One-Step Hydrothermal Synthesis of Thioglycolic Acid Capped Cds
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Sensitive Determination of PAH-DNA Adducts
View metadata, citation and similar papers at core.ac.uk brought to you by CORE provided by Elsevier - Publisher Connector Matrix Design for Matrix-Assisted Laser Desorption Ionization: Sensitive Determination of PAH-DNA Adducts M. George, J. M. Y. Wellemans, R. L. Cerny, and M. L. Gross* Midwest Center for Mass Spectrometry, Department of Chemistry, University of Nebraska-Lincoln, Lincoln, Nebraska USA K. Li and E. L. Cavalieri Eppley institute for Research in Cancer and Allied Diseases, University of Nebraska Medical Center, 600 South 42nd Street, Omaha, Nebraska USA Two matrices, 4-phenyl-cw-cyanocinnamic acid (ICC) and 4-benzyloxy-cu-cyanocinnamic acid (BCC), were identified for the determination of polycyclic aromatic hydrocarbon @‘AH) adducts of DNA bases by matrix-assisted laser desorption ionization. These matrices were designed based on the concept that the matrix and the analyte should have structural similarities. PCC is a good matrix for the desorption of not only PA&modified DNA bases, but also PAHs themselves and their rnetabolites. Detections can be made at the femtomolar level. (1 Am Sot Mass Spectrum 1994, 5, 1021-1025) he success of matrix-assisted laser desorption quire sensitive detection methods at the low picomole ionization (MALDI) for the sensitive detection of and mid-femtomole level, respectively [6]. T an analyte depends on the nature of the matrix. One method for detection that also gives structural Rational design of a matrix requires understanding of information is fast-atom bombardment (FAB) coupled the mechanism of MALDI. The mechanism is not fully with tandem mass spectrometry [6-81. Unfortunately, understood. Nevertheless, empirical criteria for matrix the combination lacks sensitivity because there is in selection have been suggested 111. -
Cadmium- Toxfaqs™
Cadmium- ToxFAQs™ CAS # 7440-43-9 This fact sheet answers the most frequently asked health questions (FAQs) about cadmium. For more information, call the CDC Information Center at 1-800-232-4636. This fact sheet is one in a series of summaries about hazardous substances and their health effects. It is important you understand this information because this substance may harm you. The effects of exposure to any hazardous substance depend on the dose, the duration, how you are exposed, personal traits and habits, and whether other chemicals are present. HIGHLIGHTS: Exposure to cadmium happens mostly in the workplace where cadmium products are made. The general population is exposed from breathing cigarette smoke or eating cadmium contaminated foods. Cadmium damages the kidneys, lungs, and bones. Cadmium has been found in at least 1,014 of the 1,669 National Priorities List (NPL) sites identified by the Environmental Protection Agency (EPA). What is cadmium? How might I be exposed to cadmium? Cadmium is a natural element in the earth’s crust. It is • Eating foods containing cadmium; low levels are usually found as a mineral combined with other elements found in all foods (highest levels are found in leafy such as oxygen (cadmium oxide), chlorine (cadmium vegetables, grains, legumes, and kidney meat). chloride), or sulfur (cadmium sulfate, cadmium sulfide). • Smoking cigarettes or breathing cigarette smoke. All soils and rocks, including coal and mineral fertilizers, • Breathing contaminated workplace air. contain some cadmium. Most cadmium used in the United States is extracted during the production of other metals • Drinking contaminated water. like zinc, lead, and copper. -
Draft Permit
