Effect of Drying on Physicochemical Characteristics of Bhut Jolokia (Chilli Pepper)
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United States Patent Office Patented Feb
3,646,061 United States Patent Office Patented Feb. 29, 1972 2 3,646,061 Since the alcohol such as methanol, ethanol, propanol, METHOD OF PREPARENG N-ALKOXALYL AND N-FORMYL DERVATIVES OF oz-AMNO ACID iso-propanol and n-butanol, acts as a reagent as well as a ESTERS solvent, the alcohol is used in an excess amount, usually Itsutoshi Maeda, Kanagawa-ken, Hideshi Miyayashiki, 10-50 moles per mole of amino acid. Tokyo, and Ryonosuke Yoshida, Kanagawa-ken, Japan, 5 Formic acid or oxalic acid is usually employed in an assignors to Ajinomoto Co., Inc., Tokyo, Japan amount of 1-5 moles, preferably 2-3 moles per mole of No Drawing. Filed May 29, 1969, Ser. No. 829,139 amino acid. Claims priority, application Japan, June 10, 1968, The reaction proceeds easily when the mixture of amino 43/39,796; Aug. 10, 1968, 43/56,916 acid, alcohol and formic or oxalic acid is heated at a Int, CI, C07d 27/60; C07c 101/00 10 temperature within the range of 80 to 200° C. U.S. C. 260-326.14 T 6 Claims When formic acid is used, the product is a formylamino acid ester, however, when oxalic acid is used esters of the N-formylamino acid are also formed. At a ratio of which ABSTRACT OF THE DISCLOSURE depends mainly on the reaction temperature. Alkyl esters of alkoxalylamino or N-formylamino acids In general, the yield of alkoxalylamino acid ester de are produced in high yields directly by heating the acids creases and that of N-formylamino acid ester increases with oxalic acid or formic acid and a lower alkyl alcohol with increasing reaction temperature, when the reaction at 80-200 C. -
Oxalic Acid 1
MSDS Number: O6044 * * * * * Effective Date: 03/28/11 * * * * * Supercedes: 11/21/08 OXALIC ACID 1. Product Identification Synonyms: Ethanedioic acid, dihydrate; oxalic acid dihydrate CAS No.: 144-62-7 (Anhydrous); 6153-56-6 (Dihydrate) Molecular Weight: 126.07 Chemical Formula: HOOCCOOH.2H2O Product Codes: J.T. Baker: 0229, 0230 Macron: 2752, 7296 2. Composition/Information on Ingredients Ingredient CAS No Percent Hazardous --------------------------------------- ------------ ------------ --------- Oxalic Acid 144-62-7 99 - 100% Yes 3. Hazards Identification Emergency Overview -------------------------- POISON! DANGER! MAY BE FATAL IF SWALLOWED. CORROSIVE. CAUSES SEVERE IRRITATION AND BURNS TO SKIN, EYES, AND RESPIRATORY TRACT. HARMFUL IF INHALED OR ABSORBED THROUGH SKIN. MAY CAUSE KIDNEY DAMAGE. SAF-T-DATA(tm) Ratings (Provided here for your convenience) ----------------------------------------------------------------------------------------------------------- Health Rating: 4 - Extreme (Poison) Flammability Rating: 1 - Slight Reactivity Rating: 1 - Slight Contact Rating: 3 - Severe (Corrosive) Lab Protective Equip: GOGGLES & SHIELD; LAB COAT & APRON; VENT HOOD; PROPER GLOVES Storage Color Code: White (Corrosive) ----------------------------------------------------------------------------------------------------------- Potential Health Effects ---------------------------------- Oxalic acid is corrosive to tissue. When ingested, oxalic acid removes calcium from the blood. Kidney damage can be expected as the calcium is removed from the -
Production of Oxalic Acid by Aspergillus Niger
