, Canada and the USA. On an inter- criterion due to its indirect contribution to For refrigerant properties, application national level, the so-called "Kigali Amend - the greenhouse effect. On top of that there ranges and lubricant specifications, see ment" was adopted in 2016 under the is the direct global warming potential (GWP) pages 42 to 45. due to refrigerant emission. Montreal Protocol, in which a step-by-step For reasons of clarity the less or only reduction of HFCs ("HFC phase-down") was Therefore a calculation method has been regionally known products are not specified agreed upon starting in 2019. developed for the qualified evaluation of a in this issue, which is not intended to imply Even though indirect emissions caused by system which enables an analysis of the any inferiority. energy production are considerably higher total influence on the greenhouse effect. 3 Alternative refrigerants – overview Alternative Refrigerants Transitional/Service Medium and Long Refrigerants* Term Refrigerants HCFC/HFC HFC "Low GWP " Halogen free – partly chlorinated – – chlorine free – Refrigerants Single Single Single Single Substances Blends Substances Blends Substances Blends Substances Blends e.g.. R22 predominantly e.g. R134a e.g. R404A R1234yf R1234yf/ e.g. NH 3 e.g. R600a/ R123 R22 -Based R125 R507A R1234ze(E) R1234ze(E)/ R290 R290 R124 R32 R407-Serie HFKW R1270 R290/ R142b R143a R410A R600a R170 R152a R417A/B R170 R422 A/D R744 R723 R427A * Service refrigerants contain HCFC as blend component. They are therefore subject to the same legal regulations as R22 (see page 8). As a result of the continued refurbishment of older installations, the importance of these refrigerants is