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United States Patent Office Patented Oct 3,535,260 United States Patent Office Patented Oct. 20, 1970 2 3,535,260 wherein R is a radical selected from the group consisting METHOD OF STABLIZNG AMONOETH of hydrogen and an alkyl having from 1 to 4 carbon ANOLAMENE SOLUTION BY ADDING atoms. A TRALKANOLAMINE Such compounds which were found to be of particular Kshatra Pati Singh, Montreal, Quebec, Canada, assignor advantage were triethanolamine, triisopropanolamine and to Union Carbide Canada Limited, Toronto, Ontario, Canada, a company of Canada triisobutanolamine. These compounds can be prepared by No Drawing. Fied Mar. 25, 1968, Ser. No. 715,566 various methods known in the art, for example, by react Int. C. B01d 47/02; C07c 91/04 ing ammonia with the corresponding alkylene oxide. U.S. C. 252--189 7 Claims It was found that the compounds of the present inven 0 tion provide most effective stability in an aqueous mono ethanolamine solution when they are present in an amount ABSTRACT OF THE DISCLOSURE of from 0.1 percent by weight to about 15 percent by weight based on the weight of monoethanolamine. A In the use of aqueous monoethanolamine solutions in particularly favourable concentration is from about 0.5 the purification of natural gas, degradation of the mono 5 percent by weight to about 5 percent by weight. ethanolamine frequently occurs due to the presence of The exact nature of the process whereby the compounds certain impurities such as hydrogen sulfide, carbonyl sul of this invention act as stabilizers in monoelkanolamine fide and mercaptains in the gas. Improved resistance to deg solutions is not known. It appears however that the deg radation is obtained by incorporating certain tertiary radation of monoethanolamine is accompanied by the amines such as triethanolamine in the monoethanolamine 20 formation of such certain degradative products of mono solution. ethanolamine. The products include: oxazolidinone-2 The present invention relates to the treating of gas with (OX) aqueous monoethanolamine to remove certain impurities (1) oxazolidinone-2 (OX). therefrom. More particularly it relates to a method and (2) N-(2-hydroxyethyl)-ethylene diamine (HEED). composition for "sweetening' natural gas by means of an 25 (3) N-(2-hydroxyethyl)-imidazolidinone-2 (IMID). aqueous monoethanolamine solution. (4) Unknown nitrogeneous and sulfur containing com The use of aqueous monoethanolamine to remove cer pounds depending upon the nature of the impurities tain impurities such as water, carbon dioxide, hydrogen present in the solution. sulfide and mercaptans from gas such as air or, natural 30 In the samples tested it was found that aqueous mono gas is well known. In the case of natural gas, purification ethanolamine solutions without a stabilizing compound systems for "sweetening' the natural gas are frequently of the present invention and tested under the conditions established at the wellhead site so that the above impuri described below in the presence of carbon dioxide and ties can be removed before the gas is delivered to a pipe hydrogen sulfide contained considerable amounts of the line. 35 four degradative products mentioned above. On the other Briefly the process of removing such impurities from hand monoethanolamine solutions containing triethanol natural gas with aqueous monoethanolamine utilizes the amine as described in Examples 3 and 4 below contained principle of absorption and adsorption wherein a solution little or no trace of such degradative products. of monoethanolamine is contacted with the sour gas in A particular test method was carried on a monoetha a tray or packed absorber at a temperature ranging from 40 nolamine solution containing certain impurities to deter 60° F. to 140 F. at moderate to high pressure. The mine the extent of degradation. The test was carried out process is usually a cyclic one wherein the monoethanol on solutions containing the triethanolamine derivatives and amine solution is contacted with the sour gas as explained those without such derivatives for purposes of comparison. above, and then the impurity rich monoethanolamine is Since it is known from the experience of gas processors discharged from the bottom of the adsorber and is subse 45 that monoethanolamine degradation occurs faster at high quently regenerated by heat at 220-250 F. at which temperatures, the test was carried out at a temperature of temperature the most of the adsorbed impurities are re approximately 150° C. and an operating pressure from moved. 