The Ash Occurs in Three Large Pockets Intermixed with Clay Material

Total Page:16

File Type:pdf, Size:1020Kb

The Ash Occurs in Three Large Pockets Intermixed with Clay Material Lament GeologicalObservatory^ Columbia University . Preliminary Description ..... ^uoT FOR PUBL1CMI9JL V - 15 - 8 Megascopic Description of Split Core Latitude: 10°11'N Longitude: 78°30'W Corr. depth: 1798 M P.D.R. depth: 963 fm. Date taken: 9 Nov 1958 Date opened: 20 Feb 1961 Described by: T. Willis Core length: 551 cm Plow-in: ~ 0-42 cm Brown silty calcilutite containing about 10% forams, becoming generally lighter with depth. Top 10 cm a disturbed gray and light brown mixture. Manganese appears to constitute an important part of the silt fraction, with a 1mm manganese nodule appearing at 14 cm. A reworked layer of^dark brown calcilutite containing an increased fraction of manganese occurs at 16-18 cm. The layer is indistinctly burrow mottled with lighter brown material in the upper section and with gray material in the lower section. Lower contact gradational and arbitrary. 42-39-8 cm ' Gray silty calcilutite containing about 10% forams and occasional pteropods, becoming slightly greener with depth. The layer, which was stored in the first tube (0-30 0 ) has been almost completely oxidized to a light brown color with a watery texture, while the rest of the core is in reasonably good condition. Burrow mottling is evident in the section after 300 cm, and, since there is no material change, by inference, in the 42-300 cm zone as well, although it cannot be readily seen. The burrows are filled with generally darker, coarser material. Prominent burrows occur at 295-315 cm, and at 335 and 344 cms. Black streaks of a sulfide material, probably ferrous sulfide, occur irregularly through the layer, with slight concentrations at 60-92cm, 124 cm, 168-175 cm and 224-228cms. Well defined streaks occur in the second section from 295- 351 cm. Irregular orange brown streaks of hydrotroilite also appear, generally in the form of poorly defined faint horizontal bands. These irregular bands occur at 54, 76, 124, 1 3 1 . 217 and 319 cms. 348-355 cm Fine white ash in a highly disturbed state, probably due to the impact of the core pipe on the firm layer. The ash occurs in three large pockets intermixed with clay material. The pocket at 353 cm seems to be the least disturbed and from it can be inferred that the layer was 1.5-2 cm thick and occured at approximately that level. 355-551 cm Gray green silty calcilutite somewhat darker than 42-351 cm, but essentially similar. Well defined lamina of hydrotroilalfe occur at 399 and 400 cm, with a less well defined band at 415 cm. Horizontal Lamont Geological Observatory CO o f < Columbia University Cb Preliminary Description ^ NOT FOR PUBLICATION <£5 V - 15 - 8 ZD Megascopic Description of Split Core continued f'V O streaked lamina of ferrous sulfide occur at 459 Q and 482 cms. These lamina, as well as the CD hydrotroilite bands} seem to be associated with a slight increase in the foram fraction. The layer is burrow mottled. Observations: The ash layer appears to be the eastern counterpart of the Worzel ash layer on the west coast. LL £ N* LJ 00 Li< Cl cb 2E Z> DC o oCD Lamont Geolog C olum'b ia Un 1 v e r s 1 1:y Preliminary Description *Tnrp WOP PUBLICATION Megascopic Description of a Split Gore Latitude : Ok 15*N Longitude: 85 06'¥ Corr, depth: 3266 M P.D.R depth: 1750 fra Date taken: 1 December 1958 Date opened: Described by: C. Fray Flow-in: 280 csn. Core length: 959 era. 0-120 cm.- Lutite, grayish-green with slight purplish tint, fairly soft. Color is mottled indicating material reworked by burrowing organisms except between 93 and 101 era. where tnere is no clear evidence of mottling. Lutite contains numerous foraraini- fera. Bottom contact horizontal and distinct due to color change. 