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INDEX to PESTICIDE TYPES and FAMILIES and PART 180 TOLERANCE INFORMATION of PESTICIDE CHEMICALS in FOOD and FEED COMMODITIES
US Environmental Protection Agency Office of Pesticide Programs INDEX to PESTICIDE TYPES and FAMILIES and PART 180 TOLERANCE INFORMATION of PESTICIDE CHEMICALS in FOOD and FEED COMMODITIES Note: Pesticide tolerance information is updated in the Code of Federal Regulations on a weekly basis. EPA plans to update these indexes biannually. These indexes are current as of the date indicated in the pdf file. For the latest information on pesticide tolerances, please check the electronic Code of Federal Regulations (eCFR) at http://www.access.gpo.gov/nara/cfr/waisidx_07/40cfrv23_07.html 1 40 CFR Type Family Common name CAS Number PC code 180.163 Acaricide bridged diphenyl Dicofol (1,1-Bis(chlorophenyl)-2,2,2-trichloroethanol) 115-32-2 10501 180.198 Acaricide phosphonate Trichlorfon 52-68-6 57901 180.259 Acaricide sulfite ester Propargite 2312-35-8 97601 180.446 Acaricide tetrazine Clofentezine 74115-24-5 125501 180.448 Acaricide thiazolidine Hexythiazox 78587-05-0 128849 180.517 Acaricide phenylpyrazole Fipronil 120068-37-3 129121 180.566 Acaricide pyrazole Fenpyroximate 134098-61-6 129131 180.572 Acaricide carbazate Bifenazate 149877-41-8 586 180.593 Acaricide unclassified Etoxazole 153233-91-1 107091 180.599 Acaricide unclassified Acequinocyl 57960-19-7 6329 180.341 Acaricide, fungicide dinitrophenol Dinocap (2, 4-Dinitro-6-octylphenyl crotonate and 2,6-dinitro-4- 39300-45-3 36001 octylphenyl crotonate} 180.111 Acaricide, insecticide organophosphorus Malathion 121-75-5 57701 180.182 Acaricide, insecticide cyclodiene Endosulfan 115-29-7 79401 -
Validation Report 28
EURL for Cereals and Feeding stuff National Food Institute Technical University of Denmark Validation Report 28 Determination of pesticide residues in hay by LC-MS/MS and GC-MS/MS (QuEChERS method) Susan Strange Herrmann Mette Erecius Poulsen February 2018 Page 2 of 67 CONTENT: 1. Introduction ...................................................................................................................................... 3 2. Principle of analysis......................................................................................................................... 3 3. Validation design ............................................................................................................................. 4 4. Calibration curves............................................................................................................................ 4 5. Validation parameters...................................................................................................................... 4 6. Criteria for the acceptance of validation results ............................................................................. 5 7. Results and conclusion ..................................................................................................................... 6 9. References ........................................................................................................................................ 6 Appendix 1a. GCMSMS transitions used for validation of pesticides in Hay .................................... -
Bottle Bioassays of Field Collected Mosquitoes for Level of Etofenprox Resistance in Central Massachusetts 2019 Update
BOTTLE BIOASSAYS OF FIELD COLLECTED MOSQUITOES FOR LEVEL OF ETOFENPROX RESISTANCE IN CENTRAL MASSACHUSETTS 2019 UPDATE FRANK H. CORNINE III Central Mass. Mosquito Control Project 111 Otis Street Northborough, MA 01532 (508) 393-3055 • www.cmmcp.org • [email protected] ABSTRACT Using protocols and supplies distributed from the Centers for Disease Control and Prevention, CMMCP conducted bottle bioassays on locally collected adult mosquitoes against the active ingredient etofenprox. The overwhelming majority of these specimens were of the species Coquillettidia perturbans. Resistance to etofenprox was examined because the primary adulticide product of CMMCP is Zenivex® E4, of which etofenprox is the sole active ingredient. Results from these ongoing bottle bioassays are given to the CDC in an effort to help expand the understanding of pesticide resistance in mosquitoes of the United States. BACKGROUND Although examples of pesticide resistance have been well documented, Pesticide resistance in this age of vector- the scope of the issue and its real world borne disease can hamper the ability of impact on public health control