Quarter 3 2016 Pesticide Residues Monitoring Results
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Pesticide Residues in Food 2007 – Report, 2007 (E)
FAO Pesticide residues PLANT PRODUCTION in food 2007 AND PROTECTION PAPER Joint FAO/WHO Meeting on Pesticide Residues 191 Report of the Joint Meeting of the FAO Panel of Experts on Pesticide Residues in Food and the Environment and the WHO Core Assessment Group on Pesticide Residues Geneva, Switzerland, 18–27 September 2007 WORLD HEALTH ORGANIZATION FOOD AND AGRICULTURE ORGANIZATION OF THE UNITED NATIONS Rome, 2007 The designations employed and the presentation of material in this information product do not imply the expression of any opinion whatsoever on the part of the Food and Agriculture Organization of the United Nations (FAO) concerning the legal or development status of any country, territory, city or area or of its authorities, or concerning the delimitation of its frontiers or boundaries. The mention of specific companies or products of manufacturers, whether or not these have been patented, does not imply that these have been endorsed or recommended by FAO in preference to others of a similar nature that are not mentioned. ISBN 978-92-5-105918-0 All rights reserved. Reproduction and dissemination of material in this information product for educational or other non-commercial purposes are authorized without any prior written permission from the copyright holders provided the source is fully acknowledged. Reproduction of material in this information product for resale or other commercial purposes is prohibited without written permission of the copyright holders. Applications for such permission should be addressed to: Chief Electronic -
Historical Perspectives on Apple Production: Fruit Tree Pest Management, Regulation and New Insecticidal Chemistries
Historical Perspectives on Apple Production: Fruit Tree Pest Management, Regulation and New Insecticidal Chemistries. Peter Jentsch Extension Associate Department of Entomology Cornell University's Hudson Valley Lab 3357 Rt. 9W; PO box 727 Highland, NY 12528 email: [email protected] Phone 845-691-7151 Mobile: 845-417-7465 http://www.nysaes.cornell.edu/ent/faculty/jentsch/ 2 Historical Perspectives on Fruit Production: Fruit Tree Pest Management, Regulation and New Chemistries. by Peter Jentsch I. Historical Use of Pesticides in Apple Production Overview of Apple Production and Pest Management Prior to 1940 Synthetic Pesticide Development and Use II. Influences Changing the Pest Management Profile in Apple Production Chemical Residues in Early Insect Management Historical Chemical Regulation Recent Regulation Developments Changing Pest Management Food Quality Protection Act of 1996 The Science Behind The Methodology Pesticide Revisions – Requirements For New Registrations III. Resistance of Insect Pests to Insecticides Resistance Pest Management Strategies IV. Reduced Risk Chemistries: New Modes of Action and the Insecticide Treadmill Fermentation Microbial Products Bt’s, Abamectins, Spinosads Juvenile Hormone Analogs Formamidines, Juvenile Hormone Analogs And Mimics Insect Growth Regulators Azadirachtin, Thiadiazine Neonicotinyls Major Reduced Risk Materials: Carboxamides, Carboxylic Acid Esters, Granulosis Viruses, Diphenyloxazolines, Insecticidal Soaps, Benzoyl Urea Growth Regulators, Tetronic Acids, Oxadiazenes , Particle Films, Phenoxypyrazoles, Pyridazinones, Spinosads, Tetrazines , Organotins, Quinolines. 3 I Historical Use of Pesticides in Apple Production Overview of Apple Production and Pest Management Prior to 1940 The apple has a rather ominous origin. Its inception is framed in the biblical text regarding the genesis of mankind. The backdrop appears to be the turbulent setting of what many scholars believe to be present day Iraq. -
