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Abstract Book 26th CRSI-National Symposium in Chemistry CRSI-NSC-26 February 07-09, 2020 Abstract Book Jointly Organized by Department of Chemistry VIT Vellore, CRSI, & RSC, UK Contents Welcome Organizing Committee Message from Founder President, CRSI Message from Founder Chancellor, VIT Message from Pro Vice Chancellor, VIT Message from President, CRSI Message from Dean, School of Advance Science Acknowledgements Program Abstracts President’s Lecture Animesh Chakravorty Endowment Lecture CRSI Medal Lecture C. N. R. Rao National Prize for Chemical Research CRSI Honorary Fellowship Lecture C. N. R. Rao Award Lecture Silver Medal Lecture Mizushima - Raman Lecture Third Charusita Chakravarty Memorial Lecture Lifetime Achievement Award Lecture Bronze Medal Lectures Invited Lectures Abstracts Posters Welcome Message from Organizers On behalf of organizing committee of the 26th National Symposium in Chemistry (NSC) and 14th Royal Society of Chemistry Joint Symposium under the auspices of the Chemical Research Society of India (CRSI), we are delighted to welcome you to the symposium and to the Vellore Institute of Technology Vellore. The 26th CRSI-NSC meeting is attended by a large number of scientists, academicians and students from universities and academic/research institutions spread across the length and breadth of India. The meeting is attended by nearly 200 registered participants. The symposium has 34 lectures that include CRSI medal lectures, special lectures. More than 130 posters will be presented by faculty and students. The Royal Society of Chemistry, UK has been partnering with CRSI in organizing a one day symposium, along with the CRSI National Symposium over the years. This year also, there will be a CRSI-RSC symposium on February 6, 2020, preceding the CRSI National Symposium at Vellore. The main purpose of the NSC meeting is to create a platform where scientists, teachers and students across the country come together and discuss recent developments in the area of chemical sciences. Meetings like this that encompass all the domains of chemistry can help to build long lasting collaborative endeavours in the frontier areas of chemistry and its allied disciplines. We thank the CRSI governing body and council members for their valuable inputs and continuous encouragement. The credit of the success of this meeting shall go all the faculty members and students of the Department of Chemistry, VIT Vellore. We acknowledge our gratitude to The Chancellor, Vice-Presidents, Asst. Vice-President, Vice-Chancellor, Pro-VC, Registrar, and the Dean of SAS for their support. We thank the sponsors for their financial aid and support. Last but not the least, we thank all the participants who have travelled far to attend the symposium. We wish you a great time at VIT Vellore during the symposium Sincerely R Vijayaraghavan, Kaushik Chanda and Priyankar Paira (on behalf of the Organizing Team) 1 Organizing Committee Department of Chemistry, VIT Vellore S. No. Committee Members 1 Dean Dr. A. Mary Saral 2 HoD Dr. S.L. Manju 3 Convener Dr. R. Vijayaraghavan Dr. Kaushik Chanda 4 Organizing Secretaries Dr. Priyankar Paira 5 Registration Dr. I.V. Asha Rani Dr. K. Thenmozhi 6 Reception 7 Transport Dr. K.K. Cheralathan 8 Printing Dr. A. Anand Prabu Dr. Madhvesh Pathak 9 Guest Care Dr. Tamas Panda 10 VIP Guest Care