activities public health officials to successfully is not known. This is partially due to control threats. Potential resistance may varying levels of resistance surveillance also lead to the reemergence of several programs that currently exist. This factor diseases that would have been otherwise is shown in Massachusetts where some contained through control measures organized mosquito control agencies (Brogdon 1998). Current resistance in conduct zero resistance surveillance, select mosquito populations may be the while others have limited to well- result of historical insecticide use in the developed programs collecting data on agricultural and pest control industries pesticide resistance in mosquitoes. -
Who Specifications and Evaluations for Public
WHO SPECIFICATIONS AND EVALUATIONS FOR PUBLIC HEALTH PESTICIDES ETOFENPROX 2-(4-ethoxyphenyl)-2-methylpropyl 3-phenoxybenzyl ether TABLE OF CONTENTS PAGE DISCLAIMER 3 INTRODUCTION 4 PART ONE SPECIFICATIONS FOR ETOFENPROX ETOFENPROX INFORMATION 6 ETOFENPROX TECHNICAL MATERIAL (JULY 2007) 7 ETOFENPROX WETTABLE POWDER (JULY 2007) 8 ETOFENPROX EMULSION, OIL IN WATER (JULY 2007) 10 PART TWO 2006 EVALUATION REPORT FOR ETOFENPROX 14 SUPPORTING INFORMATION 18 ANNEX 1: HAZARD SUMMARY PROVIDED BY THE PROPOSER 22 ANNEX 2: REFERENCES 27 Page 2 of 29 Disclaimer1 WHO specifications are developed with the basic objective of promoting, as far as practicable, the manufacture, distribution and use of pesticides that meet basic quality requirements. Compliance with the specifications does not constitute an endorsement or warranty of the fitness of a particular pesticide for a particular purpose, including its suitability for the control of any given pest, or its suitability for use in a particular area. Owing to the complexity of the problems involved, the suitability of pesticides for a particular purpose and the content of the labelling instructions must be decided at the national or provincial level. Furthermore, pesticides which are manufactured to comply with these specifications are not exempted from any safety regulation or other legal or administrative provision applicable to their manufacture, sale, transportation, storage, handling, preparation and/or use. WHO disclaims any and all liability for any injury, death, loss, damage or other prejudice of any kind that may be arise as a result of, or in connection with, the manufacture, sale, transportation, storage, handling, preparation and/or use of pesticides which are found, or are claimed, to have been manufactured to comply with these specifications. -
Eupt-Fv17- Target Pesticide List
EUPT-FV17- TARGET PESTICIDE LIST MRRL Pesticide (mg/Kg) 3-hydroxy-carbofuran 0.01 Acephate 0.01 Acetamiprid 0.01 Acrinathrin 0.01 Aldicarb 0.01 Aldicarb Sulfone 0.01 Aldicarb Sulfoxide 0.01 Azinphos-methyl 0.01 Azoxystrobin 0.01 Benfuracarb 0.01 Benomyl 0.01 Bifenthrin 0.01 Bitertanol 0.01 Boscalid 0.01 Bromopropylate 0.01 Bromuconazole 0.01 Bupirimate 0.01 Buprofezin 0.01 Cadusafos 0.006 Carbaryl 0.01 Carbendazim 0.01 Carbofuran 0.01 Carbosulfan 0.01 Chlorfenapyr 0.01 Chlorfenvinphos 0.01 Chlorobenzilate 0.01 Chlorothalonil 0.01 Chlorpropham (only parent compound) 0.01 Chlorpyrifos 0.01 Chlorpyrifos-methyl 0.01 Clofentezine (only parent compound) 0.01 Clothianidin 0.01 Cyfluthrin (cyfluthrin incl. other mixtures of constituent isomers (sum of isomers)) 0.01 Cypermethrin (cypermethrin incl. other mixtures of constituent isomers (sum of isomers)) 0.01 Cyproconazole 0.01 Cyprodinil 0.01 Deltamethrin 0.01 Demeton-S-methylsulfone 0.006 Desmethyl-pirimicarb 0.01 Diazinon 0.01 Dichlofluanid (only parent compound) 0.01 Dichlorvos 0.01 Dicloran 0.01 Dicofol 0.01 Diethofencarb 0.01 Difenoconazole 0.01 Diflubenzuron 0.01 Dimethoate 0.003 Dimethomorph 0.01 Dimethylaminosulfotoluidide (DMST) 0.01 Diniconazole 0.01 Diphenylamine 0.01 Endosulfan alpha 0.01 Endosulfan beta 0.01 Endosulfan sulfate 0.01 EPN 0.01 Epoxiconazole 0.01 Ethion 0.01 Ethirimol 0.01 Ethoprophos 0.008 Etofenprox 0.01 Fenamidone 0.01 Fenamiphos 0.01 Fenamiphos sulfone 0.01 Fenamiphos sulfoxide 0.01 Fenarimol 0.01 Fenazaquin 0.01 Fenbuconazole 0.01 Fenhexamid 0.01 Fenitrothion 0.01 -
A Pesticide Decision-Making Guide to Protect Pollinators in Landscape