190 to about 200 p.s.i.g. The details of such adsorption of natural gas impurities The test equipment consists essentially of a stainless is well known in the art and although gas "sweetening” 50 steel pressure vessel equipped with a mechanical stirrer with monoethanolamine has many advantages, shutdown and a heating jacket. Gas inlet means is located on the and replacement of the ethanolamine solution must be car vessel so that when the aqueous monoethanolamine test ried out frequently due to degradation of the monoetha solution is in the vessel under pressure, a measured amount nolamine. This is particularly true where the gas being of nitrogen purge gas and samples of impurity gas such subjected to purification contains sulfide compounds such 55 as carbon dioxide, hydrogen sulfide and mercaptains can as hydrogen sulfide, carbonyl sulfide and mercaptains. be added to the vessel. A vent means is also located on the It is therefore an object of the present invention to vessel for venting off excess gas. A thermocouple is also provide an aqueous monoethanolamine solution which located in the vessel for indicating the temperature of the has improved resistance to degradation in the presence solution during testing. of certain acid gases. 60 It is another object of the invention to provide a mono EXAMPLE I ethanolamine solution for sweetening natural gas on a 61.0 grams of monoethanolamine was charged into a continuous basis which requires less frequent replace reactor vessel containing 244.0 gms. of water. After flush ment, ing the reactor vessel with nitrogen, 51.8 gms. of carbon These objects are accomplished by incorporating into 65 dioxide was introduced into the reactor at a pressure of an aqueous solution of monoethanolamine a stabilizing approximately 50 p.s.i.g. The reactor was heated to 152 C. amount of a compound of the formula: and the pressure inside the vessel was increased to 199 p.s.i.g. This temperature and pressure was maintained for I approximately 4 hours during which time the reaction was Ho-CH-CH-N-CH-CH-OH 70 stirred vigorously. C-CH-OH At the end of the 4 hours, the reaction was cooled and R the pressure reduced. The excess gas was vented off. The 3,535,260 3 4. contents of the reactor were removed and analyzed by for 4.1 hours at 197 p.s.i.g. pressure. 30.8 gms. of mono vapor phase gas chromatograph. The extent of degrada ethanolane was recovered equivalent to 99.56 percent of tion was calculated based on the amount of monoethanol starting material. amine recovered. 58.89 gms. of monoethanolamine or The analysis tests of the solutions described in the above 96.54% of starting material was recovered. Therefore the examples were carried out and an F & M Model 810 gas amount of monoethanolamine degraded during the heat chromatograph using 10 percent polyphenylether and 2 ing period was 3.46 percent. percent "Carbowax' 20M on Fluoropak 80 support in a EXAMPLE 2 4 ft. x 4' O.D. stainless steel column. claim: 61.0 gms, of monoethanolamine was charged into a 1. A method of stabilizing an aqueous monoethanol reactor together with 244.0 gms. of water. After flushing O amine solution against degradation in the presence of a the reactor vessel with nitrogon, 21.0 gms. of hydrogen gas selected from the group consisting of carbon dioxide sulfide and 30.0 gms. of carbon dioxide were introduced and hydrogen sulfide which comprises incorporating in into the reactor at a pressure of approximately 50 p.s.i.g. said solution a stabilizing amount of a compound of the The reactor was heated to 151° C. and the pressure inside 5 formula: the vessel was increased to 193 p.S.i.g. This temperature and pressure was maintained for approximately 9.6 hours R R during whitich time the reaction was stirred vigorously. At IO- d I-CH-N-CH- -OH the end of this period the recovered monoethanolamine H-CH-OH was measured in the manner described in Example 1. 20 l 58.46 gms. of monoethanolamine was recovered or 95.84 wherein R is a radical selected from the group consisting percent of starting material. Therefore the amount of of hydrogen, and an alkyl having from 1 to 4 carbon atoms. monoethanolamine degraded was 4.16 percent. 2. A method as claimed in claim 1 wherein the said EXAMPLE 3 25 compound is triethanolamine. 46.0 gms, of monoethanolamine and 244.0 gms, of 3. A method as claimed in claim 2 wherein the tri water were charged into a reactor as described in Example ethanolamine is present in an amount of from 0.1 percent 1. In addition 2.3 gms. of triethanolamine equivalent to to 15 percent by weight of monoethanolamine. approximately 5 percent by weight of monoethanolamine 4. A method as claimed in claim 2 wherein the tri was added to the reactor. 11.0 gms. of carbon dioxide and 30 ethanolamine is present in an amount of from 0.5 percent 16.7gms. of hydrogen sulfide were introduced into the reac to 5 percent by weight of monoethanolamine. tor at a pressure of approximately 50 p.s.i.g. The reactor 5. A method as claimed in claim 1 wherein the said was heated to 152 C.
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