The Picking Table Volume 17, No. 1
Total Page:16
File Type:pdf, Size:1020Kb
Load more
Recommended publications
-
L. Jahnsite, Segelerite, and Robertsite, Three New Transition Metal Phosphate Species Ll. Redefinition of Overite, an Lsotype Of
American Mineralogist, Volume 59, pages 48-59, 1974 l. Jahnsite,Segelerite, and Robertsite,Three New TransitionMetal PhosphateSpecies ll. Redefinitionof Overite,an lsotypeof Segelerite Pnur BnnN Moone Thc Departmcntof the GeophysicalSciences, The Uniuersityof Chicago, Chicago,Illinois 60637 ilt. lsotypyof Robertsite,Mitridatite, and Arseniosiderite Peur BmaN Moonp With Two Chemical Analvsesbv JUN Iro Deryrtrnent of GeologicalSciences, Haraard Uniuersity, Cambridge, Massrchusetts 02 I 38 Abstract Three new species,-jahnsite, segelerite, and robertsite,-occur in moderate abundance as late stage products in corroded triphylite-heterosite-ferrisicklerite-rockbridgeite masses, associated with leucophosphite,hureaulite, collinsite, laueite, etc.Type specimensare from the Tip Top pegmatite, near Custer, South Dakota. Jahnsite, caMn2+Mgr(Hro)aFe3+z(oH)rlPC)oln,a 14.94(2),b 7.14(l), c 9.93(1)A, p 110.16(8)", P2/a, Z : 2, specific gavity 2.71, biaxial (-), 2V large, e 1.640,p 1.658,t l.6lo, occurs abundantly as striated short to long prismatic crystals, nut brown, yellow, yellow-orange to greenish-yellowin color.Formsarec{001},a{100},il2oll, jl2}ll,ft[iol],/tolll,nt110],andz{itt}. Segeierite,CaMg(HrO)rFes+(OH)[POdz, a 14.826{5),b 18.751(4),c7.30(1)A, Pcca, Z : 8, specific gaavity2.67, biaxial (-), 2Ylarge,a 1.618,p 1.6t5, z 1.650,occurs sparingly as striated yellow'green prismaticcrystals, with c[00], r{010}, nlll0l and qll2l } with perfect {010} cleavage'It is the Feg+-analogueofoverite; a restudy on type overite revealsthe spacegroup Pcca and the ideal formula CaMg(HrO)dl(OH)[POr]r. Robertsite,carMna+r(oH)o(Hro){Ponlr, a 17.36,b lg.53,c 11.30A,p 96.0o,A2/a, Z: 8, specific gravity3.l,T,cleavage[l00] good,biaxial(-) a1.775,8 *t - 1.82,2V-8o,pleochroismextreme (Y, Z = deep reddish brown; 17 : pale reddish-pink), @curs as fibrous massesand small wedge- shapedcrystals showing c[001 f , a{1@}, qt031}. -
Mineral Processing
Mineral Processing Foundations of theory and practice of minerallurgy 1st English edition JAN DRZYMALA, C. Eng., Ph.D., D.Sc. Member of the Polish Mineral Processing Society Wroclaw University of Technology 2007 Translation: J. Drzymala, A. Swatek Reviewer: A. Luszczkiewicz Published as supplied by the author ©Copyright by Jan Drzymala, Wroclaw 2007 Computer typesetting: Danuta Szyszka Cover design: Danuta Szyszka Cover photo: Sebastian Bożek Oficyna Wydawnicza Politechniki Wrocławskiej Wybrzeze Wyspianskiego 27 50-370 Wroclaw Any part of this publication can be used in any form by any means provided that the usage is acknowledged by the citation: Drzymala, J., Mineral Processing, Foundations of theory and practice of minerallurgy, Oficyna Wydawnicza PWr., 2007, www.ig.pwr.wroc.pl/minproc ISBN 978-83-7493-362-9 Contents Introduction ....................................................................................................................9 Part I Introduction to mineral processing .....................................................................13 1. From the Big Bang to mineral processing................................................................14 1.1. The formation of matter ...................................................................................14 1.2. Elementary particles.........................................................................................16 1.3. Molecules .........................................................................................................18 1.4. Solids................................................................................................................19 -