120-123 cm.- Brown lutite containing forarainiiera. May have greater silt content than sections above and below. Bottom contact hori- zontal and sharp due to color change. Slight mottling due to burrowing. 123-153 cm.- Lutite, grayish-green with purplish tint. Color mottled due to burrowing. Lutite contains forarainifera. From 15.0-11:3 cm. sediment is darker green and oxidizes to a greenish-brown in- stead of to a brown as do the sections above. Bottom contact horizontal and distinct due to color change. 153-155 cn.- Lutite, light grayish-green with purplish tint which oxidizes to a light brown. Color is mottled. Lutite contains foramini- fera. Bottom contact horizontal and distinct due to color change. 155-302 cm.- Lutite, grayish-green with purplish tint. Color mottled due to burrowing. Lutite contains forarainifera throughout section. This section is similar to 0-120 era. Bottom contact horizontal and distinct due to color change and material. A patch of clean white volcanic ash (V/orzel Ash?) 1 x 3 cm. occurs at 156-159 cm. This ash does not form a layer but is surrounded by lutite. No similar material is apparent in this section. The possibility exists that the clay surrounding the patch of ash at 156 era. may have been introduced as a result of organisms burrowing through the ash and that the ash represents a distinct layer. 302-312 cm.- Greenish-brown silty lutite containing forarainifera. Color mottled due to burrowing. Bottom contact fairly distinct due to color and material change. 312-559 cm.- Similar to sections 0-120 cm. and 155-302 cm. Bottom contact sharp and horizontal due to color and material change. Between 382-558 cm. sediment is a more dark green in color but there does not appear to be any change in material. Lamont Geological Observatory 01 . Pnlnni’biQ- Jniversi'ty 2. Preliminary Description $0T FOR PUBLICATION ^ 3 51*9-582 cm.- Brown foraminiferal lutite. Mottling indicates material re- worked by burrowing. Bottom contact sharp and essentially horizontal due to color and material change. Piston effect occurs between 551-560 cm. 582-611 cm.- Similar to 0-120 cm. section. 611-612 cm.- Light brown lutite. Bottom contact above and below is hori- zontal and distinct. No mottling evident. It probably re- presents oxidation of the overlying lutite at the contact with the ash during storage as a result of the greater porosity of the ash allowing the circulation of air. 612 6 6 - l cm.- Volcanic ash, grayish-white with a somewhat purple tint. Contact with underlying lutite sharp and horizontal. 616-632 cm.- Similar to section 582-611 and 0-120 cm. 632-716 cm.- Similar tc 616-632 cm. layer except it oxidizes to a lighter brown giving it the appearance of a distinct layer. 716-772 cm.- Similar to section 0-120 cm. except it is darker in color and oxidizes to a greenish-brown. 772-828 cm.- Similar to 632-716 cm. layer. 828-81*5 cm.- Lutite, dark grayish-green with purple tint. Color is mottled. Contains foraminifera. Two possible incipient manganese nodules occur at 838 and 839 cm. Bottom contact sharp and horizontal due to color change. 81*5-959 cra.