Anthophyllite Miners Occup Environ Med: First Published As 10.1136/Oem.51.3.212 on 1 March 1994

Total Page:16

File Type:pdf, Size:1020Kb

Anthophyllite Miners Occup Environ Med: First Published As 10.1136/Oem.51.3.212 on 1 March 1994 212 Occupational and Environmental Medicine 1994;5l:212-215 Four cases of mesothelioma among Finnish anthophyllite miners Occup Environ Med: first published as 10.1136/oem.51.3.212 on 1 March 1994. Downloaded from A Karjalainen, L 0 Meurman, E Pukkala Abstract theless, often constituted a large proportion Four cases of mesothelioma in a cohort of the total fibre burden and could therefore of 999 Finnish anthophyllite miners and not be excluded as a cause of mesothelioma. millers are described. Three deaths were In one of the patients with a reasonably low due to pleural mesothelioma and one to concentration of fibres only anthophyllite was peritoneal mesothelioma among the total detected.5 of 503 male deaths up to 1991. All four In this report we describe four cases of patients with mesothelioma had had long mesothelioma that occurred in the ongoing term (13 to 31 years) exposure in antho- follow up of the cohort of Finnish anthophyl- phyllite mining and milling. The latency lite miners and millers. time from the onset of employment until diagnosis was 39 to 58 years. All four patients were smokers or ex-smokers and Materials and methods had asbestosis. In three of the cases the THE COHORT OF ANTHOPHYLLITE MINERS pulmonary fibre concentration and fibre Two anthophyllite asbestos quarries were type were analysed by transmission elec- worked in Finland during the period tron microscopy. High concentrations 1918-75. They were owned by the same (270 to 1100 million fibreslg dry tissue) of company and located within 10 km of each anthophyllite fibres were detected. The other in a sparsely populated area about 50 anthophyllite fibres were thicker and had km from the nearest city. The workers were lower aspect ratios than the values recruited mainly from the farming population reported for crocidolite fibres retained in living in this area. In the 1950s and 1960s the the lungs ofpatients with mesothelioma. annual output was about 10 000 tonnes. The quarries were combined with a dry hammer (Occup Environ Med 1994;51:212-215) mill, which crushed, ground, and classified the broken rock into asbestos products for various industrial applications. Numerous reports from several countries A fairly complete personnel register was have described cases or series of pleural and kept by the company in the form of salary http://oem.bmj.com/ peritoneal mesotheliomas in relation to occu- lists from 1936. The register contained the pational exposure to various types and mix- names, dates of birth, working periods, and tures of asbestos. In 1960 Wagner and roughly the kind of work done. The series of coworkers described 33 cases of pleural miners and millers included all workers mesotheliomas in the neighbourhood of a employed for three months or longer between crocidolite mine in South Africa.' In later 1 January, 1936 and 1 July, 1967 (miners, studies, mesotheliomas have been found after millers, forestry workers, transportation work- on October 2, 2021 by guest. Protected copyright. occupational exposure to crocidolite, amosite, ers, and office workers). After the exclusion tremolitic material, and chrysotile asbestos.2 of workers who could not be identified, the In Finland, anthophyllite asbestos has been follow up was completed in 999 workers up exceptionally widely used because of its to the end of 1991. The deaths in the cohort domestic production from 1918-75, and spe- were researched through the death files of cial attention has been focused on the role of Statistics Finland. The deaths from cancer anthophyllite asbestos in the aetiology of were based on the files of the Finnish Cancer Institute of Occupational Health, mesothelioma. Anthophyllite fibres have Registry. Helsinki, Finland induced mesotheliomas in animal experi- A Karjalainen ments both after inhalation and intrapleural HISTOLOGICAL VERIFICATION OF THE Department of administration, but epidemiological studies DIAGNOSES Pathology, University ofTurku, Turku, have failed to firmly connect exposure to In all four cases of mesothelioma tissue sam- Finland anthophyllite and mesothelioma in humans. ples taken from the tumour at necropsy or L 0 Meurman In a cohort of about 1000 anthophyllite min- thoracotomy were available for histopatholog- Finnish Cancer ers and millers an increased risk of lung can- ical examination. The diagnoses of mesothe- Registry, Helsinki, cer was found, but no confirmed cases of lioma were confirmed the Finnish Finland by E Pukkala mesothelioma were reported up to 1977.34 In Mesothelioma Panel. Formalin-fixed and a more recent Request for reprints to: study of 29 Finnish patients paraffin embedded tissue blocks were used in Antti Karialainen, Institute with mesothelioma, raised concentrations