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Large scale Variscan granitoid intrusion throughout : a lateral geochronological trend? K. Oud BScThesis,FacultyofEarthSciences,UtrechtUniversity,July2006 Abstract LargescalegranitoidintrusionduringtheVariscanorogeny(370to250Ma)inEurope abovesubductionzonesofthattimeisassumedtobetheresultofaheatpulseduetoslab detachment. This would show from a lateral trend in age of emplacement of all granitic bodies,migratingthroughthecompleteVariscanfold belt, and thus, a younging direction perpendicular to the former subduction zones. To test this, an inventory of intrusion ages (onthebasisofUPb,RbSrandKAranalysis),typology(IorStype)andlocationof70 granitic bodies in the European Variscan fold belt, from the Armorican to the BohemianMassif,wasmade.Fromthecollecteddata,nolateraltrendinageisobserved. However,atrendinageparalleltoformersubductionzonesisshowninmostmassifs,with a younging direction towards the thrusting vergence. This is probably the result of nappe stacking. In the Armorican Massif and Massif Central, are all Stype, which is probablythecauseofcontinentalsubduction.IncentralEurope,thetypologyismixedS andItype,whichcanbecausedbysubductionofeithercontinentaloroceaniclithosphere. 1. Introduction result of the ‘usual’ heat and melt generation attributed to subduction The Variscan orogeny yielded a large processes. However, there is another numberofgranitoidintrusionsthroughout possibility of emplacement that all of the European Variscides. In all canbeconsidered,whichisnotcommonly orogenic events like subduction and mentioned in related studies. During the continentalcollision,thecrustandmantle final stages of subduction, the subducted aresubjectedtoextremetemperatureand slab may breakoff and sink into the pressure conditions; thermal pulses astenosphere. This is called slab caused by such conditions are abundant. detachment(fig.1)[WortelandSpakman, These often result in heating of the crust 2000]. during burial, or decompression during lateorogenic extension, and the subsequent melting of the crust and/or mantlewhichproduces(granitic)magmas that intrude into the middle and upper crust. It has been shown that granitic magmas can have a rather varying ? composition, which means a derivation from differing source regions and source rocks [Chappell and White, 2001]. Therefore,theoccurrenceofgranitesinan orogenic belt is a reflection of its tectonothermal evolution and its deep structuresandprocessesthataretheleast accessible and the worst exposed [Finger etal,1997]. The massive occurrence of granites throughout the Variscan fold belt gives rise to the assumption of a large scale Fig. 1 . Slab detachment with possible thermal pulse along the entire Variscan granitic intrusion (indicated by the ‘?’). After . It is possible that this is just the WortelandSpakman,2000.

1 Whena‘cold’slabdetaches,itcanbe From previous studies concerning replaced by hot astenospheric material Variscan granites, I listed the ages of that creates a heat pulse underneath the intrusion from the granitic bodies, aiming overlying plate, which may cause to use the most reliable dating method magmatism [Wortel et al, 2003]. As is available. On the basis of geochemical shown by Wortel and Spakman [2000], information of the bodies involved, I slabdetachmentcantakeplaceduringthe determined whether they can be last stages of an orogeny, after ocean considered an Itype or Stype. All those closure and continent collision. With this datawillbeplottedinageologicalmapof process, the chance of breaking of the Europeandwiththis,itwillbepossibleto slab along the entire plate boundary at seewhetherthereisatrendintheageof oncewouldbeverysmall.Rather,theslab intrusion or not and thus, if the intrusion wouldstarttobreakatasmallareawhere ofgranitesisthepossibleresultofaheat applied stresses would overcome the pulsefromslabdetachment. strength of the plate segment. This fracture would then start to extend and migrate laterally along the plate 2. Geological and tectonothermal boundary.Consequently,onecouldexpect background a similar lateral trend in the related heat pulseandgraniteemplacement,shownin The Variscan orogeny resulted from the crust above. Because it is shown by thecollisionofEuramerica(i.e.Laurentia, tomography [Bijwaard et al, 1998] that Baltica and ) and Gondwanaland the Variscan subducting slabs are no () which began in early Palaeozoic longer present under Europe, they must time (from 480 Ma, fig. 2). It meant the have detached. It is suggested by Franke subductionofapartofthelattercontinent [2000]thatatleastatsomeplacesinthe under Euramerica. The suture was Variscan belt, subducting slabs broke off completed during the late with subsequent rising of astenospheric /early(250Ma)and materialandformationofgraniticmelts. formed the This paper aims to test whether the [Stanley,1999]. large scale granite intrusion during the ThenorthernmarginofGondwanaland Variscan orogeny was caused by a heat was very fragmented and the collision pulse from slab detachment. For this area was therefore composed of purpose,Imadeaninventoryoftheages continental microplates, separated by a and typology of the granitic intrusions in system of ridges and troughs, basins and the Variscan massifs in Europe, from the oceanic rifts [Pin, 1990b]. These ArmoricantotheBohemianMassif. were the origin of the European

Fig. 2. Schematicmapshowingthe worldanditscontinents,microplatesandoceansduringMiddle (fromScotese[2003]).

