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New Mineral Names*
American Mineralogist, Volume 96, pages 1654–1661, 2011 New Mineral Names* PAULA C. PIILONEN,1,† RALPH ROWE,1 GLENN POIRIER,1 AND KIMBERLY T. TAIT2 1Mineral Sciences Division, Canadian Museum of Nature, P.O. Box 3443, Station D, Ottawa, Ontario K1P 6P4, Canada 2Department of Natural History, Royal Ontario Museum,100 Queen’s Park, Toronto, Ontario M5S 2C6, Canada NEW MINERALS The streak is white and the Mohs hardness is estimated to be about 1½. Thin crystal fragments are flexible, but not elastic. The fracture is irregular and there are three cleavage directions: {001} AFMITE* perfect, {010} and {110} good. The mineral is non-fluorescent A.R. Kampf, S.J. Mills, G.R Rossman, I.M. Steele, J.J. Pluth, under all wavelengths of ultraviolet radiation. The density mea- sured by sink-float in aqueous solution of sodium polytungstate and G. Favreau (2011) Afmite, Al3(OH)4(H2O)3(PO4) is 2.39(3) g/cm3. The calculated density, based on the empirical (PO3OH)·H2O, a new mineral from Fumade, Tarn, France: de- 3 scription and crystal structure. Eur. J. Mineral., 23, 269–277. formula and single-crystal cell, is 2.391 g/cm and that for the ideal formula is 2.394 g/cm3. Afmite is found at Fumade, Castelnau-de-Brassac, Tarn, Electron microprobe analyses provided Al2O3 40.20 and France (43°39′30″N, 2°29′58″E). The phosphates occur in P2O5 38.84 wt% and CHN analyses provided H2O 25.64 wt%, fractures and solution cavities in shale/siltstone exposed in total 103.68 wt%. -
A Review of the Structural Architecture of Tellurium Oxycompounds
Mineralogical Magazine, May 2016, Vol. 80(3), pp. 415–545 REVIEW OPEN ACCESS A review of the structural architecture of tellurium oxycompounds 1 2,* 3 A. G. CHRISTY ,S.J.MILLS AND A. R. KAMPF 1 Research School of Earth Sciences and Department of Applied Mathematics, Research School of Physics and Engineering, Australian National University, Canberra, ACT 2601, Australia 2 Geosciences, Museum Victoria, GPO Box 666, Melbourne, Victoria 3001, Australia 3 Mineral Sciences Department, Natural History Museum of Los Angeles County, 900 Exposition Boulevard, Los Angeles, CA 90007, USA [Received 24 November 2015; Accepted 23 February 2016; Associate Editor: Mark Welch] ABSTRACT Relative to its extremely low abundance in the Earth’s crust, tellurium is the most mineralogically diverse chemical element, with over 160 mineral species known that contain essential Te, many of them with unique crystal structures. We review the crystal structures of 703 tellurium oxysalts for which good refinements exist, including 55 that are known to occur as minerals. The dataset is restricted to compounds where oxygen is the only ligand that is strongly bound to Te, but most of the Periodic Table is represented in the compounds that are reviewed. The dataset contains 375 structures that contain only Te4+ cations and 302 with only Te6+, with 26 of the compounds containing Te in both valence states. Te6+ was almost exclusively in rather regular octahedral coordination by oxygen ligands, with only two instances each of 4- and 5-coordination. Conversely, the lone-pair cation Te4+ displayed irregular coordination, with a broad range of coordination numbers and bond distances. -
Revision of the Crystal Structure of Ulrichite, Cacu (UO2)(PO4)2Б4H2O