- Similar to 772-828 cm. layer. •Lamont Geological Observatory of G n Columbia UrAvfirr:’ty '^Preliminary Do scrip tiori 15 - 40 ROT FOR PUBLICATION Latitude: 11 °05'S Longitude: 82°31'W Corr. depth: 4470 M P.D.R. depth: 2380 fm. Date Taken: 11 Dec. 1958 Date Described: 22 June 1961 Described By: D. Bauchelle Flow-in: 0 Core Length: 1662 cm. BOORUM BOORUM & IASE “ MoTI General Description: This core falls in the red-clay category. Various shades of beige and brown define the layers. M a n y show reworking by burrowers. The bottom 20 feet± have the texture associated with diatoms, volcanic glass, or radiolarians. This type material also occurs scattered at higher levels. There is a 9-10 c m . layer of ma n g a n e s e grains at ~ 2 l ft. 0-0*29 cm. A grey-brown lutite speckled by dark br o w n ma n g a n e s e stains above 18 cm. Part of the manganese has been oxidized to orange. Burrows of two sizes mottle this layer - s o m e with diameters of o»l c m . , others with burrows of 1 m m . size. The top 5 cm. m a y be another layer of lighter lutite also marked by dark brown manganese coloring. Bottom contact burrowed but clear by color. 29-32 c m . Slightly lighter grey-brown than above. B u r r o w e d and reworked. Contacts ” <f ” <f irregular but clear. v r / 32-37 c m . s Grey-brown color of 5-28 cm. zone. Slightly darker though. Both large and small burrows as all above layers. , 37-58 cm. Lighter beige lutite. Not so grey as above. Burrow mottled, few small burrows, m a n y large. One large (l| x 2 cm.) burrow between 54 and 56 cm. is greenish and flecked with manganese grains. Surface of sliced core shows some small tears usually characteristic of a coarser material in the lutite, s e e m s to be volcanic glass and/or radiolaria. Radiolaria have been identified lower in the core. The concentration here does not justify a search. Contact burrowed. 58-332 c m . BOORUM BOORUM & PEASE * N 5 £ Grey-brown lutite. Color is graded and changed by iron oxide stains from the core pipe. Section reworked by large burrowers. Surface of core shows s o m e small tears characteristic of gritty lutite especially between 100-140 cm. and 170-250 cm. Five ’'proto-inanganese nodules" about pea size occur in a chain at 234 cm.
Recommended publications
  • Ocean Drilling Program Scientific Results Volume
    9. GEOCHEMICAL EXPRESSION OF EARLY DIAGENESIS IN MIDDLE EOCENE-LOWER OLIGOCENE PELAGIC SEDIMENTS IN THE SOUTHERN LABRADOR SEA, SITE 647, ODP LEG 1051 M. A. Arthur,2 W. E. Dean,3 J. C. Zachos,2 M. Kaminski,4 S. Hagerty Rieg,2 and K. Elmstrom2 ABSTRACT Geochemical analyses of the middle Eocene through lower Oligocene lithologic Unit IIIC (260-518 meters below seafloor [mbsf]) indicate a relatively constant geochemical composition of the detrital fraction throughout this deposi­ tional interval at Ocean Drilling Program (ODP) Site 647 in the southern Labrador Sea. The main variability occurs in redox-sensitive elements (e.g., iron, manganese, and phosphorus), which may be related to early diagenetic mobility in anaerobic pore waters during bacterial decomposition of organic matter. Initial preservation of organic matter was me­ diated by high sedimentation rates (36 m/m.y.). High iron (Fe) and manganese (Mn) contents are associated with car­ bonate concretions of siderite, manganosiderite, and rhodochrosite. These concretions probably formed in response to elevated pore-water alkalinity and total dissolved carbon dioxide (C02) concentrations resulting from bacterial sulfate reduction, as indicated by nodule stable-isotope compositions and pore-water geochemistry. These nodules differ from those found in upper Cenozoic hemipelagic sequences in that they are not associated with methanogenesis. Phosphate minerals (carbonate-fluorapatite) precipitated in some intervals, probably as the result of desorption of phosphorus from iron and manganese during reduction. The bulk chemical composition of the sediments differs little from that of North Atlantic Quaternary abyssal red clays, but may contain a minor hydrothermal component. The silicon/ aluminum (Si/Al) ratio, however, is high and variable and probably reflects original variations in biogenic opal, much of which is now altered to smectite and/or opal CT.
