Chemical Safety Versus Terrorism

Total Page:16

File Type:pdf, Size:1020Kb

Chemical Safety Versus Terrorism CHEMICAL SAFETY VERSUS TERRORISM Pavel CASTULIK CBRNE Consultant [email protected]; [email protected] Prepared for Seminar on the OPCW`s Contribution to Security and Non-proliferation of Chemical Weapons Civilians are the most vulnerable victims WWI Phosgene experience Guidance for Chemical Terrorism Phosgene is still there, however, there is no antidote available BHOPAL MEMENTO Chemical leak of methyl isocyanide 7 Scene of Casualties EURATOX 2002 courtesy Dr. A. Ziegler Terrorism The term terrorism was first used to describe the post-revolutionary French "reign of terror" of 1793 to 1794 The term is now applied also to CBRNE releases and other actions that violate international law, and which seek to intimidate, demoralize, or subjugate a population for political, religious, or ideological purposes Terrorism targets High-risk targets for acts of terrorism include military and civilian government facilities, international airports, large cities, and high- profile landmarks Terrorists might also target large public gatherings, water and food supplies, utilities, and corporate centers Further, terrorists are capable of spreading fear by sending explosives or chemical, biological and radiological agents through the mail Potential methods used by terrorists Contamination of reservoirs Dispersal in bombs or and urban water supply projectiles systems Miscellaneous direct methods: Contamination of food, hand sprayers, water guns, beverages, drugs, or parcels cosmetics in manufacturing, Release of industrial/agricultural distribution processes and chemicals via attacks on near the point of consumption production or storage facilities Miscellaneous product Release of industrial/agricultural contaminations: chemicals via attacks on truck, stamps/envelopes, IV fluids, rail, or barge shipping etc. Miscellaneous releases of Release of gases or aerosols industrial/agricultural chemicals, into building HVAC systems especially anhydrous ammonia, Release of gases or aerosols fumigants and pesticides, and from aircraft and unmanned disinfectant gases (e.g., vehicles chlorine, chlorine dioxide, ethylene oxide) Criteria for determining terrorist priority chemical agents Chemical agents already known to be used as weaponry Availability of chemical agents to potential terrorists Chemical agents likely to cause major morbidity or mortality Potential of agents for causing public panic and social disruption, and Agents that require special action for public health preparedness Categories of chemicals include CW Agents Flammable industrial Pulmonary agents gases and liquids phosgene Gasoline chlorine Propane vinyl chloride Explosive nitro Volatile toxins compounds and benzene oxidizers chloroform ammonium nitrate combined with fuel oil trihalomethanes Categories of chemicals include cont. Psychochemical agents Corrosive industrial acids and bases, Pesticides Nitric acid, Persistent, and Sulfuric acid Non-persistent Fluoride acid Caustic soda Rodenticides Sodium fluoracetate Tetramethylenedisulfotetramine Dioxins, furans, and polychlorinated biphenyls (PCBs) Poison industrial gases, liquids, and solids, Heavy metals and compounds Cyanides, Arsenic Nitriles Barium Lead Mercury Thallium Chemical Facility-Security and Safety Concerns • Chemical manufacturers • Chemical processors • Ports and terminals • Storage • Transportation facilities • Corporate headquarters • Warehouses, etc. Chemical Sector vs Other Sectors The Chemical Sector covering: Transportation Systems Energy Basic chemicals Water Specialty chemicals Dams Petrochemicals Agriculture & Food Agricultural chemicals Emergency Services Healthcare and Public Health Pharmaceuticals Postal & Shipping Consumer products Information Technology is dependent on, depended on by, Communications and overlaps with a wide range Banking & Finance of other sectors, including: Governmental Facilities Commercial Facilities Nuclear Reactors, Materials, and Waste Processing-Storage-Transport of Chemicals Vulnerability of chemical facilities When we look at all of the different targets for a potential attack around us and ask ourselves which target present the greatest possibility of mass casualties and are the least well-secured at the present time - „these are chemical facilities“ The government needs more authority and collaboration with chemical facilities owners to reduce the vulnerability of chemical plants to a terrorist attack or sabotage High-risk chemical facilities Chemical manufacturing, Energy and utilities storage and distribution Mining Agriculture and food Electronics Paints and coatings Public Water Systems Explosives (chlorine) Plastics Refrigeration industry Healthcare (ammonia) Nuclear industry Sport facilities (ice skating-ammonia) Chemical Industry Material source for chemical terrorism A reasonably open society with a well-developed chemical industry provides many vulnerabilities that might be exploited by skilled, committed, and adequately-funded makers of improvised chemical weapons Safety and security of chemical facilities is still lagging behind nuclear installations Key Shortages in Effective Chemical Security Planning • Most chemical-related firms have • Most firms do not have dedicated comprehensive emergency security managers typically the planning and response processes security function is managed by • However, those processes someone who: typically don't consider or allow • wears "many hats," which may for security-related include emergencies and crises • EHS • Safety • The most chemical firms have • Human Resources done much to screen and manage their own employees • Facilities Management/Maintenance, • While relatively little has been • Engineering, etc. done concerning contractors and non-company drivers who may have equal levels of access and exposure Chemical Facility Safety & Security Course of Action Gaps in chemical Chemical security facility's safety & vulnerability assessments security is an invitation Development chemical for terrorism to attack security plans for chemical facilities chemical facilities and/or gain chemical Build up capabilities and products for intentional capacities for chemical facilities safety and use during terrorist security events Chemical facilities as source chemical terrorism Release-Fire-Explosion -Toxic, flammable, or explosive chemicals or materials that, if released from a facility, have the potential for significant adverse consequences for human life or health Theft or Diversion - Chemicals or materials that, if stolen or diverted, have the potential to be misused as weapons or easily converted into weapons using simple chemistry, equipment or techniques, in order to create significant adverse consequences for human life or health Sabotage or Contamination - Chemicals or materials that, if mixed with readily available materials, have the potential to create significant adverse consequences for human life or health Cyber attack at chemical facility 1. Defeat the perimeter fence 2. Gain access to the control cabinet 3. Install a wireless “man in the middle” device Use the wireless device to damage the information network Physical Damage (offset by Safety Shutdown Systems) Economic Damage I. Historical Data II. Accounting Information III. Tuning and other instrument information Counter-terrorism considerations In addition to counter- Sabotage terrorism considerations, Arson chemical security assessments should Theft and pilferage consider all sorts of Hijacking security-related harm that Vandalism could occur including: Trespassing Workplace violence Activist disruption Contamination Cyber attack, etc. Lower chemical facility's risk To assess vulnerability and Reducing the amount of have plans to reduce hazards hazardous substances Two factors that must be Using less hazardous considered: materials The ease of access to the site To switch chemical facilities to and are security measures inherently less dangerous adequate? processes where feasible and To place each plant in a ''risk Simplifying plant design and tier" based on the kinds and procedures amounts of chemicals it has and its proximity to dense populations Key Concepts of Effective Chemical Security Planning • An effective chemical security The team-based chemical program should complement plant security vulnerability existing programs and assessment processes: Positive security awareness by • including safety and safety employees is the most awareness powerful, cost effective and • environmental management frequently neglected of all • hiring and screening security countermeasures procedures Modification of comprehensive • emergency and crisis planning emergency planning and and response response processes • shipping and receiving, etc. Risk Based Performance Standards Restrict area perimeter and Cyber access Training Physical Security Around Personnel surety Control of Vehicles Around Elevated threats Inspection of Vehicles Around Response Background checks on personnel Monitoring with access to materials or the Specific threats, vulnerabilities, or systems that control them risks Shipping, receipt, and storage Reporting of significant security Secure site assets incidents Screen and control access Significant security incidents and Deter, detect, delay suspicious activities Theft and diversion Officials and organization Sabotage Records Chemical plant security include Perform chemical and refinery Develop emergency and crisis security and vulnerability
Recommended publications
  • Disaster Response and Biological/Chemical Terrorism
    Disaster Response and Biological/Chemical Terrorism Information Packet Prepared by: Emergency Medical Services Department October 2001 Disaster Response and Biological/Chemical Terrorism Clearinghouse Information The College has been very active in disaster planning and response as well as biological/chemical terrorism preparation for a number of years. The membership section, Disaster Medicine, was the first membership section organized in 1989. They have been one of the largest in membership and one of the most active. The EMS Department maintains information for members and the public on disaster response and biological/chemical terrorism topics in a variety of formats and publications. POLICY STATEMENTS The College has current policies addressing the following: · Disaster Data Collection (Oct. 2000) · Disaster Medical Service (June 2000) · Support for National Disaster Medical System-NDMS (Mar. 1999) · Handling of Hazardous Materials (June 1999) TEXT BOOKS The College developed and published the text: Community Medical Disaster Planning and Evaluation Guide through a section grant with the Disaster Medicine Section. This is an excellent guide for developing or updating a hospital or city/county disaster plan. While biological or chemical agents are not specifically mentioned, many of the same disaster planning and response issues remain the same. This text can be ordered through the College bookstore at 1-800-798- 1822, ext. 6for $69.00, item number 513000-1020. NBC TASK FORCE The College’s nuclear, biological and chemical (NBC) Task Force recently completed a grant with the Department of Health and Human Services (HHS), Office of Emergency Preparedness (OEP) to develop objectives, content and competencies for the training of emergency medical technicians, emergency physicians, and emergency nurses to care for casualties resulting from nuclear, biological, or chemical (NBC) incidents.