Mineralogical Magazine, December 2001, Vol. 65(6), pp. 717–724 Revision of the crystal structure of ulrichite, 2+ CaCu (UO2)(PO4)2Á4H2O U. KOLITSCH* AND G. GIESTER Institut fu¨r Mineralogie undKristallographie, Universita¨t Wien, Geozentrum, Althanstr. 14, A-1090 Wien, Austria ABSTRACT 2+ The crystal structure of ulrichite, CaCu (UO2)(PO4)2Á4H2O (space group P21/c, a = 12.784(3), b = 6.996(1), c = 13.007(3) A˚ , b = 91.92(1)8, V = 1162.7(4) A˚ 3, Z = 4) was redetermined using X-ray diffraction data measured from a twinned crystal with Mo-Ka radiation and a CCD area detector (2510 unique reflections with Fo >4s(Fo), R1 = 8.8%). Ulrichite crystallizes in space group P21/c rather than C2/m reportedpreviously. The newly determinedatomicpositions give reasonable coordination polyhedra. One unique Ca atom is irregularly coordinated by eight O atoms (<CaÀO> = 2.46 A˚ ). One unique U atom shows a [2+5] coordination with characteristic bond angles and lengths (1.806(11) A˚ , 1.842(12) A˚ andfive bondsbetween 2.252(15) and2.441(11) A ˚ ). Furthermore, the structure contains groups in which strongly elongatedCuO 6 ‘octahedra’ (also describable as CuO4 squares) are corner- linkedto two PO 4 tetrahedra via two opposite, equatorial O atoms. Edge- and corner-sharing UO7, CaO8 andPO 4 polyhedra form heteropolyhedral sheets parallel to (001) that are linked to adjacent sheets via the CuO6 ‘octahedra’ and hydrogen bonds. KEYWORDS: ulrichite, crystal structure, twinning, uranium, phosphates. Introduction with a = 12.79(3), b = 6.85(2), c = 13.02(3) A˚ , b = 91.03(7)8, V = 1140.3 A˚ 3, Z = 4, andspace group 2+ ULRICHITE, CaCu (UO2)(PO4)2Á4H2O, is a very C2/m. -
Australia and New Zealand Micromineral News
Australia and New Zealand Micromineral News Issue 12 – January 2016 Editor: Steve Sorrell – [email protected] Cover photo: Pseudocubic Peatite-(Y) Poudrette Quarry, Mont Saint Hilaire, Canada 7 images stacked using Zerene Stacker Taken with Canon 750D through microscope Photo width 2.5mm across Photo and Specimen: Steve Sorrell Australia and New Zealand Micromineral News: Issue 12 1 In This Issue Introduction Happy New Year to you all! Omitted from the last issue (apologies) – “Many thanks to the NSW Micromineral Group for their research and interesting article with photographs on the Woodlawn mine in Issue 10”. The inaugural Australian Fine Mineral Show happened in early December. Yes, there were micros available! And of course, the famous Tucson show is about to start. Unfortunately, I won’t be there this year. Probably a good thing the way the Australian dollar is going! Contributions – We Still Need Your Input! Articles should be submitted to the editor in Word format, and any photos should be of a sufficient quality for publication. If you believe that you can provide a suitable article for the next issue, please advise the editor as soon as possible. Planning for the next issue begins as soon as the current one is published! Contacts If you want to find out what’s happening with micromounting or microminerals in your region, get in touch with one of the following: New South Wales: George Laking – [email protected] New Zealand: Jocelyn Thornton – [email protected] Queensland: Russell Kanowski – [email protected] South Australia: Peter Keller – [email protected] Tasmania: Ralph Bottrill – [email protected] Victoria: John Haupt – [email protected] Western Australia: Susan Koepke – [email protected] Forward Diary Please send details of micromounting or micromineral upcoming events (up to six months ahead would be good) for inclusion in the next issue of the Australian and New Zealand Micromineral News. -
