Atmos. Chem. Phys., 21, 2105–2124, 2021 https://doi.org/10.5194/acp-21-2105-2021 © Author(s) 2021. This work is distributed under the Creative Commons Attribution 4.0 License. Concentrations, particle-size distributions, and dry deposition fluxes of aerosol trace elements over the Antarctic Peninsula in austral summer Songyun Fan1, Yuan Gao1, Robert M. Sherrell2, Shun Yu1, and Kaixuan Bu2 1Department of Earth and Environmental Sciences, Rutgers University, Newark, NJ 07102, USA 2Department of Marine and Coastal Sciences, Rutgers University, New Brunswick, NJ 08901, USA Correspondence: Yuan Gao (
[email protected]) Received: 1 July 2020 – Discussion started: 26 August 2020 Revised: 3 December 2020 – Accepted: 8 December 2020 – Published: 12 February 2021 Abstract. Size-segregated particulate air samples were col- sition processes may play a minor role in determining trace lected during the austral summer of 2016–2017 at Palmer element concentrations in surface seawater over the conti- Station on Anvers Island, western Antarctic Peninsula, to nental shelf of the western Antarctic Peninsula. characterize trace elements in aerosols. Trace elements in aerosol samples – including Al, P, Ca, Ti, V, Mn, Ni, Cu, Zn, Ce, and Pb – were determined by total digestion and a 1 Introduction sector field inductively coupled plasma mass spectrometer (SF-ICP-MS). The crustal enrichment factors (EFcrust) and Aerosols affect the climate through direct and indirect ra- k-means clustering results of particle-size distributions show diative forcing (Kaufman et al., 2002). The extent of such that these elements are derived primarily from three sources: forcing depends on both physical and chemical properties (1) regional crustal emissions, including possible resuspen- of aerosols, including particle size and chemical composi- sion of soils containing biogenic P, (2) long-range transport, tion (Pilinis et al., 1995).