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(12) Patent Application Publication (10) Pub. No.: US 2011/0064678 A1 Knappe Et Al

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(12) Patent Application Publication (10) Pub. No.: US 2011/0064678 A1 Knappe Et Al US 2011 OO64678A1 (19) United States (12) Patent Application Publication (10) Pub. No.: US 2011/0064678 A1 Knappe et al. (43) Pub. Date: Mar. 17, 2011 (54) STYLINGAGENTS GIVING A HIGH DEGREE Publication Classification OF HOLD (51) Int. Cl. (75) Inventors: Thorsten Knappe, Schenefeld set, . CR (DE); Sabine Albrechtsen, O ( .01) Easter SR Uwe Bergemann, (52) U.S. Cl. ........................................ 424/47; 424/70.16 amburg (73) Assignee: HENKELAG & CO. KGAA, (57) ABSTRACT Dusseldorf, DE (DE) An agent for the temporary deformation of keratinic fibers comprises, in a cosmetically acceptable carrier, a) at least one (21) Appl. No.: 12/442,878 copolymer A formed from: at least one monomer A1 selected 1-1. from acrylic acid, methacrylic acid, acrylic acid alkyl esters, (22) PCT Filed: Aug. 16, 2007 and methacrylic acid alkyl esters; at least one monomer A2 (86). PCT No.: PCT/EP07/58492 selected from acrylic acid hydroxyalkyl esters and meth acrylic acid hydroxyalkyl esters; and at least one monomer S371 (c)(1) A3 selected from Succinic acid monoalkyl esters and Succinic (2), (4) Date: Mar 25, 2009 acid dialkyl esters; and at least one film-forming and setting s 9 amphoteric polymer. A method for using the agent for the (30) Foreign Application Priority Data temporary deformation of hair, and an aerosol hair spray containing the agent and at least one propellant also are pro Sep. 27, 2006 (DE) ......................... 102O06O45966.O vided. Patent Application Publication Mar. 17, 2011 Sheet 3 of 3 US 2011/006.4678 A1 H H ". HC-Ns CHS0, HC-NS C OCH, FIG. 20 FIG. 21 CH, -O-KH - CH, - - H te, C l, C FIG. 22 FIG. 23 CH CH CH H X- -( )-(Y, CX- - )-( th. C l, C FIG. 24 FIG. 25 NH US 2011/0064678 A1 Mar. 17, 2011 STYLNGAGENTS GIVINGA HIGH DEGREE 0007 Accordingly, it is desirable to provide an agent for OF HOLD the temporary deformation of keratinic fibers that is notable for a very high degree of hold, such that the flexibility, elas CROSS-REFERENCE TO RELATED ticity, and plasticity of the polymer film are retained. In addi APPLICATION tion, other desirable features and characteristics will become apparent from the Subsequent Summary and detailed descrip 0001. This application is a U.S. National Stage entry under tion and the appended claims, taken in connection with the 35 U.S.C S371 based on International Application No. PCT/ accompanying drawings and this background EP2007/058492, filed 16 Aug. 2007, which was published under PCT Article 21(2) and claims the benefit of the filing DESCRIPTION OF THE DRAWINGS date of German Patent Application No 10 2006 0459660 filed 27 Sep. 2006, the disclosures of which applications are 0008. The present invention will hereinafter be described hereby incorporated herein by reference. in conjunction with the following drawing figures, wherein like numerals denote like elements, and FIELD OF THE INVENTION 0009 FIG. 1 is an illustration of the structural formula of a linear dimethiconol that can be used in an embodiment of 0002 The present invention relates in general to cosmetic the present invention; compositions. In particular, the present invention relates to 0010 FIG. 2 is an illustration of the structural formula of agents for the temporary deformation of keratinic fibers, con a branched dimethiconol that can be used in an embodiment taining a specific combination of polymers; to the use of said of the present invention; agents for the temporary deformation of keratinic fibers; and 0011 FIG. 3 is an illustration of the structural formula of to aerosol hair sprays based on said agents. a linear dimethicone that can be used in an embodiment of the present invention; BACKGROUND OF THE INVENTION 0012 FIG. 4 is an illustration of the structural formula of 0003. “Keratin-containing fibers are understood in prin a branched dimethicone that can be used in an embodiment of ciple as all animal hairs, e.g. wool, horsehair, angora wool, the present invention; furs, feathers, and products or textiles produced therefrom. 0013 FIG. 5 is an illustration of the structural formula of By preference, however, the keratinic fibers are human hairs. a dimethicone copolyol that can be used in an embodiment of 0004 An attractive-looking hairstyle is generally the present invention; regarded these days as an indispensable element of a well 0014 FIG. 6 is an illustration of the structural formula of groomed appearance. Given the currents of fashion, more and another dimethicone copolyol that can be used in an embodi more hairstyles regarded as chic are ones that, for many types ment of the present invention; of hair, can be constructed, or maintained for a longer period 0015 FIG. 7 is an illustration of the structural formula of of time of up to several days, only with the use of setting a branched dimethicone copolyol that can be used in an ingredients. Hair treatment agents that serve for permanent or embodiment of the present invention; temporary shaping of the hair therefore play an important 0016 FIG. 8 is an illustration of the structural formula of role. Temporary shaping actions that are intended to yield another branched dimethicone copolyol that can be used in an good hold without impairing the hair's healthy appearance, embodiment of the present invention; for example its shine, can be achieved, for example, using hair 0017 FIG. 9 is an illustration of the structural formula of sprays, hair waxes, hair gels, hair foams, blow-dry waves, etc. an aminofunctional silicone that can be used in an embodi 0005 Corresponding agents for the temporary shaping ment of the present invention; usually contain synthetic polymers as a shaping component. 