    [Show full text]
  • Estimation Of'hetrazan'in Body Fluids
    No. 4183 December 31, 1949 NATURE II 35 strated by a coupled oxidation of alcohol in the blank value of about 1 (J.gm.fml. Further, trichlor­ presence of catalase6 • As an artificial ascorbic oxidase acetic acid precipitation removes about 20 per cent it had a Qo8 ((.Ll. oxygen per mgm. dry weight per hr.) of added 'Hetrazan'. Therefore, although it may at pH 7·2 and 39° C. of about 10,000. Hydrogen be more tedious, it is preferable to extract serum or cyanide inhibited this catalysed oxidation of ascorbic plasma. acid by combining with modified ferricytochrome c, Urines show a blank value of about 5 flgm.fml., thus preventing its reduction, while carbon monoxide, but occasionally, in concentrated urines, the blank by combining with modified ferrocytochrome c, may reach 20 vgm.jml. prevented its oxidation. The carbon monoxide The method is sufficiently sensitive to measure a inhibition was somewhat light-sensitive. This reaction blood concentration of 'Hetrazan' of 1 (J.gm.jml. Like was also inhibited by methyl isocyanide and nitroso­ most of these methods, it lacks specificity, but has benzene. Modified cytochrome c also catalysed the been found useful in following the concentration jn decomposition of hydrogen peroxide, being itself blood and urine after oral administration of the drug. destroyed in this reaction. Cyanide inhibited this A full account of the results of these experiments catalysed decomposition of hydrogen peroxide. will be published later. Typically, ingestion of The result of this experiment agrees with an 10 mgm.jkgm. body-weight of the hydrochloride observation of Keilin and Hartrees that when cyto­ results in a maximum plasma concentration of about chrome c is made autoxidizable it loses its catalytical 5-7 [lgm.jml., reached in three hours.
    [Show full text]
  • Interferometric Observations of Large Biologically Interesting Interstellar and Cometary Molecules
    SPECIAL FEATURE: PERSPECTIVE Interferometric observations of large biologically interesting interstellar and cometary molecules Lewis E. Snyder* Department of Astronomy, University of Illinois, 1002 West Green Street, Urbana, IL 61801 Edited by William Klemperer, Harvard University, Cambridge, MA, and approved May 26, 2006 (received for review March 3, 2006) Interferometric observations of high-mass regions in interstellar molecular clouds have revealed hot molecular cores that have sub- stantial column densities of large, partly hydrogen-saturated molecules. Many of these molecules are of interest to biology and thus are labeled ‘‘biomolecules.’’ Because the clouds containing these molecules provide the material for star formation, they may provide insight into presolar nebular chemistry, and the biomolecules may provide information about the potential of the associated inter- stellar chemistry for seeding newly formed planets with prebiotic organic chemistry. In this overview, events are outlined that led to the current interferometric array observations. Clues that connect this interstellar hot core chemistry to the solar system can be found in the cometary detection of methyl formate and the interferometric maps of cometary methanol. Major obstacles to under- standing hot core chemistry remain because chemical models are not well developed and interferometric observations have not been very sensitive. Differentiation in the molecular isomers glycolaldehdye, methyl formate, and acetic acid has been observed, but not explained. The extended source structure for certain sugars, aldehydes, and alcohols may require nonthermal formation mechanisms such as shock heating of grains. Major advances in understanding the formation chemistry of hot core species can come from obser- vations with the next generation of sensitive, high-resolution arrays.