of light microscopical histopathological, and of Occupational Health, Topeliuksenkatu 41 a A, anthophyllite fibres often occurred in their immunohistochemical examination. In one of SF-00250 Helsinki, Finland. lungs, but usually together with other types of the cases (case 2 in table 1) a morphologically Accepted 28 June 1993 asbestos fibres. Anthophyllite fibres, never- typical pleural mesothelioma with sarcoma- Four cases ofmesothelioma among Finnish anthophyllite miners 213 Table 1 Age, tumour type, exposure, and lungfibre concentration in thefour cases ofmesothelioma among Finnish anthophyllite miners Fibre concentration Age at Tumour Year of in lung tissue Fibre types Occup Environ Med: first published as 10.1136/oem.51.3.212 on 1 March 1994. Downloaded from Case No diagnosis Tumour type location diagnosis Years in mining (million fibresig) detected 1 82 Epithelial Peritoneal 1989 31, 1936-67 1100 Anthophyllite 2 75 Sarcomatous Pleural 1987 13, 1929-56 270 Anthophyllite 3 57 Sarcomatous Pleural 1986 28, 1947-75 1100 Anthophyllite 4 62 Epithelial Pleural 1991 23, 1950-75 -= No sample tous histology remained negative in cytoker- were used. All inorganic particles having atin staining and a sarcoma could not be roughly parallel sides and a length to width completely excluded. ratio greater than three were defined as fibres and counted. The dimensions of the fibres ANALYSES BY ELECTRON MICROSCOPY were measured directly on the screen with In three cases a sample of lung tissue was magnifications up to 100 000. The dimen- available for analysis of the retained mineral sions of 100 fibres per sample were measured. fibres by electron microscopy. In one of these An energy dispersive x ray microanalyser cases (case 2 in table 1) the tissue was stored (Tracor TN 5500) was used to identify the in 4% formalin. In the two other cases the mineral type of each fibre. The intensity specimens were embedded in paraffin, which ratios of Si, Mg, Fe, Ca, and Na were used in was subsequently dissolved with xylene. As the identification by comparing the spectra the tissue weight is known to decrease during peak ratios to standard spectra. Four hundred the process of embedding due to the extrac- fibres per sample were identified. This gave tion of lipids,6 the fibre concentrations of the an analytical sensitivity of <0-25% for fibre paraffin embedded samples were corrected types other than anthophyllite. According to assuming a dry weight loss of 20%. Poisson statistics this equals a detection limit A piece of tissue of about 100 mg wet of <1 0% (four times the analytical sensitiv- weight was taken for the fibre analysis. The ity). samples were prepared according to a previ- ously described method,5 which included low temperature ashing of the lung tissue and fil- Results tration of the remaining ash on polycarbonate In a recent follow up of 999 anthophyllite filters. The filters were further coated with miners and millers, a total of 593 deaths (503 carbon and placed on electron microscopy men and 90 women) were noted up to the grids. The filter material was dissolved with end of 1991; 72 of these were were due to chloroform in a modified Jaffe washer. The lung cancer, four to mesothelioma, and 31 to fibres were counted with a JEOL 100 CX- asbestosis. The diagnosis of asbestosis was ASID4D electron microscope in STEM mentioned in 20% of all death certificates. A mode on a CRT screen. An acceleration volt- detailed report on the incidence of cancer in http://oem.bmj.com/ age of 100 kV and a magnification of 15 000 this cohort is under preparation. Table 1 presents the pathological charac- teristics of the four mesotheliomas and the Table 2 Dimensions ofanthophyllitefibres in the lungs of three cases of mesothelioma among Finnish anthophyllite exposure data of the patients. Three of the miners workers had pleural and one had peritoneal mesothelioma (one of the pleural mesothe- Case No 1 2 3 liomas had also invaded the abdominal cav- Fibre length (pm): All four were male smokers or on October 2, 2021 by guest. Protected copyright. Range 0-80-27 0 70-44 0-80-31 ity). Mean 6-1 7.9 7-3 ex-smokers and had asbestosis. The three Median 4-1 3.9 5-1 cases with available tissue had a Distribution of lung samples fibre length (%): very high concentration of anthophyllite <1*0 4 2 4 fibres in their about 1% of the fibres 1-04-9 50 55 44 lungs; 5 0-9 9 26 14 29 were coated asbestos bodies. When 400 fibres >10 20 29 23 per sample were identified, only anthophyllite Fibre width (um): fibres were detected. Numerous talc particles Range 0-05-1 1 0-06-1-5 0-05-1-5 were also detected in the Mean 035 040 0-45 samples. Median 030 035 0-35 All four patients had had long term (13 to Distribution of 31 years) exposure in the mining of asbestos fibre width (%): <0-1 13 8 9 (see table 1). The occupational histories indi- 0-1-0-49 56 62 56 cated no to asbestos other than in 0-5{)-99 30 27 25 exposure )1.0 1 3 10 the Paakkila mine.