Scandiobabingtonite, a New Mineral from the Baveno Pegmatite
American Mineralogist, Volume 83, pages 1330-1334, 1998 Scandiobabingtonite,a new mineral from the Bavenopegmatite, Piedmont, Italy Ploro ORl.tNnIrr'* Ma,nco PasERorr and GrovlNNa Vn,zzllrNr2 rDipartimento di Scienzedella Terra, Universitd di Pisa, Via S. Maria 53,1-56126 Pisa, Italy '?Dipartimento di Scienzedella Terra, Universitd di Modena, Via S Eufemia 19, I-41 100 Modena, Italy Ansrntcr Scandiobabingtonite,ideally Ca,(Fe,*,Mn)ScSi,O,o(OH) is the scandium analogue of babingtonite; it was found in a pegmatitic cavity of the Baveno granite associatedwith orthoclase, albite, muscovite, stilbite, and fluorite. Its optics are biaxial (+) with 2V : : ^v: 64(2)",ct 1.686(2),P: 1.694(3), 1.709(2).D-"." : 3.24(5)slcm3, D.",.:3.24 sl cm3, and Z : 2. Scandiobabingtoniteis colorless or pale gray-green, transparent,with vitreous luster. It occurs as submillimeter sized, short, tabular crystals, slightly elongated on [001],and characterizedby the associationof forms {010}, {001}, {110}, {110}, and {101}. It occurs also as a thin rim encrustingsmall crystals of babingtonite.The strongest lines in the X-ray powder pauern are at2.969 (S), 2.895 (S), 3.14 (mS), and 2.755 (mS) 4. fn" mineralis triclinic, ipu.. g.oup PT, with a : 7.536(2),b : 1L734(2),c : 6.t48(Z) A, : 91.10(2), : 93.86(2), : lO+.S:(2)'. Scandiobabingtoniteis isostructural " B r with babingtonite, with Sc replacing Fe3* in sixfold coordination, but no substitution of Fer* by Sc takes place. Due to the lack of a suitably large crystal of the new species, such a replacementhas been confirmed by refining the crystal structure of a Sc-rich babingtonite (final R : O.O47)using single-crystal X-ray diffraction (XRD) data. -
New Mineral Names*,†
American Mineralogist, Volume 106, pages 1360–1364, 2021 New Mineral Names*,† Dmitriy I. Belakovskiy1, and Yulia Uvarova2 1Fersman Mineralogical Museum, Russian Academy of Sciences, Leninskiy Prospekt 18 korp. 2, Moscow 119071, Russia 2CSIRO Mineral Resources, ARRC, 26 Dick Perry Avenue, Kensington, Western Australia 6151, Australia In this issue This New Mineral Names has entries for 11 new species, including 7 minerals of jahnsite group: jahnsite- (NaMnMg), jahnsite-(NaMnMn), jahnsite-(CaMnZn), jahnsite-(MnMnFe), jahnsite-(MnMnMg), jahnsite- (MnMnZn), and whiteite-(MnMnMg); lasnierite, manganflurlite (with a new data for flurlite), tewite, and wumuite. Lasnierite* the LA-ICP-MS analysis, but their concentrations were below detec- B. Rondeau, B. Devouard, D. Jacob, P. Roussel, N. Stephant, C. Boulet, tion limits. The empirical formula is (Ca0.59Sr0.37)Ʃ0.96(Mg1.42Fe0.54)Ʃ1.96 V. Mollé, M. Corre, E. Fritsch, C. Ferraris, and G.C. Parodi (2019) Al0.87(P2.99Si0.01)Ʃ3.00(O11.41F0.59)Ʃ12 based on 12 (O+F) pfu. The strongest lines of the calculated powder X-ray diffraction pattern are [dcalc Å (I%calc; Lasnierite, (Ca,Sr)(Mg,Fe)2Al(PO4)3, a new phosphate accompany- ing lazulite from Mt. Ibity, Madagascar: an example of structural hkl)]: 4.421 (83; 040), 3.802 (63, 131), 3.706 (100; 022), 3.305 (99; 141), characterization from dynamic refinement of precession electron 2.890 (90; 211), 2.781 (69; 221), 2.772 (67; 061), 2.601 (97; 023). It diffraction data on submicrometer sample. European Journal of was not possible to perform powder nor single-crystal X-ray diffraction Mineralogy, 31(2), 379–388. -
