SPECIAL PUBLICATION No. 6 —9929

Unrestricted Mintek publications 1966 to 1984

by

H.W. GLEN UNRESTRICTED MINTEK PUBLICATIONS 1966 TO 1984

by

H.W. Glen

Special publication no. 6 April 1984

Printed and published by the Council for Mineral Technology, Private Bag X3015, Randburg, 2125 South Africa

ISBN 0 86999 653 3 First printed April 1976 (as Report 1812) Reprinted with additions and amendments

June 1977 (as Report 1894) June 1978 (as Report 1970) June 1979 (as Report 2013) August 1980 (as Report 2067) March 1983 (as Report M85) April 1984 (as Special Publication 6) SYNOPSIS

This publication lists the 895 unrestricted reports, 508 papers, 45 patents, 5 special publications, and 2 technical bulletins that were issued as publications of the National Institute for Metallurgy (NIM) and the Council for Mineral Technology (Mintek) from 1966 (the year of NIM's inception) to 31st March 1984. For ease of reference, these publications are also classified under research topics. Also included are details of the periodicals issued by Mintek and a list of its current miscellaneous publications, which include brochures and leaflets of various kinds.

SAMEVATTING

Hierdie publikasie lys die 895 onbeperkte verslae, 508 referate, 45 patente, 5 spesiale publikasies en 2 tegniese bulletyne wat sedert 1966 — die stigtingsjaar van die Nasionale Instituut vir Metallurgie (NIM) — tot 31 Maart 1984 as publikasies van NIM en die Raad vir Mineraaltegnologie (Mintek) uitgegee is. Hierdie publikasies word vir maklike verwysing ook onder navorsingsonderwerpe, geklassifiseer. Daar word ook besonderhede verstrek van die blaaie wat Mintek uitgee en 'n lys van diverse publikasies soos verskillende soorte brosjures en pamflette, ingesluit. PREFACE

This publication, which supersedes Report M85, is a compilation of all the publications of the National Institute for Metallurgy (NIM) and its successor, the Council for Mineral Technology (Mintek), having an unrestricted distribution list. The NIM reports end with Report 213SD, and the Mintek reports start with Report Ml. The present publication includes all the unrestricted reports and the patents issued and registered by these organizations from 1966 to 31st March, 1984, the confidential reports that were declassified during that period, all the papers published during that period where one of the authors was, or is, a member of staff, znd the other publications that do not fall into the categories already mentioned. The total number of unrestricted reports included is 895, the patents amount to 45, the number of papers published is 508, and the other publications amount to 7. For ease of reference, all the reports, papers, patents, technical bulletins, and special publications listed here have been classified as far as possible into various research topics. A list of these topics is given in Section 6, together with the .lumbers of the pages on which the publications are classified according to topic. This publication also gi'es details of the periodicals issued by Mintek and concludes with a list of miscellaneous publications, which are additional to those mentioned above. These include current brochures. CONTENTS

PREFACE

1. LIST OF UNRESTRICTED REPORTS 1

2. PAPERS BY STAFF 42

3. PATENTS 77

4. SPECIAL PUBLICATIONS 81

5. TECHNICAL BULLETINS 81

6. CLASSIFICATION OF RESEARCH TOPICS 82

7. CLASSIFICATION OF PUBLICATIONS ACCORDING TO RESEARCH TOPIC 86

8. PERIODICAL PUBLICATIONS 179

9. MISCELLANEOUS PUBLICATIONS 180 MINTEK PUBLICATIONS

1. LIST OF UNRESTRICTED REPORTS

Copies of most of these reports are available free of charge from Mintek, Private Bag X3015, Randburg, 2125 South Africa. For those reports that are out of print, photocopies can be supplied at a nominal charge. The reports that have become available since the previous issue of this list (NIM Report M85 are marked •. MINTEK PUBLICATIONS

No. Title Year

2 The dissolution of gold in cyanide solutions containing copper in a carbonate/bicarbonate

medium. Preliminary results 1966

S The spectrophotometric determination of trace amounts of tin 1966

8 Mineralogy and chemical behaviour of some refractory gold ores from the Barberton Mountain Land 1966 10 The determination of phosphate in silicate samples 1966

11 Gravimetric determination of carbon dioxide in cyanide solutions 1966

12 Exploratory tests on the concentration of tin ore from Kuils River, C.P. 1966

14 A comparison of the effects of additions of carbonate/bicarbonate as opposed to additions

of lime in the leaching of a Blyvooruitzicht gold ore 1966

16 The rotating-disc system and its applications in the dissolution of gold 1966

18 The 8th Commonwealth Mining and Metallurgical Congress — Australasia — 27th February to 15th April, 1965. Visits to various places in Australia and Tasmania 1966 20 The determination of small amounts of gold in barren cyanide solution by atomic- absorption spectrophotometry 1966

21 The use of heavy-medium separation for the recovery of spodumene 1966

24 Determination of gold in barren cyanide solutions by atomic-absorption spectrophotometry 1966

25 Quantitative mineralogical examination of six samples of pulverized mine ores submitted by the Chemical Engineering Group, CSIR 1966

26 Economic evaluations of the possible production of alumina from Sasol ashes by the ammonium sulphate baking process and the ammonium fluoride and sulphuric acid leaching process \967

27 Spectrophotometric determination of gold in cyanide solutions after solvent extraction as the bromo-aurate complex 1966

28 Exploratory tests on the dissolution of manganese dioxide by reaction with sulphuric acid

and a metallic sulphide 1966

29 The determination of selenium and tellurium in silver chloride 1966

30 The extraction of alumina from Sasol coal ash 1966 34 Qualitative electron-microprobe investigation of cobalt-gadolinium intermetallic compounds 1966

35 The determination of gold ores and solutions by neutron-activation analysis 1966

37 The determination of aluminium in silicate samples by complexometric titration 1966

38 Chemical treatment of refractory gold ores. Literature survey 1966 MINTEK PUBLICATIONS

No. Title Year

39 The determination of small amounts of silica in zirconium ores and concentrates 1966

40 The spectrophotometric determination of tin in silicate materials 1966

41 Table of the isomeric states of stable nuclides 1966

42 The redox potential of solutions of potassium ethyl xanthate 1966

43 The effect of oxygen on the stability of solutions of potassium ethyl xanthate 1966

44 The zero point of charge of uranium dioxide and uraninite 1966

45 An apparatus used in the study of interactions between sulphide minerals, sulphydryl reagents and oxygen 1966

48 The investigation of a suspected siilimanite-bearing sample 1966

49 The spectrophotometric determination of silica in zirconium oxide 1966

51 Exploratory tests on the recovery of diaspore from a ferruginous shale from the Gamagararand 1966

53 Differential thermal investigation of Moore-filter residues for the Anglo American Research Laboratory 1966

54 Electron-microprobe investigation of magnetite from the Bushveld Igneous Complex 1966

63 X-ray and spectrographic analyses of seven samples of manganese ere 1966

64 The determination of the hafnium/zirconium ratio in ammonium diuranate produced

by the Bufflex Process 1966

65 Samples of manganese dioxide for battery tests by the CSIR 1966

66 The study of propagation modes effective in around-the-World radio-wave propagation

in the 15-Mc/s to 30-Mc/s band 1966

67 The application of silicon controlled rectifiers to instruments using half-cycle heating 1966

69 Preliminary examination of ijolite from Spitzkop 1966

76 The electron-microprobe investigation of a gold concentrate from the Louis Moore Mine 1966 77 Concentration of fluorspar from the farm Strydfontein, Marico District. Preliminary investigation 1966 78 X-ray investigation of four samples of manganese ore 1966

79 Investigation into the improvement of gold recovery in the cyanidation circuit of the Louis Moore Gold Mine 1966

80 The resolution of photopeaks obtained from the products of stable nuclides irradiated by neutrons 1966 MINTEK PUBLICATIONS

No. Title Year

81 The solvent extraction of copper cyanide 1966

82 The spectrophotometric determination of cobalt with 2-nitroso-l-naphthol 1966

83 Qualitative X-ray examination of two samples of MnO2 ore 1966

84 Leaching tests on the copper sulphide mineral valleriite from Palabora Mining Company

— a preliminary report 1966

85 The roasting of refractory gold ores and concentrates. Literature survey 1966

86 The investigation of six samples of serpentinite from the Barberton area 1966

88 Quantitative electron-microprobe investigation of the distribution of nickel in serpentinites

and associated minerals and rocks from the Barberton area 1966

89 Mineralogical examination of ijolite from Spitzkop 1966

90 Mineralogical examination of schist sample from the Giant Reefs Mine 1966

91 Half-cycle heating applied to an X-ray powder camera 1966

96 The mode of occurrence of beryl in grey gneiss along the contact with the Gesie pegmatite 1966 97 X-ray-diffraction analysis of six samples of manganese ore from Graskop, eastern Transvaal 1966

98 Qualitative X-ray analysis of manganese dioxide ore from Graskop 1966

99 Determination of molybdenum in uranium compounds 1966

101 Electron-microprobe identification of opaque minerals in gold ore from the Basal Reef,

Free State Geduld Mine 1966

102 Micas of the Noumas pegmatite 1966

103 Techniques for the examination of inorganic compounds on an infrared spectrograph 1966 104 The infrared examination of microlite, muscovite, apatite in the presence of carbonate, asbestos, paragonite, and various uranium salts 1967 105 Report on overseas visit 1966

107 Investigations on the treatment of refractory gold ores from the Giant Reefs Mine 1966

108 An X-ray-diffraction method for the quantitative determination of nsutite (y-MnO2) and cryptomelane (a-MnO2) in ores from Gopani Mine, Transvaal 1966

109 The possibility of establishing a local cost index for the estimation of metallurgical and chemical plant 1967

111 The X-ray investigation of a sample of upgraded material from the GrasKor» wa;I deposit 1966

113 The identification, by means of the electron microprobe, of an opaque mineral from the Artonvilla Mine, Messina ]%6 MINTEK PUBLICATIONS

No. Title Year

120 Exploratory tests on the recovery of apatite and magnetite from the farm Schiel 1967

127 Comments on the size of gold particles observed in polished sections of ore from the Giant Reefs Mine 1967

128 Exploratory concentration test for the rec /ery of cassiterite from Sandspruit No. 51, Bronkhorstspruit district 1967

129 The poterographic determination of total hexavalent uranium as uranyl fluoride in uranous fluoride 1967

131 The spectrographic determination of titanium oxide, ferric oxide, and silica, in baddeleyite 1967

132 Mineralogical and spectrographic investigation of a mineral concentrate from Koster, western Transvaal 1967

133 Gold recovery by cyanidation from mill products obtained after pyrite flotation. Progress made up to 1st July, 1967 1967

136 Determination of aluminium in silicate materials by solvent extraction and atomic- absorption spectrophotometry 1967

137 Determination of aluminium by atomic-absorption spectrophotometry with the nitrous

oxide and acetylene flame 1966

138 The determination of beryllium by atomic-absorption spectrophotometry 1967

139 A preliminary survey of gold-recovery problems arising in the production of pyrite 1967 140 A preliminary mineralogical investigation of pyrite from the Kimberley and the Main Reefs, Vogelstruisbult Gold Mine 1967

142 Micas from the Namaqualand pegmatite area 1967

143 A review of the investigations into the possibility of producing alumina and aluminium

from South African ores 1967

148 The recovery of gold from the Fairview dump after pretreatment with sulphurous acid 1967

149 The extraction of alumina, potash, and soda from a nepheline concentrate 1967

151 The spectrophotometric determination of minor amounts of antimony 1967

152 The determination of beryllium by irradiation with gamma rays 1967

153 The spectrographic determination of zirconium in uranium oxide 1967 154 The leaching of various copper minerals with dilute sodium cyanide and dilute solutions containing sulphuric acid and ferric ions 1967

155 The quantitative estimation of valleriite in the presence of other copper minerals 1967

156 Preliminary observations on the automation of the TBP method for determining uranium 1967 MINTEK PUBLICATIONS

No. Title Year

157 Results of tests to obtain pure valleriite 1967

158 Aerosol formation with a high-speed spinning surface 1967

159 A radioactive-tracer technique for the study of flotation of valleriite 1967

160 The determination of copper in rocks and ores by atomic-absorption spectrophotometry 1967

161 The quantitative electron-microprobe determination of magnesium content of magnetite

from Phalaborwa 1967

162 The growth of radioactivity in uranium after separation from its daughter products 1967

163 The fJuorimetric determination of uranium 1967

165 Gold recovery from pyrite flotation mill products by cyanidation. Progress made up to

1st May, 1967 1967

167 The determination of thiocyanate in uranium solutions 1967

172 The solvent extraction of copper cyanide 1967

173 The determination of beryllium by atomic-absorption spectrophotometry 1967

174 Determination of chloride in uranium solutions 1967

175 Copper extraction by leaching magnetites from Palabora Mining Company 1967

177 Compensating for flux variation in neutron-activation analysis 1967

179 The nickel distribution in weathered serpentinites from Volspruit, Potgietersrus 1967

180 The distribution of nickel in a rock sample from Louis Moore Mine, northern Transvaal 1967

190 Micas from the Namaqualand pegmatite area 1967

193 An investigation into the use of platinum ware for silicate analysis 1967

200 The spectrochemical analysis of silicate material by a plasma-jet source 1967

207 The analysis of baddeleyite by X-ray-fluorescence spectroscopy 1967

208 Determination of fluorine in fluorspar ores by neutron-activation analysis 1967

211 Refractory gold ores. Report on investigations into roasting of gold concentrates in the

Edwards roaster of the Fairview and the New Consort reduction plants 1967

216 The determination of minor quantities of manganese in silicate materials 1967

218 Exploratory comminution and flotation tests to indicate some characteristics of valleriite 1967

219 A review of some of the mineralogical factors influencing the flotation of pyrite 1967

225 Test to recover tantalite-columbite from a bulk sample of tailing from the Noumas pegmatite by pneumatic tabling 1967 MINTEK PUBLICATIONS

No. Title Year

• 227 The spectrophotometric determination of vanadium in uranium compounds 1967

23z A comparison of open-circuit and closed-circuit grinding for the control of slime formation 1967

233 A chemical and mineralogical study of microiite from the Noumas pegmatite [available only on loan from Mintek library] 1967 236 The determination of some of the major constituents of ores and minerals by fast-neutron activation analysis 1967

237 The mineralogy of uranium in Western Areas ores 1967

• 238 The determination of silicon in uranous fluoride 1967

• 239 The determination of tin in tungsten ores 1967

241 Investigation of the effects of sulphydryl flotation reagents on the cyanidation of native

gold 1967

244 The determination of selenium and tellurium in silver chloride and uranium compounds 1967

256 The determination of carbon in uranium tetrafluoride 1967

257 The determination of uranium by the TBP method 1967

258 Exploratory concentration tests by Warren Spring Laboratory on the use of the fluidized-

bed concentrator for the recovery of spodumene 1967

260 The electron-microprobe investigation of two samples of magnetite catalyst from Sasol 1967

262 Preliminary gravity concentration tests for the recovery of scheelite, wolframite, and cassiterite from the tailing dump at Boksputs in the Gordonia district 1967 264 A new detector unit for the Techtron model AA3 atomic-absorption spectrophotometer 1967 265 The spectrophotometric determination of minor quantities of chromium in silicate materials 1967

266 Concentration tests for the recovery of lepidolite from tailing dumps at Helicon and Rubicon Mines by electrostatic separation and flotation 1968

268 A power-failure safety device and operational aid for the electron microprobe 1968

269 A literature survey of the vertical distribution of gold and uranium in various auriferous reefs 1968

272 The determination of iron, titanium, and zirconium, in baddeleyite by X-ray-fluorescence spectroscopy 1968

276 The determination of vanadium in silicate materials by atomic-absorption spectrophotometry 1968

277 The determination of small quantities of xanthate in cyanide solution 1968

278 Gold recovery cyanidation from mill products obtained after pyrite flotation 1968 MINTEK PUBLICATIONS

No. Title Year

• 279 The determination of sodium, potassium, lithium, and calcium in uranium compounds 1968

• 280 The spectrophotometric determination of cobalt with 2-nitroso-l-naphthol 1968

281 The determination of xanthate in cyanide solutions 1968

286 A mineralogical and petrographic study of the pre-Transvaal rocks in borehole K. 1, Koster district, western Transvaal 1968

287 A preliminary examination of kieselguhr from Witdraai, south of Postmasburg 1968

288 Ramsdellite (MnO2) from the Hotazel Mine, northern Cape Province 1968

289 The determination of lead in silicate materials by atomic-absorption spectrophotometry 1968

291 Nickel minerals from Barberton, South Africa. I. Ferroan 1968

298 The recovery of potassium from phlogopite 1968

300 The mixed-collector system xanthate plus quaternary ammonium halide. A literature survey 1968

302 Mineralogical examination of phosphate in pyroxenite from St. Agnesfontein, north- western Transvaal 1968

306 The effect of preaeration in two samples of thickener underflow from the Venterspost

Gold Mine 1968

307 Preliminary examination of kyanite-bearing material from Granville, Leydsdorp 1968

308 A mineralogical study of gold particles in pulp residues from the Bracken Gold Mine 1968

312 An investigation of the influence of alkyl trimethyl ammonium halides on the stability

of potassium ethyl xanthate in aqueous solution 1968

313 The qualitative investigation of inclusions in free-cutting steel with the electron microprobe 1968

316 The flotation of pyrite from siliceous gangue by cationic collectors. A literature survey 1968

317 Results of tests carried out at the Loraine Gold Mine during the period 5th to 7th February,

1968 1968

• 318 The spectrophotometric determination of nickel in uranium compounds 1968

321 Aeration of ore from the Loraine Gold Mine before the addition of cyanide 1968

323 The colorimetric determination of cyanide in solutions from gold cyanidation plants 1968

325 Investigation for nickel and precious metals in samples from Malelane 1968

327 Information theory and tht u- -f experiments 1968 328 A mineralogical examination of iron ore from Nooitgedacht, near Airlie Station, eastern Transvaal 1968 331 A literature survey of the preparation of standard rock samples 1968 M1NTEK PUBLICATIONS

No. Title Year

332 Collection and preparation of standard rock samples 1968

333 The hot-water leaching process for refining arsenious oxide in flue dusts from the Fairview Mine 1968

340 The detection of the formation of a bulk adduct between potassium ethyl xanthate and dodecyl trimethyl ammonium bromide in aqueous solution 1968

341 An experimental on-stream colorimetric uranium monitor and solvent-addition controller for the Purlex process 1968

343 A mineralogical investigation of gold-bearing sulphidic ore from the Florence-Devonian Mine, Barberton 1968

344 Nickel minerals from Barberton: II. Nimite, a nickelian chlorite 1968

347 Concentration tests on 'rich blue nobby' kyanite-bearing ore from Nkandhla, Zululand 1968

348 The determination of gold and silver in pyrite and banket by atomic-absorption spectrophotometry 1968

349 The separation of platinum from solution after fusion with potassium bifluoride 1968

350 Concentration of cassiterite from two samples from Enkeldoorn, Bronkhorstspruit district 1968

352 Nickel minerals from Barbenon: III. Willemseite, a nickelian talc 1968

354 The determination of trace amounts of arsenic in uranium tetrafluoride 1968

358 The determination of mercury at concentrations of parts per thousand million in geological samples 1968

359 The separation and determination of calcium and magnesium in silicate material 1968

360 The determination of the alkali metal carbonates and hydroxides or carbonates and bicarbonates in the presence of permanganate ions 1968

361 The spectrophotometric determination of small amounts of calcium and magnesium in

glass sands and allied materials 1968

362 The determination of cobalt in geological samples by atomic-absorption spectrophotometry 1968

363 The determination of thorium in solid samples of baddeleyite and carbonatite ores and

in the solutions resulting from leaching these ores 1968

367 Felix Project: imperfect mixing in continuous leaching at Buffelsfontein uranium plant 1968

371 A preliminary investigation of cyanide-sulphydryl mixed-ligand complexes of mercuric ion 1968

377 Examination of pulp samples, treated with cyanide, for coated gold 1968

378 A literature survey on the manufacture of ferrochrome 1968

379 The inhibition of the rate of cyanidation of native gold by Aeromine 3037 1968 MINTEK PUBLICATIONS

No. Title Year

380 Preparation of gold ore before cyanidation 1968

385 The determination of the nature of coatings on gold particles 1968

392 The spectrophotometric determination of small amounts of calcium and magnesium in glass sands and allied materials 1968

414 The geochemistry of some uranium minerals in the Dominion Reef and Witwatersrand Systems 1968

415 Uranium compounds in the Dominion Reefs, and their association with phosphorus compounds 1968

416 Comminution kinetics: batch tests in small mills, and model development 1968

417 Determination of molybdenum in uranium compounds 1968

428 Nickel minerals from Barberton, South Africa: IV. Reevesite, a member of the hydrotalcite group 1968

429 The determination of chromium in 1968

430 A mineralogical investigation of pyrite from the Loraine Gold Mine, Orange Free State 1968

433 The spectrophotometric determination of microgram quantities of vanadium in U3O8,

UO3, and UF4 1968

434 The determination of titanium in uranium compounds 1968

435 The liquid-liquid extraction of ferric thiocyanate complexes with Versatic 911 1968

437 The bathochromic shift of 381 nm absorption peak in aqueous solutions of potassium ethyl xanthate containing dodecyltrimethyl ammonium bromide 1968 439 The determination of free acid in the presence of hydrolysable cations 1968 440 Separation of hafnium and zirconium oxides from uranium preliminary to the spectrographic determination of hafnium 1968

442 'n Ondersoek na die gebruik van die Hallimondbuis vir die kwantitatiewe bestudering van flottasieverskynsels met besondere verwysing na die kondisionering van apatiet en kalsiet 1968

443 The determination of anionic surface-active agents in dilute aqueous solution 1968

445 The use of californium-252 fission neutron sources 1969

447 Chemical beneficiation and agglomeration of low-grade chromite ores — a literature study 1969

449 The determination of cationic surface-active agents in dilute aqueous solution 1968

450 The spectrographic determination of alkali metals and alkaline earths in uranium oxide 1968

451 The determination of thorium in baddeleyite and carbonatite ores and in the solutions resulting from leaching of these ores 1968

10 MINTEK PUBLICATIONS

No. Title Year

452 The Purlex Process — a description of the pilot plant leading to the use of the process in South Africa 1969

455 Determination of uranium by the TBP method after extraction with ethyl acetate 1968

456 Method for the determination of vanadium in silicate materials by atomic-absorption spectrophotometry 1969 457 The determination of rubidium and caesium in silicate materials by atomic-absorption spectrophotometry 1969

459 Determination of tantalum in rocks and minerals by paper-partition chromatography 1969

460 A rapid method for the determination of minor amounts of thorium in aqueous solutions of uranyl nitrate or chloride 1969

464 The saturation pressure of nitrogen in determinations of surface area 1969

465 The determination of aminoid nitrogen in organic compounds by the Kjeldahl method 1969

466 The volumetric determination of aluminium in silicate materials 1969

470 Rapid estimation of uranium in raf finate solutions containing thorium by the pyridylazo- naphthol method 1969 473 Mineralogical examination of tantalite-bearing samples from the Warmbad district, South West Africa 1968

474 The IAEA Conference on the Use of Nuclear Techniques in the Prospecting and Development of Mineral Resources 1969

477 Balanced-temperature analysers 1969

482 Review of work on the treatment of pegmatites 1969

483 Summary of the mineralogical investigation of pegmatites 1969

485 Gravimetric determination, using nitron, of nitrates in uranium compounds 1969

486 Determination of strontium in ores by atomic-absorption and emission spectrophotometry 1969

487 The spectrophotometric determination of minor quantities of vanadium in silicate materials 1969

489 Thermal analysis. Overseas visit 1969

491 The determination of nickel, copper, and cobalt in a nickel alloy matte 1969

493 Concentration of andalusite from alluvial sands from the farm Goedgelegen, Groot Marico district 1969

494 A preliminary study of beryllium distribution in phyllosilicates from the Etiro pegmatite, Karibib, South West Africa 1969

496 A preliminary study of beryllium distribution in quartzes from the Etiro pegmatite, Karibib, South West Africa 1969

li MINTEK PUBLICATIONS

No. Title Year

497 The determination of ferric iron using Tiron 1969

498 An infrared investigation of the potassium alkyl xanthate and alkyi trimethyl ammonium bromide mixed-collector system 1969

499 The determination of molybdenum by atomic-absorption spectrophotometry 1969

502 The volumetric determination of chloride and bromide using mercurous perchlorate 1969

503 Rapid estimation, by the ammonium thiocyanate method, of uranium in raffinate solutions containing thorium, lead, and copper 1969

504 The influence of preadsorbed oleate ions on the adsorption of water vapour by insoluble ionic crystals 1969

508 The distribution of nickel in serpentinite samples of borehole cores from the Msauli Mine,

Barberton 1969

510 The performance of a clarifier subject to low-intensity turbulence 1969

511 The determination of silica in chrome ores and chrome refractories 1969

512 The distribution of nickel in two surface samples of serpentinite 1969 513 Gold recovery by cyanidation from mill products obtained after pyrite flotation 1969

515 The influence of sulphydryl and cationic flotation reagents on the cyanidation of native gold 1969

517 Radiotracer tests on the pachucas on the uranium plant at Western Reefs Mine 1969

518 The prediction of gravity or inertial separation efficiencies from heavy-liquid tests and Tromp-type efficiency curves. An improved method 1969

524 The determination of minor amounts of molybdenum in soil samples 1969

526 The determination of the platinum-group metals and gold in ore samples 1969

527 Quantitative aspects of the interaction between galena, xanthate, and oxygen at a pH

value of 10 1969

529 The determination of uranium in the organic solvent from the Purlex Process 1969

530 The measurement of 14MeV neutron fluxes from a neutron generator 1969

533 Determination of the stoichiometry and stability constants of mercury(ll)-cyanide- xanthate complexes. I. Low-concentration region 1969 536 The distribution of nickel in limonite-bearing birbirite and gossan from Vlakfontein and Groenfontein in the western Transvaal 1969

537 Flame-photometric determination of lithium with the Techtron AA4 spectrophotometer 1969

837 The association of gold and uranium with other minerals in different Witwatersrand reefs 1969

12 MINTEK PUBLICATIONS

No. Title Year

845 An electron-microprobe study of the nickel distribution in a serpentinite from Volspruit, Potgietersrus 1969

847 The liquid-liquid extraction of ferric thiocyanate complexes with carboxylic acids 1969

848 The distribution of nickel in serpentine from Lusinzi, north-eastern Transvaal 1969

853 The determination of silicon in ferrochrome alloys 1970

857 The volumetric determination of bismuth in metallurgical ores and concentrates 1969

870 Determination of the stoichiometry and stability constants of mercury(ii)-cyanide-

xanthate complexes. II. High-concentration region 1970

884 Review of information on the mineral industry of Mozambique 1970

889 The simultaneous determination, by instrumental thermal-neutron activation analysis, of some selected trace elements likely to be present in lunar material 1969 890 The determination of the platinum-group metals and gold in ore samples — Part II 1969 891 Calibration of the 'Universal Voltronics' power supply for the neutron generator manufactured by Accelerators Incorporated 1969

894 The determination of thorium in silicate rocks 1969

897 Nickel in South Africa with special reference to low-grade nickeli erous ores 1970

898 The development of a computer programme for countercurrent operations involving liquid- solid solute separations 1970

911 The recovery of gold from sulphidic and arsenical ores mainly from the Barberton area 1970

938 Life test on IRA 400 resin during the recovery of zinc chloride 1970

• 942 The determination of trace elements on nylon thread 1970

943 An electron-microprobe investigation of chiastolite crystals 1970

950 A mineralogical study of eight samples of phosphate ore from Steenkampskraal, Van Rhynsdorp, Cape Province 1970

951 Colorimetric determination of minor quantities of nitrate in uranium compounds 1970

952 The analysis of ferrochrome slag 1970

961 The preparation of standard solutions of the platinum-group metals and gold 1970

964 The recovery of copper from sulphate leach liquors by liquid ion exchange with LIX-64N 1970

965 The spectrophotometric determination of phosphate in leach residues and solutions 1970

967 Automatic timing of the neutron-generator counting station 1970

13 MINTEK PUBLICATIONS

No. Title Year

970 The determination, by atomic-absorption spectrophotometry, of platinum, palladium, rhodium, ruthenium, gold, silver, and lead, in prills 1970

971 The determination of gold by atomic absorption, and of platinum, palladium, rhodium,

and indium by spectrophotometry, in solutions 1970

975 Visit to the Tripartite Chemical Engineering Conference in Montreal 1970

976 The determination, by atomic-absorption spectrophotometry, of gold in cupellation prills and in platinum-metal concentrates 1970 977 The collection and rapid determination of noble metals in ores and concentrates by the fusion technique using lead as a collector 1970

987 Rhythmic-activation analysis 1970

991 The determination of thorium in solid samples and in solutions resulting from the leaching of ores 1970

994 The separation and determination of noble metals by reversed-phase extraction

chromatography 1971

996 An improved distributed-parameter model for the kinetics of mineral flotation 1970

998 The determination of macroscopic amounts of total rare-earth oxides and thorium oxide 1970

1003 The chromatographic separation and determination of platinum, palladium, rhodium,

and iridium 1970

1005 Modifications to the Intertechnique 4000-channel analyser 1970

1010 The leaching, with hydrofluoric acid, of materials containing tantalum and niobium 1970 1012 The coordination numbers of cyanide complexes of zinc, cadmium, and mercury in aqueous solution 1970 1013 The instrumental neutron-activation analysis of samples taken at different levels of the E.R.P.M. Mine 1970

1017 The spectrophotometric determination of rhodium 1970

1020 Phase relationships involving iron, chromium, silicon, and carbon, with special reference

to high-carbon ferrochromium and ferrochromium-silicide alloys. A literature survey 1970

1025 An introduction to stochastic differential equations. Abbreviated lecture notes 1971

1026 Small-scale flotation techniques 1970

1028 Exploratory heavy-liquid separation tests on a low-grade apatite concentrate 1970

1031 The dissolution of UO2 as an electron-transfer reaction 1970

1037 The determination of gold in concentrates of the platinum-group metals after extraction with dibutyl 'Carbitol' 1970

14 MINTEK PUBLICATIONS

No. Title Year

1043 The determination of ruthenium in uranyl fluoride 1970

1044 The determination of ruthenium in uranyl fluoride 1970

1048 The determination, by neutron-activation and tracer techniques, of the losses of indium during the fire-assay procedure for the platinum-group metals 1970

1049 Exchange visit to the Institut für Spektrochemie und Angewandte Spektroskopie in Dortmund, West Germany 1970

1075 The preparation of PADAP — 2-(2-pyridylazo)-5-diethyIaminophenol (zinc complex) 1970

1076 The direct determination of acid-soluble uranium in silicate ores and in the solutions resulting from leaching these ores 1970

1077 The determination of acid-soluble, acid-insoluble, and total uranium in silicate ores 1970

1078 The complexometric determination of zinc in ores and concentrates, with ion-exchange resin 1970

1085 The optimization of the design of a countercurrent liquid-liquid-extraction plant using LIX-64N 1970

1086 The determination, by atomic-absorption spectroscopy, of platinum, palladium, rhodium, ruthenium, and gold in the presence of base metals 1970

1088 The determination of ferrous iron in refractory minerals 1970

1089 The rapid volumetric determination of calcium in pregnant solutions in uranium plants 1970

1093 The calculation of the equilibrium distribution of metal-ion complexes in multicomponent aqueous systems 1970 1096 The spectrophotometric determination of titanium in ores, rocks, and minerals, with diantipyrylmethane 1970

1106 Computerization of atomic-absorption data with the Oiivt:ti Programma 101 1970

1108 Interferences relating to the determination of the noble metals by atomic-absorption

spectrophotometry 1970

1113 The determination of uranium in ores and solutions by X-ray fluorescence 1970

1114 A study of the products of reaction between galena and aqueous xanthate solutions 1970

1125 Studies of the stability of xanthates and dixanthogen in aqueous solution, and the chemistry

of iron xanthates and cobalt xanthates 1971

1137 The determination of the platinum-group metals and gold in ore samples — Part III 1971

1144 Three-dimensional predominant-area and solubility diagrams for the uranyl carbonate and uranyl sulphate systems at 25 °C 1971 1145 The use of 2-(2-pyridylazo)-5-diethylaminophenol as a spectrophotometric reagent for the determination of uranium 1970

15 MINTEK PUBLICATIONS

No. Title Year

1151 E(/Eo diagrams'; Their use in the estimation of unknown standard reduction potentials, with particular reference to the d10 electron-configuration ions 1970

1154 The extraction and separation of niobium and tantalum by liquid-liquid extraction using tri-n-butyl phosphate 1970

1158 The production of ferric sulphate and sulphuric acid by the autoxidation process using the Fring's Aerator 1970

1163 The computer programming of atomic-absorption measurements on the Olivetti

Programma 101 1970

1172 A visit to Outokumpu Oy Research Laboratory in Finland 1970

1178 Further leaching tests, with hydrofluoric acid, on a tantalite concentrate 1970

1179 The spectrophotometric determination of indium 1971

1185 The recovery of noble metals for analysis. A radiotracer investigation of losses 1971

1203 The chromite of the Bush veld Igneous Complex. An assessment of published information 1971 1204 The flotation of phoscorite ores. Possible correlations between chemical variaWes in solution and metallurgical performance 1971

1205 The adsorption of uranyl species on pyrophyllite, quartz, and acid-treated South African uranium ores. A preliminary investigation 1971

1206 A review of the South African platinum-mining industry 1971

1209 The economics of instrumentation for the cyanidation of gold 1971

1217 Investigation of beach sands from Bantu Area No. 4, Nhlabane, Zululand 1971

1218 The acid-extraction of noble metals from low-grade concentrates and ores, and the subsequent determination of platinum, palladium, rhodium, and gold 1971

1219 Spectrographic analysis for the noble metals present in solutions 1971

1222 The liquid-liquid extraction of zinc from zinc chloride solutions by the use of di-2-ethyl

hexyl phosphoric acid 1971

1230 The determination of copper and zinc in borehole cores with the Ekco Mineral Analyser 1971

1232 The determination of osmium 1971

11241 The determination of impurities in niobium and tantalum fluorides 1971

1245 The separation of non-volatile noble metals by reversed-phase extraction chromatography 1971 1247 The pelletizing of chromite fines. A preliminary investigation of the preparation of cold- bonded pellets 1971

1257 Aspects of the Seventh X-ray Analytical Conference, Durham, September 1970 1971

16 MINTEK PUBLICATIONS

No. Title Year

1260 Interference by base metals in the spectrophotometric determination of platinum metals 1971

1267 The development of an electrodeless conductivity meter 1971

1268 A two-stage process for the recovery of flotation concentrates from copper-zinc ores 1971

1273 The coprecipitation of noble metals from tellurium. I. Platinum, palladium, rhodium, and gold 1971

1281 The heavy-medium cyclone concentration plant for the treatment of andalusite sands on the farm 'Wonderfontein', Groot Marico district !971

1282 The determination of free hydrofluoric acid in the leach liquors from tantalum-niobium ores 1971

1296 A review of reactions in the flotation system galena-xanthate-oxygen 1971

1305 The determination of total sulphur in the dust from nylon thread 1971

1308 Heavy-medium tests for the treatment of pegmatite ores and dump material in Namaqualand 1971

1310 South African costs of industrial equipment for the metallurgical industry 1971

1318 The determination, by atomic-absorption spectrophotometry, of osmium and iridium in solution 1971

1319 Nickel minerals from Barberton. V. Trevorite 1971

1322 The preparation and analysis of minerals for use as reference material. Progress report no. 1 1971

1324 The separation of base metals from noble metals by cation exchange 1971

1340 The cadmium-cyanide-xanthate system 1971

1343 The Pyrometallurgical Research Group's current research programme on ferro-alloys 1971

1351 Preliminary report on the analysis of the six NIMROC geochemical standard samples 1972

1356 Nickel in samples of serpentinite from Kaapsehoop, Barberton 1971

1361 An electron-microprobe analysis of gold in the Witwatersrand banket and in ores from

the Barberton Mountain Land 1971

1364 Ihiourea anion-exchange resins for the recovery of platinum-group metals and gold 1971

1365 Studies of incipient fusion in ihe system chromite-MgO-Al2O3-SiO2-C 1972 1366 Liquidus temperatures, viscosities, and electrical conductivities of lime-containing slags produced during the smelting of high-carbon ferrochromium and ferrochromium-silicide alloys 1971 1371 Concentration of noble metals by a fire-assay technique using nickel sulphide as the collector 1971

17 MINTEK PUBLICATIONS

No. Title Year

1372 The electrical double-layer properties of kimberlite suspensions 1971

1374 Flotation tests on copper-zinc ore from Letaba district 1971

1380 An electrochemical model for the leaching of uranium dioxide 1972

• 1383 The determination of low concentrations of uranium in solutions containing high

concentrations of thorium 1971

1384 Flotation tests on samples of Canadian copper-zinc ores 1971

1388 Flotation tests on samples of copper-zinc ores from Finland 1971

1394 The determination of ferrous iron in aid chromium ores 1972

1398 The pelletization of chromite fines. Preparation of pellets bonded with bentonite and indurated by heat treatment 971 1401 The pressure dissolution of platiniferous materials by the sealed-tube technique [superseded

by Report 1852] 1972

1402 A study of mineral-surface properties by the use of gas-adsorption measurements 1972

1403 The coagulation and flocculation of suspensions of kimberlite 1972

1408 The determination of molybdenum in the solids and solutions resulting from the processing of Witwatersrand uranium ores 1972 ' 114 The use of a closed recirculation apparatus in the study of the galena-oxygen-xanthate system 1972

1415 The interrelation of the chemical, physical, and certain metallurgical properties of chrome from the Bushveld Igneous Complex 1972

1423 The effects of chromium oxide, iron oxide, and calcium oxide on the liquidus temperatures, viscosities, and electrical conductivities of slags in the system MgO-Al2O3-SiO2 1972

1424 A review of the World's fluorspar industry, with particular reference to South Africa 1972

1425 The effect of the reactivity of lime on desulphurization efficiency in the basic oxygen furnace 1972

1427 The pressed-fused disc — a technique for the preparation of ore samples to be analysed for uranium by X-ray fluorescence 1972

1428 The separation and determination of trace and minor amounts of individual rare earths li silicates 1972

1430 Th: use of the Ekco Mineral Analyser for the determination of copper and zinc in the presence of iron 1972

1432 The determination of ruthenium and osmium in the residues resulting from the leaching of mattes 1972

1435 The determination of chrorrium, manganese, iron, cobalt, and nickel by atomic-absorption spectrophotometry using he nitrous oxide-acetylene flame 1972

18 MINTEK PUBLICATIONS

No. Title Year

1436 A computer programme for the simulation of the performance of a flotation plant. Revised

report 1973

1438 A mineralogical examination of fluorspar ores from the Ottoshoop area 1972

1439 The reaction of sulphide minerals and thiol compounds 1972

1443 Gravity concentration tests on four samples from Tantalite Valley, S.W.A. 1972

1445 Cost assessments for the production of andalusite concentrates 1972 1447 A preliminary electrochemical investigation of the galena-xanthate-oxygen system in aqueous solution 1972

1448 A potentiostatic study of the anodic dissolution of uranium dioxide in aqueous solutions 1972

1454 A dynamic model for the extraction bank of Purlex plants 1972

1457 Phase equilibria in the Cr-Fe-Si-C system in the composition range representative of high-carbon ferrochromium alloys produced in South Africa 1972

1458 Liquidus temperatures in the Cr-Fe-Si system in the composition range representative of ferrochromium-silicide alloys produced in South Africa 1972

1463 Liquidus temperatures and activities of manganese(ll) oxide in slags associated with the

production of high-carbon ferromanganese alloys 1972

1467 The spectral analysis of solutions. I. The analysis of rare-earth minerals 1972

1476 A magnetic-tape-oriented system for data reduction in neutron-activation analysis 1972

1477 The control of Purlex plants 1972 1478 An examination of two andalusite-bearing samples from Magostad No. 6, Marico district, western Transvaal 1972

1479 Infrared studies of the adsorption of oleate species on mineral surfaces, with special reference to fluorite 1972

1482 Reactions occurring during the smelting of high-car jon ferro^hromium from Transvaal chromite ores 1973

1483 The South African manpower requirements in extracthe metallurgy 1972

1484 Cost estimates for the production of copper wirebars from sulphidic ores 1972

1486 Review of the fluorochemical industry of the World 1972

1488 Extraction of rutile from High veld smelter slags 1972

1489 The breakage of Soderberg electrodes 1972

1490 The adsorption of krypton, nitrogen, and water vapour on sodium oleate 1972

1491 Technology and economics of the Claus kiln under South African conditions 1972

19 MINTEK PUBLICATIONS

No. Title Year

1495 A method for the determination of elemental sulphur on the surface of sulphide minerals 1972

1499 The production of medium-carbon ferrochromium 1972

1500 The chromatographic separation and determination of noble metals in matte-leach residues 1973

1503 Fast-neutron-activation analysis for the determination of oxygen in rock samples 1973

1505 The production of the refractory aluminium silicates, with special reference to South Africa 1973

1508 The selection of economically mineralized pegm-'.ites according to their border-zone characteristics 1973

1509 The instrumentation developed for electrochemical studies of the leaching of uranium oxide 1973

1513 The upgrading of chromite ore from Moreesburg 1973

1514 The determination by X-ray-fluorescence spectrometry of minor amounts of niobium and tantalum in geological materials 1973

1515 A mineralogical investigation of titaniferous magnetite from the Mambula Intrusion, Natal 1973

1517 Computer-controlled flotation plants in Canada and Finland 1973

1521 The dissipation of electrical power in the burden of a submerged-arc furnace 1973

1522 An electron-microprobe investigation of an exsolved mineral in a sample of magnetite 1973

1526 Heat of solution as a control of aqueous-ammonia concentration 1973

1527 The physicochemical properties of slags associated with the smelting of nickel sulphide concentrates 1973

1529 South African costs of equipment for the metallurgical industry (1972) 1973

1530 AUREOL — an X-ray-absorption analyser for the determination of the uranium on loaded resin in ion-exchange plants 1973