2 Variscan fold belt; they drifted northward southern margins of the Rheinisches from Gondwanaland, colliding with the Schiefergebirge and the . The basin northern continents. This is shown in wasclosedduringtheEarlyCarboniferous. several zones by the occurrence of thick The Variscan collision yielded large sequences of marine sediment and small scale (thinskinned) nappethrusting and but extensive occurrences of eclogites, (thickskinned) crustal stacking and the originated from MORbasalts which show Precambrianoftheridgesfused thattheriftingatleastmusthavereached with thick layers of sediment and ocean anarrowoceanstage[Franke,1989]. floor of rift basins from Early Palaeozoic There are several hypotheses about time. The thrusting caused large scale theexactcompositionandevolutionofthe Barroviantype (medT/medP) regional microplates involved in the suture, but , most extensive in the geological and palaeomagnetic evidence interior of the Moldanubian zone. During indicates that the two largest terranes, thelateEarlyCarboniferoustheprocessof Avalonia and , were the nappestacking stopped because of foundationsoftheVariscanfoldbelt. dextralwrenchingofrelativeto These microplates are said to be Euramerica, which in turn led to dextral composedofseveralsmallerterranes[Tait transpressional and transtensional et al, 1997] and are believed to be tectonics [Arthaud and Matte, 1977]. attached to Baltica and Laurentia before During this process, large parts of the thelargecollisionbetweenGondwanaand Moldanubianzonewereaffectedbysevere Euramerica.Also,twooceanicbasins highT/lowP metamorphism. Also, the – each consisting of several smaller antiparallel subducted mantleslabs oceanic basins – are recognized: the possibly joined and became detached, Iapetus ocean between Avalonia, Baltica which caused the rise of astenospheric and Laurentia and the Rheic ocean material and therefore a large scale between Avalonia and Gondwana [Matte, intrusionofposttectonicgranites[Franke, 2001]. Closing of the first caused the 2000] (fig. 3, the red areas in the Caledonian orogeny in western and massifs).Thishypothesiswillbetestedin northern Europe during middle Silurian to thispaper. early (430 Ma to 370 Ma). The During the Late Carboniferous and Variscan orogeny was caused by the Permian, postorogenic uplift and closureoftheRheicOcean. extension of the Variscan crust occurred. The generally believed theory for the In the Late Carboniferous, along the compositionoftheEuropeanVariscanfold southern margins of the fold belt, there belt is that it consists of two large might have been some renewed subduction zones which originated before subduction of oceanic crust and accretion the collision in the ridgetrough system of terranes, which had sheared of from described above. A southern, northward Gondwanaland while this was drifting dipping system by which the Massif westward. However, it is not clear what Central and intraAlpine oceans were their exact relationship was before these closed(theMoldanubianzone,fig.3)and terranes were deformed by the Alpine more to the north a southward dipping orogeny in the Mesozoic and Tertiary system which led to the closure of the [Fingeretal,1997]. Saxothuringian and Rhenohercynian basins. This closure began during late to early Devonian time, first 3. Granitoids involving oceanic crust, followed by subductionofcontinentalcrustduringthe 3.1 Intrusion

Late Carboniferous. Contrasting with this Granite intrusions occur when heat or convergence is the opening of the water is added to the mantle or crust – Rhenohercynian basin during the having various geodynamic causes such Devonian.Thisispossiblycausedbyback thatitmeltsandrisestointrudeshallower arc spreading due to the northward crust. Granitic melts (magmas) can be subduction of oceanic crust further to the formed either through the addition of south [Franke, 1989]. Traces of the volatiles (i.e. water) in the mantle, openingofthisbasincanbefoundatthe decompressionofthecrustormantleor

3 Fig. 3. Map showing the main geological and tectonic units of the Variscan fold belt in Europe (afterFranke,1989;Fingeretal,1997).AM:ArmoricanMassif,MC:MassifCentral,RS:Rheinisches Scheifergebirge,H:Harz,O:Odenwald,V:,SW:Schwarzwald(BlackForest),BM:Bohemian Massif. heat transfer from rising magma rocks (Itype) [Chappell and White, [Marshak, 2001]. When hydrated crust, 2001].Partialmeltingofmetasedimentary e.g. marine sediments, is buried during source rocks is a process called anatexis subduction it is heated rapidly and or ultrametamorphism. Igneous source dehydrates, which causes melting of the rocksthathavenotbeenweatheredatthe rock. Extending the crust causes rapid surface can produce Itype granitoids, pressure decrease, while the temperature which also can be created from crystal can remain equal. This decompression fractionation of magmas. A third type of leadstomeltingoftherock,asisalsothe granite is recognized by Loiselle and casewithheatingofthecrustbyasimple Wones[1979],whichisrelatedtomantle increase in temperature, for example by plumes and is thus called Atype heat transfer from rising magma in the (anorogenic). surrounding crust. Another form of Indeterminingwhetheragranitebody decompression melting can be caused by can be considered Stype or Itype, slab detachment. When a portion of a several methods are used. This often can subductingslabbreaksaway,itsinksinto be difficult, because the boundaries the mantle and the overlying portion of between the two are not always very the crust is suddenly exposed to a heat precise. Granites can be distinguished by pulse from the mantle which rises to their chemical composition and mineral replace the ‘cold’ slab and, as a content. Also, some workers use field consequence, may melt because of criteria,butthosewillnotbeusedinthis decompression[Worteletal,2003]. paper. Itype granitoids are rich in sodium and calcium, which is characteristic for a 3.2 Typology and classification largeinputfromthemantleorlowercrust, whereas Stypes are Napoor and rich in A subdivision made in 1974 by aluminium, which results from a large Chappell and White for classification of inputfrommetasedimentaryrocksandare granitesisnowcommonlyconsideredasa thus crustderived. These chemical goodmeasureanddistinguishestwotypes propertiesofStypegranitoidsaredueto of granites. These are the result from the fact that during sedimentary partialmeltingofdifferentkindsofsource fractionation, Na is removed into sea rocks: (meta)sedimentary source rocks water (and evaporates) and Ca into (Stype) and older, preexisting igneous carbonates, which means a relative