Lnd Thorium-Bearing Minerals IQURTH EDITION
:]lossary of Uranium lnd Thorium-Bearing Minerals IQURTH EDITION y JUDITH W. FRONDEL, MICHAEL FLEISCHER, and ROBERT S. JONES : EOLOGICAL SURVEY BULLETIN 1250 1list of uranium- and thorium-containing vtinerals, with data on composition, type f occurrence, chemical classification, ~nd synonymy NITED STATES GOVERNMENT PRINTING OFFICE, WASHINGTON: 1967 UNITED STATES DEPARTMENT OF THE INTERIOR STEWART L. UDALL, Secretary GEOLOGICAL SURVEY William T. Pecora, Director Library of Congress catalog-card No. GS 67-278 For sale by the Superintendent of Documents, U.S. Government Printing, Office Washington, D.C. 20402 - Price 30 cents (paper cover) CONTENTS Page Introduction _ _ __ _ _ _ __ _ _ _ _ _ _ _ _ _ _ _ _ __ _ __ __ _ __ _ _ _ _ _ _ __ __ _ _ __ __ __ _ _ __ 1 Chemical classification of the uranium and thorium minerals____________ 5 A. Uranium and thorium minerals _ _ __ _ __ __ _ __ _ _ __ _ __ __ _ _ _ __ _ _ __ __ _ _ 10 B. Minerals with minor amounts of uranium and thorium______________ 50 C. Minerals reported to contain uranium and thorium minerals as im- purities or intergrowths_______________________________________ 61 Index____________________________________________________________ 65 In GLOSSARY OF URANIUM- AND THORIUM-BEARING MINERALS FOURTH EDITION By JuDITH W. FRONDEL, MicHAEL FLEISCHER, and RoBERTS. JoNES INTRODUCTION The first edition of this work was published as U.S. Geological Survey Circular 74 in April1950, the second edition as Circular 194 in February 1952, and the third edition in 1955 as U. S. -
The Crystal Structure of Khinite and Polytypism in Khinite and Parakhinite
Mineralogical Magazine, June 2008, Vol. 72(3), pp. 763–770 The crystal structure of khinite and polytypism in khinite and parakhinite 1 1, 2 M. A. COOPER ,F.C.HAWTHORNE * AND M. E. BACK 1 Department of Geological Sciences, University of Manitoba, Winnipeg, Manitoba, Canada, R3T 2N2 2 Department of Earth Sciences, Royal Ontario Museum, 100 Queen’s Park, Toronto, Ontario, Canada, M5S 2C6 [Received 2 May 2008; Accepted 17 September 2008] ABSTRACT 2+ 2+ 6+ The crystal structure of khinite, Pb Cu3 Te O6(OH)2, orthorhombic, a = 5.7491(10), b= ˚ ˚ 3 3 10.0176(14), c = 24.022(3) A, V = 1383.6(4) A , space group Fdd2, Z =8,Dcalc = 6.29 g/cm , from the Empire mine, Tombstone, Arizona, USA, has been solved by direct methods and refined to R1 = 3.2% on the basis of 636 unique observed reflections. There is one distinct Te site occupied by Te and coordinated by six O atoms in an octahedral arrangement with a <TeÀO> distance of 1.962 A˚ , typical of Te6+. There are three octahedrally-coordinated Cu sites, each of which is occupied by Cu2+ with <CuÀO> distances of 2.132, 2.151 and 2.308 A˚ , respectively. Each Cu octahedron shows four short meridional bonds (~1.95 A˚ ) and two longapical bonds (2.46 À2.99 A˚ ) characteristic of Jahn- Teller-distorted Cu2+ octahedra. There is one distinct Pb site occupied by Pb and coordinated by six O ˚ atoms and two (OH) groups with a <PbÀO, OH> distance of 2.690 A.TeF6 and CuF6 octahedra share edges and corners to form an [MF2] (where F = O, OH) layer of composition [TeCu3F8]. -