1533 Fields of application for dispersive and non-dispersive X-ray-fluorescence instruments 1973

1534 The determination, by atomic-absorption spectrophotometry, of noble metals in the presence of sodium, barium, or sulphate ions. A comparison of uranium and lanthanum as releasing agents 1973

1541 Further tests on beach sands from Bantu Area No. 4, Nhlabane, Zululand 1973

1544 The recovery of salable ferrochromium from material discarded by Ferrometals Limited 1973

1545 A mineralogical investigation of leach residues from the Blyvooruitzicht Gold Mine 1973

1546 Pilot-plant smelting campaign on iron ores from Tete 1973

1547 Physicochemical and thermodynamic properties of slags in the system MgO-AlO^-SiOj 1973

20 MINTEK PUBLICATIONS

No. Title Year

1548 Physicochemical properties of slags in the system MgO-Al2O3-SiO2 and their application to the technology of ferro-alloy smelting 1973

1549 Thermodynamic and related physicochemical factors pertaining to the production of ferromanganese. A literature survey 1973

1550 A fundamental study of the dissolution in acid solutions of uranium minerals from South African ores '973

1552 The preparation and analysis of minerals for use as reference material. Progress report nc. 2 1973

1553 Characterization of the flotation properties of fluorspar from small-scale batch and pilot- plant tests 1973

1555 The analysis, by atomic-absorption spectrophotometry, of matte-leach residues 1973

1556 The spectral analysis of solutions. 2. The analysis of leach liquors, concentrates, slags,

and residues 1973

1557 Cost estimates for the production of pig iron in the Tete district of Mocambique 1973

1559 A cost assessment of the production of elemental sulphur by chlorination roasting 1973

1562 Application of a flotation model to an industrial plant 1973

1563 Neutron-activation analysis of samples from the Kimberley Reef conglomerate 1973

1565 A mineralogical investigation of the vanadium-rich titaniferous iron ore from Tete, and

the slag produced from it 1973

1566 Comparative tests on coke, char, and anthracite 1973

1567 Estimation of the parameters in the distributed-constant flotation model 1974

1568 A computer programme for the estimation of parameters in flotation 1973

1569 The use of DDTU as an analytical reagent for the noble metals 1973

1571 The commissioning of a direct-reading spectrometer for the analysis of silicate rocks by the use of the graphite-pellet technique 1973 1573 A pilot-plant investigation of a flotation model 1974 1574 The chromatographic separation and gravimetric determination of noble metals in matte- leach residues 1973

1575 The recovery of zinc from pickle liquors by ion exchange 1973

1577 Quantitative analysis of fluorite ores by X-ray diffraction 1973

1579 The determination of tin in geochemical-survey samples 1973

1580 The determination of silver in ores, concentrates, and mattes 1973

21 MINTEK PUBLICATIONS

No. Title Year

1581 The computer calculation, f n fundamental parameters, of influence coefficients for X-ray spectrometry 1974

1582 The construction and testing of a precision calorimeter 1973

1583 Preliminary tests on winnowing for the recovery of mica 1973

1587 A preliminary investigation of the flotation of copper-activated sphalerite without the use of collectors 1973

1589 Preliminary investigations into the flotation of tin dioxide, cassiterite, and some related gangue minerals 1973

1590 The separation of osmium from ruthenium in hydrochloric acid solutions 1974

1591 The inductive measurement of conductivity in slags 1974

1592 The determination of line intensities in the presence of interfering spectra in dispersive X-ray-fluorescence spectrometry 1974

1595 Preliminary tests on low-grade brecciated fluorspar ore from the Ottoshoop district 1973

1597 The role of sulphur in the flotation of sulphide minerals 1974

1598 The use of carbon-rod devices in the determination of noble metals by atomic-absorption spectrophotometry 1974

1599 The analysis of silicate rocks and metallurgical slags by X-ray-fluorescence spectrometry 1974

1600 Dilute-acid leaching of slag from Tete ore 1973

1602 The roasting of Tete slag for the extraction of vanadium 1973

1606 The electrical-resistance characteristics of the charge in the electric reduction furnace 1974

1607 The analysis of ion-exchange resins by X-ray-fluorescence 1974

1609 An interlaboratory analysis of two ferrochromium slags 1974

1611 The X-ray-fluorescence determination of percentage concentrations of niobium and tantalum in ores and minerals 1974

1612 Flotation tests on sulphide-bearing high-grade brecciated and wad ores 1974

1613 The deactivation of copper-activated sphalerite with cyanide 1974

1614 The extraction of rutile from smelter slags 1974

1615 Fluorspar pellets. A survey of the World market and an assessment of future South African production 1974

1617 An electronic differential precision thermometer 1974

1619 Reduction of the chromium in ilmenite concentrates 1974

22 MINTEK PUBLICATIONS

No. Title Year

1620 The recovery of titanium oxide from Tete slag by the sulphate route 1974

1621 Correction for matrix effects in the analysis of solutions by X-ray-fluorescence spectrometry 1974

1622 The electrical conductivity of the charge in a ferrosilicon furnace 1974

1625 The determination of uranium and thorium by use of delayed neutrons 1974

1626 Formation constants of zinc chlorocomplexes in perchlorate medium 1974

1628 The recovery of non-ferrous metals from a secondary blast-furnace slag 1974

1629 The thermodynamics of the formation of complexes of silver with some substituted pyridines 1974

1630 An electrochemical investigation of the dissolution of copper, nickel, and copper-nickel alloys in ammonium carbonate solutions 1974

1632 A mineralogical examination of beach-sand concentrates from a pilot plant at Richards Bay 1974

1635 Magnetic separation tests on Tete slag and ore 1974

1636 Trace elements in diamonds from the Premier, Finsch, and Jagersfontein Mines, and their petrogenetic significance 1975

1638 The determination of trace elements in natural diamonds by instrumental neutron- activation analysis 1975

1639 The determination, by 14MeV neutron-activation analysis, of small amounts of oxygen

and silicon in diamond 1974

1640 A semi-automatic titrimeter for cyanide analysis 1974

1643 Further tests on low-grade brecciated fluorspar ore from the Ottoshoop district 1974

1644 Prospects for the recovery of minerals from the sea 1974

1646 Examination of the methods of analysis for calcium fluoride in fluorspar 1974

1647 The industrial application of KEGOLD electrodes 1974

1649 The establishment of preferred values for a series of fluorspar samples 1974

1650 The production of medium-carbon ferrochromium alloys by solid-state reduction 1974 1652 The identification of diamonds from Premier, Finsch, and Jagersfontein Mines, by

statistical analysis of data obtained from instrumental neutron-activation analysis 1975

1654 The determination of osmium in platiniferous media 1975

1656 The analysis of geological samples for trace elements by direct-reading emission spectrometry 1974 1660 An economic assessment of the production of high-grade fluorspar pellets 1974

23 MINTEK PUBLICATIONS

No. Title Year

1664 The smelting of copper-nickel concentrates in an electric furnace 1974

1665 The determination of minor amounts of antimony in ores and concentrates by atomic- absorption spectrophotometry 1974

1668 An updated summary of the World's fluorspar industry 1974

1669 An assessment of the carbon-rod atomizer for the determination of silver 1974

1670 Neutron-activation analysis of routine mineral-processing samples 1974

1671 Pyrometallurgical retreatment of a slag for the recovery of vanadium 1974

1679 The detection of noble-metal impurities in refined noble-metal solutions by thin-layer

chromatography 1974

1681 The determination of sulphur and phosphorus in chromite 1975

1684 The application of three-phase liquid-liquid extraction to the separation and concentration of noble metals 1974 1685 The METSEP process for the separation and recovery of zinc, iron, and hydrochloric acid from spent pickle liquors 1974

1687 The viscosities and electrical conductivities of slags associated with the production of high- carbon ferromanganese alloys 1975

1688 The analysis of nickel-refining solutions: separation of trace elements by liquid-liquid extraction followed by atomic-absorption measurement 1974

1689 The determination, by atomic-absorption spectrophotometry, of arsenic, selenium, tellurium, antimony, and bismuth on ion-exchange resins 1975

1691 The determination of zirconium and aluminium by 14MeV neutron-activation analysis 1975

1693 Research at the National Institute for Metallurgy on the engineering aspects of copper

electrowinning 1975

1696 The preparation and certification of a reference sample of a precious metal ore 1975

1697 A petrographic and mineralogical investigation of silica samples from the farm Elandskraal

470 JQ, Rustenburg district 1975

1698 Measurement of the electrical resistance of ferrochromium furnace charges 1975

1703 The geochemistry of some selected South African kimberlites and associated heavy minerals 1976 1705 The effects of various matrix elements on the efficiency of the fire-assay procedure using nickel sulphide as the collector 1975 1706 Concentration of magnesite from Apiesbomen, Burgersfort district 1975

1707 The work of the Pyrometallurgy Research Group at the University of the Witwatersrand 1975

24 MINTEK PUBLICATIONS

No. Titie Year

!708 An examination of the suitability of various reducing agents for the production of ferrochromium 1975

1709 The mineralogy, chemistry, and certain aspects of reactivity of chromitite from the Bushveld Igneous Complex 1975

1710 The recovery of scheelite from Shongona, north-western Transvaal 1975

1711 The oxidation of aqueous solutions of ferrous sulphate in a bubble column 1975

1712 The thermodynamics of the formation of chlorocomplexes of nickel and copper(ii) in perchlorate medium 1975

1714 The efficiency of the fire-assay procedure with nickel sulphide as the collector in the determination of platinum, silver, gold, and iridium 1975

1715 Flotation tests on various types of ore from the Ottoshoop district 1975

1717 The use of isothioronium compounds as liquid-liquid extractants 1975

1718 The determination of silver in lead, copper, and zinc concentrates by instrumental neutron- activation analysis 1975

1719 An evaluation of the X-ray-fluorescence analysis of rocks and silicates under routine conditions 1975

1720 The initial development of processes for the direct leaching of iron-nickel-copper mattes containing platinum-group metals, and for the production of ferronickel 1975

1721 A preliminary investigation into the mechanism of depression in the flotation of sulphide minerals 1975

1722 The determination of small amounts of fluoride in uranium compounds by use of an ion-selective electrode 1975

1723 The determination of zirconium and aluminium in zirconium-aluminium alloys 1975

1724 The preparation and reduction of chromite pellets containing a reducing agent 1975

1725 The determination of silica in fluorspar by 14MeV neutron-activation analysis 1975

1726 Mertieite and an unnamed compound of palladium with arsenic and tin in a minerai intergrowth from the Atok Mine 1975

1730 The chromite from the Marico occurrence, western Transvaal, its alteration, and possible reasons for its refractory nature 1975

1732 A mineralogical examination of eight nickel-bearing rocks from the Grasvally Chromite

Mine 1975

1733 A mineralogical investigation of weathered carbonatite from Salpeterkop 1975

1736 The determination, by atomic-absorption spectrophotometry and liquid-liquid extraction, of antimony (parts per million) in ores and concentrates 1975

25 MINTEK PUBLICATIONS

No. Title Year

1739 The determination of trace amounts of noble metals in sulphate media 1975

1741 South African costs of equipment for the metallurgical industry (1975) 1975

1742 The determination of tin in ores, residues, and concentrates by X-ray-fluorescence spectrometry 1975

1744 The refining of the platinum-group metals 1975

1746 The determination, by atomic-absorption spectrophotometry, of minor elements in zinc,

lead, and copper sulphide concentrates 1975

1747 Magnetohydrostatic separation of gold from gravity concentrates 1975

1749 Epithermal-neutron-activation analysis for uranium in Barberton and Bushveld granites 1975

1750 A review of the present and future development of sulphur production in South Africa 1975

1753 Full-scale flotation-plant data for modelling purposes 1975 1754 A new three-dimensional anodic electrode for reduced power consumption during the electrowinning of metals 1975

1761 The determination, by atomic-absorption spectrophotometry, of minor elements in anode sludges and residues 1975

1762 The determination, by instrumental neutron-activation analysis, of some elements in the NIMROC standard reference materials 1975

1764 Correlations of the free-energy and enthalpy changes of the dlu metal ions Ag4, Hg2+,

and Cd2+ with a variety of monodentate Iigands 1975

1768 Some developments in gold extraction from Witwatersrand ores 1975

1769 An evaluation of the low-pressure ammonia-ammonium sulphate system for the leaching of local base-metal sulphides 1976 1770 The spectrophotometric determination of vanadium in chromium-bearing materials 1975

1771 The determination of silver, selenium, tellurium, antimony, tin, lead, and arsenic in anode sludges 1975

1772 A study of copper recovery by the lime-roast leach process 1975

1776 The extraction of copper from copper-nickel catholyte by cation exchange 1975

1777 Ferro-alloys in Brazil 1976

1778 An apparatus for the automatic measurement of current efficiencies during the uuii of nickel in chloride media 1976

1779 A summary of work done on the concentration of andalusite from deposits in the western Transvaal 1976

1781 The determination, by ion-selective electrode, of fluoride in complex materials 1976

26 MINTEK PUBLICATIONS

No. Title Year

1782 The application of air-sparging techniques to industrial electrodeposition of zinc from acidic zinc sulphate solutions 1976

1783 The spectrographic determination of minor and trace elements in copper, lead, and zinc concentrates 1976

1784 A single-standard calibration method for use in analysis by X-ray-fluorescence spectrometry 1976

1785 Some thermodynamic aspects of systems relevant to the flotation of sphalerite 1976

1787 The determination, by atomic-absorption spectrophotometry, of trace elements in sulphide concentrates 1976

1788 A computer programme for emission-spectrographic calculations 1976

1790 The rapid determination of manganese, vanadium, and aluminium by instrumental neutron-activation analysis 1976

1791 A motivation for a pyrometallurgical pilot plant 1976

1792 The determination, by instrumental neutron-activation analysis, of some trace elements in sulphide ores and concentrates 1976

1793 The kinetics of mechanism of solvent extraction of copper by LIX 64N and KELEX 100 1976

1794 The application of three-phase liquid-liquid extraction to the analysis of bismuth and tellurium in sulphide concentrates 1976

1795 The determination of minor and trace elements in the leach liquors from anode sludges 1976

1796 The mechanism of the electrodeposition and dissolution of nickel from chloride media 1976

1797 A rapid atomic-absorption method for the determination of silver in sulphide ores and concentrates 1976

1798 Interferences in the determination, by atomic-absorption spectrophotometry, of copper, lead, and zinc in sulphide concentrates 1976

1799 An electrochemical investigation of copper cementation on iron 1976

1800 An electrochemical investigation of the dissolution and passivation of platinum in acid solutions 1976

1803 The preparation and analysis of minerals for use as reference material. Progress report

no. 3 1976

1804 The electrodeposition of nickel from ammoniacal solutions 1976

1807 The establishment of preferred values for a series of rare-earth samples 1976 1808 Spectrophotometric determination (with pyrocatechol violet as chromogenic agent) of aluminium in zirconium metals and in the residues from anode sludges 1976

27 MINTEK PUBLICATIONS

No. Title Year

1809 The analysis, by flameless atomic-absorption spectrophotometry, of pure selenium and tellurium 1976

1812 List of unrestricted NIM reports and papers published during the first decade of NIM's existence (1966 to 1975) [superseded by Report 1894] 1976

1813 The economic potential of some pegmatites from the Kenhardt area in relation to the trace-element content of their border zones 1976

1814 An updated summary of the World's fluorspar industry, 1975 1976

1815 The commissioning of an induction-coupled plasma system and its application to the analysis of copper, lead, and zinc concentrates 1976

1817 The rapid determination by X-ray-fluorescence spectrometry of tungsten in tungsten ores

and concentrates 1976

1818 A microprocessor-based system to control the feed to a ferro-alloy furnace 1976

1820 The thermodynamics of the formation of chlorocomplexes of iron(iii), cobalt(ii), iron(ii),

manganese(ll), and copper(ii) in perchlorate medium 1976

1822 Stability constants and linear free-energy relations for the platinum-group metals 1976

1823 The recovery of gold and pyrite from a residue dump at Crown Mines 1976

1825 The full automation of a Philips 1220 X-ray spectrometer 1976 1826 Dithiocarbamate as a releasing agent in the atomic-absorption determination of noble metals in organic media 1976

1828 7-picoline adducts of the nickel, copper, and zinc chelates of 2-thenoyltrifluoroacetone 1976

1829 An investigation of weathered carbonatite from Salpeterkop 1976

1830 The determination of iron in zircon beach sands and its leachability 1977

1833 Effective thermal conductivities of packed beds of chromite ores 1976 1834 The analysis of slag and silicate samples with a fully automatic sequential X-ray spectrometer 1976

1836 The analysis of pilot-plant products for copper, zinc, and lead with Telsec Lab-X-250 Analyser 1977

1837 The rapid and precise determination of noble metals in matte-leach residues by atomic- absorption spectrophotometry 1976

1838 An investigation of the atomic-absorption spectrophotometric measurement of the elements that form gaseous hydrides and their determination in metal sulphide concentrates 1976

1839 A valence-bond study of dialkalis and alkali hydrides 1977

1840 The spectrophotometric determination of total uranium in silicate ores and leach liquors by use of bromo-PADAP 1976

28 MINTEK PUBLICATIONS

No. Title Year

1841 The determination of acid-soluble uranium in silicate ores and solutions 1976

1843 The treatment of Athlone Sewerage-plant effluent by the DESAL process 1976

1844 An electrochemical and kinetic investigation of the behaviour of gold in chloride solutions.

II. The anodic dissolution of gold 1976

1845 The composition and mode of occurrence of gold in Witwatersrand ores and leach residues 1976

1846 An electrochemical and kinetic investigation of the behaviour of gold in chloride solutions.

III. The gold(iii)/gold(i) reaction on platinum and the disproportionation of gold(i) 1976

1847 A pilot-plant investigation of a kinetic model for flotation 1976

1848 An electrochemical and kinetic investigation of the behaviour of gold in chloride solutions. I. The cathodic deposition of gold 1976 1852 A revised method for the dissolution of platiniferous materials by the sealed-tube technique [superseding Report 1401] 1976

1853 Chloromethylation of polystyrene resins 1977

1854 The interaction of pyrite, oxygen, and xanthate 1977

1856 A study of model systems in anion exchange 1977

1857 The determination of some trace elements in sulphide concentrates by spectrophotometry 1977 1858 The kinetics and mechanism of the non-oxidative dissolution of some iron sulphides in aqueous acidic solutions 1976

1859 Increased current efficiency during electrodeposition of manganese from sulphate electrolytes 1976

1860 A preliminary investigation of materials of construction for ore hoppers 1976

1861 The determination of some impurities in zirconium metal by instrumental neutron- activation analysis 1976

1864 The preparation of primary standard solutions for each of the noble metals 1977

1865 A sensitive method for the measurement of osmium by atomic-absorption spectrophotometry 1977

1867 NIM decennial review (1966 to 1976) 1977

1868 The reduction of fluxed and non-fluxed manganese ores by ferromanganese suicide 1977

1869 The separation and determination of trace elements in iron ore 1977

1871 Batch and pilot-plant flotation tests on copper-nickel ore from the Uitkomst ore-body 1976

1872 The determination of mercury by cold-vapour atomic-absorption spectrophotometry 1977

1873 The rapid reduction of gamma-ray spectra with a desk-top calculator 1977

29 MINTEK PUBLICATIONS

No. rule Year

1874 Activation analysis and classification to source of samples from the Kimberley Reef conglomerates 1977

1875 The determination of tungsten and iron in ferrotungsten alloys by X-ray-fluorescence spectrometry 1977

1876 The determination, by ultrasonic measurement, of the mud level in a thickener and the

resin level in an ion-exchange column 1977

1878 The electrochemical dissolution of galena in aqueous solutions 1977

1879 Alkalis in the iron blast furnace 1977

1880 The electrochemical reduction of silver chloride and its application to the refining of silver 1977

1881 n-octylaniline, a new treatment for noble metals 1977

1883 The determination of iron, chromium, titanium, and tungsten in ores and other materials,

by X-ray-fluorescence spectrometry 1977

1884 The use of capacitance probes for the determination of interfaces 1977

1885 A data-logging system for a submerged-arc ferro-alloy furnace 1977

1886 A rapid method for the determination of fluoride in geological samples 1977 1888 The Imperial Smelting Process and its application to the smelting of complex zinc-lead- copper ores 1977 1889 Entropy relations in the formation of complexes of silver(i), mercury(ii), and cadmium(ii) with monodentate ligands 1977

1894 List of unrestricted NIM publications issued from 1966 to 1977 [superseded by Report 1970] 1977

1895 A review of applications of plasma technology with particular reference to ferro-alloy production 1977

1896 The interaction of chalcocite, oxygen, and xanthates 1977

1897 A study of aggregation in the organic phase of solvent-extraction systems and its influence

on the extraction process 1977

1898 Batch and pilot-plant tests on Merensky Reef ore from the Western Platinum Mine 1977

1899 The production of stainless steel in South Africa 1977

1902 The determination of boron in aluminium of high purity 1977

1904 Separation of rare earths from solutions of phosphoric acid 1977

1905 An examination of fire-assay techniques as applied to chromite-bearing materials 1977 1906 An automated instrument for measuring the effects of impurities on cathodic-current efficiency during the electrowinning of zinc 1977

30 MINTEK PUBLICATIONS

No. Title Year

1907 The application of the induction-coupled plasma system to spectral analysis 1977

1908 An analysis of the replies to a questionnaire on materials of construction for ore hoppers 1977

1911 Methods for the analysis of zinc-bearing materials, electrolytes, and process solutions 1977

1912 The determination, by X-ray-fluorescence spectrometry, of noble and base metals in matte- leach residues 1977

1913 The mechanism and rate of reduction of Mamatwan manganese-ore fines by carbon 1977

1914 The thermodynamics of the formation of sulphate complexes of iron(lll), cobalt(li), iron(ii), rranganese(ii), and copper(ii) in perchlorate medium 1977

1917 The instru nental neutron-activation analysis of granites from the Bush veld Complex 1978

1919 The determination, by X-ray-fluorescence spectrometry, of gold in activated charcoal 1977

1920 A mineralogical investigation of Mamatwan and Wessels manganese ores 1977

1924 The composition of chromite grains from various Witwatersrand reefs 1977

1926 The analysis of anode sludges by X-ray-fluorescence spectrometry 1978

1928 A liquid-nitrogen monitor for lithium-drifted germanium detectors 1977

1931 The equilibrium between the slag and the metal in the production of low-carbon ferromanganese 1977

1932 A basic computer programme for the evaluation of intensity data from the Telsec Lab-X-250 Analyser 1978

1933 The determination of trace elements by thin-film X-ray-fluorescence spectrometry, and its application to zirconium 1977

1934 The spectrometric analysis of chromium-bearing materials with particular reference to ferrochromium slags and chromite ores 1977

1935 The construction and testing of a small mixer-settler for use in the laboratory 1977

1936 The analysis of mineralogical and metallurgical materials. A guide to the analytical techniques and instrumentation available at the National Institute for Metallurgy 1978

1939 An industrial microprocessor system 1978

1940 The extraction of the noble metals with «-octylaniline, and its application to the analysis of platinum-bearing materials 1978

1941 The recovery of chromite and platinum from the UG-2 Upper Chromitite Layer of the Bushveld Complex at the Pandora Mine 1978

1942 The accuracy of assays for platinum-group metals and gold on flotation tailings of platinum ores from the Merensky Reef 1977

31 MINTEK PUBLICATIONS

No. Title Year

1943 A review of the literature on the separation and determination of rare-earth elements 1978

1945 Analyses of the NIMROC reference samples for minor and trace elements 1978

1947 The cation- and anion-exchange behaviour of various base-metal chlorides in polar organic solvents 1978

1948 The measurement of trace amounts of gold in solution by atomic-absorption spectrophotometry and carbon-rod atomization 1978

1949 The kinetics of the leaching of zinc sulphide concentrates in acidic solutions containing ferric sulphate 1978

1950 Factors affecting the carbon contents of alloys formed during the prereduction of chromite ores 1978

1951 Potentialities and limitations of four-parameter equations for the correlation of formation constants of metal-ion complexes in aqueous solution 1978

1952 The effect of slag composition on copper losses to silica-saturated iron silicate slags 1978

1953 A fundamental investigation into the depression of copper-activated sphalerite 1978

1956 An improved ion-exchange separation of rare-earth elements for spectrographic analysis 1978

1957 Solid-state reduction, by graphite and carbon monoxide, of chromite from the Bushveld Complex 1978

1958 A mineralogical examination of sulphide-bearing chromitite from the Loskop Dam area 1978

1959 The slag-metal equilibrium and the activities of slag and metal components in the production of high-carbon ferromanganese 1978

1960 The recovery of ferrochromium furnace slags and related products 1976

1962 Supergene alteration of sulphide ores. I. Literature survey, measurement, and effect on floatability and teachability 1978

1963 An evaluation of the methods used at the National Institute for Metallurgy for the analysis

of base-metal sulphide concentrates 1978

1964 The separation, by anion exchange, of noble metals on substituted cellulose 1978

1965 Analyses, by several laboratories, of three ferromanganese slags 1978

1966 A mineralogical investigation of ores from the Merensky Reef and their flotation products 1978 1967 The movement of the burden in submerged-arc furnace, for the production of high-carbon ferromanganese 1978

1968 The influence of carbonaceous reducing agents on the rate of reduction of representative manganese and chromium ores 1978

1969 The interaction of silicon monoxide gas with carbonaceous reducing agents 1978

32 MINTEK PUBLICATIONS

No. Title Year

1970 List of unrestricted NIM publications issued from 1966 to 1978 [superseded by Report 2013] 1978

1971 The effect of open- and closed-circuit operation in the copper-cleaning flotation circuit

of a complex sulphide ore 1978

1972 The preparation and certification of a reference sample of high-carbon ferrochromium 1978

1975 Reactions in the production of high-carbon ferromanganese from Mamatwan ore 1978

1976 The preparation and certification of two samples of chromium ore 1978

1977 The preparation and certification of a reference sample of hematite ore 1978

1978 The preparation and certification of a reference sample of magnetite ore 1978

1979 An electrochemical and kinetic investigation of the behaviour of gold in chloride solutions. IV. Results obtained from Phase 2 of the investigation 1978 1982 The resistivity of mixtures of Mamatwan manganese ore and reducing agents 1978

1984 The commissioning of the AEI MS702 mass spectrometer 1978

1985 The determination of boron in high-purity aluminium metal by spark-source mass spectrometry 1978

1988 The effect of panicles on the stability of flotation froths 1978

1991 The determination, by atomic-absorption spectrophotometry, of europium in phosphoric

acid and in rare-earth oxides 1978

1992 The use of optical emission spectrometry for the determination of impurities in metals 1979

1996 The extraction of gold from chloride solutions 1978

1997 A laboratory investigation of reducing agents for use in the electric-smelting industry 1979

1998 Electrode response to the addition of zinc during the cementation of gold 1979

2001 An assessment of vibrating viscometers on slurries 1979

2002 The spectrochemical determination of phosphorus, magnesium, and iron in phosphate rocks and sulphuric acid leach liquors 1979 2003 An electrodeless conductivity meter of improved sensitivity and reliability 1979

2004 Laboratory and pilot-plant tests on ore from the Witkop fluorspar mine 1979

2005 The spectrometric analysis of manganese-bearing materials, with particular reference to ferromanganese slags and metals 1979

2006 An examination of procedures for the analysis of dry powders by atomic-absorption spectrophotometry 1979

33 MINTEK PUBLICATIONS

No. Title Year

2007 The instrumentation and computerization of a 25MV-A submerged-arc furnace 1977

2009 A review of the activities of the NIM Measurement and Control Engineering Research

Group 1979

2010D A process for the recovery of mixed rare-earth oxides from monazite 1979

2011 The analysis of anode sludges, and their process solutions and beneficiation products 1979

2012 A mineralogical investigation of borehole cores from the Trompsburg Complex 1979

2013 List of unrestricted NIM publications issued from 1966 to 1979 [superseded by Report 2067] 1979 2014 The determination, by spark-source mass spectrometry, of chlorine and phosphorus in high-purity tungsten oxide 1979

2015 The preparation of synthetic standards for instrumental neutron-activation analysis 1979

2016 Analysis of the NIMROC reference samples for major elements 1979

2017 Vanadium-bearing titaniferous iron ores from the Rooiwater, Usushwana, Mambula, Kaffirskraal, and Trompsburg Igneous Complexes 1979

2018 Supergene alteration of sulphide ores. II. The effect on the floatability of chalcopyrite, galena, and sphalerite 1979

2020 The prereduction of Mamatwan-type ores 1979

2022 The determination of thallium and indium in sulphide concentrates 1979

2023 Atomic-absorption spectrophotometry with hydride generation: an improved technique 1979

2025 The determination of uranium in solids and solutions by X-ray-fluorescence spectrometry and a background-ratio method with a derived exponent 1979

2026 The determination of uranium in pyrite samples 1979

2029 The commissioning of a 5 kW inductively coupled plasma unit for use with a 3,4 m Ebert spectrograph 1979

2030 Chemical unhomogeneity of sphalerite in a base-metal sulphide deposit 1979

2032 The Cancer Project: a summary of the computer-aided operation of a 48MV-A ferrochromium furnace 1979

2034 A rapid method for the determination of uranium in ores and carbonaceous materials

by X-ray-fluorescence spectrometry 1980

2036 The determination of thallium in ores, concentrates, and metals 1980

2037 The removal of contaminants from recycled water in a mineral-flotation plant 1980

2038 Leaching of sphalerite in acidic ferric sulphate media in the absence of elemental oxygen 1980

34 MINTEK PUBLICATIONS

No. Title Year

2039 The determination of free acid in the presence of hydrolysable cations 1980

2040 A solid-state constant-current power unit for the magnetic analyser of the MS702R mass spectrometer 1980

2042 The preparation and analysis of minerals for use as reference material. Progress report no. 4 1980

2044 The separation and determination of anions by ion chromatography 1980

2051 The supergene alteration of sulphide ores. HI. The influence of the chemistry of sphalerite on its floatability 1980 2052 An investigation of the impurities in native gold by neutron-activation analysis 1980

2053 A study of the measurement, by electrothermal atomization and atomic-absorption spectrophotometry, of hydride-forming elements 1980

2054 The determination, by X-ray spectrometry, of trace amounts of tin in titanium-bearing ores and concentrates and in siliceous materials 1980

2056 The mineralogy and geochemistry of the copper, lead, and zinc sulphides of the Otavi Mountainland 1980

2057 A mineralogical study of the Rooibokkop-Boschhoek copper deposit in the Marble Hall area 1980

2058 An elementary introduction to image analysis — a new field of interest at the National Institute for Metallurgy 1980

2059 Distributed computer control of industrial processes 1980

2060 The analysis, by atomic-absorption spectrophotometry, of activated charcoal 1980

2061 The determination, by anodic-stripping voltammetry, of copper and lead in silicate reference materials 1980

2062 The reduction by computer of phosphate data obtained by spark-source mass spectrometry 1980

2063 Aerosol deposition and carbon-rod atomization of gold 1980

2064 The on-line monitoring of gold in barren solutions 1980

2065 The determination, by X-ray-fluorescence spectrometry, of gold, silver, and base metals

in activated carbon 1980

2067 List of unrestricted NIM publications issued from 1966 to 1980 [superseded by Report M85] 1980

2068 The determination of platinum, palladium, rhodium, and gold in ores and concentrates

by the fusion technique with lead as the collector 1980

2069 Automatic setting of the distance between sample and detector in gamma-ray spectroscopy 1980

2070 The prereduction of chromites from the UG-2 Reef 1980

35 MINTEK PUBLICATIONS

No. Title Year

2071 The determination, by X-ray-fluorescence spectrometry, of tin and tungsten in scheelite

and cassiterite ores and concentrates 1980

2073D A preliminary investigation of the concentration process at Ucar Minerals Corporation 1980

2075 The optimization of some of the conditions for analysis by spark-source mass spectrometry 1980

2076 Wet high-intensity magnetic separation. Laboratory tests conducted in 1978 and 1979 1980

2082 A survey of the literature on gravity separation 1980 2083 The determination, by anodic-stripping voltammetry, of zinc and lead in six NIMROC reference materials 1980

2Gu4 The analysis, by a fusion procedure and X-ray-fluorescence spectrometry, of silicates and

slags 1980

2085 A large-capacity sample changer for automated gamma-ray spectroscopy 1980

2086 An automatic sampling probe for use in the carbon-in-pulp process 1980

2089 An investigation of the confidence limits of the Gastwirth median 1980

2090 Observations made during the dig-out of a 48 MVA ferrochromium furnace 1981

2092D The recovery of pyrite from gold ore by gravity separation 1981

2093 The measurement of electrical variables in a submerged-arc furnace 1981 2094 The determination, by atomic-absorption spectrophotometry, of impurities in manganese dioxide 1981

• 2096D A meter for the measurement of moisture in mill feed 1981

2099 Copper losses and the distribution of impurities in the systems FeO-Fe2O3-SiO2-Al2O3-

Cu and FeO-Fe2O3-SiO2-Al2O3-CaO-Cu at 1300 °C " 1981

2100 The anodic polarization of copper, tin, and copper-tin alloys in fluosilicate solutions 1981

• 2102D The recovery of magnesite from dump fines from the Strathmore Mine 1981

2105 The determination, by anodic-stripping voltammetry, of silver in polymetallic sulphide ores 1981

• 2106D The evaluation of drill cores and a bulk sample from a deposit of andalusite near

Thabazimbi 1981

2107 The separation of some weak-acid anions by ion-exclusion chromatography 1981

• 2108D Evaluation of a grinding aid in batch grinding, classification, and gravity concentration 1981

• 2109D The evaluation of an andalusite deposit at Kleinfontein, Groot Marico 1981

2110 The investigation of a on one side of a skip bridle in a mine shaft 1981

36 MINTEK PUBLICATIONS

No. Title Year

2111 Pilot-plant tests for the recovery of chromite and the noble metals from the UG-2 Reef

at Maandagshoek 1981

2112 The behaviour of UG-2 chromite concentrates during smelting 1981

2113 Multivariable control of a milling circuit at East Driefontein Gold Mine 1981

2115 Estimation of material variation in powdered materials 1981 2116 Optimum operation of a direct-reading spectrometer with excitation by a 5 kW inductively coupled plasma torch 1981

2117 Disc storage of the data obtained from photographic plates in spark-source mass spectrometry 1981

2121 Five robust indicators of central value 1981

2124 The direct determination, by differential pulse anodic-stripping voltammetry at the thin mercury-film electrode, of cadmium, lead, and copper 1981

2126 The determination, by microwave techniques, of the interface between the pulp and the froth 1981

2127 The preparation of a reference material of South African zirconium concentrate from Richards Bay 1981

2128 The determination, by differential pulse anodic-stripping voltammetry at the thin mercury- film electrode, of cadmium and thallium in six NIMROC reference materials 1981

2129 An electrode controller for submerged-arc furnaces 1981

2130 The organizing of conferences 1981

2131 The separation of trace elements in manganese dioxide 1981

2132 The assessment of pellicular anion-exchange resins for the determination of anions by

ion chromatography 1981

2134D On-line analysis, by X-ray diffraction, of fluorspar-containing slurries 1981

2135D On-line analysis, by X-ray diffraction, of pyrite-containing slurries 1981

Ml ICAM 81 1981

M2 The preparation of two reference materials of South African fluorspar 1981

M3 The platinum-group minerals in the UG-2 Layer of the Bushveld Complex at Maandagshoek 254KT 1982 M4 An instrument to detect the position of the froth-pulp interface during flotation 1982

M6 A comparative study of the effects of changes in liner patterns and mill speeds on rod-mill parameters 1982

• M7D The beneficiation of chromite ore from the MG-1 seam near Marikana 1982

37 MINTEK PUBLICATIONS

No. Title Year

M8 A determination, using solid zirconia electrolytes, of the activities of chromium oxide in ferrochromium alloys and slags at 1650 °C 1982

Mil The application of split conditioning to the flotation of coarse particles 1982

M12 A mineralogical investigation of the chlorine content of the fluorspar from a deposit in the Zeerust area 1982 Ml3 Factors affecting the production of fines during the screening and handling of high- carbon ferromanganese 1982

• M14D The liberation and size distribution of products from the plants at the Black Mountain Mine 1982

MIS The separation and determination of trace elements in chromic oxide 1982

M16 The preparation and certification of ten uranium reference materials 1982

• Ml 8D The recovery of pyrite and gold from acid-leach residues from Merriespruit Gold Mine 1982

M19 Beneficiation tests on two samples of bauxite from Natal 1982

• M20D The separation of ore from Cooke into high- and low-grade fractions 1982

M24 Atomic-absorption programmes for the Hewlett Packard H.P.97S programmable

calculator 1982

M28 The measurement of flow velocity distribution in fluids 1982

M29 Interactions between sulphide minerals and metal ions in the activation, deactivation, and depression of mixed-sulphide ores 1982 M31 Software for the design of multivariable control systems by use of the Inverse Nyquist Array 1982

• M33D Exploratory tests on the reduction of the sulphur content of sponge iron 1982

M34 The determination, by atomic-absorption spectrophotometry using electrothermal atomization, of platinum, palladium, rhodium, ruthenium, and iridium 1982 M37 A literature survey of the metallurgical aspects of minerals in Witwatersrand gold ores 1982 The use of masking agents in the determination, by hydride generation and atomic- absorption spectrophotometry, of arsenic, antimony, selenium, tellurium, and bismuth in the presence of noble metals 1982 M40 The use of X-ray-fluorescence spectrometry in the determination of uranium, cobalt, and sulphur in materials from mine dumps 1982

• M42D The recovery of tantalite and cassiterite from a bulk sample of pegmatite 1982

• M43D Beneficiation tests on andalusite-bearing shales from a farm near Thabazimbi 1982

M44 An on-line dilution system for spectrometry using an inductively coupled plasma source 1982 MINTEK PUBLICATIONS

No. Title Year

M45 Two computer programmes for the calculation of mass and heat balances in the production of high-carbon ferromanganese 1982

M47 The separation of trace elements from iron, and the analysis of iron-rich ores for use as reference materials 1982

M49 A programme in BASIC for the appending of computer files 1982

M50 The development of an on-line gold analyser 1982

• M52 A high-speed, multi-input serial-interfacing system with simultaneous back-up recording on magnetic tape 1983 • M53 The development of an automatic sample-changer and con.rol instrumentation for isotope-source neutron-activation analysis 1983

M54 Major amounts of mercury in native gold from upper Witwatersrand sediments 1982

M55 A new robust method for the treatment of analytical data 1982

• M56 A computer programme for the evaluation of process routes in the production of ferrochromium 1983 The hydrometallurgical treatment of liquors generated by the leaching of a low-grade matte 1982

CM59D Testwork on samples of oxidized ore from the Potgietersrus Prospect 1982

• M60D The production of electrolytic manganese dioxide from furnace sludge 1982

M61 An atomic-absorption programme for the Apple II Plus computer 1982

• M62 A preliminary investigation into the extraction of zinc by direct oxidative leaching of

high-manganese sphalerite 1983

M63 A general-purpose data logger 1982

• M64D Isotope-source neutron-activation analysis for the determination of manganese in bulk

samples 1982

• M65 A preliminary survey of the corrosivity of water in gold mines 1983

• M66 A review of corrosion inhibitors.' theory and practice 1983

• M67 The determination of total cyanide in solutions containing uranium and gold 1983

• M68 The suitability of Doppler flowmeters for use in the minerals-processing industry 1983

• M69 The determination, by X-ray-fluorescence spectrometry, of tin and tungsten in ores, concentrates, and residues of scheelite, wolframite, and cassiterite 1983 • M70 The preparation and certification of two reference materials of South African manganese ore 1983

39 MINTEK PUBLICATIONS

No. Title Year

• M76 A mineraJogical investigation of a refractory gold ore, and of a sulphide concentrate and calcined tailing from that ore 1983

• M77 Analysis of the results of a marked-ball test in relation to theories of ball wear in rotary

mills 1983

• M78 An evaluation of the Leeds laboratory-scale flotation cell 1983

• M79 An investigation into the determination by X-ray-fluorescence spectrometry of gold and uranium on resin 1983 • M80 The installation and commissioning of the Siemens SRS200 sequential X-ray- fluorescence spectrometer 1983

• M81 The application of the inductively coupled plasma system to the simultaneous

determination of precious metals 1983

• M83 Arc monitoring on a JOOkVA experimental furnace 1983

The preparation and certification of a uranium reference material 1983

• M85 List of unrestricted Mintek publications issued from 1966 to 1982 [superseded by Special Publication no. 6] 1983 • The recovery of platinum-group metals and gold by the lead-collection step of the fire-

assay procedure 1983

The preparation of beneficiated bauxite for an evaluation of quality 1983

The automation of fusions with sodium peroxide in zirconium crucibles 1983

• M95 Modern applications of polarography and voltammetry to inorganic analysis 1983

• M96 The mathematical modelling of the reduction behaviour of chromite from the Upper Chromitite Layer of the Bushveld Complex ] 983 • M97 Reduction in metal consumption by the use of alternating lines of higher and lower lifter bars in a rod mill 1983

• M98 Multivariable control and optimization of the operation of a milling circuit at East

Driefontein Gold Mine 1983

• M101 The potentiality of heat-treated balls in the grinding of gold ores 1983

• M104 The preparation and analysis of reference materials, and the provision of recommended

values. Progress report No. 5 1983

• Mill The determination, by flow-injection analysis, of iron sulphate, silver, and cadmium 1983

• Ml 13 The selective flotation of South African chromite 1983

• Ml 14 Analytical methods associated with the recovery of uranium 1983

• Ml 16 Abrasive and impactive wear of high-chromium cast-iron grinding balls 1984

40 MINTEK PUBLICATIONS

No. Title Year

• MI17 An assessment of the merits of various types of balls in the milling of ores 1983

• M119 A versatile computer programme for data capture in multi-element analysis by a

sequential X-ray spectrometer 1983 • M120 South African costs of equipment for the metallurgical industry (1983) 1983 • M121 The determination of trace elements in coal by atomic-absorption spectroscopy 1983 • M125 Commissioning of the microphotometer used in spark-source mass spectrometry 1983

41 MINTEK PUBLICATIONS

2. PAPERS BY STAFF

The papers are arranged alphabetically according to author/s, and chronologically below author/s. Co-authors from other organizations are indicated by a series of superscripts, which are explained at the end of the list. These papers are not available from Mintek, but can be consulted in the relevant journals or books to which reference is made. The papers that have been published since the previous issue of this list (Report M85) are marked •.