ProductionINDONESIAN of Oxalic MINING Acid By JOURNAL Aspergillus Vol. Niger, 12, No.Sri 2,Handayani June 2009 and : 85 Suratman - 89 PRODUCTION OF OXALIC ACID BY ASPERGILLUS NIGER Sri Handayani and Suratman R&D Centre for Mineral and Coal Technology Jl. Jend. Sudirman 623 Bandung 40211 Ph.62-22-6030483, fax. 62-22-6003373, e-mail: [email protected] ABSTRACT Oxalic acid has been suggested to be essential in the metal leaching processes by Aspergillus niger. The ability of Aspergillus niger strain to produce a high amount of oxalic acid on glucose and sucrose media was investigated. The experimental results show that glucose is favorable for oxalic acid biosynthesis which can produce 14.47 g/L oxalic acid compared to 7.09 g/L oxalic acid on sucrose medium. The production pattern, however, were identical on both substrates. The main drawback of this fermentation was the low yield attained (75.47 % from theoretical yield) probably because some of glucose was oxidized to gluconic acid at the beginning of fermentation, and due to some limitation of growing the A. niger in shake flask condition because pH of the culture cannot be fully controlled in shake flask system. Therefore, batch culture in fully controlled fermentor can be carried out as further steps of experiment after shake flask. Keywords : oxalic acid, biosynthesis, Aspergillus niger, glucose, sucrose search was conducted to get an optimum condi- INTRODUCTION tion for oxalic acid production by the strain of As- pergillus niger, which obtained from the quartz Oxalic acid is known as organic acid used as pre- sample of the Karimum island. -
Oxalic Acid Metabolism of Microbial
View metadata, citation and similar papers at core.ac.uk brought to you by CORE provided by Publications of the IAS Fellows DOWNLOADED FROM MICROBIAL METABOLISM OF OXALIC ACID William B. Jakoby and J. V. Bhat 1958. MICROBIAL METABOLISM OF OXALIC ACID. Microbiol. Mol. Biol. mmbr.ASM.ORG - Rev. 22(2):75-80. Updated information and services can be found at: http://mmbr.asm.org July 19, 2010 These include: CONTENT ALERTS Receive: RSS Feeds, eTOCs, free email alerts (when new articles cite this article), more>> Information about commercial reprint orders: http://journals.asm.org/misc/reprints.dtl To subscribe to an ASM journal go to: http://journals.asm.org/subscriptions/ DOWNLOADED FROM MICROBIAL METABOLISM OF OXALIC ACID WILLIAM B. JAKOBYl AND J. V. BHAT2 Although the synthesis of urea by Wbhler in study of compounds supporting bacterial growth, 1828 is credited with dispelling the notion of Den Dooren de Jong (7) and Ayers et al. (8) vital forces involved in the synthesis of organic were unable to obtain growth of a variety of chemicals, the first organic compound to be as- saprophytic bacteria when oxalate was the sole mmbr.ASM.ORG - sembled from inorganic matter is the subject of carbon source. Much of the literature pertaining the present review. Legend has it that because to attempts at demonstrating bacterial utiliza- of the empirical formula, written as C203 H20 tion of oxalate has been reviewed (9). at the time, oxalic acid prepared from cyanogen To date several organisms have been isolated by W6hler in 1824 was judged to be "inorganic." which are able to grow on a medium containing More pertinent here is the interest of the micro- only inorganic salts, a nitrogen source, and biologist and biochemist in oxalic acid as the oxalate. -
Reimer Seeds Catalog
