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SAFETY DATA SHEET Arsenic

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SAFETY DATA SHEET Arsenic Bayville Chemical Supply Company Inc. 70-G East Jefryn Boulevard, Deer Park, New York 11729 USA Telephone: 631-586-4309 E-Mail: [email protected] Fax: 631-254-5591 SAFETY DATA SHEET Arsenic 1. PRODUCT IDENTIFICATION Manufacturer/Supplier: Bayville Chemical Supply Company Inc 70-G East Jefryn Boulevard, Deer Park, NY 11729 USA Tel (631) 586-4309 * Fax (631) 254-5591 E-Mail: [email protected] Emergency Contact: CHEMTEL: (800) 255-3928 International CHEMTEL: (813) 248-0585 Trade Name: Arsenic Metal Chemical Family: Metal CAS #: 7440-38-2 EC#: 231-148-6 Formula: As Relevant identified uses of the substance or mixture and uses advised against: Scientific research and development. 2. HAZARDOUS IDENTIFICATION Classification of the substance or mixture Classification of the substance or mixture in accordance with 29 CFR 1910 (OSHA HCS) HS06 Skull and crossbones Acute Tox. 3 H301 Toxic if swallowed. Acute Tox. 3 H331 Toxic if inhaled. Hazards not otherwise classified: No information known. Label elements GHS label elements: The product is classified and labeled in accordance with 29 CFR 1910 (OSHA HCS) Hazard pictograms HS06 Signal word: Danger Hazard statements H301+H331 Toxic if swallowed or if inhaled. Precautionary statements P261 Avoid breathing dust/fume/gas/mist/vapors/spray P301+P310 IF SWALLOWED: Immediately call a POISON CENTER/ doctor. P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing. P311 Call a POISON CENTER/doctor. P405 Store locked up. P501 Dispose of contents/container in accordance with local/regional/national/ international regulations. Classification system HMIS Rating: HMIS ratings (scale 0-4) (Hazardous Materials Identification System) Health: 3 Flammability: 0 Reactivity: 1 Health (acute effects) = 3 Flammability = 0 Physical Hazard = 1 Other hazards Results of PBT and vPvB assessment PBT: Not applicable. vPvB: Not applicable. 3. COMPOSITION/INFORMATION ON INGREDIENTS Chemical characterization: Substances CAS# Description 7440-38-2 Arsenic Concentration ≤100% Identification number(s): EC number: 231-148-6 Index number: 033-001-00-X 4. FIRST-AID MEASURES Description of first aid measures General information: Immediately remove any clothing soiled by the product. Remove breathing Apparatus only after contaminated clothing has been completely removed. In case of irregular breathing or respiratory arrest provide artificial respiration. After inhalation: Supply fresh air. If required, provide artificial respiration. Keep patient warm. Seek immediate medical advice. After skin contact: Immediately wash with water and soap and rinse thoroughly. Seek immediate medical advice. After eye contact: Rinse opened eye for several minutes under running water. Then consult a doctor. After swallowing: Do not induce vomiting; immediately call for medical help. Information for doctor Most important symptoms and effects, both acute and delayed: Toxic if inhaled. Toxic if swallowed. Indication of any immediate medical attention and special treatment needed: No further relevant information available. 5. FIRE-FIGHTING MEASURES Extinguishing media Suitable extinguishing agents: Special powder for metal fires. Do not use water. For safety reasons unsuitable extinguishing agents: Water Special hazards arising from the substance or mixture If this product is involved in a fire, the following can be released: Arsenic oxides Advice for firefighters Protective equipment: Wear self-contained respirator. Wear fully protective impervious suit. 6. ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures: Wear protective equipment. Keep unprotected persons away. Ensure adequate ventilation Environmental precautions: Do not allow material to be released to the environment without proper governmental permits. Methods and material for containment and cleaning up: Dispose of contaminated material as waste according to section 13. Ensure adequate ventilation. Prevention of secondary hazards: No special measures required. Reference to other sections: See Section 7 for information on safe handling, See Section 8 for information on personal protection equipment, See Section 13 for disposal information. Protective Action Criteria for Chemicals PAC-1: 1.5 mg/m3 PAC-2: 17 mg/m3 PAC-3: 100 mg/m3 7. HANDLING AND STORAGE Handling Precautions for safe handling: Keep container tightly sealed. Store in cool, dry place in tightly closed containers. Ensure good ventilation at the workplace. Open and handle container with care. Information about protection against explosions and fires: No information known. Conditions for safe storage, including any incompatibilities Storage Requirements to be met by storerooms and receptacles: No special requirements. Information about storage in one common storage facility: Store away from oxidizing agents. Further information about storage conditions: Keep container tightly sealed. Store in cool, dry conditions in well-sealed containers. Specific end use(s): No further relevant information available. