Turfgrass Weed Control
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(12) United States Patent (10) Patent No.: US 8,586,504 B2 Wright Et Al
USOO85865.04B2 (12) United States Patent (10) Patent No.: US 8,586,504 B2 Wright et al. (45) Date of Patent: Nov. 19, 2013 (54) HERBICIDAL COMPOSITIONS CONTAINING FOREIGN PATENT DOCUMENTS GLYPHOSATE AND A PYRONE ANALOG AU 100.73/92 B 10, 1992 CA 2340240 A1 2, 2000 (75) Inventors: Daniel R. Wright, St. Louis, MO (US); EP O 808 569 A1 11, 1997 Joseph J. Sandbrink, Chesterfield, MO GB 2267 825 A 12/1993 (US); Paul G. Ratliff, Olivette, MO WO 99/00013 1, 1999 WO OO,30452 6, 2000 (US) WO OO,642.57 11, 2000 WO OO/67571 11, 2000 (73) Assignee: Monsanto Technology LLC, St. Louis, WO O1/35740 A2 5, 2001 MO (US) WO 02/21924 A2 3, 2002 (*) Notice: Subject to any disclaimer, the term of this OTHER PUBLICATIONS patent is extended or adjusted under 35 Exhibit PMH-17 Supplemental Labeling regarding Roundup Pro U.S.C. 154(b) by 0 days. Herbicide by Monsanto, EPA Reg. No. 524-475 (Nov. 1995), 11 pageS. (21) Appl. No.: 13/404,861 Exhibit PMH-18 Notice of Pesticide Registration issued on Oct. 5, 2000, 35 pages. Exhibit PMH-19 EPA Application for Pesticide, ID No. 200405 (22) Filed: Feb. 24, 2012 (Sep. 1995), 33 pages. Exhibit PMH-20-Documentation regarding Starmas Racun/ (65) Prior Publication Data Rumpai Herbicide (bears the year 2003), 10 pages. Exhibit PMH-21—Documentation regarding Starmix Racun/ US 2012/O157309 A1 Jun. 21, 2012 Rumpai Herbicide (Date Unknown), 3 pages. Exhibit PMH-22—article entitled Control of Eucalyptus grandis cut stumps by Keith Little et al., ICFR Bulletin Series, No. -
2,4-Dichlorophenoxyacetic Acid
2,4-Dichlorophenoxyacetic acid 2,4-Dichlorophenoxyacetic acid IUPAC (2,4-dichlorophenoxy)acetic acid name 2,4-D Other hedonal names trinoxol Identifiers CAS [94-75-7] number SMILES OC(COC1=CC=C(Cl)C=C1Cl)=O ChemSpider 1441 ID Properties Molecular C H Cl O formula 8 6 2 3 Molar mass 221.04 g mol−1 Appearance white to yellow powder Melting point 140.5 °C (413.5 K) Boiling 160 °C (0.4 mm Hg) point Solubility in 900 mg/L (25 °C) water Related compounds Related 2,4,5-T, Dichlorprop compounds Except where noted otherwise, data are given for materials in their standard state (at 25 °C, 100 kPa) 2,4-Dichlorophenoxyacetic acid (2,4-D) is a common systemic herbicide used in the control of broadleaf weeds. It is the most widely used herbicide in the world, and the third most commonly used in North America.[1] 2,4-D is also an important synthetic auxin, often used in laboratories for plant research and as a supplement in plant cell culture media such as MS medium. History 2,4-D was developed during World War II by a British team at Rothamsted Experimental Station, under the leadership of Judah Hirsch Quastel, aiming to increase crop yields for a nation at war.[citation needed] When it was commercially released in 1946, it became the first successful selective herbicide and allowed for greatly enhanced weed control in wheat, maize (corn), rice, and similar cereal grass crop, because it only kills dicots, leaving behind monocots. Mechanism of herbicide action 2,4-D is a synthetic auxin, which is a class of plant growth regulators. -
Armortech ® THREESOME ® Label
