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SHORT COMMUNICATION INCIDENCE OF GOLD IN SUBGREENSCHIST TO GREENSCHIST FACIES METABASALT OF BHOWALI, NAINITAL DISTRICT, UTTARANCHAL RAVISHANKER I, S . NAG^ and S . SHOME' Geological Survey of India, 'Kolkata, 'Lucknow Mesoproterozoic metavolcano-sedimentary sequence The purpose of the present paper is to report the in and around Bhowali-Khairna area, Uttaranchal, incidence of gold in the metabasalts of Bhowali for the first constitute mostly metabasalts with quartzites, phyllites time and propose a probable mechanism by which gold and variegated slates, referable to Bhimtal Formation. was deposited. Our study was centred on metabasalts and the rocks occurring in close spatial association with them. Detailed PETROLOGY petro-mineralogical and SEM-EDS studies have revealecl the presence of gold which we report here for the first Within the limits of study area (Fig. I), the rock types time. Of the two types of metabasalts viz., massive, encountered are: (I) dark greenish, predominantly massive, crudely foliated type and foliated type, both showing compact and rarely crudely foliated basalt with vesicles, mineralogical assemblages of subgreenschist facies and (2) greenish, aphanitic, often foliated basalt, (3) dark greenschist facies respectively, gold is commonly found greenish, well foliated tuff, often appearing as chlorite in the foliated type and rarely in the massive type. schist and (4) quartzite with pebbles at places, subordinate Presence of gold as tiny grains in disseminated fashion grit, phyllite and variegated slate. Late stage quartz- suggest that widespread hydrothermal activity caused calcite-epidote veins are conspicuous in these basalts precipitation of gold after the rocks had witnessed peak and occasionally these veins produce anastomosing metamorphism. patterns. The massive, crudely foliated basalt (hereafter called CMIZ) comprise albite with minor oligoclase, amphibole INTRODUCTION (actinolite-ferroactinolite,following IMA nomenclature, The Bkowali (29O23'10"N : 79"30150"E)metabasalt and Leake et al. 1997), clinopyroxene (mostly augite to diopsidic associated quartzite with subordinate grit, phyllite and slate augite, following IMA nomenclature, Morimoto et al. 1988), constitute the Bhimtal Formation. The metabasalts occupy chlorite, epidote, quartz, pumpell yite, sphene, calcite, the core of a distorted anticline trending NW-SE magnetite, hematite, pyrite, occasional chalcopyrite and rare (Varadarajan, 1974; Raina and Dungrakoti, 1975; Pal and prehnite as replacement of augite (Varadarajan, 1974) and Merh, 1974; Shah and Merh, 1976). With a view to calcic plagioclase (this study). developing a logical petrogenetic model of evolution of In aphanitic foliated basalt (hereafter called AFB), the these metabasalts and understanding the effects of mineralogical assemblages are albite, chlorite, amphibole associated hydrothermal processes, detailed petrographic (actinolite-ferroactinolite with rare ferroactinoli tic studies coupled with mineral chemistry, whole rock hornblende, following IMA nomenclature, Leake et al. chemistry (major, trace by XRF, AAS and REE by NAA 1997), epidote, calcite, quartz, sphene, muscovite, pyrite, methods') were carried out on rocks exposed between magnetite with rims of titanomagnetite, occasional biotite Khairna (29'29'42"N : 79'28'55"E) and Naukuchiyatal and stipnomelane. Pumpellyite and prehnite are (29" 19'35"N : 79O35'00"E). To understand the detailed characteristically absent in this rock. Epidote composition mineral chemistry, selected samples of metabasalts were (pistacite, Fe+3/(Fe+3+A1)usually range from 0.28-0.35 in analysed by electron microprobe (using Cameca SX 5 1 AFB rocks whereas in CMB rocks the same range from electron microprobe) followed by SEM-EDS (using LEO 0.18-0.32, a feature similarly observed in the prehnite- S-440 scanning electron microscope). EDS analyses were pumpellyite (0.18-0.32) and greenschist (0.21-0.35) facies done using Oxford Link ISIS system at an accelerating metabasites of Smartville Complex, California (Springer voltage of 20 kV and filament current of 5mA. et a1. 