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GUIDE TO MATERIALS TOP SEIKO CO., LTD. Application Metals with Tungsten • Filaments for illumination, crucible; high melting • Vacuum furnace for heaters as well as (W) Atomic number: 74 point construction materials; • All kinds of electrodes for discharge lamps, electrical contacts; Properties • Heat screen material, (the highest Melting point (ºC) 3387 TIG welding electrodes; from all metals) • Source components for Thermal conductivity 172 semiconductor ions; ・ (W/(m K)) • Sputtering targets; Thermal expansion (the lowest 4.5 • Balance weight coefficient (×10⁻⁶) from all metals) Specific gravity 19.3 (equal to gold) Carbide: extremely hard (WC) Hardness (Hv) (GPa) 4.2 Young's modulus (GPa) 345 ◇Heat-resistant, high heat conductivity, high specific gravity Molybdenum Application (Mo) Atomic number: 42 • Illumination parts, light bulb filament support wire; • Heaters used in hot water kilns as well as Properties shields; Melting point (ºC) 2623 • Crucible, sinter board; Thermal conductivity 142 • Parts for power devices; (W/(m・K)) • Magnetron parts used in microwave ovens; Thermal expansion 5.3 • Sputtering targets material coefficient (×10⁻⁶) Specific gravity 10.2 Hardness (Hv) (GPa) 2.6 Young's modulus (GPa) 276 ◇Heat-resistant, high heat conductivity Tantalum (Ta) Atomic number: 73 Application • Parts for heat exchanger; • High temperature reactor components; Properties • Source components for semiconductor ions Melting point (ºC) 2990 Thermal conductivity Powder: condenser, target materials; 57.5 (W/(m・K)) Oxide: optical lenses' additive; Thermal expansion Carbide: cemented carbide tool 6.3 coefficient (×10⁻⁶) Specific gravity 16.7 Hardness (Hv) (GPa) 0.7 Young's modulus (GPa) 185 ◇Heat-resistant Niobium (Nb) Atomic number: 41 Application • Iron and steel additive Properties Carbide: cemented carbide tool; Melting point (ºC) 2415 Intermetallic compound: superconducting Thermal conductivity 54 magnet; ・ (W/(m K)) Compound metal: sputtering target material Thermal expansion 7.0 coefficient (×10⁻⁶) Specific gravity 8.6 Hardness (Hv) (GPa) 0.8 Young's modulus (GPa) 107 ◇Heat-resistant Universal Silver Application metal (Ag) Atomic number: 47 • Electric lines (low electric resistance); • Audio cables; • Wiring handling high frequency; Properties • Tableware, jewels, dentist treatment; Melting point (ºC) 960 • Water purifiers (sterilization); Thermal conductivity 420 (W/(m・K)) Can be used as a compound metal Thermal expansion 19.0 coefficient (×10⁻⁶) Specific gravity 10.5 Hardness (Hv) (GPa) 0.9 Young's modulus (GPa) 73 ◇High heat conductivity, high electric conductivity Copper Application (Cu) Atomic number: 29 • Wiring materials for electric appliances; • Electric lines (electric resistance is low and it is cheaper than silver); Properties • Coins, building materials; Melting point (ºC) 1084 Thermal conductivity 398 Can be used as a compound metal brass (W/(m・K)) products etc. Thermal expansion 16.6 coefficient (×10⁻⁶) Specific gravity 8.9 Hardness (Hv) (GPa) 0.8 Young's modulus (GPa) 130 ◇High heat conductivity, high electric conductivity Aluminum (Al) Atomic number: 13 Application • Coins, beverage cans, pots