2,4-D • MECOPROP-p • DICAMBA Threesome® Herbicide Selective broadleaf weed control for turfgrass including use on sod farms. To control clover, dandelion, henbit, plantains, wild onion, and many other broadleaf weeds. Also for highways, rights-of-way and other similar non-crop areas as listed on this label. Contains 2,4-D, mecoprop-p, and dicamba. ACTIVE INGREDIENTS KEEP OUT OF REACH OF CHILDREN Dimethylamine Salt of 2,4-Dichlorophenoxyacetic Acid* .......30.56% Dimethylamine Salt of (+)-R-2-(2-Methyl-4-Chlorophenoxy) DANGER – PELIGRO propionic Acid**‡ .......................................................................8.17% Si usted no entiende la etiqueta, busque a alguien para que se la Dimethylamine Salt of Dicamba (3,6-Dichloro-o-anisic Acid)*** 2.77% explique a usted en detalle. (If you do not understand the label, find someone to explain it to you OTHER INGREDIENTS: ......................................................................58.5% in detail.) TOTAL: ....................................................................................100.00% Isomer Specific Method, Equivalent to: *2,4-Dichlorophenoxyacetic Acid ................................... 25.38%, 2.38 lbs/gal PRECAUTIONARY STATEMENTS **(+)-R-2-(2-Methyl-4-Chlorophenoxy)propionic Acid.... 6.75%, 0.63 lbs/gal HAZARDS TO HUMANS AND DOMESTIC ANIMALS ***3,6-Dichloro-o-anisic Acid .......................................... 2.30%, 0.22 lbs/gal Corrosive. Causes irreversible eye damage. Do not get in eyes, or on skin or clothing. ‡CONTAINS THE SINGLE ISOMER FORM OF MECOPROP-p Harmful if swallowed. FIRST AID IF • Call a poison control center or doctor immediately for treatment advice. HOT LINE NUMBER SWALLOWED: • Have person sip a glass of water if able to swallow. Have the product container or label with you when calling a poison control • Do not induce vomiting unless told to do so by the poison control center or doctor. -
Weed Discrimination Using Ultrasonic Sensors
INSIGHTS DOI: 10.1111/j.1365-3180.2011.00876.x Weed discrimination using ultrasonic sensors D ANDU´JAR*, A ESCOLA` , J DORADO* & C FERNA´NDEZ-QUINTANILLA* *Instituto de Ciencias Agrarias, CSIC, Madrid, Spain, and Universitat de Lleida, Lleida, Spain Received 11 March 2011 Revised version accepted 7 June 2011 Subject Editor: Peter Lutman, UK sis revealed that the ultrasonic data could separate three Summary groups of assemblages: pure stands of broad-leaved A new approach is described for automatic discrimina- weeds (lower height), pure stands of grasses (higher tion between grasses and broad-leaved weeds, based on height) and mixed stands of broad-leaved and grass their heights. An ultrasonic sensor was mounted on the weeds (medium height). Dynamic measurements con- front of a tractor, pointing vertically down in the inter- firmed the potential of this system to detect weed row area, with a control system georeferencing and infestations. This technique offers significant promise for registering the echoes reflected by the ground or by the the development of real-time spatially selective weed various leaf layers. Static measurements were taken at control techniques, either as the sole weed detection locations with different densities of grasses (Sorghum system or in combination with other detection tools. halepense) and broad-leaved weeds (Xanthium strumar- Keywords: weed species discrimination, site-specific ium and Datura spp.). The sensor readings permitted the weed management, wide-row crops, ultrasound detec- discrimination of pure stands of grasses (up to 81% tion, patch, sonar. success) and pure stands of broad-leaved weeds (up to 99% success). Moreover, canonical discriminant analy- ANDU´JAR D, ESCOLA` A, DORADO J&FERNA´NDEZ-QUINTANILLA C (2011). -
