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Pesticide Residues in Food 2007 – Report, 2007 (E)
FAO Pesticide residues PLANT PRODUCTION in food 2007 AND PROTECTION PAPER Joint FAO/WHO Meeting on Pesticide Residues 191 Report of the Joint Meeting of the FAO Panel of Experts on Pesticide Residues in Food and the Environment and the WHO Core Assessment Group on Pesticide Residues Geneva, Switzerland, 18–27 September 2007 WORLD HEALTH ORGANIZATION FOOD AND AGRICULTURE ORGANIZATION OF THE UNITED NATIONS Rome, 2007 The designations employed and the presentation of material in this information product do not imply the expression of any opinion whatsoever on the part of the Food and Agriculture Organization of the United Nations (FAO) concerning the legal or development status of any country, territory, city or area or of its authorities, or concerning the delimitation of its frontiers or boundaries. The mention of specific companies or products of manufacturers, whether or not these have been patented, does not imply that these have been endorsed or recommended by FAO in preference to others of a similar nature that are not mentioned. ISBN 978-92-5-105918-0 All rights reserved. Reproduction and dissemination of material in this information product for educational or other non-commercial purposes are authorized without any prior written permission from the copyright holders provided the source is fully acknowledged. Reproduction of material in this information product for resale or other commercial purposes is prohibited without written permission of the copyright holders. Applications for such permission should be addressed to: Chief Electronic -
COMBINED LIST of Particularly Hazardous Substances
COMBINED LIST of Particularly Hazardous Substances revised 2/4/2021 IARC list 1 are Carcinogenic to humans list compiled by Hector Acuna, UCSB IARC list Group 2A Probably carcinogenic to humans IARC list Group 2B Possibly carcinogenic to humans If any of the chemicals listed below are used in your research then complete a Standard Operating Procedure (SOP) for the product as described in the Chemical Hygiene Plan. Prop 65 known to cause cancer or reproductive toxicity Material(s) not on the list does not preclude one from completing an SOP. Other extremely toxic chemicals KNOWN Carcinogens from National Toxicology Program (NTP) or other high hazards will require the development of an SOP. Red= added in 2020 or status change Reasonably Anticipated NTP EPA Haz list COMBINED LIST of Particularly Hazardous Substances CAS Source from where the material is listed. 6,9-Methano-2,4,3-benzodioxathiepin, 6,7,8,9,10,10- hexachloro-1,5,5a,6,9,9a-hexahydro-, 3-oxide Acutely Toxic Methanimidamide, N,N-dimethyl-N'-[2-methyl-4-[[(methylamino)carbonyl]oxy]phenyl]- Acutely Toxic 1-(2-Chloroethyl)-3-(4-methylcyclohexyl)-1-nitrosourea (Methyl-CCNU) Prop 65 KNOWN Carcinogens NTP 1-(2-Chloroethyl)-3-cyclohexyl-1-nitrosourea (CCNU) IARC list Group 2A Reasonably Anticipated NTP 1-(2-Chloroethyl)-3-cyclohexyl-1-nitrosourea (CCNU) (Lomustine) Prop 65 1-(o-Chlorophenyl)thiourea Acutely Toxic 1,1,1,2-Tetrachloroethane IARC list Group 2B 1,1,2,2-Tetrachloroethane Prop 65 IARC list Group 2B 1,1-Dichloro-2,2-bis(p -chloropheny)ethylene (DDE) Prop 65 1,1-Dichloroethane -
Historical Perspectives on Apple Production: Fruit Tree Pest Management, Regulation and New Insecticidal Chemistries
Historical Perspectives on Apple Production: Fruit Tree Pest Management, Regulation and New Insecticidal Chemistries. Peter Jentsch Extension Associate Department of Entomology Cornell University's Hudson Valley Lab 3357 Rt. 9W; PO box 727 Highland, NY 12528 email: [email protected] Phone 845-691-7151 Mobile: 845-417-7465 http://www.nysaes.cornell.edu/ent/faculty/jentsch/ 2 Historical Perspectives on Fruit Production: Fruit Tree Pest Management, Regulation and New Chemistries. by Peter Jentsch I. Historical Use of Pesticides in Apple Production Overview of Apple Production and Pest Management Prior to 1940 Synthetic Pesticide Development and Use II. Influences Changing the Pest Management Profile in Apple Production Chemical Residues in Early Insect Management Historical Chemical Regulation Recent Regulation Developments Changing Pest Management Food Quality Protection Act of 1996 The