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834FX-A Black Flexible Epoxy, Thermally Conductive–Flame Retardant, Encapsulating and Potting Compound (Part A) MG Chemicals UK Limited Version No: A-1.01 Issue Date: 12/04/2019 Safety Data Sheet (Conforms to Regulation (EU) No 2015/830) Revision Date: 17/03/2020 L.REACH.GBR.EN SECTION 1 IDENTIFICATION OF THE SUBSTANCE / MIXTURE AND OF THE COMPANY / UNDERTAKING 1.1. Product Identifier Product name 834FX-A Synonyms SDS Code: 834FX-Part A, 834FX-450ML, 834FX-1.7L, 834FX-7.4ML, 834FX-40L Other means of identification Black Flexible Epoxy, Thermally Conductive–Flame Retardant, Encapsulating and Potting Compound (Part A) 1.2. Relevant identified uses of the substance or mixture and uses advised against Relevant identified uses epoxy resin Uses advised against Not Applicable 1.3. Details of the supplier of the safety data sheet Registered company name MG Chemicals UK Limited MG Chemicals (Head office) Heame House, 23 Bilston Street, Sedgely Dudley DY3 1JA United Address 9347 - 193 Street Surrey V4N 4E7 British Columbia Canada Kingdom Telephone +(44) 1663 362888 +(1) 800-201-8822 Fax Not Available +(1) 800-708-9888 Website Not Available www.mgchemicals.com Email [email protected] [email protected] 1.4. Emergency telephone number Association / Organisation Verisk 3E (Access code: 335388) Not Available Emergency telephone numbers +(44) 20 35147487 Not Available Other emergency telephone +(0) 800 680 0425 Not Available numbers SECTION 2 HAZARDS IDENTIFICATION 2.1. Classification of the substance or mixture Classification according to H411 - Chronic Aquatic Hazard Category 2, H302 - Acute Toxicity (Oral) Category 4, H315 - Skin Corrosion/Irritation Category 2, H319 - Eye Irritation regulation (EC) No 1272/2008 Category 2, H361 - Reproductive Toxicity Category 2, H317 - Skin Sensitizer Category 1 [CLP] [1] Legend: 1. Classified by Chemwatch; 2. Classification drawn from Regulation (EU) No 1272/2008 - Annex VI 2.2. Label elements Hazard pictogram(s) SIGNAL WORD WARNING Hazard statement(s) H411 Toxic to aquatic life with long lasting effects. H302 Harmful if swallowed. H315 Causes skin irritation. H319 Causes serious eye irritation. H361 Suspected of damaging fertility or the unborn child. H317 May cause an allergic skin reaction. Continued... Page 2 of 25 834FX-A Black Flexible Epoxy, Thermally Conductive–Flame Retardant, Encapsulating and Potting Compound (Part A) Supplementary statement(s) Not Applicable Precautionary statement(s) Prevention P201 Obtain special instructions before use. P280 Wear protective gloves/protective clothing/eye protection/face protection. P261 Avoid breathing mist/vapours/spray. P270 Do not eat, drink or smoke when using this product. P273 Avoid release to the environment. P272 Contaminated work clothing should not be allowed out of the workplace. Precautionary statement(s) Response P308+P313 IF exposed or concerned: Get medical advice/ attention. P302+P352 IF ON SKIN: Wash with plenty of water and soap. P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P333+P313 If skin irritation or rash occurs: Get medical advice/attention. P337+P313 If eye irritation persists: Get medical advice/attention. P362+P364 Take off contaminated clothing and wash it before reuse. P391 Collect spillage. P301+P312 IF SWALLOWED: Call a POISON CENTER/doctor/physician/first aider/if you feel unwell. P330 Rinse mouth. Precautionary statement(s) Storage P405 Store locked up. Precautionary statement(s) Disposal P501 Dispose of contents/container in accordance with local regulations. 2.3. Other hazards REACh - Art.57-59: The mixture does not contain Substances of Very High Concern (SVHC) at the SDS print date. SECTION 3 COMPOSITION / INFORMATION ON INGREDIENTS 3.1.Substances See 'Composition on ingredients' in Section 3.2 3.2.Mixtures 1.CAS No 2.EC No %[weight] Name Classification according to regulation (EC) No 1272/2008 [CLP] 3.Index No 4.REACH No 1.25085-99-8 2.500-033-5 bisphenol A/ diglycidyl ether Eye Irritation Category 2, Chronic Aquatic Hazard Category 2, Skin Sensitizer Category 1, Skin 22 3.603-074-00-8 resin, liquid Corrosion/Irritation Category 2; H319, H411, H317, H315 [2] 4.01-2119456619-26-XXXX 1.21645-51-2 2.244-492-7 22 alumina hydrate EUH210 [1] 3.Not Available 4.01-2119529246-39-XXXX 1.68333-79-9 2.269-789-9 19 ammonium polyphosphate Chronic Aquatic Hazard Category 4; H413 [1] 3.Not Available 4.01-2120090300-70-XXXX 1.1344-28-1. 