Herbicide Mode of Action Table High Resistance Risk
Herbicide Mode of Action Table High resistance risk Chemical family Active constituent (first registered trade name) GROUP 1 Inhibition of acetyl co-enzyme A carboxylase (ACC’ase inhibitors) clodinafop (Topik®), cyhalofop (Agixa®*, Barnstorm®), diclofop (Cheetah® Gold* Decision®*, Hoegrass®), Aryloxyphenoxy- fenoxaprop (Cheetah®, Gold*, Wildcat®), fluazifop propionates (FOPs) (Fusilade®), haloxyfop (Verdict®), propaquizafop (Shogun®), quizalofop (Targa®) Cyclohexanediones (DIMs) butroxydim (Factor®*), clethodim (Select®), profoxydim (Aura®), sethoxydim (Cheetah® Gold*, Decision®*), tralkoxydim (Achieve®) Phenylpyrazoles (DENs) pinoxaden (Axial®) GROUP 2 Inhibition of acetolactate synthase (ALS inhibitors), acetohydroxyacid synthase (AHAS) Imidazolinones (IMIs) imazamox (Intervix®*, Raptor®), imazapic (Bobcat I-Maxx®*, Flame®, Midas®*, OnDuty®*), imazapyr (Arsenal Xpress®*, Intervix®*, Lightning®*, Midas®* OnDuty®*), imazethapyr (Lightning®*, Spinnaker®) Pyrimidinyl–thio- bispyribac (Nominee®), pyrithiobac (Staple®) benzoates Sulfonylureas (SUs) azimsulfuron (Gulliver®), bensulfuron (Londax®), chlorsulfuron (Glean®), ethoxysulfuron (Hero®), foramsulfuron (Tribute®), halosulfuron (Sempra®), iodosulfuron (Hussar®), mesosulfuron (Atlantis®), metsulfuron (Ally®, Harmony®* M, Stinger®*, Trounce®*, Ultimate Brushweed®* Herbicide), prosulfuron (Casper®*), rimsulfuron (Titus®), sulfometuron (Oust®, Eucmix Pre Plant®*, Trimac Plus®*), sulfosulfuron (Monza®), thifensulfuron (Harmony®* M), triasulfuron (Logran®, Logran® B-Power®*), tribenuron (Express®), -
U.S. EPA, Pesticide Product Label, DICAMBAZINE, 09/25/2003
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY WASHINGTON. D.C. 20460 OFFICE OF PREVENTION, PESTICIDES AND TOXIC SUBSTANCES SEP 2 5 2003 Albaugh, Inc. clo Pyxis Regulatory Consulting, Inc. ATTN: Michael Kellogg 11324 1']'1' Ave. Ct. NW Gig Harbor, W A 98332 Dear Mr. Kellogg: Subject: Fast Track Amendment for Atrazine Product Product: Dicambaiine EPA Registration Number: 42750-41 Submission Date: 04/24/03 The labeling referred to above, submitted in connection with registration under the Federal Insecticide, Fungicide and Rodenticide Act, as amended is acceptable, provided you make the followmg changes before you release the product for shipment. 1. Change the PPE section to the following: • "Some materials that are chemical-resistant to this product are barrier laminate> 14 mils, neoprene rubber> 14 mils, polyvinyl chloride (PVC) > 14 mils, butyl rubber> 14 mils, orviton >14 mils. Ifyou want more options, follow the instructions for category A on an EPA chemical-resistance category selection chart. " • "Mixers, loaders, applicators and other handlers not using Engineering Controls must wear: Coveralls over long sleeved ~hirt and long pants Chemical resistant gloves Chemical resistant footwear plus socks Chemical resistant headgear (if overhead exposure) A NlOSH approved dust mist filtering respirator with any N, R, P or HE filter A chemical resistant apron (if exposed to undiluted product)" • "Mixers, loaders, applicators and other handlers using Engineering Controls must wear: Long-sleeved shirt and long pants Chemical resistant gloves and apron for mixers and loaders Shoes plus socks See Engineering Controls for additional requirements" Note to registrant: You must drop the N type filter from the respirator statement if the product contains or is used with oil. -