    [Show full text]
  • United States Patent Office Patented Jan
    3,712,911 United States Patent Office Patented Jan. 23, 1973 1. 2 Another possibility is for R1 and R2 to jointly form an 3,712,911 alkylidene radical, as in the compound METALLIZED SOCYANDES Ulrich Schoellkopf, Bovenden, and Fritz Gerhart, Gottin EC-CEI-CE=C-N=C gen, Germany, assignors to Badische Anilin- & Soda Fabrik Aktiengesellschaft, Ludwigshafen (Rhine), Ger Me many or to denote a carboxylic radical together with the alpha No Drawing. Filed Oct. 20, 1969, Ser. No. 867,941 carbon atom of the isocyanide, as in cyclohexylisocyanide. Int, C. C07c 119/02 The radicals R in the ROOC- and ROC-groups may U.S. C. 260-464 8 Claims in principle have the same meanings as the radicals R and R. In ROOC-R may also be a metal ion (Me) and in O ov-ROC-hydrogen. ABSTRACT OF THE DISCLOSURE Me in the first-mentioned general formula stands for ov-Metalated isocyanides containing the radical alkali metal, i.e. lithium, sodium or potassium, or an equivalent of magnesium, zinc or cadmium. 5 As can be seen from the details given above, the metal lized isocyanides of this invention constitute a new class Me of compounds characterized by the as an essential portion of the molecule. Me stands for alkali or an equivalent of magnesium, zinc or cadmium. Their manufacture is accomplished by replacing hydrogen 20 on the cy-carbon of an isocyanide with said metals. The portion of the molecule. compounds open up new routes for organic synthesis and Examples of individual compounds of this class are therefore have outstanding importance as intermediates, c-metal methyl isocyanide, a-metal ethyl isocyanide, c e.g.
    [Show full text]
  • High-Threat Chemical Agents: Characteristics, Effects, and Policy Implications
    Order Code RL31861 CRS Report for Congress Received through the CRS Web High-Threat Chemical Agents: Characteristics, Effects, and Policy Implications Updated September 9, 2003 Dana A. Shea Analyst in Science and Technology Policy Resources, Science, and Industry Division Congressional Research Service ˜ The Library of Congress High-Threat Chemical Agents: Characteristics, Effects, and Policy Implications Summary Terrorist use of chemical agents has been a noted concern, highlighted after the Tokyo Sarin gas attacks of 1995. The events of September 11, 2001, increased Congressional attention towards reducing the vulnerability of the United States to such attacks. High-threat chemical agents, which include chemical weapons and some toxic industrial chemicals, are normally organized by military planners into four groups: nerve agents, blister agents, choking agents, and blood agents. While the relative military threat posed by the various chemical types has varied over time, use of these chemicals against civilian targets is viewed as a low probability, high consequence event. High-threat chemical agents, depending on the type of agent used, cause a variety of symptoms in their victims. Some cause death by interfering with the nervous system. Some inhibit breathing and lead to asphyxiation. Others have caustic effects on contact. As a result, chemical attack treatment may be complicated by the need to identify at least the type of chemical used. Differences in treatment protocols for the various high-threat agents may also strain the resources of the public health system, especially in the case of mass casualties. Additionally, chemical agents trapped on the body or clothes of victims may place first responders and medical professionals at risk.
