Hazardous Substances and Waste Dangerous Goods Regulations
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United States Patent Office Patented Aug
3,202,556 United States Patent Office Patented Aug. 24, 1965 2 mannan. As a consequence, crosslinking agents are used METHOD FOR GELiNGWATER-BEARNG3,282,555 EX to hasten the formation of gels, or they may be employed PLGSIVE COMPOSTIONS CONTAINNG GAYLAC to form gels which have desired physical properties at rel TOMANNAN (GUAS atively low gum concentrations, or even have properties Joseph D. Chrisp, Caymorf, Dai, assig or to E. I. du not obtainable by the use of the gum alone. An effective Poit de Neno Ers and Company, Wilmington, De., a and Well known crosslinking agent for the hydrated galac corporation of Delaware tomannans, especially for guar gum, is the borate ion No iPrawing. Fied July 23, 1963, Ser. No. 296,932 which acts as a crosslinking agent with hydrated guar gum 14 (Claims. (C. 49-20) to form cohesive structural gels. The process of cross 10 linking guar-containing compositions by adding borate This invention relates to a process for gelling aqueous ions has been employed in the manufacture of ammonium solutions of water-dispersible, non-ionic hydroxyl poly nitrate-based blasting agent compositions, as disclosed and mers. More particularly, this invention relates to a proc claimed in U.S. Patent No. 3,072,509. Such blasting ess for making water-bearing gels containing galactoman agents have a desirable body which resists dispersion of nans and to certain products obtained thereby including 5 the compositions by water and facilitates their handling explosives. and loading. Also, such crosslinked blasting agents are Water-soluble gums have been articles of commerce economical and safe to use, and have better storage prop for hundreds of years. -
WO 2015/179628 Al 26 November 2015 (26.11.2015) P O P C T
(12) INTERNATIONAL APPLICATION PUBLISHED UNDER THE PATENT COOPERATION TREATY (PCT) (19) World Intellectual Property Organization International Bureau (10) International Publication Number (43) International Publication Date WO 2015/179628 Al 26 November 2015 (26.11.2015) P O P C T (51) International Patent Classification: (81) Designated States (unless otherwise indicated, for every C08F 210/16 (2006.01) kind of national protection available): AE, AG, AL, AM, AO, AT, AU, AZ, BA, BB, BG, BH, BN, BR, BW, BY, (21) International Application Number: BZ, CA, CH, CL, CN, CO, CR, CU, CZ, DE, DK, DM, PCT/US20 15/03 1952 DO, DZ, EC, EE, EG, ES, FI, GB, GD, GE, GH, GM, GT, (22) International Filing Date: HN, HR, HU, ID, IL, IN, IR, IS, JP, KE, KG, KN, KP, KR, 2 1 May 2015 (21 .05.2015) KZ, LA, LC, LK, LR, LS, LU, LY, MA, MD, ME, MG, MK, MN, MW, MX, MY, MZ, NA, NG, NI, NO, NZ, OM, (25) Filing Language: English PA, PE, PG, PH, PL, PT, QA, RO, RS, RU, RW, SA, SC, (26) Publication Language: English SD, SE, SG, SK, SL, SM, ST, SV, SY, TH, TJ, TM, TN, TR, TT, TZ, UA, UG, US, UZ, VC, VN, ZA, ZM, ZW. (30) Priority Data: 14/284,689 22 May 2014 (22.05.2014) US (84) Designated States (unless otherwise indicated, for every kind of regional protection available): ARIPO (BW, GH, (71) Applicant: CHEVRON PHILLIPS CHEMICAL COM¬ GM, KE, LR, LS, MW, MZ, NA, RW, SD, SL, ST, SZ, PANY LP [US/US]; 10001 Six Pines Drive, The Wood TZ, UG, ZM, ZW), Eurasian (AM, AZ, BY, KG, KZ, RU, lands, TX 77380 (US). -
CF 7.4 V2.Indd