Exposure to Herbicides in House Dust and Risk of Childhood Acute Lymphoblastic Leukemia
Journal of Exposure Science and Environmental Epidemiology (2013) 23, 363–370 & 2013 Nature America, Inc. All rights reserved 1559-0631/13 www.nature.com/jes ORIGINAL ARTICLE Exposure to herbicides in house dust and risk of childhood acute lymphoblastic leukemia Catherine Metayer1, Joanne S. Colt2, Patricia A. Buffler1, Helen D. Reed3, Steve Selvin1, Vonda Crouse4 and Mary H. Ward2 We examine the association between exposure to herbicides and childhood acute lymphoblastic leukemia (ALL). Dust samples were collected from homes of 269 ALL cases and 333 healthy controls (o8 years of age at diagnosis/reference date and residing in same home since diagnosis/reference date) in California, using a high-volume surface sampler or household vacuum bags. Amounts of agricultural or professional herbicides (alachlor, metolachlor, bromoxynil, bromoxynil octanoate, pebulate, butylate, prometryn, simazine, ethalfluralin, and pendimethalin) and residential herbicides (cyanazine, trifluralin, 2-methyl-4- chlorophenoxyacetic acid (MCPA), mecoprop, 2,4-dichlorophenoxyacetic acid (2,4-D), chlorthal, and dicamba) were measured. Odds ratios (OR) and 95% confidence intervals (CI) were estimated by logistic regression. Models included the herbicide of interest, age, sex, race/ethnicity, household income, year and season of dust sampling, neighborhood type, and residence type. The risk of childhood ALL was associated with dust levels of chlorthal; compared to homes with no detections, ORs for the first, second, and third tertiles were 1.49 (95% CI: 0.82–2.72), 1.49 (95% CI: 0.83–2.67), and 1.57 (95% CI: 0.90–2.73), respectively (P-value for linear trend ¼ 0.05). The magnitude of this association appeared to be higher in the presence of alachlor. -
Weed Control in Direct-Seeded Field Pea Gregory J
Weed Control in Direct-seeded Field Pea Gregory J. Endres and Blaine G. Schatz Weed control and field pea response to selected soil- and POST-applied herbicides were evaluated in a randomized complete-block design with three replicates. The experiment was conducted on a Heimdahl loam soil with 6.7 pH and 2.9% organic matter at the NDSU Carrington Research Extension Center. Herbicide treatments were applied to 5- by 25-ft plots with a pressurized hand-held plot sprayer at 17 gal/A and 30 psi through 8002 flat-fan nozzles. Fall sulfentrazone treatments were applied October 25, 2004 to a moist soil surface with 47 F, 71% RH, 15% clear sky, and 11 mph wind. On April 28, 2005, inoculated 'Integra' field pea was seeded into standing wheat stubble in 7-inch rows at a rate of 300,000 pure live seeds/A. PRE treatments were applied to a dry soil surface on April 30 with 31 F, 64% RH, 30% clear sky, and 10 mph wind. Rainfall totaled 1.22 inches 8 d following PRE application. The trial area was treated on May 6 with a PRE burn-down application of glyphosate at 0.75 lb ae/A plus ammonium sulfate at 1% v/v. The early POST (EPOST) treatment was applied on May 23 with 73 F, 35% RH, 100% cloudy sky, and 6 mph wind to 2-inch tall field pea, 1- to 2-leaf green and yellow foxtail, 0.5-inch tall common lambsquarters, 0.5-inch tall prostrate and redroot pigweed, and 0.5-inch tall wild buckwheat. -
Beta Cinema Presents a Purple Bench Films / Zero Gravity Films / Live Through the Heart Films / Barry Films / Furture Films Production “Walter” Andrew J