4 enrichmentinAlinthemainsedimentary primitive igneous rocks. Stypes typically stack. In this paper, the molar have a δ 18 O ratio higher than 9‰,

Al 2O3/(Na 2O+K 2O+CaO) ratio is used a whereasItypeshaveavaluethatislower few times. For Itypes, this ratio is less than 9‰, which gives a very clear than 1.1, whereas for Stypes itislarger distinction[O’NeillandChappell,1977]. than 1.1. This is logical because of the Itype and Stype granitoids are also highAlandlowNacontentinsedimentary characterised by different mineral rocks. assemblages, because of their differences Furthermore,becausesedimentisrich in source material. The most important inSiO 2,Stypegranitoidshavealsoahigh difference is the absence of muscovite in SiO 2 content – between 65% and 74% Itypes and its presence in Stypes. which means they are more felsic in HornblendeisgenerallypresentinmostI composition and are usually light types,butisabsentinmorefelsicStypes coloured.ItypesarelowerinSiO 2content [ChappellandWhite,2001]. –53%andhigher–andhavethereforea composition which ranges from felsic to mafic, being granitic to tonalitic, and are 3.3 Tectonic setting consequently richer in Mg and Fe and darker in colour. Granitoids that contain BothItypeandStypegranitoidsform less than 65% SiO 2 can be considered to in subduction settings, wherein Stypes beItype[from‘Granites’]. occur as a result of melting of the higher Also very important are various crust (supracrustal) and Itypes from isotopic compositions, wherein Sr 87 /Sr 86 meltingofthelowercrustandhighmantle ratios, εNd values and oxygen isotopic (infracrustal)[from‘Granites’].In‘normal’ ratios are the most important for continental collision, i.e. the suture classificationofgranitoids.Itisshownthat betweentwocontinentalplates,mostlyS in Stype granitoids, strontium is more types occur because of thickening of the radiogenic [Chappel and White, 2001], continental crust, which yields higher with initial Sr 87 /Sr 86 ratios of 0.708 to temperatures and thus melting of the 0.720. Itype granitoids give initial crust (fig. 4a). In subduction settings Sr 87 /Sr 86 ratiosof0.704to0.712.Ascan whereinoceaniccrustisinvolved,moreI be seen, there is a significant overlap type granitic intrusions occur. This is between the initial isotopic compositions because the subduction of oceanic crust of the S and Itype, which makes yields metamorphosis of the subducting distinction sometimes difficult. Isochron slab, which results in the release of plotsgivearegularlinearsetofpointsfor volatiles in it, and melting of the lower Itype granitoids while for Stypes, the lithosphere above it as a consequence of points are scattered over a large area. heattransfer.Thiscausestheformationof This variation in initial Sr 87 /Sr 86 ratios more Itype granitoids (fig. 4b), together withinasingleigneousbodywouldbethe withStypes.Magmaticunderplatingasa result from a heterogeneous source result of slab detachment generally material[ChappellandWhite,2001]. produces Itype granitoids. This is Another ratio that is often used in because the hot mantle material that related papers are Neodymium isotopic replaces a cold slab melts because of values.TheseareexpressedasεNd,which decompression. is the deviation of the 143 Nd/144 Nd ratio Postorogenic collapse is often related fromitspresentdayaveragevalueinthe toslabdetachment.Aftertheformationof earth. For Itype granitoids, εNd ranges an orogenic belt, either compression from +3.5 to 8.9 and for Stypes it ceases or the slab slowly detaches. This ranges from 5.8 to 8.8. For this paper, results in extension and collapse of the the εNd ratio is not used very much, crust, thinning of the lithosphere and becausetheoverlapisoftentoolargefor subsequent rise of the asthenosphere, determining the type of granite. In which cause decompression melting and contrast, the δ 18 O ratio of granitoids is meltingfromtheincreasedheatflux.Both usedquiteoften.Theδ18 OratioofStype postorogenicStypeandItypegranitoids andItypegranitoidsreflectsthefactthat are produced by this tectonic setting (fig. sedimentary rocks are richer in O 18 than 5).

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Fig. 4a and b. The formation of Stype granitoids in continentcontinent collision and of Itype granitoidsinoceancontinentcollision.From‘Granites’. Fig. 5.Theformationofgranitoidsasaresultofpostorogeniccollapseofanorogenicbelt.From ‘Granites’. 4. Dating methods the ratio between present parent and daughter isotopes and by calculating the In determining the age of time needed to produce that ratio. emplacement of a granitic body, several Complications occur when the amount of dating methods are commonly used, all daughter isotopes is not zero from the based on the radioactive decay of certain start. This amount is always calculated isotopes present in minerals in the rock. carefully, mostly by determining the Radioactive isotopes (parent isotopes) differentamountsofparentanddaughter decay to daughter isotopes at a certain isotopes present in different minerals in rate per year. Every isotope has a therockandbycomparingthose. constant and characteristic rate, Agesofgraniticintrusionsinthispaper expressed as its half life: the time at werebasedmostlyondatingbyUranium whichhalfoftheamountofparentisotope Lead and RubidiumStrontium methods. hasdecayedtoitsdaughterisotope. PotassiumArgon and ArgonArgon were In slowly cooling igneous bodies, like used only in case of lack of one of the granites, various minerals start to formerdatingmethods,becausetheyare crystalllize at various temperatures. This less accurate for this purpose; they closuretemperature(i.e.thetemperature measure cooling temperatures which are at which isotopes do not exchange freely somewhat too low for cooling granites between minerals in the fluid anymore; [Begemannetal,2001;Minetal,2000]. theybecomelockedinthemineral)isthe Radiometricdatingbasedonthedecay start of the radioactive decay of the of 238 U and 235 U to 206 Pb and 207 Pb, isotope and thus the start of the dating respectively, nowadays gives the most clock [Bennington]. Knowing the decay reliable result. It is one of the earliest rateofanisotopeallowsonetodetermine methods, and hence, its decay constants the age of crystallization of the involved are intensively studied, particularly in mineralandthus,toacertainextent,the zircon. The occurrence of this mineral in ageofintrusionandcoolingofanigneous felsicigneousrocksiswidespreadanditis body. Granitic intrusions start to extremely resistant to isotopic resetting crystallizeatabout800 oCorlower[from (the resetting of the radioactive clock ‘Bowen’s reaction series’ (BRS)]. The age through a reheating event like oftheintrusionismeasuredbycalculating metamorphism) [Begemann et al, 2001].