LCTRONICLCTRONIC CATALOGCATALOG Drying Hot Peppers HP320‐20 ‐ Achar Hot Peppers HP321‐10 ‐ Aci Sivri Hot Peppers 85 days. Capsicum annuum. Open 85 days. Capsicum annuum. Open Pollinated. The plant produces good yields Pollinated. The plant produces good yields of 3 ¼" long by 1" wide hot peppers. Peppers of 7 ½" long by ½" wide Cayenne type hot are hot, have medium thin flesh, and turn peppers. Peppers are medium hot, have from green to deep red when mature. The medium thin flesh, and turn from light plant has green stems, green leaves, and yellowish‐green to red when mature. The white flowers. Excellent for pickling and plant has green stems, green leaves, and seasoning spice. A variety from India. United white flowers. Excellent drying, pickling, and States Department of Agriculture, PI 640826. seasoning powder. An heirloom variety from Scoville Heat Units: 27,267. Turkey. HP21‐10 ‐ Afghan Hot Peppers HP358‐10 ‐ African Fish Hot Peppers 85 days. Capsicum annuum. Open 85 days. Capsicum annuum. Open Pollinated. The plant produces good yields Pollinated. The plant produces good yields of 3" long by ½" wide Cayenne hot peppers. of 1 ½" long by ½" wide hot peppers. Peppers are very hot, have medium thin Peppers are medium‐hot, have medium thin flesh, and turn from green to red when flesh, and turn from cream white with green mature. The plant has green stems, green stripes, to orange with brown stripes, then leaves, and white flowers. Excellent for to red when mature. The plant has Oriental cuisine and for making hot pepper variegated leaves. An African‐American flakes and seasoning spice powder. -
APPENDIX G Acid Dissociation Constants
harxxxxx_App-G.qxd 3/8/10 1:34 PM Page AP11 APPENDIX G Acid Dissociation Constants § ϭ 0.1 M 0 ؍ (Ionic strength ( † ‡ † Name Structure* pKa Ka pKa ϫ Ϫ5 Acetic acid CH3CO2H 4.756 1.75 10 4.56 (ethanoic acid) N ϩ H3 ϫ Ϫ3 Alanine CHCH3 2.344 (CO2H) 4.53 10 2.33 ϫ Ϫ10 9.868 (NH3) 1.36 10 9.71 CO2H ϩ Ϫ5 Aminobenzene NH3 4.601 2.51 ϫ 10 4.64 (aniline) ϪO SNϩ Ϫ4 4-Aminobenzenesulfonic acid 3 H3 3.232 5.86 ϫ 10 3.01 (sulfanilic acid) ϩ NH3 ϫ Ϫ3 2-Aminobenzoic acid 2.08 (CO2H) 8.3 10 2.01 ϫ Ϫ5 (anthranilic acid) 4.96 (NH3) 1.10 10 4.78 CO2H ϩ 2-Aminoethanethiol HSCH2CH2NH3 —— 8.21 (SH) (2-mercaptoethylamine) —— 10.73 (NH3) ϩ ϫ Ϫ10 2-Aminoethanol HOCH2CH2NH3 9.498 3.18 10 9.52 (ethanolamine) O H ϫ Ϫ5 4.70 (NH3) (20°) 2.0 10 4.74 2-Aminophenol Ϫ 9.97 (OH) (20°) 1.05 ϫ 10 10 9.87 ϩ NH3 ϩ ϫ Ϫ10 Ammonia NH4 9.245 5.69 10 9.26 N ϩ H3 N ϩ H2 ϫ Ϫ2 1.823 (CO2H) 1.50 10 2.03 CHCH CH CH NHC ϫ Ϫ9 Arginine 2 2 2 8.991 (NH3) 1.02 10 9.00 NH —— (NH2) —— (12.1) CO2H 2 O Ϫ 2.24 5.8 ϫ 10 3 2.15 Ϫ Arsenic acid HO As OH 6.96 1.10 ϫ 10 7 6.65 Ϫ (hydrogen arsenate) (11.50) 3.2 ϫ 10 12 (11.18) OH ϫ Ϫ10 Arsenious acid As(OH)3 9.29 5.1 10 9.14 (hydrogen arsenite) N ϩ O H3 Asparagine CHCH2CNH2 —— —— 2.16 (CO2H) —— —— 8.73 (NH3) CO2H *Each acid is written in its protonated form. -
Content of Capsaicinoids and Physicochemical Characteristics of Manzano Hot Pepper Grown in Greenhouse
Available online: www.notulaebotanicae.ro Print ISSN 0255-965X; Electronic 1842-4309 Notulae Botanicae Horti AcademicPres Not Bot Horti Agrobo, 2019, 47(1):119-127. DOI:10.15835/nbha47111241 Agrobotanici Cluj-Napoca Original Article Content of Capsaicinoids and Physicochemical Characteristics of Manzano Hot Pepper Grown in Greenhouse Mario PÉREZ-GRAJALES 1, María T. MARTÍNEZ-DAMIÁN 1*, Oscar CRUZ-ALVAREZ 2, Sandra M. POTRERO-ANDRADE 1, Aureliano PEÑA-LOMELÍ 1, Víctor A. GONZÁLEZ-HERNÁNDEZ 3, Angel VILLEGAS-MONTER 3 1Autonomous University Chapingo, Department of Plant Science, Km. 38.5 Mexico-Texcoco Highway, CP 56230 Chapingo, State of Mexico, Mexico; [email protected] ; [email protected] ; [email