BETA CINEMA PRESENTS A PURPLE BENCH FILMS / ZERO GRAVITY FILMS / LIVE THROUGH THE HEART FILMS / BARRY FILMS / FURTURE FILMS PRODUCTION “WALTER” ANDREW J. WEST JUSTIN KIRK NEVE CAMPBELL LEVEN RAMBIN MILO VENTIMIGLIA JIM GRAFFIGAN BRIAN WHITE PETER FACINELLI VIRGINIA MADSEN WILLIAM H. MACY CASTING J.C. CANTU MUSIC DAN ROMER MUSIC SUPERVISOR KIEHR LEHMAN EDITING KRISTIN MCCASEY DIRCTOR OF PHOTOGRAPHY STEVE CAPITANO CALITRI PRODUCTION DESIGN MICHAEL BRICKER COSTUMES LAUREN SCHAD EXECUTIVE PRODUCERS BILL JOHNSON SAM ENGELBARDT JENNIFER LAURENT RICK ST. GEORGE JOHN FULLER CARL RUMBAUGH TIM HILL RICKY MARGOLIS SIMON GRAHAM-CLARE WOLFGANG MUELLER MICHEL MERKT ANNA MASTRO CO-EXECUTIVE PRODUCERS STEFANIE MASTRO MICHAEL DAVID MASTRO KEITH MATSON AND JOANNE MATSON CO-PRODUCER ANTONIO SCLAFANI ASSOCIATE PRODUCER MICHAEL BRICKER PRODUCED BY MARK HOLDER CHRISTINE HOLDER BRENDEN PATRICK HILL RYAN HARRIS BENITO MUELLER WRITTEN BY PAUL SHOULBERG DIRECTED BY ANNA MASTRO Director Anna Mastro (GOSSIP GIRL) Cast William H. Macy (SHAMELESS, FARGO) Virginia Madsen (SIDEWAYS) Peter Facinelli (TWILIGHT) Andrew J. West (THE WALKING DEAD) Justin Kirk (WEEDS, MR. MORGAN‘S LAST LOVE) Neve Campbell (SCREAM, WILD THINGS) Milo Ventimiglia (HEROS, THAT´S MY BOY) Genre Comedy / Drama Language English Length 88 min Produced by Zero Gravity, Purple Bench Films, Barry Films and Demarest Films WALTER SYNOPSIS Walter believes himself to be the son of God. As such, it is his responsibility to judge whether people will spend eternity in heaven or hell. That’s a lot to manage along with his job as a ticket- tearer at a movie theater, his loving but neurotic mother, and his growing but unspoken affection for his co-worker Kendall. -
Safety and Efficacy of Postemergence Herbicides for Container-Grown Landscape Groundcovers
1 17B-Student-Conner-IPPS-2018.doc Safety and Efficacy of Postemergence Herbicides for Container-Grown Landscape Groundcovers© Crystal J. Connera, Chris Marble, and Annette Chandler Mid-Florida Research and Education Center, University of Florida, 2725 S. Binion Road, Apopka, Florida 32703, USA aEmail: [email protected] KeyWords: Landscape nursery, weed management, asiatic jasmine, Trachelospermum asiaticum ‘Minima’, perennial peanut, Arachis glabrata ‘Ecoturf’ SUMMARY Research was conducted to determine crop tolerance of asiatic jasmine (Trachelospermum asiaticum ‘Minima’) and perennial peanut (Arachis glabrata ‘Ecoturf’) to postemergence herbicides including bentazon, sulfentrazone, iron HEDTA, indaziflam (a preemergence herbicide), sulfosulfuron, and clopyralid. Efficacy of these herbicides was evaluated on flowering eclipta (Eclipta prostrata) and hairy beggarticks (Bidens pilosa). All herbicides with the exception of bentazon caused no significant damage to asiatic jasmine; injury resulting from bentazon was minimal. In perennial peanut, the highest injury was noted in plants treated with indaziflam, sulfosulfuron, or clopyralid, but injury was less than 30% and considered acceptable. All herbicides evaluated provided poor control of either weed species with the exception of clopyralid, which provided over 90% control of hairy beggarticks. Results indicate that several postemergence herbicides labeled for use in either nurseries or landscapes could be used to manage weeds in asiatic jasmine or perennial peanut groundcovers but further testing is needed. 1 2 INTRODUCTION Turfgrass is the most widely planted irrigated crop in the United States and occupies the vast majority of most residential and commercial landscapes in Florida (NTRI, 2003). However, the common mantra of landscape design is “right plant right place”. In many neighborhoods, parks, and other areas containing significant tree canopy, turfgrass is not suitable due to limited sunlight. -