6 Thisisbecausetheclosuretemperatureof data was available, ages from RbSr and zircon is around 850±50 oC [from ‘BRS’], KAr analysis were taken. The ages and whichmakesittheperfect representation characteristics of all granites are given in forthecoolingageoftheigneousbodyin Table1. which it is present. A problem occurs In two geologic maps that cover the when the zircon originates from an older area, all Variscan graniticintrusions were granitefromwhichtheclockhasnotbeen indicated. A division in age was made, reset. This would give much older ages. indicated with different colours, which However, taking more samples and differs slightly from the division made by compare their ages will reduce the effect Finger et al [1997], because this gives a ofthisrisk. clearer overview. The intervals were The decay of Rubidium87 to chosenbetween370and330Ma,330and Strontium87 is mostly measured from 300 Ma and 300 Ma and younger. With hornblende, biotite and muscovite, which this division plotted indifferent shades of have closure temperatures of about 700 pink(thelighter,theyoungerthegranite) oC, 600 oC and 500 oC, respectively ontheintrusionsinthemap,itturnedout [‘BRS’]. 87 Rb/87 Sr analysis is because of to be more clear and easier to determine these lower closure temperatures a trend. Bodies of unknown age are somewhat less accurate than UPb plottedinblue.Theageofintrusionisalso analysis. indicated on the map, together with its 40 K/ 40 Ar and 40 Ar/ 39 Ar dating are the uncertainty interval. These are indicated least accurate of the three. This is for a with green or red, in which green stands major part because there is much for Itype and red for Stype, which discussion about the exact decay makes it possible to see if this division constantsof 40 Kand 40 Ar.Also,theclosure also shows a trend. Granitic intrusions temperature from the used minerals is from whichitis not certain whether they relatively low for the cooling of a granitic can be considered as I or Stype have body. Biotite and muscovite are used the agesindicatedinblue. most,togetherwithKfeldspar,whichhas a closure temperature of about 500 oC. Anotherimportantremarktothismethod 5.1 and Vendée is the fact that Ar is a gas and is thus presentintheformofbubblesintherock. From the Armorican Massif and the It can be quite easy for a gas to escape Vendée area southwest of it, 15 data from the original rock to other rocks or pointswereobtained(fig.6).Alltheages the atmosphere, which means that the of granites from the Vendée area were ratioofparentanddaughterisotopescan determined on the basis of KAr analysis. be changed, and not only by decay of In the Armorican Massif, ages were parentisotopes[Bennington]. obtained through RbSr analysis. Here, Variscan granites intruded particularly in the south, in the north most granitic 5. Data analysis bodies intruded during preVariscan time (the early Palaeozoic and Precambrian), A total of 70 data points in granites butoneVariscanbodyisclearlypresentin wascollected,40intheArmoricanMassif, thenorth.AllgranitesareStypes,butin Vendée,MassifCentralandVosgesand30 the Vendée, the typology is not clear. In in the Black Forest, Odenwald, Harz and age, a rather clear trend can be seen. It theBohemianMassif,whicharemostlyin shows a younging direction to the the Moldanubian and, to a lesser extent, southwest, over the whole width. intheSaxothuringianzone(figs.6to9). Remarkable is the fact that the age of The Rhenohercynian does not have any intrusion runs parallel to the subduction Variscangraniticintrusions,exceptforthe zoneoftheMassifCentralsuture.Northof Brocken granite in the Harz. From each this range, there are a few granites that granitic body considered, its age and havenodeterminedageortype.Northof typology were determined. For as far as thatisthePloumanac’hgranite,whichlies possible,agesobtainedonthebasisofU directlyontheformersouthward Pbanalysisweretaken,butwhennoUPb