Impact of Pesticide Use on Health in Developing Countries
Impact of pesticide use on health in developing countries Proceedings of a symposium held in Ottawa, Canada, 1 7-20 September 1990 IDRC CRDI International Development Research Centre Centre de recherches pour le devetoppement international 1 March 1993 Dear Reader/Librarian, IDRC is a public corporation created by the Canadian parliament in 1970 to help developing countries find viable solutions to their problems through research. At the 1992 Earth Summit, IDRC's mandate was broadened to emphasize sustainable development issues. As part of IDRC's strengthened commitment to global action and harüony, we are pleased to send you a complimentary copy of our most recent publication: The impact of pesticide use on health in developing countries (March 1993, 352 pages, 0-88936-560-1, $17.95). The first part of this book presents a brief survey of the global situation and the results of twelve epidemiological studies carried out by researchers from Africa, Latin America, Asia and the Middle East. These focus on poisonings resulting from organophosphates, herbicides, and pyrethroids. The second part illustrates the role of the process of development, production, spraying techniques and legislation in protecting the health of workers. A discussion of the benefits and modalities of access to pertinent information for the prevention of pesticide poisonings is provided in the third section. Finally, in the fourth section, consideration is given to the advantages and disadvantages of certain alternatives to the use of synthetic pesticides in agriculture and public health, such as botanical pesticides and integrated pest management strategies. We hope this book is a valuable addition to your collection. -
Chemical Name Federal P Code CAS Registry Number Acutely
Acutely / Extremely Hazardous Waste List Federal P CAS Registry Acutely / Extremely Chemical Name Code Number Hazardous 4,7-Methano-1H-indene, 1,4,5,6,7,8,8-heptachloro-3a,4,7,7a-tetrahydro- P059 76-44-8 Acutely Hazardous 6,9-Methano-2,4,3-benzodioxathiepin, 6,7,8,9,10,10- hexachloro-1,5,5a,6,9,9a-hexahydro-, 3-oxide P050 115-29-7 Acutely Hazardous Methanimidamide, N,N-dimethyl-N'-[2-methyl-4-[[(methylamino)carbonyl]oxy]phenyl]- P197 17702-57-7 Acutely Hazardous 1-(o-Chlorophenyl)thiourea P026 5344-82-1 Acutely Hazardous 1-(o-Chlorophenyl)thiourea 5344-82-1 Extremely Hazardous 1,1,1-Trichloro-2, -bis(p-methoxyphenyl)ethane Extremely Hazardous 1,1a,2,2,3,3a,4,5,5,5a,5b,6-Dodecachlorooctahydro-1,3,4-metheno-1H-cyclobuta (cd) pentalene, Dechlorane Extremely Hazardous 1,1a,3,3a,4,5,5,5a,5b,6-Decachloro--octahydro-1,2,4-metheno-2H-cyclobuta (cd) pentalen-2- one, chlorecone Extremely Hazardous 1,1-Dimethylhydrazine 57-14-7 Extremely Hazardous 1,2,3,4,10,10-Hexachloro-6,7-epoxy-1,4,4,4a,5,6,7,8,8a-octahydro-1,4-endo-endo-5,8- dimethanonaph-thalene Extremely Hazardous 1,2,3-Propanetriol, trinitrate P081 55-63-0 Acutely Hazardous 1,2,3-Propanetriol, trinitrate 55-63-0 Extremely Hazardous 1,2,4,5,6,7,8,8-Octachloro-4,7-methano-3a,4,7,7a-tetra- hydro- indane Extremely Hazardous 1,2-Benzenediol, 4-[1-hydroxy-2-(methylamino)ethyl]- 51-43-4 Extremely Hazardous 1,2-Benzenediol, 4-[1-hydroxy-2-(methylamino)ethyl]-, P042 51-43-4 Acutely Hazardous 1,2-Dibromo-3-chloropropane 96-12-8 Extremely Hazardous 1,2-Propylenimine P067 75-55-8 Acutely Hazardous 1,2-Propylenimine 75-55-8 Extremely Hazardous 1,3,4,5,6,7,8,8-Octachloro-1,3,3a,4,7,7a-hexahydro-4,7-methanoisobenzofuran Extremely Hazardous 1,3-Dithiolane-2-carboxaldehyde, 2,4-dimethyl-, O- [(methylamino)-carbonyl]oxime 26419-73-8 Extremely Hazardous 1,3-Dithiolane-2-carboxaldehyde, 2,4-dimethyl-, O- [(methylamino)-carbonyl]oxime. -
