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Experiment 5: Molar Volume of a Gas (Mg + Hcl)
1 CHEM 30A EXPERIMENT 5: MOLAR VOLUME OF A GAS (MG + HCL) Learning Outcomes Upon completion of this lab, the student will be able to: 1) Demonstrate a single replacement reaction. 2) Calculate the molar volume of a gas at STP using experimental data. 3) Calculate the molar mass of a metal using experimental data. Introduction Metals that are above hydrogen in the activity series will displace hydrogen from an acid and produce hydrogen gas. Magnesium is an example of a metal that is more active than hydrogen in the activity series. The reaction between magnesium metal and aqueous hydrochloric acid is an example of a single replacement reaction (a type of redox reaction). The chemical equation for this reaction is shown below: Mg(s) + 2HCl(aq) è MgCl2(aq) + H2(g) Equation 1 When the reaction between the metal and the acid is conducted in a eudiometer, the volume of the hydrogen gas produced can be easily determined. In the experiment described below magnesium metal will be reacted with an excess of hydrochloric acid and the volume of hydrogen gas produced at the experimental conditions will be determined. According to Avogadro’s law, the volume of one mole of any gas at Standard Temperature and Pressure (STP = 273 K and 1 atm) is 22.4 L. Two important Gas Laws are required in order to convert the experimentally determined volume of hydrogen gas to that at STP. 1. Dalton’s law of partial pressures. 2. Combined gas law. Dalton’s Law of Partial Pressures According to Dalton’s law of partial pressures in a mixture of non-reacting gases, the total pressure exerted is equal to the sum of the partial pressures of the individual gases. -
FS/2018 ORGANIC CHEMISTRY I LAB CHEM 226 (2219) Instructor
FS/2018 ORGANIC CHEMISTRY I LAB CHEM 226 (2219) Instructor: Terry Bone 120-B Schrenk Hall [email protected] 341-4820 http://www.mst.edu/~tbone 9:00-10:00, Tu-Th, or by appt. Cynthia Bolon 213 Schrenk Hall [email protected] 341-4439 OBJECTIVES: Course objectives are to develop facility with performing laboratory techniques involving the handling of organic chemicals safely and the keeping of proper records of experiments conducted in the laboratory. Crystallization, distillation, extraction and chromatography are emphasized as separation and purification techniques. Melting points, boiling points, and refractive indices are used routinely as measures of purity. Safe handling of chemicals and proper disposal of waste products are priority goals in this course. To help in attaining such goals, the first week of the semester is devoted to SAFETY in the chemistry laboratory. For the remainder of the semester, most of the experiments are conducted on a micro scale. BOOKS: 1. 100 pg. set Organic Chemistry Laboratory Notebook 2. “Organic Chemistry Laboratory Laboratory Techniques, 2nd ed”. Available as free pdf download at https://open.umn.edu/opentextbooks/BookDetail.aspx?bookId=369 3. “Microscale Techniques for the Organic Laboratory, 2nd ed”, (MTOL), Mayo, Pike, Butcher and Trumper, John Wiley & Sons, Inc.,2001 (on reserve at library circulation desk-currently out of print but available on Amazon) 4. “Right to Know pocket guide for School & University Employees”, Genium Publishing Corp., 1990. (optional) (#1 can be purchased from the book store) LAB SYLLABUS: Originally prepared by Prof. S. B. Hanna, modified by D. E. Hoiness, T.Bone. GENERAL GUIDELINES SAFETY Goggles must be worn at all times in the lab. -
EWRE Lab Regulations