42 MINTEK PUBLICATIONS

ALBERTS, L. Closing address. INFACON 80. PROCEEDINGS OF THE SECOND INTERNATIONAL FERRO-ALLOYS CONGRESS. Lausanne, Instltut des Producteurs tie Ferro- Alliages d'Europe Occidentale, 1981. pp. 436-443.

ALBERTS, L. Research management by objectives. J. S.Afr. Inst. Min. Metall., vol. 82, no. 6. Jun. 1982. pp. 157-159.

ALBERTS, L. Scientific and technological infrastructure in relation to the security of investments and mineral supplies. PROCEEDINGS, TWELFTH CONGRESS OF THE COUNCIL OF MINING AND METALLURGICAL INSTITUTIONS. Glen, H.W. (ed.). Johannesburg, The South African Institute of Mining and Metallurgy, 1982. vol. 2. pp. 665-671.

ALBERTS, L., LEVIN, J., and LAXEN, P.A. Developments in the extraction of gold from Witwatersrand ores. Trans. Instn Min. Metall., Sec. A.: Mining Industry, vol. 90. Jul. 81. pp. AI43-A148.

• ALLISON, S.A., DUNNE, R.C., and DE WAAL, S.A. The flotation of gold and pyrite from South African gold-mine residues. PREPRINTS — XIV INTERNATIONAL MINERAL PROCESSING CONGRESS •'WORLDWIDE INDUSTRIAL APPLICATION OF MINERAL PROCESSING TECHNOLOGY". Ottawa, The Canadian Institute of Mining and Metallurgy, 1982. pp. II-9.1 to II-9.18.

ALLISON, S.A., and FINKELSTEIN, N.P. A study of the products of reaction between galena and aqueous xanthate solutions. Trans. Instn Min. Metall., vol. 80, no. 781. Dec. 1971. pp. C235-C239.

ALLISON, S.A., GOOLD, L.A., NICOL, M.J., and GRANVILLE, A. The products of reaction between sulphide minerals and aqueous xanthate solutions, and a correlation of the products with electrode rest potentials. Metall. Trans., vol. 3, no. 10. Oct. 1972. pp. 2613-2618.

ALLISON, S.A., HARRIS, P.J., and MARSICANO, F. Depression and deactivation of sphalerite. J. S.Afr. Inst. Min. Metall., vol. 76, spec, issue. Oct. 1975. pp. 123-124.

AMTHAUER, G.36, McIVER, J.R.2, and VILJOEN, E.A. 57Fe and "9Sn Mössbauer studies of natural tin-bearing garnets. Phys. Chem. Miner., vol. 4. 1979. pp. 235-244.

ANDEWEG, A.H. A large capacity sample changer for fully automated gamma ray spectroscopy. IEEE Trans. Nucl. Sci., vol. NS-27, no. 1. Feb. 1980. pp. 728-732.

ASHURST, K.G., and FINKELSTEIN, N.P. The influence of sulphydryl and cationic flotation reagents on the cyanidation of native gold. J. S.Afr. Inst. Min. Metall., vol. 70, no. 6, pt 2. Jan. 1970. pp. 248-256.

ASHURST, K.G., FINKELSTEIN, N.P., and GOOLD, L.A. The coordination numbers of cyanide complexes of zinc, cadmium, and mercury in aqueous solution. J. Chem. Soc. (A), 1971. pp. 1899-1902.

ASHURST, K.G., FINKELSTEIN, N.P., and RICE, N.M. Studies of cyanide-xanthate mixed-ligand complexes of mercury(ii). J. Chem. Soc. (A), 1970. pp. 2302-2307.

ASHURST, K.G., and HANCOCK, R.D. Characterization of inner- and outer-sphere complexes by thermodynamics and absorption spectra. Part 1. Sulphato-complexes of the first-row transition elements. J. Chem. Soc, Dalton Trans., 1977. pp. 1701-1707.

ASHURST, K.G., and HANCOCK, R.D. The characterization of inner- and outer-sphere complexes by thermodynamics and absorption spectra. Part 2. Chloro-complexes of copper. J. Chem. Soc., Dalton Trans., 1981. pp. 245-250.

ASHURST, K.G., and NEALE, R.W. The porosity of gold electrodeposits. Trans. Inst. Metal Finishing, vol. 45, no. 2. 1967. pp. 75-82.

43 MINTEK PUBLICATIONS

ATMORE, R.B.', HOWAT, D.D.% and JOCHENS, P.R. The effect of slag and gold bullion composition on the removal of copper from mine bullion by oxygen injection. J. S.Afr. Inst. Min. MetalL, vol. 72, no. 1. 1971. pp. 5-11.

AUSTEN, C.E., and STEELE, T.W. The computer calculation, from fundamental parameters, of influence coefficients for X-ray spectrometry. ADVANCES IN X-RAY ANALYSIS. Pickles, W.L., Barrett, C.S., Newkirk, J.B., and Rund, CO. (eds.). London, Plenum Press, 1975. vol. 18. pp. 362-371.

BALAES, G.E.E., DIXON, K., RUSSELL, G.M., and WALL, G.J. Analysis of activated carbon, as used in the carbon-in-pulp process, for gold and eight other constituents. S.Afr. J. Chem., vol. 35, no. 1. 1982. pp. 4-8.

BARCZA, N.A. Slag-metal equilibrium in the production of low-carbon ferromanganese. J. S.Afr. Inst. Min. MetalL, vol. 79, no. 10. May 1979. pp. 269-280.

BARCZA, N.A., CURR, T.R., WINSHIP, W.D.45, and HEANLEY, C.P/6 The production of ferrochromium in a transferred-arc plasma furnace. 39TH ELECTRIC FURNACE CONFERENCE PROCEEDINGS. Houston, Iron and Steel Society of AIME, 1982. pp. 243-260.

BARCZA, N.A., FEATHERSTONE, R.A.20, and FINN, C.W.P. Recent developments in the ferro-alloy field in South Africa. PROCEEDINGS, TWELFTH CONGRESS OF THE COUNCIL OF MINING AND METALLURGICAL INSTITUTIONS. Glen, H.W. (ed.). Johannesburg, The South African Institute of Mining and Metallurgy, 1982. vol. 2. pp. 595-604.

BARCZA, N.A., JOCHENS, P.R., and HOWAT, D.D.2 The mechanism and kinetics of reduction of Transvaal chromite ores. 29TH ELECTRIC FURNACE CONFERENCE PROCEEDINGS. Metallurgical Society of AIME. New York, AIME, 1972. vol. 29. pp. 88-93.

BARCZA, N.A., KOURSARIS, A., SEE, J.B., and GERICKE, W.A.29 The 'dig out' of a 75 MV-A high-carbon ferromanganese electric smelting furnace. 37TH ELECTRIC FURNACE CONFERENCE PROCEEDINGS. Detroit, AIME, 1979. pp. 19-33.

BARCZA, N.A., and O'SHAUGHNESSY, D.P.30 Optimum slag-alloy relationships for the production of medium- to low-carbon ferromanganese. Canad. Metall. Q., vol. 20, no. 3. 1981. pp. 285-294.

BARKER, I. J. Arcing in the electrical circuit of a submerged-arc furnace. Elektrowarme Int., vol. 38, no. Bl. Feb. 1980. pp. B28-B32.

• BARKER, I.J., and HULBERT, D.G. Dynamic behaviour in the control of milling circuits. 4THIFAC SYMPOSIUM ON AUTOMATION IN MINING, MINERAL AND METAL PROCESSING. PREPRINTS. Westerlund, T. (ed.). Helsinki, Finnish Society of Automatic Control, 1983. pp. 101-115.

BARKER, I.J., and KING, R.P.2 A real-time recursive filter applied to a milling circuit to estimate particle-size distributions. AUTOMATION IN MINING, MINERAL AND METAL PROCESSING. Lancaster, F.H. (ed.). Pretoria, South African Council for Automation and Computation, 1977. pp. 263-275.

BARKER, I.J., and STEWART, A.B. Inductive reactance, and the operation of large submerged-arc furnaces. /. S.Afr. Inst. Min. Metall., vol. 80, no. 3. Mar. 1980. pp. 123-128.

• BARNES, A.R., FINN, C.W.P., and ALGIE, S.H. The prereduction and smelting of chromite concentrate of low chromium-to-iron ratio. J. S.Afr. Inst. Min. Metall., vol. 83, no. 3. Mar. 1983. pp. 49-54.

BATRA, K.3, SEE, J.B., and KING, T.B.4 Flow behaviour of liquid metals on solid substrates. Metal Sci., vol. 11, no. 5. May 1977. pp. 145-151.

44 MINTEK PUBLICATIONS

BERNING, J.5, COOKE, R.6, HIEMSTRA, S.A., and HOFFMAN, U.5 The Rössing uranium deposit, South West Africa. Econ. Geol., vol. 71. 1976. pp. 351-368.

BIBBY, D.M., and RASMUSSEN, S.E. Reactor neutron flux monitoring with iron foils. Radiochem. Radioanalyt. Lett., vol. 9, no. 1. 1972. pp. 1-8.

BIBBY, D.M., and RASMUSSEN, S.E. Performance of a counting head for an automatic sample changer. Radiochem. Radioanalyt. Lett., vol. 14, no. 1. 1973. pp. 9-15.

BIBBY, D.M., and SELLSCHOP, J.P.F.2 Determination of copper, zinc, iron, and silicon in copper/zinc ore flotation products by fast neutrons. Radiochem. Radioanalyt. Lett., vol. 12, no. 4-5. 1972. pp. 245-257.

BIBBY, D.M., and SELLSCHOP, J.P.F.2 The determination of oxygen and silicon in diamonds by 14MeV activation analysis. J. Radioanalyt. Chem., vol. 22. 1974. pp. 103-131.

• BIRKETT, M.D. Electrowinning and refining of other metals [cadmium, chromium, gallium, antimony, tellurium, tin, lead, nickel]. VACATION SCHOOL: ELECTROMETALLURGY. Johannesburg, The South African Institute of Mining and Metallurgy, 1983. pp. 279-2%.

BOEYENS, J.C.A. Electrostatic calculation of bond energy. J. S.Afr. Chem. lnst., vol. 26, no. 3. 1973. pp. 94-105.

BOEYENS, J.C.A., and HAEGELE, R. Oxygen as a di-/a-peroxo bridge; synthesic and structure of benzyltrimethylammonium-di-^i-peroxohexachlorodiuranyl(Vi). Inorg. Chim. Ada, vol. 20. 1976. p. L7.

BOEYENS, J.C.A., McDOUGALL, G.J., and SMIT, J.V.R.- Crystallographic study of the ammonium-potassium 12-molybdophosphate ion-exchange system. J. Solid State Chem., vol. 18. 1976. pp. 191-199.

BOYDELL, D.W.7, LAXEN, P.A., BOSCH, D.W.8, and CRAIG, W.M.7 New uranium-recovery circuit at Blyvooruitzicht. CIM Bull., vol. 72, no. 805. May 1979. pp. 127-134.

BOYDELL, D.W., and VILJOEN, E.B." Uranium processing in South Africa from 1961 to 1981. PROCEEDINGS, TWELFTH CONGRESS OF THE COUNCIL OF MINING AND METALLURGICAL INSTITUTIONS. Glen, H.W. (ed.). Johannesburg, The South African Institute of Mining and Metallurgy, 1982. vol. 2. pp. 575-582.

BRAAE, M., GRAY, G.T.42, HULBERT, D.G., and WALSH, H.P.43 A microprocessor-based multivariable controller. PROCEEDINGS, TWELFTH CONGRESS OF THE COUNCIL OF MINING AND METALLURGICAL INSTITUTIONS. Glen, H. W. (ed.). Johannesburg, The South African Institute of Mining and Metallurgy, 1982. vol. 2. pp. 827-831.

BRAAE, M., and HULBERT, D.G. A suite for the computer-aided design of control systems. Pulse, Jul. 1981. pp. 18-23.

BRAAE, M., and RUTHERFORD, D.A.9 Fuzzy relations in a control setting. Kybernetes, vol. 7. 1978. pp. 185-188.

BRAAE, M., and RUTHERFORD, D.A.9 Selection of parameters for a fuzzy logic controller. Fuzzy Sets and Systems, vol. 2. 1979. pp. 185-199.

BRAAE, M., and RUTHERFORD, D.A.9 Theoretical and linguistic aspects of the fuzzy logic controller. Automatica, vol. 15, no. 5. Sep. 1979. pp. 553-577.

45 MINTEK PUBLICATIONS

BRENNER, I.B.27, WATSON, A.E., RUSSELL, G.M., and GONCALVES, M. A new approach to the determination of the major and minor constituents in silicate and phosphate rocks. Chem. Geol., vol. 28. 1980. pp. 321-330.

BRENNER, I.B.27, WATSON, A.E., STEELE, T.W., JONES, E.A., and GONCALVES, M. Application of an argon-nitrogen inductively coupled radiofrequency plasma (ICP) to the analysis of geological and related materials for their rare earth contents. Spectrochim. Ada, vol. 36B, no. 8. 1981. pp. 785-797.

BROOKS, H.C.10, and PAUL, R.L. Densities and excess volumes of fused halides. Z. Naturforsch., vol. 30a. 1975. pp. 64-6G.

BRYNARD, H.J., DE VILLIERS, J.P.R., and VILJOEN, E.A. A mineralogical investigation of the Merensky Reef at the Western Platinum Mine, near Marikana, South Africa. Econ. Geot., vol. 71, no. 7. 1976. pp. 1299-1307.

BUCHANAN, D.L.14, NOLAN, J.37, and VILJOEN, E.A. Determination of silica activity in Bushveld rocks. Contrib. Min. Pet., vol. 73. 1980. pp. 311-319.

BUSHELL, L.A., and VEITCH, M.L. The influence of chemical environment during milling on the flotation of zinc from complex sulphide ores. J. S.Afr. Inst. Min. Metall., vol. 76, spec, issue. Oct. 1975. pp. 143-145.

• CARTWRIGHT, A. Fundamental aspects of electrocrystallization. VACATION SCHOOL: ELECTROMETALLURGY. Johannesburg, The South African Institute of Mining and Metallurgy, 1983. pp. 55-84.

CARTWRIGHT, A., and PAUL, R.L. A study of the mechanism of manganese dioxide deposition. MANGANESE DIOXIDE SYMPOSIUM, TOKYO, 1980. Schumm, B. Jnr, Joseph, H.M., andKozawa, A. (compilers). Cleveland (U.S.A.), I.C. MnO2 Sample Office, 1981. vol. 2. pp. 290-304.

CHANNON, W.P., and SEE, J.B. The reduction of fluxed and non-fluxed manganese ores by ferromanganese suicide. J. S.Afr. Inst. Min. Metal/., vol. 77, no. 8. Mar. 1977. pp. 151-162.

CHANNON, W.P., URQUHART, R.C., and HOW AT, D.D.2 The mode of current transfer between electrode and slag in the submerged-arc furnace. J. S.Afr. Inst. Min. Metall., vol. 75, no. 1. Aug. 1974. pp. 4-7.

CLARKE, P.J. The National Institute for Metallurgy, South Africa. Stahl und Eisen, vol. 97, no. 18. 8th Sep., 1977. pp. 895-899.

CLARKE, P.J. A new centre for metallurgical research — the National Institute for Metallurgy in Randburg. Afrika-Post, vol. 24, no. 11. Nov. 1977. pp. 337-340. (In German.)

CLARKE, P.J. Recent progress of the National 'nstitute for Metallurgy. Metall, vol. 32, no. 3. Mar. 1978. pp. 288-289. (In German.)

CLARKE, P.J. Mineral expansion — spotlight on research. Processing, vol. 1, no. 1. 1980. pp. 15-16,21.

CLARKE, P.J. Carbon and the recovery of gold — some developments by the National Institute for Metallurgy. Metall, vol. 34, no. 2. Feb. 1980. pp. 128-131.

CLARKE, P.J. South Africa's National Institute for Metallurgy. Int. J. Miner. Processing, vol. 6, no. 4. Feb. 1980. pp. 341-347.

CLOETE, F.L.D. The Relix process for the resin-in-pulp recovery of uranium. J. S.Afr. Inst. Min. Metall., vol. 81, no. 3. Mar. 1981. pp. 66-73.

46 MINTEK PUBLICATIONS

COALE, R.D.2, WOLHUTER, C.W.2, JOCHENS, P.R., and HOWAT, D.D.2 Cementitious properties of metallurgical slags. Cem. Concr. Res., vol. 3, no. 1. 1973. pp. 81-92.

COLBORN, R.P.\ and NICOL, M.J. An investigation into the kinetics and mechanism of the oxidation of iron(il) by oxygen in aqueous chloride solutions. J. S.A/r. Inst. Mitt. MetalL, vol. 73, no. 9. Apr. 1975. pp. 281-289.

COOK, E.B.T., and GEREGHTY, A. The spectrophotometric determination of uranium by use of 2-(2-pyridylazo)-5-diethylaminophenol (PADAP). Bull. S.Afr. Inst. Assayers Analysts, no. 12. Jul. 1971. pp. 1-10.

COPELOWITZ, I., and LOVEDAY, B.K. An analysis of continuous resin contacting. HydrometalL, vol. 4. 1979. pp. 259-268.

CORRANS, I. J. A development in the application of wet high-intensity magnetic separation. FINE PARTICLES PROCESSING. Somasundaran, P. New York, American Institute of Mining, Metallurgical and Petroleum Engineers Inc., 1980. vol. 2. pp. 1294-1309.

CORRANS, I.J., BRUGMAN, C.F.39, OVERBEEK, P.W., and McRAE, L.B. The recovery of platinum-group metals from ore of the UG-2 Reef in the Bushveld Complex. PROCEEDINGS, TWELFTH CONGRESS OF THE COUNCIL OF MINING AND METALLURGICAL INSTITUTIONS. Glen, H. W. (ed.). Johannesburg, The South African Institute of Mining and Metallurgy, 1982. vol. 2. pp. 629-634.

• CORRANS, I.J., DUNNE, R.C., and ALLISON, S.A. The recovery of platinum-group metals from the chromite reefs of the Bushveld Complex. PREPRINTS — XIV INTERNATIONAL MINERAL PROCESSING CONGRESS "WORLDWIDE INDUSTRIAL APPLICATION OF MINERAL PROCESSING TECHNOLOGY". Ottawa, The Canadian Institute of Mining and Metallurgy, 1982. pp. II-10.1 to 11-10.21.

• CORRANS, I.J., GILBERT, W.A.32, LIDDELL, K.S., and DUNNE, R.C. The performance of an industrial wet high-intensity magnetic separator for the recovery of gold and uranium. J. S.Afr. Inst. Min. Metall., vol. 84, no. 3. Mar. 1984. pp. 57-63.

CORRANS, I.J., and LEVIN, J. Wet high-intensity magnetic separation for the concentration of Witwatersrand gold-uranium ores and residues. J. S.Afr. Inst. Min. Metall., vol. 79, no. 8. Mar. 1979. pp. 210-228.

CRAIG, W.M.7, HAINES, A.K., NICOL, D.I., OLËN, CM., DOUGLAS, M.E.E.", and LOUW, G.D.8 The design and operation of a continuous ion-exchange demonstration plant for the recovery of uranium. J. S.Afr. Inst. Min. Metall., vol. 78, no. 12. Jul. 1978. pp. 316-324.

• CUNLIFF, J. de B. Practical considerations in the electrowinning and electrorefining of metals. VACATION SCHOOL: ELECTROMETALLURGY. Johannesburg, The South African Institute of Mining and Metallurgy, 1983. pp. 123-149.

• CURR, T.R., BARCZA, N.A., MASKE, K.U., and MOONEY, J.F. The design and operation of transferred-arc plasma systems for pyrometallurgical applications. 6TH INTERNATIONAL SYMPOSIUM ON PLASMA CHEMISTRY. Boulos, M.I., andMunz, R.J. (eds.). Sherbrooke (Canada), Université de Sherbrooke, 1983. vol. 1, pp. 175-180.

CZAMANSKE, G.K., and MIHALIK, P. Oxidation during magnetic differentiation, Jinmoskia Complex, Oslo area, Norway: Part 1. The opaque oxides. J. Petrol., vol. 13, no. 3. pp. 493-509.

• DANN, M.S. Variable turns ratio inductance transducer for measurement of translational displacement. J. Phys. E. Sci. Instrum., vol. 17, no. 3. Mar. 1984. pp. 184-185.

47 MINTEK PUBLICATIONS

DE VILLIERS, J.P.R. The of braunite with reference to its solid-solution behaviour. Am. Mineralogist, vol. 60. 1975. pp. 1098-1104.

DE VILLIERS, J.P.R. The crystal structure of braunite u and its relation to bixbyite and braunite. Am. Mineralogist, vol. 65. 1980. pp. 756-765.

DE VILLIERS, J.P.R., and BOEYENS, J.C.A. Crystal structure of a calcium sulphate-urea complex. J. Cryst. Mol. Struct., vol. 5. 1975. pp. 215-226.

• DE VILLIERS, J.P.R., ORMROD, G.T.W., and COLE, A.E.4' On-stream analysis, by X-ray diffraction, of apatite-containing slurries. ICAM 81. PROCEEDINGS OF THE FIRST INTERNATIONAL CONGRESS ON APPLIED MINERALOGY. De Villiers, J.P.R., and Cawthorn, P.A. (eds.). Johannesburg, The Geological Society of South Africa, 1983. pp. 435-442.

DE WAAL, S.A. Ramsdellite from the Hotazel Mine, northern Cape Province, South Africa. Eton. Geol., vol. 64, no. 2. 1969. pp. 221-222.

DE WAAL, S.A. On the origin of hydrogrossularite and other calcium silicates in serpentinites. Trans. Geol. Soc. S.Afr, vol. 72, pt 1. Jan.-Mar. 1969. pp. 23-27.

DE WAAL, S.A. Nickel minerals from Barberton, South Africa: I. Ferroan trevorite. Am. Mineralogist, vol. 54, no. 7/8. Jul.-Aug. 1969. pp. 1204-1208.

DE WAAL, S.A. Interference-folding of Bushveld Igneous Complex age in the Transvaal System north of Marble Hall, Transvaal. Johannesburg, The Geological Society of South Africa, spec. pub. 1, 1970. pp. 283-298.

DE WAAL, S.A. Nickel minerals from Barberton, South Africa: II. Nimite, a nickel-rich chlorite. Am. Mineralogist, vol. 55, no. 1/2. Jan.-Feb. 1970. pp. 18-30.

DE WAAL, S.A. Nickel minerals from Barberton, South Africa: III. Willemseite, a nickel-rich talc. Am. Mineralogist, vol. 55, no. 1/2. Jan.-Feb. 1970. pp. 31-42.

DE WAAL, S.A. South African nickeliferous serpentinites. Miner. Sci. Engng, vol. 3, no. 2. Apr. 1971. pp. 32-45.

DE WAAL, S.A. The Bushveld granites in the Zaaiplaats area. Trans. Geol. Soc. S.Afr., vol. 75, pt 2. May-Aug. 1972. pp. 135-144.

DE WAAL, S.A. Nickel minerals from Barberton, South Africa: V. Trevorite redescribed. Am. Mineralogist, vol. 57, no. 9/10. Sep.-Oct. 1972. pp. 1524-1527.

DE WAAL, S.A. The ferromanganese deposit at Lisbon Falls, near Graskop, Transvaal, and its similarity to ferromanganese nodules of the ocean floor. Trans. Geol. Soc. S.Afr., vol. 80, pt 2. 1977. pp. 131-136.

DE WAAL, S.A. Carbon dioxide and water from metamorphic reactions as agents for sulphide and precipitation in mafic magmas. Trans. Geol. Soc. S.Afr., vol. 80, pt 3. 1977. pp. 193-196.

DE WAAL, S.A. The alteration and possible reasons for the refractory nature of chromitite from the Marico occurrence, western Transvaal. Trans. Geol. Soc. S.Afr., vol. 80, pt 3. 1977. pp. 235-239.

DE WAAL, S.A. The nickel deposit at Bon Accord, Barberton, South Africa — a proposed paleometeorite. Mineralization in metamorphic terranes. Johannesburg, The Geological Society of South Africa, spec. pub. 4, 1978. pp. 87-98.

48 MINTEK PUBLICATIONS

DE WAAL, S.A. Nickel minerals from Barberton, South Africa: VIII. The spinels chochromite and nichromite and their significance to the Bon Accord nickel deposit. Bull. B.R.G.M., Section II, no. 3. 1978. pp. 225-230.

DE WAAL, S.A. The metamorphism of the Bon Accord nickel deposit by the Nelspruit Granite. Trans. Geol. Soc. S.Afr., vol. 82, no. 3. Sep.-Dec. 1979. pp. 335-342.

DE WAAL, S.A. Neoformed supergene sphalerite and possible precipitation control by gahnite. Bull. Miner., vol. 104. 1981. pp. 732-736.

• DE WAAL, S.A. The effects of supergene alteration on the chemistry and floatability of sphalerite. ICAM 81. PROCEEDINGS OF THE FIRST INTERNATIONAL CONGRESS ON APPLIED MINERALOGY. De Villiers, J.P.R., andCawthorn, P.A. (eds.). Johannesburg, The Geological Society of South Africa, 1983. pp. 245-251.

DE WAAL, S.A., and CALK, L.C.12 Nickel minerals from Barberton, South Africa: VI. Liebenbergite, a nickel olivine. Am. Mineralogist, vol. 58, no. 7/8. Jul.-Aug. 1973. pp. 733-735.

DE WAAL, S.A., and CALK, L.C.12 The sulfides in the garnet pyroxenite xenoliths from Salt Lake Crater, Ohio. J. Petrol., vol. 16, no. 1. Feb. 1975. pp. 134-153.

DE WAAL, S.A., and HERZBERG, W. Uranium and gold mineralization of the Black Reef Series in the Kaapse Hoop area, Nelspruit District, eastern Transvaal. Annals Geol. Surv. S.Afr., vol. 7. 1968-1969. pp. 111-124.

DE WAAL, S.A., and JOHNSON. J.A. Chemical heterogeneity of sphalerite in a base metal sulfide deposit. Econ. Geol., vol. 76. 1981. pp. 694-705.

DE WAAL, S.A., and VILJOEN, E.A. Nickel minerals from Barberton, South Africa: IV. Reevesite, a member of the hydrotalcite group. Am. Mineralogist, vol. 56, no. 5/6. May-Jun. 1971. pp. 1077-1081.

DE WAAL, S.A., VILJOEN, E.A., and CALK, L.C.12 Nickel minerals from Barberton, South Africa. VII. Bonaccordite, the nickel analogue of ludwigite. Trans. Geol. Soc. S.Afr., vol. 77, pt 3. Sep.-Dec. 1974. p. 375.

DUS, H.M., and SMITH, D.J. Factors affecting the resistivity and reactivity of carbonaceous reducing agents for the electric-smelting industry. J. S.Afr. Inst. Min. Metall., vol. 80, no. 8. Aug. 1980. pp. 286-296.

• DIPPENAAR, A. The destabilization of froth by solids. I. The mechanism of film rupture. Int. J. Miner. Process., vol. 9. 1982. pp. 1-14.

• DIPPENAAR, A. The destabilization of froth by solids. II. The rate determining step. Int. J. Miner. Process., vol. 9. 1982. pp. 15-27.

DIXON, K., RUSSELL, G.M., WALL, G., and EDDY, B. The analysis of anode slimes, especially copper slimes, by instrumental techniques. Talanta, vol. 26, no. 9. Sep. 1979. pp. 833-839.

EALES, H.V.35, and VILJOEN, E.A. Determination of the silver content of natural gold alloys by reflected light microscopy. Trans. Instn Min. Metall., vol. 82. 1973. pp. B47-B50.

EDDY, B.T. Instrumental neutron-activation analysis of uranium reference materials. Geostand. Newsl., vol. 6, no. 1. Apr. 1982. pp. 83-89,

EDDY, B.T., WATTERSON, J.I.W., and ERASMUS, C.S. Preparation of synthetic standards for use in instrumental neutron activation analysis. Geostand. Newsl., vol. 4, no. 2. Oct. 1980. pp. 229-237.

49 MINTEK PUBLICATIONS

EDWARDS, R.I. Selective solvent ex tract ants for the refining of platinum metals. PROCEEDINGS OF THE INTERNA TIONAL SOL VENT EXTRACTION CONFERENCE ISEC 77. Toronto, Canadian Institute of Mining and Metallurgy, 1979. (CIM Special Volume 21). vol. 1. pp. 24-31.

ELLIOT, B.J., SEE, J.B., and RANKIN, W.J. Effect of slag composition on copper losses to silica- saturated iron silicate slags. Trans. Instn Min. Metall., vol. 87. Sep. 1978. pp. C204-C211.

ELLIS, P.J. The theoretical grain index, an index for use in the assessment of analyte segregation in powdered material. Powder Technol., vol. 30, no. 2. Nov.-Dec. 1981. pp. 225-236.

ELLIS, P.J., COPELOWITZ, I., and STEELE, T.W. The estimation of the mode by the dominant cluster method. Geostand. Newsl., vol. 1, no. 2. Oct. 1977. pp. 123-130.

ENGELBRECHT, J.A., and WOODBURN, E.T.10 The effects of froth height, aeration rate, and gas precipitation on flotation. J. S.A/r. Inst. Min. Metall., vol. 76, spec, issue. Oct. 1975. pp. 125-132.

ENGLISH, R.B.31, HAINES, R.J.10, and STEEN, N.D.C.T. Synthesis and molecular structure of [Rh4(/z-PPh2)4(/i-CO)2(CO)4], an edge-bridged tetrahedral cluster of rhodium. S.Afr. J. Chem., vol. 34, no. 3. 1981. pp. 88-89.

ERASMUS, C.S., and BOEYENS, J.C.A.13 Crystal structure of the praseodynium 0-diketonate of 2,2,6,6-tetramethyl-3,5-heptanedione, Pr2(thd)6. Ada Crystallographica, vol. B26, pt 11. Nov. 1970. pp. 1843-1854.

ERASMUS, C.S., and BOEYENS, J.C.A.13 Crystal and molecular structure of tris (2,2,6,6-tetramethyl-3,5-heptanedionato) aquodysprosium(lli), Dy(thd),H,O. J. Cryst. Mol. Struct., vol. 1. 1971. pp. 83-91.

ERASMUS, C.S., FESQ, H.W.7, KABLE, E.J.D., RASMUSSEN, S.E., and SELLSCHOP, J.P.F.2 The NIMROC samples as reference materials for neutron activation analysis. J. Radioanalyt. Chem., vol. 39. 1977. pp. 323-334.

ERASMUS, C.S.. NOVAK, E., and SELLSCHOP, J.P.F.2 The determination of copper in native gold by radiochemical separation and neutron-activation analysis. ABSRACTS, 5TH SYMPOSIUM ON RECENT DEVELOPMENTS IN ACTIVATION ANALYSIS. Geel (Belgium), Central Bureau for Nuclear Measurements, Joint Research Centre of the European Communities, pp. 126 (a, b, c, d).

ERASMUS, C.S., SARGEANT, J., SELLSCHOP, J.P.F.2, and WATTERSON, J.I.W. Multielement analysis of air and water pollutants in gold mines by thermal and epithermal neutron activation. METHODS AND STANDARDS FOR ENVIRONMENTAL MEASUREMENT PROCEEDINGS OF THE8THIMR SYMPOSIUM. Kirchoff, W.H. (ed.). Washington, National Bureau of Standards, spec, pub. 464. pp. 129-136.

ERASMUS, C.S., SELLSCHOP, J.P.F.2, BIBBY, D.M., FESQ., H.W.7, KABLE, E.J.D., KEDDY, R.J., HAWKINS, D.M.2, MINGAY, D.W., RASMUSSEN, S.E., RENAN, M.J., and WATTERSON, J.I.W. Natural diamonds — major, minor and trace impurities in relation to source and physical properties. J. Radioanalyt. Chem., vol. 38. 1977. pp. 133-146.

FARBACH, D.O.E.2, HOWAT, D.D.2, and JOCHENS, P.R. Comparison of techniques for determining the resistance of refractories to slag attack. Trans. Br. Ceram. Soc, vol. 68, no. 4. 1969. pp. 151-158.

FAURE, A.1, and TUNLEY, T.H. Uranium recovery by liquid-liquid extraction in South Africa. THE RECOVERY OF URANIUM. International Atomic Energy Agency. Vienna, the Agency, 1971. pp. 241-251.

50 MINTEK PUBLICATIONS

FESQ, H.W.7, BIBBY, D.M., SELLSCHOP, J.P.F.2, and WATTERSON, J.I.W. The determination of trace-element impurities in natural diamonds by instrumental neutron-activation analysis. J. Radioanalyt. Chem., vol. 17. 1973. pp. 195-216.

FESQ, H.W.7, KABLE, E.J.D., and GURNEY, J.J.2 Aspects of the geochemistry of kimberlites from the Premier Mine and other selected South African occurrences with particular reference to the rare earth elements. PHYSICS AND CHEMISTRY OF THE EARTH. Ahrens, L.H., Dawson, J.B., Duncan, A.R., and Erlank, A.J. (eds.). Oxford, Pergamon, 1975. vol. 9. pp. 687-707.

FILMER, A.O. The non-oxidative dissolution of nickel mattes in aqueous acidic solutions. J. S.Afr. Inst. Min. Metall., vol. 81, no. 3. Mar. 1981. pp. 74-84.

FILMER, A.O. The dissolution of gold from roasted pyrite concentrates. J. S.Afr. Inst. Min. Metall., vol. 82, no. 3. Mar. 1982. pp. 90-94.

FILMER, A.O., and BALESTRA, P.E.L. The non-oxidative dissolution of nickel concentrate in aqueous acidic solutions. J. S.Afr. Inst. Min. Metall., vol. 81, no. 1. Jan. 1981. pp. 26-32.

FILMER, A.O., and NICOL, M.J. The non-oxidative dissolution of nickel sulphides in aqueous acidic solutions. J. S.Afr. Inst. Min. Metall., vol. 80, no. 12. Dec. 1980. pp. 415-424.

FINKELSTEIN, N.P. Kinetic and thermodynamic aspects of the interaction between potassium ethyl xanthate and oxygen in aqueous solution. Trans. Instn Min. Metall., vol. 76, no. 724. Mar. 1967. pp. C51-C59.

FINKELSTEIN, N.P. The influence of alkyltrimethyl ammonium halides on the stability of potassium ethyl xanthate in aqueous solution. J. Appl. Chem., vol. 19. Mar. 1969. pp. 73-76.

FINKELSTEIN, N.P. Quantitative aspects of the role of oxygen in the interaction between xanthate and galena. Sepn Sci., vol. 5, no. 3. Jun. 1970. pp. 227-256.

FINKELSTEIN, N.P. The chemistry of the extraction of gold from its ores. GOLD METALLURGY IN SOUTH AFRICA. Adamson, R.J. (ed.). Johannesburg, Chamber of Mines of South Africa, 1972. pp. 284-351.

FINKELSTEIN, N.P. The rate of decomposition of alkaline xanthate solutions. Colloid Polymer Sci., vol. 255. 1977. pp. 168-169.

FINKELSTEIN, N.P., and ALLISON, S.A. The chemistry of activation, deactivation and depression in the flotation of zinc sulphide: a review. FLOTATION, A.M. GAUDIN MEMORIAL VOLUME. Fuerstenau, M.C. (ed.). New York, American Institute of Mining, Metallurgical and Petroleum Engineers Inc., 1976. vol. 1. pp. 414-457.

FINKELSTEIN, N.P., ALLISON, S.A., LOVELL, V.M., and STEWART, B.V. Natural and induced hydrophobicity in sulphide mineral systems. ADVANCES IN INTERFACIAL PHENOMENA OF P'ARTICULATE/SOLUTION'/GAS SYSTEMS; APPLICATION TO FLOTATION RESEARCH. Somasundaran, P., and Grieves, R.B. (eds.). New York, AIChE, Chemical Engineering Progress Symposium Series no. 13, 1975.

FINKELSTEIN, N.P., and HANCOCK, R.D. A new approach to the chemistry of gold. Gold Bull., vol. 7, no. 3. Jul. 1974. pp. 72-77.

FINKELSTEIN, N.P., and LOVELL, V.M. Fundamental studies of the flotation process: the work of the National Institute for Metallurgy. J. S.Afr. Inst. Min. Metall., vol. 72, no. 12. Jul. 1972. pp. 328-341.

51 MINTEK PUBLICATIONS

FINKELSTEIN, N.P., and POLING, G. W. The role of dithiolates in the flotation of sulphide minerals. Miner. Sci. Engng, vol. 9, no. 4. Oct. 1977. pp. 177-197.

FINN, C.W.P. Spotlight on INFACON 80. J. S.Afr. Inst. Min. Metall., vol. 81, no. 5. May 1981. pp. 136-138.

FINN, C.W.P., and KUCUKKARAGOZ, C.S. Reaction mechanisms for the prereduction of Winterveld chrome spinels. INFACON 80. PROCEEDINGS OF THE SECOND INTERNATIONAL FERRO- ALLOYS CONGRESS. Lausanne, Institut des Producteurs de Ferro-Alliages d'Europe Occidentale, 1981. pp. 149-230(i).

FINN, C.W.P., and WELLBELOVED, D.B. Determination of the activities of Cr and Cr2O3 in slag- metal systems of ferrochromium smelting composition using stabilized zirconia electrolytes. Solid State Ionics, vol. 2, pt 3/4. 1981. pp. 547-550.

FLEMING, C.A. Origin of the selectivity of LIX65N and KELEX 100 for copperd) over iron(iii). Trans. Instn Min. Metall., vol. 85. Dec. 1976. pp. C211-C212.

FLEMING, C.A. The origin of the selectivity of oxines and oximes for copper(ii) over iron(iii). Trans. Instn Min. Metall., vol. 88. Dec. 1979. pp. C253-C255.

FLEMING, C.A. Some aspects of the chemistry of carbon-in-pulp and resin-in-pulp processes. PAPERS PRESENTED AT THE SEMINAR ON CARBON-IN-PULP TECHNOLOGY FOR THE EXTRACTION OF GOLD. Kalgoorlie (Australia), The Australasian Institute of Mining and Metallurgy, 1982. pp. 397-422.

• FLEMING, C.A. Recent developments in carbon-in-pulp technology in South Africa. HYDROMETALLURGY — RESEARCH, DEVELOPMENT AND PLANT PRACTICE. Osseo-Asare, K., and Miller, J.D. (eds.). Warrendale (U.S.A.), The Metallurgical Society of AIME, 1982. pp. 839-857.

FLEMING, C.A., GREEN, B.R, and ASHURST, K.G. The origin of the selectivity of oxines and oximes for copperdi) over iron(iil). PROCEEDINGS, INTERNATIONAL SOLVENT EXTRACTION CONFERENCE, ISEC 80. Association des Ingénieurs feds.). Liége, Université de Liége, 1980. vol. 2. p. 224.

FLEMING, C.A., and HANCOCK, R.D. The mechanism in the poisoning of anion-exchange resins by cobalt cyanide complexes. J. S.Afr. Inst. Min. Metall., vol. 79, no. 11. Jun. 1979. pp. 334-341.

FLEMING, C.A., and MONHEMIUS, A.J.14 On the extraction of various base metal chlorides from polar organic solvents into cation and anion exchange resins. Hydrometall., vol. 4, no. 2. Mar. 1979. pp. 159-167.

FLEMING, C.A., and NICOL, M.J. A comparative study of kinetic models for the extraction of uranium by strong-base anion-exchange resins. /. S.Afr. Inst. Min. Metall., vol. 80, no. 2. Feb. 1980. pp. 89-99.

FLEMING, C.A., and NICOL, M.J. The kinetics and mechanism of solvent extraction of Fe(Hl) and Cu(ii) by oxine reagents. I. The aqueous-phase reaction between Fe(iii) and 8-hydroxy quinoline. J. Inorg. Nucl. Cfiem., vol. 42. 1980. pp. 1327-1334.

FLEMING, C.A., and NICOL, M.J. The kinetics and mechanism of solvent extraction of Fe(iii) and Cu(ii) by oxine reagents. II. The extraction of Fe(lii) into a toluene solution of 8-hydroxyquinoIine. J. Inorg. Nucl. Chem., vol. 42. 1980. pp. 1335-1339.

FLEMING, C.A., and NICOL, M.J. Alternative processes to filtration: carbon-in-pulp and resin-in- pulp in the metallurgical industry. HYDROMETALLURGY 81. London, the Society, 1981. pp. C2/1 to C2/16.

52 MJNTEK PUBLICATIONS

FLEMING, C.A., NICOL, M.J., HANCOCK, R.D., and FINKELSTEIN, N.P. The kinetics of the extraction of copper by L1X65N and the catalytic role of L1X63 in this reaction. J. Appl. Chem. Biotechnol., vol. 28. 1978. pp. 443-452.

FLEMING, C.A., NICOL, M.J., HANCOCK, R.D., and FINKELSTEIN, N.P. The kinetics of the extraction of copper by LIX64N. Discussion of the rate law. INTERNATIONAL SOLVENT EXTRACTION CONFERENCE. Lucas, B.H., et al. {eds.). Montreal, Canadian Institute of Mining and Metallurgy, 1979. pp. 193-197.

FLETCHER, G. W. Process control. GOLD METALLURGY IN SOUTH AFRICA. Adamson, R.J. fed.). Johannesburg, Chamber of Mines of South Africa, 1972. pp. 256-283.

