10800 Realgar

Total Page:16

File Type:pdf, Size:1020Kb

10800 Realgar 10800 Realgar Chemical composition : As4S4 C.I. 77085, Pigment Yellow 39 Realgar is the natural orange-red sulphide of arsenic. It is closely related chemically and associated in nature with orpiment. The two minerals are often found in the same deposits. Realgar occurs as a minor constituent in certain ore veins associated with orpiment and other arsenic minerals, with stibnite, lead, gold and silver. It is found in Romania, the former Czechoslovakia, and the former Yugoslavia, Greece, Germany, Italy, Corsica and the western United States. The name is derived from the Arabic rahj al ghar, powder of the mine. The Latin term was sandarach and De Mayerne who was writing in the seventeenth-century referred to it as rubis d'orpiment. Realgar has been found on a few works by Tintoretto and from Bulgarian icons dating from the Middle Ages to the Renaissance. Realgar has also been reported on Indian sixteenth- to seventeenth-century paintings and an eleventh- to thirteenth-century manuscript from Central Asia. Realgar appears to be less permanent and is known to change to orpiment after long exposure to light. Chinese realgar figurines from the eighteenth-century had oxidized to orpiment and arsenious oxide (Daniels). The chemical and physical properties are similar to orpiment. It belongs to the same crystal system (monoclinic). Its color is orange or an orange-red by transmitted light but usually many yellow particles of orpiment can also be seen. The particles of mineral realgar are usually granular, coarse to fine and have a resinous to greasy luster. Excerpts from: Artist's Pigments Vol.3 Elisabeth West Fitzhugh (editor) and Painting Materials Rutherford J. Gettens and George L. Stout Page 1 of 1 Kremer Pigmente GmbH & Co. KG · Hauptstr. 41-47 · DE-88317 Aichstetten ·Tel. 0049 7565 914480 · [email protected] · www.kremer-pigmente.com We do not assume any warranty for the guidance shown above. In any case, we recommend production and evaluation of samples. .
Recommended publications
  • Stibnite Gold Project
    STIBNITE GOLD PROJECT PAYETTE & BOISE NATIONAL FORESTS INTERMOUNTAIN REGION August 22, 2018 STIBNITE MINING DISTRICT, PAYETTE NATIONAL FOREST, KRASSEL RANGER DISTRICT Regarding Locatable Minerals , 36 CFR 228, Subpart A: requires the Forest Service to: "Where conflicting interests Respond to a mining plan, evaluate that plan must be reconciled, the Consider requirements to minimize adverse effects to the extent feasible question shall always be Comply with applicable laws, regulations and answered from the stand- standards for environmental protection point of the greatest good of Assure appropriate reclamation Further respond by following National Environmental the greatest number in the Policy Act (NEPA) processes. long run." - James Wilson, Secretary Per 36 CFR 228.4, the Forest Service is required to take of Agriculture, 1905 in a letter to Gifford action to ensure that “operations are conducted so as, Pinchot, 1st Chief of the Forest Service. where feasible, to minimize adverse environmental impacts on National Forest surface resources. 1 Table of Contents Project Context STIBNITE GOLD Project Location 4 Mining History at Stibnite 5 PROJECT Who is Midas Gold 6 Stibnite Plan of Operations PAYETTE & BOISE NATIONAL Proposed Mining Plan of FOREST - INTERMOUNTAIN REGION Operations 7 Open Pit Mining 8 Anadromous Fish - Tunnel 9 Inventoried Roadless Areas - Why is this project of interest to many Access and Powerline 10 people and organizations? Facilities During Mining Operations 10 5 million recoverable ounces of gold x
    [Show full text]
  • Theoretical Studies on As and Sb Sulfide Molecules