2007 VOLUME 7 NUMBER 4 Product Directory Grignard and Organozinc Reagents RIEKE® HIGHLY REACTIVE METALS GRIGNARD REAGENTS ORGANOZINC HALIDES DIALKYLMAGNESIUM AND DIALKYZINC REAGENTS 2-Pyridylzinc bromide: a shelf-stable 2-pyridyl anion equivalent; an important motif in many pharmacologically active molecules. sigma-aldrich.com 2 Table of Contents Sigma-Aldrich is committed to providing the most extensive portfolio of high-quality Grignard, organozinc, and other organometallic reagents, and we continually expand our product listing. Within each section of this directory, products are listed by increasing carbon content. Rieke® Highly Reactive Metals If viewing the electronic version simply select Grignard Reagents a category to jump to that section or activate Alkyl Alkenyl Alkynyl Aryl Heteroaryl your Adobe Bookmarks. You may also search by name, product number, molecular formula, Organozinc Halides or CAS registry number simply by using the “find” feature in Adobe (Ctrl+F in Windows or Alkyl Alkenyl Aryl Heteroaryl Introduction Command+F in a Mac environment). Dialkylmagnesium and Dialkylzinc Reagents If you are unable to find a reagent for your research “Please Bother Us” at [email protected], or contact your local Sigma-Aldrich office (see back cover). Foreword Reuben D. Rieke President and CEO, Rieke Metals, Inc. Professor Emeritus, University of Nebraska Lincoln, NE In the last 35 years, considerable research has been done in the area of generating reactive metals that can be used to synthesize novel organometallic reagents. In 1972, we reported a general approach for preparing highly reactive metal powders, relying on the reduction of metal salts with alkali metals in ethereal or hydrocarbon solvents. -
Chemical Name Federal P Code CAS Registry Number Acutely
Acutely / Extremely Hazardous Waste List Federal P CAS Registry Acutely / Extremely Chemical Name Code Number Hazardous 4,7-Methano-1H-indene, 1,4,5,6,7,8,8-heptachloro-3a,4,7,7a-tetrahydro- P059 76-44-8 Acutely Hazardous 6,9-Methano-2,4,3-benzodioxathiepin, 6,7,8,9,10,10- hexachloro-1,5,5a,6,9,9a-hexahydro-, 3-oxide P050 115-29-7 Acutely Hazardous Methanimidamide, N,N-dimethyl-N'-[2-methyl-4-[[(methylamino)carbonyl]oxy]phenyl]- P197 17702-57-7 Acutely Hazardous 1-(o-Chlorophenyl)thiourea P026 5344-82-1 Acutely Hazardous 1-(o-Chlorophenyl)thiourea 5344-82-1 Extremely Hazardous 1,1,1-Trichloro-2, -bis(p-methoxyphenyl)ethane Extremely Hazardous 1,1a,2,2,3,3a,4,5,5,5a,5b,6-Dodecachlorooctahydro-1,3,4-metheno-1H-cyclobuta (cd) pentalene, Dechlorane Extremely Hazardous 1,1a,3,3a,4,5,5,5a,5b,6-Decachloro--octahydro-1,2,4-metheno-2H-cyclobuta (cd) pentalen-2- one, chlorecone Extremely Hazardous 1,1-Dimethylhydrazine 57-14-7 Extremely Hazardous 1,2,3,4,10,10-Hexachloro-6,7-epoxy-1,4,4,4a,5,6,7,8,8a-octahydro-1,4-endo-endo-5,8- dimethanonaph-thalene Extremely Hazardous 1,2,3-Propanetriol, trinitrate P081 55-63-0 Acutely Hazardous 1,2,3-Propanetriol, trinitrate 55-63-0 Extremely Hazardous 1,2,4,5,6,7,8,8-Octachloro-4,7-methano-3a,4,7,7a-tetra- hydro- indane Extremely Hazardous 1,2-Benzenediol, 4-[1-hydroxy-2-(methylamino)ethyl]- 51-43-4 Extremely Hazardous 1,2-Benzenediol, 4-[1-hydroxy-2-(methylamino)ethyl]-, P042 51-43-4 Acutely Hazardous 1,2-Dibromo-3-chloropropane 96-12-8 Extremely Hazardous 1,2-Propylenimine P067 75-55-8 Acutely Hazardous 1,2-Propylenimine 75-55-8 Extremely Hazardous 1,3,4,5,6,7,8,8-Octachloro-1,3,3a,4,7,7a-hexahydro-4,7-methanoisobenzofuran Extremely Hazardous 1,3-Dithiolane-2-carboxaldehyde, 2,4-dimethyl-, O- [(methylamino)-carbonyl]oxime 26419-73-8 Extremely Hazardous 1,3-Dithiolane-2-carboxaldehyde, 2,4-dimethyl-, O- [(methylamino)-carbonyl]oxime. -
Grignard Reagents and Silanes