Dr. S. Sasikumar Mementos/Banners/ Tags/Abstract Dr. Kaushik Chanda 11 Book/Pen Drive Dr. Anisha Thomas Dr. Kannadasan i/c Dr. K.K. Cheralathan 12 Food Committee Dr. K.R. Ethiraj Dr. G. Thirumanavelan Dr. K. Thirumoorthy 13 Men's Hostel Dr. M. Shiva Shankar 14 Ladies Hostel Dr. Barnali Maiti 15 Cultural Dr. G. Madhumitha Dr. R. Vijayaraghavan (i/c) Dr. Kaushik Chanda 16 Finance Dr. Priyankar Paira Dr. Mausumi Goswami 17 Accounts Dr. R. Vijayaraghavan Dr. V. Vijayakumar i/c 18 Poster Committee Dr. S. Rajasekar Reddy Dr. Sovan Roy 2 Dr. G. Buvaneswari 19 Poster Evaluation Dr. V. Vijayakumar 20 Hall Arrangement Dr. Pundlik Rambhau Bhagat 21 Website Dr. R. Vijayaraghavan 22 Pre Conference Dr. U. Vijayalakshmi Abstract Compilation/Segregation/ 23 Dr. Priyankar Paira Data Extraction Formatting/Abstract Book 24 Dr. Kaushik Chanda Making/RSC&CRSI Writing to all speakers/Council 25 Dr. R.Vijayaraghavan Members/RSC Delegates 3 Message from Professor C. N. R. Rao Founder President of CRSI 4 5 Message from Dr G. Viswanathan Founder Chancellor, VIT 6 7 Message from Dr S. Narayanan Pro Vice Chancellor, VIT 8 9 10 Message from Professor N. Sathyamurthy President of CRSI 11 Message from the President, Chemical Research Society of India (CRSI) I am delighted that the Division of Chemical Sciences at the Vellore Institute of Technology (VIT), Vellore has come forward to host the 26th CRSI National Symposium in Chemistry during February 7-9, 2020. This is the first time that the CRSI National Symposium is hosted by a private university. We are particularly pleased that VIT, an Institution of Eminence is hosting the event. On behalf of CRSI and on my own, I would like to express our gratitude to Professor R Vijayaraghavan and his colleagues for organizing the symposium consisting of several bronze, silver, gold and other CRSI medal lectures and invited lectures by different awardees and a special symposium on Materials. I could see that it is going to be an exciting event. We are pleased that Chemistry – An Asian Journal has brought out a special issue to celebrate 20 years of CRSI, founded by Professor C N R Rao. It will be released at the Symposium and it showcases the chemistry research in India. It is worth mentioning here that India is No. 3 (China (1), USA (2)) in terms of total number of publications in the world now. The Royal Society of Chemistry, UK has been partnering with CRSI in organizing a one day symposium, along with the CRSI National Symposium over the years. This year also, there will be a CRSI-RSC symposium on February 6, 2020, preceding the CRSI National Symposium at Vellore. With an ever increasing life membership and an increasing participation by young research scholars, each CRSI National Symposium reflects truly the state of chemistry in the country. There is a number of prizes to be won by young chemists for their work presented in the form of posters. Looking forward to a fruitful meeting in VIT Vellore, Yours sincerely, N. Sathyamurthy President, Chemical Research Society of India, Bengaluru 12 Message from Professor A. Mary Saral Dean, SAS 13 14 15 Acknowledgements 16 26th CRSI National Symposium in Chemistry (NSC-26) Programme Friday, 7 February 2020, Venue- Ambedkar Auditorium, Technology Tower , Ground Floor , 9.30 to 18.05 08:30 - 09:30 Registration SESSION I: INAUGURATION AND PRESIDENTIAL ADDRESS 09:30– 10:30 10:30 – 11:00 HIGH TEA SESSION