FORD, M.A., SMITS, G., and McCULLOCH, H.W.7 The recovery of uranium with molybdenum as a byproduct from deposits in the Karoo. PROCEEDINGS. TWELFTH CONGRESS OF THE COUNCIL OF MINING AND METALLURGICAL INSTITUTIONS. Glen, H.W. (ed.). Johannesburg, The South African Institute of Mining and Metallurgy, 1982. vol. 2. pp. 583-593.

FRICK, C.M, and VILJOEN, E.A. The De Hoek meteorite: a plessitic octahedrite from South Africa. S.Afr. J. Sci., vol. 69. 1973. pp. 310-312.

FRICK, C.M, and VILJOEN, E.A. The Etosha meteorite: a medium octahedrite from South West Africa. S.Afr. J. Sci., vol. 69. 1973. pp. 345-348.

FRITZ, J.S.47, GJERDE, D.T.48, and POHLANDT, C. Ion chromatography. New York, Hiithig, 1982. 213 pp.

FROST, F., and GLASSER, D.: An apparatus for fractional ion-exchange separation. PROCEEDINGS CONFERENCE ON ION EXCHANGE IN THE PROCESS INDUSTRIES. London, Society of Chemical Industry, 1970. pp. 188-194.

GASPARRINI, E. Electron-microprobe quantitative analysis by energy-dispersive spectrometry. PROCEEDINGS, ELECTRON MICROSCOPY SOCIETY OF SOUTHERN AFRICA, PRETORIA CONFERENCE. Durban, the Society, 1975. vol. 5. pp. 121-122.

GASPARRINI, E. The energy-dispersive spectrometer: a new tool of investigation for the earth scientist. Miner. Sci. Engng, vol. 81, no. 1. Jan. 1976. pp. 3-22.

GASPARRINI, E., and HIEMSTRA, S.A. Paolovite (Pd2Sn) from the Atok Mine in the Merensky Reef. Trans. Geol. Soc. S.Afr., vol. 78. 1975. pp. 167-169.

GAUDIN, A.M.4, and FINKELSTEIN, N.P. Interactions in the system galena-potassium ethyl xanthate-oxygen. Nature, Lond., vol. 207, no. 4995. Jul. 1965. pp. 389-391.

GIESEKKE, E.W. Spectroscopie studies on surface reactions between minerals and reagents in flotation systems. SURFACE SCIENCE AND ITS INDUSTRIAL IMPLICATIONS. Gries, W.H., and Crooke, M. (eds.). Pretoria, CSIR, 1981. pp. 229-236.

• GIESEKKE, E.W. A review of spectroscopie techniques applied to the study of interactions between minerals and reagents in flotation systems. Int. J. Miner. Process., vol. 11. 1983. pp. 19-56.

GLEN, H.W. (ed.). INFACON 74. Proceedings of the First International Ferro-alloys Congress, Johannesburg, 22nd to 26th April, 1974. Johannesburg, The South African Institute of Mining and Metallurgy, 1975. 320 pp.

GLEN, H.W. (ed.). South Africa's strategic minerals — pieces on a continental chess board, by W.C.J. van Rensburg and D.A. Pretorius. Johannesburg, Valiant Publishers, 1977. 172 pp.

53 M1NTEK PUBLICATIONS

GLEN, H.W. (ed.). Proceedings of Asbestos Symposium, Johannesburg, 3rd-7th October, 1977. Johannesburg, Department of Mines, 1978. 1S6 pp.

GLEN, H.W. Technical English — a 'dead' language. J. S.Afr. Inst. Min. Metall., vol. 79, no. 13. Aug. 1979. pp. 382-385.

GLEN, H.W. User attitudes to scientific editing: just change the was's and weré's. J. Res. Commun. Studies, vol. 3. 1981. pp. 221-227.

GLEN, H.W. Spotlight on the Council for Mineral Technology (Mintek). J. S.Afr. Inst. Min. Metall., vol. 81, no. 12. Dec. 1981. pp. 352-353.

GLEN, H.W. (ed.). Proceedings, Twelfth Congress of the Council of Mining and Metallurgical Institutions. Johannesburg, The South African Institute of Mining and Metallurgy, 1982.2 vols., 1060 pp.

GOOLD, L.A., LIN, I.J., LOVELL, V.M., and FINKELSTEIN, N.P. Oil-levitation extraction: a variation of flotation. J. S.Afr. Inst. Min. Metall., vol. 76, spec, issue. Oct. 1975. pp. 132-134.

GÖSSLING, H.H., and McCULLOCH, H.W. Fluorspar — the use of a non-metallic mineral. Miner. Sci. Engng, vol. 6, no. 4. Oct. 1974. pp. 206-222.

GOSSMAN, G.I.40, HULBERT, D.G., KOUDSTAAL, J.13, BRAAE, M., and BUNCOMBE, A41. The application of computer control to a gold-milling circuit at East Driefontein Gold Mine. PROCEEDINGS, TWELFTH CONGRESS OF THE COUNCIL OF MINING AND METALLURGICAL INSTITUTIONS. Glen, H. W. (ed.). Johannesburg, The South African Institute of Mining and Metallurgy, 1982. vol. 2. pp. 817-825.

GRANVILLE, A. The recovery of deep-sea minerals: problems and prospects. Miner. Sci. Engng, vol. 7, no. 3. Jul. 1975. pp. 170-188.

GRANVILLE, A., FINKELSTEIN, N.P., and ALLISON, S.A. Review of reactions in the flotation system galena-xanthate-oxygen. Trans. Instn Min. Metall., vol. 81, no. 784. 1972. pp. C1-C30.

GRAY, G.T. The design and implementation of a microcomputer system for the control of a submerged arc furnace. PROCEEDINGS OF THE 6THIFAC/IFIP CONFERENCE ON DIGITAL COMPUTER APPLICATION TO PROCESS CONTROL. Isermann, R., and Kaltenecker, H. feds.). Oxford, Pergamon, 1981. pp. 91-102.

GRAY, G.T., and POTGIETER, J.H. Experience with the introduction of microprocessor systems into industry. Pulse, Jan. 1979. pp. 18-20.

GRAY, G.T., and RODD, M.G.15 The development of an extended macro-assembler for the production of microprocessor software. Trans. S.Afr. Inst. Elec. Engrs, vol. 69, no. 7. Jul. 1978. pp. 201-205.

GREEN, B.R., and HANCOCK, R.D. Diluent-modified impregnates for the selective extraction of copper. Sepn Sci. Techno!., vol. 15, no. 5. 1980. pp. 1229-1241.

GREEN, B.R., and HANCOCK, R.D. The role of matrix effects on selectivity in ion-exchange resins. Hydrometall., vol. 6. 1981. pp. 353-363.

GREEN, B.R., and HANCOCK, R.D. Recent advances in the development of resins for use in hydrometallurgy. HYDROMETALLURGY8I. London, Society of Chemical Industry, 1981. pp. E6/1- E6/13.

GREEN, B.R., and HANCOCK, R.D. Useful resins for the selective extraction of copper, nickel, and cobalt. J. S.Afr. Inst. Min. Metall., vol. 82, no. 10. Oct. 1982. pp. 303-307.

54 MINTEK PUBLICATIONS

GRIMSLEY, W.D., SEE, J.B., and KING, R.P.2 The mechanism and rate of reduction of Mamatwan manganese-ore fines by carbon. J. S.Afr. Inst. Min. Metall., vol. 78, no. 3. Oct. 1977. pp. 51-62.

GUEST, R.N. A laboratory investigation of the importance of the circulating load in the control of particle-size distribution. J. S.Afr. Mech. Engrs, vol. 22, no. 2. Feb. 1972. pp. 46-51.

GUEST, R.N. The recovery of pyrite from Witwatersrand gold ores. J. S.Afr. fnst. Min. Metall., vol. 76, spec, issue. Oct. 1975. pp. 103-105.

GUEST, R.N. Reichert cones for Witwateii.-ind gold ores. J. S.Afr. Inst. Min. Metall., vol. 82, no. 8. Aug. 1982. pp. 227-232.

GURNEY, J.J.2, FESQ, H.W.7, and KABLE, E.J.D. Clinopyroxene-ilmenite xenolites from kimberlites. LESOTHO KIMBERLITES. Nixon, P.H. fed.). Maseru, Lesotho National Development Corporation, 1973. pp. 238-254.

HAEGELE, R., and BOEYENS, J.C.A. Crystal structure of benzyltrimethylammonium fi2-peroxo- bis[trichlorodioxouranate(Vi>], a binuclear uranium complex containing dioxygen in a fi2-pemxo linkage. J. Chem. Soc, Dalton Trans., 1977. pp. 648-650.

HAINES, A.K. The develoj nent of continuous fluidized-bed ion exchange in South Africa, and its use in the recovery of uraniun. J. S.Afr. Inst. Min. Metall., vol. 78, no. 12. Jul. 1978. pp. 303-315.

HAINES, A.K., CRAIG, W.M.7, FAURE, A.7, HENDRIKSZ, A.R.7, WILLS, W.J.7, and NICOL, D.I. The use of weak-base resins in the recovery of uranium from unclarified leach liquors. ELEVENTH INTERNA TIONAL MINERAL PROCESSING CONGRESS. Instituto diArte Mineraria. Rome, Aziende Tipografiche Bardi, 1976. Paper 32, pp. 1-28.

HAINES, A.K., EDWARDS, R.I., and TE RIELE, W.A.M. The separation of gold from acidic leach liquors with Amberlite XAD-7. THE THEORY AND PRACTICE OF ION EXCHANGE. Streat, M. fed.). London, Society of Chemical Industry, 1976. pp. 40.1-40.12.

HAINES, A.K., KING, R.P., and WOODBURN, E.T.10 The interrelationship between bubble motion and solids mixing in a gas-fluidized bed. AIChE, vol. 18, no. 3. May 1972. pp. 591-599.

HAINES, A.K., TUNLEY, T.H., TE RIELE, W.A.M., CLOETE, F.L.D., and SAMPSON, T.D.16 The recovery of zinc from pickle liquors by ion exchange. J. S.Afr. Inst. Min. Metall., vol. 74, no. 4. Nov. 1973. pp. 149-157.

HAINES, R.J.10, and STEEN, N.D.C.T. Synthesis and molecular structure of [Rhi(fi-PPh2)3(fX-Cl)2(fi-CO)(CO)3], a unique triangular rhodium cluster derivative. J. Chem. Soc, Chem. Commun. 057. 1981. pp. 407-408.

HAINES, R.J.10, STEEN, N.D.C.T., and ENGLISH, R B.31 Synthesis and molecular structure of [Rh3(/z-PPh2)3(CO5)], an edge-bridged triangular cluster of rhodium. J. Organometall. Chem., no. 209. 1981. pp. C34-C36.

HAINES, R.J.'0, STEEN, N.D.T.C., and ENGLISH, R.B.31 Synthesis and X-ray crystal and molecular structure of [{RhFe(/i-PPh2)2-(/x-CO)(CO)3j2], an unusual tetranuclear compound with a straight-chain structure. J. Chem. Soc, Chem. Commun. 144. 1981. pp. 587-588.

HAINES, R.J.'0, STEEN, N.D.C.T., LAING, M.'°, and SOMMERVILLE, P.10 A non-closed tetranuclear metal cluster derivative of rhodium and iron: synthesis and molecular structure. J. Oiganometall. Chem., no. 198. 1980. pp. C72-C74.

55 MINTEK PUBLICATIONS

HALL, P.G.2, LOVELL, V.M., and FINKELSTEIN, N.P. Adsorption of water vapour on ionic solids containing preadsorbed sodium oleate. Part 1. Calcium fluoride. Trans. Farad. Soc, vol. 66, no. 570, pt 6. Jun. 1970. pp. 1520-1529.

HALL, P.G.2, LOVELL, V.M., and FINKELSTEIN, N.P. Adsorption of water vapour on ionic solids containing preadsorbed sodium oleate. Part 2. Calcium carbonate. Trans. Farad. Soc, vol. 66, no. 574, pt 10. Oct. 1970. pp. 2629-2635. HAMBLYN, S.M.L. Plasma technology and its application to extractive metallurgy. Miner. Sci. Engng, vol. 9, no. 3. Jul. 1977. pp. 151-176.

HANCOCK, R.D. Formation constants of silvenu-ammonia complexes, and of the ammonium ion, at high free-ammonia concentrat ins. S.Afr. J. Chem., vol. 32, no. 2. 1979. pp. 49-51.

HANCOCK, R.D. Polar and steric effects on the stability of complexes of primary amines. J. Chem. Soc, Dalton Trans., no. 3. 1980. pp. 416-418.

HANCOCK, R.D., and EVERS, A. Formation constant of PdfCH)2,'. Inorg. Chem., vol. 15. 1976. pp. 995-996.

HANCOCK, R.D., and FINKELSTEIN, N.P. TT and ff-bonding in the stabilities of d10 metal-ion complexes in aqueous solution. /. Inorg. Nucl. Chem. Lett., vol. 7. 1971. pp. 477-484.

HANCOCK, R.D., FINKELSTEIN, N.P., and EVERS, A. Stabilities of cyanide complexes of the monovalent group IB metal ions in solution. J. Inorg. Nucl. Chem., vol. 34. 1972. pp. 3474-3751.

HANCOCK, R.D., FINKELSTEIN, N.P., and EVERS, A. Ligand-field theory and metal-ligand force constants. Inorg. Nucl. Chem. Lett., vol. 35. 1973. pp. 2558-2561.

HANCOCK, R.D., FINKELSTEIN, N.P., and EVERS, A. Linear free energy relationships in aqueous complex-formation reactions of the dw metal ions. J. Inorg. Nucl. Chem., vol. 36. 1974. pp. 2539-2543.

HANCOCK, R.D., FINKELSTEIN, N.P., and EVERS, A. Some observations on a recent determination of the stability of the dicyanocuprate(i) ion. J. Inorg. Nucl. Chem., vol. 38. 1976. pp. 343-344.

HANCOCK, R.D., JACKSON, G., and EVERS, A. The affinity of lanthanoid(Iii) ions for nitrogen- donor ligands in aqueous solution. J. Chem. Soc, Dalton Trans., pt 9. Sep. 1979. pp. 1384-1387.

HANCOCK, R.D., and MARSICANO, F. The chelate effect: a simple quantitative approach. /. Chem. Soc, Dalton Trans., 1976. pp. 1096-1098.

HANCOCK, R.D., and MARSICANO, F. The linear free-energy relation in the thermodynamics of complex formation. Part 1. Correlations involving enthalpy changes on complex formation of silver(i) and mercury(ii) with 'soft' donor ligands. /. Chem. Soc, Dalton Trans., 1976. pp. 1832-1837.

HANCOCK, R.D., and MARSICANO, F. Parametric correlation of formation constants in aqueous solution. Part I. Ligands with small donor-atoms. Inorg. Chem., vol. 17, no. 3. 1978. pp. 560-564.

HANCOCK, R.D., and McDOUGALL, G.J. The role of electronic delocalization over the chelate ring in stabilizing complexes of 2,2'-bipyridyl. J. Chem. Soc, Dalton Trans., 1977. pp. 67-70.

HANCOCK, R.D., and McDOUGALL, G.J. The affinity of lead(ii) for nitrogen-donor ligands. J. Co-ord. Chem., vol. 6. 1977. pp. 163-166.

HANCOCK, R.D., and McDOUGALL, G.J. Origin of macrocyclic enthalpy. J. Am. Chem. Soc, vol. 102, no. 21. 1980. pp. 6551-6553.

56 MINTEK PUBLICATIONS

HANCOCK, R.D., McDOUGALL, G.J., MARSICANO, F., and BOEYENS, J.C.A. Empirical force- field calculations of strain-energy contributions to the thermodynamics of complex formation. Part III. The cheiate effect in complexes of polyamines. Inorg. Chem., vol. 18, no. 10. 1979. pp. 2847-2852.

HARRIS, PJ. Surface chemistry in the flotation of minerals. SURFACE SCIENCE AND ITS INDUSTRIAL IMPLICATIONS. Cries, W.H., and Crooke, M. (eds.). Pretoria, CSIR, 1981. pp. 221-228.

HARRIS, P.J., and FINKELSTEIN, N.P. Interactions between sulphide minerals and xanthates. I. The formation of monothiocarbonate at galena and pyrite surfaces. Int. J. Miner. Proc, vol. 2, no. 1. 1975. pp. 77-iOO.

HARRIS, P.J., and FINKELSTEIN, N.P. The formation of monothiocarbonates during the reaction between xanthates and sulphide minerals in flotation systems. PROCEEDINGS ELEVENTH MINERAL PROCESSING CONGRESS. Ente Minerario Sardo. Cagliari, Instituto di Arte Mineraria. Special volume. 1975. pp. 35-57.

HAWKINS, D.M.2, and RASMUSSEN, S.E. Use of discriminant analysis for the classification of strata in sedimentary succession. Math. GeoL, vol. 5, no. 2. 1973. pp. 163-177.

2 HEJJA, A.A., HOWAT, D.D. , and JOCHENS, P.R. The effect of the reactivity of lime on desulphurization efficiency in the basic oxygen furnace. /. S.A/r. Inst. Min. Metall., vol. 73, no. 8. Mar. 1973. pp. 249-257.

HIEMSTRA, s.A. The mineralogy and petrology of the uraniferous conglomerate of the Dominion Reefs Mine, Klerksdorp area. Trans. GeoL Soc. S.A/r., vol. 71, no. 1. 1968. pp. 1-65.

HIEMSTRA, S.A. The geochemistry of the uraniferous conglomerate of the Dominion Reefs Mine, Klerksdorp area. Trans. Geol. Soc. S.Afr., vol. 71, no. 1. 1968. pp. 67-100.

HIEMSTRA, S.A. Photomicrography. Miner. Sci. Engng, vol. 1, no. 2. Jul. 1969. pp. 34-50.

• HIEMSTRA, S.A. The iridescent coating of polished sections, and its application to ore microscopy and image analysis. ICAM81. PROCEEDINGS OF THE FIRST INTERNA TIONAL CONGRESS ON APPLIED MINERALOGY. De Villiers, J.P.R., and Cawthorn, P.A. (eds.). Johannesburg, The Geological Society of South Africa, 1983. pp. 479-483.

• HIGGINSON, A. Recent advances in corrosion-science research in Great Britain. Some impressions of the 24th Corrosion Science Symposium. Corrosion and Coatings, vol. 11, no. 1. 1984. pp. 25, 27, 33.

• HIGGINSON, A., and WHITE, R.T. A preliminary survey of the corrosivity of water in South African gold mines. J. S.Afr. Inst. Min. Metall., vol. 83, no. 6. Jun. 1983. pp. 133-141.

HOW AT, D.D. Spotlight on wear and abrasion in industry. J. S.Afr. Inst. Min. Metall., vol. 81, no. 6. Jun. 1981. pp. 200-202.

HOW AT, D.D., and ENRIGHT, D.P. The performance, wear characteristics, and failures of austenitic manganese-steel castings used in crushing and rod milling. J. S.Afr. Inst. Min. Metall., vol. 80, no. 2. Feb. 1980. pp. 63-81.

HOYER, D.I., and DAWSON, M.F. Some results of laboratory experiments on batch centrifugal ball milling. J. S.Afr. Inst. Min. Metall., vol. 82, no. 5. May 1982. pp. 125-133.

• HULBERT, D.G., and WOODBURN, E.T.9 Multivariable control of a wet-grinding circuit. AIChE J., vol. 29, no. 2. pp. 186-191.

57 MINTEK PUBLICATIONS

JAMES, H.E., DUNNE, R.C., DE WAAL, S.A., and LAXEN, P.A. Established procedures and new advances in the extraction of gold, uranium, and pyrite from Witwatersrand ores. PROCEEDINGS, TWELFTH CONGRESS OF THE COUNCIL OF MINING AND METALLURGICAL INSTITUTIONS. Glen, H. W. fed.). Johannesburg, The South African Institute of Mining and Metallurgy, 1982. vol. 2. pp. 515-525.

JOCHENS, P.R. Technology transfer between a State-sponsored research institute and industry. PROCEEDINGS OF THE SYMPOSIUM ON TECHNOLOGY TRANSFER. South African Council for Scientific and Industrial Research. Pretoria, CSIR, 1974. pp. 38-52.

JOCHENS, P.R. The energy requirements of the mining and metallurgical industry in South Africa. J. S.Afr. Inst. Min. Metall., vol. 80, no. 9. Sep. 1980. pp. 331-343.

JOCHENS, P.R. Metallurgical-engineering curricula and syllabuses at South African universities and technikons. KONFERENSIE OOR INGENIEURSMANNEKRAG — ONTWIKKELING VIR DIE21STE EEU. Pretoria, University of Pretoria, 5th Nov., 1980. vol. 2. pp. 3N-3N/8.

JOCHENS, P.R. Highlights of current metallurgical research and development in the South African precious-metals and ferro-alloys industries. CIMME Bull., vol. 25, no. 1. Mar. 1981. pp. 15-28.

JOCHENS, P.R. Optimum versus maximum recovery of gold. J. S.Afr. Inst. Min. Metall., vol. 81, no. 7. Jul. 1981. p. 229.

JOCHENS, P.R., and STANKO, J.S. Ferro-alloy industry looks to big coal supply. Coal, Gold Base Miner., vol. 23, no. 4. Jul. 1975. pp. 51, 55, 57, 58, 63, 64.

JOHNSON, J.A., and VILJOEN, E.A. The effects of the sample surface on quantitative electron- microprobe analyses. ELECTRON MICROSCOPY SOCIETY OF SOUTHERN AFRICA — PROCEEDINGS. Durban, the Society, 1980. vol. 10. pp. 21-22.

JOHNSTON, G.H., JOCHENS, P.R., and HOWAT, D.D.2 Physicochemical properties of slags in the systems MgO-AI2O3-SiO2 and their application to the technology of ferro-alloy smelting. INFACON 74. PROCEEDINGS OF THE FIRST INTERNA TIONAL FERRO-ALLOYS CONGRESS. Glen, H. W. fed.). Johannesburg, The South African Institute of Mining and Metallurgy, 1975. pp. 217-225.

• JONES, E.A. Spectrophotometric determination of sulphate in sodium hydroxide solutions by flow- injection analysis. Analyt. Chim. Acta, no. 156. 1984. pp. 313-317.

JONES, E.A., WARSHAWSKY, A., DIXON, K., and NICOLAS, D.J. The group extraction of noble metals with S-(l decyl)-N,A/-'diphenylisothiouronium bromide and their determination in the organic extract by atomic-absorption spectrometry. Analyt. Chim. Acta, vol. 94. 1977. pp. 257-268.

KABLE, E.J.D., FESQ, H.W.7, and GURNEY, J.J.2 The significance of interelement relationships of some elements in South African kimberlites. PHYSICS AND CHEMISTR Y OF THE EAR TH. Ahrens, L.H., Dawson, J.B., Duncan, A.R., andErland, A.J. feds.). Oxford, Pergamon, 1975. vol. 9. pp. 709-734.

KELEGHAN, W.T.H. Some potential applications of wet high-intensity magnetic separation. J. S.Afr. Inst. Min. Metall., vol. 76, spec, issue. Oct. 1975. pp. 108-110.

KELEGHAN, W.T.H. WHIMS for low-grade uranium. Nucl. Active, no. 16. Jan. 1977. pp. 3-5.

KING, R.P. Some problems in chemical reactor analysis with stochastic features. / & EC Fundamentals, vol. 9, no. 1. Feb. 1970. pp. 190-191.

KING, R.P. Continuous flow systems with stochastic transfer functions. II. Solution by the associated Kolmogorov equation. Chem. Engng Sci., vol. 26, no. 5. May 1971. pp. 729-737.

58 MINTEK PUBLICATIONS

KING, R.P. Continuous flow systems with stochastic transfer functions. III. Stationary operation with chemical reaction. PROCEEDINGS OF INTERNATIONAL SYMPOSIUM ON CHEMICAL REACTION ENGINEERING. Amsterdam, Elsevier Publishing Co., 1971. pp. B4-35-B4-46.

KING, R.P. Flotation research work of the NIM Research Group, and the Department of Chemical Engineering, University of Natal. J. S.Afr. Inst. Metall., vol. 72, no. 9. Apr. 1972. pp. 235-245.

KING, R.P. An analytical solution to the batch-comminution equation. J. S.Afr., Inst. Min. Metall., vol. 73, no. 4. Nov. 1972. pp. 127-131.

KING, R.P. Model for the design and control of flotation plants. APPLICA TION OF COMPUTER METHODS IN THE MINERAL INDUSTRY. Salomon, M.D.G., and Lancaster, F.H. (eds.). Johannesburg, The South African Institute of Mining and Metallurgy, 1973. pp. 341-350.

KING, R.P. On-line digital computer control of slurry conditioning in mineral flotation. Automatica, vol. 10, no. 1. Jan. 1974. pp. 5-14.

KING, R.P. Application of soft stochastic differential equations to chemical engineering problems — an introductory review. Chem. Engng Commun., vol. 1, no. 4. Nov. 1974. pp. 221-237.

KING, R.P. Simulation of flotation plants. Trans. Soc. Min. EngrsAIME, vol. 258, no. 4. Dec. 1975. pp. 286-293.

KING, R.P. A pilot-plant investigation of a kinetic model for flotation. J. S.Afr. Inst. Min. Metall., vol. 78, no. 12. Jul. 1978. pp. 325-338.

KING, R.P., GLASSER, D.2, and STONE, S.L.2 The optimal catalyst-concentration profile for bifunctional catalysts. Journal of Optimization Theory and Application, vol. 10, no. 2. Aug. 1972. pp. 94-108.

KING, R.P., HATTON, T.A.10, and HULBERT, D.G.10 Bubble loading during flotation. Trans. Instn Min. Metall., Sec. C, vol. 83, no. 811. Jun. 1974. pp. C112-C115.

KING, R.P., WOODBURN, E.T.10, COLBORN, R.P.10, EDWARDS, R., and SMITH, W.E. Dynamic testing of mineral processing equipment using radioisotopes. NUCLEAR TECHNIQUES AND MINERAL RESOURCES. International Atomic Energy. Vienna, the Agency, 1969. pp. 117-127.

KING, R.P., WOODBURN, E.T.10, and TE RIELE, W.A.M. The dispersion of material in slowly moving fluids. Can. J. Chem. Engng, vol. 50, no. 1. Feb. 1972. pp. 3-8.

KLEYENSTÜBER, A.S.E. A review of the geology and mining of the Kalahari manganese field. PROCEEDINGS, TWELFTH CONGRESS OF THE COUNCIL OF MINING AND METALLURGICAL INSTITUTIONS. Glen, H.W. (ed.). Johannesburg, The South African Institute of Mining and Metallurgy, 1982. vol. 1. pp. 213-220.

KNIGHT, A. Nuclear power reactors in Britain. S.Afr. Engr, vol. 57, no. 582. Nov. 1966. pp. 57-61.

KNIGHT, A. Neutron activation analysis. S.Afr. Engr, vol. 58, no. 585. Feb. 1967. pp. 37, 39, 41.

KOURSARIS, A., and SEE, J.B. Reactions in the production of high-carbon ferromanganese from Mamatwan ore. J. S.Afr., Inst. Min. Metall., vol. 79, no. 6. Jan. 1979. pp. 149-158.

KOURSARIS, A., and SEE, J.B. The resistivity of mixtures of Mamatwan manganese ore and reducing agents. J. S.Afr. Inst. Min. Metall., vol. 80, no. 7. Jul. 1980. pp. 229-247.

59 MINTEK PUBLICATIONS

• KOURSARIS, A., KLEYENSTÜBER, A.S.E., and FINN, C.W.P. A mineralogical investigation of the reduction of Mamatwan manganese ore with carbon. ICAM81. PROCEEDINGS OF THE FIRST INTERNATIONAL CONGRESS ON APPLIED MINERALOGY. De Villiers. J.P.R., andCawthorn, P.A. (eds.). Johannesburg, The Geological Society of South Africa, 1983. pp. 375-382.

• KRYNAUW, J.R. A preliminary investigation into the suitability of South African anthracites for Sriderberg electrodes. ICAM8I. PROCEEDINGS OF THE FIRST INTERNATIONAL CONGRESS ON APPLIED MINERALOGY. De Villiers, J.P.R., and Cawthorn, P.A. (eds.). Johannesburg, The Geological Society of South Africa, 1983. pp. 149-155.

LASCHINGER, J.E. Focus on vital role of the National Institute for Metallurgy. S.Afr. Engr, vol. 59, no. 602. Jul. 1968. pp. 24-29.

LASCHINGER, J.E. The National Institute for Metallurgy. S.Afr. Min. EngngJ., vol. 81. 24th Mar., 1969. pp. 279-287.

LAXEN, P.A. A kinetic study of the dissolution of uraninites in sulphuric acid. RESEARCH IN CHEMICAL AND EXTRACTION METALLURGY. Australasian Institute of Mining and Metallurgy. Sydney, the Institute, 1967. pp. 181-192.

LAXEN, P.A. The dissolution of UO, as an electron-transfer reaction. THE RECOVERY OF URANIUM. International Atomic Energy Agency. Vienna, the Agency, 1971. pp. 321-330.

LAXEN, P.A. Carbon-in-pulp in South Africa. PAPERS PRESENTED AT THE SEMINAR ON CARBON-IN-PULP TECHNOLOGY FOR THE EXTRACTION OF GOLD. Kalgoorlie (Australia), The Australasian Institute of Mining and Metallurgy, 1982. pp. 17-41.

LAXEN, P.A., BECKER, G.S.M., and RUBIN, R. Developments in the application of carbon-in-pulp to the recovery of gold from South African ores. J. S.Afr. Inst. Min. Metall., vol. 79, no. 11. Jun. 1979. pp. 315-326.

LAXEN, P.A., FLEMING, C.A., HOLTUM, D.A.'\ and RUBIN, R. A review of pilot-plant testwork conducted on the carbon-in-pulp process for the recovery of gold. PROCEEDINGS, TWELFTH CONGRESS OF THE COUNCIL OF MINING AND METALLURGICAL INSTITUTIONS. Glen, H.W. (ed.). Johannesburg, The South African Institute of Mining and Metallurgy, 1982. vol. 2. pp. 551-561.

LEITNER, J.R. A microprocessor-based cross-correlation flowmeter. APPLICATION OF MICROPROCESSORS IN DEVICES FOR INSTRUMENTA TION AND A UTOMA TIC CONTROL. The Institute of Measurement and Control (eds.). London, the Chameleon Press, 1980. pp. 67-76.

LEITNER, J.R., and NAUDÉ, D.E.H. Slurry flow-rate measurement using correlation. Pulse, Sep. 1979. pp. 25-28.

LEVIN, J. Mixing and sampling procedures used at the National Institute for Metallurgy, South Africa. SAMPLING IN THE MINERAL AND METALLURGICAL PROCESSING INDUSTRIES. Institution of Mining and Metallurgy. London, the Institution, 1973. pp. 28-37.

LEVIN, J., and VEITCH, M.L. Laboratory tests on the flotation of pyrite from Witwatersrand gold ores by cationic collectors. J. S.Afr. Inst. Min. Metall., vol. 70, no. 6, pt 2. Jan. 1970. pp. 259-275.

LIEBENBERG, W.R. Mineralogy and the metallurgist. Miner. Sci. Engng, vol. 2, no. 4. Oct. 1970. pp. 3-23.

LIEBENBERG, W.R. Mineralogical features of gold ores in South Africa. GOLD METALLURGY IN SOUTH AFRICA. Adamson, R.J. (ed.). Johannesburg, Chamber of Mines of South Africa, 1972. pp. 352-446.

60 M1NTEK PUBLICATIONS

LIN, LJ., and FINKELSTEIN, N.P. The application of magnetohydrostatic separation to metallurgical processes. J. S.Afr. Inst. Min. Metall., vol. 76, spec, issue. Oct. 1975. pp. 111-112.

LIN, I.J., NADIV, S.i7, and GRODZIAN, D.J.M.17 Changes in the state of solids and mechano- chemical reactions in prolonged comminution processes. Miner. Sci. Engng, vol. 7, no. 4. Oct. 1975. pp. 314-336.

LLOYD, P.J. The extraction of the neutral and anionic nitrato complexes of nitrosylruthenium by long- chain alkyl amines. /. S.Afr. Chem. Inst., vol. 20, no. 2. Jun. 1967. pp. 174-185.

» LOMBAARD, T., and HIEMSTRA, S.A. Development of an apparatus for the magnetohydrostatic separation of minerals. ICAM81. PROCEEDINGS OF THE FIRST INTERNATIONAL CONGRESS ON APPLIED MINERALOGY. De Viliiers, J.P.R., and Cawthorn, P. 4. (eds.). Johannesburg, The Geological Society of South Africa, 1983. pp. 485-489.

LOO, J.P., COETZEE, C.F.B., and CORRANS, I.J. Beneficiation tests on ore from a complex copper- lead-zinc deposit in the north-western Cape. PROCEEDINGS, TWELFTH CONGRESS OF THE COUNCIL OF MINING AND METALLURGICAL INSTITUTIONS. Glen, H. W. (ed.). Johannesburg, The South African Institute of Mining and Metallurgy, 1982. vol. 2. pp. 879-888.

LOUW, G.D.", and LAXEN, P.A. The beneficiation of residue at Blyvooruitzicht Gold Mine. J. S.Afr. Inst. Min. Metall., vol. 76, spec, issue. Oct. 1975. pp. 136-139.

LOVEGAY, B.K.7 Analysis of froth flotation kinetics. Trans. Instn Min. Metall., vol. 75, Sec. C. Sep. 1966. pp. 219-225.

LOVEDAY, B.K.7 An analysis of comminution kinetics in terms of size-distribution parameters. J. S.Afr. Inst. Min. Metall., vol. 68, no. 3. Oct. 1967. pp. 111-131.

LOVEDAY, B.K.7 The prediction of gravity or inertial separation efficiencies from heavy-liquid tests and Tromp-type efficiency curves. An improved method. Trans. Instn Min. Metall., vol. 79, no. 763. Jun. 1970. pp. C137-C140.

LOVEDAY, B.K.7 A model for the leaching of non-porous particles. J. S.Afr. Inst. Min. Metall., vol. 76, no. 2. Sep. 1975. pp. 16-19.

LOVEDAY, B.K. Pilot-plant testing and scale-up of autogenous milling. GRINDING — THEORY AND PRACTICE. Johannesburg, The South African Institute of Mining and Metallurgy, Vacation School 8th-12th Aug., 1977. pp. 88-97.

LOVEDAY, B.K. Control of milling circuits — definition of aims. GRINDING — THEORY AND PRACTICE. Johannesburg, The South African Institute of Mining and Metallurgy, Vacation School 8th-12th Aug., 1977. pp. 111-122.

LOVEDAY, B.K.7, and MARCHANT, G.R.18 Simulation of multicomponent flotation plants. APPLICA TION OF COMPUTER METHODS IN THE MINERAL INDUSTR Y. Salomon, M.D.G., and Lancaster, F.H. (eds.). Johannesburg, The South African Institute of Mining and Metallurgy, 1973. pp. 325-330.

LOVEDAY, B.K.7, and TOLMAY, A.T. The development of a mathematical model for large-scale mills. CHEMECA 70. Australian Institute of Chemical Engineers. Sydney, the Institute, 1971. pp. 141-151.

LOVELL, V.M. The determination of the surface area of minerals by the B.E.T. method: some associated problems. Powder Technol., vol. 12. 1975. pp. 71-76.

61 MINTEK PUBLICATIONS

LOVELL, V.M. Froth characteristics in phosphate flotation. FLOTATION. A.M. GAUDIN MEMORIAL VOLUME. Fuerstenau, M.C. (ed.). New York, American Institute of Mining, Metallurgical and Petroleum Engineers Inc., 1976. vol. 1. pp. 597-621.

LOVELL, V.M., GOOLD, L. A., and FINKELSTEIN, N.P. Infrared studies of the adsorption of oleate species on calcium fluoride. Int. J. Miner. Process., vol. 1, no. 1. Jan. 1974. pp. 183-192.

LUSHER, J. A. The association of calcium ion with nickeliferous pyrrhotite. Surface ScL, vol. 5, 1966. pp. 252-254.

LYCETT, R.A.H.2, JOCHENS, P.R., and HOWAT, D.D.: The crystallization of rutile from titaniferous slags. S.A/r. Inst. Min. Metall., vol. 76, no. 2. Sep. 1975. pp. 20-24.

MACKENZIE, J.M.W. Zeta-potential studies in mineral processing: measurement techniques and applications. Miner. Sci. Engng. vol. 3, no. 3. Jul. 1971. pp. 25-43.

MALLETT, R.C.7 A review of techniques for the determination of gold and silver by atomic- absorption spectroscopy. Miner. Sci. Engng, vol. 2, no. 3. Jul. 1970. pp. 28-37.

MALLETT, R.C. The determination of platinum-group metals by atomic-absorption spectrophotometry. ASSA YING AND ANAL YTICAL TECHNIQUES FOR THE DETERMINA TION OF THE NOBLE METALS. SYMPOSIUM. Williams, B.J., andMunro, H.C. (eds.). Johannesburg, South African Institute of Assayers and Analysts, 1980.

MALLETT, R.C.7, PEARTON, D.C.G., RING, E.J., and STEELE, T.W. Interferences and their elimination in the determination of the noble metals by atomic-absorption spectrophotometry. Talanta, vol. 19, no. 2. 1972. pp. 181-195.

MALLETT, R.C.7, PEARTON, D.C.G., RING, E.J., and STEELE, T.W. Interferences encountered in the determination of the noble metals by atomic-absorption spectrophotometry. J. S.Afr. Chem. Inst., vol. 25, no. 3. 1972. pp. 219-229.

MALLETT, R.C., ROYAL, S.J., and STEELE, T.W. A sensitive method for the measurement of osmium by atomic-absorption spectrophotometry. Analyt. Chem., vol. 51. 1979. pp. 1617-1620.

MARSICANO, F., and HANCOCK, R.D. A potentiometric and calorimetric study of the thermodynamics of formation of some of the complexes of the d[0 metal ions silver(i), mercury(ii), and cadmium(li) with thiodiglycol, thiourea, and sulphite ion. J. Coord. Chem., vol. 6. 1976. pp. 21-29.

MARSICANO, F., and HANCOCK, R.D. The linear free-energy relation in the thermodynamics of complex formation. Part 2. Analysis of the formation constants of complexes of the large metal ions silver(l), mercury(li), and cadmium(ll) with ligands having 'soft' and nitrogen-donor atoms. J. Chem. Soc, Dalton Trans., no. 3. 1978. pp. 228-234.

McDOUGALL, G.J., and HANCOCK, R.D. Activated carbons and gold — a literature survey. Miner. Sci. Engng, vol. 12, no. 2. Apr. 1980. pp. 85-99.

McDOUGALL, G.J., and HANCOCK, R.D. The N-M-N bond angle in the chelate ring of ethylenediamine. The crystal structure of tetra-aqua(ethylenediamine)nickel(ii) nitrate. J. Chem. Soc, Dalton Trans., no. 4. 1980. pp. 654-658.

McDOUGALL, G.J., HANCOCK, R.D., and BOEYENS, J.C.A. Empirical force-field calculations of strain-energy contributions to the thermodynamics cf complex formation. Part I: The difference in stability between complexes with five- and six-membered rings. J. Chem. Soc., Dalton Trans., no. 11. 1978. p. 1438.

62 MINTEK PUBLICATIONS

McDOUGALL, G.J., HANCOCK, R.D., NICOL, M.J., WELLINGTON, O.L., and COPPERTHWAITE, R.G. The mechanism of the adsorption of gold cyanide on activated carbon. J. S.Afr. lnst. Min. Metall., vol. 80, no. 9. pp. 344-356.

McIVER, J.R.\ and MIHALIK, P. Stannian andradite from 'Davib Ost\ South West Africa. Can. Mineralogist, vol. 13, no. 3. Aug. 1975. pp. 217-221.

McLAREN, C.H., and DE VILLIERS, J.P.R. The platinum-group chemistry and mineralogy of the UG-2 Chromitite Layer of the Bushveld Complex. Econ. Geol., vol. 77, no. 6. Sep.-Oct. 1982. pp. 1348-1366.

McNALLAN, M.J.4, SEE, J.B., OBERTEUFFER, J.A.4, and RUSSELL, K.C.1" Treatment of steelplant effluents by high gradient magnetic separation. Iron SteelEngr, vol. 53, no. 1. 1976. pp. 40-44.

McRAE, L.B.2, POTHAS, E.2, JOCHENS, P.R., and HOWAT, D.D.2 Physicochemical properties of titaniferous slags. J. S.Afr. lnst. Min. Metall., vol. 69, no. 11. 1969. pp. 577-594.

McRAE, L.B., and SELMER-OLSEN, S.A.20 An investigation into the pelletizing and prereduction of Transvaal chromites. AGGLOMERATION 77. Sastry, K. V.S. (ed.). New York, AIME, 1977. vol. I. pp. 356-377.

MIHALIK, P. The electron microprobe X-ray analysis. S.Afr. Chem. Process., vol. 2, no. 2. Apr.- May 1967. pp. 37-42.

MIHALIK, P. An aid for the alignment, positioning, and checking of the beam in the electron microprobe. Lab. Practice, vol. 19, no. 3. Mar. 1970. p. 288.

MIHALIK, P., and HIEMSTRA, S.A. Apparatus permitting visual observation during the vacuum- deposition of thin films. Lab. Practice, vol. 21, no. 4. Jan. 1972. pp. 29-30.

MIHALIK, P., HIEMSTRA, S.A., and DE VILLIERS, J.P.R. Rustenburgite and atokite, two new platinum-group metals from the Merensky Reef, Bushveld Igneous Complex. Can. Mineralogist, vol. 13, no. 2. 1975. pp. 146-150.

MIHALIK, P., JACOBSEN, J.B.E.2, and HIEMSTRA, S.A. Platinum-group minerals from a hydrothermal environment. Econ. Geol., vol. 609, no. 2. Mar.-Apr. 1974. pp. 257-262.