Air Individual Permit Major Amendment 14900013-104 Permittee: DENCO II LLC Facility name: DENCO II LLC 227 County Road 22 Morris, MN 56267-4691 Stevens County Operating permit issuance date: May 1, 2019 Expiration date: May 1, 2024 * All Title I Conditions do not expire Major Amendment: [Action Issue Date] Permit characteristics: State; Limits to avoid Part 70/ Limits to avoid NSR; Limits to avoid NSR The emission units, control equipment and emission stacks at the stationary source authorized in this permit amendment are as described in the submittals listed in the Permit Applications Table. This permit amendment supersedes Air Emission Permit No. 14900013-103 and authorizes the Permittee to operate the stationary source at the address listed above unless otherwise noted in the permit. The Permittee must comply with all the conditions of the permit. Any changes or modifications to the stationary source must be performed in compliance with Minn. R. 7007.1150 to 7007.1500. Terms used in the permit are as defined in the state air pollution control rules unless the term is explicitly defined in the permit. Unless otherwise indicated, all the Minnesota rules cited as the origin of the permit terms are incorporated into the SIP under 40 CFR § 52.1220 and as such are enforceable by U.S. Environmental Protection Agency (EPA) Administrator or citizens under the Clean Air Act. Signature: [ ] This document has been electronically signed. for the Minnesota Pollution Control Agency for Steven S. Pak, P.E., Manager Air Quality Permits Section Industrial Division Table of Contents Page 1. Permit applications table ............................................................................................................................................ -
Isoprene Photochemistry Over the Amazon Rainforest
Isoprene photochemistry over the Amazon rainforest Yingjun Liua, Joel Britob, Matthew R. Dorrisc, Jean C. Rivera-Riosc,d, Roger Secoe, Kelvin H. Batesf, Paulo Artaxob, Sergio Duvoisin Jr.g, Frank N. Keutscha,c,d, Saewung Kime, Allen H. Goldsteinh, Alex B. Guenthere,i, Antonio O. Manzij, Rodrigo A. F. Souzak, Stephen R. Springstonl, Thomas B. Watsonl, Karena A. McKinneya,1, and Scot T. Martina,m,1 aJohn A. Paulson School of Engineering and Applied Sciences, Harvard University, Cambridge, MA 02138; bDepartment of Applied Physics, University of São Paulo, São Paulo 05508, Brazil; cDepartment of Chemistry, University of Wisconsin-Madison, Madison, WI 53706; dDepartment of Chemistry and Chemical Biology, Harvard University, Cambridge, MA 02138; eDepartment of Earth System Science, University of California, Irvine, CA 92697; fDivision of Chemistry and Chemical Engineering, California Institute of Technology, Pasadena, CA 91125; gDepartment of Chemistry, Universidade do Estado do Amazonas, Manaus, AM 69050, Brazil; hDepartment of Environmental Science, Policy, and Management, University of California, Berkeley, CA 94720; iPacific Northwest National Laboratory, Richland, WA 99354; jInstituto Nacional de Pesquisas da Amazonia, Manaus, AM 69067, Brazil; kDepartment of Meteorology, Universidade do Estado do Amazonas, Manaus, AM 69050, Brazil; lDepartment of Environmental and Climate Sciences, Brookhaven National Laboratory, Upton, NY 11973; and mDepartment of Earth and Planetary Sciences, Harvard University, Cambridge, MA 02138 Edited by Mark H. Thiemens, University of California, San Diego, La Jolla, CA, and approved April 13, 2016 (received for review December 23, 2015) Isoprene photooxidation is a major driver of atmospheric chemistry forests like Amazonia where there are few anthropogenic NO over forested regions. -
Cadmium Sulfide
SIGMA-ALDRICH sigma-aldrich.com SAFETY DATA SHEET Version 6.1 Revision Date 05/28/2017 Print Date 08/08/2019 1. PRODUCT AND COMPANY IDENTIFICATION 1.1 Product identifiers Product name : Cadmium sulfide Product Number : 208183 Brand : Aldrich Index-No. : 048-010-00-4 CAS-No. : 1306-23-6 1.2 Relevant identified uses of the substance or mixture and uses advised against Identified uses : Laboratory chemicals, Synthesis of substances 1.3 Details of the supplier of the safety data sheet Company : Sigma-Aldrich Inc. 3050 Spruce Street ST. LOUIS MO 63103 UNITED STATES Telephone : +1 314 771-5765 Fax : +1 800 325-5052 1.4 Emergency telephone number Emergency Phone # : +1-703-527-3887 2. HAZARDS IDENTIFICATION 2.1 Classification of the substance or mixture GHS Classification in accordance with 29 CFR 1910 (OSHA HCS) Acute toxicity, Oral (Category 4), H302 Germ cell mutagenicity (Category 2), H341 Carcinogenicity (Category 1B), H350 Reproductive toxicity (Category 2), H361 Specific target organ toxicity - repeated exposure (Category 1), H372 Acute aquatic toxicity (Category 1), H400 Chronic aquatic toxicity (Category 1), H410 For the full text of the H-Statements mentioned in this Section, see Section 16. 