GRIGNARD REAGENTS AND SILANES By B. Arkles REPRINTED FROM HANDBOOK OF GRIGNARD REAGENTS by G. Silverman and P. Rakita Pages 667-675 Marcel Dekker, 1996 Gelest, Inc. 612 William Leigh Drive Tullytown, Pa. 19007-6308 Phone: [215] 547-1015 Fax: [215] 547-2484 Grignard Reagents and Silanes 32 Grignard Reagents and Silanes BARRY ARKLES Gelest Inc., Tullytown, Pennsylvania I. INTRODUCTION This review considers two aspects of the interaction of Grignards with silanes. First, focusing on technologies that are still viable within the context of current organosilane and silicone technology, guidelines are provided for silicon-carbon bond formation using Grignard chemistry. Second, the use of silane-blocking agents and their stability in the presence of Grignard reagents employed in organic synthesis is discussed. II. FORMATION OF THE SILICON-CARBON BOND A. Background The genesis of current silane and silicone technology traces back to the Grignard reaction. The first practical synthesis of organosilanes was accomplished by F. Stanley Kipping in 1904 by the Grignard reaction for the formation of the silicon-carbon bond [1]. In an effort totaling 57 papers, he created the basis of modern organosilane chemistry. The development of silicones by Frank Hyde at Corning was based on the hydrolysis of Grignard-derived organosilanes [2]. Dow Corning, the largest manufacturer of silanes and silicones, was formed as a joint venture between Corning Glass, which had silicone product technology, and Dow, which had magnesium and Grignard technology, during World War II. In excess of 10,000 silicon compounds have been synthesized by Grignard reactions. Ironically, despite the versatility of Grignard chemistry for the formation of silicon-carbon bonds, its use in current silane and silicone technology has been supplanted by more efficient and selective processes for the formation of the silicon-carbon bond, notably by the direct process and hydrosilylation reactions. -
Public Health Goal for ANTIMONY in Drinking Water
Public Health Goal for ANTIMONY in Drinking Water Prepared by Pesticide and Environmental Toxicology Section Office of Environmental Health Hazard Assessment California Environmental Protection Agency December 1997 LIST OF CONTRIBUTORS PHG PROJECT MANAGEMENT REPORT PREPARATION SUPPORT Project Officer Author Administrative Support Anna Fan, Ph.D. Lubow Jowa, Ph.D. Edna Hernandez Coordinator Chemical Prioritization Primary Reviewer Laurie Bliss Report Outline Robert Brodberg, Ph.D. Sharon Davis Joseph Brown, Ph.D. Kathy Elliott Coordinator Secondary Reviewer Vickie Grayson David Morry, Ph.D. Michael DiBartolomeis, Ph.D. Michelle Johnson Yi Wang, Ph.D. Juliet Rafol Final Reviewers Genevieve Shafer Document Development Anna Fan, Ph.D. Tonya Turner Michael DiBartolomeis, Ph.D. William Vance, Ph.D. Coordinator Library Support George Alexeeff, Ph.D. Editor Mary Ann Mahoney Hanafi Russell, M.S. Michael DiBartolomeis, Ph.D. Valerie Walter Yi Wang, Ph.D. Website Posting Public Workshop Robert Brodberg, Ph.D. Michael DiBartolomeis, Ph.D. Edna Hernandez Coordinator Laurie Monserrat, M.S. Judy Polakoff, M.S. Judy Polakoff, M.S. Organizer Hanafi Russell, M.S. Methodology/Approaches/ Review Comments Joseph Brown, Ph.D. Robert Howd, Ph.D. Coordinators Lubow Jowa, Ph.D. David Morry, Ph.D. Rajpal Tomar, Ph.D. Yi Wang, Ph.D. We thank the U.S. EPA’s Office of Water, Office of Pollution Prevention and Toxic Substances, and National Center for Environmental Assessment for their peer review of the PHG documents, and the comments received from all interested parties. ANTIMONY in Drinking Water ii December 1997 California Public Health Goal (PHG) PREFACE Drinking Water Public Health Goal of the Office of Environmental Health Hazard Assessment This Public Health Goal (PHG) technical support document provides information on health effects from contaminants in drinking water. -
Acutely / Extremely Hazardous Waste List