The List of Extremely Hazardous Substances)
APPENDIX A (THE LIST OF EXTREMELY HAZARDOUS SUBSTANCES) THRESHOLD REPORTABLE INVENTORY RELEASE QUANTITY QUANTITY CAS NUMBER CHEMICAL NAME (POUNDS) (POUNDS) 75-86-5 ACETONE CYANOHYDRIN 500 10 1752-30-3 ACETONE THIOSEMICARBAZIDE 500/500 1,000 107-02-8 ACROLEIN 500 1 79-06-1 ACRYLAMIDE 500/500 5,000 107-13-1 ACRYLONITRILE 500 100 814-68-6 ACRYLYL CHLORIDE 100 100 111-69-3 ADIPONITRILE 500 1,000 116-06-3 ALDICARB 100/500 1 309-00-2 ALDRIN 500/500 1 107-18-6 ALLYL ALCOHOL 500 100 107-11-9 ALLYLAMINE 500 500 20859-73-8 ALUMINUM PHOSPHIDE 500 100 54-62-6 AMINOPTERIN 500/500 500 78-53-5 AMITON 500 500 3734-97-2 AMITON OXALATE 100/500 100 7664-41-7 AMMONIA 500 100 300-62-9 AMPHETAMINE 500 1,000 62-53-3 ANILINE 500 5,000 88-05-1 ANILINE,2,4,6-TRIMETHYL- 500 500 7783-70-2 ANTIMONY PENTAFLUORIDE 500 500 1397-94-0 ANTIMYCIN A 500/500 1,000 86-88-4 ANTU 500/500 100 1303-28-2 ARSENIC PENTOXIDE 100/500 1 THRESHOLD REPORTABLE INVENTORY RELEASE QUANTITY QUANTITY CAS NUMBER CHEMICAL NAME (POUNDS) (POUNDS) 1327-53-3 ARSENOUS OXIDE 100/500 1 7784-34-1 ARSENOUS TRICHLORIDE 500 1 7784-42-1 ARSINE 100 100 2642-71-9 AZINPHOS-ETHYL 100/500 100 86-50-0 AZINPHOS-METHYL 10/500 1 98-87-3 BENZAL CHLORIDE 500 5,000 98-16-8 BENZENAMINE, 3-(TRIFLUOROMETHYL)- 500 500 100-14-1 BENZENE, 1-(CHLOROMETHYL)-4-NITRO- 500/500 500 98-05-5 BENZENEARSONIC ACID 10/500 10 3615-21-2 BENZIMIDAZOLE, 4,5-DICHLORO-2-(TRI- 500/500 500 FLUOROMETHYL)- 98-07-7 BENZOTRICHLORIDE 100 10 100-44-7 BENZYL CHLORIDE 500 100 140-29-4 BENZYL CYANIDE 500 500 15271-41-7 BICYCLO[2.2.1]HEPTANE-2-CARBONITRILE,5- -
Multi-Residue Analysis of 210 Pesticides in Food Samples by Triple Quadrupole UHPLC-MS/MS
Multi-Residue Analysis of 210 Pesticides in Food Samples by Triple Quadrupole UHPLC-MS/MS David R. Baker1, Chris Titman1, Alan J. Barnes1, Neil J. Loftus1, Alexander Mastoroudes2, Simon Hird3 1Shimadzu Corporation, Manchester, UK 2Kings College London, London, UK 3Food and Environment Research Agency, York, UK Abstract Pesticides and their metabolites are of great concern to society as they are harmful to human health, pollute natural resources and disturb the equilibrium of the ecosystem. Consequently, stricter food safety regulations are being enforced around the world, placing pesticide analysis laboratories under increasing pressure to expand the list of targeted pesticides, detect analytes at lower levels and with greater precision, reduce analysis turnaround times, and all the while maintaining or reducing costs. In this study a method was successfully developed for the quantitation of 210 commonly analysed pesticides in food samples using the Nexera UHPLC and LCMS-8040. Initial validation was performed to demonstrate instrument capabilities. Limits of detection (LOD) for 90 % of compounds were less than 0.001 mg kg-1 (1 ppb) and all compounds were less than 0.01 mg kg-1 (10 ppb) for both the quantifying and qualifying transitions using only a 2 µL injection. Repeatability at the 0.01 mg kg-1 reporting level was typically less than 5 %RSD for compounds and correlation coefficients were typically greater than 0.997 in a variety of studied food extracts. Consequently, the LCMS-8040 is ideally suited for routine monitoring of pesticides below the 0.01 mg kg-1 default level set by EU and Japanese legislation. Keywords: Pesticides; Multi-residue analysis; LCMS-8040; Food safety; Fruit; Vegetables 1. -
(12) United States Patent (10) Patent No.: US 6,528,079 B2 Podszun Et Al
