Electrochemistry Volume 14
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Electrochemistry Volume 14 Published on 03 March 2017 http://pubs.rsc.org | doi:10.1039/9781782622727-FP001 View Online Published on 03 March 2017 http://pubs.rsc.org | doi:10.1039/9781782622727-FP001 View Online A Specialist Periodical Report Electrochemistry Volume 14 Editors Craig Banks, Manchester Metropolitan University, UK Steven McIntosh, Lehigh University, Bethlehem PA, USA Authors N. Alonso-Vante, University of Poitiers, France S. D. Bhat, CSIR Madras Complex, Chennai, India Mary Clare Sison Escan˜o, University of Fukai, Japan Sadia Kabir, University of New Mexico, Albuquerque, NM, USA Y. Luo, University of Poitiers, France Javier Parrondo, Washington University in St. Louis, MO, USA Vijay Ramani, Washington University in St. Louis, MO, USA A. K. Sahu, CSIR Madras Complex, Chennai, India Alexey Serov, University of New Mexico, Albuquerque, NM, USA P. Sridhar, Mesha Energy Solutions Pvt. Ltd., Bengaluru, India Lihui Wang, Illinois Institute of Technology, Chicago, IL, USA Zhongyang Wang, Washington University in St. Louis, MO, USA Published on 03 March 2017 http://pubs.rsc.org | doi:10.1039/9781782622727-FP001 View Online Print ISBN: 978-1-78262-114-0 PDF eISBN: 978-1-78262-272-7 ePUB eISBN: 978-1-78801-150-1 ISSN: 0305-9979 DOI: 10.1039/9781782622727 A catalogue record for this book is available from the British Library r The Royal Society of Chemistry 2017 All rights reserved Apart from fair dealing for the purposes of research or private study for non-commercial purposes, or for private study, criticism or review, as permitted under the Copyright, Designs and Patents Act, 1988 and the Copyright and Related Rights Regulations 2003, this publication may not be reproduced, stored or transmitted, in any form or by any means, without the Published on 03 March 2017 http://pubs.rsc.org | doi:10.1039/9781782622727-FP001 prior permission in writing of The Royal Society of Chemistry, or in the case of reproduction in accordance with the terms of the licences issued by the Copyright Licensing Agency in the UK, or in accordance with the terms of the licences issued by the appropriate Reproduction Rights Organization outside the UK. Enquiries concerning reproduction outside the terms stated here should be sent to The Royal Society of Chemistry at the address printed on this page. Published by The Royal Society of Chemistry, Thomas Graham House, Science Park, Milton Road, Cambridge CB4 0WF, UK Registered Charity Number 207890 For further information see our web site at www.rsc.org Printed in the United Kingdom by CPI Group (UK) Ltd, Croydon, CR0 4YY, UK Preface DOI: 10.1039/9781782622727-FP005 We are happy to introduce volume 14 of Specialist Periodical Reports in Electrochemistry which presents comprehensive and critical reviews with a thematic discussion of recent progress in electrolytes and elec- trocatalysts for fuel cells. In this volume, Escan˜o provides an in-depth review of recent density functional theory studies of borohydride electro- oxidation on metal electrodes that provide new insights the composition and structural dependence of this critical reaction for direct borohydride fuel cells. Continuing with the theme of emerging types of fuel cell, Ramani and co-workers review the most recent advances in anion exchange membranes with insights into both the most promising com- positions and identifying the critical material requirements. This is complemented by the excellent review of anode electrocatalysts for direct alcohol anion exchange membrane fuel cells authored by Kabir and Serov. They focus their review on the critical need to understand how the complex interactions between structure, composition and physico- chemical properties of the catalysts dictate the electrode performance. The goal of direct alcohol utilization within fuel cells is further discussed by Sridhar and co-authors who discuss the recent progress in developing both polymer electrolytes and electrocatalysts for proton conducting direct alcohol fuel cells. Finally, Luo and Alonso-Vante have authored an insightful discussion of the application of metal organic frameworks (MOFs) in fuel cell electrocatalysis where they can play the role of electro- catalytic centers, electrocatalyst supports, or as electrocatalyst precursors. Steven McIntosh Published on 03 March 2017 http://pubs.rsc.org | doi:10.1039/9781782622727-FP005 Electrochemistry,2017,14,v–v| v c The Royal Society of Chemistry 2017 Author biographies DOI: 10.1039/9781782622727-FP006 Nicolas Alonso-Vante is Professor at the University of Poitiers. He has developed materials based on transition metal and chalcogenides in metallic and semiconduct- ing form in Germany and France for photo- electrocatalytic processes. He has pioneered the use