    [Show full text]
  • Meteoric Be and Be As Process Tracers in the Environment
    Chapter 5 Meteoric 7Be and 10Be as Process Tracers in the Environment James M. Kaste and Mark Baskaran 7 10 Abstract Be (T1/2 ¼ 53 days) and Be (T1/2 ¼ occurring Be isotopes of use to Earth scientists are the 7 1.4 Ma) form via natural cosmogenic reactions in the short-lived Be (T1/2 ¼ 53.1 days) and the longer- 10 atmosphere and are delivered to Earth’s surface by wet lived Be (T1/2 ¼ 1.4 Ma; Nishiizumi et al. 2007). and dry deposition. The distinct source term and near- Because cosmic rays that cause the initial cascade of constant fallout of these radionuclides onto soils, vege- neutrons and protons in the upper atmosphere respon- tation, waters, ice, and sediments makes them valuable sible for the spallation reactions are attenuated by tracers of a wide range of environmental processes the mass of the atmosphere itself, production rates of operating over timescales from weeks to millions of comsogenic Be are three orders of magnitude higher in years. Beryllium tends to form strong bonds with oxygen the stratosphere than they are at sea-level (Masarik and atoms, so 7Be and 10Be adsorb rapidly to organic and Beer 1999, 2009). Most of the production of cosmo- inorganic solid phases in the terrestrial and marine envi- genic Be therefore occurs in the upper atmosphere ronment. Thus, cosmogenic isotopes of beryllium can be (5–30 km), although there is trace, but measurable used to quantify surface age, sediment source, mixing production as oxygen atoms in minerals at the Earth’s rates, and particle residence and transit times in soils, surface are spallated (in situ produced; see Lal 2011, streams, lakes, and the oceans.
    [Show full text]
  • 4. a Growth Model for Polymetallic Nodules
    A GEOLOGICAL MODEL OF POLYMETALLIC NODULE DEPOSITS IN THE CLARION‐CLIPPERTON FRACTURE ZONE ISA TECHNICAL STUDY SERIES Technical Study No. 1 Global Non‐Living Resources on the Extended Continental Shelf: Prospects at the year 2000 Technical Study No. 2 Polymetallic Massive Sulphides and Cobalt‐Rich Ferromanganese Crusts: Status and Prospects Technical Study No. 3 Biodiversity, Species Ranges and Gene Flow in the Abyssal Pacific Nodule Province: Predicting and Managing the Impacts of Deep Seabed Mining Technical Study No. 4 Issues associated with the Implementation of Article 82 of the United Nations Convention on the Law of the Sea Technical Study No. 5 Non‐Living resources of the Continental Shelf beyond 200 nautical miles: Speculations on the Implementation of Article 82 of the United Nations Convention on the Law of the Sea PAGE | II A GEOLOGICAL MODEL OF POLYMETALLIC NODULE DEPOSITS IN THE CLARION‐ CLIPPERTON FRACTURE ZONE This report contains a summary of two documents – A Geological Model of Polymetallic Nodule Deposits in the Clarion‐Clipperton Fracture Zone and a Prospector’s Guide prepared under the project ‘Development of a Geological Model of Polymetallic Nodule Deposits in the Clarion‐Clipperton Fracture Zone, Pacific Ocean’. ISA TECHNICAL STUDY: NO. 6 International Seabed Authority Kingston, Jamaica PAGE | III The designation employed and the presentation of materials in this publication do not imply the expression of any opinion whatsoever on the part of the Secretariat of the International Seabed Authority concerning the legal status of any country or territory or of its authorities, or concerning the delimitation of its frontiers or maritime boundaries. All rights reserved.