protected] ; [email protected] (*corresponding author) 2Autonomous University of Chihuahua, Faculty of Agrotechnological Sciences, Pascual Orozco Avenue, Campus 1, Santo Niño, CP 31350 Chihuahua, Mexico; [email protected] 3Postgraduate College, Campus Montecillo, Texcoco, CP 56230 Montecillo, State of Mexico, Mexico; [email protected] ; [email protected] Abstract The hotness of the chili fruit ( Capsicum spp.) is mainly due to the presence of capsaicinoids (capsaicin, nordihydrocapsaicin and dihydrocapsaicin). The aim of the present research was to evaluate the content of capsaicinoids and characteristics of physicochemical quality in fruits of manzano hot pepper grown in the greenhouse. The experimental design used was completely randomized with 3 and 4 replications. The parameters evaluated were total capsaicinoids, vitamin C, total carotenoids (TC), total soluble solids (TSS), titratable acidity, pH, firmness and color of the fruit. Among the hybrids with the highest content of total capsaicinoids and vitamin C, L4XL8 and L5XL7 (27 371 and 21 700 SHU, respectively) stand out as well as L2XL5 with 809.35 mg 100 g -1. -
Dissociation Constants of Oxalic Acid in Aqueous Sodium Chloride and Sodium Trifluoromethanesulfonate Media to 175 °C
View metadata, citation and similar papers at core.ac.uk brought to you by CORE provided by DigitalCommons@University of Nebraska University of Nebraska - Lincoln DigitalCommons@University of Nebraska - Lincoln Earth and Atmospheric Sciences, Department Papers in the Earth and Atmospheric Sciences of 1998 Dissociation Constants of Oxalic Acid in Aqueous Sodium Chloride and Sodium Trifluoromethanesulfonate Media to 175 °C Richard Kettler University of Nebraska-Lincoln, [email protected] David J. Wesolowski Oak Ridge National Laboratory Donald A. Palmer Oak Ridge National Laboratory Follow this and additional works at: https://digitalcommons.unl.edu/geosciencefacpub Part of the Earth Sciences Commons Kettler, Richard; Wesolowski, David J.; and Palmer, Donald A., "Dissociation Constants of Oxalic Acid in Aqueous Sodium Chloride and Sodium Trifluoromethanesulfonate Media to 175 °C" (1998). Papers in the Earth and Atmospheric Sciences. 135. https://digitalcommons.unl.edu/geosciencefacpub/135 This Article is brought to you for free and open access by the Earth and Atmospheric Sciences, Department of at DigitalCommons@University of Nebraska - Lincoln. It has been accepted for inclusion in Papers in the Earth and Atmospheric Sciences by an authorized administrator of DigitalCommons@University of Nebraska - Lincoln. J. Chem. Eng. Data 1998, 43, 337-350 337 Dissociation Constants of Oxalic Acid in Aqueous Sodium Chloride and Sodium Trifluoromethanesulfonate Media to 175 °C Richard M. Kettler*,† Department of Geology, University of Nebraska, Lincoln, Nebraska 68588-0340 David J. Wesolowski‡ and Donald A. Palmer§ Chemical and Analytical Sciences Division, Oak Ridge National Laboratory, Oak Ridge, Tennessee 37831-6110 The first and second molal dissociation constants of oxalic acid were measured potentiometrically in a concentration cell fitted with hydrogen electrodes. -
Atmospheric Production of Oxalic Acid/Oxalate and Nitric Acid/Nitrate in the Tampa Bay Airshed: Parallel Pathways