Palermo Zanazziite (Pdf)
A Palermo Mineral Identification Search Tom Mortimer Forward: Mineral collectors take great satisfaction in placing accurate labels on their specimens. This article follows my 22 year quest to identify a self-collected Palermo specimen. I have recently narrowed my initial choices to the most plausible species. However my investigation illustrates that even those collectors with access to modern tools of mineral ID such as EDS, they may still be left with ambiguities. This is the forth re-write of this article. My thanks to Jim Nizamoff and Bob Wilken for their most helpful reviews. Background: Locality: Palermo #1 Mine, N. Groton, NH Specimen Size: 2.8 cm specimen Field Collected: Tom Mortimer - 1997 Catalog No.: # 217 Notes: This specimen was in my NH Species Display as fairfieldite for several years. It was visually identified by Bob Whitmore as fairfieldite. I understood that this was the spherical form of fairfieldite referred to in Bob Whitmore's book, The Pegmatite Mines Known as Palermo. The Story: A goal of my New Hampshire mineral species web site and display is to confirm species with analytic testing. This is particularly true for uncommon species and specimens where a visual identification is problematic. A 2017 investigation of NH fairfieldite and messelite revealed that my specimen #217 was not fairfieldite. A first polished grain Energy Dispersive Analysis (EDS) (BC77a – set 6) indicated a Ca, Mg, Fe, phosphate with a Ca:Fe:Mg:P ratio of about 2:1:1.4:5. No Mn was detected, 2+ 2+ essential for fairfieldite. Fairfieldite chemistry is: Ca2(Mn ,Fe )(PO4)2 · 2H2O . -
Gatehouseite Mn (PO4)2(OH)4
2+ Gatehouseite Mn5 (PO4)2(OH)4 c 2001-2005 Mineral Data Publishing, version 1 Crystal Data: Orthorhombic. Point Group: 222. As bladelike crystals, with prominent {001}, {110}, {102}, elongated along [010], to 100 µm, in radiating to divergent groups and overgrowths on arsenoclasite. Twinning: On {001}, contact twins. Physical Properties: Cleavage: On {010}, distinct. Fracture: Splintery. Hardness = ∼4 D(meas.) = n.d. D(calc.) = 3.74 Optical Properties: Transparent. Color: Pale brownish orange to yellow or pale yellow. Streak: Pale yellow. Luster: Adamantine. Optical Class: Biaxial. Pleochroism: Distinct; brown to nearly colorless. Orientation: Parallel extinction; length-slow. α = 1.74(1) β = n.d. γ = 1.76(1) 2V(meas.) = n.d. Cell Data: Space Group: P 212121 (probable). a = 9.097(2) b = 5.693(2) c = 18.002(10) Z=4 X-ray Powder Pattern: Iron Monarch quarry, Australia. 2.90 (100), 2.702 (80), 2.853 (70), 2.802 (50), 2.022 (15), 1.608 (15), 4.483 (10) Chemistry: (1) (2) (3) SO3 0.10 P2O5 22.18 23.05 26.65 As2O5 3.58 3.32 V2O5 0.38 Al2O3 0.10 FeO 0.19 0.32 MnO 64.42 63.34 66.59 CuO 0.03 0.04 ZnO 0.03 PbO 0.05 0.05 H2O [6.44] [6.43] 6.76 Total [97.40] [96.65] 100.00 (1) Iron Monarch quarry, Australia; by electron microprobe, total Mn as MnO, total Fe as FeO, H2O calculated for 4(OH); corresponds to Mn5.09Fe0.01Al0.01[(P0.87As0.08V0.01)Σ=0.96O4]2(OH)4. -
A New Mineralspeciesfromthe Tip Top Pegmatite, Custer County, South Dakota, and Its Relationship to Robertsite'