    Mineral Spectroscopy: A Tribute to Roger G. Bums © The Geochemical Society, Special Publication No.5, 1996 Editors: M. D. Dyar, C. McCammon and M. W. Schaefer Theoretical studies on As and Sb sulfide molecules J. A. TOSSELL Department of Chemistry and Biochemistry University of Maryland, College Park, MD 20742, U.S.A. Abstract-Dimorphite (As4S3) and realgar and pararealgar (As4S4) occur as crystalline solids con- taining As4S3 and As4S4 molecules, respectively. Crystalline As2S3 (orpiment) has a layered structure composed of rings of AsS3 triangles, rather than one composed of discrete As4S6 molecules. When orpiment dissolves in concentrated sulfidic solutions the species produced, as characterized by IR and EXAFS, are mononuclear, e.g. ASS3H21, but solubility studies suggest trimeric species in some concentration regimes. Of the antimony sulfides only Sb2S3 (stibnite) has been characterized and its crystal structure does not contain Sb4S6 molecular units. We have used molecular quantum mechanical techniques to calculate the structures, stabilities, vibrational spectra and other properties of As S , 4 3 As4S4, As4S6, As4SIO, Sb4S3, Sb4S4, Sb4S6 and Sb4SlO (as well as S8 and P4S3, for comparison with previous calculations). The calculated structures and vibrational spectra are in good agreement with experiment (after scaling the vibrational frequencies by the standard correction factor of 0.893 for polarized split valence Hartree-Fock self-consistent-field calculations). The calculated geometry of the As4S. isomer recently characterized in pararealgar crystals also agrees well with experiment and is calculated to be about 2.9 kcal/mole less stable than the As4S4 isomer found in realgar. The calculated heats of formation of the arsenic sulfide gas-phase molecules, compared to the elemental cluster molecules As., Sb, and S8, are smaller than the experimental heats of formation for the solid arsenic sulfides, but shown the same trend with oxidation state.
    [Show full text]
  • 40 Common Minerals and Their Uses
    40 Common Minerals and Their Uses Aluminum Beryllium The most abundant metal element in Earth’s Used in the nuclear industry and to crust. Aluminum originates as an oxide called make light, very strong alloys used in the alumina. Bauxite ore is the main source aircraft industry. Beryllium salts are used of aluminum and must be imported from in fluorescent lamps, in X-ray tubes and as Jamaica, Guinea, Brazil, Guyana, etc. Used a deoxidizer in bronze metallurgy. Beryl is in transportation (automobiles), packaging, the gem stones emerald and aquamarine. It building/construction, electrical, machinery is used in computers, telecommunication and other uses. The U.S. was 100 percent products, aerospace and defense import reliant for its aluminum in 2012. applications, appliances and automotive and consumer electronics. Also used in medical Antimony equipment. The U.S. was 10 percent import A native element; antimony metal is reliant in 2012. extracted from stibnite ore and other minerals. Used as a hardening alloy for Chromite lead, especially storage batteries and cable The U.S. consumes about 6 percent of world sheaths; also used in bearing metal, type chromite ore production in various forms metal, solder, collapsible tubes and foil, sheet of imported materials, such as chromite ore, and pipes and semiconductor technology. chromite chemicals, chromium ferroalloys, Antimony is used as a flame retardant, in chromium metal and stainless steel. Used fireworks, and in antimony salts are used in as an alloy and in stainless and heat resisting the rubber, chemical and textile industries, steel products. Used in chemical and as well as medicine and glassmaking.