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American Mineralogist, Volume 75, pages240-246, 1990 NEW MINERAL NAMES JosN L. JAvrnon CANMET, 555 Booth Street,Ottawa, Ontario KIA 0G1, Canada Enwlnn S. Gnnw Department of GeologicalSciences, University of Maine, Orono, Maine 04469, U.S.A. Baiyuneboite-(Ce) the formula for cordylite-(Ce)requires revision such that Pigqiu Fu, Xlanze Su (1987)Baiyuneboite-A new min- cordylite-(Ce)and baiyuneboite-(Ce)may be identical. The eral. Acta Mineralogica Sinica, 7,289-297 (in Chinese, Chairman thereforewithdrew the approval and askedthat English abstract). the authors withhold publication of their description of Pingqiu Fu, Youhua Kong, Guohong Gong, Meicheng baiyuneboite-(Ce)until the matter could be resolved.The Shao, Jinzi Qian (1987) The crystal structure of bai- request,unfortunately, was ignored. J.L.J. yuneboite-(Ce).Acta Mineralogica Sinica, 7, 298-304 (in Chinese,English abstract). Diaoyudaoite* Electron-microprobe analysesof ten grains, whose va- lidity was checkedby single-crystalX-ray methods prior Shunxi Shen,Lirong Chen, Anchun Li, Tailu Dong, Qiu- to analysis,gave an averageof NarO 4.73, CaO 1.04,BaO huo Huang,Wenqiang Xu (1986)Diaoyudaoite-A new Acta Mineralogica 6, 224-227 (in 20.3 8, CerO,24.21, I-a2O 3 10.92,Pr rO,0.62, NdrO3 I 0.04, mineral. Sinica, GdrO30.13, F 2.50,CO, (by gaschromatography) 24.64, Chinese,English abstract). = O F 1.05, sum 98.16 wt0/0,corresponding to Nalo8- The averageof l3 electron-microprobe analysesgave (Bao ,oCao ,r)", or(Ce, 05La048Ndo o2ProorGdo o,)", nnFonrC, nr- NarO4.54,AlrO3 93.00, CrrO, 1.95,MgO 0.10,CaO 0.10, O,, or,ideally NaBaCerF(COr)0.The mineral occursas yel- SiOr 0.23, KrO 0. -
Chalcosiderite Cufe (PO4)4(OH)8 • 4H2O
3+ • Chalcosiderite CuFe6 (PO4)4(OH)8 4H2O c 2001-2005 Mineral Data Publishing, version 1 Crystal Data: Triclinic. Point Group: 1. Crystals short prismatic, with a number of forms noted, typically in sheafs, to 3 mm; in crusts. Physical Properties: Cleavage: One, perfect; another, less perfect. Hardness = 4.5 D(meas.) = 3.22 D(calc.) = [3.28] Optical Properties: Transparent. Color: Pale siskin-green to dark green. Streak: White to greenish, pale green. Luster: Vitreous. Optical Class: Biaxial (–). Pleochroism: Weak; X = colorless; Z = pale green. Orientation: X (107◦,57◦); Y (–143◦,68◦); Z (–32◦,40◦) using (φ,ρ). Dispersion: r> v,very strong, crossed. α = 1.775 β = 1.840 γ = 1.844 2V(meas.) = 22(2)◦ Cell Data: Space Group: P 1. a = 7.653(4) b = 7.873(4) c = 10.190(4) α =67.57(2)◦ β =69.17(2)◦ γ =64.93(2)◦ Z=1 X-ray Powder Pattern: Cornwall, England. 3.77 (100), 3.39 (70), 3.02 (60), 3.56 (40), 2.96 (40), 2.14 (40), 2.07 (40) Chemistry: (1) (2) P2O5 29.93 28.77 As2O5 0.61 Al2O3 4.45 Fe2O3 42.81 48.56 CuO 8.15 8.06 H2O 15.00 14.61 Total 100.95 100.00 • (1) West Phoenix mine, Cornwall, England. (2) CuFe6(PO4)4(OH)8 4H2O. Polymorphism & Series: Forms a series with turquoise. Mineral Group: Turquoise group. Occurrence: A rare mineral in the oxidized zone of some hydrothermal mineral deposits. Association: Dufr´enite,goethite (West Phoenix mine, Cornwall, England); dufr´enite,cyrilovite, leucophosphite (Gunheath china clay pit, Cornwall, England); sampleite, libethenite, crandallite, cyrilovite, pseudomalachite, sal´eeite, torbernite, ulrichite (Lake Boga quarry, Australia). -
CLIFFORDITE-A NEW TELLURITE MINERAL from MOCTEZUMA, SONORA, MEXICO Rrcnanp V. G,Trnns, Kazerccki Berylco Indwstries, Inc', Boyer