    [Show full text]
  • ECONOMIC ASPECTS of NODULE MINING Although Deep-Sea
    CHAPTER 11 ECONOMIC ASPECTS OF NODULE MINING J. L. MERO INTRODUCTION Although deep-sea manganese nodules were discovered over a'century ago by scientists of the HMS Challenger expedition, few analyses of the nodules for the economically significant elements such as nickel, copper, cobalt and molybdenum were made in those early days and no consideration was given to these deposits as a possible commercial source of metals until the early 1950's when the mining of the nodules was advocated as a possible source of manganese (Mero, 1952). As the result of a haul of nodules taken in relatively shallow water (900 m) about 370 km east of Tahiti on the western edge of the Tuamoto Plateau during the 1957-58 International Geophysical Year (the nodules contained about 2% of cobalt, a valuable metal at that particular time), a study was initiated by the Institute of Marine Resources of the University of California to determine if it might be economic to mine and process the nodules for their cobalt, nickel and copper contents. The results of that study were favourable' with respect to the technical and economic factors involved in mining and processing the nodules. All the research and development in this matter dates from the release of the report describing the results of that study (Mero, 1958). To the present time (1975) over $150 million* has been expended in the exploration of the nodule deposits and in the development of mining and processing systems. An additional $100 million is to be spent in the next few years in these activities.
    [Show full text]
  • Study of the Structure Model of Todorokite
    Title Study of the Structure Model of Todorokite Author(s) Miura, Hiroyuki Citation 北海道大学理学部紀要, 23(1), 41-51 Issue Date 1991-07 Doc URL http://hdl.handle.net/2115/36772 Type bulletin (article) File Information 23-1_p41-51.pdf Instructions for use Hokkaido University Collection of Scholarly and Academic Papers : HUSCAP Jour. Fac. Sci., Hokkaido Univ., Ser. IV, vol. 23, no. 1, July., 1991, pp. 41 -51 STUDY OF THE STRUCTURE MODEL OF TODOROKITE by Hiroyuki Miura (with 5 text-figures and 3 tables) Abstract The X - ray diffraction study of todorokite from Japan was carried out and appropriate struc­ tural model was calculated by Rietveld method. The calculation of the theoretical diffraction pattern was done for a layer structural model and the calculated results show that the layer model can explain the observed diffraction data. Some of the properties of todorokite such as superstructure or shrinkage of c-axis on heating can be explained by the layer model which con­ tains random H 20 between the [MnOs] layers. Introduction Todorokite is a manganese oxide mineral having H 20 in its structure. It was reported first from the Todoroki gold mine, Hokkaido, Japan (Yoshimura, 1934) . This mineral occurs as aggregate of fine acicular crystals. It also contains H20, Ca, Ba and Mg. The X -ray powder diffraction data of todorokite clearly show diffraction peaks of 9.6, 4.8, 3.2, 2.45 and 1.42 A. Since 1934 there has been many reports of todorokite like minerals from all over the world (Frondel, 1953; Frondel et aI. , 1960; Ljunggren, 1960; Straczek et aI., 1960; Faulring, 1961 ; Larson, 1962; Radtke et aI., 1967; Lawrence et aI., 1968; Harada, 1982; Siegel and Turner, 1983) .
    [Show full text]
  • Petrogenesis of Ferromanganese Nodules from East of the Chagos Archipelago, Central Indian Basin, Indian Ocean
    ELSEVIER Marine Geology 157 (1999) 145±158 Petrogenesis of ferromanganese nodules from east of the Chagos Archipelago, Central Indian Basin, Indian Ocean Ranadip Banerjee a,Ł, Supriya Roy b, Somnath Dasgupta b, Subir Mukhopadhyay b, Hiroyuki Miura c a Geological Oceanography Division, National Institute of Oceanography, Dona Paula, Goa 403004, India b Department of Geological Sciences, Jadavpur University, Calcutta, 700032, India c Department of Geology and Mineralogy, Faculty of Science, Hokkaido University, Sapporo, 060, Japan Received 28 May 1997; accepted 24 July 1998 Abstract Deep-sea ferromanganese nodules occur over a large area and on many different sediment types of the Central Indian Basin, Indian Ocean. Selected samples were studied to determine their chemical and mineralogical compositions and microstructural features. Repeated laminations of variable thickness, alternately dominated by todorokite and vernadite, are characteristic of these nodules. These laminae show, on electron microprobe line scans, corresponding interlaminar partitioning of Mn±Cu±Ni and Fe±Co. The bulk chemical compositions of these nodules plot in both the hydrogenetic and early diagenetic ®elds on the Fe±Mn±(Ni C Cu C Co) ð10 ternary diagram. The binary diagram depicting the covariation of Mn C Ni C Cu against Fe C Co shows two distinct parallel regression lines, one delineated by nodules from terrigenous, siliceous ooze and siliceous ooze±terrigenous sediments and the other by nodules from red clay, siliceous ooze±red clay and calcareous ooze±red clay. An increasing diagenetic in¯uence in the nodules with the nature of the host sediment types was observed in the sequence: terrigenous ! siliceous ooze and red clay ! siliceous=calcareous ooze±red clay.