1992). JOUR.GEOL.SOC.INDIA,VOL.59, APRIL 2002 RAVI SHANKER AND OTHERS Meso Proterozoic hnrritpur Granite Meso- to Pnleo- Pmtcwroic efl Rmgarh Gmup Poleo Proterozoic MBT - Main Boundary Thrust RT = .Ramgarh Thnrst Fig.1. Geological map of the area around Bhowali, Nainital District, Uttaranchal (modified after Ravi Shanker et al. 1989). In both CMB and AFB, very minute grains of monazite material present in this rock may result from alteration of (usally 2-5 pm) and zircon (maximum up to 10 pm) in the original volcanic ash or release of Fe-oxide during late groundmass were detected through SEM-EDS studies. stage deuteric alteration of tuffs. Minor jarosite is present in these rocks and it has been While carrying out SEM-EDS analysis on samples of confirmed also through detailed XRD studies. metabasalts, we have found specks of gold, mostly in Am. The tuffaceous rocks essentially comprise dominant Gold occurs as dissemination in the groundmass, interstitial chlorite, which impart a foliation to the rock, along with to mafic and felsic silicates and also in close association cryptocrystalline to cherty silica, tiny streaks of brownish with pyrite. Altogether 13 selected samples (mostly fermginous clayey material and small anhedral quartz metabasalts and one each of quartzite and intrusive Amritpur grains occurring in random fashion. The brownish clayey granite) were studied by SEM-EDS and presence of gold JOUR.GEOL.SOC,INDIA,VOL.59, APRIL 202 INCIDENCE OF GOLD IN SUBGREENSCHIST TO GREENSCHIST FACIES METABASALT OF BHOWALI 38 1 was confirmed only in two samples of AFB from Ratighat The mineralogical assemblages in CMB rocks, represent (sp. no. RTG-711) and Naukuchiyatal (sp. no. NKT-24) and a high pressure series and correspond to pumpellyite- one sample of CMB from Bhimtal (sp. no. BMT-27). actinolite facies without prehnite and prehnite-pumpellyite facies with prehnite corresponding to high-P and low-P bathozones in the system Ca0-Mg0-A120,-Si02-H,0 DISCUSSION (Powell et al. 1993). Phillips and Brown (1987) have shown In most orogenic belts, subgreenschist and greenschist that in the greenschist facies, metabasites have typical facies metamorphic rocks are widespread. The assemblages assemblage of actinolite + chlorite + epidote + albite + calcite of minerals in metabasites are sensitive indicators of + quartz + pyrite. The mineralogical assemblage in AFB of metamorphic grade. The low-temperature mineral equilibria Bhowali thus clearly indicate that the rocks had undergone (Liou et al. 1985, 1987; Frey et al. 1991) of these rocks greenschist facies of metamorphism. have provided a useful petrogenetic grid for metamorphism In the background of transition of burial metamorphic of model basaltic system at low-temperature (Powell et al. (subgreenschist facies)- to regional metamorphic (green- 1993). schist facies) rocks at Bhowali we have recorded the Fig.2. Representative BSE image showing (a) specks of gold as interstitial to felsic silicates (scale bar = 1 pm) and (b) disseminated gold grains in groundmass silicates (left, scale bar = 20 pm) and the same magnified image (right, scale bar = 10 pm). Fig.3. Showing energy dispersive spectral lines of gold grains as shown in Fig.LZ(a) and (b). JOUR.GEOL.SOC.INDIA,VOL.59, APRIL 2002 382 RAVI SHANKER AND OTHERS Table 1. Reprcscntative SEM-EDS analyses of gold grains in metabasnlts clinopyroxene or glassy material, although second of Rhowali, Nainital. generation primary crystallized chlorite is common and Sp. Nos. RTG-711 BMT-27 usually occurs as infillings in the vesicular cavities. Fc 1.26 1.37 Uralitisation of clinopyroxene is common, apart from Mo 0.60 independent amphibole crystals. Epidote occurs as patches, W 5.87 discrete grains, veins and sometimes in the vesicular cavities Ag 0.37 and are intimately associated with chloriteluralite. Au 66.23 75.84 Albitisation of calcic plagioclases in these rocks is Total 73.96 77.58 pronounced and breakdown of calcic plagioclase to pumpellyite and sericite are conspicuous. Tiny monazite presence of gold mostly in AFB-domain whereas in the (with 19.61-25.89 P,O,, 20.82-28.20 Ce,O,, total (REE),O, CMB-domain the same is relatively minor in proportion (including Ce,O,) ranging from 46.38-80.34 and 5.16-7.63 (Fig.2). The representative EDS analysis of elemental WO,) grains in the groundmass of albitised CMB- and AFB- abundance (%) is presented above along with energy rocks are the resuIt of hydrothermal activity. Similar dispersive spectral lines (Fig. 3) of the gold grains as shown hydrothermal monazite (Ce) in gold deposits from albitised in Fig.2. The fact that the analysed gold grain in AFB rocks is reported from Sudbury Complex, Ontario, Canada (sp. no. RTG-711) show presence of W and Mo is because (Schandl et al. 1994). Presence of jarosite in these rocks of induced effects from the adjoining monazite grains, as indicates that there were widespread hydrothermal activity. evidenced from their chemistry. The common association ofjarosite with gold is usually seen Studies on numerous gold deposits in various provinces in hydrothermal environment. Thus, the presence of (e.g. Archaean greenstones, Archaean Witwatersrand, disseminated gold and its relationship with associated Palaeozoic slate belt, Cenozoic epithermal deposits, etc.) minerals suggest that widespread hydrothermal activity have established a positive relationship between gold and caused precipitation of gold after the rocks had