    [Show full text]
  • How States Respond to Terrorist Attacks: an Analysis of the Variance in Responses
    How States Respond to Terrorist Attacks: An Analysis of the Variance in Responses A Thesis Submitted to The University of Michigan In partial fulfillment of the requirements for the degree of Honors Bachelor of Arts Department of Political Science Lauren A Bondarenko March 2014 Advisor: Allan Stam Table of Contents Acknowledgements………………………………………………………………………………………… i Acronyms/Abbreviations………………………………………………………………………………... ii Preface…………………………………………………………………………………………………………… 1 Chapter 1: Introduction Conceptualizations………………………………………………………………………………. 4 National Security…………………………………………………………………………….. 4 Terrorism……………………………………………………………………………………….. 6 Literature Review………………………………………………………………………………… 8 Institutions……………………………………………………………………………………... 8 National Security as a Collective Action Problem……………………………… 11 American Institutional Reform………………………………………………………… 12 European Institutional Reform………………………………………………………… 15 Applying the Balance of Threat Theory…………………………………………….. 18 What the Literature is Missing…………………………………………………………. 21 Hypotheses…………………………………………………………………………………………... 22 Chapter Previews…………………………………………………………………………………. 23 Chapter 2: Methodology Use of the Global Terrorism Database…………………………………………………… 25 Reason for Database Selection…………………………………………………………. 25 Information Missing in the Database………………………………………………... 25 Creation of My Dataset…………………………………………………………………………. 27 Using GTD………………………………………………………………………………………. 27 Coding System………………………………………………………………………………… 28 Case Selection……………………………………………………………………………………… 29 A Note on Style…………………………………………………………………………………….
    [Show full text]
  • Prevalence of Complex Organic Molecules in Prestellar Cores Within the Taurus Star Forming Region
    Prevalence of Complex Organic Molecules in Prestellar Cores Within the Taurus Star Forming Region! Samantha Scibelli! 3rd year Graduate Student and NSF Fellow! Advised by Dr. Yancy Shirley! Steward Observatory, University of Arizona Celebrating The First 40 Years Of Alexander Tielens’ Contribution To Science:! The Physics And Chemistry Of The ISM! Palais des Papes in Avignon, France. 2nd – 6th September 2019! Origins of Complex Molecules! + - Gas: CH3OH2 + e à CH3OH + H only 3% yield … too SLOW (Geppert et al. 2006) Photo- Gas-phase Chemistry desorption d Ion-molecule Reactions UV/XUV! à COM abundances several Silicate or ! Irradiation! / of orders of magnitude lower than Carbonaceous ! & Cosmic observed grain! Rays (Charnley & Tielens 1992) Chemical reactions! How do complex organics form in Ion- radiation (Burke & Brown 2010) cold (10 K), UV- shielded environments? Origins of Complex Molecules! Solid: CO + H à HCO + H à H2CO + H à CH3O + H à CH3OH Chemical Chemical Reactive desorption Desorption d Neutral-Neutral Silicate or ! / Carbonaceous ! reactions of radicals ! grain! Chemical Models predict reactions! abundances Ion- radiation (Minissale et al. 2016, which we can Vasyunin et al. 2017) constrain! COMs in Prestellar Cores! B68 Methanol When, where CH3OH and how are these molecules forming in Acetaldehyde prestellar CH3CHO cores?! Dimethyl Birthplace of low-mass stars Ether (M ≤ a few M¤) CH₃OCH₃ 4 5 -3 Dense (10 - 10 cm ) & cold (≤ 10K ) COMs in Prestellar Cores! ! ! ! (K) mb arcsec T arcsec "$ "$ V (km s-1)! "# arcsec! "# arcsec! LSR L1498 L1517B Tafalla et al. 2006! TMC-1 CH3CHO CH3CHO (5-4) A (5-4) E CH3OH (20,2 - 10,1 A ) C34S (J = 2 − 1) Soma et al.