Science Behind The Methodology Pesticide Revisions – Requirements For New Registrations III. Resistance of Insect Pests to Insecticides Resistance Pest Management Strategies IV. Reduced Risk Chemistries: New Modes of Action and the Insecticide Treadmill Fermentation Microbial Products Bt’s, Abamectins, Spinosads Juvenile Hormone Analogs Formamidines, Juvenile Hormone Analogs And Mimics Insect Growth Regulators Azadirachtin, Thiadiazine Neonicotinyls Major Reduced Risk Materials: Carboxamides, Carboxylic Acid Esters, Granulosis Viruses, Diphenyloxazolines, Insecticidal Soaps, Benzoyl Urea Growth Regulators, Tetronic Acids, Oxadiazenes , Particle Films, Phenoxypyrazoles, Pyridazinones, Spinosads, Tetrazines , Organotins, Quinolines. 3 I Historical Use of Pesticides in Apple Production Overview of Apple Production and Pest Management Prior to 1940 The apple has a rather ominous origin. Its inception is framed in the biblical text regarding the genesis of mankind. The backdrop appears to be the turbulent setting of what many scholars believe to be present day Iraq. -
Toxic Influence of Diazinon As an Organophosphate Pesticide on Parameters of Dry Matter Degradability According to in Situ Technique M
International Journal of Basic & Applied Sciences IJBAS-IJENS Vol:12 No:06 229 Toxic Influence of Diazinon as an Organophosphate Pesticide on Parameters of Dry Matter Degradability According to in Situ Technique M. Kazemi*, A. M. Tahmasbi, R. Valizadeh, A. A. Naserian Department of Animal Science, Excellence Center for Animal Science, Faculty of Agriculture, Ferdowsi University of Mashhad, P. O. Box 91775-1163, Mashhad, Islamic Republic of Iran. *Corresponding author email: [email protected] Abstract-- Many feed and forages are exposed to low, medium metabolizing phosphate insecticides in vitro. Parathion was or high levels of organophosphorous (OP) pesticides. It is unclear reduced to aminoparathion by bovine rumen fluid. Kutches et whether these exposures (for example diazinon as an OP al. [15] reported that toxaphene was the most inhibitory of the pesticide) impact dry matter degradability parameters. So, pesticides tested and resulted in greater decreases of the in different levels (0, 0.7, 2.8 and 5.6 mg) of diazinon as an OP vitro dry matter disappearance, volatile fatty acids and rumen pesticide with different levels of calcium bentonite (CB) (0 and 100 mg) as a toxin binder were tested for their toxicological protozoa. Inhibitory effects of OP pesticides such as effects on in vitro dry matter disappearance. Also we investigated phosphomidon, chlorpyrifos and phosalone on tetrahymena whether CB can inactivate the probably deleterious effects of Spp. Were reported by Hoskin et al. [10]. Dauterman et al. [7] contaminated forage with diazinon in the situ procedure or not. treated rats and cattle with radioactive dimethoate and The study indicated that effect of diazinon with adding the analyzed blood, tissue, milk, and excreta. -
Validation Report 20
EURL for Cereals and Feeding stuff National Food Institute Technical University of Denmark Validation Report 20 Determination of pesticide residues in rice baby food by GC-MS/MS and LC-MS/MS (QuEChERS method) Parvaneh Hajeb Susan Strange Herrmann Mette Erecius Poulsen December 2015 Page 2 of 18 CONTENT: 1. Introduction ...................................................................................................................................... 3 2. Principle of analysis......................................................................................................................... 3 3. Validation design ............................................................................................................................. 4 4. Chromatograms and calibration curves .......................................................................................... 5 5. Validation parameters...................................................................................................................... 9 6. Criteria for the acceptance of validation results ........................................................................... 10 7. Results and discussion ................................................................................................................... 10 8. Conclusions .................................................................................................................................... 12 9. References ..................................................................................................................................... -