MIHALIK, P., and SAAGER, R. Chromite grains showing altered borders from the Basal Reef, Witwatersrand System. Am. Mineralogist, vol. 53, no. 9/10. Sep.-Oct. 1968. pp. 1543-1550.

MINNITT, R.C.A.2, BUTTON, A.2, and KABLE, E.J.D. The gold content of pre-Malmani argillaceous sediments in the Transvaal Supergroup, north-eastern Transvaal. University of the Witwatersrand, Economic Geology Research Unit, Information Circular no. 82. Jul. 1973.

MOODLEY, K.G.2', and NICOL, M.J. Kinetics of the reduction of platinum(iv) by tin(ii) and copper(i) in aqueous chloride solutions. J. Chem. Soc, Dalton Trans., no. 3. Mar. 1977. pp. 239-243.

MOORE, G.L. Some candle! CHEMSA, vol. 8, no. 7. Jul. 1982. pp. 80-81.

MOORE, G.L., WATSON, A.E., and HUMPHRIES-CUFF, P. An on-line dilution system for ICP spectrometry. Spectrochim. Ada, vol. 37B, no. 9. 1982. p. 835.

MOYS, M.H. The control of autogenous and semi-autogenous mills: the relation between measurements of bearing pressure and parameters describing the mill load. J. S.Afr. lnst. Min. Metall., vol. 80, no. II. Nov. 1980. pp. 4G1-408.

63 MINTEK PUBLICATIONS

MOYS, M.H., and LOVEDAY, B.K. Autogenous-milling research at the South African National Institute for Metallurgy. PROCEEDINGS OF THE AUTOGENOUS GRINDING SEMINAR. Digne, M. (ed.). Trondheim (Norway), Jan. 1980. pp. F2:l-17.

MRKUSIC, P.G., SCIARONE, M., and SIMONSEN, H.E. Gold recovery by cyanidation from mill products obtained after pyrite flotation. J. S.Afr. Inst. Min. Metall., vol. 70, no. 6. Pt 2. Jan. 1970. pp. 236-247.

NAKAN1, B.S.44, and GIESEKKE, E.W. A study of lanthanide p-toluene sulphonic acid complexes in solution. Polyhedron, vol. 1, no. 3. 1982. pp. 253-256.

• NATTRASS, W. A., and TE RIELE, W.A.M. Pressure leaching of sphalerite below the melting point of sulphur — an integrated process. ZINC 83. Edmonton (Canada), CIM Metallurgical Society Hydrometallurgy Section, Aug. 1983. Paper 13.

NEEDES, C.R.S., NICOL, M.J., and FINKELSTEIN, N.P. An electrochemical model for the leaching of uranium dioxide. 2. Alkaline carbonate media. LEACHING AND REDUCTION IN HYDROMETALLURGY. Burkin, A.R. (ed.). London, Institution of Mining and Metallurgy, 1975. pp. 12-19.

NEEDES, C.R.S., NICOL, M.J., and FINKELSTEIN, N.P. An electrochemical model for the leaching of uranium dioxide. 2. Alkaline carbonate media. LEACHING AND REDUCTION IN HYDROMETALLURGY. Burkin, A.R. (ed.). London, Institution of Mining and Metallurgy, 1975. pp. 12-19.

NEEDES, C.R.S., NICOL, M.J., FINKELSTEIN, N.P., and ORMROD, G.T.W. The industrial application of a uranium dioxide electrode. J. S.Afr. Inst. Min. Metall., vol. 76, no. 4. Nov. 1975. pp. 238-246.

NICOL, M.J. The new electrochemistry and its part in a new technology. Probe 71-2. 1972. pp. 23-26.

NICOL, M.J. An electrochemical investigation of the dissolution of copper, nickel, and copper-nickel alloys in ammonium carbonate solutions. J. S.Afr. Inst. Min. Metall., vol. 75, no. 11. Jun. 1975. pp. 291-302.

NICOL, M.J. Mechanism of aqueous reduction of chalcopyrite by copper, iron and lead. Trans. Instn Min. Metall., vol. 84. 1975. pp. C206-C209.

• NICOL, M.J. An introduction to the basic concepts of electrochemistry. LECTURE/NOTES: SCHOOL OF PURE AND APPLIED ELECTROCHEMISTRY. Randburg, Council for Mineral Technology, 1979. pp. 1-23.

• NICOL, M.J. Application of electrochemical principles to problems in the metallurgical industry. LECTURE/NOTES: SCHOOL OF PURE AND APPLIED ELECTROCHEMISTRY. Randburg, Council for Mineral Technology, 1979. pp. 1-27.

NICOL, M.J. Anodic behaviour of gold. Part I — in acidic solutions. Gold Bull., vol. 13, no. 2. Apr. 1980. pp. 46-55.

NICOL, M.J. Anodic behaviour of gold. Part II — in alkaline solutions. Gold Bull., vol. 13, no. 3. Jul. 1980. pp. 105-111.

NICOL, M.J. The kinetics of the oxidation of copper(l) by hydrogen peroxide in acidic chloride solutions. S.Afr. J. Chem., vol. 35, no. 3. 1982. pp. 77-79.

64 MINTEK PUBLICATIONS

• NICOL, M.J. The non-oxidative leaching of oxides and sulphides: an electrochemical approach. HYDROMETALLURGY — RESEARCH, DEVELOPMENT AND PLANT PRACTICE. Osseo-Asare, K., and Miller, J.D. feds.). Warrendale (U.S.A.), The Metallurgical Society of AIME, 1982. pp. 177-195.

• NICOL, M.J. Overview of electrometallurgy. VACA TION SCHOOL: ELECTROMETALLURGY. Johannesburg, The South African Institute of Mining and Metallurgy, 1983. pp. 4-10.

• NICOL, M.J. Current distribution in electrochemical reactions. VACATION SCHOOL: ELECTROMETALLURGY. Johannesburg, The South African Institute of Mining and Metallurgy, 1983. pp. 98-111.

• NICOL, M.J. Recent and future developments [in electro winning]. VACATION SCHOOL: ELECTROMETALLURGY. Johannesburg, The South African Institute of Mining and Metallurgy, 1983. pp. 297-303.

• NICOL, M.J., FLEMING, C.A., and CROMBERGE, G. The absorption of gold cyanide onto activated carbon. I. The kinetics of absorption from pulps. J. S.Afr. Inst. Min. Metal!., vol. 84, no. 2. Feb. 1984. pp. 50-54.

• NICOL, M. J., FLEMING, C.A., and CROMBERGE, G. The absorption of gold cyanide onto activated carbon. II. Application of the kinetic model to multistage absorption circuits. J. S.Afr. Inst. Min. Metall., vol. 84, no. 3. Mar. 1984. pp. 70-78.

NICOL, M.J., and NEEDES, C.R.S. The anodic dissolution of uranium dioxide. I. In perchlorate solutions. Electrochim. Ada, vol. 20, no. 8. Aug. 1975. pp. 585-589.

NICOL, M.J., and NEEDES, C.R.S. The anodic dissolution of uranium dioxide. II. In carbonate solutions. Electrochim. Ada, vol. 22. 1977. pp. 1381-1384.

NICOL, M.J., NEEDES, C.R.S., and FINKELSTEIN, N.P. An electrochemical model for the leaching of uranium dioxide. 1. Acid media. LEACHING AND REDUCTION IN HYDROMETALLURGY. Burkin, A.R. (ed.). London, Institution of Mining and Metallurgy, 1975. pp. 1-11.

NICOL, M.J., PAUL, R.L., and DIGGLE, J.W. The electrochemical behaviour of galena (lead sulphide) — II. Cathodic reduction. Electrochim. Ada, vol. 23. 1978. pp. 635-639.

NICOL, M.J., SCHALCH, E., BALESTRA, P.E.L., and HEGEDUS, H. A modern study of the kinetics and mechanism of the cementation of gold. J. S.Afr. Inst. Min. Metall., vol. 79, no. 7. Feb. 1979. pp. 191-198.

NICOL, M.J., and SCOTT, P.D. The kinetics and mechanism for the non-oxidative dissolution of some iron sulphides in aqueous acidic solutions. S.Afr. Inst. Min. Metall., vol. 79, no. 10. May 1979. pp. 298-305.

• OOSTHUYZEN, E.J. The application of automatic image analysts to mineralogy and extractive metallurgy. ICAM 81. PROCEEDINGS OF THE FIRST INTERNATIONAL CONGRESS ON APPLIED MINERALOGY. De Villiers, J.P.R., and Cawthorn, P.A. (eds.). Johannesburg, The Geological Society of South Africa, 1983. pp. 449-464.

OOSTHUYZEN, E.J., and VILJOEN, E.A. Quantitative mineralogy applied to a study of the process involved in the production of ferrochromium from Transvaal chromite ore. PREPRINTS — XIV INTERNATIONAL MINERAL PROCESSING CONGRESS "WORLDWIDE INDUSTRIAL APPLICA TION OF MINERAL PROCESSING TECHNOLOG Y". Ottawa, The Canadian Institute of Mining and Metallurgy, 1982. pp. VIII-6.1 to VIII-6.17.

ORMROD, CT.W. The control of aqueous ammonia concentrations by a thermal method. Electron. Instrumn, vol. 6, no. 8. Aug. 1975. pp. 73, 77, 79.

65 MINTEK PUBLICATIONS

ORMROD, G.T.W. The control of aqueous ammonia concentrations by a thermal method. CHEMSA, Dec. 1975. pp. 284-286.

ORMROD, G.T.W. Electrodeless conductivity meters in the measurement and control of the amount of lime in alkaline slurries. Pulse, Apr. 1979. pp. 16-18.

• ORMROD, G.T.W. The use of Doppler flowmeters for measuring slurry flows. Pulse, Feb. 1983. pp. 21-22.

ORMROD, G.T.W., and SOMMER, G. Analytical instrumentation for control of the leaching process. AUTOMATION IN MINING, MINERAL AND METAL PROCESSING. Lancaster, F.H. (ed.). Pretoria, South African Council for Automation and Computation, 1977. pp. 521-530.

OSSIN, D.I. The production of stainless steel in South Africa. Miner. Sci. Engng, vol. 10, no. 2. Apr. 1978. pp. 101-129.

OSSIN, D.I. Prospects for the expansion of stainless-steel production in South Africa. Miner. Sci. Engng, vol. 11, no. 3. Jul. 1979. pp. 177-187.

OSSIN, D.I., HOW AT, D.D.2, and JOCHENS, P.R. Liquidus temperatures, viscosities and electrical conductivities of lime-containing slags produced during the smelting of high-carbon ferrochromium and ferrochromium-silicide alloys. 29TH ELECTRIC FURNACE CONFERENCE PROCEEDINGS. Metallurgical Society of AIME. New York, AIME, 1972. vol. 29. pp. 94-100.

OVERBEEK, P.W. An assessment of the efficiency of the Dryflo concentrator by the use of specific gravity markers. J. S.Afr. Inst. Min. Metall., vol. 76, spec, issue. Oct. 1975. pp. 120-122.

OVERBEEK, P.W. The beneficiation of andalusite. S.A. CERAMIC SOCIETY 14TH ANNUAL SYMPOSIUM PROCEEDINGS. Pretoria, South African Ceramic Society, 1982. 34 pp.

OVERBEEK, P.W. The development of the andalusite industry in South Africa. PROCEEDINGS, TWELFTH CONGRESS OF THE COUNCIL OF MINING AND METALLURGICAL INSTITUTIONS. Glen, H. W. (ed.). Johannesburg, The South African Institute of Mining and Metallurgy, 1982. vol. 2. pp. 505-513.

PALMER, I., PALMER, R., and STEELE, T.W. The separation of platinum, palladium, rhodium and gold from ores and concentrates by aqua regia extraction and by high-temperature chlorination followed by acid leaching. J. S.Afr. Chem. Inst., vol. 25, no. 3. 1972. pp. 190-197.

PARKER, A.J.22, CLARE, B.W.22, and SMITH, R.P. Solvation of ions. Some applications. IV. A novel process for the recovery of pure silver from impure silver chloride. Hydrometall., vol. 4. 1979. pp. 233-245.

• PARKER, A.J.22, PAUL, R.L., and POWER, G.P. Electrochemical aspects of leaching copper from chalcopyrite in ferric and cupric salt solutions. Austral. J. Chem., vol. 34. pp. 13-34.

• PARKER, A.J.22, PAUL, R.L., and POWER, G.P. Electrochemistry of the oxidative leaching of copper from chalcopyritv.. J. Electro-analyt. Chem. Interfacia! Electrochem., vol. 118. 1981. pp. 305-316.

PAUL, R.L. A circuit design for a motor-speed controller of high precision. Electrochim. Ada, vol. 23, no. 10. Oct. 1978. pp. 991-994.

• PAUL, R.L. Some guidelines to the design of an electrochemical experiment. LECTURE/NOTES: SCHOOL OF PURE AND APPLIED ELECTROCHEMISTRY. Randburg, Council for Mineral Technology, 1979. pp. 1-17.

66 MINTEK PUBLICATIONS

• PAUL, R.L. A quantitative approach to mass transfer in electroanalytical chemistry. LECTURE/NOTES: SCHOOL OF PURE AND APPLIED ELECTROCHEMISTRY. Randburg, Council for Mineral Technology, 1979. pp. 18-33.

• PAUL, R.L. Fundamental aspects of electrode processes. VACATION SCHOOL: ELECTROMETALLURGY. Johannesburg, The South African Institute of Mining and Metallurgy, 1983. pp. 11-54.

• PAUL, R.L. EJectrowinning of gold and silver. VACATION SCHOOL: ELECTROMETALLURGY. Johannesburg, The South African Institute of Mining and Metallurgy, 1983. pp. 262-278.

PAUL, R.L., and BALESTRA, P.E.L. The descaling of 3CR12 steel. SURFACE SCIENCE AND ITS INDUSTRIAL IMPLICATIONS. Gries, W.H., and Crooke, M. (eds.). Pretoria, CSIR, 1981. pp. 213-217.

PAUL, R.L., and BROOKS, H.C.'° Energies of mixing of molten silver bromide-alkali bromide system. Inorg. Nucl. Chem. Lett., vol. 8, no. 7. 1972. pp. 629-631.

PAUL, R.L., and BROOKS, H.C.10 Binary silver bromide-alkali bromide melts. Calculated and measured energies of mixing. Inorg. Chem., vol. 13, no. 3. 1974. pp. 683-690.

• PAUL, R.L., FILMER, A.O., and NICOL, M.J. The recovery of gold from concentrated aurocyanide solutions. HYDROMETALLURGY — RESEARCH, DEVELOPMENT AND PLANT PRACTICE. Osseo-Asare, K., and Miller, J.D. (eds.). Warrendale (U.S.A.), The Metallurgical Society of AIME, 1982. pp. 689-704.

PAUL, R.L., NICOL, M.J., DIGGLE, J.W., and SAUNDERS, A.P. The electrochemical behaviour of galena (lead sulphide) — I. Anodic dissolution. Electrochim. Ada, vol. 23. 1978. pp. 625-633.

PAULL, J.M., and SEE, J.B. The interaction of silicon monoxide gas with carbonaceous reducing agents. J. S.Afr. Inst. Min. Metall., vol. 79, no. 2. Sep. 1978. pp. 35-41.

PAYNTER, J.C. A review of copper hydrometallurgy. J. S.Afr. Inst. Min. Metall., vol. 74, no. 4. Nov. 1973. pp. 158-170.

PAYNTER, J.C., LOVEDAY, B.K., and ROBINSON, C.G. Optimization studies on the design of a processing plant for a large mining venture. APPLICATION OF COMPUTER METHODS IN THE MINERAL INDUSTRY. Salamon, M.D.G., and Lancaster, F.H. (eds.). Johannesburg, The South African Institute of Mining and Metallurgy, 1973. pp. 171-176.

PEARTON, D.C.G., BRECKENRIDGE, R.L., DUBOIS, M., and STEELE, T.W. The pressure dissolution of platiniferous materials by the sealed-tube technique and the analysis of the resulting solutions. J. S.Afr. Chem. Inst., vol. 25, no. 3. 1972. pp. 244-253.

PEARTON, D.C.G., and TAYLOR, J.D. The determination of copper in rocks and ores by atomic absorption spectroscopy. Bull. S.Afr. Inst. Assayers Analysts, no. 4. Jul. 1969.

PEARTON, D.C.G., TAYLOR, J.D., FAURE, P.K., and STEELE, T.W. The determination of vanadium in silicate materials by atomic absorption spectrophotometry. Analyt. Chim. Acta, vol. 44. 1969. pp. 353-359.

PHILIP, H.I., and NICOL, M.J. Underpotential deposition and its relation to the anomalous deposition of metals in alloys. J. Electroanalyt. Chem., vol. 70. 1976. pp. 233-237.

PHILIP, H.I., and NICOL, M.J. The kinetics and mechanism of the deposition of nickel from chloride solutions. INTERNATIONAL SYMPOSIUM ON CHLORIDE HYDROMETALLURGY, PROCEEDINGS. Brussels, Benelux Metallurgie, 1977. pp. 250-269.

67 MINTEK PUBLICATIONS

PLUMMER, V. Computerized information systems and services. AN INTRODUCTORY COURSE FOR INFORMATION WORKERS. Pretoria, CSIR, 1979. pp. 91-108.

POHLANDT, C. The extraction of noble metals with /i-octylaniline. Talanta, vol. 26, no. 3. Mar. 1979. pp. 199-206.

POHLANDT, C. Determination of anions by ion chromatography. S.Afr. J. Chem., vol. 33, no. 3. 1980. pp. 87-91.

POHLANDT, C. The use of octylaniline as an extractant in the analysis of platinum-bearing materials. ASSA YING AND ANAL YTICAL TECHNIQUES FOR THE DETERMINA TION OF THE NOBLE METALS SYMPOSIUM. Williams, B.J., andMunro, H.C. (eds.). Johannesburg, South African Institute of Assayers and Analysts, 1980.

POHLANDT, C. Separation of some weak-acid anions by ion-exclusion chromatography. S.Afr. J. Chem., vol. 35, no. 3. 1982. pp. 96-100.

POHLANDT, C, COOKE, E.B.T., and STEELE, T. W. Determination of small quantities of xanthate. Talanta, vol. 16, no. 8. 1969. pp. 1129-1135.

POHLANDT, C, and FRITZ, J.S.23 Extraction of metal ions from chloride solution with N,N-dioctylacetamide. Talanta, vol. 26. 1979. pp. 395-399.

POHLANDT, C, and FRITZ, J.S.23 Separation of metal ions on a new amide resin. J. Chromat., no. 176. 1979. pp. 189-197.

• POHLANDT, C, JONES, E.A., AND LEE, A.F. A critical evaluation of methods applicable to the determination of cyanides. J. S.Afr. Inst. Min. Metall., vol. 83, no. 1. Jan. 1983. pp. 11-19.

POHLANDT, C, ROBERT, R.V.D., VALLÉE, A.M., and STEELE, T.W. The separation of non- volatile noble metals on cellulose, and the application of the technique to the analysis of matte-leach residues. J. S.Afr. Chem. Inst., vol. 25, no. 3. 1972. pp. 198-213.

POHLANDT, C, and STEELE, T.W. Separation of the non-volatile noble metals by reversed-phase extraction chromatography. Talanta, vol. 19, no. 7. 1972. pp. 839-850.

POHLANDT, C., and STEELE, T.W Chromatographic separation and determination of noble metals in matte-leach residues. Talanta, vol. 21, 1974. pp. 919-925.

POPE, L.E, and BOEYENS, J.C.A. Crystal structures of S-benzylisothiouronium hexachloroplatinate(iV) and tetrachloroaurate(iii). J. Cryst. Mol. Struct., vol. 5, no. 1. 1975. pp. 47-58.

POWER, G.P. An electrochemical method for the recycling of tungsten carbide and other hard metal carbides using a rotating drum anode. Chemistry in Australia, vol. 46, no. 7. 1979. pp. 303-307.

PRATT, J.M.2, and TILLEY, R.I. The reaction of Cu(ii) with LIX65N in homogeneous solution. Hydrometali., vol. 5. 1979. pp. 29-45.

PRESTON, J.S. Solvent extraction of cobalt and nickel by organophosphorus compounds. I. Comparison of phosphoric, phosphonic and phosphinic acid systems. Hydrometali., vol. 9, no. 2. Nov. 1982. pp. 115-133.

• PRESTON, J.S. Non-chelating oximes in the solvent extraction of base metals. ISEC '83. New York, American Institute of Chemical Engineers, 1983. pp. 357-358.

68 MINTEK PUBLICATIONS

• PRESTON, J.S. Solvent extraction of cobalt(il) and nickel(ll) by a quaternary ammonium thiocyanate. Sepn Sci. Techno!., vol. 17, no. 15. 1982-83. pp. 1697-1718.

• PRESTON, J.S. Solvent extraction of nickel and cobalt by mixtures of carboxylic acids and non-chdating oximes. HydrometalL, vol. 11, no. 1. 1983. pp. 105-124.

• PRESTON, J.S. Solvent extraction of base metals by mixtures of organophosphoric acids and non- chelating oxides. HydrometalL, vol. 10, no. 2. May 1983. pp. 187-204.

• PRESTON, J.S. Recent developments in the separation of nickel and cobalt from sulphate solutions by solvent extraction. /. S.A/r. Inst. Min. Metall., vol. 83, no. 6. Jun. 1983. pp. 126-132.

• PRESTON, J.S., and FLEMING, C.A. The recovery of nickel by solvent extraction from acidic sulphate solutions. HYDROMETALLURGY — RESEARCH, DEVELOPMENT AND PLANT PRACTICE. Osseo-Asare, K., and Miller, J.D. (eds.). Warrendale (U.S.A.), The Metallurgical Society of AIME, 1982. pp. 475-489.

RANKIN, W.J. Silica solubility and the activity of MnO in MnO-SiO2 slags. Metall. Trans., vol. 9B. 1978. pp. 726-728.

RANKIN, W.J., and BISWAS, A.K.24 The oxidation states of chromium in slag and chromium distribution in slag-metal systems at 1600 °C. Trans. Instn Min. Metall., vol. C87. Mar. 1978. pp. C60-C70.

RANKIN, W.J., and SEE, J.B. The alkali problem in the blast furnace. Miner. Sci. Engng, vol. 9, no. 2. Apr. 1977. pp. 68-82.

RASMUSSEN, S.E., SELLSCHOP, J.P.F.2, FESQ, H.W.7, and HAWKINS, D.M.2 Characterization of sedimentary strata using trace element patterns. PROCEEDINGS TWELFTH INTERNA TIONAL SYMPOSIUM ON THE APPLICATION OF COMPUTERS AND MATHEMATICS IN THE MINERALS INDUSTRY. Johnson, T.B., and-Gentry, D. W. (eds.). Golden, Colorado School of Mines, 1974. pp. D41-D56.

• RENNIE, M.S. The application of on-line data and the development of models relating to the production of charge chrome. 37TH ELECTRIC FURNACE CONFERENCE PROCEEDINGS. Detroit, AIME, 1979. pp. 202-208.

RENNIE, M.S., HOW AT, D.D.2, and JOCHENS, P.R. The effects of chromium oxide, iron oxide, and calcium oxide on the liquidus temperatures, viscosities, and electrical conductivities of slags in the system MgO-Al2O3-SiO2. /. S.Afr. Inst. Min. Metall., vol. 73, no. 1. Aug. 1972. pp. 1-9.

ROBERT, R.V.D., VAN WYK, E., PALMER, R., and STEELE, T.W. The development of a fire-assay procedure using nickel sulphide as the collector for the noble metals. J. S.Afr. Chem. Inst., vol. 25, no. 3. 1972. pp. 179-189.

ROBINSON, R.E. The fifth James Moir memorial lecture. S.Afr. Chem. Process., Jun.-Jul. 1967. pp. CP72-CP84.

ROBINSON, R.E. Would you encourage your son to undertake a mining career? Coal, Gold Base Miner., vol. 19, no. 3. May 1971. pp. 19-27.

ROBINSON, R.E. The utilization and conservation of mineral resources. S.Afr. J. Sci., vol. 68, no. 4. April. 1972. pp. 105-110.

ROBINSON, R.E. The case for national research in mineral processing. J. S.Afr. Inst. Min. Metall., vol. 76, no. 3. Oct. 1975. pp. 196-213.

69 MINTEK PUBLICATIONS

ROBINSON, R.E. Metallurgical problems in the utilization of Southern Africa's resources. RESOURCES OF SOUTHERN AFRICA TODAY AND TOMORROW. Baker, G. fed.). Johannesburg, Associated Scientific and Technical Societies of Southern Africa, 1976. pp. 308-318.

RODD, M.G.15, and POTGIETER, J.H. A microprocessor based weighing and feed control system. AUTOMATION IN MINING, MINERAL AND METAL PROCESSING. Lancaster, F.H. (ed.). Pretoria, South African Council for Automation and Computation, 1977. pp. 381-388.

RODD, M.G.15, and RABEY, C.C. A computer based system for the evaluation of electric fields in a model submerged arc furnace. AUTOMATION IN MINING, MINERAL AND METAL PROCESSING. Lancaster, F.H. (ed.). Pretoria, South African Council for Automation and Computation, 1977. pp. 371-379.

RUSSELL, B.G. Flame-photometric determination of sodium and potassium in manganese ores. Analyst, Lond., vol. 91, no. 1085. Aug. 1966. pp. 511-519.

RUSSELL, B.G., and DOMEL, G. The analysis of uranium by X-ray-fluorescence techniques. Bull. S.Afr. Inst. Assayers Analysts, no. 6. Jan. 1970.

RUSSELL, B.G., EDDY, B.T., BECKMANN, G., and STEELE, T.W. The application of X-ray- fluorescence techniques to the determination of the noble metals. J. S.Afr. Chem. Inst., vol. 25, no. 3. 1972. pp. 297-310.

RUSSELL, B.G., SPANGENBERG, J.D., and STEELE, T.W. An investigation into the use of platinum ware for silicate analysis. Talanta, vol. 16, no. 4. 1969. pp. 487-496.

RUSSELL, B.G., WILSON, A., LUBBE, M.V., JONES, E., TAYLOR, J.D., and STEELE, T.W. The determination of selenium and tellurium in silver chloride and uranium oxide. Talanta, vol. 14, no. 8. Aug. 1967. pp. 957-966.

RUSSELL, G.M., and WATSON, A.E. The use of an inductively coupled plasma source in the determination of the precious metals by emission spectrometry. ASSAYING AND ANALYTICAL TECHNIQUES FOR THE DETERMINATION OF THE NOBLE METALS. SYMPOSIUM. Williams, B.J., and Munro, H.C. (eds.). Johannesburg, South African Institute of Assayers and Analysts, 1980.

SAAGER, R., and MIHALIK, T. Notes on two vanciies of pyrite from the Basal Reef of the Witwatersrand System. Econ. Geol., vol. 62. 1967. pp. 719-731.

SAUNDERS, A.P., PHILIP, I., and MARTIN, J.P. An automated instrument for the determination of the effects of impurities on the cathodic current efficiency during the electrowinning of zinc. AUTOMATION IN MINING, MINERAL AND METAL PROCESSING. Lancaster, F.H. (ed.). Pretoria, South African Council for Automation and Computation, 1977. pp. 531-542.

SCHALCH, E., and NICOL, M.J. Electrochemical investigation of copper cementation on iron. Trans. Instn Min. Metall., vol. 87. Mar. 1978. pp. C16-C22.

SCHALCH, E., and NICOL, M.J. A study of certain problems associated with the electrolytic refining of gold. Gold Bull., vol. 11, no. 4. Oct. 1978. pp. 117-123.

SCHALCH, E., NICOL, M.J., and CHARLTON, B.D.25 An electrochemical study of some problems related to the electrorefining of gold in chloride solutions. INTERNATIONAL SYMPOSIUM ON CHLORIDE HYDROMETALLURGY, PROCEEDINGS. Brussels, Benelux Metallurgie, 1977. pp. 336-356.

SCHWELLNUS, J.S.I.26, HIEMSTRA, S.A., and GASPARRIN1, E. The Merensky Reef at the Atok Platinum Mine and its environs. Econ. Geol., vol. 71. 1976. pp. 249-260.

70 M1NTEK PUBLICATIONS

SCOTT, P.D., GLASSER, D.% and NiCOL, M.J. Thermal determination of the kinetics of the iron(il))-tin(Ji) redox reaction in chloride solution. J. Chem. Soc., Farad. Trans, I, vol. 71, no. 7. 1975. pp. 1413-1421.

SCOTT, P.D., GLASSER, D.% and NICOL, M.J. Kinetics of dissolution of tf-uranium trioxide in acid and carbonate solutions. J. Chem. Soc., Dalton Trans., 1977. pp. 1939-1946.

SCOTT, P.D., and NICOL, M.J. Kinetics of the non-oxidative dissolution of galena in acidic chloride solutions. Trans. Instn Min. Metall., vol. 85. Mar. 1976. pp. C40-C44.

SCOTT, P.D., and NICOL, M.J. The kinetics and mechanisms of the non-oxidative dissolution of metal sulphides. TRENDS IN ELECTROCHEMISTRY. Bockris, J. O'M., Rand. D.A.J., and Welch, B.J. (eds.). New York, Plenum Press, 1977. pp. 303-316.

SCOTT, P.D., WILLIAMS, D.F.:, and GLASSER, D.: The thermal determination of liquid phase kinetics. S.Afr. J. Sri., vol. 70, no. 1. 1974. pp. 10-12.

SEE, J.B. The development of fundamental and applied research in the sphere of ferro-alloys in South Africa. FERROALEACONES: TECHNOLOGIA YD1SPONIB1LIDAD. Instituto Lalinoamericano del Fierro y el Acero. Santiago, Instituto, 1975. pp. T1-T19. (In Spanish.)

SEE, J.B. Fluorspar and fluorine compounds in high-temperature smelting and refining of metals. Miner. Sci. Engng, vol. 8, no. 4. Oct. 1976. pp. 217-241.

SELLSCHOP, J.P.F.% BIBBY, D.M., ERASMUS, C.S., and MINGAY, D.W. Determination of impurities in diamonds by nuclear methods. DIAMOND RESEARCH 1974. London, Industrial Diamond Information Bureau, 1974. pp. 43-50.

• SELLSCHOP, J.P.F.2, MAD1BA, C.C.P.% ANNEGARN, H.J.2, and ANDEWEG, A.H. Positron analysis as a quantitative technique in ion beam analysis. PROCEEDINGS OF THE SIXTH INTERNATIONAL CONFERENCE ON ION BEAM ANALYSIS. Siegbahn, K. (e±) Amsterdam, North-Holland, 1983. p. 836. Also in: Nucl. Instrnm. Methods Phys. Res., vol. 218, nos. i-3. 15th Dec, 1983. pp. 23-28.

• SIMONSEN, H.A. The engineering economics of uranium processing. PROCEEDINGS OF THE WORKSHOP ON ECONOMICS OF URANIUM ORE PROCESSING OPERA TIONS. Paris, Nuclear Energy Agency, 1983.

SMITH, R.P., and WOODBURN, E.T.10 Prediction of multicomponent ion exchange equilibria for the ternary system SO; -NO3 -Cl from data of binary systems. AIChE J., vol. 24, no. 4. Jul. 1978. pp. 577-588.

• SMITS, G., and UITERWIJK, B.H. The uranium mineralization in the south-western Karoo: its mineralogy and genesis. ICAM81. PROCEEDINGS OF THE FIRST INTERNA TIONAL CONGRESS ON APPLIED MINERALOGY. De Villiers, J.P.R., and Cawthorn, P.A. (eds.). Johannesburg, The Geological Society of South Africa, 1983. pp. 301-313.

SOMMER, G. Temperature measurement with thermocouples. Electron. Instrumn, vol. 2, no. 1. Apr. 1971. pp. 2-5.

SOMMER, G. Less hands in uranium extraction. Nucl. Active, Jul. 1973. pp. 16-19.

SOMMER, G., BARCZA, N.A., BARKER, I.J., RENNIE, M.S., and STEWART, A.B. Computer- aided control for the production of ferrochromium in a submerged-arc furnace. INFACON 80. PROCEEDINGS OF THE SECOND INTERNA TIONAL FERRO-ALLOYS CONGRESS. Lausanne, Institut des Producteurs de Ferro-AUiages d'Europe Occidentale, 1981. pp. 53-70, 82(i)-82(iv).

71 MINTEK PUBLICATIONS

SOMMER, G., and JOCHENS, P.R. Techniques of micro-thermal analysis based on a thermocouple as heating source and specimen holder. Miner. Sci. Engng, vol. 3, no. 1. Jan. 1971. pp. 3-16.

SOMMER, G., JOCHENS, P.R.28, and HOWAT, D.D.2 Solid state circuitry for a microdifferential thermal analyser. J. Phys. E; Scient. Instrum., vol. 1. 1968. pp. 1116-1118.

SOMMER, G., and MILLER, R.P. A hot stage microscope incorporating a differential thermal analysis unit. J. Scient. Instrum., vol. 43, no. 5. May 1966. pp. 293-297.

SOMMER, G., ORMROD, G.T.W., and CHAIX, R.P. Automation of uranium processing plants. Electron. Instrumn, vol. 3, no. 10. Jan. 1973. pp. 9, 11, 13, 15, 17, 19, 21.

SOMMER, G., ORMROD, G.T.W., and CHAIX, R.P. Recent developments in the instrumentation and automation of uranium-processing plants. J. S.Afr. Inst. Min. Metall., vol. 73, no. 12. JuL 1973. pp. 413-420.

SOMMER, G., and SANDER, H.W. Balanced temperature analyser. 2ND INTERNATIONAL CONFERENCE ON THERMAL ANALYSIS, 1968. Schwenker, R.F., andGarn, P.D. (eds.). New York, Academic Press, 1969. vol. 1. pp. 163-175.

• SOMMER, G., and STEWART, A.B. The introduction of advanced control equipment into mineral- processing operations. 4THIFAC SYMPOSIUM ON AUTOMATION IN MINING, MINERAL AND METAL PROCESSING. PREPRINTS. Westerlund, T. (edj. Helsinki, Finnish Society of Automatic Control, 1983. pp. 197-202.

STANLEY, G.G. Mechanisms in the autogenous mill and their mathematical representation. J. S.Afr. Inst. Min. Metall., vol. 75, no. 4. Nov. 1974. pp. 77-98.

STANLEY, G.G. Considerations in the application of autogenous milling. /. S.Afr. Inst. Min. MetalL, vol. 76, spec, issue. Oct. 1975. pp. 53-55.

STEELE, T. W., and GUERIN, B.D. A new graphite rod for flameless atomic-absorption spectroscopy. Analyst, vol. 97, no. 1150. Jan. 1972. p. 77.

STEELE, T.W., and HANSEN, R.G. Major element data (1966-1978) for the six 'NIMROC' reference samples. Geostand. News!., vol. 3, no. 2. Oct. 1979. pp. 135-172.

STEELE, T.W., WILSON, A., GOUDVIS, R., ELLIS, P.J., and RADFORD, A.J. Trace element data (1966-1977) for the six NIMROC reference samples. Geostand. Newsl., vol. 2, no. 1. Apr. 1978. pp. 71-106.

STEWART, A.B. The use of computers in the South African ferro-alloy industry. PROCEEDINGS, TWELFTH CONGRESS OF THE COUNCIL OF MINING AND METALLURGICAL INSTITUTIONS. Glen, H. W. (ed.). Johannesburg, The South African Institute of Mining and Metallurgy, 1982. vol. 2. pp. 803-808.

STEWART, A.B., and BARKER, I.J. A solution to measurement problems and interaction effects in the control of submerged-arc furnaces. INFACON 80. PROCEEDINGS OF THE SECOND INTERNATIONAL FERRO-ALLOYS CONGRESS. Lausanne, Institut des Producteurs de Ferro- Alliages d'Europe Occidentale, 1981. pp. 71-82(iv).

STEWART, A.B., and MARTIN, P.D. The implementation of data logging and raw-material feed control on a submerged-arc furnace. AUTOMATION IN MINING, MINERAL AND METAL PROCESSING. Lancaster, F.H. (ed.). Pretoria, South African Council for Automation and Computation, 1977. pp. 583-588.

72 MINTEK PUBLICATIONS

STOCH, H., STEELE, T.W., and RANKIN, R.S. The preparation and certification of two samples of chromium ore. Geastand. Newsl., vol. 3, no. I. Apr. 1979. pp. 25-45.

• TE RIELE, W.A.M. Electrowinning of manganese dioxide. VACATION SCHOOL: ELECTROMETALLURGY. Johannesburg, The South African Institute of Mining and Metallurgy, 1983. pp. 238-261.

TUNLEY, T.H., KOHLER, P.16, and SAMPSON, T.D.16 The Metsep Process for the separation and recovery of zinc, iron, and hydrochloric acid from spent pickle liquors. J. S.Afr. Inst. Min. Metall., vol. 76, no. 10. May 1976. pp. 423-427.

UKEN, E-A. Neutron-activation analysis. Miner. Sci. Engng, vol. 2, no. 2. Apr. 1970. pp. 24-34.

UKEN, E-A., WATTERSON, J.I.W., KNIGHT, A., and SELLSCHOP, J.P.F.2 The determination of gold in ores and solutions by activation analysis with a neutron generator. Int. J. Appl. Rad. Isotopes, vol. 19. 1968. pp. 615-623.

UKEN, E-A., WATTERSON, J.I.W., KNIGHT, A., and STEELE, T.W. The application of neutron activation analysis to sorting Witwatersrand gold-bearing ores. J. S.Afr. Inst. Min. Metall., vol. 67, no. 3. Oct. 1966. pp. 99-114.

UKEN, E-A., and WILLIAMSON, J.E. Radioactivity build-up of freshly separated radium from the uranium, actinium and thorium series. Radiochim. Ada, vol. 8, no. 1. 1967. j_p. 60-63.

• ÜLVAN, E., and KOURSAkiS, A. Metal formability in bulk deformation processes. J. Metals, vol. 35, no. 12. Dec. 1983. pp. 20-26.

URQUHART, R.C. The production of high-carbon ferrochromium in a submerged-arc furnace. Miner. Sci. Engng, vol. 4, no. 4. Oct. 1972. pp. 48-65.

URQUHART, R.C., JOCHENS, P.R., and HOW AT, D.D.2 The dissipation of electrical power in the burden of a submerged-arc furnace. 31ST ELECTRIC FURNACE CONFERENCE PROCEEDINGS. Metallurgical Society of AIME. New York, AIME, 1973. vol. 31. pp. 29-48.

URQUHART, R.C., JOCHENS, P.R., and HOWAT, D.D.2 A laboratory investigation of the smelting mechanisms associated with the production of high-carbon ferrochromium. INFACON 74. PROCEEDINGS OF THE FIRST INTERNATIONAL FERRO-ALLOYS CONGRESS. Glen, H.W. fed.). Johannesburg, The South African Institute of Mining and Metallurgy, 1975. pp. 195-205.

URQUHART, R.C., RENNIE, M.S., and RABEY, C.C. The smelting of copper-nickel concentrates in an electric furnace. THE EXTRACTIVE METALLURGY OF COPPER. Yannopoulos, Y., and Agarwal, J. (eds.). New York, AIME, 1976. vol. 1. pp. 274-295.

VAN RENSBURG, W.C.J. Changing patterns in the World's supply of minerals. Miner. Sci. Engng, vol. 6, no. 3. Jul. 1974. pp. 142-153.

VERBAAN, B., and MULLINDER, B. The simultaneous electrowinning, at high current efficiencies, of manganese dioxide and zinc from purified neutral zinc sulphate. Hydrometall., vol. 7. 1981. pp. 339-352.

• VERMEULEN, L.A., HOWAT, D.D., and GOUGH, C.L.M.39 Theories of ball wear and the results of a marked-ball test in ball milling. J. S.Afr. Inst. Min. Metall., vol. 83, no. 8. Aug. 1983. pp. 189-197.

• VILJOEN, E.A., and JOHNSON, J.A. Microbeam techniques in applied mineralogy. ICAM 81. PROCEEDINGS OF THE FIRST INTERNA TIONAL CONGRESS ON APPLIED MINERALOGY. De Villiers, J.P.R., and Cawthorn, P. A. (eds.). Johannesburg, The Geological Society of South Africa, 1983. pp. 499-506.

73 MINTEK PUBLICATIONS

VILJOEN, E.A., JOHNSON, J.A., and HAIG, L. Some factors governing the quality of quantitative electron-microprobe analysis. ELECTRON MICROSCOPY SOCIETY OF SOUTHERN AFRICA — PROCEEDINGS. Durban, the Society, 1980. vol. 10. pp. 19-20.

VON RAHDEN, H. V.R. Apparent fineness values of gold from two Witwatersrand gold mines. Econ. Geol., vol. 60, 1965. pp. 980-997.

VON RAHDEN, H.V.R. A modified halide-disc holder for infrared spectrometry. J. Scienl. Instrum., vol. 44. 1967. p. 168.

VON RAHDEN, H.V.R., and DICKS, L.W.R. Descloizite, mottramite, and vanadinite from South West Africa — an infrared and X-ray study. Am. Mineralogist, vol. 52, Jul.-Aug. 1967. pp. 1067-1076.

WARREN, G.F., JOCHENS, P.R., and HOW AT, D.D.2 Liquidus temperatures and the activities of manganesedi) oxide in slags associated with the production of high-carbon ferromanganese alloys. INFACON 74. PROCEEDINGS OF THE FIRST INTERNATIONAL FERRO-ALLOYS CONGRESS. Glen, H.W. (edj. Johannesburg, The South African Institute of Mining and Metallurgy, 1975. pp. 175-185.

WARSHAWSKY, A. The liquid-liquid extraction of nickel: a review. Miner. Sci. Engng, vol. 5, no. 1. Jan. 1973. pp. 36-52.

WARSHAWSKY, A. Solvent-impregnated resins in hydrometaliurgical applications. Trans. Instn Min. Metall., vol. 83, no. 811. Jun. 1974. pp. C101-C104.

WARSHAWSKY, A. Polystyrenes impregnated with B-diphenylglyoxime, a selective reagent for palladium. Talanta, vol. 21, no. 6. 1974. pp. 624-626.