Department of Civil & Environmental Engineering University of Massachusetts College of Engineering University of Massachusetts September 2012 CONTENTS UNIVERSITY OF MASSACHUSETTS ......................................................................................................................... 1 CONTENTS ...................................................................................................................................................................... 2 A. LABORATORY SAFETY AND SECURITY ........................................................................................................... 1 1. GENERAL RULES .......................................................................................................................................................... 1 2. EMERGENCY ................................................................................................................................................................ 2 3. DISPOSAL OF CHEMICALS ............................................................................................................................................ 2 a. What chemical wastes are hazardous or non-hazardous? ...................................................................................... 2 b. Disposal of hazardous wastes ................................................................................................................................. 2 4. FUME HOODS .............................................................................................................................................................. -
22 Bull. Hist. Chem. 8 (1990)
22 Bull. Hist. Chem. 8 (1990) 15 nntn Cn r fr l 4 0 tllOt f th r h npntd nrpt ltd n th brr f th trl St f nnlvn n thr prt nd ntn ntl 1 At 1791 1 frn 7 p 17 AS nntn t h 3 At 179 brr Cpn f hldlph 8Gztt f th Untd Stt Wdnd 3 l 1793 h ntr nnnnt rprdd n W Ml "njn h Cht"Ch 1953 37-77 h pn pr dtd 1 l 179 nd nd b Gr Whntn th frt ptnt d n th Untd Stt S M ntr h rt US tnt" Ar rt Invnt hn 199 6(2 1- 19 ttrfld ttr fnjn h Arn hl- phl St l rntn 1951 pp 7 9 20h drl Gztt 1793 (20 Sptbr Qtd n Ml rfrn 1 1 W Ml rfrn 1 pp 7-75 William D. Williams is Professor of Chemistry at Harding r brt tr University, Searcy, Al? 72143. He collects and studies early American chemistry texts. Wyndham D. Miles. 24 Walker their British cultural heritage. To do this, they turned to the Avenue, Gaithersburg, MD 20877, is winner of the 1971 schools (3). This might explain why the Virginia assembly Dexter Award and is currently in the process of completing the took time in May, 1780 - during a period when their highest second volume of his biographical dictionary. "American priority was the threat of British invasion following the fall of Chemists and Chemical Engineers". Charleston - to charter the establishment of Transylvania Seminary, which would serve as a spearhead of learning in the wilderness (1). -
Determination of Calcium Metal in Calcium Cored Wire
Asian Journal of Chemistry; Vol. 25, No. 17 (2013), 9439-9441 http://dx.doi.org/10.14233/ajchem.2013.15017 Determination of Calcium Metal in Calcium Cored Wire 1,* 1 2 1 1 HUI DONG QIU , MEI HAN , BO ZHAO , GANG XU and WEI XIONG 1Department of Chemistry and Chemical Technology, Chong Qing University of Science and Technology, Chongqing 401331, P.R. China 2Shang Hai Entry-Exit Inspection and Quarantine Bureau, P.R. China *Corresponding author: Tel: +86 23 65023763; E-mail: [email protected] (Received: 24 December 2012; Accepted: 1 October 2013) AJC-14200 The calcium analysis method in cored wire products is mainly measuring the total calcium content, including calcium oxide and calcium carbonate. According to the chemical composition of calcium cored wire and the chemical property of the active calcium in it, the gas volumetric method has been established for the determination of calcium content in calcium cored wire and a set of analysis device is also designed. Sampling in the air directly, intercepting the inner filling material of samples, reacting with water for 10 min, using standard comparison method and then the accurate calcium content can be available. The recovery rate of the experimental method was 93-100 %, the standard deviation is less than 0.4 %. The method is suitable for the determination the calcium in the calcium cored wire and containing active calcium fractions. Key Words: Calcium cored wire, Active calcium, Gas volumetric method. INTRODUCTION various state of the calcium. However, because the sample is heterogeneous and the amount of the sample for instrumental 1-4 The calcium cored wire is used to purify the molten analysis is small, thus such sampling can not estimate charac- steel, modify the form of inclusions, improve the casting and teristics of the whole ones accurately, so there are flaws to use mechanical properties of the steel and also reduce the cost of the instrumental analysis to determine the calcium metal in steel. -