7 # name lat lon type age err (+/- dating reference (N) (E) (Ma) Ma)) method 1 Odenwald 4959 846 I 369 5 KAr Todt(1995) 2 StareSedlo/Mirotice 4931 1418 I 373 5 UPb Kosler(1993) 3 Sazavasuite 4949 1444 I 350 12 UPb(E) Holub(1997) 4 Leuchtenberggranite 4938 1217 I/S 342 6 UPb Kohler(1996),Behrmann (1997),(Siebel(1995a)) 5 Falkenberggranite 4950 1216 S 311 4 RbSr Siebel(1995a),Wendt (1989) 6 Mitterteichgranite 4955 1214 S 310 6 RbSr Siebel(1995b),Siebel (2003) 9 Weinsberggranite 0 0 I/S 318 4 Finger(1995) 10 Leuchtenberggranite 4947 1212 I/S 325 2 RbSr,Pb Siebel(1995a),Siebel Pb (2003) 11 Rastenberger 4835 1520 I 338 2 UPb Klotzli(1996),Vellmer granodiorite (1994) 12 Schardinggranite 4828 1341 S 319 6 UPb Finger(1997),Frasl (1991) 13 Eisgarngranite 4858 1506 S 327 4 UPb Vellmer(1994),Frasl (1991) 14 Malsburggranite 4745 746 I/S 328 6 UPb Schaltegger(2000),Todt (1976) 15 St.Blasiengranite 4746 806 I/S 333 2 UPb Schaltegger(2000) 16 Barhaldegranite 4750 808 S 332 3 UPb Schaltegger(2000) 17 Albtalgranite 4739 804 I/S 334 3 UPb Schaltegger(2000) 18 Oberkirchgranite 4829 802 I/S 320 5 RbSr Hoefs(1983) 19 Forbachgranite 4843 824 S 293 3 RbSr vonDrach(1974) 20 Triberggranite 4813 816 S 325 6 UPb,Rb Schleicher(1994) Sr 21 Karkonosze/Reichenber 5048 1508 I 328/3 12/14 RbSr/U Oberc(2005),Kroner ggranite 04 Pb(E) (1994) 22 Brockengranite 5146 1040 A 295 3 UPb Baumann(1991) 23 Eibenstock 5028 1238 S 297 8 UPb Kempe(2004) SHRIMP 24 Kirchberg 5037 1228 I/S 330/3 5/7 UPb/Rb Kempe(2003),Forster 10 Sr (1999) 25 G1 5005 1202 I/S 325/3 /14 RbSr Irber(1997),Besang 10 (1976) 26 G2 5010 1200 S 305/2 /7 RbSr Irber(1997),Besang 91 (1976) 27 G3 4958 1150 S 305/2 /4 RbSr Irber(1997),Besang 88 (1976) 28 G4 5001 1150 S 290/2 /6 RbSr Irber(1997),Besang 85 (1976) 30 Bor 4946 1246 I/S 332 8 UPb Siebel(1997) 31 Rozvadov 4940 1240 S 304 19 RbSr Siebel(1997) 32 Karlsbad/KarlovyVary 5010 1256 I 303 7 ? Cathro(2005) batholith 33 Meissen 5111 1330 I 328 8 U/Pb Nasdala(1999),Wenzel (1997) 34 (Molkenrain) 4749 706 338 5 U/Pb Schaltegger(1996) 35 Ballonsgranite 4749 654 I 340 3 U/Pb Schaltegger(1996) 36 NorthernVosgesgranite 4822 711 I 331 5 U/Pb Schaltegger(1997) 37 Bornegranite 4428 400 310 10 U/Pb Talbot(2004) 38 Velaygranite 4441 416 301 5 U/Pb Ledru(2001) 39 Margeridegranite 4445 332 S 323/3 12/7 RbSr/U Ledru(2001), 34 Pb 40 Roclesgranite 4429 410 318 3 U/Pb BeMezeme(2006) 41 MtLozere 4427 340 S? 285 15 RbSr Vialette(1977) 42 Tournon 4457 454 337 13 Rb/Sr Ledru(2001) 43 StSylvestre 4613 133 S 324 4 UPb Turpin(1990) 44 Gueret 4615 151 S 355 10 RbSr Turpin(1990) 45 Millevaches 4602 149 S 345 12 RbSr Turpin(1990) 46 Luzygranite 4649 404 S 300 4 RbSr Rolin(1991) 47 Settonsgranite 4708 417 340 5 RbSr Rolin(1991) 48 Lormes/PierrequiVire 4718 404 S 324 8 RbSr/U Rolin(1991),Duthou granite Pb (1984) 49 ChateauChinongranite 4706 354 301 7 U/Pb Rolin(1991),Carpena (1984)

8 50 Usselgranite 4525 225 S 327 3 RbSr Vialette(1973) 51 Echassieresgranite 4613 259 312 8 RbSr Faure(2002) 52 PouzolServantgranite 4608 258 330 9 RbSr Faure(2002) 53 StGervaisgranite 4602 250 349 8 RbSr Pin(1990a) 54 AigoualStGuiralLiron 4404 335 S 285 5 RbSr Sinclair(1993) granite 55 BoisNoirsMadeleine 4558 344 S 330 10 RbSr Pin(1990a),Vialette StJulienlaVetre (1973) 56 Blond 4603 57 S 318 13 UPb Alexandrov(2002) 57 Crevant 4631 153 S 312 Rb/Sr Pin(1990a) 58 StDier 4540 330 S 330 RbSr Pin(1990a) 59 Ploemeurleucogranite 4743 324 S 304 6 Rb/Sr BernardGriffiths(1985) 60 Liziogranite 4752 237 S 338 13 Rb/Sr BernardGriffiths(1985) 61 PontivyRostrenen 4801 315 S 344 8 Rb/Sr BernardGriffiths(1985) granite 62 PointduRazgranite 4802 435 S 310 20 Rb/Sr BernardGriffiths(1985) 63 Quimpergranite 4759 410 S 318 7 Rb/Sr BernardGriffiths(1985) 64 Questembertgranite 4742 235 S 329 21 Rb/Sr BernardGriffiths(1985) 65 Pontl'Abbegranite 4752 416 S 305 6 Rb/Sr BernardGriffiths(1985) 66 Sarzeaugranite 4731 250 S 300 10 Rb/Sr BernardGriffiths(1985) 67 Ploumanac'hgranite 4847 328 S 290 10 68 LesCerqueuxde 4656 42 309 K/Ar Ries(1979) Maulevrier 69 Poiroux 4630 127 296 K/Ar Ries(1979) 70 StAubinleCloud 4638 22 321 K/Ar Ries(1979) 71 LesClouzeaux 4633 116 297 K/Ar Ries(1979) 72 Noirlieu 4654 30 328 K/Ar Ries(1979) 73 L'Ecarpiere 4701 107 306 K/Ar Ries(1979) Table 1 . Ages and characteristics of all listed granites. Numbers correspond to numbers on the maps. Another possible trend in intrusion age can also be seen. This is in the southern line of granites of the Armorican Massif. Granitebodiesinthislinerangegradually from310Mainthenorthwest,to300Ma in the southeast, thus, perpendicular to thesubductionzone. 5.2 The Massif Central exposes much of the Variscan basement dominated by granitic intrusions. It yielded a list of 22 granites (fig. 7). More than half of the ages of those were obtained on the basis of RbSr analysis, some in combination withUPbdata(Table1).Forninegranitic bodiesitwasnotpossibletodetermineits type, however, the largest part of the otherintrusionsturnedouttobeStype. As can be seen in the map, older Fig. 6. Variscan granitoids with age of granites appear somewhat in the middle intrusionandtypeintheArmoricanMassifand oftheMassifCentral,asyoungergranites Vendée.Scale1:4100000. appear more towards the edges. The youngest intrusions, again, are in the south.Inthe(south)westernand–eastern subduction zone north of the Armorican rimsarequitesomeintrusionsthathave Massif. nodeterminedage.However,forthe