Recommended publications
  • Chemographic Exploration of Amphibole Assemblages from Central Massachusetts and Southwestern New Hampshire
    Mineral. Soc. Amer, Spec. Pap. 2, 251-274 (1969). CHEMOGRAPHIC EXPLORATION OF AMPHIBOLE ASSEMBLAGES FROM CENTRAL MASSACHUSETTS AND SOUTHWESTERN NEW HAMPSHIRE PETER ROBINSON AND HOWARD W. JAFFE Department of Geology, University of Massachusetts, Amherst, Massachusetts 01002 ABSTRACT Fourteen wet chemical and forty electron-probe analyses were made of amphiboles from critical assemblages in the kyanite and sillimanite zones of central Massachusetts and southwestern New Hampshire. The rocks studied in- clude plagioclase amphibolites that are metamorphosed mafic lavas and tuffs, aluminous anthophyllite rocks of uncertain derivation, quartz-garnet-amphibole granulites that are metamorphosed ferruginous cherts, and pods of ultramafic amphibolite. The rocks contain the following associations: hornblende-anthophyllite, hornblende-cummingtonite, anthophyllite-cummingtonite, hornblende-anthophyllite-cummingtonite, anthophyllite-cordierite, and anthophyllite- kyanite-sillimanite-staurolite_garnet. The following generalizations are made: 1) The cummingtonites are compositionally simple, containing neither sig- nificant AI/AI, NaJAI, nor Ca substitution. 2) The hornblendes are high in AI/AI substitution. Those coexisting with cummingtonite in the kyanite zone or in retrograded rocks have a higher Al content than those coexisting with cum- mingtonite in the sillimanite zone, in close agreement with the prograde reaction tschermakitic hornblende -7 cumming- tonite + plagioclase + H20 proposed by Shido. The Na content of hornblende is considerably less than that of the theoretical edenite end member and is relatively insensitive to variation in the Na content of coexisting plagioclase. 3) Anthophyllites coexisting with hornblende contain about 1as much AI/AI substitution and 1as much Na substitution as coexisting hornblendes. Ca is negligible. Anthophyllites with cordierite, aluminosilicates, or garnet equal or surpass hornblende in AI/AI and Na substitution.