Canadian Mineralogist Vol. 27, pp. 451-455 (1989) PARAROBERTSITE, Ca2Mn~+(P04h02.3H20, A NEW MINERALSPECIESFROMTHE TIP TOP PEGMATITE, CUSTER COUNTY, SOUTH DAKOTA, AND ITS RELATIONSHIP TO ROBERTSITE' ANDREW C. ROBERTS Geological Survey of Canada, 601 Booth Street, Ottawa, Ontario KIA OE8 B. DARKO STURMAN Departmentof Mineralogy,Royal OntarioMuseum, Toronto, OntarioM5S 2C6 PETE J. DUNN Departmentof MineralSciences,SmithsonianInstitution,Washington,D.C. 20560,U.S.A. WILLARD L. ROBERTS* South DakotaSchoolof Minesand Technology,Rapid City, South Dakota57701,U.S.A. ABSTRACT SOMMAIRE Pararobertsite is rare, occurring as thin red transparent La pararobertsite, espece rare, se presente sous forme single plates, or clusters of plates, on whitlockite at the Tip de plaquettes isolees minces et rouge transparent, ou en Top pegmatite, Custer County, South Dakota. Associated agregats de telles plaquettes, situees sur la whitlockite dans minerals are carbonate-apatite and quartz. Individual crys- la pegmatite de Tip Top, comte de Custer, Dakota du Sud. tals are tabular on {100}, up to 0.2 mm long and are less Lui sont associes apatite carbonatee et quartz. Les plaquet- than 0.02 mm in thickness. The streak is brownish red; tes, tabulaires sur {IOO}, atteignent une longueur de 0.2 luster vitreous; brittle; cleavage on {I oo} perfect; indiscer- mm et moins de 0.02 mm en epaisseur. La rayure est rouge nible fluorescence under long- or short-wave ultraviolet brunatre, et l' eclat, vitreux; cassante; clivage {100} par- light; hardness could not be determined, but the mineral fait; fluorescence non-discernable en lumiere ultra-violette apparently is very soft; D (meas.) 3.22 (4), D (calc.) 3.22 (onde courte ou longue); la durete, quoique indeterminee, (for the empirical formula) or 3.21 g/cm3 (for the ideal- semble tres faible; Dmes 3.22(4), Deale 3.22 (formule empi- ized formula). -
STRONG and WEAK INTERLAYER INTERACTIONS of TWO-DIMENSIONAL MATERIALS and THEIR ASSEMBLIES Tyler William Farnsworth a Dissertati
STRONG AND WEAK INTERLAYER INTERACTIONS OF TWO-DIMENSIONAL MATERIALS AND THEIR ASSEMBLIES Tyler William Farnsworth A dissertation submitted to the faculty at the University of North Carolina at Chapel Hill in partial fulfillment of the requirements for the degree of Doctor of Philosophy in the Department of Chemistry. Chapel Hill 2018 Approved by: Scott C. Warren James F. Cahoon Wei You Joanna M. Atkin Matthew K. Brennaman © 2018 Tyler William Farnsworth ALL RIGHTS RESERVED ii ABSTRACT Tyler William Farnsworth: Strong and weak interlayer interactions of two-dimensional materials and their assemblies (Under the direction of Scott C. Warren) The ability to control the properties of a macroscopic material through systematic modification of its component parts is a central theme in materials science. This concept is exemplified by the assembly of quantum dots into 3D solids, but the application of similar design principles to other quantum-confined systems, namely 2D materials, remains largely unexplored. Here I demonstrate that solution-processed 2D semiconductors retain their quantum-confined properties even when assembled into electrically conductive, thick films. Structural investigations show how this behavior is caused by turbostratic disorder and interlayer adsorbates, which weaken interlayer interactions and allow access to a quantum- confined but electronically coupled state. I generalize these findings to use a variety of 2D building blocks to create electrically conductive 3D solids with virtually any band gap. I next introduce a strategy for discovering new 2D materials. Previous efforts to identify novel 2D materials were limited to van der Waals layered materials, but I demonstrate that layered crystals with strong interlayer interactions can be exfoliated into few-layer or monolayer materials. -
A Specific Gravity Index for Minerats