and pans; • Building materials, car parts; Properties • Petrol engines; Melting point (ºC) 660 • Universal machine parts Thermal conductivity 237 (W/(m・K)) Can be used as a compound metal duralumin Thermal expansion etc. 23.2 coefficient (×10⁻⁶) Specific gravity 2.7 Hardness (Hv) (GPa) 0.5 Young's modulus (GPa) 71 ◇Light weight Application Stainless steel • Austenite type: (SUS) steel alloy kitchen equipment, tableware, utensils used in chemical medicine, universal machine parts; Properties • Martensite type: Melting point (ºC) 1450 kitchen knives, Thermal conductivity high-durability quenching machine 16.3 (W/(m・K)) parts; Thermal expansion • Ferrite type: 18.0 coefficient (×10⁻⁶) pots using electromagnetic cooker, etc. Specific gravity 7.9 Hardness (Hv) (GPa) 2.0 Young's modulus (GPa) 200 ◇Corrosion-resistant Alumina Ceramics 1 Application (Aluminum oxide) Al2O3 • Insulators, parts insulating electricity; • Furnace walls, furnace parts, jigs; Properties • Nozzles, spinning tube; Melting point (ºC) 2054 • Reaction crucible, reaction vessels; Thermal Shock • Semiconductor-related parts; 200 Resistance (ºC) • Liquid crystal production parts; Thermal conductivity • Electron tube parts, pumps, 30 (W/(m・K)) grinding materials Thermal expansion 5.3 coefficient (×10⁻⁶) Specific gravity 3.9 Hardness (Hv) (GPa) 18 ◇High intensity, abrasion-resistant, heat-resistant, corrosion-resistant Aluminum nitride Application AlN • Crucible; • Components for heat sink, heat- resistant sheets; Properties • Semiconductor devices' parts: Melting point (ºC) 2200 heaters, ESC, Thermal Shock dummy wafers, 400 Resistance (ºC) susceptor rings, Thermal conductivity shower plates, 160 (W/(m・K)) chambers, Thermal expansion RF-windows 2.4 coefficient (×10⁻⁶) Specific gravity 3.3 Hardness (Hv) (GPa) 13 ◇High heat conductivity Silicon nitride Si N 3 4 Application • Parts for engines; • Gas turbine parts; Properties • Bearing, guide rolls; Melting point (ºC) 1600 • Cutting tools, pulverizer parts; Thermal Shock 650 • Gas burner parts; Resistance (ºC) • Mixing blades Thermal conductivity 13 (W/(m・K)) Thermal expansion 1.5 coefficient (×10⁻⁶) Specific gravity 3.2 Hardness (Hv) (GPa) 16 ◇High intensity, abrasion resistive, thermal shock-resistant Silicon carbide SiC Application • Parts using hot water; Properties • Slide parts: Melting point (ºC) 2730 bearing, Thermal Shock mechanical seals 450 Resistance (ºC) Thermal conductivity DPF components (filters collecting dust) 150 (W/(m・K)) Thermal expansion 2.9 coefficient (×10⁻⁶) Specific gravity 3.1 Hardness (Hv) (GPa) 24 ◇High solidity, high rigidity, high heat conductivity Ceramics 2 Zirconia (Zirconium dioxide) ZrO2 Application • Industrial purposes cutlery; • Scissors, kitchen knife; Properties • Gauges: Melting point (ºC) 2715 pin gauge, block gauge, Thermal Shock 280 wrecking ball; º Resistance ( C) • Various wear resistant parts Thermal conductivity 3 (W/(m・K)) Thermal expansion 7.7 coefficient (×10⁻⁶) Specific gravity 6.0 Hardness (Hv) (GPa) 13 ◇High tenacity, high intensity, abrasion-resistant Boron nitride BN Application • High temperature atmospheric furnace insulator; Properties • Various semiconductors; Melting point (ºC) 2700 • Compound semiconductor crucible; Thermal Shock • Electrical part assembly jigs; 1500 Resistance (ºC) • Heat sinks Thermal conductivity 63 Powder: high temperature lubrication additive, (W/(m・K)) Thermal expansion release agent cosmetic products 1.4 coefficient (×10⁻⁶) Specific gravity 1.8 Hardness (Hv) (GPa) 0.8 ◇High temperature insulation resistance, thermal shock-resistant Silicon Semi-metal (Si) Atomic number : 14 Application Properties • Semi-conductor parts; Melting point (ºC) 1400 • Semi-conductor manufacturing Thermal Shock - equipment parts; Resistance (ºC) • Solar battery Thermal conductivity 148 (W/(m・K)) Thermal expansion 4.2 coefficient (×10⁻⁶) Specific gravity 2.3 Hardness (Mohs) 6.5 Application Glass Quartz glass • Optics: optical lens and prisms, various lasers lenses; Properties • Chemistry: Melting point (ºC) 1700 solvent distilling container, Thermal Shock chemical experiment 1000 Resistance (ºC) equipment; Thermal conductivity • Semi conductor industrial uses: 1.4 (W/(m・K)) CVD, all kinds of furnace tube Thermal expansion for diffusion purposes, 0.5 coefficient (×10⁻⁶) photomasks and etc. Specific gravity 2.2 Hardness (Hv) (GPa) 9 ◇Thermal shock-resistant, low expansion Metal Material Properties Table 1 ※Published data is for reference only Material Metals with high melting point Alloys Heavy alloy Alloy Alloy Sealing alloy Sealing alloy Data Unit Tungsten Molybdenum Tantalum Niobium Titan Heavy metal (W-Cu) (Mo-Cu) (Kovar) (Kovar) (W-) FeNiCo FeNiCo Material symbol W Mo Ta Nb Ti W-Cu Mo-Cu W:90% (sintered) (HIP) ~ ~ ~ Ni:29% Co:17% Fe:53.5% Ni:29% Co:17% Fe:53.5% Component amount [%] 99.9% 99.99% 99.9% 99.99% 99.9% 99.99% 99.8% 99.98% W:89% Cu:11% Mo:65% Cu:35% W:90% Mn:0.3% Si: 0.2% Mn:0.3% Si: 0.2% Density [g/cm3] 19.3 10.2 16.6 8.47 4.54 17.00 9.70 17.0 8.0 8.35 Vickers hardness 1.30(1 type-HB) 1.60(2 type-HB) 1.70 < 3.20(Hv30) Hardness Hv1 [GPa] 4.20 2.60 0.69~1.20 0.50~0.80 2.00(3 type-HB) 3.00 1.60 1.50 2.30(4 type-HB) ※rolled sheet 26(HRC) (load=9.807N) 20℃ [MPa] 207 124 270~410(1 type-RT) > 480 > 280 590 540 540 690 600℃ [MPa] 200(100℃) 340~510(2 type-RT) (Compressive Tensile strength 2.0 800℃ [MPa] 175(200℃) 480~620(3 type-RT) impact value 1000℃ [MPa] 160(250℃) 550~750(4 type-RT) Machining >165(1 type-RT) properties >215(2 type-RT) Yield strength [MPa] 138 85 >345(3 type-RT) 510 270 270 >485(4 type-RT) >27(1type-RT) >15(2 type-RT) Dilation [%] 20 25 >18(3 type-RT) 0.4 35 35 >485(4 type-RT) Flexural rigidity [GPa] 1900 1.4 Young's modulus [GPa] 403 327 185 103 106 330 220 280 159 159 Poisson's ratio - 0.32 0.35 0.38 0.34 Depending on Max. use temp. [℃] 3000 1900 700 and more atmosphere Recrystallization temperature [℃] 1150~1350 900~1200 900~1400 Melting point [℃] 3387 2623 3017 2468 1668 1450 1450 Boiling point [℃] 5527 4827 RT [*10-6/℃] 5.10 5.2(200℃) 5.2(200℃) RT~100℃ [*10-6/℃] 4.5 5.2 7.1 8.4 6.1 8.6 6.0 Linear 5.1(300℃) 5.1(300℃) 4.9(400℃) 4.9(400℃) expansion RT~500℃ [*10-6/℃] 4.6 5.7 3.6 6.4(300℃) 9.2(300℃) 6.2(300℃) 5.3(450℃) 5.3(450℃) Thermal coefficient RT~1000℃ [*10-6/℃] 4.6 5.75 6.7(450℃) 9.6(450℃) 6.2(450℃) 6.2(500℃) 6.2(500℃) properties 5.4(2000℃) RT~1500℃ [*10-6/℃] 6.51 6.0 6.6(3000℃) 20℃ [W/(m・K)] 168 142 17 180 210 90