    [Show full text]
  • Crystal Structure of Protoamphibole
    Mineral. Soc. Amer. Spec. Pap. 2, 101-109 (1969). CRYSTAL STRUCTURE OF PROTOAMPHIBOLE G. V. GIBBS Department of Geological Sciences, Virginia Polytechnic Institute Blacksburg, Virginia 24061 ABSTRACT The structure proposed for protoamphibole (Gibbs et al., 1960) has been verified and refined by three-dimensional Fourier and least-squares methods using data collected with a Weissenberg single crystal counter-diffractometer. The symmetry is Pnmn with a = 9.330, b = 17.879 and c = 5.288 A and the unit-cell content is 2(Nao.03Li",oMg, ••) (Si r. ,.Alo.040,1.71) (OHo.15F,.14). The structure consists of layers of interlocking chains of fluorine-centered hexagonal rings of SiO. groups. The layers are bound together by Mg.Li cations which are coordinated between the chains, the coordination being effected by a ~(cI3) stagger between adjacent layers. An additional stagger of ~(-cI3) in the sequence along a gives an overall displacement of zero between alternate layers, accounting for the 9.33 A a cell edge and the orthogonal geometry. The direction of stagger can be related to the placement of the cations in the octahedral layer. The M -cation coordination groups are nearly regular octahedra with the exception of M(4) which is similar to Mg(l) in protoenstatite. The M(3), M(1) and M(2) sites are occupied principally by Mg. In addition to being randomly distributed around the cavity walls of the A-site, Li ions are also segregated in about 25% of the M(4) sites, the others being occupied by Mg ions. The individual Si-O bond distances in the chains are consistent with Cruickshank's d-p -n: bonding model: Si-O(non- bridging) bonds [Si(1)-O(1) = 1.592; Si(2)-0(4) = 1.592; Si(2)-0(2) = 1.605 AJ are significantly shorter, on the average, than the Si-O(bridging) bonds [Si(1)-0(5) = 1.616; Si(1)-0(6) = 1.623; Si(1)-0(7) = 1.624; Si(2)-0(5) = 1.626; Si(2)-0(6) = 1.655 AJ.
    [Show full text]
  • ANTHOPHYLLITE Revised: Published by A.E
    FROM: Robinson, G.W., 2004 Mineralogy of Michigan by E.W. Heinrich updated and ANTHOPHYLLITE revised: published by A.E. Seaman Mineral Mg7Si8O22(OH)2 Museum, Houghton, MI, 252p. The only common orthorhombic member of the amphibole group; forms a solid solution series with ferro-anthophyllite. Anthophyllite is a metamorphic mineral, occurring in various schists, gneisses, and some iron formations. It also occurs as a hydrothermal mineral species in altered peridotites. The Marquette County localities cited below were reported by Brooks (1873). The identity of his anthophyllites has never been verified or supported by optical data. It is suspected that some, if not all, of the amphibole he reported as anthophyllite may actually be grunerite, inasmuch as some of Brooks’ localities are underlain by Bijiki or Negaunee Iron Formation which in the Marquette district includes grunerite- magnetite schists (Van Hise and Leith, 1911; Richarz, 1927a, b, c; 1932). Northern Peninsula. Baraga County: Spurr Mountain: “Anthophylite” containing 1.78% Mn is reported by Brooks (1873). Dickinson County: 1. Metronite quarry near Felch: Lamey (1934) reports, along with other silicates, the presence of “feranthophyllite” (=ferro-anthophyllite). This has not been verified and is very doubtful (Heinrich, 1962b). 2. NE ¼ NE ¼, section 23, T42N, R29W: In the Skunk Creek Member of the Solberg Schist, actinolite(?) fringed by an amphibole that “may be anthophyllite” was found in a hornblende- magnetite schist (James et al., 1961). 3. Vulcan Iron Formation: One variant consists of grunerite with magnetite, quartz, and anthophyllite (James et al., 1961). Marquette County: 1. Washington mine: Anthophyllite-quartz-magnetite schist. 2. South of New England mine: In slaty magnetite schist.