    [Show full text]
  • Effect of Size and Processing Method on the Cytotoxicity of Realgar Nanoparticles in Cancer Cell Lines
    International Journal of Nanomedicine Dovepress open access to scientific and medical research Open Access Full Text Article ORIGINAL RESEARCH Effect of size and processing method on the cytotoxicity of realgar nanoparticles in cancer cell lines Weizhong Zhao1 Abstract: In this study, the effects of the size and Chinese traditional processing (including Xun Lu3 elutriation, water cleaning, acid cleaning, alkali cleaning) on realgar nanoparticles (RN)-induced Yuan Yuan1 antitumor activity in human osteosarcoma cell lines (MG-63) and hepatoma carcinoma cell lines Changsheng Liu1 (HepG-2) were investigated. The human normal liver cell line (L-02) was used as control. RN Baican Yang3 was prepared by high-energy ball milling technology. The results showed that with the assistance Hua Hong1 of sodium dodecyl sulfate, the size of realgar could be reduced to 127 nm after 12 hours’ ball milling. The surface charge was decreased from 0.83 eV to -17.85 eV and the content of As O Guoying Wang3 2 3 clearly increased. Except for elutriation, the processing methods did not clearly change the size Fanyan Zeng2 of the RN, but the content of As2O3 was reduced dramatically. In vitro MTT tests indicated that 1The State Key Laboratory in the two cancer cell lines, RN cytotoxicity was more intense than that of the coarse realgar of Bioreactor Engineering, 2Key Laboratory for Ultrafine nanoparticles, and cytotoxicity was typically time- and concentration-dependent. Also, RN Materials of Ministry of Education cytotoxicities in the HepG-2 and L-02 cells all increased with increasing milling time. Due to and Engineering Research Center the reduction of the As O content, water cleaning, acid cleaning, and alkali cleaning decreased for Biomedical Materials of Ministry 2 3 of Education, East China University RN cytotoxicity in HepG-2, but RN after elutriation, with the lowest As2O3 (3.5 mg/g) and the of Science and Technology, 3Pharmacy smallest size (109.3 nm), showed comparable cytotoxicity in HepG-2 to RN without treatment.
    [Show full text]
  • Ralphcannonite, Agzn2tlas2s6, a New Mineral of the Routhierite
    1 1 Ralphcannonite, AgZn2TlAs2S6, a new mineral of the 2 routhierite isotypic series from Lengenbach, Binn 3 Valley, Switzerland 4 1* 2 3 5 LUCA BINDI , CRISTIAN BIAGIONI , THOMAS RABER , PHILIPPE 4 5 6 ROTH , FABRIZIO NESTOLA 7 8 9 10 1 Dipartimento di Scienze della Terra, Università degli Studi di Firenze, Via G. La Pira, 4, I- 11 50121 Firenze, Italy 12 2 Dipartimento di Scienze della Terra, Università di Pisa, Via Santa Maria, 53, I-56126 Pisa, 13 Italy 14 3 FGL (Forschungsgemeinschaft Lengenbach), Edith-Stein-Str. 9, D-79110 Freiburg, 15 Germany 16 4 FGL (Forschungsgemeinschaft Lengenbach), Ilanzhofweg 2, CH-8057 Zurich, Switzerland 17 5 Dipartimento di Geoscienze, Università di Padova, Via Gradenigo, 6, I-35131 Padova, Italy 18 19 20 21 22 *e-mail address: [email protected] 23 2 24 ABSTRACT 25 The new mineral species ralphcannonite, AgZn2TlAs2S6, was discovered in the Lengenbach 26 quarry, Binn Valley, Wallis, Switzerland. It occurs as metallic black equant, isometric to 27 prismatic crystals, up to 50 μm, associated with dufrénoysite, hatchite, realgar, and baryte. 28 Minimum and maximum reflectance data for COM wavelengths in air are [λ (nm): R (%)]: 29 471.1: 25.8/27.1; 548.3: 25.2/26.6; 586.6: 24.6/25.8; 652.3: 23.9/24.8. Electron microprobe 30 analyses give (wt%): Cu 2.01(6), Ag 8.50(16), Zn 10.94(20), Fe 3.25(8), Hg 7.92(12), Tl 31 24.58(26), As 18.36(19), Sb 0.17(4), S 24.03(21), total 99.76(71).