THE AMERICAN MINERALOGIST' VOL .54, MAY'JUNE, I969 CLIFFORDITE-A NEW TELLURITE MINERAL FROM MOCTEZUMA,SONORA, MEXICO Rrcnanp V. G,trNns,Kazerccki Berylco Indwstries, Inc', BoYertown,P ennsYlaani'a19 5 1 2. ABsrRAcr This new mineral occurs along joint surfaces in the oxidized zone of the san Miguel mine, a telluriurn-gold-silver prospect near Moctezuma, sonora, associated with mackayite, barite, quartz, and limonite. It has also been found in very small quantities at the Mocte- zuma mine in the same district, associated with native tellurium and paratellurite in small vugs. The small octahedrons are bright yellow with adamantine luster. The mineral is iso- gave 31.3 percent U and 52.6 percent Te, which corresponds closely to the formula uTeroa. Specific gravity, measured on synthetic material, was 6.57, and calculated specific gravity ls o./o. Singlecrystalprecessionphotographsshowedo:11.371Aandspacegroup Pa3,Z:8' The principal powder lines with corresponding intensities are 3.273 (10): 2.844 (8): 2.007 (8): 2.755(7): and r.712(7). Cliffordite from the Moctezuma mine contains a little lead and is identical with the sup- posed lead oxy-fluoride from this mine described by Mandarino and Williams in 1961. The lead oxy-fluoride is therefore not a valid species. The name is for Clifiord Frondel, in recognition of his many contributions to the study of the mineralogy of uranium. INtnooucuow In 1963 the writer noticed crusts of bright yellow microscopic crystals on some mackayite specimensfrom the San Miguel Mine, Moctezuma, Sonora,Mexico. Subsequentinvestigations establishedthat thesecrystals consistedof uranium tellurite, a new mineral. Later on it was found that this mineral is identical with a substance from the Moctezuma Mine which had been first observedin 1961 and mistakenly identified as lead oxy-fluoride. -
SCHMITTERITE-A NEW URANYL TELLURITE from MOCTEZUMA, SONORA Rrcnano V
THE AMERICAN MINERALOGIST, VOL.56, MARCH-APRIL, 1971 SCHMITTERITE-A NEW URANYL TELLURITE FROM MOCTEZUMA, SONORA Rrcnano V. GarNrs AssrRnct A new mineral, uranyl tellurite UOiTeO3, has been found at the Moctezuma Mine, Moctezuma, Sonora. The mineral is pale straw yellow in color and occurs in minute rosettes of micaceous crystals, usually associated with emmonsite. It is orthorhombic, space group Pmab with a 7sffi, b 10.089, and c 5.363 A; there are four foimula units per ceII, 11:1; G:6.878 (meas), 6.916 (calc). The mineral is biaxial negative with indices above 2.00. Principal powder lines are 3.682 (10), 5.35 (9),3.099, (9),4.73 (8), 3.170 (8), and t.971 (7). The name is for Eduardo Schmitter V. of the University of Mexico' INrnooucrroN While studying the Moctezuma tellurium-gold deposit in 1961, an unidentified light yellow mineral was noted in small tufts and micaceous scales growing on emmonsite. Subsequent study at the Instituto de Geologia showed that this mineral was new and consisted of uranium, lellurium, and oxygen only. The description of this mineral was delayed becauseits scarcity and the lack of measurablecrystals made a complete description difficult to achieve. These problems were finally solved, and the name schmitterite is now proposed for this species. OccutnBNcp Schmitterite was found at the Moctezuma Mine, Moctezuma, Sonora, along with a number of other new oxy-salts of tellurium (Gaines, 1965). In the great majority of samples of schmitterite that have been col- lected the mineral is sparingly scattered on knobs or typical groups of curved fibers of emmonsite, or is on limonite surfaces adjacent to em- monsite encrustations. -