    [Show full text]
  • Structural Economic Assessment of Polymetallic Nodules Mining Project with Updates to Present Market Conditions
    minerals Article Structural Economic Assessment of Polymetallic Nodules Mining Project with Updates to Present Market Conditions Tomasz Abramowski 1,2,* , Marcin Urbanek 3 and Peter Baláž 2 1 Faculty of Navigation, Maritime University of Szczecin, 70-500 Szczecin, Poland 2 Interoceanmetal Joint Organization IOM, 71-541 Szczecin, Poland; [email protected] 3 Qvistorp, 71-487 Szczecin, Poland; [email protected] * Correspondence: [email protected] Abstract: This paper presents the economic structure, assumptions, and relations of deep-sea mining project assessment and the results of its evaluation, based on exploration activities and research in the field of geology, mining technology, processing technology, and environmental and legislative studies. The Interoceanmetal Joint Organization (IOM) and cooperating organizations conducted a study incorporating those elements of the project that are recognized as most important for commercial viability. On the basis of formulated financial flow of operating and capital expenses of one processing technology the possible market unit price of polymetallic nodules was estimated and the result is presented in this paper. The rapidly changing economic situation, affected inter alia by the COVID- 19 pandemic, is reflected in the study and updated results are based on recent changes in metal prices. Although assumptions related to mining costs need to be confirmed during pilot mining tests, promising results have been shown in the case of the use of high-pressure acid leaching processing technology (HPAL) as well as in the case of raw ore sales. A pre-feasibility study of the project will Citation: Abramowski, T.; Urbanek, focus on the two most promising variants of the model.
    [Show full text]
  • Predicting the Impacts of Nodule Mining in the Pacific Ocean
    SUPPORTED BY Research Team Peer Reviewers Editorial Team Dr. Andrew Chin, Prof. Alex David Rogers, Dr. Helen Rosenbaum, College of Science and Science Director, REV Ocean, Deep Sea Mining Campaign, Engineering, James Cook Oksenøyveien 10, NO-1366 Australia University, Townsville, Australia Lysaker, Norway. Mr. Andy Whitmore, Ms. Katelyn Hari, Dr. Kirsten Thompson, Deep Sea Mining Campaign, College of Science and Lecturer in Ecology, University of United Kingdom Engineering, James Cook Exeter, United Kingdom Dr. Catherine Coumans, University, Townsville, Australia Dr. John Hampton, Mining Watch Canada Dr. Hugh Govan, Chief Scientist, Fisheries Ms. Sian Owen, Adjunct Senior Fellow, School of Aquaculture and Marine Deep Sea Conservation Coalition, Government, Development and Ecosystems Division (FAME), Netherlands International Affairs, University of Pacific Community, Noumea, the South Pacific, Suva, Fiji New Caledonia Mr. Duncan Currie, Deep Sea Conservation Coalition, Dr. Tim Adams, To cite this report New Zealand Fisheries Management Consultant, Chin, A and Hari, K (2020), Port Ouenghi, New Caledonia Design: Ms. Natalie Lowrey, Predicting the impacts of Dr. John Luick, Deep Sea Mining Campaign, mining of deep sea polymetallic Oceanographer, Australia nodules in the Pacific Ocean: Flinders University of South A review of Scientific literature, Australia, Adelaide, Australia For Correspondence: Deep Sea Mining Campaign and Dr. Helen Rosenbaum, MiningWatch Canada, 52 pages Prof. Matthew Allen, DSM Campaign Director of Development [email protected] Studies, School of Government, Development and International Affairs, University of the South Pacific, Suva, Fiji FRONT COVER: A SPERM WHALE AND FREEDIVER. IF NODULE MINING DEVELOPS DEEP-DIVING WHALES LIKE THE VULNERABLE SPERM WHALE COULD BE ADVERSELY IMPACTED.
