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Ferric Ammonium Oxalate Hazard Summary

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Ferric Ammonium Oxalate Hazard Summary Common Name: FERRIC AMMONIUM OXALATE CAS Number: 14221-47-7 RTK Substance number: 0919 DOT Number: NA 9119 Date: August 1986 Revision: October 2001 ------------------------------------------------------------------------- ------------------------------------------------------------------------- HAZARD SUMMARY WORKPLACE EXPOSURE LIMITS * Ferric Ammonium Oxalate can affect you when breathed The following exposure limits are for soluble Iron salts in. (measured as Iron): * Contact can irritate and burn the skin and eyes. * Breathing Ferric Ammonium Oxalate can irritate the NIOSH: The recommended airborne exposure limit is 3 nose and throat causing coughing and wheezing. 1 mg/m averaged over a 10-hour workshift. * Prolonged eye contact may cause a brownish discoloration of the eyes. ACGIH: The recommended airborne exposure limit is 3 1 mg/m averaged over an 8-hour workshift. IDENTIFICATION Ferric Ammonium Oxalate is a yellowish-green, sand-like WAYS OF REDUCING EXPOSURE solid with a light, burnt-sugar odor. It is used in photography. * Where possible, enclose operations and use local exhaust ventilation at the site of chemical release. If local exhaust REASON FOR CITATION ventilation or enclosure is not used, respirators should be * Ferric Ammonium Oxalate is on the Hazardous worn. Substance List because it is cited by ACGIH, DOT, * Wear protective work clothing. NIOSH and EPA. * Wash thoroughly immediately after exposure to Ferric * Definitions are provided on page 5. Ammonium Oxalate. * Post hazard and warning information in the work area. In HOW TO DETERMINE IF YOU ARE BEING addition, as part of an ongoing education and training effort, communicate all information on the health and EXPOSED safety hazards of Ferric Ammonium Oxalate to The New Jersey Right to Know Act requires most employers potentially exposed workers. to label chemicals in the workplace and requires public employers to provide their employees with information and training concerning chemical hazards and controls. The federal OSHA Hazard Communication Standard, 1910.1200, requires private employers to provide similar training and information to their employees. * Exposure to hazardous substances should be routinely evaluated. This may include collecting personal and area air samples. You can obtain copies of sampling results from your employer. You have a legal right to this information under OSHA 1910.1020. * If you think you are experiencing any work-related health problems, see a doctor trained to recognize occupational diseases. Take this Fact Sheet with you. FERRIC AMMONIUM OXALATE page 2 of 6 This Fact Sheet is a summary source of information of all WORKPLACE CONTROLS AND PRACTICES potential and most severe health hazards that may result from exposure. Duration of exposure, concentration of the substance Unless a less toxic chemical can be substituted for a hazardous and other factors will affect your susceptibility to any of the substance, ENGINEERING CONTROLS are the most potential effects described below. effective way of reducing exposure. The best protection is to --------------------------------------------------------------------------- enclose operations and/or provide local exhaust ventilation at the site of chemical release. Isolating operations can also HEALTH HAZARD INFORMATION reduce exposure. Using respirators or protective equipment is less effective than the controls mentioned above, but is Acute Health Effects sometimes necessary. The following acute (short-term) health effects may occur immediately or shortly after exposure to Ferric Ammonium In evaluating the controls present in your workplace, consider: Oxalate: (1) how hazardous the substance is, (2) how much of the substance is released into the workplace and (3) whether * Contact can irritate and burn the skin and eyes. harmful skin or eye contact could occur. Special controls * Breathing Ferric Ammonium Oxalate can irritate the nose should be in place for highly toxic chemicals or when and throat causing coughing and wheezing. significant skin, eye, or breathing exposures are possible. Chronic Health Effects In addition, the following control is recommended: The following chronic (long-term) health effects can occur at some time after exposure to Ferric Ammonium Oxalate and * Where possible, automatically transfer Ferric Ammonium can last for months or years: Oxalate from drums or other storage containers to process containers. Cancer Hazard * According to the information presently available to the New Good WORK PRACTICES can help to reduce hazardous Jersey Department of Health and Senior Services, Ferric exposures. The following work practices are recommended: Ammonium Oxalate has not been tested for