• WATSON, A.E. From Noah to know-how. Nucl. Active, no. 30. 1984. pp. 31-36.

WATTERSON, J.I.W. Optimization of irradiation and decay times in nuclear activation analysis. J. Radioanalyt. Chem., vol. 26. 1975. pp. 135-150.

WATTERSON, J.I.W., ANDEWEG, A.H., and RAMAHLO, J.2 Isotope source neutron activation for the accurate analysis of kilogram samples of ores and rocks. J. Radioanalyt. Chem., vol. 71, no. 1-2. 1982. pp. 365-375.

WATTERSON, J.I.W., and HAWKINS, D.M.2 Multivariate techniques for the classification of granites. PROCEEDINGS TWELFTH INTERNATIONAL SYMPOSIUM ON THE APPLICATION OF COMPUTERS AND MATHEMATICS IN THE MINERALS INDUSTRY. Johnson, T.B., and Gentry, D. W. feds.). Colorado, Colorado School of Mines, 1974. pp. D57-D76.

WATTERSON, J.I.W., MALKIN, J.T.2, MNGADI, J.T.2, RAMJEE, B.2, and SELLSCHOP, J.P.F.2 A computer-based system for absolute neutron activation analysis. COMPUTERS IN ACTIVATION ANALYSIS AND GAMMA-RAY SPECTROSCOPY. Carpenter, B.S., D'Agostino, M.D., and Yule, H.P. (eds.). Springfield (U.S.A.), National Technical Information Service, 1979. pp. 238-252.

WATTERSON, J.I.W., MNGADI, J.T.2, and SELLSCHOP, J.P.F.2 The analysis of microscopic mineral grains by absolute (parametric) neutron activation. J. Radioanalyt. Chem., vol. 71, no. 1-2. 1982. pp. 377-399.

• WATTERSON, J.I.W., MNGADI, T.J.2, and SELLSCHOP, J.P.F.2 Instrumental neutron-activation analysis of zircons from the Upper Witwatersrand System. ICAM81. PROCEEDINGS OF THE FIRST INTERNATIONAL CONGRESS ON APPLIED MINERALOGY. De Villiers, J.P.R., and Cawthorn, P.A. (eds.). Johannesburg, The Geological Society of South Africa, 1983. pp. 419-424.

74 MINTEK PUBLICATIONS

• WEDEPOHL, A., and BARCZA, N.A. The 'dig-out' of a ferrochromium furnace. ICAM 81. PROCEEDINGS OF THE FIRST INTERNA TIONAL CONGRESS ON APPLIED MINERALOGY De Villiers, J.P.R., and Cawthorn, P.A. feds.J. Johannesburg, The Geological Society of South Africa, 1983. pp. 351-363.

WETHMAR, J.C.M., HOW AT, D.D.2, and JOCHENS, P.R. Phase equilibria in the Cr-Fe-Si-C system in the composition range representative of high-carbon ferrochromium alloys produced in South Africa. J. Metall. ScL, vol. 9. 1975. pp. 291-296.

WETHMAR, J.C.M., HOWAT, D.D.2, JOCHENS, P.R., and STRYDOM, O.A.W.2 Liquidus temperatures in the Cr-Fe-Si system in the composition range representative of ferrochromium-siUcide produced in South Africa. /. S.Afr. Inst. Min. Metall., vol. 73, no. 6. Jan. 1973. pp. 181-183.

WILLEMSE, J.W.", and VILJOEN, E.A. The fate of argillaceous material in the gabbroic magma of the Bushveld Igneous Complex. Johannesburg, The Geological Society of South Africa, spec. pub. I, 1970. pp. 336-366.

WOODBURN, E.T.10, KING. R.P., BUCHALTER, E.M., and PIPER, S.E. Integrated grinding and flotation control-computational problems in an optimum decision making model. A DECADE OF DIGITAL COMPUTING IN THE MINERAL INDUSTRY. Weiss, A. (edj. New York, AIME, 1969. pp. 695-728.

WOODBURN, E.T.10, KING, R.P., and COLBORN, R.P.7 The effect of panicle size distribution on the performance of a phosphate flotation process. Metall. Trans., vol. 2, no. 11. Nov. 1971. pp. 3163-3174.

WOOLLACOTT, L.C.2, HOWAT, D.D.2, and JOCHENS, P.R. The viscosities and electrical conductivities of slags associated with the production of high-carbon ferromanganese alloys. INFACON 74. PROCEEDINGS OF THE FIRST INTERNA TIONAL FERRO-ALLOYS CONGRESS. Glen, H. W. (ed.). Johannesburg, The South African Institute of Mining and Metallurgy, 1975. pp. 227-232.

YOUNG, M.L., and SEE, J.B. Effective thermal conductivities of packed beds of chromite ores. J. S.Afr. Inst. Min. Metall., vol. 77, no. 5. Dec. 1976. pp. 103-113.

ZANDERS, J.A.J. Single-ended differential instrumentation amplifier. Electron. Instrumn, vol. 4, no. II. Mar. 1974. pp. 2-3.

ZANDERS, J.A.J. An electronic differential precision thermometer. Electron. Instrumn, vol. 4, no. 12. Apr. 1974. pp. 24-25, 28.

ZANDERS, J.A.J., BIBBY, D.M., and RASMUSSEN, S.E. A simple automatic sample changer for the gamma-ray counting of reactor-irradiated samples. J. Phys. E; Scient. Instrum., vol. 6. 1973. pp. 973-975.

Organizations Represented by Outside Co-authors

1 Robor Limited 2 University of the Witwatersrand 3 Hindustani Steel, India 4 Massachusetts Institute of Technology, Cambridge, U.S.A. 5 Rössing Uranium Limited, South West Africa 6 Rio Tinto South Africa Limited 7 Atomic Energy Board 8 Rand Mines Limited 9 UMIST (University of Manchester, Institute of Science and Technology), England 10 University of Natal 11 Blyvooruitzicht Gold Mining Co. Ltd

75 MINTEK PUBLICATIONS

12 U.S. Geological Survey, U.S.A. 13 South African Council for Scientific and Industrial Research 14 Imperial College of Science and Technology, London 15 University of Cape Town 16 Woodall-Duckham S.A. (Pty) Ltd 17 Israel Institute of Technology, Haifa, Israel 18 Kennecott Copper Corporation, U.S.A. 19 SaU Magnetics Ltd, Cambridge, U.S.A. 20 Samancor Management Services (Pty) Ltd 21 University of Durban-Westville 22 Mineral Chemistry Research Unit, Murdoch University, Australia 23 Ames Laboratory-USDOE, Ames, U.S.A. 24 University of Queensland, Brisbane, Australia 25 Rand Refinery Limited 26 Anglo-Transvaal Consolidated Investment Co. Ltd 27 Geological Survey of Israel, Jerusalem, Israel 28 Chamber of Mines of South Africa 29 Metalloys Limited 30 Hatch Associates Limited, Toronto, Canada 31 University of South Africa 32 General Mining Union Corporation Limited 33 University of Pretoria 34 Geological Survey of South Africa 35 Rhodes University 36 California Institute of Technology, U.S.A. 37 Smithsonian Institute, Washington D.C., U.S.A. 38 Gencor Research Laboratories 39 Western Platinum Limited 40 Gold Fields of South Africa Ltd 41 East Driefontein Gold Mine 42 General Computing (Pty) Ltd 43 Anglo American Corporation of South Africa Ltd 44 University of Fort Hare 45 Middelburg Steel and Alloys (Pty) Ltd 46 Tetronics Research and Development Ltd, Faringdon, England 47 Iowa State University, Ames, U.S.A. 48 Exxon Research and Engineering Company, Linden, U.S.A. 49 Phosphate Development Corporation of South Africa, Phalaborwa

76 MINTEK PUBLICATIONS

3. PATENTS

The South African patent is given first, followed by the other patents arranged chronologically according to the date on which they were first registered. Copies are not available from Mintek: copies of the South African patents can be obtained from The Registrar of Patents, Trade Marks and Designs, Private Bag X400, Pretoria 0001, and copies of the other patents from The Patent Office, 25 Southampton Buildings, London WC2A 1AY, England. The patents that have been granted since the previous issue of this list (Report M85) are marked •. Title of patent Country Patent no. Date Extraction of copper South Africa 67/2097 3-4-68 Canada 858,472 8-4-68 Congo Republic 833/A 16-4-68 Chile 25.464 30-4-68 Improvements in and relating to the contacting of liquids and South Africa W/SbZS 28-8-7Ö paniculate solids South West Africa 70/0100 28-8-70 Recovery and separation of platinum group metals and gold South Africa 71/4981 26-7-71 Bophuthatswana 71/4981 26-7-71 Transkei 71/4981 26-7-71 Separation and purification of platinum group metals and South Africa 72/0308 18-1-72 gold Bophuthatswana 72/0308 18-1-72 Transkei 72/0308 18-1-72 Venda 72/0308 18-1-72 Zimbabwe 521/72 27-12-72 Great Britain 1,418,391 2-1-73 France 73.01418 16-1-73 Italy 976.937 18-1-73 South West Africa 73/084 20-8-83 Contacting liquids and solids South West Africa 72/052 5-5-72 U.S.A. 3,957,635 8-5-72 Belgium 783.407 12-5-72 Canada 978,722 12-5-72 France 72/17146 12-5-72 West Germany P.22 23 627.7 12-5-72 Luxembourg 65.371 16-5-72 Italy 955.497 31-5-72 Solid/fluid contacting South Africa 71/3139 5-5-72 Bophuthatswana 71/3139 5-5-72 Transkei 71/3139 5-5-72 South Africa 71/3140 5-5-72 Bophuthatswana 71/3140 5-5-72 Transkei 71/3140 5-5-72 Equipment for contacting liquids and solids South Africa 72/4328 23-6-72 South West Africa 73/064 20-6-73 Venda 72/4328 20-6-73 Improved method of measuring rates of dissolution South Africa 72/8807 13-12-72 Venda 72/8807 13-12-72 South West Africa 74/7 8-1-74 Improvements relating to the controlling of processes South Africa 73/1213 21-2-73 Venda 73/1213 21-2-73 The production of ferrochromium alloys South Africa 72/6389 19-3-73 Venda 72/6389 19-3-73 The separation of platinum group metals and gold South Africa 74/5109 9-8-74 Bophuthatswana 74/5109 9-8-74 Transkei 74/5109 9-8-74 Venda 74/5109 9-8-74 Canada 1,061,121 28-7-75 Great Britain 1,490,815 28-7-75 Belgium 832.216 7-8-75 France 75.24681 7-8-75 U.S.A. 3,985,552 7-8-75 Japan 1,077,393 8-8-75 Norway 139 643 18-4-79

77 MINTEK PUBLICATIONS

Title of patent Country Patent no. Date Treatment of platinum group metals and gold South Africa 75/0593 29-1-75 Bophuthatswana 75/0593 29-1-75 Transkei 75/C593 21-1-76 Venda 75/0593 21-1-76 Canada 1,068,116 26-1-76 Norway 141,444 26-1-76 Frarce 76.02279 28-1-76 Belgium 838.029 29-1-76 Great Britain 1,481,295 29-1-76 U.S.A. 4 188 362 28-6-78 The determination of mineral concentrations in slurries South Africa 75/6387 8-10-75 thereof Stainless steel production South Africa 75/7930 22-12-75 Venda 75/7930 22-12-75 Zimbabwe 285/76 13-12-76 Purification of platinum and palladium South Africa 76/3679 21-6-76 Bophuthatswana 76/3679 21-6-76 Transkei 76/3679 21-6-76 Venda 76/3679 21-6-76 U.S.A. 4,105,742 15-6-77 France 77,18691 17-6-77 Belgium 855,936 21-6-77 Great Britain 1,533,542 21-6-77 Canada 1,086,070 22-9-80 Purification of ruthenium South Africa 76/3680 21-6-76 Bophuthatswana 76/3680 21-6-76 Transkei 76/3680 21-6-76 Venda 76/3680 21-6-76 Belgium 855,934 21-5-77 Canada 1,101,678 8-6-77 U.S.A. 4,105,442 15-6-77 France 77.18690 17-6-77 Great Britain 1.533,541 21-6-77 Purification of indium South Africa 76/3681 21-6-76 Bophuthatswana 76/3681 21-6-76 Transkei 76/3681 21-6-76 Venda 76/3681 21-6-76 Canada 1 086 069 8-6-77 U.S.A. 4 130 625 15-6-77 France 77.18692 17-6-77 Belgium 855 935 21-6-77 Great Britain 1 533 373 21-6-77 Improvements relating to briquettes South Africa 76/5287 3-9-76 Venda 76/5287 30-9-76 Bophuthatswana 76/5287 30-9-77 The control of electrical arc furnaces South Africa 77/3923 29-6-77 Venda 77/3923 29-6-77 Zimbabwe 133/78 12-6-78 Iran 19754 13-6-78 Transkei 78/0096 13-6-78 Great Britain 200061S 14-6-78 Spain 471,065 23-6-78 Belgium 868 582 29-6-78 Chile 31.286 30-6-78 Bophuthatswana 79/3823 29-6-79 Brazil PI78O4166 25-1-83 Mexico 5161 12-4-83 Improvements relating to resins South Africa 76/5165 23-8-77 Silver recovery or refining South Africa 77/5210 29-8-77 The recovery and purification of rhodium South Africa 77/5358 6-9-77 Bophuthatswana 77/5358 6-9-77 Transkei 78/0124 9-8-78

78 MJNTEK PUBLICATIONS

Title of patent Country Patent no. Date Canada 1095258 22-8-78 U.S.A. 4,155.750 29-8-78 Belgium 870.256 6-9-78 Great Britain 2.003.846B 6-9-78 Venda 77/5358 4-81 Selective ion exchange media South Africa 77/5398 7-9-77 Bophuthatswana 77/5398 7-9-77 Belgium 870,289 7-2-78 Great Britain 2 017 715B 5-9-78 South West Africa 78/0106 5-9-78 Australia 39620/78 7-9-78 Chile 31218 7-9-78 France 78.25747 7-9-78 U.S.A. 4,202,944 7-9-78 Canada 1,119,343 8-9-78 Extraction of dissolved compounds from slurries South Africa 77/7475 14-12-77 Venda 77/7475 14-12-77 Relating to magnetic separators South Africa 78/1467 14-3-78 Venda 78/1467 14-3-78 Great Britain 2 016 304 28-2-79 U.S.A. 4,260,477 5-3-79 Canada 322,854 6-3-79 Australia 519,775 9-3-79 Selective extractant for metal values South Africa 78/1905 4-4-78 Recovery for re-use of tungsten from tungsten carbide South Africa 78/2623 8-5-78 Arc furnace electrode slip monitoring device South Africa 78/4025 14-7-78 U.S.A. 4 227 030 29-6-79 Leaching process for metal sulphide containing materials South Africa 80/0024 24-1-79 U.S.A. 4,274,931 18-1-80 Canada 344311 24-1-80 Australia 525900 9-12-82 Simultaneous recovery of zinc and manganese South Africa 80/1590 28-5-79 The leaching of sulphidic mattes containing non-ferrous Bophuthatswana 82/0021 9-2-80 metals and iron South West Africa 81/0011 3-2-81 Zimbabwe 34/81 12-2-81 Spain* 499.463/9 16-2-81 Belgium* 887.544 17-2-81 Peru* 2653 17-2-81 Zambia* 16/81 19-2-81 Botswana P381 15-12-81 Leaching of sulphidic mattes containing non-ferrous metals South Africa 81/0701 18-2-80 The leaching of zinc containing sulphide materials South Africa 81/5009 14-4-80 South West Africa 81/0092 22-7-81 Bophuthatswana 81/0155 24-7-81 Venda 81/0087 27-7-81 Zimbabwe 195/81 13-8-81 Selective ion exchange resins South Africa 81/1394 3-3-81 South West Africa 81/0022 3-3-81 Bophuthatswana 81/0035 6-3-81 Belgium 887,872 10-3-81 Chile 32906 10-6-82 Treatment of insoluble iron containing materials to South Africa 82/1779 17-3-82 recover metal values therefrom Swaziland RP/14/1983 17-3-82 Venda 82/0019 24-3-82 Bophuthatswana P.417 30-3-82 Zimbabwe 66/82 2-4-82 The production of mattes containing platinum group South Africa 82/2966 30-4-82 metals and gold Swaziland RP/8/1983 30-4-82

In the name of Anglo American Corporation

79 MINTEK PUBLICATIONS

Title of patent Country Patent no. Date Bophuthatswana 82/0072 10-5-82 Botswana P.421 10-5-82 Venda 82/0038 10-5-82 Zimbabwe 96/82 10-5-82 Selective solvent extraction using organophosphorous South Africa 82/3272 12-5-82 and carboxylic icids Botswana P.435 12-5-82 Venda 82/0039 14-5-82 Zimbabwe 98/82 17-5-82 Zambia 35/82 27-5-82 The measurement of concentration of solid particles South Africa 82/3J83 17-5-82 Botswana P.424 17-5-82 Swaziland RP/10/1983 17-5-82 Venda 82/0040 18-5-82 Zimbabwe 102/82 19-5-82 The contacting of liquids and slurries with solid extractants South Africa 82/5561 2-8-82 in discrete paniculate or granular form Botswana P.429 2-8-82 Swaziland RP/14/1983 2-8-82 Zimbabwe 166/82 6-8-82 Venda 82/0068 10-8-82 The production and treatment of ferrochromiumt South Africa 82/7404 10-10-82 Venda 82/0084 15-10-82 Zimbabwe 221/82 15-10-82 Spain 516 605/5 18-10-82 The refining of ferrochromium metalt South Africa 82/7403 19-10-81 Botswana P.431 11-10-82 Zimbabwe 220/82 15-10-82 Spain 516 606/3 18-10-82 Venda 82/0082 18-10-82 • The protection of water-cooled plasma generating devices South Africa 83/1374 1-3-83 South West Africa 83/0014 1-3-83 Zimbabwe 56/83 2-3-83 • Cathode construction for plasma arc generating devices South Africa 83/1375 1-3-83 South West Africa 83/0013 1-3-83 Zimbabwe 57/83 2-3-83 • The refining of silicon South Africa 83/6819 14-9-83 South West Africa 83/0076 14-9-83 • The production and treatment of ferromanganese and South Africa 83/7183 4-10-82 silicomanganese alloys t In joint names of Mintek and Middelburg Steel Alloys (Pty) Ltd

80 MINTEK PUBLICATIONS

4. SPECIAL PUBLICATIONS

Copies of these publications are available free of charge from Mintek, Private Bag X3015, Randburg, 2125 South Africa. The publications that have become available since the previous issue of this list (Mintek report M85) are marked •

1. Notebook of experiments in extractive metallurgy for high schools. 1975. 42 pp. [Out of print.)

2. Handbook of the interference effects encountered in atomic-absorption spectrophotometry at the National Institute for Metallurgy. 28th Feb., 1978. 137 pp.

• 3. A guide to the presentation of papers. Jul. 1983. (First printed 1979.) 19 pp.

• 4. A manual of analytical methods used at Mintek. 1983. 315 pp.

• 5. A guide to the preparation of slides for technical presentations. 1983. 19 pp.

5. TECHNICAL BULLETINS

1. Continuous ion exchange in hydrometallurgy. 1976. 16 pp. [Superseded by Technical Bulletin no. 2.]

2. The NIMCIX contactor. Continuous ion exchange in hydrometallurgy. Aug. 1978.10 pp. [Out of print.]

81 MINTEK PUBLICATIONS

6. CLASSIFICATION OF RESEARCH TOPICS

In Sections A and B, the research topics at Mintek are classified according to metal or mineral. Thus, Section A, entitled 'Important Metals and Minerals', has subsections for the main base metals (cadmium, cobalt, copper, lead, nickel, and z;ic); ferro-alloys, iron, and steel; gold and silver; platinum-group metals; and uranium. Section B. ^nt fled 'Other Metals, Elements, and Minerals', includes the commodities that are not covered by Section A. Section C includes processes, equipment, reagents, and techniques that cannot be classified under a particular commodity. Section D, entitled 'Properties of Metals and Special Process ng', relates to physical metallurgy, and the last section (E) includes matters related to the wuik of Mintek that cannot be classified under any of the other headings. The page numbers on which the publications are arranged according to topic are given on the right-hand side of the following list. Where no page number is given for a topic, it means that no publications have been issued under that topic.

82 MINTEK PUBLICATIONS

Page no.

A. IMPORTANT METALS AND MINERALS

Al. Base Metals (Cadmium, Cobalt, Copper, Lead, Nickel, Zinc) Al.l. Analysis 87 A1.2. Instrumentation, Optimization, and Control A1.3. Mineralogy 89 A1.4 Nickel-bearing Serpentinites 90 A 1.5. Processes Al.5.1. Electrometallurgical 92 Al.5.2. Hydrometallurgical 92 Al.5.3. Ore-dressing 96 Al.5.4. Pyrometallurgical 97 A1.6. Refining of Lead and Zinc

A2. Ferro-alloys, Iron and Steel, and Related Fields A2.1. Chromium Metals and Chemicals A2.2. Ferro-alloys — Carbonaceous Reducing Agents 97 A2.3. Ferro-alloys — Fundamental Studies 98 A2.4. Ferro-alloys — Instrumentation and Control 102 A2.5. Ferro-alloys — Processes 104 A2.6. Iron and Steel — Conventional Processes 106 A2.7. Iron and Steel — Direct Reduction A2.8. Iron and Steel— Stainless Steel 106 A2.9. Manganese Metal 107 A2.10. Silicon Metal 107

A3. Gold and Silver A3.1. Analysis (see A4.1) A3.2. Instrumentation, Optimization, and Control 107 A3.3. Mineralogy 107 A3.4. Processes A3.4.1. Hydrometallurgical 109 A3.4.2. Ore-dressing 112 A3.4.3. Pyrometallurgical 113 A3.4.4. Refining 113

A4. Platinum-group Metals A4.1. Analysis (Including Analysis of Gold and Silver) 114 A4.2. Mineralogy 119 A4.3. Processes A4.3.1. Ore-dressing and Smelting 120 A4.3.2. Recovery and Refining 120

A5. Uranium A5.1. Analysis AS.1.1. Impurities in Uranium Compounds 122 A5.1.2. Uranium 123 A5.1.3. Uranium-associated Materials 125 A5.2. Fundamental Studies 126 A5.3. Instrumentation, Optimization, and Control 127 A5.4. Mineralogy 127 A5.5. Processes A5.5.1. Hydrometallurgical 128 A5.5.2. Ore-dressing 129

83 MINTEK PUBLICATIONS

B. OTHER METALS, ELEMENTS, AND MINERALS

Bl. Aluminium 129 B2. Aluminous Refractories 130 B3. Antimony 131 B4. Arsenic 131 B5. Asbestos 131 B6. Fluorspar 131 B7. Ilmenite, Rutile, Zircon 132 B8. Iron, Titanium, Vanadium 132 B9. Lime and Limestone BIO. Magnesite and Magnesium Oxide 134 Bll. Magnesium 134 B12. Manganese 135 B13. Niobium and Tantalum 136 B14. Pegmatite 136 B15. Phosphates and Phosphorus Chemicals 138 B16. Potassium Chemicals 138 B17. Rare Earths 138 B18. Sodium Chemicals 139 B19. Tin 139 B20. Tungsten 140 B21. Zirconium (Non-nuclear) 141

C, PROCESSES, EQUIPMENT, REAGENTS, AND TECHNIQUES

Cl. Analytical Techniques Cl.l. Neutron Activation 141 C1.2. Techniques for the Determination of Elements That Are Not Classified Separately 144 C1.3. Techniques Not Included Elsewhere 145

C2. Comminution and Classification 149

C3. Electrochemistry 150

C4. Flotation and Flocculation C4.1. Engineering Studies 152 C4.2. Fundamental Studies 154 C5. Hydrometallurgy C5.1. Fundamental Studies 157 C5.2. Processes and Equipment 161 C5.3. Reagents 163

C6. Measurement and Control 165

C7. Mineralogy CIA. General 167 C7.2. Techniques 168

C8. Ore-dressing (Excluding Flotation and Comminution) 169

C9. Pyrometallurgy 171

CIO. Reference Materials 171

Cl 1. Simulation and Control — Fundamental Studies 173

84 MINTEK PUBLICATIONS

D. PROPERTIES OF METALS AND SPECIAL PROCESSING

Dl. Selection of Materials and Optimization 174 D2. Special Processing

E. RELATED MATTERS

El. Costs and Commodities 175 E2. Manpower 175 E3. Mintek and Its Predecessor (NIM) 176 E4. Miscellaneous 176

85 MINTEK PUBLICATIONS

7. CLASSIFICATION OF PUBLICATIONS ACCORDING TO RESEARCH TOPIC

The publications are listed under topic in the following order: reports, papers, patents, special publications, and technical bulletins. Because the topics are very closely allied, many publications couH have been listed under more than one topic. A reader in search of publications on a particular subject is therefore advised to consult all the topics relevant to his subject. Copies of most of the reports and special publications are obtainable from Mintek, Private Bag X3015, Randburg, 2125 South Africa. For those which are out of print, photocopies can be supplied at a nominal charge. The papers and patents are not available from Mintek: the papers can be consulted in the journals or books in which they were published; copies of the South African patents are obtainable from The Registrar of Patents, Trade Marks and Designs, Private Bag X400, Pretoria 0001, South Africa, and copies of the other patents from the Patent Office, 25 Southampton Buildings, London WC2A 1AY, England. The publications that have been included since the last issue of this list (Report M85) are marked •. MINTEK PUBLICATIONS

A1. Base Metals

A1.1 Analysis

1. Reports

No. Title Year

29 The determination of selenium and tellurium in silver chloride 1966

82 The spectrophotometric determination of cobalt with 2-nitroso-l-napb'hol 1966

160 The determination of copper in rocks and ores by atomic-absorption spectrophotometry 1967

244 The determination of selenium and tellurium in silver chloride and uranium compounds 1967

289 The determination of lead in silicate materials by atomic-absorption spectrophotometry 1968

362 The determination of cobalt in geological samples by atomic-absorption spectrophotometry 1968

491 The determination of nickel, copper, and cobalt in a nickel alloy matte 1969

857 The volumetric determination of bismuth in metallurgical ores and concentrates 1969

1230 The determination of copper and zinc in borehole cores with the Ekco Mineral Analyser 1971

1430 The use of the Ekco Mineral Analyser for the determination of copper and zinc in the presence of iron 1972

1435 The determination of chromium, manganese, iron, cobalt, and nickel by atomic-absorption spectrophotometry using the nitrous oxide-acetylene flame 1972

1688 The analysis of nickel-refining solutions: separation of trr.ce elements by liquid-liquid extraction followed by atomic-absorption measurement 1974

1689 The determination by atomic-absorption spectrophotometry of arsenic, selenium, tellurium, antimony, and bismuth on ion-exchange resins 1974

1718 The determination of silver in lead, copper, and zinc concentrates by instrumental neutron- activation analysis 1975

1736 The determination, by atomic-absorption spectrophotometry and liquid-liquid extraction, of antimony (parts per million) in ores and concentrates 1975

1746 The determination of minor elements in zinc, lead, and copper sulphide concentrates by atomic-absorption spectrophotometry 1975

1761 The determination, by atomic-absorption spectrophotometry, of minor elements in anode sludges and residues 1975

1771 The determination of silver, selenium, tellurium, antimony, tin, lead, and arsenic in anode sludges 1975

1783 The spectrographic determination of minor and trace elements in copper, lead, and zinc concentrates 1976

87 MINTEK PUBLICATIONS

No. Title Year

1784 A single-standard calibration method for use in analysis by X-ray-fluorescence spectrometry 1976

1787 The determination, by atomic-absorption spectrophotometry, of trace elements in sulphide concentrates 1976

1792 The determination, by instrumental neutron-activation analysis, of some trace elements in sulphide ores and concentrates 1976

1794 The application of three-phase liquid-liquid extraction to the analysis of bismuth and tellurium in sulphide concentrates ]976

1795 The determination of minor and trace elements in the leach liquors from anode sludges 1976

1797 A rapid atomic-absorption method for the determination of silver in sulphide ores and concentrates 1976

1798 Interferences in the determination, by atomic-absorption spectrophotometry, of copper, lead, and zinc in sulphide concentrates 1976

1809 The analysis, by flameless atomic-absorption spectrophotometry, of pure selenium and tellurium 1976

1815 The commissioning of an induction-coupled plasma system and its application to the analysis of copper, lead, and zinc concentrates 1976

1836 The analysis of pilot-plant products for copper, zinc, and lead with the Telsec Lab-X-250 Analyser 1977

1838 An investigation of the atomic-absorption spectrophotometric measurement of the

elements that form gaseous hydrides and their determination in metal sulphide concentrates 1976

1857 The determination of some trace elements in sulphide concentrates by spectrophotometry 1977

1869 The separation and determination of trace elements in iron ore 1977

1872 The determination of mercury by cold-vapour atomic-absorption spectrometry 1977

1883 The determination of iron, chromium, titanium, and tungsten in ores and other materials,

by X-ray-fluorescence spectrometry 1977

1911 Methods for the analysis of zinc-bearing materials, electrolytes, and process solutions 1977

1926 The analysis of anode sludges by X-ray-fluorescence spectrometry 1978 1932 A basic computer programme for the evaluation of intensity data from the Telsec Lab- X-250 Analyser 1978 1963 An evaluation of the methods used at the National Institute for Metallurgy for the analysis

of base-metal sulphide concentrates 1978

2022 The determination of thallium and indium in sulphide concentrates 1979

2036 The determination of thallium in ores, concentrates, and metals 1980 M1NTEK PUBLICATIONS

No. Title Year

2061 The determination, by anodic-stripping voltammetry, of copper and lead in silicate reference materials 1980

2124 The direct determination, by differential pulse anodic-stripping voltammetry at the thin mercury-film electrode, of cadmium, lead, and copper 1981

2128 The determination, by differential pulse anodic-stripping voltammetry at the thin-film mercury electrode, of cadmium and thallium in six NIMROC reference materials 1981

M40 The use of X-ray-fluorescence spectrometry in the determination of uranium, cobalt, and sulphur in materials from mine dumps 1982

• Ml 11 The determination, by fiow-injeciiu» analysis, of iron sulphate, silver, and cadmium 1983

2. Papers BIBBY, D.M., and SELLSCHOP, J.P.F. Determination of copper, zinc, iron, and silicon in copper/zinc ore flotation products by fast neutrons. Radiochem. Radioanalyt. Lett., vol. 12, no. 4-5. 1972. pp. 245-257.

DIXON, K., RUSSELL, G.M., WALL, G., and EDDY, B. The analysis of anode slimes, especially copper slimes, by instrumental techniques. Talanta, vol. 26, no. 9. Sep. 1979. pp. 833-839.

ERASMUS. C.S., NOVAK, E., and SELLSCHOP, J.P.F. The determination of copper in native gold by radiochemical separation and neutron-activation analysis. ABSTRACTS, 5TH SYMPOSIUM ON RECENT DEVELOPMENTS IN ACTIVATION ANALYSIS. Geel (Belgium), Central Bureau of Nuclear Measurements, Joint Research Centre of the European Communities, pp. 126 (a, b, c, d).

PEARTON, D.C.G., and TAYLOR, J.D. The determination of copper in rocks and ores by atomic absorption spectroscopy. Bull. S.Afr. Inst. Assayers Analysts, no. 4. Jul. 1969.

A1. Base Metals A1.3. Mineralogy 1. Reports

No. Title Year

1958 A mineralogical examination of sulphide-bearing chromitite from the Loskop Dam area 1978

1962 Supergene alteration of sulphide ores. I. Literature survey, measurement, and effect

on floatability and leachability 1978

2012 A mineralogical investigation of borehole cores from the Trompsburg Complex 1979

2018 Supergene alteration of sulphide ores. II. The effect on the floatability of chalcopyrite,

galena, and sphalerite 1979

2030 Chemical unhomogeneity of sphalerite in a base-metal sulphide deposit 1979

2051 The supergene alteration of sulphide ores. III. The influence of the chemistry of sphalerite on its floatability 1980

89 MINTEK PUBLICATIONS

No. Title Year

2056 The mineralogy and geochemistry of the copper, lead, and zinc sulphides of the Otavi Mountainland 1980

2057 A mineralogical study of the Rooibokkop-Boschhoek copper deposit in the Marble Hall area 1980

• M14D The liberation and size distribution of products from the plants at the Black Mountain Mine 1982

2. Papers

DE WAAL, S.A. Neoformed supergene sphalerite and possible precipitation control by gahnite. Bull. Mineral., vol. 104. 1981. pp. 732-736.

• DE WAAL, S.A. The effects of supergene alteration on the chemistry and floatability of sphalerite. ICAM 81. PROCEEDINGS OF THE FIRST INTERNATIONAL CONGRESS ON APPLIED MINERALOGY. De Villiers, J.P.R., and Cawthorn, P.A. feds.). Johannesburg, The Geological Society of South Africa, 1983. pp. 245-251.

DE WAAL, S.A., and JOHNSON, J.A. Chemical heterogeneity of sphalerite in a base metal sulfide deposit. Econ. Geol., vol. 76. 1981. pp. 694-705. A1 Base Metals A1.4. Nickel-bearing Serpentinites

/. Reports

No. Title Year

86 The investigation of six samples of serpentinite from the Barberton area 1966

88 Quantitative electron-microprobe investigation of the distribution of nickel in serpentinites and associated minerals and rocks from the Barberton area 1966 179 The nickel distribution in weathered serpentinites from Volspruit, Potgietersrus 1967

180 The distribution of nickel in a rock sample from the Louis Moore Mine, northern Transvaal 1967

291 Nickel minerals from Barberton, South Africa. I. Ferroan trevorite 1968

344 Nickel minerals from Barberton: II. Nimite, a nickelian chlorit? 1968

352 Nickel minerals from Barberton: III. Willemseite, a nickelian talc 1968

428 Nickel minerals from Barberton, South Africa: IV. Reevesite, a member of the hydrotalcite group 1968 508 The distribution of nickel in serpentinite samples of borehole cores from the Msauli Mine, Barberton 1969

512 The distribution of nickel in two surface samples of serpentinite 1969

536 The distribution of nickel in limonite-bearing birbirite and gossan from Vlakfontein and Groen fontein in the western Transvaal i969

90 MINTEK PUBLICATIONS

No. Title Year

845 An electron-microprobe study of the nickel distribution in a serpentinite from Volspruit, Potgietersrus 1969

848 The distribution of nickel in serpentinite from Lusinzi, north-eastern Transvaal 1969

897 Nickel in South Africa with special reference to low-grade nickeliferous ores 1970

1319 Nickel minerals from Barberton. V. Trevorite 1971

1356 Nickel in samples of serpentinite from Kaapsehoop, Barberton 1971

1732 A mineralogical examination of eight nickel-bearing rocks from the Grasvally Chromite Mine 1975 2. Papers

DE WAAL, S. A. On the origin of hydrogrossularite and other calcium silicates in serpentinites. Trans. Geol. Soc. S.Afr., vol. 72, pt 1. Jan.-Mar. 1969. pp. 23-27.

DE WAAL, S.A. Nickel minerals from Barberton, South Africa: 1. Ferroan trevorite. Am. Mineralogist, vol. 54, no. 7/8. Jul.-Aug. 1969. pp. 1204-1208.

DE WAAL, S.A. Nickel minerals from Barberton, South Africa: II. Nimite, a nickel-rich chlorite. Am. Mineralogist, vol. 55, no. 1/2. Jan.-Feb. 1970. pp. 18-30.

DE WAAL, S.A. Nickel minerals from Barberton, South Africa: HI. WiHemseite, a nickei-rich talc. Am. Mineralogist, vol. 55, no. 1/2. Jan.-Feb. 1970. pp. 31-42.

DE WAAL, S.A. South African nickeliferous serpentinites. Miner. Sci. Engng, vol. 3, no. 2. Apr. 1971. pp. 32-45.

DE WAAL, S.A. Nickel minerals from Barberton, South Africa: V. Trevorite redescribed. Am. Mineralogist, vol. 57, no. 9/10. Sep.-Oct. 1972. pp. 1524-1527.

DE WAAL, S.A. The nickel deposit at Bon Accord, Barberton, South Africa — a proposed paleometeorite. Mineralization in metamorphic terranes. Johannesburg, The Geological Society of South Africa, spec. pub. 4, 1978. pp. 87-98.

DE WAAL, S.A. Nickel minerals from Barberton, South Africa: VIII. The spinels cochromite and nichromite and their significance to the Bon Accord nickel deposit. Bull. B.R.G.M., Section II, no. 3. 1978. pp. 225-230.

DE WAAL, S.A. The metamorphism of the Bon Accord nickel deposit by the Nelspruit Granite. Trans. Geol. Soc. S.Afr., vol. 82, no. 3. Sep.-Dec. 1979. pp. 335-342.

DE WAAL, S.A., and CALK, L.C. Nickel minerals from Barberton, South Africa: VI. Liebenbergite, a nickel olivine. Am. Mineralogist, vol. 58, no. 7/8. Jul.-Aug. 1973. pp. 733-735.

DE WAAL, S.A., and VILJOEN, E.A. Nickel minerals from Barberton, South Africa: IV. Reevesite, a member of the hydrotalcite group. Am. Mineralogist, vol. 56, no. 5/6. May-Jun. 1971. pp. 1077-1081.

DE WAAL, S.A., VILJOEN, E.A., and CALK, L.C. Nickel minerals from Barberton, South Africa. VII. Bonaccordite, the nickel analogue of ludwigite. Trans. Geol. Soc. S.Afr., vol. 77, pt 3. Sep.-Dec. 1974. p. 375.

91 MINTEK PUBLICATIONS

A1. Base Metals A1.5.1. Processes — Electrometallurgies!

1. Reports

No. Title Year

1693 Research at the National Institute for Metallurgy on the engineering aspects of copper electrowinning 1975

1782 The application of air-sparging techniques to industrial electrodeposition of zinc from acidic zinc sulphate solutions 1976

1796 The mechanism of the electrodeposition and dissolution of nickel from chloride media 1976

1804 The electrodeposition of nickel from ammoniacal solutions 1976

2. Paper

• BIRKETT, M.D. Electrowinning and refining of other metals [cadmium, chromium, gallium, antimony, tellurium, tin, lead, nickel]. VACATION SCHOOL: ELECTROMETALLURGY. Johannesburg, The South African Institute of Mining and Metallurgy, 1983. pp. 279-296.

A1. Base Metals A1.5.2. Processes — Hydrometallurgical

/. Reports

No. Title Year

28 Exploratory tests on the dissolution of manganese dioxide by reaction with sulphuric

acid and a metallic sulphide 1966

81 The solvent extraction of copper cyanide 1966

84 Leaching tests on the copper sulphide mineral valleriite from Palabora Mining Company — a preliminary report 1966 154 The leaching of various copper minerals with dilute sodium cyanide and dilute solutions containing sulphuric acid and ferric ions 1967

155 The quantitative estimation of valleriite in the presence of other copper minerals 1967

157 Results of tests to obtain pure valleriite 1967

172 The solvent extraction of copper cyanide 1967

175 Copper extraction by leaching magnetites from Palabora Mining Company 1967

435 The liquid-liquid extraction of ferric thiocyanate complexes with Versatic 911 1968

847 The liquid-liquid extraction of ferric thiocyanate complexes with carboxylic acids 1969

938 Life test on IRA 400 resin during the recovery of zinc chloride 1970

92 MINTEK PUBLICATIONS

No. Title Year

964 The recovery of copper from sulphate leach liquors by liquid ion exchange with LIX-64N 1970

1078 The complexometric determination of zinc in ores and concentrates, with ion-exchange resin 1970

1085 The optimization of the design of a countercurrent liquid-liquid-extraction plant using LIX-64N 1970

1158 The production of ferric sulphate and sulphuric acid by the autoxidation process using the Fring's aerator 1970

1222 The liquid-liquid extraction of zinc from zinc chloride solutions by the use of di-2-ethyl hexyl phosphoric acid 1971

1575 The recovery of zinc from pickle liquors by ion exchange 1973

1630 An electrochemical investigation of the dissolution of copper, nickel, and copper-nickel alloys in ammonium carbonate solutions 1974

1685 The METSEP Process for the separation and recovery of zinc, iron, and hydrochloric

acid from spent pickle liquors 1974

1711 The oxidation of aqueous solutions of ferrous sulphate in a bubble column 1975

1720 The initial development of processes for the direct leaching of iron-nickel-copper mattes containing platinum-group metals and for the production of ferronickel 1975 1769 An evaluation of the low-pressure ammonia-ammonium sulphate system for the leaching

of local base-metal sulphides 1976

1772 A study of copper recovery by the lime-roast leach process 1975

1776 The extraction of copper from copper-nickel catholyte by ion exchange 1975

1793 The kinetics of mechanism of solvent extraction of copper by LIX 64N and KELEX 100 1976

1799 An electrochemical investigation of copper cementation on iron 1976

1820 The thermodynamics of the formation of chlorocomplexes of iron(iii), cobalt(ii), manganese(ii), and copper(li) in perchlorate medium 1976 1858 The kinetics and mechanism of the non-oxidative dissolution of some iron sulphides in

aqueous acidic solutions 1976

1878 The electrochemical dissolution of galena in aqueous solutions 1977

M57 The hydrometallurgical treatment of liquors generated by the leaching of a low-grade matte 1982

»M59D Testwork on samples of oxidized ore from the Potgietersrus Prospect 1982 M62 A preliminary investigation into the extraction of zinc by direct oxidative leaching of high- manganese sphalerite 1983

93 MINTEK PUBLICATIONS

2. Papers COLBORN, R.P., and NICOL, M.J. An investigation into the kinetics and mechanism of the oxidation of iron(il) by oxygen in aqueous chloride solutions. J. S.Afr. Inst. Min. Metall., vol. 73, no. 9. Apr. 1975. pp. 281-289.

FLEMING, C.A., and MONHEMIUS, A.J. On the extraction of various base metal chlorides from polar organic solvents into cation and anion exchange resins. Hydrometall., vol. 4, no. 2. Mar. 1979. pp. 159-167.