XXIX. on the Magnetic Susceptibilities of Hydrogen and Some Other Gases
Philosophical Magazine Series 6 ISSN: 1941-5982 (Print) 1941-5990 (Online) Journal homepage: http://www.tandfonline.com/loi/tphm17 XXIX. On the magnetic susceptibilities of hydrogen and some other gases Také Soné To cite this article: Také Soné (1920) XXIX. On the magnetic susceptibilities of hydrogen and some other gases , Philosophical Magazine Series 6, 39:231, 305-350, DOI: 10.1080/14786440308636042 To link to this article: http://dx.doi.org/10.1080/14786440308636042 Published online: 08 Apr 2009. Submit your article to this journal Article views: 6 View related articles Citing articles: 16 View citing articles Full Terms & Conditions of access and use can be found at http://www.tandfonline.com/action/journalInformation?journalCode=6phm20 Download by: [RMIT University Library] Date: 20 June 2016, At: 12:34 E 3o5 XXIX. On the MAgnetic Susceptibilities of llydrogen uud some otl~er Gases. /33/TAK~; S0~; *. INDEX TO SECTIONS. 1. INTRODUCTION. ~O. METI~OD OF 5LEASUREMENT. o. APPARATUS :FOR }IEASU14EIMF~NT. (a) Magnetic bMance. (b) Compressor and measuring tube. 4. PIt0CEDUI{E :FOR BIEASUREMENTS. (a) Adjustment of the measuring tube. (b) Determination of the mass. (c) Method of filling the measuring tube with gas. (d) Electromagnet. (e} Method of experiments. 5. Ain. 6. OXYGEN. ~. CARBON DIOXIDE. 8. NITROGEN. 9. ItYDI~0G~N. (a) Preparation of pure hydrogen gas. (b) Fillin~ the measuring tube with the gas. (e) YCesults el'magnetic measurement. (d} Purity of the hydrogen gas. 10. CONCLUDING REMARKS. wi. INTRODUCTION. N the electron theory of magnetism, it is assumed that I the magnetism is duo to electrons revolving about the positive nucleus in the atom; and hence the electronic structure of the atom has a very important bearing on its magnetic properties. -
A Study of Form and Content for a Laboratory Manual to Be Used by Students in General Chemistry Laboratory
Brigham Young University BYU ScholarsArchive Theses and Dissertations 1946-01-01 A study of form and content for a laboratory manual to be used by students in general chemistry laboratory Berne P. Broadbent Brigham Young University - Provo Follow this and additional works at: https://scholarsarchive.byu.edu/etd BYU ScholarsArchive Citation Broadbent, Berne P., "A study of form and content for a laboratory manual to be used by students in general chemistry laboratory" (1946). Theses and Dissertations. 8176. https://scholarsarchive.byu.edu/etd/8176 This Thesis is brought to you for free and open access by BYU ScholarsArchive. It has been accepted for inclusion in Theses and Dissertations by an authorized administrator of BYU ScholarsArchive. For more information, please contact [email protected], [email protected]. ?_(j;, . , i. ~ ~ (12 ' -8?5: 11% -· • A STUDY OF FOFM CONTENTFOR A LABORATORY -\ .AND MANUALTO BE USED BY STUDENTSIN GENERALCEEi/IISTRY LABORATORY' A THESIS SUBMITTEDTO \ THE DEPAR'.I3\t1Ell."'T OF CHEMISTRY OF ··! BRIGHAMYOUNG UNIVERSITY,. IN PARTIALFULFII.lllENT OF THEREQ,UIREMENTS·FOR THE DEGREE OF MASTEROF SCIENCE ... .,; . •·' .. ...• • .• . • "f ... ·.. .. ,. ·: :. !./:.•:-.:.lo>•.-,:... ... ... ..........• • • • p ,.. .,• • • ...• • . ~. ••,,. ................. :... ~•••,,.c • ..............• • • • • • .. f" ·~•-~-·"••• • • • ... • .., : :·.•··•:'"'•••:'"',. ·.-··.::· 147141 BY BERNEP. BROADBENT . " 1946 .,_ - ii \ ., This Thesis by Berne P.- Broadbent is accepted in 1ts P:esent form by the Departm·ent of Chem�stry as satisfying the Thesis requirement.for the degree of .J Master of Science • ,• . - .} .. iii PREF.ACE The constantly broadening field assigned to general chemistry demands that material be carefully selected and that ever increasing attention be given to preparing this material and presenting it_ to the student.- The following study was made to develop a laboratory manual that would increase the effectiveness of laboratory work. -
Laboratory Manual