    [Show full text]
  • Supporting Information Activation Chemistry Drives the Emergence of Functionalised Protocells
    Electronic Supplementary Material (ESI) for Chemical Science. This journal is © The Royal Society of Chemistry 2020 Supporting information Activation chemistry drives the emergence of functionalised protocells Claudia Bonfio§,*, David A. Russell§, Nicholas J. Green, Angelica Mariani and John D. Sutherland Medical Research Council Laboratory of Molecular Biology, Cambridge Biomedical Campus, Francis Crick Avenue, Cambridge CB2 0QH, United Kingdom * Correspondence: [email protected] Materials and methods Supporting Figures 1 to 49 Supporting References Materials and methods Reagents and solvents were bought from Nu-Chek Prep, Avanti Polar Lipids, Sigma-Aldrich, VWR International, Alfa-Aesar and Acros Organics and were used without further purification unless otherwise stated. Oligonucleotides were purchased from IDT. For membrane growth studies, the phospholipids N-(7-nitrobenz-2-oxa-1,3-diazol-4-yl)-1,2-dihexadecanoyl-sn- glycero-3-phosphoethanolamine (NBD PE) and Lissamine rhodamine B 1,2-dihexadecanoyl- sn-glycero-3-phosphoethanolamine (Rh-DHPE) were used (Life Technologies). A Mettler Toledo SevenEasy pH Meter S20 was used to monitor the pH of the solutions, adjusted with either NaOH or HCl solutions as appropriate. Deoxygenation of H2O:D2O 9:1 mixtures was achieved by sparging anhydrous argon through the solution for 30 min. All reactions were carried out at room temperature unless otherwise stated. Purification of the synthesised molecules was performed by reverse-phase chromatography using a preparative Varian Prostar HPLC System equipped with an Atlantis T3 C18 Prep Column OBD 10 μm (19× 250 mm). Analytical HPLC was used for hydrolysis experiments, using a Waters Atlantis T3 C18 column (5 μm, 4.6 mm x 150 mm).
    [Show full text]
  • Non-Military Security and Global Order the Impact of Extremism, Violence and Chaos on National and International Security
    Non-Military Security and Global Order The Impact of Extremism, Violence and Chaos on National and International Security Peter Chalk Non-Military Security and Global Order Also by Peter Chalk WEST EUROPEAN TERRORISM AND COUNTER-TERRORISM: The Evolving Dynamic Non-Military Security and Global Order The Impact of Extremism, Violence and Chaos on National and International Security Peter Chalk National Security Research Division RAND Corporation Arlington, Virginia First published in Great Britain 2000 by MACMILLAN PRESS LTD Houndmills, Basingstoke, Hampshire RG21 6XS and London Companies and representatives throughout the world A catalogue record for this book is available from the British Library. ISBN 0–333–77373–X First published in the United States of America 2000 by ST. MARTIN’S PRESS, LLC, Scholarly and Reference Division, 175 Fifth Avenue, New York, N.Y. 10010 ISBN 0–312–23167–9 Library of Congress Cataloging-in-Publication Data Chalk, Peter. Non-military security and global order : the impact of extremism, violence, and chaos on national and international security / Peter Chalk. p. cm. Includes bibliographical references and index. ISBN 0–312–23167–9 (cloth) 1. Internal security. 2. Security, International. I. Title. HV6419 .C53 2000 363.3'2—dc21 00–021169 © Peter Chalk 2000 All rights reserved. No reproduction, copy or transmission of this publication may be made without written permission. No paragraph of this publication may be reproduced, copied or transmitted save with written permission or in accordance with the provisions of the Copyright, Designs and Patents Act 1988, or under the terms of any licence permitting limited copying issued by the Copyright Licensing Agency, 90 Tottenham Court Road, London W1P 0LP.
    [Show full text]
  • Assessing Al-Qaeda's Chemical Threat
    ISSN 1988-5237 AthenaIntelligence.org Assessing al-Qaeda’s Chemical T hreat René Pita Athena Paper, Vol. 2, No 2 Article 3/5 April 17, 2007 www.athenaintelligence.org 27 ISSN 1988-5237 AthenaIntelligence.org Introduction After the 11 September 2001 (9/11) terrorist attacks in the United States, there is a high perception of risk of possible attacks with chemical weapons (CW ), especially by groups affiliated or associated with the al-Qaeda terrorist network. Earlier, in 1994 and 1995, Aum Shinrikyo, a religious organization in Japan, used sarin, a nerve chemical warfare agent, in attacks in Matsumoto City and on the Tokyo subway, causing a large number of casualties. These terrorist attacks had a big impact on the chemical defence and intelligence communities but not on other circles, perhaps because a chemical attack by a religious organization in Japan seemed something far removed from the reality of the rest of the world. But this changed after 9/11 when the mailing of letters containing anthrax spores, accompanied by images of the attacks on the W orld Trade Center towers, increased the concern about weapons of mass destruction (W MD) attacks, including by CW . As a religious terrorist group, al-Qaeda does not fit the assumption made by Brian Jenkins in 1975 that “terrorists want a lot of people watching and a lot of people listening, and not a lot of people dead.”1 This statement fits better with secular terrorist groups. But for religious terrorist groups like al-Qaeda, “divine duty” results in disappearance of moral restraints that would justify “a lot of people dead” in their terrorist attacks,2 such as the 9/11 ones.