US006528079B2 (12) United States Patent (10) Patent No.: US 6,528,079 B2 PodsZun et al. (45) Date of Patent: *Mar. 4, 2003 (54) SHAPED BODIES WHICH RELEASE 4,845,106 A 7/1989 Shiokawa et al. .......... 514/342 AGROCHEMICALACTIVE SUBSTANCES 4,849,432 A 7/1989 Shiokawa et al. .......... 514/341 4.882,344 A 11/1989 Shiokawa et al. .......... 514/342 (75) Inventors: Wolfgang Podszun, Köln (DE); Uwe 4.914,113 A 4/1990 Shiokawa et al. .......... 514/333 Priesnitz, Solingen (DE); Jirgen 4,918,086 A 4/1990 Gsell .......................... 514/351 4,918,088 A 4/1990 Gsell .......................... 514/357 Hölters, Leverkusen (DE); Bodo 4.948.798.2- Y - A 8/1990 Gsell .......................... 514/275 Rehbold, Köln (DE); Rafel Israels, 4,963,572 A 10/1990 Gsell .......................... 514/357 Monheim (DE) 4,963,574. A 10/1990 Bachmann et al. ......... 514/357 4,988,712 A 1/1991 Shiokawa et al. .......... 514/340 (73) Assignee: Bayer Aktiengesellschaft, Leverkusen 5,001,138 A 3/1991 Shiokawa et al. .......... 514/342 (DE) 5,034.404 A 7/1991. Uneme et al. .............. 514/365 5,034,524 A 7/1991 Shiokawa et al. .......... 544/124 (*) Notice: This patent issued on a continued pros- 5,039,686 A 8/1991 Davies et al. ............... 514/341 ecution application filed under 37 CFR 5,049,571. A 9/1991 Gsell .......................... 514/345 1.53(d), and is subject to the twenty year SE A :1: S. - - - - - - - -tal.5 E.s pass" provisions of 35 U.S.C. 5,166,1642Y- - - 2 A 11/1992 NanjoOKaWa et al. -
Stockholm Convention on Persistent Organic Pollutants Compilation Of
UNITED NATIONS SC UNEP /POPS/POPRC.7/INF/11/Rev.2 Distr.: General 26 September 2011 Stockholm Convention English only on Persistent Organic Pollutants Persistent Organic Pollutants Review Committee Seventh meeting Geneva, 10–14 October 2011 Item 7 (a) of the provisional agenda* Technical work in relation to chemicals listed in the annexes to the Convention with exemptions: assessment of alternatives to endosulfan Compilation of information on alternatives to endosulfan Note by the Secretariat 1. As referred to in document UNEP/POPS/POPRC.7/9, the Secretariat has gathered information from parties and observers on chemical and non-chemical alternatives to endosulfan. The submissions received by the deadline of 31 July 2011 have been summarized in annex I and compiled in annex II to the present note. Additional information submitted by the European Union and India is set out in annexes III and IV, respectively. The annexes have not been formally edited. 2. All the submissions are available in their original form on the Stockholm Convention website at http://chm.pops.int/tabid/2269/Default.aspx. * UNEP/POPS/POPRC.7/1. K1173127 260911 UNEP/POPS/POPRC.7/INF/11/Rev.2 Contents Annex I (A) Summary of information on chemical alternatives to 3–12 endosulfan submitted by parties and observers Annex I (B) Summary of information on non-chemical alternatives to 13–21 endosulfan submitted by parties and observers Annex II Compilation of information related to alternatives to 22–115 endosulfan Annex III Submission by the European Union “Support related to the 116–124 international work on Persistent Organic Pollutants” Annex IV Submission by India 125–126 2 UNEP/POPS/POPRC.7/INF/11/Rev.2 Annex I A. -
Determination of Butocarboxim Residue in Agricultural Products by HPLC with Post-Column Derivatization System