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Additional information about design of technical systems: Properly operating chemical fume hood designed for hazardous chemicals and having an average face velocity of at least 100 feet per minute. Control parameters Components with limit values that require monitoring at the workplace: 7440-38-2 Arsenic (100.0%) PEL (USA) Long-term value: 0.5* 0.01** mg/m³ as As; *organic**inorg. compds.; 29 CFR 1910.1018 REL (USA) Ceiling limit value: 0.002 mg/m³ as As; 15min; See Pocket Guide App. A TLV (USA) Long-term value: 0.01 mg/m³ as As; BEI EL (Canada) Long-term value: 0.01 mg/m³ as As; ACGIH A1, IARC1 EV (Canada) Short-term value: 0.05 mg/m³ Long-term value: 0.01 mg/m³ as As Ingredients with biological limit values: 7440-38-2 Arsenic (100.0%) BEI (USA) 35 μg As/L Medium: urine Time: end of workweek Parameter: Inorganic arsenic plus methylated metabolites (background) Additional information: No data Exposure controls Personal protective equipment General protective and hygienic measures: The usual precautionary measures for handling chemicals should be followed. Keep away from foodstuffs, beverages and feed. Remove all soiled and contaminated clothing immediately. Wash hands before breaks and at the end of work. Store protective clothing separately. Maintain an ergonomically appropriate working environment. Breathing equipment: Use self-contained respiratory protective device in emergency situations. Recommended filter device for short term use: Use a respirator with type P100 (USA) or P3 (EN 143) cartridges as a backup to engineering controls. Risk assessment should be performed to determine if air-purifying respirators are appropriate. Only use equipment tested and approved under appropriate government standards. Protection of hands: Impervious gloves. Check protective gloves prior to each use for their proper condition. The selection of suitable gloves not only depends on the material, but also on quality. Quality will vary from manufacturer to manufacturer. Material of gloves: Nitrile rubber, NBR Penetration time of glove material (in minutes): 480 Glove thickness: 0.11 mm Eye protection: Safety glasses with side shields / NIOSH (US) or EN 166(EU) Body protection: Protective work clothing. 9. PHYSICAL AND CHEMICAL PROPERTIES Information on basic physical and chemical properties General Information Appearance (Form): Solid in various forms Odor: Odorless Odor threshold: Not determined. pH-value: Not applicable. Change in condition Melting point/Melting range: 817 °C (1503 °F) Boiling point/Boiling range: 614 °C (1137 °F) (subl) Sublimation temperature / start: Not determined Flammability (solid, gaseous): Not determined. Ignition temperature: Not determined Decomposition temperature: Not determined Auto igniting: Not determined. Danger of explosion: Product does not present an explosion hazard. Explosion limits Lower: Not determined Upper: Not determined Vapor pressure at 267 °C (513 °F): 0.01 hPa Density at 20 °C (68 °F): 5.778 g/cm³ (48.217 lbs/gal) Relative density: Not determined. Vapor density: Not applicable. Evaporation rate: Not applicable. Solubility in / Miscibility with Water: Insoluble Partition coefficient (n-octanol/water): Not determined. Viscosity dynamic: Not applicable. kinematic: Not applicable. Other information: No further relevant information available. 10. STABILITY AND REACTIVITY Reactivity: No information known. Chemical stability: Stable under recommended storage conditions. Thermal decomposition / conditions to be avoided: Decomposition will not occur if used and stored according to specifications. Possibility of hazardous reactions: Reacts with strong oxidizing agents Conditions to avoid: No further relevant information available. Incompatible materials: Oxidizing agents, Air Hazardous decomposition products: Toxic metal oxide fume, Arsenic oxides (As2Ox) 11. TOXICOLOGICAL INFORMATION Information on toxicological effects Acute toxicity: Toxic if inhaled. Toxic if swallowed. The Registry of Toxic Effects of Chemical Substances (RTECS) contains acute toxicity data for this substance. LD/LC50 values that is relevant for classification: No data Skin irritation or corrosion: No irritant effect. Eye irritation or corrosion: May cause irritation Sensitization: No sensitizing effects known. Germ cell mutagenicity: The Registry of Toxic Effects of Chemical Substances (RTECS) contains mutation data for this substance. Carcinogenicity EPA-A: human carcinogen: sufficient evidence from epidemiologic
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