GREEN, B.R., and HANCOCK, R.D. Diluent-modified impregnates for the selective extraction of copper. Sepn Sci. Technol., vol. 15, no. 5. 1980. pp. 1229-1241.

GREEN, B.R., and HANCOCK, R.D. Useful resins for the selective extraction of copper, nickel and cobalt. J. S.Afr. Inst. Min. Metall., vol. 82, no. 10. Oct. 1982. pp. 303-307.

HAINES, A.K., TUNLEY, T.H., TE RIELE, W.A.M., CLOETE, F.L.D., and SAMPSON, T.D. The recovery of zinc from pickle liquors by ion exchange. J. S.Afr. Inst. Min. Metall., vol. 74, no. 4. Nov. 1973. pp. 149-157.

• NATTRASS, W. A., and TE RIELE, W.A.M. Pressure leaching of sphalerite below the melting point of sulphur — an integrated process. ZINC 83. Edmonton (Canada), CIM Metallurgical Society Hydrometallurgy Section, Aug. 1983. Paper 13.

NICOL, M.J. An electrochemical investigation of the dissolution of copper, nickel, and capper-nickel alloys in ammonium carbonate solutions. J. S.Afr. Inst. Min. Metall., vol. 75, no. 11. Jun. 1975. pp. 291-302.

NICOL, M.J. Mechanism of aqueous reduction of chalcopyrite by copper, iron and lead. Trans. Instn Min. Metall., vol. 84. 1975. pp. C206-C209.

NICOL, M. J., PAUL, R.L., and DIGGLE, J.W. The electrochemical behaviour of galena (lead sulphide) — II. Cathodic reduction, Electrochim. Ada, vol. 23. 1978. pp. 635-639.

• PARKER, A.J., PAUL, R.L., and POWER, G.P. Electrochemical aspects of leaching copper from chalcopyrite in ferric and cupric salt solutions. Austral. J. Chem., vol. 34. pp. 13-34.

• PARKER, A. J., PAUL, R.L., and POWER, G.P. Electrochemistry of the oxidative leaching of copper from chalcopyrite. J. Electro-analyt. Chem. Interfacial Electrochem., vol. 118. 1981. pp. 305-316.

PAUL, R.L., NICOL, M.J., DIGGLE, J.W., and SAUNDERS, A.P. The electrochemical behaviour of galena (lead sulphide) — I. Anodic dissolution. Electrochim. Ada, vol. 23. 1978. pp. 625-633.

PAYNTER, J.C. A review of copper hydrometallurgy. J. S.Afr. Inst. Min. Metall., vol. 74, no. 4. Nov. 1973. pp. 158-170.

PHILIP, H.I., and NICOL, M.J. Underpotential deposition and its relation to the anomalous deposition of metals in alloys. J. Eleciroanalyt. Chem., vol. 70. 1976. pp. 233-237.

PHILIP, H.I., and NICOL, M.J. The kinetics and mechanism of the deposition of nickel from chloride solutions. INTERNATIONAL SYMPOSIUM ON CHLORIDE HYDROMETALLURGY, PROCEEDINGS. Brussels, Benelux Metallurgie, 1977. pp. 250-269.

PRATT, J.M., and TILLEY, R.I. The reaction of Cu(H) with LIX 65N in homogeneous solution. Hydrometall., vol. 5. 1979. pp. 29-45.

94 MINTEK PUBLICATIONS

PRESTON, J.S. Solvent extraction of cobalt and nickel by organophosphorus compounds. I. Comparison of phosphoric, phosphonic and phosphinic acid systems. HydrometalL, vol. 9, no. 2. Nov. 1982. pp. 115-133.

• PRESTON, J.S. Solvent extraction of cobalt(H) and nickel(ii) by a quaternary ammonium thiocyanate. Sepn Sci. Technol., vol. 17, no. 15. 1982-83. pp. 1697-1718.

• PRESTON, J.S. Non-chelating oximes in the solvent extraction of base metals. ISEC '83. New York, American Institute of Chemical Engineers, 1983. pp. 357-358.

• PRESTON, J.S. Solvent extraction of nickel and cobalt by mixtures of carboxylic acids and non-chelating oximes. HydrometalL, vol. 11, no. 1. 1983. pp. 105-124.

• PRESTON, J.S. Solvent extraction of base metals by mixtures of organophosphoric acids and non- chelating oxides. Hydrometall., vol. 10, no. 2. May 1983. pp. 187-204.

• PRESTON, J.S. Recent developments in the separation of nickel and cobalt from sulphate solutions by solvent extraction. J. S.Afr. Inst. Min. Metall., vol. 83, no. 6. Jun. 1983. pp. 126-132.

• PRESTON, J.S., and FLEMING, C.A. The recovery of nickel by solvent extraction from acidic sulphate solutions. HYDROMETALLURGY — RESEARCH, DEVELOPMENT AND PLANT PRACTICE. Osseo-Asare, K., and Miller, J.D. (eds.). Warrendale (U.S.A.), The Metallurgical Society of AIME, 1982. pp. 475-489.

TUNLEY, T.H., KOHLER, P., and SAMPSON, T.D. The METSEP Process for the separation and recovery of zinc, iron, and hydrochloric acid from spent pickle liquors. J. S.Afr. Inst. Min. Metall., vol. 76, no. 10. May 1976. pp. 423-427.

WARSHAWSKY, A. The liquid-liquid extraction of nickel: a review. Miner. Sci. Engng, vol. 5, no. 1. Jan. 1973. pp. 36-52.

WARSHAWSKY, A. Solvent-impregnated resins in hydrometallurgical applications. Trans. Instn Min. Metall., vol. 83, no. 811. Jun. 1974. pp. C101-C104.

3. Patents

Extraction of copper. S.Afr. Pat. 67/2097, 3rd Apr., 1968. (Also: Can. Pat. 858,472, 8th Apr., 1968; Chile Pat. 25.464, 30th Apr., 1968; Congo Rep. Pat. 833/A, 16th Apr., 1968.)

Recovery of zinc. S.Afr. Pat. 71/0048, 28th Dec, 1971.

Simultaneous recovery of zinc and manganese. S.Afr. Pat. 80/1590, 28th May, 1979.

The leaching of zinc containing sulphide materials. S.Afr. Pat. 81/5009, 14th Aug., 1980. (Also: Bophuthatswana Pat. 81/0155, 24th Jul., 1981; S.W. Afr. Pat. 81/0092, 22nd Jul., 1981; Venda Pat. 81/0087, 27th Jul., 1981; Zimbabwe Pat. 195/81, 13th Aug., 1981.)

4. Technical Bulletins

Continuous ion exchange in hydrometallurgy. Technical Bulletin no. 1. 1976. 16 pp. [Superseded by Technical Bulletin no. 2.]

The NIMCIX contactor. Continuous ion exchange in hydrometallurgy. Technical Bulletin no. 2. Aug. 1978. 10 pp. [Out of print.]

95 MIMTEK PUBLICATIONS

A1. Base Metals A1.5.3. Processes — Ore-dressing

1. Reports

No. Title Year

159 A radioactive-tracer technique for the study of the flotation of valleriite 1967

218 Exploratory comminution and flotation tests to indicate some characteristics of valleriite 1967

1268 A two-stage process for the recovery of flotation concentrates from copper-zinc ores 1971

1374 Flotation tests on copper-zinc ore from the Letaba district 1971

1384 Flotation tests on samples of Canadian copper-zinc ores 1971

1388 Flotation tests on samples of copper-zinc ores from Finland 1971

1587 A preliminary investigation of the flotation of copper-activated sphalerite without the

use of collectors 1973

1597 The role of sulphur in the flotation of sulphide minerals 1974

1613 The deactivation of copper-activated sphalerite with cyanide 1974

1721 A preliminary investigation into the mechanism of depression in the flotation of sulphide

minerals 1975

1785 Some thermodynamic aspects of systems relevant to the flotation of sphalerite 1976

1871 Batch and pilot-plant flotation tests on copper-nickel ore from the Uitkomst ore-body 1976

1953 A fundamental investigation into the depression of copper-activated sphalerite 1978

1971 The effect of open- and closed-circuit operation in the copper-cleaning flotation circuit

of a complex sulphide ore 1978

• M20 The separation of ore from Cooke into high- and low-grade fractions 1982

2. Papers ALLISON, S.A., HARRIS, P.J., and MARSICANO, F. Depression and deactivation of sphalerite. J. S.Afr. Inst. Min. Metall., vol. 76, spec, issue. Oct. 1975. pp. 123-124. BUSHELL, L.A., and VEITCH, M.L. The influence of chemical environment during milling on the flotation of zinc from complex sulphide ores. J. S.Afr. Inst. Min. Metall., vol. 76, spec, issue. Oct. 1975. pp. 143-145. FINKELSTEIN, N.P., and ALLISON, S.A. The chemistry of activation, deactivation and depression in the flotation of zinc sulphide: a review. FLOTATION. A.M. GAUDIN MEMORIAL VOLUME. Fuerstenau, M.C. (ed.). New York, American Institute of Mining, Metallurgical and Petroleum Engineers Inc., 1976. vol. 1. pp. 414-457.

96 MINTEK PUBLICATIONS

LOO, J.P., COETZEE, C.F.B., and CORRANS, I.J. Beneficiation tests on ore from a complex copper- lead-zinc deposit in the north-western Cape. PROCEEDINGS, TWELFTH CONGRESS OF THE COUNCIL OF MINING AND METALLURGICAL INSTITUTIONS. GlenH.W. (ed.). Johannesburg, The South African Institute of Mining and Metallurgy, 1982. vol. 2. pp. 879-888. A1. Base Metals A1.5.4. Processes — Pyrometallurgical

/. Reports

No. Title Year

1484 Cost estimates for the production of copper wirebars from sulphide ores 1972

1491 Technology and economics of the Claus kiln under South African conditions 1972

1527 The physicochemical properties of slags associated with the smelting of nickel sulphide

concentrates 1973

1628 The recovery of non-ferrous metals from a secondary blast-furnace slag 1974

1664 The smelting of copper-nickel concentrates in an electric furnace 1974 1888 The Imperial Smelting Process and its application to the smelting of complex zinc-lead- copper ores 1977

1952 The effect of slag composition on copper losses to silica-saturated iron silicate slags 1978

2. Papers

URQUHART, R.C., RENNIE, M.S., and RABEY, C.C. The smelting of copper-nickel concentrates in an electric furnace. THE EXTRACTIVE METALLURGY OF COPPER. Yannopoulos, Y., and Agarwal, J. (eds.). New York, AIME, 1976. vol. 1. pp. 274-295.

ELLIOT, B.J., SEE, J.B., and RANKIN, W.J. Effect of slag composition on copper losses to silica- saturated iron silicate slags. Trans. Instn Min. Metall., vol. 87. Sep. 1978. pp. C204-C211.

A2. Ferro-alloys, Iron and Steel, and Related Fields A2.2. Ferro-alloys — Carbonaceous Reducing Agents

1. Reports

No. Title Year

1566 Comparative tests on coke, char, and anthracite 1973

1708 An examination of the suitability of various reducing agents for the production of ferrochrcmium 1975

1968 The influence of carbonaceous reducing agents on the rate of reducing of representative manganese and chromium ores 1978

1969 The interaction of silicon monoxide gas with carbonaceous reducing agents 1978

1975 Reactions in the production of high-carbon ferromanganese from Mamatwan ore 1978

97 MINTEK PUBLICATIONS

No. Title Year

1982 The resistivity of mixtures of Mamatwan manganese ore and reducing agents 1978

1997 A laboratory investigation of reducing agents for use in the electric-smelting industry 1979

2. Papers

DUS, J.M., and SMITH, D.J. Factors affecting the resistivity and reactivity of carbonaceous reducing agents for the electric-smelting industry. J. S.Afr. Inst. Min. Metall., vol. 80, no. 8. Aug. 1980. pp. 286-296.

JOCHENS, P.R., and STANKO, J.S. Ferro-alloy industry looks to big coal supply. Coal, Gold Base Miner., vol. 23, no. 4. Jul. 1975. pp. 51, 55, 57, 58, 63, 64.

• KOURSARIS, A., KLEYENSTÜBER, A.S.E., and FINN, C.W.P. A mineralogical investigation of the reduction of Mamatwan manganese ore with carbon. ICAM 81. PROCEEDINGS OF THE FIRST INTERNATIONAL CONGRESS ON APPLIED MINERALOGY. De Villiers, J.P.R., and Cawthorn, P.A. feds.). Johannesburg, The Geological Society of South Africa, 1983. pp. 375-382.

KOURSARIS, A., and SEE, J.B. Reactions in the production of high-carbon ferromanganese from Mamatwan ore. J. S.Afr. Inst. Min. Metall., vol. 79, no. 6. Jan. 1979. pp. 149-158.

PAULL, J.M., and SEE, J.B. The interaction of silicon monoxide gas with carbonaceous reducing agents. J. S.Afr. Inst. Min. Metall., vol. 79, no. 2 Sep. 1978. pp. 35-41.

A2. Ferro-alloys, iron and Steel, and Related Fields

A2.3. Ferro-alloys — Fundamental Studies

/. Reports

No. Title Year

265 The spectrophotometric determination of minor quantities of chromium in silicate

materials 1967

429 The determination of chromium in chromite 1968

511 The determination of silica in chrome ores and chrome refractories 1969

853 The determination of silicon in ferrochrome alloys 1970

952 The analysis of ferrochrome slag 1970

1020 Phase relationships involving iron, chromium, silicon, and carbon, with special reference

to high-carbon ferrochromium and ferrochromium-silicide alloys. A literature survey 1970

1343 The Pyrometallurgical Research Group's current research programme on ferro-alloys 1971

1365 Studies of incipient fusion in the system chromite-MgO-Al2O3-SiO2-C 1972 1366 Liquidus temperatures, viscosities, and electrica! conductivities of lime-containing slags produced during the smelting of high-carbon ferrochromium and ferrochromium-silicide alloys 1971

98 MINTEK PUBLICATIONS

No. Title Year

1394 The determination of ferrous iron in chromites and chromium ores 1972

1423 The effects of chromium oxide, iron oxide, and calcium oxide in the liquidus temperatures,

viscosities, and electrical conductivities of slags in the system MgO-AI2O3-SiO2 1972 1457 Phase equilibria in the Cr-Fe-Si-C system in the composition range representative of high-carbon ferrochromium alloys produced in South Africa 1972

1458 Liquidus temperatures in the Cr-Fe-Si system in the composition range representative of ferrochromium-silicide alloys produced in South Africa 1972

1463 Liquidus temperatures and activities of manganese(ii) oxide in slags associated with the production of high-carbon ferromanganese alloys 1972

1482 Reactions occurring during the smelting of high-carbon ferrochromium from Transvaal chromite ores 1973

1547 Physicochemical and thermodynamic properties of slags in the system MgO-AlO, 5-SiO2 1973

1548 Physicochemical properties of slags in the system MgO-Al2O3-SiO2 and their application to the technology of ferro-alloy smelting 1973 1549 Thermodynamic and related physicochemical factors pertaining to the production of ferromanganese. A literature survey 1973

1606 The electrical-resistance characteristics of the charge in the electric reduction furnace 1974

1622 The electric conductivity of the charge in a ferrosilicon furnace 1974

1681 The determination of suiphur and phosphorus in chromite 1975

1687 The viscosities and electrical conductivities of slags associated with the production of high- carbon ferromanganese alloys 1975

1698 Measurement of the electrical resistance of ferrochromium furnace charges 1975

1707 The work of the Pyrometallurgy Research Group at the University of the Witwatersrand 1975

1770 The spectrophotometric determination of vanadium in chromium-bearing materials 1975

1790 The rapid determination of manganese, vanadium, and aluminium by instrumental neutron-activation analysis 1976

1791 A motivation for a pyrometallurgical pilot plant J976

1833 Effective thermal conductivities of packed beds of chromite ores 1976

1834 The analysis of slag and silicate samples with a fully automatic sequential X-ray spectrometer \916

1868 The reduction of fluxed and non-fluxed manganese ores by fc r manganese suicide 1977 1879 Alkalis in the iron blast furnace 1977

1913 The mechanism and rate of reduction of Mamatwan manganese-ore fines by car von 1977

99 MINTEK PUBLICATIONS

No. Title Year

1931 The equilibrium between the slag and the metal in the production of low-carbon feromanganese 1977

1934 The spectrometric analysis of chromium-bearir. materials with particular reference to ferrochromium slags and chromite ores 1977

1941 The recovery of chromite anH platinum from the UG-2 Upper Chromitite Layer of the Bushveld Complex at Pandoia Mine 1978

1950 Factors affecting the carbon contents of alloys formed during the prereduction of chromite ores 1978

1957 Solid-state reduction, by graphite and carbon monoxide, of chromite from the Bushveld Complex 1978

1959 The slag-metal equilibrium and the activities of slag and metal components in the production of high-carbon ferromanganese 1978

1967 The movement of the burden in submerged-arc furnaces for the production of high-carbon ferromanganese 1978

2005 The specfometric analysis of manganese-bearing materials, with particular reference to ferromanganese slags and metals 1979

2090 Observations made during the dig-out of a 48 MVA ferrochromium furnace 1981

2099 Copper Josses and the distribution of impurities in the systems FeO-Fe2O3-SiO2-Al2O3-

Cu and FeO-Fe2O3-SiO2-Al2O3-CaO-Cu at 1300 °C 1981 M8 A determination, using solid zirconia electrolytes, of the activities of chromium oxide in ferrochromium alloys and slags at 1650 °C 1982

M15 The separation and determination of trace elements in chromic oxide 1982

• M96 The mathematical modelling of the reduction behaviour of chromite from the Upper Chromitite Layer of the Bushveld Complex 1983 2. Papers

BARCZA, N.A. Slag-metal equilibrium in the production of low-carbon ferromanganese. J. S.Afr. Inst. Min. Metall., vol. 79, no. 10. May 1979. pp. 269-280.

BARCZA, N.A., JOCHENS, P.R., and HOW AT, D.D. The mechanism and kinetics of reduction of Transvaal chromite ores. 29TH ELECTRIC t* URN ACECONFERENCE PROCEEDINGS. Metallurgical Society of AIME. New York, AIME, 1972. vol. 29. pp. 88-93.

BARKER, I. J. Arcing in the electrical circuit of a submerged-arc furnace. Elektrowarme Int., vol. 38, no. Bl. Feb. 1980. pp. B28-B32.

BARKER, I.J., and STEWART, A.B. Inductive reactance, and the operation of large submerged-arc furnaces. J. S.Afr. Inst. Min. Metall., vol. 80, no. 3. Mar. 1980. pp. 123-128.

• BARNES, A.R., FINN, C.W.P., and ALGIE, S.H. The prereduction and smelting of chromite concentrate of low chromium-to-iron ratio. J. S.Afr. Inst. Min. Metall., vol. 83, no. 3. Mar. 1983. pp. 49-54.

100 MINTEK PUBLICATIONS

CHANNON, W.P., and SEE, J.B. The reduction of fluxed and non-fluxed manganese ores by ferromanganese suicide. J. S.Afr. Inst. Min. MeialL, vol. 77, no. 8.

COALE, R.D., WOLHUTER, C.W., JOCHENS, P.R., and HOWAT, D.D. Cementitious properties of metallurgical slags. Chem. Concr. Res., vol. 3, no. 1. 1973. pp. 81-92.

DE VILLIERS, J.P.R. The crystal structure of braunite with reference to its solid-solution behaviour. Am. Mineralogist, vol. 60. 1975. pp. 1098-1104.

FARBACH, D.O.E., HOWAT, D.D., and JOCHENS, P.R. Comparison of techniques for determining the resistance of refractories to slag attack. Trans. Br. Ceram. Soc, vol. 68, no. 4. 1969. pp. 151-158.

FINN, C.W.P., and KUCUKKARAGOZ, C.S. Reaction mechanisms for the prereduction of Winterveld chrome spinels. INFACON 80. PROCEEDINGS OF THE SECOND INTERNATIONAL FERRO- ALLOYS CONGRESS. Lausanne, Institut des Producteurs de Ferro-Alliages d'Europe Occidentale, 1981. pp. 149-230(i).

FINN, C.W.P., and WELLBELOVED, D.B. Determination of the activities of Cr and Cr2O3 in slag- metal systems of ferrochromium smelting composition using stabilized zirconia electrolytes. Solid State Ionics, vol. 2, pt 3/4. 1981. pp. 547-550.

GLEN, H.W. (ed.). INFACON 74. Proceedings of the First International Ferro-alloys Congress, Johannesburg, 22nd to 26th April, 1974. Johannesburg, The South African Institute of Mining and Metallurgy, 1975. 320 pp.

GRIMSLEY, W.D, SEE, J.B., and KING, R.P. The mechanism and rate of reduction of Mamatwan manganese-ore fines by carbon. J. S.Afr. Inst. Min. Metall., vol. 78, no. 3. Oct. 1977. pp. 51-62.

JOHNSTON, G.H., JOCHENS, P.R., and HOWAT, D.D. Physicochemical properties of slags in the system MgO-Al:O3-SiO2 and their application to the technology of ferro-alloy smelting. INFACON 74. PROCEEDINGS OF THE FIRST INTERNATIONAL FERRO-ALLOYS CONGRESS. Glen, H.W. (ed.). Johannesburg, The South African Institute of Mining and Metallurgy, 1975. pp. 217-225.

KOURSARIS, A., and SEE, J.B. The resistivity of mixtures of Mamatwan manganese ore and reducing agents. J. S.Afr. Inst. Min. Metall., vol. 80, no. 7. Jul. 1980. pp. 229-247.

McRAE, L.B., POTHAS, E., JOCHENS, P.R., and HOWAT, D.D. Physicochemical properties of titaniferous slags. J. S.Afr. Inst. Min. Metall., vol. 69, no. 11. 1969. pp. 577-594.

OSSIN, D.I., HOWAT, D.D., and JOCHENS, P.R. Liquidus temperatures, viscosities and electrical conductivities of lime-containing slags produced during the smelting of high-carbon ferrochromium and ferrochromium-silicide alloys. 29TH ELECTRIC FURNACE CONFERENCE PROCEEDINGS. Metallurgical Society of AIME. New York, AIME, 1972. vol. 29. pp. 94-100.

RANKIN, W.J. Silica solubility and the activity of MnO in MnO-SiO2 slags. Metall. Trans., vol. 9B. 1978. pp. 726-728.

RANKIN, W.J., and BISWAS, A.K. The oxidation states of chromium in slag and chromium distribution in slag-metal systems at 1600 °C. Trans. Instn Min. Metall., vol. C87. Mar. 1978. pp. C60- C70.

RANKIN, W.J., and SEE, J.B. The a."kali problem in the blast furnace. Miner. Sci. Engng, vol. 9, no. 2. Apr. 1977. pp. 68-82.

RENNIE, M.S., HOWAT, D.D., and JOCHENS, P.R. The effect of chromium oxide, iron oxide and calcium oxide on the liquidus temperatures, viscosities, and electrical conductivities of slags in the system MgO-AljOj-SiO,. J. S.Afr. Inst. Min. Metall., vol. 73, no. 1. Aug. 1972. pp. 1-9.

101 MINTEK PUBLICATIONS

SEE, J.B. The development of fundamental and applied research in the sphere of ferro-alloys in South Africa. FERROALEACONES: TECHNOLOGIA Y DISPONIBILIDAD. Institute Latinoamericano del Fierro y el Acero. Santiago, Institute 1975. pp. T1-T19. (In Spanish.)

URQUHART, R.C. The production of high-carbon ferrochromium in a submerged-arc furnace. Miner. Sci. Engng, vol. 4, no. 4. Oct. 1972. pp. 48-65.

URQUHART, R.C., JOCHENS, P.R., and HOWAT, D.D. A laboratory investigation of the smelting mechanisms associated with the production of high-carbon ferrochromium. INFACON 74. PROCEEDINGS OF THE FIRST INTERNATIONAL FERRO-ALLOYS CONGRESS. Glen, H.W. (ed.). Johannesburg, The South African Institute of Mining and Metallurgy, 1975. pp. 195-205.

WARREN, G.F., JOCHENS, P.R., and HOWAT, D.D. Liquidus temperatures and the activities of manganese(il) oxide in slags associated with the production of high-carbon ferromanganese alloys. INFACON 74. PROCEEDINGS OF THE FIRST INTERNATIONAL FERRO-ALLOYS CONGRESS. Glen, H. W. (ed.). Johannesburg, The South African Institute of Mining and Metallurgy, 1975. pp. 175-185.

• WEDEPOHL, A., and BARCZA, N.A. The 'dig-out' of a ferrochromium furnace. ICAM 81. PROCEEDINGS OF THE FIRST INTERNATIONAL CONGRESS UNAPPLIED MINERALOGY. De Villiers, J.P.R., and Cawthorn, P.A. (eds.). Johannesburg, The Geological Society of South Africa, 1983. pp. 351-363.

WETHMAR, J.C.M., HOWAT, D.D., and JOCHENS, P.R. Phase equilibria in the Cr-Fe-Si-C system in the composition range representative of high-carbon ferrochromium alloys produced in South Africa. J. Metall. Sci., vol. 9. 1975. pp. 291-296.

WETHMAR, J.C.M., HOWAT, D.D., JOCHENS, P.R., and STRYDOM, O.A.W. Liquidus temperatures in the Cr-Fe-Si system in the composition range representative of ferrochromium-silicide produced in South Africa. /. S.Afr. Inst. Min. Metall., vol. 73, no. 6. Jan. 1973. pp. 181-183.

WOOLLACOTT, L.C., HOWAT, D.D., and JOCHENS, P.R. The viscosities and electrical conductivities of slags associated with the production of high-carbon ferromanganese alloys. INFACON 74. PROCEEDINGS OF THE FIRST INTERNA TIONAL FERRO-ALLOYS CONGRESS. Glen, H. W. (ed.). Johannesburg, The South African Institute of Mining and Metallurgy, 1975. pp. 227-232.

YOUNG, M.L., and SEE, J.B. Effective thermal conductivities of packed beds of chromite ores. J. S.Afr. Inst. Min. Metall., vol. 77, no. 5. Dec. 1976. pp. 103-113.

A2. Ferro-alloys, Iron and Steel, and Related Fields A2.4. Ferro-alloys — Instrumentation and Control

/. Reports

No. Title Year

1818 A microprocessor-based system to control the feed to a ferro-alloy furnace 1976

1885 A data-logging system for a submerged-arc ferro-alloy furnace 1977

2007 The instrumentation and computerization of a 25MV-A submerged-arc furnace 1977

2032 The Cancer Project: a summary of the computer-aided operation of a 48MV-A ferrochromium furnace 1979

102 M1NTEK PUBLICATIONS

No. Title Year

2093 The measurement of electrical variables in a submerged-arc furnace 1981

2129 An electrode controller for submerged-arc furnaces 1981

• MS6 A computer programme for the evaluation of process routes in the production of ferrochromium 1983

• M83 Arc monitoring on a lOOkVA experimental furnace 1983

2. Papers

GRAY, G.T. The design and implementation of a microcomputer system for the control of a submerged arc furnace. PROCEEDINGS OF THE 6THIFAC/IFIP CONFERENCE ON DIGITAL COMPUTER APPLICATION TO PROCESS CON'.^OL. Isermann, /?., end Kaltenecker, H. (eds.). Oxford, Pergamon, 1981. pp. 91-102.

RODD, M.G., and POTGIETER, J.H. A microprocessor based weighing and feed control system. AUTOMATION IN MINING, MINERAL AND METAL PROCESSING. Lancaster, F.H. fed.). Pretoria, South African Council for Automation and Computation, 1977. pp. 381-388.

RODD, M.G., and RABEY, C.C. A computer based system for the evaluation of electric fields in a model submerged arc furnace. AUTOMATION IN MINING, MINERAL AND METAL PROCESSING. Lancaster, F.H. (ed.). Pretoria, South African Council for Automation and Computation, 1977. pp. 371-379.

SOMMER, G., BARCZA, N.A., BARKER, I.J., RENNIE, M.S., and STEWART, A.B. Computer- aided control for the production of ferrochromium in a submerged-arc furnace. INFACON 80. PROCEEDINGS OF THE SECOND INTERNATIONAL FERRO-ALLOYS CONGRESS. Lausanne, Institut des Producteurs de Ferro-Alliages d'Europe Occidentale 1981. pp. 53-70, 82(i)-82(iv).

STEWART, A.B., and BARKER, I.J. A solution to measurement problems and interaction effects in the control of submerged-arc furnaces. INFACON 80. PROCEEDINGS OF THE SECOND INTERNATIONAL FERRO-ALLOYS CONGRESS. Lausanne, Institut des Producteurs de Ferro- Alliages d'Europe Occidentale, 1981. pp. 71-82(iv).

STEWART, A.B. The use of computers in the South African ferro-alloy industry. PROCEEDINGS TWELFTH CONGRESS OF THE COUNCIL OF MINING AND METALLURGICAL INSTITUTIONS. Glen H. W. (ed.). Johannesburg, The South African Institute of Mining and Metallurgy 1982. vol. 2. pp. 803-808.

STEWART, A.B., and MARTIN, P.D. The implementation of data logging and raw-material feed control on a submerged-arc furnace. AUTOMATION IN MINING, MINERAL AND METAL PROCESSING. Lancaster, F.H. (ed.). Pretoria, South African Council for Automation and Computation 1977. pp. 583-588.

3. Patents

The control of electrical . ces. S.Afr. Pat. 77/3923, 29th Jun., 1977. (Also: Belg. Pat. 868 582, 29th Jun., 1978; Bophuthitswana Pat. 79/3923, 29th Jun., 1979; Brazil Pat. P17804166, 25th Jan., 1983; Br. Pat. 2000615, 14th Jun., 1978; Chile Pat. 31.286, 30th Jun., 1978; Iran Pat. 19754, 13th Jun., 1978; Mexico Pat. 5161, 12th Apr., 1983.) Sp. Pat. 471,065, 23rd Jun., 1978; Transkei Pat. 78/0096, 13th Jun., 1978; Venda Pat. 77/3923, 29th Jun., 1977; Zimbabwe Pat. 133/78, 12th Jun., 1978.)

103 MINTEK PUBLICATIONS

Arc furnace electrode slip monitoring device. S.Afr. Pat. 78/4025, 14th Jul., 1978. (Also: U.S. Pat. 4 227 030, 29th Jun., 1979.)

A2. Ferro-alloys, Iron and Steel, and Related Fields A2.5. Ferro-alloys — Processes

1. Reports

No. Title Year

378 A literature survey on the manufacture of ferrochrome 1968

447 Chemical beneficiation and agglomeration of low-grade chromite ores — a literature survey 1969

1247 The pelletizing of chromite fines. A preliminary investigation of the preparation of cold-bonded pellets 1971

1398 The pelletization of chromite fines. Preparation of pellets bonded with bentonite and

indurated by heat treatment 1971

1489 The breakage of Soderberg electrodes 1972

1499 The production of medium-carbon ferrochromium 1972

1513 The upgrading of chromite ore from Moreesburg 1973

1544 The recovery of salable ferrochromium from material discarded by Ferrometals

Limited 1973

1650 The production of medium-carbon ferrochromium alloys by solid-state reduction 1974

1724 The preparation and reduction of chromite pellets containing a reducing agent 1975

1777 Ferro-alloys in Brazil 1976

1895 A review of applications of plasma technology with particular reference to ferro-alloy production 1977 1960 The recovery of ferrochromium furnace slags and related products 1976

2020 The prereduction of Mamatwan-type ores 1981

2070 The prereduction of chromites from the LiG-2 Reef 1980

• M7D The beneficiation of chromite ore from the MG-1 seam near Marikana 1983 Ml3 Factors affecting the production of fines during the screening and handling of high- carbon ferromanganese 1982

M45 Two computer programmes for the calculation of mass and heat balances in the production of high-carbon ferromanganese 1982

• Ml 13 The selective flotation of South African chromite 1983

104 MINTEK PUBLICATIONS

JAMES, H.E., DUNNE, R.C., DE WAAL, S.A., and LAXEN, P.A. Established procedures and new advances in the extraction of gold, uranium, and pyrite from Witwatersrand ores. PROCEEDINGS, TWELFTH CONGRESS OF THE COUNCIL OF MINING AND METALLURGICAL INSTITUTIONS. Glen, H. W. fed.). Johannesburg, The South African Institute of Mining and Metallurgy, 1982. vol. 2. pp. 515-525.

LEVIN, J., and VEITCH, M.L. Laboratory tests on the flotation of pyrite from Witwatersrand gold ores by cationic collectors. J. S.Afr. Inst. Min. Metall., vol. 70, no. 6, pt 2. Jan. 1970. pp. 259-275.

LOUW, G.D., and LAXEN, P.A. The beneficiation of residue at Blyvooruitzicht Gold Mine. J. S.Afr. Inst. Min. Metall., vol. 76, spec, issue. Oct. 1975. pp. 136-139.

UKEN, E-A., WATTERSON, J.I.W., KNIGHT, A., and STEELE, T.W. The application of neutron activation analysis to sorting Witwatersrand gold-bearing ores. J. S.Afr. Inst. Min. Metall., vol. 67, no. 3. Oct. 1966. pp. 99-114.

A3. Gold and Silver

A3.4.3. Processes — PyrometaUurgical

1. Reports

No. Title Year

38 Chemical treatment of refractory gold ores. Literature survey 1966

85 The roasting of refractory gold ores and concentrates. Literature survey 1966

107 Investigations on the treatment of refractory gold ores from the Giant Reefs Mine 1966

211 Refractory gold ores. Report on investigations into roasting of gold concentrates in the Edwards roaster of the Fairview and New Consort reduction plants 1967 A3. Gold and Silver

A3.4.4. Processes — Refining

1. Report

No. Title Year

1880 The electrochemical reduction of silver chloride and its application to the refining of silver 1977

2. Papers

ASHURST, K.G., and NEALE, R.W. The porosity of gold electrodeposits. Trans. Inst. Metal Finishing, vol. 45, no. 2. 1967. pp. 75-82.

ATMORE, R.B., HOWAT, D.D., and JOCHENS, P.R. The effect of slag and gold bullion composition on the removal of copper from mine bullion by oxygen injection. J. S.Afr. Inst. Min. Metall., vol. 72, no. 1. 1971. pp. 5-11.

PARKER, A. J., CLARE, B.W., and SMITH, R.P. Solvation of ions. Some applications. IV. A novel process for the recovery of pure silver from impure silver chloride. Hydrometall., vol. 4. 1979. pp. 233-245.

113 M1NTEK PUBLICATIONS

• PAUL, R.L. Electrowinning of gold and silver. VACA TION SCHOOL: ELECTROMETALLURGY. Johannesburg, The South African Institute of Mining and Metallurgy, 1983. pp. 262-278.

SCHALCH, E., and NICOL, M. J. A study of certain problems associated with the electrolytic refining of gold. Gold Bull., vol. 11, no. 4. Oct. 1978. pp. i 17-123.

SCHALCH, E., NICOL, M. J., and CHARLTON, B.D. An electrochemical study of some problems related to the dectrorefining of gold in chloride solutions. INTERNATIONAL SYMPOSIUM ON CHLORIDE HYDROMETALLURGY, PROCEEDINGS. Brussels, Benelux Metallurgie, 1977. pp. 336-356.

3. Patent

Silver recovery or refining. S.Afr. Pat. 77/5210, 29th Aug., 1977.

A4. Platinum-group Metals

A4.1. Analysis (Including Analysis of Goid and Silver)

1. Reports

No. Title Year

349 The separation of platinum from solution after fusion with potassium bifluoride 1968

526 The determination of the platinum-group metals and gold in ore samples 1969

890 The determination of the platinum-group metals and gold in ore samples — Part II 1969

961 The preparation of standard solutions for the platinum-group metals and gold 1970

970 The determination, by atomic-absorption spectrophotometry, of platinum, palladium, rhodium, ruthenium, gold, silver, and lead, in prills 1970

971 The determination of gold by atomic absorption, and of platinum, palladium, rhodium, and iridium by spectrophotometry, in solutions 1970

976 The determination, by atomic-absorption spectrophotometry, of gold in cupellation prills and in platinum-metal concentrates 1970

977 The collection and rapid determination of noble metals in ores and concentrates by the fusion technique using lead as a collector 1970

994 The separation and determination of noble metals by reversed-phase extraction chromatography 1971

1003 The chromatographic separation and determination of platinum, palladium, rhodium, and iridium 1970

1017 The spectrophotometric determination of rhodium 1970

1037 The determination of gold in concentrates of the platinum-group metals after extraction with dibutyl 'Carbitol' 1970 1048 The determination, by neutron-activation and tracer techniques, of the losses of iridium during the fire-assay procedure for the platinum-group metals 1970

114 M1NTEK PUBLICATIONS

No. Title Year

1086 The determination, by atomic-absorption spectroscopy, of platinum, palladium, rhodium, ruthenium, and gold in the presence of base metals 1970

1108 Interferences relating to the determination of the noble metals by atomic-absorption spectrophotometry 1970

1137 The determination of the platinum-group metals and gold in ore samples — Part HI 1971

1179 The spectrophotometric determination of indium 1971

1185 The recovery of noble metals for analysis. A radio-tracer investigation of losses 1971 1218 The acid-extraction of noble metals from low-grade concentrates and ores, and the subsequent determination of platinum, palladium, rhodium, and gold 1971

1219 Spectrographic analysis for the noble metals present in solutions 1971

1232 The determination of osmium 1971

1245 The separation of non-volatile noble metals by reversed-phase extraction chromatography 197]

1260 Interference by base metals in the spectrophotometric determination of platinum metals 1971

1273 The coprecipitation of noble metals from tellurium. I. Platinum, palladium, rhodium, and gold 1971 1318 The determination, by atomic-absorption spectrophotometry, of osmium and iridium in solution 1971

1324 The separation of base metals from noble metals by cation exchange 1971

1371 Concentration of the noble metals by a fire-assay technique asing nickel sulphide as the collector 1971

1401 The pressure dissolution of platiniferous materials by the sealed-tube technique [superseded by Report 1852] 1972

1432 The determination of ruthenium and osmium in the residues resulting from the leaching of mattes 1972

1500 The chromatographic separation and determination of noble metals in matte-leach residues 1973

1534 The determination, by atomic-absorption spectrophotometry, of noble metals in the presence of sodium, barium, or sulphate ions. A comparison of uranium and lanthanum as releasing agents 1973

1555 The analysis, by atomic-absorption spectrophotometry, of matte-leach residues 1973

1569 The use of DDTU as an analytical reagent for the noble metals 1973

1574 The chromatographic separation and gravimetric determination of noble metals in matte- leach residues 1973

1580 The determination of silver in ores, concentrates, and mattes 1973

115 MINTEK PUBLICATIONS

No. Title Year

1590 The separation of osmium from ruthenium in hydrochloric acid solutions 1974

1598 The use of carbon-rod devices in the determination of noble metals by atomic-absorption

spectrophotometry 1974

1654 The determination of osmium in platiniferous media 1974

1669 An assessment of the carbon-rod atomizer for the determination of silver 1974

1679 The detection of noble-metal impurities in refined noble-metal solutions by thin-layer chromatography 1974 1684 The application of three-phase liquid-liquid extraction to the separation and concentration of noble metals 1974

1705 The effects of various matrix elements on the efficiency of the fire-assay procedure using nickel sulphide as the collector 1975

1714 The efficiency of the fire-assay procedure, using nickel sulphide as a collector, for platinum, silver, gold, and iridium, and of the subsequent parting procedure 1975

1717 The use of isothioronium compounds as liquid-liquid extractants for the noble metals and siler 1975

1739 The determination of trace amounts of noble metals in sulphate media 1975

1826 Dithiocarbamate as a releasing agent in the atomic-absorption determination of noble metals in organic media 1976

1837 The rapid and precise determination of noble metals in matte-leach residues by atomic- absorption spectrophotometry 1976

1852 A revised method for the pressure dissolution of platiniferous materials by the sealed- tube technique [superseding Report 1401] 1976

1864 The preparation of primary standard solutions for each of the noble metals 1977

1865 A sensitive method for the measurement of osmium by atomic-absorption spectrophotometry 1977

1881 n-octylaniline, a new treatment for noble metals 1977

1905 An examination of fire-assay techniques as applied to chromite-bearing materials 1977

1912 The determination, by X-ray-fluorescence spectrometry, of noble and base metals in matte- leach residues 1977

1919 The determination, by X-ray-fluorescence spectrometry, of gold in activated charcoal 1977

1940 The extraction of the noble metals with n-octylaniline, and its application to the analysis of platinum-bearing materials 1978

1948 The measurement of trace amounts of gold in solution by atomic-absorption spectrophotometry and carbon-rod atomization 1978

116 MINTEK PUBLICATIONS

No. Title Year

1953 The separation, by anion exchange, of noble metals on substituted cellulose 1978

2011 The analysis of anode sludges, and their process solutions and beneficiation products 1979

2052 An investigation of the impurities in native gold by neutron-activation analysis 1980

2063 Aerosol deposition and carbon-rod atomization of gold 1980

2064 The on-line monitoring of gold in barren solutions 1980

2065 The determination, by X-ray-fluorescence spectrometry, of gold, silver, and base metals in activated carbon 1980 2068 The determination of platinum, palladium, rhodium, and gold in ores and concentrates by the fusion technique with lead as the collector 1980

2105 The determination, by anodic stripping voltammetry, of silver in polymetallic sulphide ores 1981

M34 The determination, by atomic-absorption spectro^hotometry using electrothermal atomization, of platinum, palladium, rhodium, ruthenium, and iridium 1982

M39 The use of masking agents in the determination, by hydride generation and atomic- absorption spectrophotometry, of arsenic, antimony, selenium, tellurium, and bismuth in the presence of noble metals 1982

M50 The development of an on-line gold analyser 1982

M54 Major amounts of mercury in native gold from upper Witwatersrand sediments 1982

M67 The determination of total cyanide in solutions containing uranium and gold 1982

• M79 An investigation into the determination by X-ray-fluorescence spectrometry of gold and uranium on resin 1983 • M81 The application of the inductively coupled plasma system to the simultaneous determination of precious metals 1983

• M83 The recovery of platinum-group metals and gold by the lead-collection step of the fire-assay procedure 1983

• Ml 11 The determination, by flow-injection analysis, of iron sulphate, silver, and cadmium 1983

2. Papers

BALAES, G.E.E., DIXON, K., RUSSELL, G.M., and WALL, G. Analysis of activated carbon, as used in the carbon-in-pulp process, for gold and eight other constituents. S.Afr. J. Chem., vol. 35, no. 1. 1982. pp. 4-8.