Environmental Properties of Chemicals Volume 2
1 t ENVIRONMENTAL 1 PROTECTION Esa Nikunen . Riitta Leinonen Birgit Kemiläinen • Arto Kultamaa Environmental properties of chemicals Volume 2 1 O O O O O O O O OO O OOOOOO Ol OIOOO FINNISH ENVIRONMENT INSTITUTE • EDITA Esa Nikunen e Riitta Leinonen Birgit Kemiläinen • Arto Kultamaa Environmental properties of chemicals Volume 2 HELSINKI 1000 OlO 00000001 00000000000000000 Th/s is a second revfsed version of Environmental Properties of Chemica/s, published by VAPK-Pub/ishing and Ministry of Environment, Environmental Protection Department as Research Report 91, 1990. The pubiication is also available as a CD ROM version: EnviChem 2.0, a PC database runniny under Windows operating systems. ISBN 951-7-2967-2 (publisher) ISBN 952-7 1-0670-0 (co-publisher) ISSN 1238-8602 Layout: Pikseri Julkaisupalvelut Cover illustration: Jussi Hirvi Edita Ltd. Helsinki 2000 Environmental properties of chemicals Volume 2 _____ _____________________________________________________ Contents . VOLUME ONE 1 Contents of the report 2 Environmental properties of chemicals 3 Abbreviations and explanations 7 3.1 Ways of exposure 7 3.2 Exposed species 7 3.3 Fffects________________________________ 7 3.4 Length of exposure 7 3.5 Odour thresholds 8 3.6 Toxicity endpoints 9 3.7 Other abbreviations 9 4 Listofexposedspecies 10 4.1 Mammais 10 4.2 Plants 13 4.3 Birds 14 4.4 Insects 17 4.5 Fishes 1$ 4.6 Mollusca 22 4.7 Crustaceans 23 4.8 Algae 24 4.9 Others 25 5 References 27 Index 1 List of chemicals in alphabetical order - 169 Index II List of chemicals in CAS-number order -
Guide No. 1 – October 2020 2/12 the CONCEPT and IMPLEMENTATION of CPA GUIDANCE RESIDUE LEVELS
Cooperation Centre for Scientific Research Relative to Tobacco CORESTA GUIDE N° 1 The Concept and Implementation of CPA Guidance Residue Levels October 2020 Agro-Chemical Advisory Committee CORESTA TECHNICAL GUIDE N° 1 Title: The Concept and Implementation of CPA Guidance Residue Levels Status: Valid Note: This document will be periodically reviewed by CORESTA Document history: Date of review Information July 2003 Version 1 GRL for Pyrethrins () and Terbufos corrected. December 2003 CPA terminology corrected. June 2008 Version 2 – GRLs revised and residue definitions added Provisional GRL of 2.00 ppm for Cyfluthrin to replace previous June 2010 GRL of 0.50 ppm July 2013 Version 3 – GRLs revised October 2013 Note for Maleic Hydrazide revised Version 4 – GRLs revised + clarification that scope of GRLs July 2016 applies predominantly to the production of traditional cigarette tobaccos and GAP associated with their cultivation. June 2018 Fluopyram GRL of 5 ppm added to GRL list Version 5 – Nine new CPAs with GRL added to list. November 2019 Revision of GRLs for Chlorantraniliprole and Indoxacarb. Updated web links. October 2020 Version 6 – Flupyradifurone GRL of 21 ppm added to GRL list. CORESTA Guide No. 1 – October 2020 2/12 THE CONCEPT AND IMPLEMENTATION OF CPA GUIDANCE RESIDUE LEVELS Executive Summary • Guidance Residue Levels (GRLs) are in the remit of the Agro-Chemical Advisory Committee (ACAC) of CORESTA. Their development is a joint activity of all ACAC members, who represent the leaf production, processing and manufacturing sectors of the Tobacco Industry. The concept of GRLs and their implementation are described in this guide. • GRLs provide guidance to tobacco growers and assist with interpretation and evaluation of results from analyses of residues of Crop Protection Agents (CPAs*). -
2002 NRP Section 6, Tables 6.1 Through