Acutely / Extremely Hazardous Waste List Federal P CAS Registry Acutely / Extremely Chemical Name Code Number Hazardous 4,7-Methano-1H-indene, 1,4,5,6,7,8,8-heptachloro-3a,4,7,7a-tetrahydro- P059 76-44-8 Acutely Hazardous 6,9-Methano-2,4,3-benzodioxathiepin, 6,7,8,9,10,10- hexachloro-1,5,5a,6,9,9a-hexahydro-, 3-oxide P050 115-29-7 Acutely Hazardous Methanimidamide, N,N-dimethyl-N'-[2-methyl-4-[[(methylamino)carbonyl]oxy]phenyl]- P197 17702-57-7 Acutely Hazardous 1-(o-Chlorophenyl)thiourea P026 5344-82-1 Acutely Hazardous 1-(o-Chlorophenyl)thiourea 5344-82-1 Extemely Hazardous 1,1,1-Trichloro-2, -bis(p-methoxyphenyl)ethane Extemely Hazardous 1,1a,2,2,3,3a,4,5,5,5a,5b,6-Dodecachlorooctahydro-1,3,4-metheno-1H-cyclobuta (cd) pentalene, Dechlorane Extemely Hazardous 1,1a,3,3a,4,5,5,5a,5b,6-Decachloro--octahydro-1,2,4-metheno-2H-cyclobuta (cd) pentalen-2- one, chlorecone Extemely Hazardous 1,1-Dimethylhydrazine 57-14-7 Extemely Hazardous 1,2,3,4,10,10-Hexachloro-6,7-epoxy-1,4,4,4a,5,6,7,8,8a-octahydro-1,4-endo-endo-5,8- dimethanonaph-thalene Extemely Hazardous 1,2,3-Propanetriol, trinitrate P081 55-63-0 Acutely Hazardous 1,2,3-Propanetriol, trinitrate 55-63-0 Extemely Hazardous 1,2,4,5,6,7,8,8-Octachloro-4,7-methano-3a,4,7,7a-tetra- hydro- indane Extemely Hazardous 1,2-Benzenediol, 4-[1-hydroxy-2-(methylamino)ethyl]- 51-43-4 Extemely Hazardous 1,2-Benzenediol, 4-[1-hydroxy-2-(methylamino)ethyl]-, P042 51-43-4 Acutely Hazardous 1,2-Dibromo-3-chloropropane 96-12-8 Extemely Hazardous 1,2-Propylenimine P067 75-55-8 Acutely Hazardous 1,2-Propylenimine 75-55-8 Extemely Hazardous 1,3,4,5,6,7,8,8-Octachloro-1,3,3a,4,7,7a-hexahydro-4,7-methanoisobenzofuran Extemely Hazardous 1,3-Dithiolane-2-carboxaldehyde, 2,4-dimethyl-, O- [(methylamino)-carbonyl]oxime 26419-73-8 Extemely Hazardous 1,3-Dithiolane-2-carboxaldehyde, 2,4-dimethyl-, O- [(methylamino)-carbonyl]oxime. -
Table of Contents
UNIVERSITY OF MISSOURI-KANSAS CITY CHEMICAL MANAGEMENT PLAN Revised May 2016 UMKC CHEMICAL MANAGEMENT PLAN This document constitutes the Chemical Management Plan (CMP) for the University of Missouri-Kansas City (UMKC). It was developed by the Environmental Health and Safety Department (EHS), to ensure the safe and proper use of hazardous and non- hazardous chemicals and to comply with applicable governmental regulations addressing the disposal of these chemicals. In addition, it was developed to foster waste minimization, and to provide the faculty and the staff with a management program to reduce the potential for accidents involving hazardous chemicals and/or wastes. Elements of the CMP include: a. a procedure for identifying potential or actual hazardous chemicals or wastes b. a procedure for periodic reexamination of those hazardous chemicals or wastes identified by the procedure in (a.) above as well as a systematic method for identification and evaluation of any new potential or actual hazardous chemicals or wastes c. procedures for labeling, and inventorying hazardous chemicals or wastes d. a procedure for identification and training of personnel directly responsible for ensuring that (a.), (b.), and (c.) are implemented e. a procedure for monitoring, recording, and reporting compliance with the CMP f. a procedure by which information generated by the CMP is provided to the persons performing waste analyses Each element is addressed as part of the complete CMP in the following paragraphs. 4 Table of Contents 1 Definitions 7 2 Identification -
ANTIMONY by James F