9 Fig 8. Age and type of intrusions in the Vosges,BlackForestandOdenwald.Scale1: 5100000. west to east directed younging trend can be seen in the two areas together, as in theArmoricanMassif.Thenorthandsouth Fig. 7. Age and type of granitic intrusions of both areas are bounded by the two intheMassifCentral.Scale1:4100000. former subduction zones that define the Moldanubianzone. actual data available, there is, as in the The Odenwald lays just south of the Armorican Massif, a general trend in suture zone between the Rhenohercynian younging direction shown parallel to the and Saxothuringian zone. It only yields MC suture. There are a few exceptions; one data point, from which the age is i.e. in the southeast and northeast. Here based on KAr analysis. This lies too far aretwograniticbodiesthatareolderthan from the other two areas to include it in theobservedtrend. the observation of a possible trend, also becauseitdoesnotlieintheMoldanubian zone. 5.3 Vosges, and Odenwald 5.4 and Harz From the Vosges, Black Forest and Odenwald 11 data points are collected, TheBohemianMassifandHarzyielded which are not all shown in the map atotalof22datapoints,fromwhichone because of similar results in nearby intheBrockengraniteintheHarz(fig9). intrusions (fig. 8). The ages of the Agesaredeterminedonthebasisofeither intrusions are mostly based on UPb UPb or RbSr analysis. Most granites are analysisandtheyhavedifferenttypology. Stypes or the type is not clear. The The Vosges and Odenwald have Itype Brocken granite lays just north of the granitoids, whereas the Black Forest has former subduction zone between the two(known)Stypegranitoids,therestis Rhenohercynian and Saxothuringian. It is notdetermined. theonlygranitewhichisconsideredtobe Here, a trend in younging direction is Atype and thus does not fit in a not very clear. In the Black Forest, subductionsetting. granitesbecomeyoungertothenorthand In the Bohemian Massif, a somewhat there also is a somewhat older granite in northwest/southeast directed trend in the south. In the Vosges, there are only younging direction can be seen, with the twogranitesmeasured,thus,atrendcan oldest granites occurring in the middle notbeconsidered.However,asomewhat part.Thisisapproximatelythesametrend

10 scraped of by the overlying crust, with subsequent formation of several thrusts behind each other, so that accretion on the overlying plate occurs [van Hinsbergen et al, 2005]. When this happens,thenappesthatsubductbehind thefrontalonesubsequentlyformigneous intrusionstoo,onlyfurtherawayfromand at a later time than this nappe. This processwouldshowasimilarkindoftrend as is observed in the Variscan massifs, which would imply that during the Variscan orogeny, nappe stacking and accretion of the overlying crust occurred inmostofthesubductionzonesdescribed inFig.2.ThisisalsomentionedbyFinger et al [1997]. Especially in the Armorican Massif it is clearly shown; here, the slab subductedtothenortheast,andalongthe entire zone, granitic intrusions become youngertotheoppositedirection,i.e.the thrusting vergence which is towards the southwest. In the other Variscan massifs, Fig. 9.GranitesintheHarz(upperleft)and theprocessofnappestackingcanbeseen BohemianMassif.Scale1:2200000. lessclearlyfromtheintrusionofgranites, because a trend in younging direction is as is shown in areas considered less evident. Though, in most of the previously. However, this trend is not as massifs,itispresent.Inthemiddleofthe clear as, for example, in the Armorican MassifCentral,theMCsuturebendstothe Massif. Here, a few granites differ from northeast, which is also shown in the the general trend: at the southeastern trend in intrusions. The youngest and northwestern rim, two granites are intrusions are present in the (south)west, much older as should be expected and in south,and(south)eastofthemassif,and the north, two granites are situated theintrusionsareoldertothenorth. somewhatseparatedfromtheothersand The Vosges and Black Forest lay in do not fully fit in with the other results. between two former subduction zones Also, at the southwestern rim there is a which are directed towards each other to reasonable number of granites that thenorthandsouth[Franke,1989;Finger remainundetermined. et al, 1997]. Therefore, when following thetrendobservedinpreviousmassifs,a trend in younging direction to the north 6. Discussion and south of both massifs would be expected.Thisisindeedthecase,butnot All granitic intrusions in the Variscan veryclear,possiblybecausetheareasand fold belt lay above suture zones that thus the amount of data are just too formed the Variscan fold belt. The trends small. In the Odenwald, the granitic inageofintrusionintheareasconsidered intrusion lies somewhat south of the turn out to show a younging direction in boundaryofthesuturezonebetweenthe the direction of the vergence of the Rhenohercynian and Saxothuringian in thrusting and parallel to the former which subduction occurred to the south. subductionzone.Thiscanlogicallynotbe As a result, it is logical that this granitic the result of a heat pulse migrating bodyintrudedhere. perpendicular to the zone caused by slab In the Bohemian Massif, the observed detachment. trend can have the same cause as is the A possible cause for this is a process case for the Vosges and Black Forest. called nappe stacking. In subduction When the former northward subduction zones, parts of the subducting crust are zone south of the Moldanubian zone is