A SPECIFICGRAVITY INDEX FOR MINERATS c. A. MURSKyI ern R. M. THOMPSON, Un'fuersityof Bri.ti,sh Col,umb,in,Voncouver, Canad,a This work was undertaken in order to provide a practical, and as far as possible,a complete list of specific gravities of minerals. An accurate speciflc cravity determination can usually be made quickly and this information when combined with other physical properties commonly leads to rapid mineral identification. Early complete but now outdated specific gravity lists are those of Miers given in his mineralogy textbook (1902),and Spencer(M,i,n. Mag.,2!, pp. 382-865,I}ZZ). A more recent list by Hurlbut (Dana's Manuatr of M,i,neral,ogy,LgE2) is incomplete and others are limited to rock forming minerals,Trdger (Tabel,l,enntr-optischen Best'i,mmungd,er geste,i,nsb.ildend,en M,ineral,e, 1952) and Morey (Encycto- ped,iaof Cherni,cal,Technol,ogy, Vol. 12, 19b4). In his mineral identification tables, smith (rd,entifi,cati,onand. qual,itatioe cherai,cal,anal,ys'i,s of mineral,s,second edition, New york, 19bB) groups minerals on the basis of specificgravity but in each of the twelve groups the minerals are listed in order of decreasinghardness. The present work should not be regarded as an index of all known minerals as the specificgravities of many minerals are unknown or known only approximately and are omitted from the current list. The list, in order of increasing specific gravity, includes all minerals without regard to other physical properties or to chemical composition. The designation I or II after the name indicates that the mineral falls in the classesof minerals describedin Dana Systemof M'ineralogyEdition 7, volume I (Native elements, sulphides, oxides, etc.) or II (Halides, carbonates, etc.) (L944 and 1951). -
Shigaite Namn Al3(SO4)
2+ • Shigaite NaMn6 Al3(SO4)2(OH)18 12H2O c 2001-2005 Mineral Data Publishing, version 1 Crystal Data: Hexagonal. Point Group: 3. Hexagonal tabular crystals, to 2 cm, may be in groups; as thin films and fracture coatings. Twinning: On {0001}. Physical Properties: Cleavage: On {0001}, perfect. Tenacity: Moderately flexible. Hardness = ∼2 D(meas.) = 2.32 D(calc.) = 2.35 Optical Properties: Semitransparent. Color: Pale yellow, bright yellow, golden yellow, burnt orange; brownish yellow if included, brown to black if altered. Streak: Very pale yellow to white. Luster: Vitreous to dull. Optical Class: Uniaxial (–). Pleochroism: Distinct; O = yellow; E = very pale yellow. Absorption: O > E. ω = 1.546 = n.d. Cell Data: Space Group: R3. a = 9.51–9.52 c = 32.83–33.074 Z = 3 X-ray Powder Pattern: Ioi mine, Japan. 10.89 (100), 5.47 (90), 2.457 (90), 3.664 (80), 2.198 (60), 1.944 (60), 4.36 (40) Chemistry: (1) (2) (3) SO3 13.6 12.75 13.95 Al2O3 15.3 11.8 13.32 Fe2O3 0.9 2.6 MnO 41.7 42.1 37.08 MgO 0.25 Na2O n.d. n.d. 2.70 H2O 28.0 [30.5] 32.95 Total 99.5 [100.0] 100.00 (1) Ioi mine,Japan; by electron microprobe, total Fe as Fe2O3, total Mn as MnO, H2Oby TGA-EGA. (2) Iron Monarch quarry, Australia; by electron microprobe, average of two analyses, • total Fe as Fe2O3, total Mn as MnO, H2O by difference. (3) NaMn6Al3(SO4)2(OH)18 12H2O. Occurrence: A rare secondary mineral in metamorphosed manganese ore deposits. -
Aluminium-Bearing Strunzite Derived from Jahnsite at the Hagendorf-Su¨D Pegmatite, Germany