Lead-Tellurium Oxysalts from Otto Mountain Near Baker, California: Part VI. Telluroperite, Pb3teo4cl2, the Te Analog of Perite A
View metadata, citation and similar papers at core.ac.uk brought to you by CORE provided by Caltech Authors American Mineralogist, Volume 95, pages 1569–1573, 2010 Lead-tellurium oxysalts from Otto Mountain near Baker, California: VI. Telluroperite, 4+ Pb3Te O4Cl2, the Te analog of perite and nadorite ANTHONY R. KA MPF ,1,* STU AR T J. MILL S ,2 ROBE R T M. HOU S LEY,3 JO S EPH MAR TY,4 A ND BR ENT THO R NE 5 1Mineral Sciences Department, Natural History Museum of Los Angeles County, 900 Exposition Blvd., Los Angeles, California 90007, U.S.A. 2Department of Earth and Ocean Sciences, University of British Columbia, Vancouver, British Columbia V6T 1Z4, Canada 3Division of Geological and Planetary Sciences, California Institute of Technology, Pasadena, California 91125, U.S.A. 43457 E. Silver Oak Road, Salt Lake City, Utah 84108, U.S.A. 53898 S. Newport Circle, Bountiful, Utah 84010, U.S.A. AB S T RA CT 4+ Telluroperite, Pb3Te O4Cl2, is a new tellurite from Otto Mountain near Baker, California. The new mineral occurs on fracture surfaces and in small vugs in brecciated quartz veins in direct association with acanthite, bromine-rich chlorargyrite, caledonite, cerussite, galena, goethite, and linarite. Various other secondary minerals occur in the veins, including six new tellurates, housleyite, markcooperite, paratimroseite, ottoite, thorneite, and timroseite. Telluroperite is orthorhombic, space group Bmmb, a = 5.5649(6), b = 5.5565(6), c = 12.4750(14) Å, V = 386.37(7) Å3, and Z = 2. The new mineral occurs as rounded square tablets and flakes up to 0.25 mm on edge and 0.02 mm thick. -
New Mineral Names*
American Mineralogist, Volume 95, pages 1357–1361, 2010 New Mineral Names* PAULA C. PIILONEN † AND GLENN POIRIER Mineral Sciences Division, Canadian Museum of Nature, P.O. Box 3443, Station D, Ottawa, Ontario K1P 6P4, Canada NEW MINERALS lines on the pattern [dobs in Å(Iobs%, hkl)] include: 3.712(13,111), 3.476(11,3.473), 3.075(25,201), 2.859(100,211), 2.4563(32,310), ALU M OÅKER M ANITE * 1.9413(11,400), 1.8303(13,330), 1.7634(11,411), 1.7569(19,312), D. Wiedenmann, A.N. Zaitsev, S.N. Britvin, S.V. Krivovichev, 1.7364(13,420), and 1.3859(13,521). The crystal structure of 2+ alumoåkermanite was solved and refined using a 0.22 × 0.14 × and J. Keller (2009) Alumoåkermanite, (Ca,Na)2(Al,Mg,Fe ) 0.12 mm crystal mounted on a Stoe IPDS II Image-Plate-based (Si2O7), a new mineral from the active carbonatite-nephelin- ite-phonolite volcano Oldoinyo Lengai, northern Tanzania. X-ray diffractometer. The structure was refined using starting Mineral. Mag., 73, 373–384. parameters from a synthetic sodic melilite (Louisnathan 1970, Z. Kristallogr., 23, 314–321) inverted to obtain the absolute correct Alumoåkermanite is a new member of the melilite group structure model. The data were refined to R1 = 0.018 based on from the Oldoinyo Lengai volcano, northern Tanzania. The 439 unique reflections with |Fo| ≥ 4σF. The mineral is tetrago- 3 new mineral was found in several samples from the volcano nal, P421m, a = 7.7620(7), c = 5.0311(5) Å, V = 303.12(5) Å , and surrounding area.