International Program UAM-Boston University Laboratory Manual Organic Chemistry I 2013-2014 Departamento de Química Orgánica Ernesto Brunet Romero Ana María Martín Castro Ramón Gómez Arrayás Laboratory Manual Table of Contents ............................................................................... 1 Introduction ............................................................................... 2 Prelab preparation ............................................................................... 2 Notebook ............................................................................. 3 Safety .............................................................................. 3 Laboratory Practices and Safety Rules ............................................................. 4 Accidents and injuries ........................................................................... 5 Fires ............................................................................. 5 Chemical Wastes ............................................................................. 6 Cleaning Responsibilities ............................................................................. 6 Lab cleanliness ............................................................................. 6 Laboratory Equipment ............................................................................. 7 Proper use of glassware ............................................................................. 8 Some techniques in lab experiments Heating, cooling and stirring ............................................................................ -
CHAPTER 15 the Laboratory
CHAPTER 15 The Laboratory These skills are usually tested on the SAT Subject Test in Chemistry. You should be able to . • Name, identify, and explain proper laboratory rules and procedures. • Identify and explain the proper use of laboratory equipment. • Use laboratory data and observations to make proper interpretations and conclusions. This chapter will review and strengthen these skills. Be sure to do the Practice Exercises at the end of the chapter. Laboratory setups vary from school to school depending on whether the lab is equipped with macro- or microscale equipment. Microlabs use specialized equipment that allows lab work to be done on a much smaller scale. The basic principles are the same as when using full-sized equipment, but microscale equipment lowers the cost of materials, results in less waste, and poses less danger. The examples in this book are of macroscale experiments. Along with learning to use microscale equipment, most labs require a student to learn how to use technological tools to assist in experiments. The most common are: Gravimetric balance with direct readings to thousandths of a gram instead of a triple-beam balance pH meters that give pH readings directly instead of using indicators Spectrophotometer, which measures the percentage of light transmitted at specific frequencies so that the molarity of a sample can be determined without doing a titration Computer-assisted labs that use probes to take readings, e.g., temperature and pressure, so that programs available for computers can print out a graph of the relationship of readings taken over time LABORATORY SAFETY RULES The Ten Commandments of Lab Safety The following is a summary of rules you should be well aware of in your own chemistry lab. -
Isolation and Characterization of a Natural Product: Caffeine
Cerritos Community College Organic Chemistry 211 Laboratory Isolation and Characterization of a Natural Product: Caffeine. O O CH3 N H HN – H3C N O N N O N N P OH H2N N O O N N N N O H3C OH purine 2'-deoxyguanosine caffeine 5'-phosphate In this experiment, the techniques of solid-liquid extraction and liquid-liquid extraction will be used to isolate caffeine from tealeaves. A new purification technique, sublimation, will be used to perform the final purification. Caffeine is a member of the class of natural products called alkaloids, which contain nitrogen. Other members of this class include morphine, mescaline, and strychnine. The strong biological activity of these compounds has led to their thorough investigation by many