Mineralogical Magazine, October 2012, Vol. 76(5), pp. 1165–1174 Aluminium-bearing strunzite derived from jahnsite at the Hagendorf-Su¨d pegmatite, Germany 1, 1 2 3 I. E. GREY *, C. M. MACRAE ,E.KECK AND W. D. BIRCH 1 CSIRO Process Science and Engineering, Box 312 Clayton South, Victoria 3169, Australia 2 Algunderweg 3, D À 02694 Etzenricht, Germany 3 Geosciences, Museum Victoria, GPO Box 666, Melbourne, Victoria 3001, Australia [Received 15 May 2012; Accepted 23 July 2012; Associate Editor: Giancarlo Della Ventura] ABSTRACT 2+ 3+ Aluminium-bearing strunzite, [Mn0.65Fe0.26Zn0.08Mg0.01] [Fe1.50Al0.50] (PO4)2(OH)2·6H2O, occurs as fibrous aggregates in a crystallographically oriented association with jahnsite on altered zwieselite samples from the phosphate pegmatite at Hagendorf Su¨d, Bavaria, Germany. Synchrotron X-ray data were collected from a 3 mm diameter fibre and refined in space group P1¯ to R1 = 0.054 for 1484 observed reflections. The refinement confirmed the results of chemical analyses which showed that one quarter of the trivalent iron in the strunzite crystals is replaced by aluminium. The paragenesis revealed by scanning electron microscopy, in combination with chemical analyses and a crystal-chemical comparison of the strunzite and jahnsite structures, are consistent with strunzite being formed from jahnsite by selective leaching of (100) metalÀphosphate layers containing large divalent Ca and Mn atoms. KEYWORDS: Al-bearing strunzite, strunzite paragenesis, strunzite structure refinement, Hagendorf Su¨d secondary phosphates. Introduction The feldspar pegmatite at Hagendorf Su¨d, 2+ 3+ STRUNZITE, ideally Mn Fe2 (PO4)2(OH)2·6H2O, Bavaria, contains a large number of secondary is a relatively rare secondary phosphate mineral Al-phosphates including eosphorite, kingsmoun- found in altered granitic pegmatites (Moore, tite, paravauxite, fluellite, morinite, variscite, 1965; Viana and Prado, 2007; Dill et al., 2008). -
Description and Unique Crystal-Structure of Waterhouseite, a New Hydroxy Manganese Phosphate Species from the Iron Monarch Deposit, Middleback Ranges, South Australia
1401 The Canadian Mineralogist Vol. 43, pp. 1401-1410 (2005) DESCRIPTION AND UNIQUE CRYSTAL-STRUCTURE OF WATERHOUSEITE, A NEW HYDROXY MANGANESE PHOSPHATE SPECIES FROM THE IRON MONARCH DEPOSIT, MIDDLEBACK RANGES, SOUTH AUSTRALIA ALLAN PRING§ Department of Mineralogy, South Australian Museum, North Terrace, Adelaide, South Australia 5000, and School of Earth & Environmental Science, University of Adelaide, Adelaide, S.A. 5005, Australia UWE KOLITSCH Institut für Mineralogie und Kristallographie, Geozentrum, Universität Wien, Althanstr. 14, A–1090 Wien, Austria WILLIAM D. BIRCH Department of Mineralogy, Museum of Victoria, GPO Box 666E, Melbourne, Victoria, 3000, Australia ABSTRACT Waterhouseite from the Iron Monarch mine, Iron Knob, South Australia, is a new hydroxy manganese phosphate species that has a unique crystal-structure. The mineral was found in a carbonate-rich zone with gatehouseite, seamanite, rhodochrosite, shigaite, barite, hausmannite and hematite. It occurs as divergent sprays of orange-brown to dark brown bladed crystals up to 1 mm in length but only up to 20 m in thickness. The crystals are transparent with a pearly luster on cleavages, but it is vitreous to pearly on the tabular faces. The mineral is brittle, with a conchoidal fracture and a yellowish brown streak. There is a perfect cleavage on (100) and a probable cleavage on (001). The crystals show the principal forms {100} (dominant), {010}, {011} and {001}. All crystals are twinned on (100) by non-merohedry. The Mohs hardness is estimated to be ~4, and the measured density is 3.55(5) g/cm3 (calculated density is 3.591 g/cm3). Crystals are biaxial negative and length-slow, with ␣ 1.730(3),  ~1.738 and ␥ 1.738(4), but 2V could not be measured.