Passivation (Chemistry)
Passivation (chemistry) For the concept in nonlinear control, see Feedback pas- 2.0 sivation. For the concept in spacecraft, see Passivation 1.6 2- (spacecraft). FeO4 1.2 Fe 3+ Passivation, in physical chemistry and engineering, 0.8 refers to a material becoming “passive,” that is, less af- 0.4 nH O [V] Fe 2O 3 2 fected or corroded by the environment of future use. Pas- 2+ 0 Fe sivation involves creation of an outer layer of shield mate- ε 0 rial that is applied as a microcoating, created by chemical -0.4 Fe O43 Fe(OH) reaction with the base material, or allowed to build from 2 - HFeO2 spontaneous oxidation in the air. As a technique, passiva- -0.8 tion is the use of a light coat of a protective material, such -1.2 Fe as metal oxide, to create a shell against corrosion. Passi- vation can occur only in certain conditions, and is used in 0 2 4 6 8 10 11 14 [1] microelectronics to enhance silicon. The technique of pH passivation strengthens and preserves the appearance of metallics. In electrochemical treatment of water, passiva- Pourbaix diagram of iron.[5] tion reduces the effectiveness of the treatment by increas- ing the circuit resistance, and active measures are typi- cally used to overcome this effect, the most common be- metal, the mechanism of oxygen diffusion through the ing polarity reversal, which results in limited rejection of metal oxide to the parent metal, and the relative chemical the fouling layer. Other proprietary systems to avoid elec- potential of the oxide.
[Show full text]