2.215-691-6 14 aluminium oxide EUH210 [1] 3.Not Available 4.01-2119529248-35-XXXX 1.41638-13-5 2.Not Available dipropylene glycol diglycidyl 8 Skin Corrosion/Irritation Category 2, Skin Sensitizer Category 1; H315, H317, EUH205, EUH019 [1] 3.Not Available ether 4.Not Available 1.68609-97-2 2.271-846-8 7 (C12-14)alkylglycidyl ether Skin Sensitizer Category 1, Skin Corrosion/Irritation Category 2; H317, H315 [2] 3.603-103-00-4 4.01-2119485289-22-XXXX Continued... Page 3 of 25 834FX-A Black Flexible Epoxy, Thermally Conductive–Flame Retardant, Encapsulating and Potting Compound (Part A) 1.12767-90-7 2.215-566-6 3.Not Available Eye Irritation Category 2, Chronic Aquatic Hazard Category 1, Acute Aquatic Hazard 5 zinc borate 4.01-0000016699-53- Category 1, Reproductive Toxicity Category 2 H319, H410, H400, H361 XXXX|01-2119691658-19- XXXX|01-2120773328-46-XXXX 1.25068-38-6 2.216-823-5 Eye Irritation Category 2, Skin Sensitizer Category 1, Skin Corrosion/Irritation Category 2; H319, 1 bisphenol A diglycidyl ether 3.603-073-00-2|603-074-00-8 H317, H315 [2] 4.01-2119456619-26-XXXX 1.68037-01-4 2.500-183-1 1-decene homopolymer, 0.6 Chronic Aquatic Hazard Category 4; H413 [1] 3.Not Available hydrogenated 4.01-2119486452-34-XXXX 1.64741-65-7. 2.265-067-2 naphtha petroleum, heavy Flammable Liquid Category 3, Aspiration Hazard Category 1, Specific target organ toxicity - single 0.4 3.649-275-00-4 alkylate exposure Category 3 (narcotic effects); H226, H304, H336 [1] 4.01-2120009436-62-XXXX 1.1333-86-4 2.215-609-9 3.Not Available 0.4 carbon black Carcinogenicity Category 2; H351 [1] 4.01-2119384822-32- XXXX|01-2120767622-50- XXXX|01-0000016864-62-XXXX Legend: 1. Classified by Chemwatch; 2. Classification drawn from Regulation (EU) No 1272/2008 - Annex VI; 3. Classification drawn from C&L; * EU IOELVs available SECTION 4 FIRST AID MEASURES 4.1. Description of first aid measures If this product comes in contact with the eyes: Wash out immediately with fresh running water. Eye Contact Ensure complete irrigation of the eye by keeping eyelids apart and away from eye and moving the eyelids by occasionally lifting the upper and lower lids. Seek medical attention without delay; if pain persists or recurs seek medical attention. Removal of contact lenses after an eye injury should only be undertaken by skilled personnel. If skin contact occurs: Immediately remove all contaminated clothing, including footwear. Skin Contact Flush skin and hair with running water (and soap if available). Seek medical attention in event of irritation. If fumes, aerosols or combustion products are inhaled remove from contaminated area. Inhalation Other measures are usually unnecessary. Immediately give a glass of water. Ingestion First aid is not generally required. If in doubt, contact a Poisons Information Centre or a doctor. 4.2 Most important symptoms and effects, both acute and delayed See Section 11 4.3. Indication of any immediate medical attention and special treatment needed for phosphate salts intoxication: All treatments should be based on observed signs and symptoms of distress in the patient. Consideration should be given to the possibility that overexposure to materials other than this product may have occurred. Ingestion of large quantities of phosphate salts (over 1.0 grams for an adult) may cause an osmotic catharsis resulting in diarrhoea and probable abdominal cramps. Larger doses such as 4-8 grams will almost certainly cause these effects in everyone. In healthy individuals most of the ingested salt will be excreted in the faeces with the diarrhoea and, thus, not cause any systemic toxicity. Doses greater than 10 grams hypothetically may cause systemic toxicity. Treatment should take into consideration both anionic and cation portion of the molecule. All phosphate salts, except calcium salts, have a hypothetical risk of hypocalcaemia, so calcium levels should be monitored. Treat symptomatically. Manifestation of aluminium toxicity include hypercalcaemia, anaemia, Vitamin D refractory osteodystrophy and a progressive encephalopathy (mixed dysarthria-apraxia of speech, asterixis, tremulousness, myoclonus, dementia, focal seizures). Bone pain, pathological fractures and proximal myopathy can occur. Symptoms usually develop insidiously over months to years (in chronic renal failure patients) unless dietary aluminium loads are excessive. Serum aluminium levels above 60 ug/ml indicate increased absorption. Potential toxicity occurs above 100 ug/ml and clinical symptoms are present when levels exceed 200 ug/ml. Deferoxamine has been used to treat dialysis encephalopathy and osteomalacia. CaNa2EDTA is less effective in chelating aluminium. [Ellenhorn and Barceloux: Medical Toxicology] Copper, magnesium, aluminium, antimony, iron, manganese, nickel, zinc (and their compounds) in welding, brazing, galvanising or smelting operations all give rise to thermally produced particulates of smaller dimension than may be produced if the metals are divided mechanically. Where insufficient ventilation or respiratory protection is available these particulates may produce 'metal fume fever' in workers from an acute or long term exposure. Onset occurs in 4-6 hours generally on the evening following exposure. Tolerance develops in workers but may be lost over the weekend. (Monday Morning Fever) Pulmonary function tests may indicate reduced lung volumes, small airway obstruction and decreased carbon monoxide diffusing capacity but these abnormalities resolve after several months. Although mildly elevated urinary levels of heavy metal may occur they do not correlate with clinical effects.