Table 6.1 Scoring Table for Pesticides 2002 FSIS NRP, Domestic Monitoring Plan } +1 0.05] COMPOUND/COMPOUND CLASS * ) (EPA) (EPA) (EPA) (EPA) (EPA) (FSIS) (FSIS) PSI (P) TOX.(T) L-1 HIST. VIOL. BIOCON. (B) {[( (2*R+P+B)/4]*T} REG. CON. (R) * ENDO. DISRUP. LACK INFO. (L) LACK INFO. {[ Benzimidazole Pesticides in FSIS Benzimidazole MRM (5- 131434312.1 hydroxythiabendazole, benomyl (as carbendazim), thiabendazole) Carbamates in FSIS Carbamate MRM (aldicarb, aldicarb sulfoxide, NA44234416.1 aldicarb sulfone, carbaryl, carbofuran, carbofuran 3-hydroxy) Carbamates NOT in FSIS Carbamate MRM (carbaryl 5,6-dihydroxy, chlorpropham, propham, thiobencarb, 4-chlorobenzylmethylsulfone,4- NT 4 1 3 NV 4 4 13.8 chlorobenzylmethylsulfone sulfoxide) CHC's and COP's in FSIS CHC/COP MRM (HCB, alpha-BHC, lindane, heptachlor, dieldrin, aldrin, endrin, ronnel, linuron, oxychlordane, chlorpyrifos, nonachlor, heptachlor epoxide A, heptachlor epoxide B, endosulfan I, endosulfan I sulfate, endosulfan II, trans- chlordane, cis-chlordane, chlorfenvinphos, p,p'-DDE, p, p'-TDE, o,p'- 3444NV4116.0 DDT, p,p'-DDT, carbophenothion, captan, tetrachlorvinphos [stirofos], kepone, mirex, methoxychlor, phosalone, coumaphos-O, coumaphos-S, toxaphene, famphur, PCB 1242, PCB 1248, PCB 1254, PCB 1260, dicofol*, PBBs*, polybrominated diphenyl ethers*, deltamethrin*) (*identification only) COP's and OP's NOT in FSIS CHC/COP MRM (azinphos-methyl, azinphos-methyl oxon, chlorpyrifos, coumaphos, coumaphos oxon, diazinon, diazinon oxon, diazinon met G-27550, dichlorvos, dimethoate, dimethoate -
Bayesian Nonparametric Model for Clustering Individual Co-Exposure to Pesticides Found in the French Diet
Bayesian nonparametric model for clustering individual co-exposure to pesticides found in the French diet. Amélie Crépet, Jessica Tressou To cite this version: Amélie Crépet, Jessica Tressou. Bayesian nonparametric model for clustering individual co-exposure to pesticides found in the French diet.. 2009. hal-00438796v2 HAL Id: hal-00438796 https://hal.archives-ouvertes.fr/hal-00438796v2 Preprint submitted on 12 Jan 2011 (v2), last revised 4 Feb 2011 (v3) HAL is a multi-disciplinary open access L’archive ouverte pluridisciplinaire HAL, est archive for the deposit and dissemination of sci- destinée au dépôt et à la diffusion de documents entific research documents, whether they are pub- scientifiques de niveau recherche, publiés ou non, lished or not. The documents may come from émanant des établissements d’enseignement et de teaching and research institutions in France or recherche français ou étrangers, des laboratoires abroad, or from public or private research centers. publics ou privés. Bayesian nonparametric model for clustering individual co-exposure to pesticides found in the French diet. Am´elieCr´epet a & Jessica Tressoub January 12, 2011 aANSES, French Agency for Food, Environmental and Occupational Health Safety, 27-31 Av. G´en´eralLeclerc, 94701 Maisons-Alfort, France bINRA-Met@risk, Food Risk Analysis Methodologies, National Institute for Agronomic Re- search, 16 rue Claude Bernard, 75231 Paris, France Keywords Dirichlet process; Bayesian nonparametric modeling; multivariate Normal mixtures; clustering; multivariate exposure; food risk analysis. Abstract This work introduces a specific application of Bayesian nonparametric statistics to the food risk analysis framework. The goal was to determine the cocktails of pesticide residues to which the French population is simultaneously exposed through its current diet in order to study their possible combined effects on health through toxicological experiments. -
Dimethoate in Drinking-Water
WHO/SDE/WSH/03.04/90 English only Dimethoate in Drinking-water Background document for development of WHO Guidelines for Drinking-water Quality © World Health Organization 2004 Requests for permission to reproduce or translate WHO publications - whether for sale of for non- commercial distribution - should be addressed to Publications (Fax: +41 22 791 4806; e-mail: [email protected]. The designations employed and the presentation of the material in this publication do not imply the expression of any opinion whatsoever on the part of the World Health Organization concerning the legal status of any country, territory, city or area or of its authorities, or concerning the delimitation of its frontiers or boundaries. The mention of specific companies or of certain manufacturers' products does not imply that they are endorsed or recommended by the World Health Organization in preference to others of a similar nature that are not mentioned. Errors and omissions excepted, the names of proprietary products are distinguished by initial capital letters. The World Health Organization