11 continuedtotheBohemianMassif–which subduction zones, which do not exist is, however, not clearly shown yet from anymore nowadays, as is shown by previous studies , again, two subduction tomography by Bijwaard et al [1998]. zones were directed towards each other. Thus, the slabs must have detached, but In between, older granites would occur withoutresultingheatpulse. andyoungergranitesoccurtotheoutside, Some remarks that can be made to parallel to the subduction zones. This is this study are the following. Very exactlyobservedfromthecollecteddata. importanttotakeintoconsiderationisthe On the basis of the typology of the accuracy of some of the collected data, granites, no clear conclusion can be especially in case of the dating methods. drawn. The Armorican Massif and Massif KArdatingislesspreciseasUPbdating Central consist entirely of Stype inthedatingofgranites.Unfortunately,in granitoids, the rest of the massifs have someoftheareas,liketheVendée,there mixed typology and granites from which were no other data available. For the thetypeisnotclear.Itispossiblethatthe Vendéethisprobablydoesnotmatterthat suture zones of the first two, i.e. the MC much because the age of all granites in suture, were of continentcontinent the area is based on the same method, collision type, whereas the other massifs thus, it is all right if granites within the were (partly) of oceancontinent collision area are compared, unless there was an type.Clearevidenceforthisassumptionis event of metamorphism after the notgiveninrelatedstudies.Matte[2001] intrusion. However, if dating methods states that is built from the within areas differ, comparison of Armorican microplate, which is a intrusion ages in the concerned area continental plate that was attached to becomes less accurate. Here, ages of Euramerica during the Middle Devonian granites on the basis of differing dating (approximately 375 Ma). Yet, there is methods do not seem to show much some discussion about the time of the varying results. Though, for further suture between Armorica and Gondwana studies,Iwouldrecommendtheusage of and the exact configuration of the similardatingmethods,andespeciallythe microplates and oceanic basins in usage of UPb analysis in the dating of between. This information is essential for graniticintrusions. conclusions about the assumption above. The uncertainty in determining the However,inthelightofthefactthatthe type of a granitic intrusion is also an Variscan collision area was built from important remark. This determination can microplates and oceanic basins, it is very be quite difficult because boundaries likely that alternating subduction of between ratios that distinguish S and I oceanic and continental lithosphere has type often have an overlap to a certain takenplace. extent. In seeking a trend in typology, it The occurrence of a migrating heat can be a large problem, however, in this pulse as a result of slab detachment paperitisnotthemostimportantissue. duringoraftertheVariscanorogenyisnot provenonthebasisofthegainedresults. Atrendinintrusionageperpendiculartoa 7. Conclusions former suture zone is observed almost nowhere.Therearetwoareaswheresuch With the analysis of 70 granites a trend can be observed to a certain throughout the Variscan fold belt (from extent.ThisisintheArmoricanMassifand the Armorican Massif to the Bohemian –toalesserextent–intheVosges/Black Massif),thehypothesisthattheenormous Forestarea.Here,aheatpulseasaresult scale on which granitic intrusions occur of slab detachment may have occurred. would be the result of a heat pulse from However, the observed perpendicular slabdetachmentwasinvestigated.Agesof trends in younging direction stay within intrusion obtained from different dating the uncertainty boundaries of the dating methods – UPb, RbSr and KAr – turn methods. This makes the occurrence of a out to show rather reliable results, from heat pulse due to migrating slab whichthefollowingcanbeconcluded. detachment in the Variscan orogeny not It shows that there is no trend in certain. Yet, it is clear that there were ageingofgraniticintrusionsperpendicular