    [Show full text]
  • Orpiment As2s3 C 2001-2005 Mineral Data Publishing, Version 1
    Orpiment As2S3 c 2001-2005 Mineral Data Publishing, version 1 Crystal Data: Monoclinic. Point Group: 2/m. Commonly in foliated columnar or fibrous aggregates, with cleavages as much as 60 cm across; may be reniform or botryoidal; also granular or powdery; rarely as prismatic crystals, to 10 cm. Twinning: On {100}. Physical Properties: Cleavage: Perfect on {010}, imperfect on {100}; cleavage lamellae are flexible. Tenacity: Sectile. Hardness = 1.5–2 VHN = n.d. D(meas.) = 3.49 D(calc.) = 3.48 Optical Properties: Transparent. Color: Lemon-yellow to golden or brownish yellow. Streak: Pale lemon-yellow. Luster: Resinous, pearly on cleavage surface. Optical Class: Biaxial (–). Pleochroism: In reflected light, strong, white to pale gray with reddish tint; in transmitted light, Y = yellow, Z = greenish yellow. Orientation: X = b; Z ∧ c = 2◦. Dispersion: r> v,strong. α = 2.4 (Li). β = 2.81 (Li). γ = 3.02 (Li). 2V(meas.) = 76◦ Anisotropism: Barely observable because of strong internal reflections. R1–R2: (400) 33.0–36.5, (420) 31.0–35.2, (440) 28.9–33.9, (460) 27.4–31.5, (480) 26.0–30.3, (500) 24.9–29.3, (520) 24.0–28.4, (540) 23.3–27.8, (560) 22.8–27.3, (580) 22.3–26.9, (600) 22.0–26.5, (620) 21.7–26.3, (640) 21.5–26.0, (660) 21.2–25.7, (680) 21.0–25.5, (700) 20.8–25.3 Cell Data: Space Group: P 21/n. a = 11.475(5) b = 9.577(4) c = 4.256(2) β =90◦41(5)0 Z=4 X-ray Powder Pattern: Baia Sprie (Fels˝ob´anya), Romania.
    [Show full text]
  • 10700 Orpiment, King's Yellow PY 39
    10700 Orpiment, King's Yellow PY 39 Chemical composition: yellow sulphide of arsenic As2S3 The origin of the modern name is derived from the Latin term auripigmentum or auripigmento, literally meaning gold paint. Orpiment was once widely used, particularly in the East, but has now fallen into disuse because of its limited supply and because of its poisonous character. The principal sources in ancient times appear to have been in Hungary, Macedonia, Asia Minor and perhaps in various parts of Central Asia. There was a large deposit near Julamerk in Kurdistan. Current deposits of orpiment are in Romania, Hungary, Germany, Greece, France, Italy, Iran, Peru, China, Japan and the western United States. Orpiment occurs as a low temperature product in hydrothermal veins, as a volcanic sublimation product, as a hot spring deposit and in fire mines. It is often associated with stibnite, pyrite, realgar, calcite and gypsum. Orpiment occurs in many places but not in large quantities. Orpiment is usually described as a lemon or canary yellow or sometimes as a golden or brownish yellow with a fair covering power. Microscopically, orpiment is crystalline and may contain orange-red particles of realgar, to which it is closely related. The larger particles glisten by reflected light and have a waxy-looking surface. The toxicity of the arsenic sulfide pigments has been known since early times. The toxic properties of orpiment have been used to advantage to repel insects. Orpiment is said to be incompatible with lead- or copper-containing pigments. Orpiment is not stable in lime and therefore can not be used for fresco, a fact noted by Cennino Cennini inn the fifteenth century.
    [Show full text]
  • Antimony Data Sheet
    22 ANTIMONY (Data in metric tons of antimony content unless otherwise noted) Domestic Production and Use: In 2019, no marketable antimony was mined in the United States. A mine in Nevada that had extracted about 800 tons of stibnite ore from 2013 through 2014 was placed on care-and-maintenance status in 2015 and had no reported production in 2019. Primary antimony metal and oxide were produced by one company in Montana using imported feedstock. Secondary antimony production was derived mostly from antimonial lead recovered from spent lead-acid batteries. The estimated value of secondary antimony produced in 2019, based on the average New York dealer price for antimony, was about $34 million. Recycling supplied about 14% of estimated domestic consumption, and the remainder came mostly from imports. The value of antimony consumption in 2019, based on the average New York dealer price, was about $234 million. The estimated distribution of domestic primary antimony consumption was as follows: nonmetal products, including ceramics and glass and rubber products, 22%; flame retardants, 40%; and metal products, including antimonial lead and ammunition, 39%. Salient Statistics—United States: 2015 2016 2017 2018 2019e Production: Mine (recoverable antimony) — — — — — Smelter: Primary 645 664 621 331 370 Secondary 3,740 3,810 e3,800 e4,000 4,000 Imports for consumption: Ore and concentrates 308 119 61 96 140 Oxide 16,700 16,100 17,900 19,200 17,000 Unwrought, powder, waste and scrap1 5,790 7,150 6,830 6,500 7,200 Exports: Ore and concentrates1 31
