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MSD SDSD94292.Pdf Page 1 of 10 Safety Data Sheet acc. to HCS and GHS Printing date 01/09/2015 Reviewed on 01/09/2015 1 Identification · Product identifier · Trade name: Mineral Ice® Pain Relieving Gel · Application of the substance / the mixture Pharmaceutical Product · Details of the supplier of the Safety Data Sheet · Manufacturer/Supplier: Novartis Consumer Health, Inc. 200 Kimball Drive Parsippany, NJ 07054 USA · Information department: Novartis Consumer and Professional Affairs Call Center (800) 452-0051 (24 hours / 7 days a week) · Emergency telephone number: ChemTel Inc. (800)255-3924, +1 (813)248-0585 2 Hazard(s) identification · Classification of the substance or mixture GHS07 Eye Irrit. 2A H319 Causes serious eye irritation. · Label elements · GHS label elements The product is classified and labeled according to the Globally Harmonized System (GHS). · Hazard pictograms GHS07 · Signal word Warning · Hazard statements H319 Causes serious eye irritation. · Precautionary statements P280 Wear eye protection / face protection. P264 Wash thoroughly after handling. P305+P351+P338 If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P337+P313 If eye irritation persists: Get medical advice/attention. · Hazard description: · WHMIS-symbols: D2B - Toxic material causing other toxic effects (Contd. on page 2) 40.0.2 Page 2 of 10 Safety Data Sheet acc. to HCS and GHS Printing date 01/09/2015 Reviewed on 01/09/2015 Trade name: Mineral Ice® Pain Relieving Gel (Contd. of page 1) · Classification system: · NFPA ratings (scale 0 - 4) Health = 0 1 Fire = 1 0 0 Reactivity = 0 · HMIS-ratings (scale 0 - 4) HEALTH 0 Health = 0 FIRE 1 Fire = 1 REACTIVITY 0 Reactivity = 0 · Other hazards · Results of PBT and vPvB assessment · PBT: Not applicable. · vPvB: Not applicable. 3 Composition/information on ingredients · Chemical characterization: Mixtures · Description: Mixture of the substances listed below with nonhazardous additions. · Dangerous components: 67-63-0 propan-2-ol 10-25% Flam. Liq. 2, H225 Eye Irrit. 2, H319; STOT SE 3, H336 89-78-1 menthol 2.5% Skin Irrit. 2, H315; Eye Irrit. 2A, H319 1336-21-6 ammonia, aqueous solution 2.5% Skin Corr. 1B, H314 Aquatic Acute 1, H400 89-83-8 thymol 2.5% Skin Corr. 1B, H314 Aquatic Chronic 2, H411 Acute Tox. 4, H302 7758-98-7 copper sulphate 2.5% Aquatic Acute 1, H400; Aquatic Chronic 1, H410 Acute Tox. 4, H302; Skin Irrit. 2, H315; Eye Irrit. 2A, H319 1310-73-2 sodium hydroxide 2.5% Skin Corr. 1A, H314 (Contd. on page 3) 40.0.2 Page 3 of 10 Safety Data Sheet acc. to HCS and GHS Printing date 01/09/2015 Reviewed on 01/09/2015 Trade name: Mineral Ice® Pain Relieving Gel (Contd. of page 2) 4 First-aid measures · Description of first aid measures · General information: Take affected persons out into the fresh air. · After inhalation: Supply fresh air; consult doctor in case of complaints. · After skin contact: Product is a topical medication. If irritation occurs, discontinue use and wash affected area with soap and water. · After eye contact: Remove contact lenses if worn. Rinse opened eye for several minutes under running water. If symptoms persist, consult a doctor. · After swallowing: Rinse out mouth and then drink plenty of water. Do not induce vomiting; immediately call for medical help. · Most important symptoms and effects, both acute and delayed Dizziness Coughing Irritant to eyes. · Danger No further relevant information available. · Indication of any immediate medical attention and special treatment needed No further relevant information available. 5 Fire-fighting measures · Extinguishing media · Suitable extinguishing agents: CO2, extinguishing powder or water spray. Fight larger fires with water spray or alcohol resistant foam. · For safety reasons unsuitable extinguishing agents: None. · Special hazards arising from the substance or mixture Formation of toxic gases is possible during heating or in case of fire. · Advice for firefighters · Protective equipment: Wear self-contained respiratory protective device. Wear fully protective suit. · Additional information Use large quantities of foam as it is partially destroyed by the product. 6 Accidental release measures · Personal precautions, protective equipment and emergency procedures Wear protective equipment. Keep unprotected persons away. For large spills, use respiratory protective device against the effects of fumes/dust/aerosol. Ensure adequate ventilation. Particular danger of slipping on leaked/spilled product. · Environmental precautions: Do not allow to enter sewers/ surface or ground water. · Methods and material for containment and cleaning up: Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust). Pick up mechanically. (Contd. on page 4) 40.0.2 Page 4 of 10 Safety Data Sheet acc. to HCS and GHS Printing date 01/09/2015 Reviewed on 01/09/2015 Trade name: Mineral Ice® Pain Relieving Gel (Contd. of page 3) Dispose contaminated material as waste according to item 13. Send for recovery or disposal in suitable receptacles. · Reference to other sections See Section 7 for information on safe handling. See Section 8 for information on personal protection equipment. See Section 13 for disposal information. 