different disciplines. Caffeine possesses the oxidized skeleton of purine, a relative of which can be found as a constituent of DNA (see above). Caffeine is found in many plants with coffee and tea being the most familiar. A cup of coffee or tea provides a 25- to 100-mg “Dose” of caffeine, which stimulates the central nervous system in a widely exploited manner. From the preceding, it is not surprising that caffeine is soluble in hot water, but it is also soluble in dichloromethane, allowing the following extractive protocol to isolate it. This two-step extractive isolation assures that ionic species remain in the aqueous layer while taking advantage of the swelling that water causes in the tea leaves. Simply extracting the tealeaves with dichloromethane directly is ineffective. The sodium carbonate added to the water during the “steeping” stage is to insure that the caffeine and organic acids are deprotonated. -
5-Solution Unknown
College Prep Chemistry Lab Manual Written, compiled, edited by Brian Cox and Dan Albritton Thanks to Daniel Knowles, Eddie Taylor, Dylan Muzny, Cammie Wickham Table of Contents Reference Laboratory Safety Guidelines i, ii Lab Experiments Pages Expt #1: 5-Solution Unknown 1-2 Data Analysis: How does the Mass of Pennies Change with Age? 3-5 Expt #2: Relationship between Mass of Reactants to Mass of Products 6-13 Expt #3: Distillation: Separation of two liquids 14-17 Expt #4: Observing the Chemistry of Iron(II) and Iron(III) 18-19 Expt #5: An Activity Series of Metals (Single Replacement Rxns) 20-21 Expt #6: Precipitation Reactions (Double Replacement Rxns) 22-23 Expt #7: Recording Measurements with Correct Sig Figures and 24-26 Uncertainty Expt #8: Mole Concept – How many atoms or molecules are present? 27-30 Expt #9: Empirical Formula of a Hydrate 31-33 Expt #10: Density of Twizzler Sticks 34-35 Expt #11: A Taste of Molarity 36 Expt #12: Preparing Molar Solutions 37- 38 Expt #13: Demos to investigate concept of limiting reactant and optimal 39-42 ratio Expt #14: Determination of Percent Yield – How efficient is your reaction? 43-46 Expt #15: Determination of Universal Gas Constant 47-51 Expt #16: Emission Spectrum and Quantum Leaps 52-55 Expt #17: Beer’s Law: Determining Molar Concentration by Absorbance 56-60 Spectroscopy Expt #18: Relationship between Type of Chemical Bonds and Electrical 61-64 Conductivity Expt #19: Molecular Models (Drawing in 3-D) 65-67 Expt #20: Polar and Non-Polar Molecules in an Electric Field 68-69 Expt #21: Molecular -
Inquiry-Based Laboratory Work in Chemistry
INQUIRY-BASED LABORATORY WORK IN CHEMISTRY TEACHER’S GUIDE Derek Cheung Department of Curriculum and Instruction The Chinese University of Hong Kong Inquiry-based Laboratory Work in Chemistry: Teacher’s Guide / Derek Cheung Copyright © 2006 by Quality Education Fund, Hong Kong All rights reserved. Published by the Department of Curriculum and Instruction, The Chinese University of Hong Kong. No part of this book may be reproduced in any manner whatsoever without written permission, except in the case of use as instructional material in a school by a teacher. Note: The material in this teacher’s guide is for information only. No matter which inquiry-based lab activity teachers choose to try out, they should always conduct risks assessment in advance and highlight safety awareness before the lab begins. While every effort has been made in the preparation of this teacher’s guide to assure its accuracy, the Chinese University of Hong Kong and Quality Education Fund assume no liability resulting from errors or omissions in this teacher’s guide. In no event will the Chinese University of Hong Kong or Quality Education Fund be liable to users for any incidental, consequential or indirect damages resulting from the use of the information contained in the teacher’s guide. ISBN 962-85523-0-9 Printed and bound by Potential Technology and Internet Ltd. Contents Preface iv Teachers’ Concerns about Inquiry-based Laboratory Work 1 Secondary 4 – 5 Guided Inquiries 1. How much sodium bicarbonate is in one effervescent tablet? 4 2. What is the rate of a lightstick reaction? 18 3. Does toothpaste protect teeth? 29 4.