    [Show full text]
  • C:\Documents and Settings\Alan Smithee\My Documents\MOTM
    Itmd1//8Lhmdq`knesgdLnmsg9Rshamhsd This month’s mineral is among the most collectible of all minerals. Ours come from a Chinese antimony mine that is now recognized as a classic stibnite locality, and our write-up explains the unusual structure and properties of stibnite, describes its remarkable crystals, and details the many uses of antimony. OVERVIEW PHYSICAL PROPERTIES Chemistry: Sb2S3 Antimony Trisulfide, often containing some bismuth Class: Sulfides Group: Stibnite Crystal System: Orthorhombic Crystal Habits: Individual bladed or acicular prisms or jumbled aggregates of prisms, striated lengthwise; prisms often bent or twisted; also as radiated groups and granular and massive forms. Color: Lead-gray and gray-black to steel-gray and silvery-gray, sometimes with a bluish hue; occasionally iridescent; tarnish black. Luster: Metallic Transparency: Opaque Streak: Dark lead-gray Refractive Index: None (opaque) Cleavage: Perfect in one direction lengthwise Figure 1. Stibnite crytals. Fracture: Subconchoidal to irregular; brittle; thin prisms are slightly flexible. Hardness: 2.0 Specific Gravity: 4.6 Luminescence: None Distinctive Features and Tests: Best field identification features are softness; flexibility of thin prisms; and long, bladed and acicular crystal habits. Visually similar to bismuthinite [bismuth trisulfide, Bi2S3], which has considerably more density. Dana Classification Number: 2.11.2.1 NAME Stibnite, pronounced STIBB-nite, derives from stibi, the Greek name for the mineral. Stibnite has formerly been referred to as “antimonite,” “antimonide,” “sulfur antimonide,” “sulfur antimony,” “antimony glance,” “gray antimony,” “gray antimony ore,” “kohl,” “stibi,” “stimmi,” “stibium,” “lupus metallorum,” “platyophthalmite,” and “speissglas.” In current European mineralogical literature, stibnite appears as stibnit, stibnita, and stibnine. Antimony, pronounced ANN-tih-mow-nee, stems from the Latin word for the metal, antimonium, which means “opposed to solitude,” in allusion to its rare occurrence as a native element.
    [Show full text]
  • Minerals of Bismuthinite-Stibnite Series with Special Reference to Horobetsuite from the Horobetsu Mine, Hokkaido, Japan*
    MINERALOGICAL JOURNAL VOL . 1, No. 4, pp. 189-197, JUNE, 1955 MINERALS OF BISMUTHINITE-STIBNITE SERIES WITH SPECIAL REFERENCE TO HOROBETSUITE FROM THE HOROBETSU MINE, HOKKAIDO, JAPAN* KITARO HAYASE Institute of Mining, Faculty of Science and Engineering , Waseda University. ABSTRACT Horobetsuite occurs associated with free sulphur and iron sulphide minerals, in the sulphur deposit of Horobetsu Mine. The chemical formula of horobetsuite has been determined as (Bi, Sb)2S3. The molecular ratio of Bi2S3 to Sb2S3 varies between 9:11 and 13:7. The mineral is intermediate between bismuthinite and stibnite in lattice constant, specific gravity, optical behaviour and etching reac tion. The data obtained reveal the mineral to be a new species belonging to the bismuthinite-stibnite series. A new mineral name, horobetsuite, is proposed for the mineral of the series which should have the molecular ratio of Bi2S3 to Sb2S3 between 7:3 and 3:7. Introduction The writer1) once reported the results of the study of a Bi-Sb sul phide mineral that occurred at the Horobetsu mine, and suggested that it might represent a solid solution of bismuthinite and stibnite. The slight fluctuation observed of the molecular ratio of Bi2S3 to Sb2S3 has prompt us to a further study. Occurrence of horobetsuitel) The Horobetsu mine in which horobetsuite occurs is located at Sobetsu Village, Usu County, in the vicinity of Muroran, Hokkaido, Japan. (Fig. 1) * Read at the Annual Meeting of the Mineralogical Society of Japan held in Tokyo on June 4, 1954. 190 Minerals of Bismuthinite-Stibnite Series Fig. 1. Sulphur ore body of Horobetsu Mine.