its ability to cause cancer in animals. * Workers whose clothing has been contaminated by Ferric Ammonium Oxalate should change into clean clothing Reproductive Hazard promptly. * According to the information presently available to the New * Do not take contaminated work clothes home. Family Jersey Department of Health and Senior Services, Ferric members could be exposed. Ammonium Oxalate has not been tested for its ability to * Contaminated work clothes should be laundered by affect reproduction. individuals who have been informed of the hazards of exposure to Ferric Ammonium Oxalate. Other Long-Term Effects * Eye wash fountains should be provided in the immediate work area for emergency use. * Prolonged eye contact may cause a brownish discoloration * If there is the possibility of skin exposure, emergency of the eyes. shower facilities should be provided. * On skin contact with Ferric Ammonium Oxalate, MEDICAL immediately wash or shower to remove the chemical. * Do not eat, smoke, or drink where Ferric Ammonium Medical Testing Oxalate is handled, processed, or stored, since the chemical If symptoms develop or overexposure is suspected, the can be swallowed. Wash hands carefully before eating, following are recommended: drinking, smoking, or using the toilet. * Use a vacuum or a wet method to reduce dust during clean- * Examination of the eyes. up. DO NOT DRY SWEEP. * Serum Iron tests. PERSONAL PROTECTIVE EQUIPMENT Any evaluation should include a careful history of past and present symptoms with an exam. Medical tests that look for WORKPLACE CONTROLS ARE BETTER THAN damage already done are not a substitute for controlling PERSONAL PROTECTIVE EQUIPMENT. However, for exposure. some jobs (such as outside work, confined space entry, jobs done only once in a while, or jobs done while workplace Request copies of your medical testing. You have a legal right controls are being installed), personal protective equipment to this information under OSHA 1910.1020. may be appropriate. FERRIC AMMONIUM OXALATE page 3 of 6 OSHA 1910.132 requires employers to determine the * Where the potential for high exposure exists, use a appropriate personal protective equipment for each hazard and MSHA/NIOSH approved supplied-air respirator with a full to train employees on how and when to use protective facepiece operated in a pressure-demand or other positive- equipment. pressure mode. For increased protection use in combination with an auxiliary self-contained breathing apparatus The following recommendations are only guidelines and may operated in a pressure-demand or other positive-pressure not apply to every situation. mode. Clothing QUESTIONS AND ANSWERS * Avoid skin contact with Ferric Ammonium Oxalate. Wear protective gloves and clothing. Safety equipment Q: If I have acute health effects, will I later get chronic suppliers/manufacturers can provide recommendations on health effects? the most protective glove/clothing material for your A: Not always. Most chronic (long-term) effects result from operation. repeated exposures to a chemical. * All protective clothing (suits, gloves, footwear, headgear) should be clean, available each day, and put on before Q: Can I get long-term effects without ever having short- work. term effects? A: Yes, because long-term effects can occur from repeated Eye Protection exposures to a chemical at levels not high enough to make * Wear impact resistant eye protection with side shields or you immediately sick. goggles. * Wear a face shield along with goggles when working with Q: What are my chances of getting sick when I have been corrosive, highly irritating or toxic substances. exposed to chemicals? A: The likelihood of becoming sick from chemicals is Respiratory Protection increased as the amount of exposure increases. This is IMPROPER USE OF RESPIRATORS IS DANGEROUS. determined by the length of time and the amount of Such equipment should only be used if the employer has a material to which someone is exposed. written program that takes into account workplace conditions, requirements for worker training, respirator fit testing and Q: When are higher exposures more likely? medical exams, as described in OSHA 1910.134. A: Conditions which increase risk of exposure include dust releasing operations (grinding, mixing, blasting, dumping, * NIOSH has established new testing and certification etc.), other physical and mechanical processes (heating, requirements for negative pressure, air purifying, particulate pouring, spraying, spills and evaporation from large filter and filtering facepiece respirators. The filter surface areas such as open containers), and "confined classifications of dust/mist/fume, paint spray or pesticide space" exposures (working inside vats, reactors, boilers, prefilters, and filters for radon daughters, have been small rooms, etc.). replaced
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