Journal of Food and Drug Analysis 1999. 7(4) : 269-277 Determination of Butocarboxim Residue in Agricultural Products by HPLC with Post-Column Derivatization System SU-HSIANG TSENG*, PI-CHIOU CHANG AND SHIN-SHOU CHOU A method using high performance liquid chromatography (HPLC) for the determination of butocarboxim in agricultural products was developed. Butocarboxim was extracted from samples with acetone and the extract solution was concentrated. The residue was dissolved in sodium chloride solution and partitioned with n-hexane. The aqueous phase was collected fol- lowed by extracted with dichloromethane, which was then evaporated to a volume of 2 mL prior to passing through an aminopropyl cartridge for sample clean-up. Determination of butocarboxim residue in crops was carried out by HPLC equipped with a post-column deriva- tization system and a fluorescence detector. HPLC separation was performed on a Lichrospher 60 RP-Select B column eluted with a mobile phase of acetonitrile-water (25:75, v/v). Butocarboxim was hydrolyzed at 90°C under alkaline conditions and subsequently react- ed with o-phthaldialdehyde (OPA) / 2-mercaptoethanol reagent via a post-column reactor to generate a fluorophore, which was then detected with a fluorescence detector at Ex 340 nm and Em 455 nm. Average recoveries from radishes and bamboo sprouts, which were spiked with 0.1~0.3 and 0.2 ppm butocarboxim, respectively, were in the range of 81.9~82.6%. The detection limit was 0.05 ppm. No butocarboxim residue was detected in 10 commercial prod- ucts including radishes, carrots, and bamboo sprouts. Key words: agricultural products, butocarboxim, aminopropyl cartridge, high performance liquid chromatography (HPLC), post-column derivatization system, fluorescence detection. -
Recommended Classification of Pesticides by Hazard and Guidelines to Classification 2019 Theinternational Programme on Chemical Safety (IPCS) Was Established in 1980
The WHO Recommended Classi cation of Pesticides by Hazard and Guidelines to Classi cation 2019 cation Hazard of Pesticides by and Guidelines to Classi The WHO Recommended Classi The WHO Recommended Classi cation of Pesticides by Hazard and Guidelines to Classi cation 2019 The WHO Recommended Classification of Pesticides by Hazard and Guidelines to Classification 2019 TheInternational Programme on Chemical Safety (IPCS) was established in 1980. The overall objectives of the IPCS are to establish the scientific basis for assessment of the risk to human health and the environment from exposure to chemicals, through international peer review processes, as a prerequisite for the promotion of chemical safety, and to provide technical assistance in strengthening national capacities for the sound management of chemicals. This publication was developed in the IOMC context. The contents do not necessarily reflect the views or stated policies of individual IOMC Participating Organizations. The Inter-Organization Programme for the Sound Management of Chemicals (IOMC) was established in 1995 following recommendations made by the 1992 UN Conference on Environment and Development to strengthen cooperation and increase international coordination in the field of chemical safety. The Participating Organizations are: FAO, ILO, UNDP, UNEP, UNIDO, UNITAR, WHO, World Bank and OECD. The purpose of the IOMC is to promote coordination of the policies and activities pursued by the Participating Organizations, jointly or separately, to achieve the sound management of chemicals in relation to human health and the environment. WHO recommended classification of pesticides by hazard and guidelines to classification, 2019 edition ISBN 978-92-4-000566-2 (electronic version) ISBN 978-92-4-000567-9 (print version) ISSN 1684-1042 © World Health Organization 2020 Some rights reserved. -
IMDG Code (Amendment 37-14) Index Korean Register of Shipping