A Pesticide Decision-Making Guide to Protect Pollinators in Landscape, Ornamental and Turf Management 2019 Edition By Maria van Dyke, Emma Mullen, Dan Wixted, and Scott McArt Pollinator Network at Cornell, 2018 Cornell University, Department Of Entomology Download this guide for free from: https://pollinator.cals.cornell.edu/resources/grower-resources/ Contents Choosing lower-risk pesticides for pollinators in landscape, ornamental & turf management ____ 1 How to use this guide 3 Understanding the terms in this guide 4 EPA Pesticide toxicity standards 4 Synergistic Interactions 4 Systemic Pesticides 4 Adjuvants and/or inert ingredients 5 Tying it all together: adopting an Integrated Pest and Pollinator Management (IPPM) approach 5 IPPM: Putting the “pollinator” in IPM: 6 Table 1: Product formulations and their active ingredients 7 Table 2: Pesticide synergies and acute, chronic, and sublethal toxicities for honey bees and other pollinators 10 Literature cited 25 Appendix A: Pollination contract ______________________________________________________ 29 Acknowledgments This research and development of this guide was supported by the New York State Environmental Protection Fund and New York Farm Viability Institute grant FOC 17-001. The expert advice and consultation provided by Dan Wixted of the Cornell Pesticide Management Education Program was supported by the Crop Protection and Pest Management Extension Implementation Program [grant no. 2017-70006-27142/project accession no. 1014000] from the USDA National Institute of Food and Agriculture. 1 Choosing lower-risk pesticides for pollinators in landscape, ornamental & turf management Managing pests on ornamentals, in landscapes, and in nurseries while protecting pollinators can be a balancing act. Pollinators (mostly bees) are busy pollinating blossoms in nurseries and landscapes at the same time growers and landscapers need to be managing specific pests and diseases. -
UNITED NATIONS Stockholm Convention on Persistent Organic
UNITED NATIONS SC UNEP/POPS/POPRC.8/INF/12 Distr.: General 14 August 2012 English only Stockholm Convention on Persistent Organic Pollutants Persistent Organic Pollutants Review Committee Eighth meeting Geneva, 15–19 October 2012 Item 5 (e) and (f) of the provisional agenda* Technical work: assessment of alternatives to endosulfan; assessment of alternatives to DDT Report on the assessment of chemical alternatives to endosulfan and DDT Note by the Secretariat As referred to in documents UNEP/POPS/POPRC.8/8 and UNEP/POPS/POPRC.8/9, the report on the assessment of chemical alternatives to endosulfan and DDT is set out in the annex to the present note; it has not been formally edited. * UNEP/POPS/POPRC.8/1. K1282318 040912 UNEP/POPS/POPRC.8/INF/12 Annex Report on the assessment of chemical alternatives to endosulfan and DDT Draft prepared by the ad hoc working group on assessment of alternatives to endosulfan and DDT under the POPs Review Committee of the Stockholm Convention July 2012 2 UNEP/POPS/POPRC.8/INF/12 Table of Content 1. Disclaimer 2. Background and proposed results 3. Prioritization of Chemical Alternatives for Endosulfan with respect to the Persistent Organic Pollutant (POP) Characteristics (Annex D) 3.1. Introduction 3.2. Endpoint and data selection for prioritisation 3.3. Experimental information 3.4. QSAR information 3.5. Description of the data sources 3.6. Uncertainties 3.7. Data analysis 3.8. Results 3.9. Comments on selected alternative substances 4. Methodology for the assessment of persistent organic pollutant characteristics and identification of other hazard indicators for the assessment of chemical alternatives to Endosulfan and DDT 4.1. -
Pesticide Reference Values Comparison Study
Is Protecting Aquatic Life from Pesticides Sufficient to Ensure Human Health Protection in Sources of Drinking Water? Kelly D. Moran, Ph.D., TDC Environmental, LLC Bonny Starr, P.E., Starr Consulting October 1, 2018 Abstract California water and pesticides regulators have long operated under the informal assumption that programs to protect aquatic life from currently used pesticides will also ensure the safety of surface water drinKing water sources. This paper examines the scientific validity of this assumption for the agricultural pesticides in California’s Central Valley by comparing water quality regulatory values and benchmarks (“reference values”) for human health with those for aquatic life. Because numeric water quality criteria and other numeric regulatory values established for water quality protection exist for only a handful of currently used pesticides, the comparison relies heavily on US EPA pesticides human health and aquatic life benchmarks. For acute endpoints, both human health and aquatic life reference values typically use a one-day exposure time frame, but chronic endpoint exposure periods differ, with aquatic life exposure periods (4 to 60 days) usually shorter than human health exposure periods (annual). The evaluation looKed in detail at 301 agricultural pesticides with human health reference values. Of these 301 pesticides, only 46% had aquatic life reference values that were equal to or lower than the human health reference value. For 54% of these pesticides, either no aquatic life reference value existed or the aquatic life reference value was higher than the human health reference value. In these cases, aquatic life protection actions would not suffice to protect human health. -