    [Show full text]
  • Amorphous Arsenic Chalcogenide Films Modified Using Rare-Earth
    ARTICLE IN PRESS Journal of Non-Crystalline Solids xxx (2006) xxx–xxx www.elsevier.com/locate/jnoncrysol Amorphous arsenic chalcogenide films modified using rare-earth complexes S.A. Kozyukhin a,*, E.N. Voronkov b, N.P. Kuz’mina c a Department of Magnetic Materials, Kurnakov Institute of General and Inorganic Chemistry, RAS, Leninskii Pr., 31, Moscow 119991, Russia b Moscow Power Engineering Institute (Technical University), Moscow, 111250, Russia c Department of Chemistry, Moscow State University, Moscow, 119899, Russia Abstract The optical absorption and current–voltage characteristic of amorphous arsenic chalcogenide As2X3 (X = S, Se) films modified by rare-earth complexes with organic mixed-ligands have been studied. The following two types of complexes were used: europium dipiva- loylmethanate Eu(thd)3 and lanthanide diethyldithiocarbamates Ln(ddtc)3 (Ln = Pr, Eu). It was shown that the use of rare-earth mixed- complexes with similar volatility to the chalcogenide volatility permits the deposition of amorphous films by thermal evaporation. The decrease in absorption coefficient at the Urbach’s edge after introduction of the europium dipivaloylmethanate complexes containing oxygen in arsenic selenide has been revealed. The type of organic ligands, incorporated in the amorphous matrix, determines the shape of current–voltage characteristic. The observed results have been discussed on the basis of the different rigidity of the structure of amor- phous arsenic chalcogenides. Ó 2006 Elsevier B.V. All rights reserved. PACS: 73.61.Jc; 78.66.Jg Keywords: Electrical and electronic properties; Conductivity; Films and coatings; Chemical vapor deposition; Infrared glasses; Chalcogenides; Optical properties; Absorption; Rare-earths in glasses 1. Introduction e.g.
    [Show full text]
  • STRONG and WEAK INTERLAYER INTERACTIONS of TWO-DIMENSIONAL MATERIALS and THEIR ASSEMBLIES Tyler William Farnsworth a Dissertati
    STRONG AND WEAK INTERLAYER INTERACTIONS OF TWO-DIMENSIONAL MATERIALS AND THEIR ASSEMBLIES Tyler William Farnsworth A dissertation submitted to the faculty at the University of North Carolina at Chapel Hill in partial fulfillment of the requirements for the degree of Doctor of Philosophy in the Department of Chemistry. Chapel Hill 2018 Approved by: Scott C. Warren James F. Cahoon Wei You Joanna M. Atkin Matthew K. Brennaman © 2018 Tyler William Farnsworth ALL RIGHTS RESERVED ii ABSTRACT Tyler William Farnsworth: Strong and weak interlayer interactions of two-dimensional materials and their assemblies (Under the direction of Scott C. Warren) The ability to control the properties of a macroscopic material through systematic modification of its component parts is a central theme in materials science. This concept is exemplified by the assembly of quantum dots into 3D solids, but the application of similar design principles to other quantum-confined systems, namely 2D materials, remains largely unexplored. Here I demonstrate that solution-processed 2D semiconductors retain their quantum-confined properties even when assembled into electrically conductive, thick films. Structural investigations show how this behavior is caused by turbostratic disorder and interlayer adsorbates, which weaken interlayer interactions and allow access to a quantum- confined but electronically coupled state. I generalize these findings to use a variety of 2D building blocks to create electrically conductive 3D solids with virtually any band gap. I next introduce a strategy for discovering new 2D materials. Previous efforts to identify novel 2D materials were limited to van der Waals layered materials, but I demonstrate that layered crystals with strong interlayer interactions can be exfoliated into few-layer or monolayer materials.
    [Show full text]