    [Show full text]
  • Metallogenesis of the World's Ocean Against the Background of Oceanic Crust Evolution
    RYSZARD KOTLIÑSKI METALLOGENESIS OF THE WORLD’S OCEAN AGAINST THE BACKGROUND OF OCEANIC CRUST EVOLUTION Polish Geological Institute Special Papers,4 WARSZAWA 1999 CONTENTS Introduction ..................................................................6 Aim and methods of the studies ........................................................7 Scope of the studies and basic source data...................................................7 International legal regulations of carrying out prospecting, exploration and exploitation of mineral resources.................9 Origin and geological structure of the oceans ................................................10 Morphotectonic structures of the ocean floor ..............................................11 Major stages of ocean floor development................................................12 Evolution of environmental sedimentary conditions ..........................................16 Metallogenic systematic of the world’s ocean ................................................19 Applied essentials of the metallogenic division.............................................20 Morphotectonic megaprovinces.....................................................24 Metallogenic provinces and ore deposit formations ..........................................25 Manganese nodule formation ....................................................30 Deep-sea manganese nodules ..................................................31 Cobalt-rich manganese crusts ..................................................39 Polymetallic
    [Show full text]
  • Manganese Oxide Minerals: Crystal Structures and Economic and Environmental Significance
    Proc. Natl. Acad. Sci. USA Vol. 96, pp. 3447–3454, March 1999 Colloquium Paper This paper was presented at the National Academy of Sciences colloquium ‘‘Geology, Mineralogy, and Human Welfare,’’ held November 8–9, 1998 at the Arnold and Mabel Beckman Center in Irvine, CA. Manganese oxide minerals: Crystal structures and economic and environmental significance JEFFREY E. POST Department of Mineral Sciences, Smithsonian Institution, Washington, DC 20560-0119 ABSTRACT Manganese oxide minerals have been used ronmentally relevant insights into certain types of interactions for thousands of years—by the ancients for pigments and to between these systems and potentially serve as long-term clarify glass, and today as ores of Mn metal, catalysts, and monitors of changes within a system. battery material. More than 30 Mn oxide minerals occur in a As ores, Mn oxides have been exploited since ancient times. wide variety of geological settings. They are major components In particular, pyrolusite (MnO2) was prized as a pigment and of Mn nodules that pave huge areas of the ocean floor and for its ability to remove the green tint imparted by iron to glass bottoms of many fresh-water lakes. Mn oxide minerals are (3). By the mid-19th century Mn was an essential component ubiquitous in soils and sediments and participate in a variety in steel making, as a deoxidizer and desulfurizer and for of chemical reactions that affect groundwater and bulk soil making hard-steel alloys. Mn oxides are the predominant ore composition. Their typical occurrence as fine-grained mix- minerals in most of today’s commercially important Mn de- tures makes it difficult to study their atomic structures and posits, commonly formed by weathering of Mn-rich carbonates crystal chemistries.