7 Handling and storage · Precautions for safe handling No special measures required. · Information about protection against explosions and fires: No special measures required. · Conditions for safe storage, including any incompatibilities · Storage: · Requirements to be met by storerooms and receptacles: Avoid storage near extreme heat, ignition sources or open flame. No special requirements. · Information about storage in one common storage facility: Store away from foodstuffs. · Further information about storage conditions: Store in cool, dry conditions in well sealed receptacles. · Specific end use(s) No further relevant information available. 8 Exposure controls/personal protection · Additional information about design of technical systems: No further data; see item 7. · Control parameters · Components with limit values that require monitoring at the workplace: 67-63-0 propan-2-ol PEL (USA) Long-term value: 980 mg/m³, 400 ppm REL (USA) Short-term value: 1225 mg/m³, 500 ppm Long-term value: 980 mg/m³, 400 ppm TLV (USA) Short-term value: 984 mg/m³, 400 ppm Long-term value: 492 mg/m³, 200 ppm BEI EL (Canada) Short-term value: 400 ppm Long-term value: 200 ppm EV (Canada) Short-term value: 400 ppm Long-term value: 200 ppm LMPE (Mexico) Short-term value: 400 ppm Long-term value: 200 ppm A4, IBE 1310-73-2 sodium hydroxide PEL (USA) Long-term value: 2 mg/m³ REL (USA) Ceiling limit value: 2 mg/m³ TLV (USA) Ceiling limit value: 2 mg/m³ (Contd. on page 5) 40.0.2 Page 5 of 10 Safety Data Sheet acc. to HCS and GHS Printing date 01/09/2015 Reviewed on 01/09/2015 Trade name: Mineral Ice® Pain Relieving Gel (Contd. of page 4) EL (Canada) Ceiling limit value: 2 mg/m³ EV (Canada) Ceiling limit value: 2 mg/m³ LMPE (Mexico) Ceiling limit value: 2 mg/m³ · Ingredients with biological limit values: 67-63-0 propan-2-ol BEI (USA) 40 mg/L Medium: urine Time: end of shift at end of workweek Parameter: Acetone (background, nonspecific) · Additional information: The lists that were valid during the creation were used as basis. · Exposure controls · Personal protective equipment: · General protective and hygienic measures: The usual precautionary measures for handling chemicals should be followed. Keep away from foodstuffs, beverages and feed. Immediately remove all soiled and contaminated clothing. Wash hands before breaks and at the end of work. Do not inhale gases / fumes / aerosols. Avoid contact with the eyes. · Breathing equipment: Not required under normal conditions of use. · Protection of hands: Gloves not required under normal conditions of use. Wear protective gloves to handle contents of damaged or leaking units. · Eye protection: Not required for normal handling. Wear protective eyewear while handling damaged or leaking product. · Body protection: Not required under normal conditions of use. Protection may be required for spills. · Limitation and supervision of exposure into the environment No further relevant information available. 9 Physical and chemical properties · Information on basic physical and chemical properties · General Information · Appearance: Form: Gel liquid. Color: Blue · Odor: Characteristic · Odor threshold: Not determined. · pH-value: Not determined. · Change in condition Melting point/Melting range: Undetermined. Boiling point/Boiling range: Undetermined. (Contd. on page 6) 40.0.2 Page 6 of 10 Safety Data Sheet acc. to HCS and GHS Printing date 01/09/2015 Reviewed on 01/09/2015 Trade name: Mineral Ice® Pain Relieving Gel (Contd. of page 5) · Flash point: Not applicable. · Flammability (solid, gaseous): Not applicable. · Auto-ignition temperature: Not determined. · Decomposition temperature: Not determined. · Auto igniting: Product is not self-igniting. · Danger of explosion: Product does not present an explosion hazard. · Explosion limits: Lower: Not determined. Upper: Not determined. · Vapor pressure at 20 °C (68 °F): 43 hPa (32 mm Hg) · Density: Not determined. · Relative density Not determined. · Vapour density Not determined. · Evaporation rate Not determined. · Solubility in / Miscibility with Water: Not miscible or difficult to mix. · Partition coefficient (n-octanol/water): Not determined. · Viscosity: Dynamic: Not determined. Kinematic: Not determined. · Other information No further relevant information available.
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