Appendix C - Wildlife 9/8/2008
INVASIVE PLANT BIOLOGICAL ASSESSMENT Umatilla and Wallowa-Whitman National Forests Appendix C - Wildlife 9/8/2008 APPENDIX C - WILDLIFE C-1 INVASIVE PLANT BIOLOGICAL ASSESSMENT Umatilla and Wallowa-Whitman National Forests Appendix C - Wildlife 9/8/2008 C-2 INVASIVE PLANT BIOLOGICAL ASSESSMENT Umatilla and Wallowa-Whitman National Forests Appendix C - Wildlife 9/8/2008 Appendix C ......................................................................................................................... 1 Wildlife ............................................................................................................................... 1 Exposure Groups for Forest Service Sensitive Wildlife ................................................. 6 Effects of the Alternatives on Sensitive Wildlife ........................................................... 7 Tables C-5 – C-13 Herbicides ................................................................................... 11 Umatilla and Wallowa-Whitman National Forest Herbicide Spray Buffers ................ 12 Aquatics............................................................................................................. 15 Wildlife .............................................................................................................. 15 Worker Health: Based on backpack spray applications. ................................. 15 Public Health: ................................................................................................... 16 Summary of Herbicide Effects to Wildlife -
INDEX to PESTICIDE TYPES and FAMILIES and PART 180 TOLERANCE INFORMATION of PESTICIDE CHEMICALS in FOOD and FEED COMMODITIES
US Environmental Protection Agency Office of Pesticide Programs INDEX to PESTICIDE TYPES and FAMILIES and PART 180 TOLERANCE INFORMATION of PESTICIDE CHEMICALS in FOOD and FEED COMMODITIES Note: Pesticide tolerance information is updated in the Code of Federal Regulations on a weekly basis. EPA plans to update these indexes biannually. These indexes are current as of the date indicated in the pdf file. For the latest information on pesticide tolerances, please check the electronic Code of Federal Regulations (eCFR) at http://www.access.gpo.gov/nara/cfr/waisidx_07/40cfrv23_07.html 1 40 CFR Type Family Common name CAS Number PC code 180.163 Acaricide bridged diphenyl Dicofol (1,1-Bis(chlorophenyl)-2,2,2-trichloroethanol) 115-32-2 10501 180.198 Acaricide phosphonate Trichlorfon 52-68-6 57901 180.259 Acaricide sulfite ester Propargite 2312-35-8 97601 180.446 Acaricide tetrazine Clofentezine 74115-24-5 125501 180.448 Acaricide thiazolidine Hexythiazox 78587-05-0 128849 180.517 Acaricide phenylpyrazole Fipronil 120068-37-3 129121 180.566 Acaricide pyrazole Fenpyroximate 134098-61-6 129131 180.572 Acaricide carbazate Bifenazate 149877-41-8 586 180.593 Acaricide unclassified Etoxazole 153233-91-1 107091 180.599 Acaricide unclassified Acequinocyl 57960-19-7 6329 180.341 Acaricide, fungicide dinitrophenol Dinocap (2, 4-Dinitro-6-octylphenyl crotonate and 2,6-dinitro-4- 39300-45-3 36001 octylphenyl crotonate} 180.111 Acaricide, insecticide organophosphorus Malathion 121-75-5 57701 180.182 Acaricide, insecticide cyclodiene Endosulfan 115-29-7 79401