ARTICLE IN PRESS Atmospheric Environment 41 (2007) 4258–4269 www.elsevier.com/locate/atmosenv Atmospheric production of oxalic acid/oxalate and nitric acid/nitrate in the Tampa Bay airshed: Parallel pathways P. Kalyani Martinelango, Purnendu K. DasguptaÃ, Rida S. Al-Horr1 Department of Chemistry and Biochemistry, Texas Tech University, Lubbock, TX 79409-1061, USA Received 9 February 2006; received in revised form 1 May 2006; accepted 2 May 2006 Abstract Oxalic acid is the dominant dicarboxylic acid (DCA), and it constitutes up to 50% of total atmospheric DCAs, especially in non-urban and marine atmospheres. A significant amount of particulate H2Ox/oxalate (Ox) occurred in the coarse particle fraction of a dichotomous sampler, the ratio of oxalate concentrations in the PM10 to PM2.5 fractions ranged from 1 to 2, with mean7sd being 1.470.2. These results suggest that oxalate does not solely originate in the gas phase and condense into particles. Gaseous H2Ox concentrations are much lower than particulate Ox concentrations and are well correlated with HNO3, HCHO, and O3, supporting a photochemical origin. Of special relevance to the Bay Region Atmospheric Chemistry Experiment (BRACE) is the extent of nitrogen deposition in the Tampa Bay estuary. Hydroxyl radical is primarily responsible for the conversion of NO2 to HNO3, the latter being much more easily deposited. Hydroxyl radical is also responsible for the aqueous phase formation of oxalic acid from alkenes. Hence, we propose that an estimate of dOH can be obtained from H2Ox/Ox production rate and we accordingly show that the product of total oxalate concentration and NO2 concentration approximately predicts the total nitrate concentration during the same period. -
Bioactive Extracts of Capsicum Chinense in the Northern Amazon, Chemical Engineering Transactions, 75, 433-438 DOI:10.3303/CET1975073 434
433 A publication of CHEMICAL ENGINEERING TRANSACTIONS VOL. 75, 2019 The Italian Association of Chemical Engineering Online at www.cetjournal.it Guest Editors: Sauro Pierucci, Laura Piazza Copyright © 2019, AIDIC Servizi S.r.l. ISBN 978-88-95608-72-3; ISSN 2283-9216 DOI: 10.3303/CET1975073 Bioactive Extracts of Capsicum chinense in the Northern Amazon a a b b Karla S. Morais , Bruna S. Morais , Lucianne B. O. Vilarinho , Poliana C. Chagas , Ana C. G. Reis Meloc, Jacqueline A. Takahashid, Antonio Alves de M. Filhob,e aDepartment of Health, IFRR, Boa Vista Campus, CEP 69.303-340, Boa Vista-RR-Brazil. bPost-Graduate in Biotechnology and Biodiversity Program, Federal University of Roraima, Paricarana Campus, CEP 69304-000, Boa Vista, Roraima. cPost graduate in Natural Resources Program, Federal University of Roraima, Boa Vista-RR-Brazil. dDepartament of Chemistry, Institute of Exact Sciences, Federal University of Minas Gerais, CEP 31270-901, Belo Horizonte, Minas Gerais, Brazil. eDepartament of Chemistry, UFRR, Paricarana Campus, CEP 69304-000, Boa Vista-RR-Brazil. [email protected] The objective of this work was to analyze the bioactive potential of hexane and methanol extracts of fruits of Capsicum spp., a kind of pepper collected in Roraima, Brazil, against the yeast Candida albicans, as well as antioxidant activity and antiacetylcholinesterase inhibition. The antioxidant activity of the methanol extract of the fruits was 82%. The antiacetylcholinesterase activity was high in the hexane extract reaching 71%. Hexane extract of the fruits did not present inhibition for Candida albicans. The present study demonstrated the efficacy of Capsicum spp. as a natural antioxidant and the presence of active chemical constituents that can aid in the treatment of neurodegenerative diseases such as Alzheimer's. -
“Jalapeño” “Habanero”