    [Show full text]
  • Cordierite-Anthophyllite Rocks at Rat Lake, Manitoba
    ., , .,. '-'-' . MANlTiBA DEPARTMENJ Of MINES. RESOURCES & ENVIRONMENTAl MANIiGEMENT MINERAL BES(lJRCES DIvtSION OPEN FIIB REPORl' 76/1 OORDlERI'l'FI-ANTHOPHIWTE ROCKS AT RAT LAKE, MlNI'l'OBA; A METAMORPHOSED ALTERATION ZONE By D. A. Baldwin 19'16 Electronic Capture, 2011 The PDF file from which this document was printed was generated by scanning an original copy of the publication. Because the capture method used was 'Searchable Image (Exact)', it was not possible to proofread the resulting file to remove errors resulting from the capture process. Users should therefore verify critical information in an original copy of the publication. .. :., ,.' . .... .- .• I Tt'! OF CC!fl!fl'S .. ' i. -, Page Ifttraduct10n 1 ," Glael'll QeoloIJ 3 · ~ · " "'ell.e. ot unJcnom aft1DitJ (3, 4) 4 .' Coderite-AnthopbJlllte Roc1c1 6 ~I beU'.I.DI l'Ockl 6 .. " Quarts tree l'Ockl 6 ChIld..tl7 ot the Rat take Cordier1tWnthophJllite " BoGIe. 11 Oripn ot the Cord1.r1te-Antho~1l1tl Rocke 15 0I0phJ11ft81 IW'VI),' 18 '. :,(~, Airbome INPUT IVVi,Y 18 ..16 IUl'VI)' 20 OoIIalulonl IDCi Recoanendatianl 21 Iet.rtnael 2, Appendix "A" 25 Appendix "I" 27 \ , I .. ·. ~ . : . ~ . ·-. - 1-· IN'lRODUCTION -==ar=====:==s COrdierite-anthophyllite rocks containing disseminated sulphides of il'Onand copper, and traces of molybdn1te outcrop on the south shore of a small bay at Rat take, Manitoba (Location "5", Fig. 1). These rocks are siDdlar to those that occur in association with massive sulphide ore bodies at the Sherridon MLne, Manitoba, and the Coronation Mine, Saskatchewan. '!'he outcrops are found in an amphibolitic unit within cordierite­ s1 1limarrlte-anthophyll1te-biotite gneisses of ''unknown affinity" (Schledewitz, 1972).
    [Show full text]
  • Anthophyllite Asbestos: State of the Science Review Shannon H
    Review article Received: 11 May 2016, Accepted: 17 May 2016 Published online in Wiley Online Library: 11 July 2016 (wileyonlinelibrary.com) DOI 10.1002/jat.3356 Anthophyllite asbestos: state of the science review Shannon H. Gaffneya*, Matthew Grespinb, Lindsey Garnicka, Derek A. Drechselb, Rebecca Hazanc,DennisJ.Paustenbachd and Brooke D. Simmonsa ABSTRACT: Anthophyllite is an amphibole form of asbestos historically used in only a limited number of products. No published resource currently exists that offers a complete overview of anthophyllite toxicity or of its effects on exposed human populations. We performed a review focusing on how anthophyllite toxicity was understood over time by conducting a comprehensive search of publicly available documents that discussed the use, mining, properties, toxicity, exposure and potential health effects of anthophyllite. Over 200 documents were identified; 114 contained relevant and useful information which we present chronolog- ically in this assessment. Our analysis confirms that anthophyllite toxicity has not been well studied compared to other asbestos types. We found that toxicology studies in animals from the 1970s onward have indicated that, at sufficient doses, anthophyllite can cause asbestosis, lung cancer and mesothelioma. Studies of Finnish anthophyllite miners, conducted in the 1970s, found an increased incidence of asbestosis and lung cancer, but not mesothelioma. Not until the mid-1990s was an epidemiological link with mesothelioma in humans observed. Its presence in talc has been of recent significance in relation to potential asbestos exposure through the use of talc-containing products. Characterizing the health risks of anthophyllite is difficult, and distinguishing between its asbestiform and non-asbestiform mineral form is essential from both a toxicological and regulatory perspective.
    [Show full text]
  • Asbestos in Commercial Cosmetic Talcum Powder As a Cause of Mesothelioma in Women
    Asbestos in commercial cosmetic talcum powder as a cause of mesothelioma in women Ronald E. Gordon1, Sean Fitzgerald2, James Millette3 1Department of Pathology, Icahn School of Medicine at Mount Sinai, New York, USA, 2SAI Laboratory, Greensboro, NC, USA, 3MVA Inc., Duluth, GA, USA Background: Cosmetic talcum powder products have been used for decades. The inhalation of talc may cause lung fibrosis in the form of granulomatose nodules called talcosis. Exposure to talc has also been suggested as a causative factor in the development of ovarian carcinomas, gynecological tumors, and mesothelioma. Purpose: To investigate one historic brand of cosmetic talcum powder associated with mesothelioma in women. Methods: Transmission electron microscope (TEM) formvar-coated grids were prepared with concentra- tions of one brand of talcum powder directly, on filters, from air collections on filters in glovebox and simulated bathroom exposures and human fiber burden analyses. The grids were analyzed on an analytic TEM using energy-dispersive spectrometer (EDS) and selected-area electron diffraction (SAED) to determine asbestos fiber number and type. Results: This brand of talcum powder contained asbestos and the application of talcum powder released inhalable asbestos fibers. Lung and lymph node tissues removed at autopsy revealed pleural mesothelioma. Digestions of the tissues were found to contain anthophyllite and tremolite asbestos. Discussion: Through many applications of this particular brand of talcum powder, the deceased inhaled asbestos fibers, which then accumulated in her lungs and likely caused or contributed to her mesothelioma as well as other women with the same scenario. Keywords: Asbestos, Talcum powder, Chamber test, TEM, SEM, EDS, SAED, Mesothelioma Introduction In 1976, Rohl and Langer tested 20 consumer Malignant mesothelioma occurs in both the perito- products labeled as talc or talcum powder, including 1 neum and in the lung pleura.