of non-platinum and non-precious metal catalysts center chalcogenides, using facile chemical routes, in order to under- stand, e.g., the complex process of the oxygen reduction reaction process, in low tempera- ture fuel cells. He has received the awards of the Alexander von Humboldt foundation fellowship, of the National Polytechnic Institute-Mexico as a R&D dis- tinguished graduate, and of the Mexican Council of Technology SNI-III recognition as a Mexican researcher working outside Mexico. Dr Santoshkumar D. Bhat is a Senior Scien- tist at CSIR-Central Electrochemical Research Institute, Madras Unit, CSIR Madras Com- plex Chennai, India. His research interests are on polymer membrane electrolytes for fuel cells. In particular, he has developed new polymer electrolytes for restricting the Published on 03 March 2017 http://pubs.rsc.org | doi:10.1039/9781782622727-FP006 methanol cross-over in direct methanol fuel cells. He has also worked on new electro- catalyst support for oxygen reduction reaction in polymer electrolyte fuel cells. He has contributed towards the development of low temperature fuel cell stacks for stationary applications. He is also interested in developing wick based humidifi- cation techniques for polymer electrolyte fuel cells. He has 60 international publications and 2 patents to his credit. vi | Electrochemistry,2017,14,vi–x c The Royal Society of Chemistry 2017 View Online Dr Mary Clare Escan˜o is currently a tenure- track assistant professor at University of Fukui, Japan. She received her PhD in 2012 from the Department of Applied Physics, Osaka University, Japan. Dr Escan˜owasa Young Scientist Fellow of the Japan Society for the Promotion of Science (JSPS) for three years and is a multi-awarded early career researcher. She holds two masters degrees in experimental and theoretical applied physics and has published more than 30 original articles in high reputable journals. Her research interest involves interdisciplinary studies bridging magnetism and catalysis on metals. Sadia Kabir is a PhD candidate in the Department of Chemical and Biological Engineering at the University of New Mexico. In 2013, she received her Masters in Chem- ical Engineering from UNM while working on characterizing the structure–property relationships of nitrogen-functionalized nano- materials using a synergistic combination of computational and spectroscopic techniques. Currently, Sadia’s research is primarily focused on developing and integrating hierarchically structured nanocomposite materials for fuel cells applications; she has 7 peer-reviewed journal publications in the field. Sadia is also involved in several energy- conversion related projects in collaboration with Los Alamos National Published on 03 March 2017 http://pubs.rsc.org | doi:10.1039/9781782622727-FP006 Laboratory, Daihatsu, and the University of Utah. Yun Luo, born in China in 1984, Yun Luo obtained her MS of analytical chemistry at Sichuan University in 2005 on fluorescent probe, received her PhD in 2012 on porous and luminescent Ln-based MOFs in INSA- Rennes, France. From 2012 to 2013, she worked as post-doc on photo-electroreduction of CO2 and silicon surface grafting at University of Rennes 1. In 2013, she joined Prof. N. Alonso-Vante’s group at the University of Poitiers for a European project (Cathcat) on nanomaterials for oxygen reduction reaction and low-temperature fuel cell. Her research interests are focused on coordination polymers, solar fuels and electrocatalysis. Electrochemistry,2017,14,iv–x| vii View Online Javier Parrondo is a Research Scientist in the Department of Energy, Environmental and Chemical Engineering at Washington University in Saint Louis, Missouri. He received both his BSc and his PhD in Chemical Engineering from the University of Oviedo, Spain. He was working as Assistant Professor at the University of the Basque Country in Bilbao, Spain and as Research Associate at Illinois Institute of Technology, Chicago, Illinois. He is interested in the development of new catalysts and anion exchange membranes for alkaline mem- brane fuel cells, solid-state alkaline water electrolyzers and redox flow batteries. Vijay Ramani holds the Roma B. and Raymond H. Wittcoff Professorship in the Department of Energy Environmental and Chemical Engineering at Washington Uni- versity in St. Louis, and concurrently serves as the Director of the Center for Solar Energy and Energy Storage at Washington University. His research interests lie at the confluence of electrochemical engineering, materials science, and renewable energy technologies. Current research directions in his group include multi-functional electrolyte and electrocatalyst materials for electrochemical systems, mitigating component degradation in electrochemical devices, Published on 03 March 2017 http://pubs.rsc.org