II: SPECIAL LECTURES CHAIRPERSON: V. Krishnan 11:00 – 11:45 Animesh Chakravorty Endowment Lecture A. S. Borovik, University of California-Irvine, USA Molecular Complexity and Inorganic Chemistry: Utilizing Non-Covalent Interactions to Control Function 11:45 – 12:15 CRSI Medal Lecture Arun Yethiraj, University of Wisconsin-Madison, USA Polymers in ionic liquids 12:15 – 12:45 C. N. R. Rao National Prize for Chemical Research G. U. Kulkarni, JNCASR, Bangalore Au Au decahedra: Unusual nucleus for unconventional lattices 12:45 – 16:00 LUNCH AND POSTER SESSION I, CS hall Posters No. 1 to 65 P132-139 14:00 – 15:00 COUNCIL MEETING (Members only), Board Room, MGR Block 15:30 – 16:00 TEA/COFFEE SESSION III: MEDAL AND SPECIAL LECTURES CHAIRPERSON: S. Chandrasekaran 16:00 – 16:45 CRSI Honorary Fellowship Lecture Sunney I. Chan, Academia Sinica, Taiwan Taming Methane: A catalyst for Efficient and Selective Methane Oxidation under Ambient Conditions 16:45 – 17:05 Bronze Medal Lecture Ranjani Viswanatha, JNCASR, Bangalore Mn emission: Energy transfer or Charge transfer 17:05 – 17:25 Bronze Medal Lecture Manmohan Kapur, IISER, Bhopal Transition-metal-catalyzed Distal and Remote Functionalizations 17:25 – 17:45 Bronze Medal Lecture Rajakumar Balla, IIT Madras Measurement of absorption cross-sections and kinetics of radicals relevant to the Earth’s atmosphere using Cavity Ring Down Spectroscopy 17:45 – 18:05 Bronze Medal Lecture S. G. Srivatsan, IISER, Pune Probing Mood (Structure) Swings of Non-Canonical Nucleic Acid Motifs 17 18:15 – 19:15 CULTURAL PROGRAM, Anna Auditorium 19:30 – 21:30 DINNER, Foodys Saturday, 8 February 2020, Venue: Gallery -2, Tech, Tower, 2nd Floor 9.30 to 18.15 SESSION IV: SPECIAL/MEDAL LECTURES CHAIRPERSON: Sourav Pal 09:30 – 10:15 C. N. R. Rao Award Lecture Richard Catlow, University College London, UK Modeling, Synchroton Radiation and Neutron Scattering Studies of Structure, Dynamics and Reactivity in Catalytic Systems 10:15 - 10:45 Silver Medal Lecture K. Vijayamohanan Pillai, IISER, Tirupati Phosphorene Quantum Dots: Electrochemical Preparation, Doping and Possible Applications 10:45 – 11:15 TEA/COFFEE SESSION V: MEDAL LECTURES CHAIRPERSON: R. N. Mukherjee 11.15 – 12.00 Mizushima - Raman Lecture Tahei Tahara, Riken, Wako, Japan Time-Domain Raman Spectroscopy and Its Application to Ultrafast Photochemical / Photobiological Reactions 12.00 – 12.30 CRSI Medal Lecture Jagadese J. Vittal, National University of Singapore, Singapore My Journey with Crystals under UV Light and beyond 12.30 – 13.00 Third Charusita Chakravarty Memorial Lecture Srabani Taraphder, IIT Kharagpur Reaction Coordinate, Free Energy and Kinetics in an Enzyme Catalysed Proton Transfer Reaction 13:00 – 16:00 LUNCH AND POSTER SESSION II Venue – Foodys Poster No. 66-131, P140 15:30 – 16:00 TEA/COFFEE SESSION VI: MEDAL LECTURES CHAIRPERSON: K. P. Kaliappan 16:00– 16:30 Silver Medal Lecture Subrata Ghosh, IACS, Kolkata 18 Natural Products Synthesis – Some Fascinating Aspects 16:30 – 16:50 Bronze Medal Lecture Mahesh Hariharan, IISER, Trivandrum Ultrafast Excited State Dynamics of Twisted Aromatics 16:50 – 17:10 Bronze Medal Lecture Ashwani Kumar Tiwari, IISER, Kolkata Effects of Mode-Mode Coupling on the Dissociation Dynamics of H2O and CH4 on Metal Surfaces SESSION VII: LIFETIME ACHIEVEMENT AWARD LECTURE CHAIRPERSON: N.
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