    [Show full text]
  • Petrology and Origin of the Day Book Dunite, Yancey County, North Carolina
    PETROLOGY AND ORIGIN OF THE DAY BOOK DUNITE, YANCEY COUNTY, NORTH CAROLINA A Thesis Presented in Partial Fulfillment of the Requirements for the Degree Bachelor of Science By James S. Guentert The Ohio State U~iversity 1984 Approved By: ABSTRACT The Day Book dunite body is one of many 11 alpine-type 11 ultramafic bodies that outcrop in the Blue Ridge belt of the southern Appalachians.n The petrography of the Day Book dunite was studied in thin sections and polished surfaces to identify primary and secondary minerals, paragenetic relationships, and recrystallization and deformational textures. 01 ivine, enstat ite and chromite comprise the primary mineral assemb 1age, and theh secondary minerals include serpentine, talc, chlorite, anthophyllite, magnesite, tremolite and magnetite. Small, recrystallized olivine grains form a mosaic in which are found large, deformed, relict olivine grains. 11 Disseminated 11 chromite occurs as polygonal, straight­ sided grains that represent annealing recrystallization, whereas 11 11 massive chromite exhibits cataclastic texture and alterationn to magnetite. The Day Book body formed as upwelled mantle material in a Precambrian rift system along the margin of the North American continent, and it was squeezed and thrust into p1 ace during the Tac on i c orogeny. Lack of contact metamorphism and evidence of chilled borders indicate 11 11 that the dunite body was emplaced as cold , solid, mantle-derived ultramafic material that later underwent hydrous alteration during regional metamorphism and/or the intrusion of pegmatites. ACKNOWLEDGEMENTS I would like to thank Dr. Douglas Pride for his guidance during the research and writing of this thesis. I also would like to thank Robin Baker, Scott Langford and Mary Dylewski for preparing the thin sections and polished surfaces.
    [Show full text]
  • Crystal Structure of Protoanthophyllite: a New Mineral from the Takase Ultramafic Complex, Japan
    American Mineralogist, Volume 88, pages 1718–1723, 2003 Crystal structure of protoanthophyllite: A new mineral from the Takase ultramafic complex, Japan HIROMI KONISHI,1,* THOMAS L. GROY,2 ISTVÁN DÓDONY,2,3 RITSURO MIYAWAKI,4 SATOSHI MATSUBARA,4 AND PETER R. BUSECK1,2 1Department of Geological Sciences, Arizona State University, Tempe, Arizona 85287-1404, U.S.A. 2Department of Chemistry/Biochemistry, Arizona State University, Tempe, Arizona 85287-1604, U.S.A. 3Department of Mineralogy, Eötvös L. University, Budapest, H-1117, Pázmány Péter sétány 1/C, Hungary 4Department of Geology, National Science Museum, 3-23-1 Hyakunincho, Shinjuku, Tokyo 169-0073, Japan ABSTRACT Protoanthophyllite, (Mg, Fe)7Si8O22(OH)2, is a newly discovered amphibole species from the Takase ultramafic complex in Japan. It occurs as prismatic crystals up to 5 mm in length in a ther- mally altered serpentinite that experienced contact metamorphism. The protoanthophyllite is asso- ciated with forsterite, talc, serpentine minerals, chlorite, chromian spinel, magnetite, pentlandite, and calcite. Some protoanthophyllite crystals contain minute lamellae of anthophyllite, other pyriboles, or both. Protoanthophyllite is biaxial negative, with refractive indices na = 1.593(2), nb (calc.) = 1.609, ng = 1.615(2), and 2Vx = 64(5)∞. Electron microprobe analyses give an empirical formula of (Mg6.31Fe0.61Na0.06Mn0.01Ni0.01)S7.00(Si7.90Al0.14)S8.04O22(OH)2. It is orthorhombic with space group Pnmn. The unit-cell dimensions are a = 9.3553(8), b = 17.9308(15), and c = 5.3117(4) Å: with V = 891.0(3) Å3 and Z = 2. A single-crystal X-ray structure determination shows that, following the convention of Thompson (1981), protoanthophyllite has an (X) configuration.