12 tothesuturezonesinwhichtheyintrude. istheonlyAtype,whichcanbetheresult Only in the Armorican Massif and the frompostorogenicextension. Vosges/BlackForestarea,apossibletrend inyoungingdirectionperpendiculartothe suture zone and thus the possibility of a References heat pulse can be observed. However, all theagesstaywithinthesameuncertainty "Granites." boundaries. This, together with the www..wisc.edu/courses/g203/pdf/g203c lass21.pdf . absence of suchatrendinothermassifs, "Bowen's reaction series." proves that slab detachment in the www.bookrags.com/sciences/earthscience/bow Variscan – which must have occurred – ensreactionserieswoes01.html . didnotgotogetherwithaheatpulsefrom Alexandrov, P., Ruffet, G., Cheilletz, A. (2002) . "Muscovite recrystallization and saddleshaped the astenosphere migrating along the 40 Ar/ 39 Ar age spectra: Example from the Blond plate boundary and resulting granite(MassifCentral,France)."Geochimicaet decompression melting of the lithosphere CosmochimicaActa 66 (10):17931807. andintrusionofgranites. Arthaud, F., Matte, P. (1977) ."Latestrike slip faulting in southern Europe and northern Only convincing trends in younging Africa: result of a rightlateral shearzone directionparalleltotheformersubduction between the Appalachians and the Urals." zonesareshown,allinthedirectionofthe Geological Society of America Bulletin 88 : thrusting vergence. This is probably 13051320. Baumann, A., Grauert, B., Mecklenburg, S., Vinx, R. caused by nappe stacking or continental (1991) . "Isotopic age determinations of accretion, in which parts of the crust crystalline rocks of the Upper Harz Mountains, subductunderprevioussubductedcrust:a ."GeologischeRundschau 80 (3):669 migrating subduction zone with 690. Be Mezeme, E., Cocherie, A., Faure, M., Legendre, subsequent migrating intrusion of O., Rossi, Ph. (2006) . "Electron microprobe granites. In a tectonic setting with many monazite geochronology of magmatic events: small microplates and oceanic basins, as examples from Variscan migmatites and intheVariscan,thisprocessisverylikely. granitoids, Massif Central, France." Lithos 87 : 276288. EspeciallyintheArmoricanMassif,the Begemann, F., Ludwig, K.R., Lugmair, G.W., Min, K., trendinyoungingdirectioninthedirection Nyquist, L.E., Patchett, P.J., Renne, P.R., Shih, ofthevergenceisclearlyshown.Inother C.-Y., Villa, I.M., Walker, R.J. (2001). "Call for massifs, it is also present, though less an improved set of decay constants for geochronological use." Geochimica et clear due to some missing data. In the CosmochimicaActa 65 (1):111121. BohemianMassif,wereprobablytwoslabs Behrmann, J. H., Tanner, D.C. (1997). subducted towards each other, the "Carboniferous tectonics of the Variscan younging of granites is also directed basement collage in eastern and western Bohemia." Geologische Rundschau towards both vergences of thrusting, the 86 (Suppl.):S15S27. oldestgranitesarepresentinbetween. Bennington, J. B . "Radiometric dating of the rock In all massifs, data differing from the record." general trend in is possibly caused by http://people.hofstra.edu/faculty/j_b_benningto n/2cnotes/dating.html . small differences or errors in dating Bernard-Griffiths, J., Peucat, J.J., Sheppard, S., methods. Vidal, P. (1985). "Petrogenesis of Hercynian The typology of granites shows that leucogranites from the souhern Armorican the Armorican Massif and the Massif Massif:contributionofREEandisotopic(Sr,Nd, Pb and O) geochemical data to the study of Central are entirely of Stype. This would sourcerockcharacteristicsandages."Earthand implyamore continentcontinentcollision PlanetaryScienceLetters 74 (23):235250. type of subduction. However, this is not Besang, C., Harre, W., Kreuzer, H. (1976). clearly shown from related studies, "Radiometrische Datierung, geochemische und petrographische Untersuchungen der because workers have some discussion Fichtelgebirgsgranite." Geologisches Jahrbuch about the exact tectonic setting and ReiheE E8 . configurationbeforetheVariscanorogeny. Bijwaard, H., Spakman, W., Engdahl, E.R. (1998). Itturnsoutthatothermassifshaveno “Closing the gap between regional and global travel time tomography.” Journal of clear trend in typology. They have mixed GeophysicalResearchB:SolidEarth 103 (B12): types, which can be caused both by 3002530078. continentcontinent and oceancontinent Carpena, J., Doubinger, J., Guerin, R., Juteau, T., collision. The Brocken granite in the Harz Monnier, M. (1984). "Le volcanisme acide de l'Ouest dans son cadre géologique. Caractérisation géochimique, structurala et

13 chronologie de mise en place." Bulletin granite (Erzgebirge, Germany)." Contributions SociétéGéologiquedeFrance 7:839859. toMineralogyandPetrology 145 :107118. Cathro, R. J. (2005). "Joachimsthal,CzechRepublic." Kempe, U., Bombach, K., Matukov, D., Schlothauer, CIMBulletin . T., Hutschenreuter, J., Wolf, D., Sergeev, S. Chappell, B. W., White, A.J.R. (2001). "Two (2004). "Pb/Pb and U/Pb zircon dating of contrasting granite types: 25 years later." subvolcanic rhyolite as a time marker for Australian Journal of Earth Sciences 48 : 489 Hercynian granite magmatism and Sn 499. mineralisation in the Eibenstock granite, Duthou, J. L., Cantagrel, J.M., Didier, J., Vialette, Y. Erzgebirge, Germany: Considering effects of (1984). "Palaeozoic granitoids from the French zircon alteration." Mineralium Deposita 39 : Massif Central: age and origin studied by the 646669. 87 Rb87 Sr system." Physics of the Earth & Klötzli, U. S., Parrish R.R. (1996). 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Bohemian massif) and implications for related InternationalJournalofEarthSciences 92 :36 occurerences from the midEuropean Her 53. cynian."GeologischeRundschau 86 :556570. Sinclair, A.J., Macquar J.C., Rouvier, H. (1993). "Re Wortel, M. J. R., Spakman, W. (2000). "Subduction evaluationofleadisotopicdata,southernMassif and Slab Detachment in the Mediterranean Central, France." Mineralium Deposita 28 (2): CarpathianRegion."Science 290 :19101917. 122128. Wortel, M. J. R., van Bergen, M.J., van de Zedde, Stanley, S.M. (1999). Earth System History , W.H. D.M.A., Spakman, W. (2003). "Continental FreemanPublishers. collision, slab detachment and Krich magma Tait, J. A., Bachtadse, V., Franke, W., Soffel, H.C. tism:centralsouthernItalyasatypeexample." (1997). "GeodynamicevolutionoftheEuropean EGS AGU EUG Joint Assembly, Abstracts Variscan fold belt: palaeomagnetic and from the meeting held in Nice, France, 611 geological constraints." Geologischen April2003 abstract #11281 .

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