2.2 GHS Label elements, including precautionary statements Pictogram Signal word Danger Hazard statement(s) H302 Harmful if swallowed. H341 Suspected of causing genetic defects. H350 May cause cancer. Aldrich- 208183 Page 1 of 9 H361 Suspected of damaging fertility or the unborn child. H372 Causes damage to organs through prolonged or repeated exposure. H410 Very toxic to aquatic life with long lasting effects. Precautionary statement(s) P201 Obtain special instructions before use. -
Deposition of Cadmium Sulfide and Zinc Sulfide Thin Films by Aerosol
Turkish Journal of Chemistry Turk J Chem (2015) 39: 169 { 178 http://journals.tubitak.gov.tr/chem/ ⃝c TUB¨ ITAK_ Research Article doi:10.3906/kim-1407-37 Deposition of cadmium sulfide and zinc sulfide thin films by aerosol-assisted chemical vapors from molecular precursors Ashfaque Ahmed MEMON1, Malik DILSHAD2, Neerish REVAPRASADU2, Mohammad Azad MALIK3, James RAFTERY3, Javeed AKHTAR4;5;∗ 1Department of Chemistry, Shah Abdul Latif University, Khairpur, Sindh, Pakistan 2Department of Chemistry, University of Zululand, KwaDlangezwa, South Africa 3School of Chemistry, University of Manchester, Manchester, United Kingdom 4Polymers & Materials Synthesis (PMS) Lab, Department of Physics, COMSATS Institute of Information Technology, Islamabad, Pakistan 5Department of Chemistry, University of Azad Jummu & Kashmir, Muzaffarabad, Pakistan Received: 12.07.2014 • Accepted: 13.10.2014 • Published Online: 23.01.2015 • Printed: 20.02.2015 n II II Abstract: New complexes with the general formula [M(S 2 CN Bu 2)2 ] [where M = Cd (1) and Zn (2)] were synthesized and used as single source precursors to deposit thin films of cadmium sulfide and zinc sulfide by the aerosol-assisted chemical vapor deposition technique. The single crystal X-ray structures of 1 and 2 are also reported. Thermogravimetric analysis of 1 and 2 showed that both precursors decompose cleanly in a single step to produce their respective metal sulfides. The deposition of thin films was carried out on soda glass substrates in the 350{450 ◦ C temperature range under inert conditions. The as-deposited thin films were characterized by powdered X-ray diffraction and field emission scanning electron microscopy. Thin films of CdS deposited at low temperature (350 ◦ C) consist of densely packed granular crystallites with an average size of ca. -
Single-Molecule Fluorescence Detection
Proc. Nadl. Acad. Sci. USA Vol. 86, pp. 4087-4091, June 1989 Biophysics Single-molecule fluorescence detection: Autocorrelation criterion and experimental realization with phycoerythrin (laser-induced fluorescence/femtomolar sensitivity/fluorescence assays/phycoerythrin oligomers) KONAN PECK*, LUBERT STRYERt, ALEXANDER N. GLAZERt, AND RICHARD A. MATHIES* *Department of Chemistry, University of California, Berkeley, CA 94720; tDepartment of Cell Biology, Stanford University School of Medicine, Stanford, CA 94305; and tDepartment of Microbiology and Immunology, University of California, Berkeley, CA 94720 Contributed by Lubert Stryer, February 10, 1989 ABSTRACT A theory for single-molecule fluorescence ofindividual molecules. In this paper, we present a theory for detection is developed and then used to analyze data from single-molecule fluorescence detection and apply it in de- subpicomolar solutions of B-phycoerythrin (PE). The distri- tecting phycoerythrin at concentrations as low as 1 fM. bution of detected counts is the convolution of a Poissonian continuous background with bursts arising from the passage of individual fluorophores through the focused laser beam. The THEORY autocorrelation function reveals