https://www.seedsavers.org/search? keywords=wisconsin%20lakes https://www.seedsavers.org/jalapeno-traveler- strain-pepper https://www.seedsavers.org/red-habanero- pepper https://www.seedsavers.org/learn#growing- Only collect seed from isolated guides peppers when growing more than one DIY isolation bags: http://www.realseeds.co.uk/ variety. pepperseedsaving.html “Wisconsin Lakes” For ALL pepper varieties, harvest http://wlkr.org/2009/10/02/saving-seeds-from- peppers/ peppers that are fully ripe, red, and (Capsicum annuum) starting to soften before collecting seed. “Jalapeño” Slice open pepper and separate seeds (Capsicum annuum) from the core. “Habanero” If saving seed from a hot pepper, use gloves and do not touch your eyes or (Capsicum chinense) breathe in fumes. Rinse seeds well and spread on a coffee filter, screen or newsprint to dry. Fully dry pepper seeds will snap in half when ready for storage in airtight containers. Pepper seeds will last up to 3 years when stored in a cool, dry location. 101 Second Street SE, Rochester, MN 55904 02-2020 507.328.2309 | www.rplmn.org Cut peppers from the plant with scissors or Cross-pollination will result in seed knife to prevent breaking branches and that won’t produce the same type of damaging the plant. fruit as the parent plant. To avoid cross-pollination, grow only one variety in a species. Sweet peppers are eaten raw in salads Grow “Wisconsin Lakes” or Start seeds indoors, planting them ¼ and sandwiches. “Jalapeño” as they are both Capsicum inch deep in potting soil. annuum. Spicier peppers are used in salsas and can Keep soil warm and moist, in an area be preserved by pickling. -
Effect of Organic Fertilization on Capsaicin Content in Trinidad
253 A publication of CHEMICAL ENGINEERING TRANSACTIONS VOL. 58, 2017 The Italian Association of Chemical Engineering Online at www.aidic.it/cet Guest Editors: Remigio Berruto, Pietro Catania, Mariangela Vallone Copyright © 2017, AIDIC Servizi S.r.l. ISBN 978-88-95608-52-5; ISSN 2283-9216 DOI: 10.3303/CET1758043 Effect of Organic Fertilization on Capsaicin Content in Trinidad Scorpion (Capsicum Chinese) Peppers: Preliminary Results Niccolò Pampuroa*, Vincenzo Tebaldoa, Debora Fabbrib, Paola Calzab, Maria a a Giulia Faga , Eugenio Cavallo a Institute for Agricultural and Earth Moving Machines (IMAMOTER), Italian National Research Council (CNR) – Strada delle Cacce, 73 – 10135 Torino (TO), Italy b Department of Chemistry, University of Turin - Via P. Giuria, 5/7 - 10125 Torino (TO), Italy [email protected] Capsaicin is a pungent capsaicinoid responsible for the “hot and spicy” taste of chili peppers and pepper extracts. It is a valuable pharmacological agent with several therapeutic applications in controlling pain and inflammation. Emerging studies show that it displays patent anti-tumor activity in several human cancers. A mesocosm experiment was set for testing the influence of the organic fertilization on capsaicin content in Capsicum chinense cv Trinidad Scorpion. Pelletized organic fertilizer from the composted solid fraction of pig slurry (OF) was compared to a mineral fertilizer (MF) and a mixture of organic pellets and mineral fertilizer (OMF). The study investigated the effects of a single application of 2 different doses of nitrogen (38 kg ha-1 and 76 kg ha-1). Peppers were grown and fertilized according to the different treatments and after 500 days from the seeding fruits were collected and their capsaicin content was detected by means of the High Pressure Liquid Chromatography (HPLC) analysis.