Prohibited and Restricted Pesticides List Fair Trade USA® Agricultural Production Standard Version 1.1.0
Version 1.1.0 Prohibited and Restricted Pesticides List Fair Trade USA® Agricultural Production Standard Version 1.1.0 Introduction Through the implementation of our standards, Fair Trade USA aims to promote sustainable livelihoods and safe working conditions, protection of the environment, and strong, transparent supply chains.. Our standards work to limit negative impacts on communities and the environment. All pesticides can be potentially hazardous to human health and the environment, both on the farm and in the community. They can negatively affect the long-term sustainability of agricultural livelihoods. The Fair Trade USA Agricultural Production Standard (APS) seeks to minimize these risks from pesticides by restricting the use of highly hazardous pesticides and enhancing the implementation of risk mitigation practices for lower risk pesticides. This approach allows greater flexibility for producers, while balancing controls on impacts to human and environmental health. This document lists the pesticides that are prohibited or restricted in the production of Fair Trade CertifiedTM products, as required in Objective 4.4.2 of the APS. It also includes additional rules for the use of restricted pesticides. Purpose The purpose of this document is to outline the rules which prohibit or restrict the use of hazardous pesticides in the production of Fair Trade Certified agricultural products. Scope • The Prohibited and Restricted Pesticides List (PRPL) applies to all crops certified against the Fair Trade USA Agricultural Production Standard (APS). • Restrictions outlined in this list apply to active ingredients in any pesticide used by parties included in the scope of the Certificate while handling Fair Trade Certified products. -
Household Insects – Homeowners ` CAUTION: All Insecticides Are Toxic to Some Degree; Therefore, Care Should Be Exercised in Their Use
Household Insects – Homeowners ` CAUTION: All insecticides are toxic to some degree; therefore, care should be exercised in their use. The manufacturer’s directions on the label in the use of the material must be followed explicitly. Insect Threats Insecticides and Treatment* Remarks Ants Feed on foods and Baits (active ingredient and Remove food and clean up the area. Place (several may damage product): bait where ants occur or congregate. May species) clothing; may also sodium tetraborate decahydrate use several different baits at the same time sting, causing severe (Amdro Kills Ants Liquid Bait, Terro to discover one that ants will consume. reaction to some Liquid Ant Baits); Care should be taken not to contaminate people. hydramethylnon (Amdro Kills Ants foodstuffs. Also treat nests in yard. Follow Bait Stations and Stakes); label. orthoboric acid (Terro Perimeter Ant Bait); fipronil (Combat Max Ant Killing Bait Stations and Gel); abamectin (Raid Max Double Control Ant Baits, Raid Ant Baits III); dinotefuran (Hot Shot Ultra Clear Roach & Ant Gel Bait, Hot Shot Ultra Liquid Ant Bait); spinosad (Ortho Home Defense Liquid Ant Bait); thiamethoxam (Raid Precision Placement Ant Bait Gel) Crack and crevices: Follow label. prallethrin, esfenvalerate, pyrethrins, pyrethrum, permethrin, tetra- methrin, phenothrin, beta-cyfluthrin, cyfluthrin Indoor space: prallethrin, esfenvalerate, pyrethrins, pyrethrum, permethrin, tetramethrin, phenothrin, cyfluthrin, bifenthrin Outdoor barrier: prallethrin, esfenvalerate, permethrin, beta-cyfluthrin, cyfluthrin, bifenthrin, malathion, carbaryl Outdoor broadcast: hydramethylnon, pyriproxyfen, beta-cyfluthrin, esfenvalerate, bifenthrin, cyfluthrin, malathion, carbaryl *Labels on insecticides should state “material may be used in the household” and should be registered by the EPA for that purpose. Household Insects – Homeowners ` CAUTION: All insecticides are toxic to some degree; therefore, care should be exercised in their use. -
Pesticide Resistance in Bed Bugs Everywhere!!!!!