ANTIMONY By James F. Carlin, Jr. Domestic survey data and tables were prepared by Mahbood Mahdavi, statistical assistant, and the world production table was prepared by Regina R. Coleman, international data coordinator. More than one-half of the primary antimony used in the merging operations with Laurel, the unified operation would United States during 2004 went into flame-retardants; most of increase its competitive position. manufacturing for the joint the remainder was used by the ceramic, chemical, glass, and venture will be consolidated into the existing Great Lakes transportation industries. Secondary antimony, which was antimony production facility in Reynosa, mexico. the Laurel derived almost entirely from recycled lead-acid batteries, was production facility in La Porte, tX, which employed 4 people, used in the manufacture of new batteries. in 2004, the average ceased production by yearend 2004; production of raw materials price of antimony was 20% higher than that of 2003. for flame-retardants and catalyst grades of antimony oxide was There was no domestic antimony mine production during the transferred to the Great Lakes facility in mexico (Great Lakes year. most primary antimony metal and oxide were produced Chemical Corp., 2004). domestically from imported raw material. most domestic At yearend 2004, the United States had only one antimony smelting consisted of upgrading imported antimony trioxide to a smelter, the United States Antimony Corp. (USAC), based in higher purity. Primary antimony metal and oxide were produced Montana. USAC produced antimony metal for bearings, lead by two companies operating two plants––one in montana and alloys, and ordnance; antimony oxide as a raw material for one in texas. -
Acroseal Packaging Your Solution for Air- and Moisture- Sensitive Reagents
AcroSeal Packaging Your solution for air- and moisture- sensitive reagents Extra dry solvents Deuterated solvents Organometallic compounds Reagents in solution Organics Introduction Since the launch of AcroSealTM packaging we have introduced a new septum, which helps preserve product quality for longer. In addition, our AcroSeal portfolio has been expanded to include a broad range of solvents, organometallics, reagents in solution and organic compounds. In this brochure we have categorized our products under chemical families to make it easier to locate the product you need. Introduction Page no. AcroSeal packaging highlights 3 AcroSeal packaging performance 4 New 25mL AcroSeal packaging 4 Solvents Extra dry solvents 5-7 Solvents for biochemistry 7 Deuterated solvents 7 Organometallics Grignard reagents 8-10 Organoaluminiums 11 Organolithiums 11 Organosodiums 12 Organotins 12 Organozincs 12 Reagents in solution Amines 13 Boranes 13 Halides 14-15 Hydrides 15 Oxides 16 Silanes 16 Other reagents in solution 17 Organics Aldehydes 18 Amines 18 Epoxides 18 Halides 19 Phosphines 19 Silanes 19 Other organics 20 How to use AcroSeal packaging 21 Alphabetical index 22-23 2 Introduction AcroSeal packaging: drier reagents for longer When using air- and moisture-sensitive solvents and reagents, it is essential that these products are not only as dry as possible when you first use them, but they should remain dry in storage as well. Through the innovative quadrant-style screw cap and specially designed septum, AcroSeal packaging ensures that you have access to high-quality and low-moisture products every use, guaranteeing improved yield and consistency of your research experiments while reducing chemical waste. AcroSeal packaging highlights New septum developed from a polymeric elastomer with an inert fluoropolymer-coated surface, preserves product quality for longer with better re-seal around needle punctures. -
Electrodeposition of Magnesium and Beryllium from Organic Baths