0018 FIG. 10 is an illustration of the structural formula of Preparations that contain a dissolved or dispersed polymer a particular aminofunctional silicone of FIG. 9 that can be can be applied onto the hair by means of propellant gases or used in an embodiment of the present invention; by way of a pump mechanism. Hair gels and hair waxes in 0019 FIG. 11 is an illustration of the structural formula of particular, however, are generally not applied directly onto another particular aminofunctional silicone of FIG.9 that can the hair but rather distributed in the hair by means of a comb be used in an embodiment of the present invention; or one's hands. 0020 FIG. 12 is an illustration of the structural formula of 0006. The most important property of an agent for the a further particular aminofunctional silicone of FIG. 9 that temporary deformation of keratinic fibers, hereinafter also can be used in an embodiment of the present invention; called a styling agent, is to impart the strongest possible hold 0021 FIG. 13 is an illustration of the structural formula of to the treated fibers in the shape that is generated. If the cationic polymer that can be used in an embodiment of the keratinic fibers involved are human hairs, terms also used are present invention; a strong “hairstyle hold' or a high “degree of hold of the 0022 FIG. 14 is an illustration of the structural formula of styling agent. The hairstyle hold is determined substantially monomers having quaternary ammonium groups that can be by the nature and quantity of the synthetic polymer used, used to form amphoteric polymers useful in an embodiment although the further constituents of the styling agent can also of the present invention; have an influence. Also often desired, in addition to a high 0023 FIG. 15 is an illustration of the structural formula of degree of hold, are flexibility, elasticity, and plasticity. Many monomeric carboxylic acids that can be used to form ampho commercially available styling agents, in particular aerosol teric polymers useful in an embodiment of the present inven hair sprays, are already notable for a high degree of hold. tion; They often reach their limits, however, when faced with user 0024 FIG. 16 is an illustration of the structural formula of demands for creating increasingly wild and extreme hair dicarboxylic acids useful in an embodiment of the present styles and reliably fixing them in place. invention; US 2011/0064678 A1 Mar. 17, 2011 0025 FIG. 17 is an illustration of the structural formula of presented in the preceding background of the invention or the an ectoin or ectoin derivative useful in an embodiment of the following detailed description of the invention. present invention; 0033 Surprisingly, an agent for the temporary deforma 0026 FIG. 18 is an illustration of the structural formula of tion of keratinic fibers that is notable for a very high degree of anotherectoinorectoinderivative useful in an embodiment of hold, such that the flexibility, elasticity, and plasticity of the the present invention; polymer film are retained, can be achieved by a combination 0027 FIG. 19 is an illustration of the structural formula of of specific polymers. fatty acid partial glycerides useful in an embodiment of the 0034. In one exemplary embodiment of the present inven present invention; and tion, an agent for the temporary deformation of keratinic 0028 FIGS. 20-28 are illustrations of the structural for fibers comprises, in a cosmetically acceptable carrier, mulas of cationic direct-absorbing dyes useful in embodi 0035) a) at least one copolymer A formed from: ments of the present invention. 0036 at least one monomer A1 comprising acrylic acid, methacrylic acid, acrylic acid alkyl esters, or BRIEF SUMMARY methacrylic acid alkyl esters; 0029. An agent for the temporary deformation of keratinic 0037 at least one monomer A2 comprising acrylic fibers, a method for using the agent, and an aerosol hairspray acid hydroxyalkyl esters or methacrylic acid comprising the agent are provided. In accordance with an hydroxyalkyl esters; and exemplary embodiment of the present invention, the agent for 0038 at least one monomer A3 comprising succinic the temporary deformation of keratinic fibers comprises, in a acid monoalkyl esters or Succinic acid dialkyl esters; cosmetically acceptable carrier, at least one copolymer A and formed from: at least one monomer A1 selected from the 0.039 b) at least one film-forming and/or setting ampho group consisting of acrylic acid, methacrylic acid, acrylic teric polymer.
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