IMDG Code (Amendment 37-14) Index Substance, material or article MP Class UN No. ACETAL - 3 1088 ACETALDEHYDE - 3 1089 ACETALDEHYDE AMMONIA - 9 1841 Acetaldehyde diethyl acetal, see - 3 1088 ACETALDEHYDE OXIME - 3 2332 Acetaldol, see - 6.1 2839 beta-Acetaldoxime, see - 3 2332 ACETIC ACID, GLACIAL - 8 2789 ACETIC ACID SOLUTION more than 10% and less than 50% acid, - 8 2790 by mass ACETIC ACID SOLUTION not less than 50% but no more than 80% - 8 2790 acid, by mass ACETIC ACID SOLUTION more than 80% acid, by mass - 8 2789 Acetic aldehyde, see - 3 1089 ACETIC ANHYDRIDE - 8 1715 Acetic oxide, see - 8 1715 Acetoin, see - 3 2621 ACETONE - 3 1090 ACETONE CYANOHYDRIN, STABILIZED P 6.1 1541 Acetone hexafluoride, see - 2.3 2420 ACETONE OILS - 3 1091 Acetone-pyrogallol copolymer 2-diazo-1-naphthol-5-sulphonate - 4.1 3228 ACETONITRILE - 3 1648 3-Acetoxypropene, see - 3 2333 Acetylacetone, see - 3 2310 Acetyl acetone peroxide (concentration ≤32%, as a paste), see - 5.2 3106 Acetyl acetone peroxide (concentration ≤42%, with diluent Type A, and - 5.2 3105 water, available oxygen ≤4.7%), see ACETYL BROMIDE - 8 1716 ACETYL CHLORIDE - 3 1717 Acetyl cyclohexanesulphonyl peroxide - 5.2 3115 (concentration ≤32%, with diluent Type B), see Acetyl cyclohexanesulphonyl peroxide - 5.2 3112 (concentration ≤82%, with water), see Acetylene dichloride, see - 3 1150 ACETYLENE, DISSOLVED - 2.1 1001 Acetylene, ethylene and propylene mixtures, refrigerated liquid, see - 2.1 3138 ACETYLENE, SOLVENT FREE - 2.1 3374 Acetylene tetrabromide, see P 6.1 2504 Acetylene tetrachloride, see P 6.1 1702 ACETYL IODIDE - 8 1898 Acetyl ketene, stabilized, see - 6.1 2521 ACETYL METHYL CARBINOL - 3 2621 Acid butyl phosphate, see - 8 1718 Acid mixture, hydrofluoric and sulphuric, see - 8 1786 Acid mixture, nitrating acid, see - 8 1796 Korean Register of Shipping IMDG Code (Amendment 37-14) Index Substance, material or article MP Class UN No. -
LC-MS/MS and GC-MS/MS Multi Residue Pesticide Analysis in Fruit and Vegetable Extracts on a Single Tandem Quadrupole Mass Spectrometer
36 May / June 2017 LC-MS/MS and GC-MS/MS Multi Residue Pesticide Analysis in Fruit and Vegetable Extracts on a Single Tandem Quadrupole Mass Spectrometer by Kari Organtini1, Gareth Cleland1, Eimear McCall2, and Simon Hird2 1Waters Corporation, Milford, MA, USA 2Waters Corporation, Wilmslow, UK Hundreds of pesticides are commercially available and are approved for use on various fruit and vegetable plants to prevent pest infestation and improve shelf-life of fresh produce. Maximum Residue Levels (MRLs) are set at the highest level of pesticide that the relevant regulatory body would expect to find in that crop when it has been treated in accordance with good agricultural practice. In the EU, if a pesticide is not explicitly mentioned in the MRL legislation, a default MRL is used for enforcement. This default value is set to be equal to the limit of quantification (LOQ) achievable with the analytical methods used for analysis. National authorities control and enforce MRLs by testing samples for pesticide residue levels using analytical surveillance programs. These programs check for compliance with MRLs, assess dietary exposure, and check for use of unauthorised pesticides. The food industry also carries out its own due diligence analyses. Mass spectrometry (MS) coupled with fragile or easily fragmented compounds. in this study (listed in appendix tables) were both gas chromatography (GC) and liquid APGC ionisation can occur using two chosen to cover a wide range of different chromatography (LC) is needed to provide mechanisms; proton transfer (wet source) pesticide classes and chemistries. The multi comprehensive analysis of a wide range of or charge transfer (dry source).