does not warrant that the information contained in this publication is complete and correct and shall not be liable for any damage incurred as a results of its use. Preface One of the primary goals of WHO and its member states is that “all people, whatever their stage of development and their social and economic conditions, have the right to have access to an adequate supply of safe drinking water.” A major WHO function to achieve such goals is the responsibility “to propose ... regulations, and to make recommendations with respect to international health matters ....” The first WHO document dealing specifically with public drinking-water quality was published in 1958 as International Standards for Drinking-water. -
Ingleby Prohibited Pesticides May 2018
1[5] INGLEBY PROHIBITED PESTICIDES MAY 2018 Active ingredient Type Acaricides Cyhexatin Acaricide Parathion-ethyl Acaricide/Insecticide Tetradifon Acaricide Tebufenpyrad Acaricide Fumigants 1,2-Dibromoethane Fumigant 1,2-dichloroethane Fumigant Fungicides 2-Aminobutane (aka sec-butylamine) Fungicide Allyl alcohol Fungicide Benomyl Fungicide Binapacryl Fungicide Bitertanol Fungicide Blasticidin-S Fungicide Cadmium Fungicide Captafol Fungicide Chloranil Fungicide Chloromethoxypropyl-mercuric-acetate (CPMA) Fungicide Chlozolinate Fungicide Di(phenylmercury)dodecenylsuccinate (PMDS) Fungicide Diammonium ethylenebis Fungicide DNOC Fungicide / Herbicide /Insecticide Edifenphos Fungicide Fenarimol Fungicide Fentin acetate Fungicide Flusilazole Fungicide Hexachlorobenzene (HCB) Fungicide Hexaconazole Fungicide Iminoctadine Fungicide Leptophos Fungicide Maneb Fungicide Mercuric oxide Fungicide Mercurous chloride (calomel) Fungicide Mercury compounds Fungicide Nickel bis Fungicide Nuarimol Fungicide Oxadixyl Fungicide Penconazole Fungicide Ingleby Farms & Forests May 2018 Prohibited Active Ingredients 2[5] INGLEBY PROHIBITED PESTICIDES MAY 2018 Active ingredient Type Fungicides (continued) Phenylmercury acetate Fungicide/Herbicide Phenylmercuric oleate [PMO] Fungicide Prochloraz Fungicide Procymidone Fungicide Propineb Fungicide Pyrazophos Fungicide Pyrifenox Fungicide Tecnazene Fungicide Tricyclazole Fungicide Tridemorph Fungicide Vinclozolin Fungicide Zineb Fungicide Herbicides 2,4,5-T Herbicide Acifluorfen Herbicide Alachlor Herbicide Arsenic -
Liquid and Gas Chromatographic Multi-Residue Pesticide Determination in Animal Tissues
Pestic. Sci. 1997, 49,56È64 Liquid and Gas Chromatographic Multi-residue Pesticide Determination in Animal Tissues Aurora Navas Dj az,* Angeles Garcj a Pareja & Francisco Garcj aSanchez Departamento de Qu•mica Anal•tica, Facultad de Ciencias, Universidad de Malaga, 29071-Malaga, Spain (Received 13 June 1995; revised version received 17 April 1996; accepted 16 August 1996) Abstract: A liquid chromatography multi-residue method with photometric detection has been developed. The method is applicable to the quantitative deter- mination of organochlorine (tetradifon, dicofol, chlorfenson, chlorobenzilate), organophosphorus (fenitrothion, azinphos-ethyl) and carbamate (pirimicarb) pesticides in animal tissues. The extracted residues are cleaned up by gel- permeation chromatography. A further fractionation on silica Sep-Pack car- tridges is included in the procedure. A gas chromatographic method with electron-capture detection for the analysis of the same pesticides was carried out and the results in the two cases compared. Lower detection and quantitation limits and similar recoveries of pesticides from spiked pig liver and brain samples were obtained by the LC method. Key words: liquid chromatography, gas chromatography, multi-residue pesti- cides, animal tissues 1 INTRODUCTION by various element-sensitive detectors, leading to reli- ance on mass spectrometry because of its ability to help Pest control in modern agriculture includes treatment to deÐne the structure. This has especially been true in of crops pre- and post-harvest with a variety of chemi- the case of the combination of gas chromatography cals, such as herbicides and insecticides in the pre- with mass spectrometry (GC/MS). One of the obvious harvest stage and with fungicides and rodenticides in Ðelds of application for this technique was the analysis the storage stage of the total harvest process.