2/24/2018 Pesticide Resistance in Bed bugs were virtually eradicated from the U.S. in Bed Bugs the post WWII era due to DDT and other powerful Shujuan (Lucy) Li insecticides. University of Arizona Alvaro Romero New Mexico State University 2 By the 1960s, bed bugs had developed resistance Public housing Apartments to DDT, methoxychlor and analogues, BHC, Schools dieldrin and analogues , and pyrethrins ( Busvine 1958, Hospitals Nursing homes Cwilich & Mer 1957, Mallis and Miller 1964 ) . Homes Transportation Child care Medical facilities Hotels & motels Health care facilities Airports Movie theaters Department stores Products, vendors, or commercial services mentioned or pictured in this seminar are for Everywhere!!!!! illustrative purposes only and are not meant to be endorsements. 3 4 University of Arizona; Arizona Pest Management Center 1 2/24/2018 Possible reasons for treatment failure? Missed some Clutter Reintroduction Have you seen these after treatments? 5 6 Dose - response assays for field - collected strains Bed bugs survived direct insecticide sprays 99 deltamethrin 90 Ft. Dix F1 50 ) e l a c 10 s t CIN1 i b o 1.0 r p ( y t i l a t r 99 - cyhalothrin o m e 90 g a t n Resistance ratio (RR) at least 6,000 !!! e c Ft. Dix r 50 e P 10 CIN1 Suspend® ( Deltamethrin ) 1.0 10 -7 10 -6 10 -5 10 -4 10 -3 10 -2 10 -1 10 0 10 1 10 2 10 3 10 4 Treatment (mg active ingredient/cm 2 ) Products, vendors, or commercial services mentioned or pictured in this seminar are for illustrative purposes only and are not meant Romero et al. -
Recommended Classification of Pesticides by Hazard and Guidelines to Classification 2019 Theinternational Programme on Chemical Safety (IPCS) Was Established in 1980
The WHO Recommended Classi cation of Pesticides by Hazard and Guidelines to Classi cation 2019 cation Hazard of Pesticides by and Guidelines to Classi The WHO Recommended Classi The WHO Recommended Classi cation of Pesticides by Hazard and Guidelines to Classi cation 2019 The WHO Recommended Classification of Pesticides by Hazard and Guidelines to Classification 2019 TheInternational Programme on Chemical Safety (IPCS) was established in 1980. The overall objectives of the IPCS are to establish the scientific basis for assessment of the risk to human health and the environment from exposure to chemicals, through international peer review processes, as a prerequisite for the promotion of chemical safety, and to provide technical assistance in strengthening national capacities for the sound management of chemicals. This publication was developed in the IOMC context. The contents do not necessarily reflect the views or stated policies of individual IOMC Participating Organizations. The Inter-Organization Programme for the Sound Management of Chemicals (IOMC) was established in 1995 following recommendations made by the 1992 UN Conference on Environment and Development to strengthen cooperation and increase international coordination in the field of chemical safety. The Participating Organizations are: FAO, ILO, UNDP, UNEP, UNIDO, UNITAR, WHO, World Bank and OECD. The purpose of the IOMC is to promote coordination of the policies and activities pursued by the Participating Organizations, jointly or separately, to achieve the sound management of chemicals in relation to human health and the environment. WHO recommended classification of pesticides by hazard and guidelines to classification, 2019 edition ISBN 978-92-4-000566-2 (electronic version) ISBN 978-92-4-000567-9 (print version) ISSN 1684-1042 © World Health Organization 2020 Some rights reserved.