single-molecule events and Consider a solution of fluorophores flowing through a fo- provides a criterion for optimizing experimental parameters. cused laser beam. The emission from the illuminated volume The transit time of fluorescent molecules through the 120-fl consists of bursts of fluorescence from molecules passing imaged volume was 800 ps. The optimal laser power (32 mW through the beam superimposed on a continuous background at 514.5 nm) gave an incident intensity of 1.8 x 1023 due to Rayleigh and Raman scattering from the solvent (Fig. photons-cm 2.S-, corresponding to a mean time of 1.1 ns lA). -
I Fluorescent Detection of Chiral Amino Acids
i Fluorescent Detection of Chiral Amino Acids: A Micelle Approach Gengyu Du Yilong, Sichuan, China B.S. in Chemistry University of Science and Technology of China, Hefei, China, 2015 A Dissertation presented to the Graduate Faculty of the University of Virginia in Candidacy for the Degree of Doctor of Philosophy Department of Chemistry University of Virginia April 2020 ii Abstract Fluorescent Detection of Chiral Amino Acids: A Micelle Approach 1,1’-Bi-2-naphthol (BINOL)-based fluorescent probes have been developed as powerful tools for the molecular recognition of many chiral molecules. High sensitivity and enantioselectivity for chiral amino acids have been achieved in organic media, but the recognition in water media has been limited by their poor solubility in aqueous solution. By using a diblock copolymer PEG-PLLA, 3,3’-diformyl-BINOL was encapsulated into micelles to form a micelle probe. It allowed the detection of chiral lysine (Lys) both chemoselectively and enantioselectively in carbonate buffer solution. A limit of detection (LOD) of 848 nM and 2nd order fit of ee detection was obtained for D-Lys. The chemoselectivity was attributed to the selective reaction of Lys’s terminal amino groups with the probe. Series of monoformyl-BINOL with varying substituents were synthesized and engineered into micelle probes. These probes achieved specific detection of chiral tryptophan (Trp) both enantioselectively and chemoselectively in carbonate buffer solution, with LOD of 2.6 µM and 1st order fit of ee detection. A non-C2 symmetric molecule, 3,3’-diformyl-tetrahydro-BINOL, was fabricated into a micelle probe. It achieved specific detection of chiral His both enantioselectively and chemoselectively in carbonate buffer solution, with LOD of 107 nM and 2nd order fit of ee detection. -
18.4.3.7 Detection and Quantification Capabilities
18.4.3.7 Detection and quantification capabilities Among the most important Performance Characteristics of the Chemical Measurement Process (CMP) are those that can serve as measures of the underlying detection and quantification capabilities. These are essential for applications in research, international commerce, health, and safety. Such measures are important for planning measurements, and for selecting or developing CMPs that can meet specified needs, such as the detection or quantification of a dangerous or regulated level of a toxic substance. Equations 18.4.1-6 provide the basis for our considering the meaning of minimum detectable and minimum quantifiable amounts (signals, concentrations) in Analytical Chemistry. In each case, the determining factor is the distribution function of the estimated quantity (estimated net signal Sˆ , concentration or amount xˆ ). If normality can be assumed, it is sufficient to know the standard deviation of the estimated quantity as a function of S (or x). Detection limits (minimum detectable amounts) are based on the theory of hypothesis testing and the probabilities of false positives α, and false negatives ß. Quantification limits are defined in terms of a specified value for the relative standard deviation. It is important to emphasize that both types of limits are CMP Performance Characteristics, associated with underlying true values of the quantity of interest; they are not associated with any particular outcome or result. The detection decision, on the other hand, is result-specific; it is made by comparing the experimental result with the Critical Value, which is the minimum significant estimated value of the quantity of interest. Terminology. Unfortunately, a host of terms have been used within the chemical community to describe detection and quantification capabilities. -