    [Show full text]
  • Methyl Isocyanide Isomerization Kinetics: Determination of Collisional Deactivation Parameters Fulfowhg C-H Overtone Excitation
    3544 J. Phys. Chem. 1986, 90, 3544-3549 SnI5 surfaces, as well as on silica surface: wherein the experi- relative to studies in other laboratories7 may be explained by the mental curves did follow the strong collider curve at the same lower high temperature seasoning of the surface that occurs in our work. temperatures, indicates otherwise. The predicted magnitude of fractional surface coverage 6 in such case would be only 6 - 1Om5 Acknowledgment. This work was supported by the National and virtually independent of temperature. Science Foundation and by the Office of Naval Research. Finally the higher a,,values found in this work on metal surfaces Registry No. Cyclobutene, 822-35-5; gallium, 7440-55-3. Methyl Isocyanide Isomerization Kinetics: Determination of Collisional Deactivation Parameters fulfowhg C-H Overtone Excitation Deanne L. SnaveIy,+ Richard N. Zare,* Department of Chemistry, Stanford University, Stanford, California 94305 James A. Miller, and David W. Chandler Combustion Research Facility, Sandia National Laboratories. Livermore, California 94550 (Received: January 15, 1986; In Final Form: April 8, 1986) The isomerization of methyl isocyanide (CH3NC) to acetonitrile (CH3CN) was studied by excitation of the 5uC-” (726.6 nm) and 6vC-H (621.4 nm) overtone states, which lie about 1 and 8 kcal/mol, respectively, above the isomerization barrier. Product yields were measured as a function of pressure and collision partner. A Stern-Volmer plot (yield-’ vs. pressure) shows that (1) deactivation by collision with pure CH3NCis more rapid than with C3H6,sF6, or Ar, (2) the collisional deactivation efficiencies decrease in going from C3H6to SF6 to Ar, and (3) the single-collisiondeactivation approximation (strong collider approximation) fails for both the 6vC+, and 5vCmHdata.
    [Show full text]
  • NCTC Annex of the Country Reports on Terrorism 2008
    Country Reports on Terrorism 2008 April 2009 ________________________________ United States Department of State Publication Office of the Coordinator for Counterterrorism Released April 2009 Page | 1 Country Reports on Terrorism 2008 is submitted in compliance with Title 22 of the United States Code, Section 2656f (the ―Act‖), which requires the Department of State to provide to Congress a full and complete annual report on terrorism for those countries and groups meeting the criteria of the Act. COUNTRY REPORTS ON TERRORISM 2008 Table of Contents Chapter 1. Strategic Assessment Chapter 2. Country Reports Africa Overview Trans-Sahara Counterterrorism Partnership The African Union Angola Botswana Burkina Faso Burundi Comoros Democratic Republic of the Congo Cote D‘Ivoire Djibouti Eritrea Ethiopia Ghana Kenya Liberia Madagascar Mali Mauritania Mauritius Namibia Nigeria Rwanda Senegal Somalia South Africa Tanzania Uganda Zambia Zimbabwe Page | 2 East Asia and Pacific Overview Australia Burma Cambodia China o Hong Kong o Macau Indonesia Japan Republic of Korea (South Korea) Democratic People‘s Republic of Korea (North Korea) Laos Malaysia Micronesia, Federated States of Mongolia New Zealand Papua New Guinea, Solomon Islands, or Vanaatu Philippines Singapore Taiwan Thailand Europe Overview Albania Armenia Austria Azerbaijan Belgium Bosnia and Herzegovina Bulgaria Croatia Cyprus Czech Republic Denmark Estonia Finland France Georgia Germany Greece Hungary Iceland Ireland Italy Kosovo Latvia Page | 3 Lithuania Macedonia Malta Moldova Montenegro
    [Show full text]