    [Show full text]
  • Thn AUERICAN Mtl,Ieralogist of AMERICA JOURNAL of the MINERALOGICAL SOCIETY
    THn AUERICAN Mtl,IERALoGIST OF AMERICA JOURNAL OF THE MINERALOGICAL SOCIETY 6 Vol. 33 MAY-JUNE, 1948 Nos. 5 and A NEW STUDY OF THE ANTHOPHYLLITE SERIES*I JorN C. RAnBrrt, U. S. GeologicalSuruey, Washington, D' C' ColltrNrs Abstiact...... 263 The problem. 264 Nomenclatureandclassification...... 266 Conclusions and suggestions for a revision of the series. 315 316 Acknowledgments. 317 References and selected bibliography ' AssrRect series The composition and some physical properties of 96 varieties in the anthophyllite Cherry are studied. Included is data on- r"u"n ,t"* anthophyllites from the pie-Beltian optical Creek rocks of Southwestern Montana. Chemical analyses, spectrographic analyses, presented for the Montana varieties' -similarproperties, densities, and unit-cell structure are x-ray information is presented in part for 89 varieties described in the literature' * Abridged from a Ph.D. thesis, "Anthophyllite and Its Occurrence in Southwestern Montana,"bepartment of Mineralogy and Petrography, Harvard University, 1946' and Petrography, Harvard Uni- t Contribuion from the Department of Mineralogy versity, No. 296. 264 JOHN C. RABBITT The name anthophyllite should be used for all members of the series. Chemical suffixes as proposed by Schaller (1930) can be used to indicate any variation in composition if krrown' All synonymsr such as gedrite, amosite, picroamosite, and ferroanthophylite, should be dropped. The series can be characterized by the general formula XzyeOz(OH, F)e where X is chiefly Mg, Fe", Al and in minor part Mn, Ti, Fe,.,,,Ca, Na, K; y is chiefly Si and in part Al. In X the maximum of Al is (Mg, Fe,,)sAlr and the maximum amount of Fe,, is about (Mg3.s Fe3.s).In Y the maximum amount of Al is (Si6Alr).
    [Show full text]
  • The Effect of Grinding on Tremolite Asbestos and Anthophyllite Asbestos
    minerals Article The Effect of Grinding on Tremolite Asbestos and Anthophyllite Asbestos Andrea Bloise 1,* ID , Robert Kusiorowski 2 ID and Alessandro F. Gualtieri 3 1 Department of Biology, Ecology and Earth Sciences, University of Calabria, via Pietro Bucci, I-87036 Rende, CS, Italy 2 Institute of Ceramics and Building Materials, Refractory Materials Division in Gliwice, ul. Toszecka 99, 44-100 Gliwice, Poland; [email protected] 3 Department of Chemical and Geological Sciences, University of Modena and Reggio Emilia, I-41125 Modena, Italy; [email protected] * Correspondence: [email protected]; Tel.: +39-0984-493588 Received: 4 June 2018; Accepted: 25 June 2018; Published: 28 June 2018 Abstract: The six commercial asbestos minerals (chrysotile, fibrous actinolite, crocidolite, amosite, fibrous tremolite, and fibrous anthophyllite) are classified by the IARC as carcinogenic to humans. There are currently several lines of research dealing with the inertisation of asbestos minerals among which the dry grinding process has received considerable interest. The effects of dry grinding on tremolite asbestos and anthophyllite asbestos in eccentric vibration mills have not yet been investigated. Along the research line of the mechanical treatment of asbestos, the aim of this study was to evaluate the effects of dry grinding in eccentric vibration mills on the structure, temperature stability, and fibre dimensions of tremolite asbestos from Val d’Ala, (Italy) and UICC standard anthophyllite asbestos from Paakkila mine (Finland) by varying the grinding time (30 s, 5 min, and 10 min). After grinding for 30 s to 10 min, tremolite asbestos and anthophyllite asbestos showed a decrease in dehydroxylation and breakdown temperatures due to the increase in lattice strain and the decrease in crystallinity.