Towards the 1000 Atom Detection Limit for 244Pu. R
50th Lunar and Planetary Science Conference 2019 (LPI Contrib. No. 2132) 2978.pdf TOWARDS THE 1000 ATOM DETECTION LIMIT FOR 244PU. R. Trappitsch,1 M. R. Savina,1 J. M. Rolison,1 L. N. Harrison,1 and N. Dauphas2, 1Lawrence Livermore National Laboratory, Nuclear and Chemical Sciences Divi- sion, Livermore, CA 94551, ([email protected]) 2The University of Chicago, Enrico Fermi Institute, and Chicago Center for Cosmochemistry, Chicago, IL 60637 Introduction Plutonium-244 is a radionuclide with a size of ∼ 3% of the sample area we slowly desorbed half-life of 80 Ma that can only be produced by the rapid sample material from the surface, subsequently ionized neutron capture (r-) process. While the sources of the Pu neutrals using a three-color, three-photon resonance r-process are poorly constrained and heavily discussed ionization scheme, and then analyzed these photoions in [e.g.,1], optical spectroscopy of the neutron star merger a time-of-flight mass spectrometer. By assuming a ho- associated with the gravitational-wave event GW170817 mogeneous distribution of the sample material over the indicated the presence of freshly nucleosynthesized lan- surface we calculated that 2:6 × 105 239Pu, 3:7 × 104 thanides [2], a main product expected from r-process 240Pu, and 1:8 × 103 242Pu atoms were in the anal- nucleosynthesis calculations. Proxy measurements of ysis spot. Plutonium-238 and 241Pu atoms were also 244Pu in the early Solar System, measured via 244Pu in the analysis spot, however, interferences with non- fission-produced xenon in meteorites [3], show a rather resonantly ionized 238U and 241Am, respectively, pre- high abundance. -
Limit of Detection for Calibration Methods
Limit of detection for calibration methods MARÍA JOSÉ RODRÍGUEZ CUESTA Doctoral Thesis ROVIRA I VIRGILI UNIVERSITY Tarragona 2006 UNIVERSITAT ROVIRA I VIRGILI LIMIT OF DETECTION FOR SECOND-ORDER CALIBRATION METHODS. M. José Rodríguez Cuesta ISBN: 978-84-690-7787-0 / DL: T.1349-2007 UNIVERSITAT ROVIRA I VIRGILI LIMIT OF DETECTION FOR SECOND-ORDER CALIBRATION METHODS. M. José Rodríguez Cuesta ISBN: 978-84-690-7787-0 / DL: T.1349-2007 Limit of detection for second-order calibration methods Doctoral thesis ROVIRA I VIRGILI UNIVERSITY UNIVERSITAT ROVIRA I VIRGILI LIMIT OF DETECTION FOR SECOND-ORDER CALIBRATION METHODS. M. José Rodríguez Cuesta ISBN: 978-84-690-7787-0 / DL: T.1349-2007 UNIVERSITAT ROVIRA I VIRGILI LIMIT OF DETECTION FOR SECOND-ORDER CALIBRATION METHODS. M. José Rodríguez Cuesta ISBN: 978-84-690-7787-0 / DL: T.1349-2007 Rovira i Virgili University Department of Analytical Chemistry and Organic Chemistry Limit of detection for second-order calibration methods Dissertation presented by María José Rodríguez Cuesta to receive the degree Doctor of the Rovira i Virgili University European PhD Tarragona, 2006 Supervisor Dr. Ricard Boqué i Martí UNIVERSITAT ROVIRA I VIRGILI LIMIT OF DETECTION FOR SECOND-ORDER CALIBRATION METHODS. M. José Rodríguez Cuesta ISBN: 978-84-690-7787-0 / DL: T.1349-2007 UNIVERSITAT ROVIRA I VIRGILI LIMIT OF DETECTION FOR SECOND-ORDER CALIBRATION METHODS. M. José Rodríguez Cuesta ISBN: 978-84-690-7787-0 / DL: T.1349-2007 ROVIRA I VIRGILI UNIVERSITY Department of Analytical Chemistry and Organic Chemistry Dr -
Chiral Separation of Amines by Non-Aqueous Capillary Electrophoresis Using Low Molecular Weight Selectors
Digital Comprehensive Summaries of Uppsala Dissertations from the Faculty of Pharmacy 31 Chiral Separation of Amines by Non-Aqueous Capillary Electrophoresis using Low Molecular Weight Selectors YLVA HEDELAND ACTA UNIVERSITATIS UPSALIENSIS ISSN 1651-6192 UPPSALA ISBN 91-554-6524-2 2006 urn:nbn:se:uu:diva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