    [Show full text]
  • Major and Trace Element Distributions in Manganese Nodules and Micronodules As Well As Abyssal Clay from the Clarion-Clipperton Abyssal Plain, Northeast Pacific O.G
    Major and trace element distributions in manganese nodules and micronodules as well as abyssal clay from the Clarion-Clipperton abyssal plain, Northeast Pacific O.G. Duliu, V. Alexe, Jacques Moutte, S.A. Szobotca To cite this version: O.G. Duliu, V. Alexe, Jacques Moutte, S.A. Szobotca. Major and trace element distributions in manganese nodules and micronodules as well as abyssal clay from the Clarion-Clipperton abyssal plain, Northeast Pacific. Geo-Marine Letters, Springer Verlag, 2009, 29 (2), pp.71-83. 10.1007/s00367-008- 0123-5.. hal-00493837 HAL Id: hal-00493837 https://hal.archives-ouvertes.fr/hal-00493837 Submitted on 21 Jun 2010 HAL is a multi-disciplinary open access L’archive ouverte pluridisciplinaire HAL, est archive for the deposit and dissemination of sci- destinée au dépôt et à la diffusion de documents entific research documents, whether they are pub- scientifiques de niveau recherche, publiés ou non, lished or not. The documents may come from émanant des établissements d’enseignement et de teaching and research institutions in France or recherche français ou étrangers, des laboratoires abroad, or from public or private research centers. publics ou privés. Geo-Marine Letters, 2009, 29(2), 71-83, doi : 10.1007/s00367-008-0123-5. MMMaaajjjooorrr aaannnddd tttrrraaaccceee eeellleeemmmeeennnttt dddiiissstttrrriiibbbuuutttiiiooonnnsss iiinnn mmmaaannngggaaannneeessseee nnnoooddduuullleeesss aaannnddd mmmiiicccrrrooonnnoooddduuullleeesss aaasss wwweeellllll aaasss aaabbbyyyssssssaaalll ccclllaaayyy fffrrrooommm ttthhheee CCClllaaarrriiiooonnn---CCCllliiippppppeeerrrtttooonnn
    [Show full text]
  • Geochemistry of Niobium and Tantalum
    Geochemistry of Niobium and Tantalum GEOLOGICAL SURVEY PROFESSIONAL PAPER 612 Geochemistry of Niobium and Tantalum By RAYMOND L. PARKER and MICHAEL FLEISCHER GEOLOGICAL SURVEY PROFESSIONAL PAPER 612 A review of the geochemistry of niobium and tantalum and a glossary of niobium and tantalum minerals UNITED STATES GOVERNMENT PRINTING OFFICE, WASHINGTON : 1968 UNITED STATES DEPARTMENT OF THE INTERIOR STEWART L. UDALL, Secretary GEOLOGICAL SURVEY William T. Pecora, Director Library of Congress catalog-card No. GS 68-344 For sale by the Superintendent of Documents, U.S. Government Printing Office Washington, D.C. 20402 - Price 50 cents (paper cover) CONTENTS Page Page Abstract_ _ __-_.. _____________________ 1 Geochemical behavior Continued Introduction. _________________________ 2 Magmatic rocks Continued General geochemical considerations. _____ 2 Volcanic rock series______--____---__.__-_-__ 2. Abundance of niobium and tantalum_____ 3 Sedimentary rocks______________________________ 2. Crustal abundance-________________ 3 Deposits of niobium and tantalum.___________________ 2£ Limitations of data________________ 3 Suggestions for future work__--___-_------__-___---_- 26 Abundance in rocks._______________ 5 References, exclusive of glossary______________________ 27 Qualifying statement.__________ 5 Glossary of niobium and tantalum minerals.___________ 3C Igneous rocks_________________ 6 Part I Classification of minerals of niobium and Sedimentary rocks.____________ 10 tantalum according to chemical types_________ 31 Abundance in meteorites and tektites. 12 Part II Niobium and tantalum minerals..-_______ 32 Isomorphous substitution.______________ 13 Part III Minerals reported to contain 1-5 percent Geochemical behavior._________________ 15 niobium and tantalum_______________________ 38 Magma tic rocks ___________________ 15 Part IV Minerals in which niobium and tantalum Granitic rocks_________________ 16 have been detected in quantities less than 1 Albitized and greisenized granitic rocks.
    [Show full text]