    [Show full text]
  • Metamorphism of Hydrothermally Altered Rocks in a Volcanogenic Massive Sulfide Deposit: the Palmeirópolis, Brazil, Example
    Revista Brasileira de Geociencias 25(3):173-184, setembro de 1995 METAMORPHISM OF HYDROTHERMALLY ALTERED ROCKS IN A VOLCANOGENIC MASSIVE SULFIDE DEPOSIT: THE PALMEIRÓPOLIS, BRAZIL, EXAMPLE SYLVIA M. ARAUJO*,1, J. JEFFREY FAWCETT** & STEVEN D. SCOTT** ABSTRACT The PALMEIRÓPOLIS Cu-Zn (Pb) volcanogenic massive sulfide deposit, Brazil, consists of three ore bodies enclosed by hydrothermal alteration zones. The ore bodies and the alteration zones were metamorphosed under amphibolite fades conditions. The Palmeirdpolis alteration zones are characterized by a great diversity of bulk rock composition that originated a wide variety of low variance mineral assemblages. These assemblages are composed of orthoamphiboles (anthophyllite and gedrite), hornblende, biotite, garnet, staurolite, sillimanite, gahnite and, rarer, cordierite. Based on analyses of mineral chemistry aad mineral assemblages, temperatures are estimated to have been 550 - 625°C and pressures 2 - 5.5 kbar. The temperature of metamorphism that prevailed at the Palmeirdpolis deposit is comparable to other amphibolite fades massive sulfide deposits, such as Geco and Linda, Canada; Falun, Sweden; and Bleikvassli, Norway. The mineralogy of the alteration zones is similar in all these deposits even though they were metamorphosed at different pressure conditions, reflected by the crystallization of one of Al2SiO5 phase (andalusite, sillimanite or kyanite). Keywords: volcanogenic deposit, hydrothermal alteration zones, amphibolite fades. RESUMO METAMORFISMO DE ROCHAS HIDROTERMALMENTE ALTERADAS ASSOCIADAS A DEPÓSITO DE SULFETO MACIÇO VULCANOGÊNICO: O EXEMPLO DE PALMEIRÓPOLIS, BRASIL O depósito de sulfeto MACIÇO a Zn e Cu vulcanogenico de Palmeirdpolis, Brasil, consiste de tres corpos de minério associados a zonas de alteração hidrotermal. Os corpos de minério e as zonas de alteração foram metamorfisados no fades anfibolito.
    [Show full text]
  • Identification Tables for Common Minerals in Thin Section
    Identification Tables for Common Minerals in Thin Section These tables provide a concise summary of the properties of a range of common minerals. Within the tables, minerals are arranged by colour so as to help with identification. If a mineral commonly has a range of colours, it will appear once for each colour. To identify an unknown mineral, start by answering the following questions: (1) What colour is the mineral? (2) What is the relief of the mineral? (3) Do you think you are looking at an igneous, metamorphic or sedimentary rock? Go to the chart, and scan the properties. Within each colour group, minerals are arranged in order of increasing refractive index (which more or less corresponds to relief). This should at once limit you to only a few minerals. By looking at the chart, see which properties might help you distinguish between the possibilities. Then, look at the mineral again, and check these further details. Notes: (i) Name: names listed here may be strict mineral names (e.g., andalusite), or group names (e.g., chlorite), or distinctive variety names (e.g., titanian augite). These tables contain a personal selection of some of the more common minerals. Remember that there are nearly 4000 minerals, although 95% of these are rare or very rare. The minerals in here probably make up 95% of medium and coarse-grained rocks in the crust. (ii) IMS: this gives a simple assessment of whether the mineral is common in igneous (I), metamorphic (M) or sedimentary (S) rocks. These are not infallible guides - in particular many igneous and metamorphic minerals can occur occasionally in sediments.
    [Show full text]