NASA CR-111850 ELECTRODEPOSITION OF MAGNESIUM AND BERYLLIUM FROM ORGANIC BATHS by Abner Brenner and John L. Sligh Prepared under Purchase Request L-37,566 by NATIONAL BUREAU OF STANDARDS Washington, DC 20234 for NATIONAL URONAUTICS AND SPACE ADMINISTWTION ELECTRODEPOSITION OF MAGNESIUM AND BERYLLIUM FROM 0,RGANIC BATHS Abner Brenner and John Le Sligh National Bureau of Standards, Washington, D. C. 20234 ABSTRACT Solutions that are feasible for electrodepositing magnesium were prepared from Grignard reagents with the addition of boranes in ether solutions. A typical bath consisted of methylmagnesium chloride, 3-molar9 (dissolved in tetrahydrofuran) and l-molar in triethylboron. The deposits were white, ductile and contained at least 99% of Mg. Cathode and anode current efficiencies were 100%. A similar beryllium plating solution, prepared with beryllium dimethyl and decaborane, yielded dark grey, coherent deposits containing 85% to 90% beryllium. KEY WORDS: Magnesium, electrodeposition of; Beryllium, electrodeposition of; nonaqueous plating baths; Grignard reagents; Beryllium dimethyl; Beryllium azide; Beryllium thiocyanate, decaborane; triethylboron; Organic plating baths. ELECTRODEPOSITION OF MAGNESIUM AND BERYLLIUM FROM ORGANIC BATHS Abner Brenner and John Le Sligh National Bureau of Standards, Washington, D. C. 20234 I e INTRODUCTION The chief interest in electrodepositing the light structural metals, beryllium, magnesium, and aluminum is for the purpose of electroforming light-weight engineering components of complex shape or precise dimen- sions that are needed in satellites. These metals are too active to be electrodeposited from aqueous solutions, hence, organic baths must be used. Of the three metals, aluminum is the only one that has been suc- cessfully electrodeposited and used in pilot-scale investigations. -
The Hazardous Substances and Waste Dangerous Goods Regulations
1 HAZARDOUS SUBSTANCES AND WASTE DANGEROUS GOODS E-10.2 REG 3 The Hazardous Substances and Waste Dangerous Goods Regulations being Chapter E-10.2 Reg 3 (effective April 1, 1989) as amended by Saskatchewan Regulations 25/92, 107/92, 28/94, 3/95 and 63/2000. NOTE: This consolidation is not official. Amendments have been incorporated for convenience of reference and the original statutes and regulations should be consulted for all purposes of interpretation and application of the law. In order to preserve the integrity of the original statutes and regulations, errors that may have appeared are reproduced in this consolidation. 2 HAZARDOUS SUBSTANCES AND E-10.2 REG 3 WASTE DANGEROUS GOODS Table of Contents 1 Title 11 Decision to grant approval INTERPRETATION 12 Approval not assignable, exception 2 Interpretation 13 Duties of operator, owner HAZARDOUS SUBSTANCES 14 Prohibition re storage in above-ground tanks 3 Designation of hazardous substances 15 Prohibition re storage in underground tanks 16 Prohibition re storage in certain containers or DESIGNATION AS HAZARDOUS WASTES stockpiles 3.1 Designation of waste dangerous goods 17 Decommissioning as hazardous wastes TRANSFERAL OF WASTE DANGEROUS GOODS CHARACTERIZATION OF SUBSTANCES 18 Transferal of waste dangerous goods 4 Characteristics of certain hazardous substances EXEMPTION FROM REQUIREMENTS Appendix A 5 General Exemptions INDUSTRIAL HAZARDOUS SUBSTANCES 6 Underground storage facilities Appendix B 7 Above-ground storage facilities ACUTE HAZARDOUS SUBSTANCES 8 Storage in small containers Appendix C APPROVAL TO STORE ENVIRONMENTAL PERSISTENT OR 9 Approval to store CHRONIC HAZARDOUS SUBSTANCES APPROVAL TO CONSTRUCT Appendix D 10 Approval to construct WASTE DANGEROUS GOODS 3 HAZARDOUS SUBSTANCES AND WASTE DANGEROUS GOODS E-10.2 REG 3 CHAPTER E-10.2 REG 3 The Environmental Management and Protection Act Title 1 These regulations may be cited as The Hazardous Substances and Waste Dangerous Goods Regulations.