ERASMUS, C.S., NOVAK, E., and SELLSCHOP, J.P.F. The determination of copper in native gold by radiochemical separation and neutron-activation analysis. ABSTRACTS, 5TH SYMPOSIUM ON RECENT DEVELOPMENTS IN ACTIVATION ANALYSIS. Geel (Belgium), Central Bureau of Nuclear Measurements, Joint Research Centre of the European Communities, pp. 126 (a, b, c, d).

117 MINTEK PUBLICATIONS

JONES, E.A., WARSHAWSKY, A., DIXON, K., and NICOLAS, D. J. The group extraction of noble metals with S-(decyl)-7v*,iV'-diphen>i isothiouronium bromide and their determination in the organic extract by atomic-absorption spectrometry. Analyt. Chim. Ada, vol. 94. 1977. pp. 257-268.

MALLETT, R.C. The determination of platinum-group metals by atomic-absorption spectrophotometry. ASSA YING AND ANAL YTICAL TECHNIQUES FOR THE DETERMINA TION OF THE NOBLE METALS. SYMPOSIUM. Williams, B.J., andMunro, H.C. (eds.). Johannesburg, South African Institute of Assayers and Analysts, 1980.

MALLETT, R.C., PEARTON, D.C.G., RING, E.J., and STEELE, T.W. Interferences and their elimination in the determination of the noble metals by atomic-absorption spectrophotometry. Talanta, vol. 19, no. 2. 1972. pp. 181-195.

MALLETT, R.C., PEARTON, D.C.G., RING, E.J., and STEELE, T.W. Interferences encountered in the determination of the noble metals by atomic-absorption spectrophotometry. J. S.Afr. Chem. Inst., vol. 25, no. 3. 1972. pp. 219-229.

MALLETT, R.C., ROYAL, S.J., and STEELE, T.W. A sensitive method for the measurement of osmium by atomic-absorption spectrophotometry. Analyt. Chem., vol. 51. 1979. pp. 1617-1620.

PALMER, I., PALMER, R., and STEELE, T.W. The separation of platinum, palladium, rhodium, and gold from ores and concentrates by aqua regia extraction and by high-temperature chlorination followed by acid leaching. J. S.Afr. Chem. Inst., vol. 25, no. 3. 1972. pp. 190-197.

PEARTON, D.C.G., BRECKENRIDGE, R.L., DUBOIS, M., and STEELE, T.W. The pressure dissolution of platiniferous materials by the sealed-tube technique and the analysis of the resulting solutions. J. S.Afr. Chem. Inst., vol. 25, no. 3. 1972. pp. 244-253.

POHLANDT, C. The extraction of noble metals with n-octylaniline. Talanta. vol. 26, no. 3. Mar. 1979. pp. 199-206.

POHLANDT, C. The use of octylaniline as an extractant in the analysis of platinum-bearing materials. ASSA YING AND ANAL YTICAL TECHNIQUES FOR THE DETERMINA TION OF THE NOBLE METALS. SYMPOSIUM. Williams, B.J., andMunro, H.C. (eds.). Johannesburg, South African Institute of Assayers and Analysts, 1980.

• POHLANDT, C, JONES, E.A., and LEE, A.F. A critical evaluation of methods applicable to the determination of cyanides. J. S.Afr. Inst. Min. Metall., vol. 83, no. 1. Jan. 1983. pp. 11-19.

POHLANDT, C, ROBERT, R.V.D., VALLÉE, A.M., and STEELE, T.W. The separation of non- volatile noble metals on cellulose, and the application of the technique to the analysis of matte-leach residues. J. S.Afr. Chem. Inst., vol. 25, no. 3. 1972. pp. 198-213.

POHLANDT, C, and STEELE, T.W. Separation of the non-volatile noble metals by reversed-phase extraction chromatography. Talanta, vol. 19, no. 7. 1972. pp. 839-850.

POHLANDT, C, and STEELE, T.W. Chromatographic separation and determination of noble metals in matte-leach residues. Talanta, vol. 21, 1974. pp. 919-925.

ROBERT, R.V.D., VAN WYK, E., PALMER, R., and STEELE, T.W. The development of a fire- assay procedure using nickel sulphide as the collector for the noble metals. J. S.Afr. Chem. Inst., vol. 25, no. 3. 1972. pp. 179-189.

RUSSELL, B.G., EDDY, B.T., BECKMANN, G., and STEELE, T.W. The application of X-ray- fluorescence techniques to the determination of the noble metals. J. S.Afr. Chem. Inst., vol. 25, no. 3. 1972. pp. 297-310.

118 MINTEK PUBLICATIONS

RUSSELL, G.M., and WATSON, A.E. The use of an inductively coupled plasma source in the determination of the precious metals by emission spectrometry. ASSAYING AND ANALYTICAL TECHNIQUES FOR THE DETERMINATION OF THE NOBLE METALS. SYMPOSIUM. Williams, B.J., and Munro, H.C. (eds.). Johannesburg, South African Institute of Assayers and Analysts, 1980.

A4. Platinum-group Metals

A4.2. Mineralogy

1. Reports

No. Title Year

325 Investigation for nickel and precious metals in samples from Malelane 1968

1203 The chromite of the Bushveld Igneous Complex. An assessment of published information 1971

1415 The interrelation of the chemical, physical, and certain metallurgical properties of chrome spinels from the Bushveld Igneous Complex 1972

1709 The mineralogy, chemistry, and certain aspects of reactivity of chromitite from the Bushveld Igneous Complex 1975

1726 Mertieite and an unnamed compound of palladium with arsenic and tin in a mineral intergrowth from the Atok Mine 1975

1730 The chromitite from the Marico occurrence, western Transvaal, its alteration, and possible

reasons for its refractory nature 1975

1966 A mineraiogical investigation of ores from the Merensky Reef and their flotation products ! 978

M3 The platinum-group minerals in the UG-2 Layer of the Bushveld Complex at Maandagshoek 254KT 1982

2. Papers

BRYNARD, H.J., DE VILLIERS, J.P.R., and VILJOEN, E.A. A mineraiogical investigation of the Merensky Reef at the Western Platinum Mine, near Marikana, South Africa. Econ. GeoL, vol. 71, no. 7. 1976. pp. 1299-1307.

GASPARRINI, E., and HIEMSTRA, S.A. Paolovite (Pd2Sn) from the Atok Mine in the Merensky Reef. Trans. Geol. Soc. S.Afr., vol. 78. 1975. pp. 167-169.

McLAREN, C.H., and DE VILLIERS, J.P.R. The platinum-group chemistry and mineralogy of the UG-2 Chromitite Layer of the Bushveld Complex. Econ. Geol., vol. 77, no. 6. Sep.-Oct. 1982. pp. 1348-1366.

MIHAL1K, P., HIEMSTRA, S.A., and DE VILLIERS, J.P.R. Rustenburgite and atokite, two new platinum-group metals from the Merensky Reef, Bushveld Igneous Complex. Can. Mineralogist, vol. 13, no. 2. 1975. pp 146-150.

M1HALIK, P., JACOBSEN, J.B.E., and HIEMSTRA, S.A. Platinum-group minerals from a hydrothermal environment. Econ. Geol., vol. 69, no. 2. Mar.-Apr. 1974. pp. 257-262.

SCHWELLNUS, J.S.I., HIEMSTRA, S.A., and GASPARRINI, E. The Merensky Reef at the Atok Platinum Mine and its environs. Econ. Geol., vol. 71. 1976. pp. 249-260.

119 MINTEK PUBLICATIONS

A4. Platinum-group Metals

A4,3.1. Processes — Ore-dressing and Smelting

/. Reports

No. Title Year

1206 A review of the South African platinum-mining industry 1971

1898 Batch and pilot-plant tests on Merensky Reef ore from the Western Platinum Mine 1977

1941 The recovery of chromite and platinum from the UG-2 Upper Chromitite Layer of the Bush veld Complex at the Pandora Mine 1978

1942 The accuracy of assays for platinum-group metals and gold on flotation tailings of platinum ores from the Merensky Reef 1977

1966 A mineralogical investigation of ores from the Merensky Reef and their flotation products 1978

2111 Pilot-plant tests for the recovery of chromite and the noble metals from the UG-2 Reef at Maandagshoek 1981

2112 The behaviour of UG-2 chromite concentrates during smelting 1981

2. Papers

CORRANS, I.J., BRUGMAN, C.F., OVERBEEK, P.W., and McRAE, L.B. The recovery of platinum- group metals from ore of the UG-2 Reef in the Bushveld Complex. PROCEEDINGS, TWELFTH CONGRESS OF THE COUNCIL OF MINING AND METALLURGICAL INSTITUTIONS. Glen, H. W. fed.). Johannesburg, The South African Institute of Mining and Metallurgy, 1982. vol. 2. pp. 629-634.

• CORRANS, I.J., DUNNE, R.C., and ALLISON, S.A. The recovery of platinum-group metals from the chromite reefs of the Bushveld Complex. PREPRINTS — XIV INTERNA TIONAL MINERAL PROCESSING CONGRESS "WORLDWIDE INDUSTRIAL APPLICATION OF MINERAL PROCESSING TECHNOLOGY". Ottawa, The Canadian Institute of Mining and Metallurgy, 1982. pp. II-10.1 to 11-10.21.

URQUHART, R.C., RENNIE, M.S., and RABEY, C.C. The smelting of copper-nickel concentrates in an electric furnace. THE EXTRACTIVE METALLURGY OF COPPER. Yannopoulos, Y., and Agarwat, J. (eds.J. New York, AIME, 1976. pp. 274-295.

A4. Platinum-group Metals

A4.3.2. Processes — Recovery and Refining

I. Reports

No. Title Year

1364 Thiourea anion-exchange resins for the recovery of platinum-group metals and gold 1971

1744 The refining of the platinum-group metals 1975

120 MINTEK PUBLICATIONS

No. Title Year

1800 An electrochemical investigation of the dissolution and passivation of platinum in acid solutions 1976

1822 Stability constants and linear free-energy relations for the platinum-group metals 1976

1864 The preparation of primary standard solutions for each of the noble metals 1977

1996 The extraction of gold from chloride solutions 1978

2. Papers

EDWARDS, R.I. Selectiv „- solvent extractants for the refining of platinum metals. PROCEEDINGS OF THE INTERNA TIONAL SOL VENT EXTRACTION CONFERENCE ISEC 77. for—to, Canadian Institute of Mining and Metallurj; , 1979. (CIM Special Volume 21). vol. 1, pp. 24- . i.

LLOYD, P.J. The extraction of the neutral and anionic nitrato complexes of nitrosylruthenium by long- chain alkyl amines. J. S.Afr. Chem. Inst., vol. 20, no. 2. Jun. 1967. pp. 174-185.

WARSHAWSKY, A. Polystyrenes impregnated with B-diphenylglyoxime, a selective agent for palladium. Talanta, vol. 21, no. 6. 1974. pp 624-626.

3. Patents

Separation and purification of platinum group metals and gold. S.Afr. Pat. 72/0308, 18th Jan., 1972. (Also: Bophuthatswana Pat. 72/0308, 18th Jan., 1972; Brit. Pat. 1,418,391, 2nd Jan., 197?; Fr. Pat. 73.01418, 16th Jan., 1973; Ital. Pat. 976.937, 18th Jan. 1973; S. W. Afr. Pat. 73/084, 20th Aug., 1973; Transkei Pat. 72/0308, 18th Jan., 1972; Venda Pat. 72/0308, 18th Jan., 1972; Zimbabwe Pat. 521/72, 27th Dec, 1972.)

Recovery and separation of platinum group metals and gold. S.Afr. Pat. 71/4981, 26th Jul., 1972. (Also: Bophuthatswana Pat. 71/4981, 26th Jul., 1972; Transkei Pat. 71/4981, 26th Jul., 1972.)

The separation of platinum group metals and gold. S.Afr. Pat. 74/5109, 9th Aug., 1974. (Also: Belg. Pat. 832.216, 7th Aug., 1975; Bophuthatswana Pit. 74/5109, 9th Aug., 1974; Brit. Pat. 1,490,815, 28th Jul., 1975; Can. Pat. 1,061,121, 28th Jul., 1975; Fr. Pat. 75.24681, 7th Aug., 1975; Japan. Pat. 1,077,393, 8th Aug., 1975; Norw. Pat. 139 643, 18th Apr., 1979; Transkei Pat. 74/5109, 9th Aug., 1974; U.S. Pat. 3,985,552, 7th Aug., 1975; Venda Pat. 74/5109. 9th Aug., 1974.)

Treatment of platinum group metals and gold. S.Afr. Pat. 75/0593, 29th Jan., 1975. (Also: Belg. Pat. 838.029, 29th Jan., 1976; Bophuthatswana Pat. 75/0593, 29th Jan., 1976; Br. Pat. 1,481,295, 29th Jan., 1976; Can. Pat. 1,068,116, 26th Jan., 1976; Fr. Pat. 76.02279, 28th Jan., 1976; Norw. Pat. 141,444, 26th Jan., 1976; Transkei Pat. 75/0593, 21st Jan., 1976; U.S. Pat. 4 188 362, 28th Jun., 1978; Venda Pat. 75/0593, 21st J?n., 1976.)

Purification of iridium. S.Afr. Pat. 76/3681, 21st Jun., 1976. (Also: Belg. Pat. 855 935, 21st Jun., 1977; Bophuthatswana Pat. 76/3681, 21st Jun., 1976; Brit. Pat. 1 533 373,21st June., 1977; Can. Pat. 1 086 069, 8th Jun., 1977; Fr. Pat. 77.18692, 17th Jun., 1977; Transkei Pat. 76/3681, 21st Jun., 1976; U.S. Pat. 4 130 625, 15th Jun., 1977; Venda Pat. 76/3681, 21st Jun., 1976.)

121 MINTEK PUBLICATIONS

Purification of platinum and palladium. S.Afr. Pat. 76/3679, 21st Jun., 1976. (Also: Belg. Pat. 855,936, 21st May, 1977; Bophuthatswana Pat. 16/2619, 21st Jun., 1976; Brit. Pat. 1,533,542, 21st Jun., 1977; Can. Pat. 1,086,070, 22nd Sep., 1980; Fr. Pat. 77,18691, 17th Jun., 1977; Transkei Pat. 76/3679, 21st Jun., 1976; U.S. Pat. 4,105,742, 15th Jun., 1977; Venda Pat. 16/2619, 21st Jun., 1976.)

Purification of ruthenium. S.Afr. Pat. 76/3680, 21st Jun., 1976. (Also: Belg. Pat. 855,934, 21st May, 1977; Bophuthatswana Pat. 76/3680, 21st Jun., 1976; Brit. Pat. 1,533,541, 21st Jun., 1977; Can. Pat. 1,101,678, 8th Jun., 1977; Fr. Pat. 77.18690, 17th Jun., 1977; Transkei Pat. 76/3680, 21st Jun., 1976; U.S. Pat. 4,105,442, 15th Jun., 1977; Venda Pat. 76/3680, 21st Jun., 1976.)

The recovery and purification of rhodium. S.Afr. Pat. 77/5358, 6th Sep., 1977. (Also: Belg. Pat. 870,256, 6th Sep., 1978; Bophuthatswana Pat. 77/5358, 6th Sep., 1977; Br. Pat. 2,OO3,846B, 6th Sep., 1978; Can. Pat. 1095258, 22nd Aug., 1978; Transkei Pat. 78/0124, 9th Aug., 1978; U.S. Pat. 4,155,750, 29th Aug., 1978; Venda Pat. 77/5358, Apr. 1981.)

The production of mattes containing platinum group metals and gold. S.Afr. Pat. 82/2966, 30th Apr., 1982. (Also: Bophuthatswana Pat. 82/0072, 10th May, 1982; Botswana Pat. P. 421, 10th May, 1982; Swaziland Pat. RP/8/1983, 30th Apr., 1982; Venda Pat. 82/0038,10th May, 1982; Zimbabwe Pat. 96/82, 10th May, 1982.)

A5. Uranium

A5.1.1. Analysis — Impurities in Uranium Compounds

1. Reports

No. Title Year

64 The determination of the hafnium/zirconium ratio in ammonium diuranate produced

by the Bufflex Process 1966

99 Determination of molybdenum in uranium compounds 1966

129 The polarographic determination of total hexavalent uranium as uranyl fluoride in uranous

fluoride 1967

153 The spectrographic determination of zirconium in uranium oxide 1967

167 The determination of thiocyanate in uranium solutions 1967

174 Determination of chloride in uranium solutions 1967

• 227 The spectrophotometric determination of vanadium in uranium compounds 1967

• 238 The determination of silicon in uranous fluc'ide 1967

256 The determination of carbon in uranium tetrafluoride 1967

• 279 The determination of sodium, potassium, lithium, and calcium in uranium compounds 1968

• 280 The spectrophotometric determination of cobalt with 2-nitroso-l-naphthol 1968

• 318 The spectrophotometric determination of nickel in uranium compounds 1968

354 The determination of trace amounts of arsenic in uranium tetrafluoride 1968

417 Determination of molybdenum in uranium compounds 1968

122 MINTEK PUBLICATIONS

No. Title Year

433 The spectrophotometric determination of microgram quantities of vanadium in U3O8, UO3, and UF4 1968

434 The determination of titanium in uranium compounds 1968

440 Separation of hafnium and zirconium oxides from uranium preliminary to the

spectrographic determination of hafnium 1968

450 The spectrographic determination of alkali metals and alkaline earths in uranium oxide 1968

460 A rapid method for the determination of minor amounts of thorium in aqueous solutions

of uranyl nitrate or chloride 1969

485 Gravimetric determination, using nitron, of nitrates in uranium compounds 1969

• 942 The determination of trace elements on nylon thread 1970

951 Colorimetric determination of minor quantities of nitrate in uranium compounds 1970

1043 The determination of ruthenium in uranyl fluoride 1970

1044 The determination of ruthenium in uranyl fluoride 1970

1089 The rapid volumetric determination of calcium in pregnant solutions in uranium plants 1970

1408 The determination of molybdenum in the solids and solutions resulting from the processing of Witwatersrand uranium ores 1972 1722 The determination of small amounts of fluoride in uranium compounds by use of an ion-selective electrode 1975

2. Paper

RUSSELL, B.G., WILSON, A., LUBBE, M.V., JONES, E., TAYLOR, J.D., and STEELE, T.W. The determination of selenium and telnrium in silver chloride and uranium oxide. Talanta, vol. 14, no. 4. Aug. 1967. pp. 957-966.

A5. Uranium

A5.1.2. Analysis — Uranium

/. Reports

No. Title Year

156 Preliminary observations on the automation of the TBP method for determining uranium 1967

162 The growth of radioactivity in uranium after separation from its daughter products 1967

163 The fluorimetric determination of uranium 1967

257 The determination of uranium by the TBP method 1967

123 MINTEK PUBLICATIONS

No. Title Year

455 Determination of uranium by the TBP method after extraction with ethyl acetate 1968

470 Rapid estimation of uranium in raffinate solutions containing thorium by the pyridylazo- naphthol method 1969 503 Rapid estimation, by the ammonium thiocyanate method, of uranium in raffinate solutions containing thorium, lead, and copper 1969

529 The determination of uranium in the organic solvent from the Purlex Process 1969

1075 The preparation of PADAP — 2-(2-pyridylazo)-5-diethylaminophenol (zinc complex) 1970 1076 The direct determination of acid-soluble uranium in silicate ores and in the solutions resulting from leaching these ores 1970

1077 The determination of acid-soluble, acid-insoluble, and total uranium in silicate ores 1970

1113 The determination of uranium in ores and solutions by X-ray fluorescence 1970

1145 The use of 2-(2-pyridylazo)-5-diethylaminophenol as a spectrophotometric reagent for the determination of uranium 1971

• 1383 The determination of low concentrations of uranium in solutions containing high concentrations of thorium 1971

1625 The determination of uranium and thorium by the use of delayed neutrons 1974

1749 Epithermal-neutron-activation analysis for uranium in Barberton and Bushveld granites 1975

1840 The spectrophotometric determination of total uranium in silicate ores and leach liquors by use of bromo-PADAP 1976

1841 The determination of acid-soluble uranium in silicate ores and solutions 1976

2025 The determination of uranium in solids and solutions by X-ray-fluorescence spectrometry and a background-ratio method with a derived exponent 1979

2026 The determination of uranium in pyrite samples 1979

2034 A rapid method for the determination of uranium in ores and carbonaceous materials by X-ray-fluorescence spectrometry 1980

M16 The preparation and certification of ten uranium reference materials 1982

M40 The use of X-ray-fluorescence spectrometry in the determination of uranium, cobalt, and sulphur in materials from mine dumps 1982 • M79 An investigation into the determination by X-ray-fluorescence spectrometry of gold and uranium on resin 1983

• M84 The preparation and certification of a uranium reference material 1983

• Ml 14 Analytical methods associated with the recovery of uranium 1983

124 MINTED PUBLICATIONS

2. Papers

COOK, E.B.T., and GERtGHTY, A. The spectrophotometric determination of uranium by use of 2-(2-pyridylazo)-5-diethylaminophenoI (PADAP). Bull. S.Afr. Inst. Assayers Analysts, no. 12. Jul. 1971. pp. 1-10.

RUSSELL, B.G., and DOMEL, G. The analysis of uranium by X-ray-fluorescence techniques. Bull. S.Afr. Inst. Assayers Analysts, no. 6. Jan. 1970.

UKEN, E-A., and WILLIAMSON, J.E. Radioactivity build-up of freshly separated radium from the uranium, actinium and thorium series. Radiockim. Ada, vol. 8, no. 1. 1967. pp. 60-63.

A5. Uranium

A5.1.3. Analysis — Uranium-associated Materials

I. Reports

No. Title Year

39 The determination of small amounts of silica in zirconium ores and concentrates 1966

49 The spectrophotometric determination of silica in zirconium oxide 1966

131 The spectrographic determination of titanium oxide, ferric oxide, and silica, in baddeleyite 1967

207 The analysis of baddeleyite by X-ray-fluorescence spectroscopy 1967

272 The determination of iron, titanium, and zirconium, in baddeleyite by X-ray- fluorescence spectroscopy 1968

363 The determination of thorium in solid samples of baddeleyite and carbonatite ores and in the solutions resulung from leaching these ores 1968

451 The determination of thorium in baddeleyite and carbonatite ores and in the solutions resulting from leaching of these ores 1968

894 The determination of thorium in silicate rocks 1969

991 The determination of thorium in solid samples and in solutions resulting from the

leaching of ores 1970

1691 The determination of zirconium and aluminium by 14 MeV neutron-r ;tivation analysis 1975

1723 The determination of zirconium and aluminium in zirconium-aluminium alloys 1975

1985 The determination of boron in high-purity aluminium metal by spark-source mass spectrometry 1978

12S MINTEK PUBLICATIONS

AS. Uranium

A5.2. Fundamental Studies

/. Reports No. Title Year

44 The zero point of charge of uranium dioxide and uraninite 1966

1031 The dissolution of UO2 as an electron-transfer reaction 1970

1144 Three-dimensional predominant-area and solubility diagrams for the uranyl carbonate and uranyl sulphate system at 25 °C 1971

1205 The adsorption of uranyl species on pyrophyllite, quartz, and acid-treated South African uranium ores. A preliminary investigation 1971

1380 An electrochemical model for the leaching of uranium dioxide 1972

1448 A potentiostatic study of the anodic dissolution of uranium dioxide in aqueous solutions 1972

1550 A fundamental study of the dissolution in acid solutions of uranium minerals from South African ores 2. Papers

FLEMING, C.A., and NICOL, M.J. A comparative study of kinetic models for the extraction of uranium by strong-base anion-exchange resins. J. S.Afr. Inst. Min. Metall., vol. 80, no. 2. Feb. 1980. pp. 89-99.

LAXEN, P.A. A kinetic study of the dissolution of uraninites in sulphuric acid. RESEARCH IN CHEMICAL AND EXTRACTION METALLURGY. Australasian Institute of Mining and Metallurgy. Sydney, the Institute, 1967. pp. 181-192.

LAXEN, P.A. The dissolution of UO2 as an electron-transfer reaction. THE RECOVERY OF URANIUM. International Atomic Energy Agency. Vienna, the Agency. 1971. pp. 321-330.

NEEDES, C.R.S., NICOL, M.J., and FINKELSTEIN, N.P. An electrochemical model for the leaching of uranium dioxide. II. Alkaline carbonate media. LEACHING AND REDUCTION IN HYDROMETALLURGY. Burkin, A.R. (ed.J. London, Institution of Mining and Metallurgy, 1975. pp. 12-19.

NICOL, M.J., and NEEDES, C.R.S. The anodic dissolution of uranium dioxide. I. In perchlorate solutions. Electrochim. Acta, vol. 20, no. 8. Aug. 1975. pp. 585-589.

NICOL, M.J., and NEEDES, C.R.S. The anodic dissolution of uranium dioxide. II. In carbonate solutions. Electrochim. Acta, vol. 22. 1977. pp. 1381-1384.

NICOL, M.J., NEEDES, C.R.S., and FINKELSTEIN, N.P. An electrochemical model for the leaching of uranium dioxide. I. Acid media. LEACHING AND REDUCTION IN HYDROMETALLURGY. Burkin, A.R. fed.}. London, Institution of Mining and Metallurgy, 1975. pp. 1-11.

SCOTT, P.D., GLASSER, D., and NICOL, M.J. Kinetics of dissolution of/3-uranium trioxide in acid and carbonate solutions. J. Chem. Soc, Dalton Trans., 1977. pp. 1939-1946.

126 MINTEK PUBLICATIONS

A5. Uranium

A5.3. Instrumentation, Optimization, and Control

/. Reports

No. Title Year

341 An experimental on-stream colorimetric uranium monitor and solvent-addition controller for the Purlex process 1968

1477 The control of Purlex plants 1972

1530 AUREOL — an X-ray-absorption analyser for the determination of the uranium on loaded resin in ion-exchange plants 1973

2. Papers

NEEDES, C.R.S., NICOL, M.J., FINKELSTEIN, N.P., and ORMROD, G.T.W. The industrial application of a uranium dioxide electrode. J. S.Afr. Inst. Min. Metall., vol. 76, no. 4. Nov. 1975. pp. 238-246.

SOMMER, G. Less hands in uranium extraction. Nucl. Active, Jul. 1973. pp. 16-19.

SOMMER, G., ORMROD, G.T.W., and CHAIX, R.P. Automation of uranium processing plants. Electron. Instrumn, vol. 3, no. 10. Jan. 1973. pp. 9, 11, 13, 15, 17, 19, 21.

SOMMER, G., ORMROD, G.T.W., and CHAIX, R.P. Recent developments in the instrumentation and automation of uranium-processing plants. J. S.Afr. Inst. Min. Metall., vol. 73, no. 12. Jul. 1973. pp. 413-420.

A5. Uranium

A5.4. Mineralogy

1. Reports

No. Title Year

237 The mineralogy of uranium in Western Areas ores 1967

414 The geochemistry of some uranium minerals in the Dominion Reef and Witwatersrand Systems 1968

415 Uranium compounds in the Dominion Reefs, and their association with phosphorus compounds 1968

2. Papers

BERNING, J., COOKE, R., HIEMSTRA, S.A., and HOFFMAN, U. The Rössing uranium deposit, South West Africa. Econ. Geol., vol. 71. 1976. pp. 351-368.

HIEMSTRA, S.A. The mineralogy and petrology of the uraniferous conglomerate of the Dominion Reefs Mine, Klerksdorp area. Trans. Geol. Soc. S.Afr., vol. 71, no. 1. 1968. pp. 1-65.

127 MINTEK PUBLICATIONS

HIEMSTRA, S.A. The geochemistry of the uraniferous conglomerate of the Dominion Reefs Mine, Klerksdorp area. Trans. Geol. Soc. S.Afr., vol. 71, no. 1. 1968. pp. 67-100.

• SMITS, G., and UITERWIJK, B.H. The uranium mineralization in the south-western Karoo: its mineralogy and genesis. ICAM81. PROCEEDINGS OF THE FIRST INTERNA TIONAL CONGRESS ON APPLIED MINERALOGY. De VUliers, J.P.R., and Cawthorn, P.A. feds.). Johannesburg, The Geological Society of South Africa, 1983. pp. 301-313.

A5. Uranium

A5.5.1. Processes — Hydrometallurgical

1. Reports

No. Title Year

452 The Purlex Process — a description of the pilot plant leading to the use of the process

in South Africa 1969

1454 A dynamic model for the extraction bank of Purlex plants 1972

2. Papers BOYDELL, D.W., LAXEN, P.A., BOSCH, D.W., and CRAIG, W.M. New uranium-recovery circuit at Blyvooruitzicht. CIM Bull., vol. 72, no. 805. May 1979. pp. 127-134. BOYDELL, D.W., and VILJOEN, E.B. Uranium processing in South Africa from 1961 to 1981. PROCEEDINGS, TWELFTH CONGRESS OF THE COUNCIL OF MINING AND METALLURGICAL INSTITUTIONS. Glen, H. W. (ed.). Johannesburg, The South African Institute of Mining and Metallurgy, 1982. vol. 2. pp. 575-582.

CLOETE, F.L.D. The Relix process for the resin-in-pulp recovery of uranium. J. S.Afr. Inst. Min. Metall., vol. 81, no. 3. Mar. 1981. pp. 66-73.

CRAIG, W.M., HAINES, A.K., NICOL, D.I., OLËN, CM., DOUGLAS, M.E.E., and LOUW, G.D. The design and operation of a continuous ion-exchange demonstration plant for the recovery of uranium. J. S.Afr. Inst. Min. Metall., vol. 78, no. 12. Jul. 1978. pp. 316-324.

FAURE, A., and TUNLEY, T.H. Uranium recovery by liquid-liquid extraction in South Africa. THE RECOVERY OF URANIUM. International Atomic Energy Agency. Vienna, the Agency, 1971. pp. 241-251.

FORD, M.A., SMITS, G., and McCULLOCH, H.W. The recovery of uranium with molybdenum as a byproduct from deposits in the Karoo. PROCEEDINGS, TWELFTH CONGRESS OF THE COUNCIL OF MINING AND METALLURGICAL INSTITUTIONS. Glen, H. W. (ed.). Johannesburg, The South African Institute of Mining and Metallurgy, 1982. vol. 2. pp. 583-593.

HAINES, A.K. The development of continuous fluidized-bed ion exchange in South Africa, and its use in the recovery of uranium. J. S.Afr. Inst. Min. Metall., vol. 78, no. 2. Jul. 1978. pp. 303-315.

HAINES, A.K., CRAIG, W.M., FAURE, A., HENDRIKSZ, A.R., WILLS, W.J., and NICOL, D.I. The use of weak-base resins in the recovery of uranium from unclarified leach liquors. ELEVENTH INTERNA TIONAL MINERAL PROCESSING CONGRESS 1975. Instituto di Arte Mineraria. Rome, Aziende Tipografiche Bardi, 1976. Paper 32, pp. 1-28.

128 MINTEK PUBLICATIONS

JAMES, H.E., DUNNE, R.C., DE WAAL, S.A., and LAXEN, P.A. Established procedures and new advances in the extraction of gold, uranium, and pyrite from Witwatersrand ores. PROCEEDINGS, TWELFTH CONGRESS OF THE COUNCIL OF MINING AND METALLURGICAL INSTITUTIONS. Glen. H. W. (ed.J. Johannesburg, The South African Institute of Mining and Metallurgy, 1982. vol. 2. pp. 515-525.

• SIMONSEN, H.A. The engineering economics of uranium processing. PROCEEDINGS OF THE WORKSHOP ON ECONOMICS OF URANIUM ORE PROCESSING OPERA TIONS. Paris, Nuclear Energy Agency, 1983.

A5. Uranium

A5.5.2. Processes — Ore-dressing

2. Papers

CORRANS, I.J., and LEVIN, J. Wet high-intensity magnetic separation for the concentration of Witwatersrand gold-uranium ores and residues. J. S.Afr. Inst. Min. Metall., vol. 79, no. 8. Mar. 1979. pp. 210-228.

KELEGHAN, W.T.H WHIMS for low-grade uranium. Nucl. Active, no. 16. Jan. 1977. pp. 3-5.

B1. Aluminium

I. Reports

No. Title Year

26 Economic evaluations of the possible production of alumina from Sasol ashes by the ammonium sulphate baking process and the ammonium fluoride and sulphuric acid leaching process 1967

30 The extraction of alumina from Sasol coal ash 1966

37 The determination of aluminium in silicate samples by complexometric titration 1966

51 Exploratory tests on the recovery of diaspore from a ferruginous shale from the

Gamagararand 1966

69 Preliminary examination of ijolite from Spitzkop 1966

89 Mineralogical examination of ijolite from Spitzkop 1966 136 Determination of aluminium in silicate materials by solvent extraction and atomic- absorption spectrophotometry 1967

137 Determination of aluminium by atomic-absorption spectrophotometry with the nitrous oxide and acetylene flame 1966

143 A review of the investigations into the possibility of producing alumina and aluminium from South African ores 1967

149 The i \,w of alumina, potash, and soda from a nepheline concentrate 1967

466 The volumetric determination of aluminium in silicate materials 1969

129 MINTEK PUBLICATIONS

No. Title Year

1808 Spectrophotometric determination (with pyrocatechol violet as chromogenic agent) of aluminium in zirconium metals and in the residues from anode sludges 1976

1902 The determination of boron in aluminium of high purity 1977

M19 Beneficiation tests on two samples of bauxite from Natal 1982

• M89 The preparation of beneficiated bauxite for an evaluation of quality 1983

B2. Aluminous Refractories

/. Reports

No. Title Year

48 The investigation of a suspected sillimanite-bearing sample 1966

307 Preliminary examination of kyanite-bearing material from Granville, Leydsdorp 1968

347 Concentration tests on 'rich blue nobby' kyanite-bearing ore from Nkandhla, Zululand 1968

493 Concentration of andalusite from alluvial sands from the farm Goedgelegen, Groot Marico district 1969

1281 The heavy-medium cyclone concentration plant for the treatment of andalusite sands on the farm 'Wonderfontein', Groot Marico district 1971

1445 Cost assessment for the production of andalusite concentrates 1972

1478 An examination of two andalusite-bearing samples from Magostad No. 6, Marico district, western Transvaal 1972 1505 The production of the refractory aluminium silicates, with special reference to South Africa 1973

1779 A summary of work done on the concentration of andalusite from deposits in the western Transvaal 1976

• 2106D The evaluation of drill cores and a bulk sample from a deposit of andalusite near Thabazimbi 1981

• 2109D The evaluation of an andalusite deposit at Kleinfontein, Groot Marico 1981

• M43D Beneficiation tests on andalusite-bearing shales from a farm near Thabazimbi 1982

2. Papers

OVERBEEK, P.W. The beneficiation of andalusite. S.A. CERAMIC SOCIETY 14TH ANNUAL SYMPOSIUM PROCEEDINGS. Pretoria, South African Ceramic Society, 1982. 34 pp.

OVERBEEK, P.W. The development of the andalusite industry in South Africa. PROCEEDINGS, TWELFTH CONGRESS OF THE COUNCIL OF MINING AND METALLURGICAL INSTITUTIONS. Glen, H. W. (ed.). Johannesburg, The South African Institute of Mining and Metallurgy, 1982. vol. 2. pp. 505-513.

130 MINTEK PUBLICATIONS

B3. Antimony

/. Reports

No. Title Year

151 The spectrophotometric determination of minor amounts of antimony 1967

1665 The determination of minor amounts of antimony in ores and concentrates by atomic- absorption spectrophotometry 1974

B4. Arsenic

/. Report

No. Title year

333 The hot-water leaching process for refining arsenious oxide in flue dusts from the Fairview Mine 1968 B5. Asbestos

2. Papers GLEN, H.W. (ed.). Proceedings of Asbestos Symposium, Johannesburg, 3rd-7th October, 1977. Johannesburg, Department of Mines, 1978. 156 pp.

B6. Fluorspar

1. Reports

No. Title Year

77 Concentration of fluorspar from the farm Strydfontein, Marico district. Preliminary

investigation 1966

208 Determination of fluorine in fluorspar ores by neutron-activation analysis 1967

1424 A review of the World's fluorspar industry, with particular reference to South Africa 1972

1438 A mineralogical examination of fluorspar ores from the Ottoshoop area 1972

1486 Review of the fluorochemical industry of the World 1972

1577 Quantitative analysis of fluorite ores by X-ray diffraction 1973

1595 Preliminary tests on low-grade brecciated fluorspar ore from the Ottoshoop district 1973

1612 Flotation tests on sulphide-bearing high-grade brecciated and wad ores 1974

1615 Fluorspar pellets. A survey of the World market and an assessment of future South African production 1974 1643 Further tests on low-grade brecciated fluorspar ore from the Ottoshoop district 1974

131 MINTEK PUBLICATIONS

No. Title Year

1646 Examination of the method of analysis for calcium fluoride in fluorspar 1974

1660 An economic assessment of the production of high-grade fluorspar pellets 1974

1668 An updated summary of the World's fluorspar industry 1974

1715 Flotation tests on various types of ore from the Ottoshoop district 1975

1725 The determination of silica in fluorspar by 14 MeV neutron-activation analysis 1975

1814 An updated summary of the World's fluorspar industry, 1975 1976

1886 A rapid method for the determination of fluoride in geological samples 1977

2004 Laboratory and pilot-plant tests on ore from the Witkop fluorspar mine 1980

2134D On-line analysis, by X-ray diffraction, of fluorspar-containing slurries 1981

M12 A mineralogical investigation of the chlorine content of the fluorspar from a deposit in the Zeerust area 1982

Papers

GÖSSLING, H.H., and McCULLOCH, H.W. Fluorspar — the use of a non-metallic mineral. Miner. Sci. Engng, vol. 6, no. 4. Oct. 1974. pp. 206-222.

SEE, J.B. Fluorspar and fluorine compounds in high-temperature smelting and refining of metals. Miner. Sci. Engng, vol. 8, no. 4. Oct. 1976. pp. 217-241.

B7. llmenite, Rutile, Zircon

/. Reports

No. Title Year

1217 Investigation of beach sands from Bantu Area No. 4, Nhlabane, Zululand 1971

1541 Further tests on beach sands from Bantu Area No. 4, Nhlabane, Zululand 1973

1619 Reduction of the chromium in ilmenite concentrates 1974

1632 A mineralogical examination of beach-sand concentrates from a pilot plant at Richards Bay 1974

1830 The determination of iron in zircon beach sands and its leachability 1977

B8. Iron, Titanium, Vanadium

1. Reports

No. Title Year

54 Electron-microprobe investigation of magnetite from the Bushveld Igneous Complex 1966

132 MINTEK PUBLICATIONS

No. Title Year

161 The quantitative electron-microprobe determination of the magnesium content of magnetite from Phalaborwa 1967

276 The determination of vanadium in silicate materials by atomic-absorption spectrophotometry 1968

328 A mineralogical examination of iron ore from Nooitgedacht, near Airlie Station, eastern Transvaal 1968

456 Method for the determination of vanadium in silicate materials by atomic-absorption

spectrophotometry 1969

487 The spectrophotometric determination of minor quantities of vanadium in silicate materials 1969

497 The determination of ferric iron using Titron 1969

1088 The determination of ferrous iron in refractory materials 1970

1096 The spectrophotometric determination of titanium in ores, rocks, and minerals, with

diantipyrylmethane 1970

1488 Extraction of rutile from Highveld smelter slags 1972

1515 A mineralogical investigation of titaniferous magnetite from the Mambula Intrusion, Natal 1973

1522 An electron-microprobe investigation of an exsolved mineral in a sample of magnetite 1973

1546 Pilot-plant smelting campaign on iron ores from Tete 1973

1557 Cost estimates for the production of pig iron in the Tete district of Mocambique 1973

1565 A mineralogical investigation of the vanadium-rich titaniferous iron ore from Tete, and

the slag produced from it 1973

1600 Dilute-acid leaching of slag from Tete ore 1973

1602 The roasting of Tete slag for the extraction of vanadium 1973

1614 The extraction of rutile from smelter slags 1974

1620 The recovery of titanium dioxide from Tete slag by the sulphate route 1974

1635 Magnetic tests on Tete slag and ore 1974

1671 Pyrometallurgical retreatment of a slag for the recovery of vanadium 1974

1830 The determination of iron in zircon beach sands and its leachability 1977

1875 The determination of tungsten and iron in ferrotungsten alloys by X-ray-fluorescence spectrometry 1977 2002 The spectrochemical determination of phosphorus, magnesium, and iron in phosphate rocks and sulphuric acid leach liquors 1979

133 MINTEK PUBLICATIONS

No. Title Year

2017 Vanadium-bearing titaniferous iron ores from the Rooiwater, Usushwana, Mambula, Kaffirskraal, and Trompsburg Igneous Complexes 1979

2073D A preliminary investigation of the concentration process at Ucar Minerals Corporation 1980

• M33D Exploratory tests on the reduction of the sulphur content of sponge iron 1982

M47 The separation of trace elements from iron, and the analysis of iron-rich ores for use as reference materials 1982 • Mill The determination, by flow-injection analysis, of iron sulphate, silver, and cadmium 1983

2. Papers

JOCHENS, P.R., SOMMER, G., and HOWAT, D.D. Preliminary equilibrium and non-equilibrium phase studies of titaniferous slags. J. Iron Steel Inst., vol. 207, no. 2. Feb. 1969. pp. 187-192.

LYCETT, R.A.H., JOCHENS, P.R., and HOWAT, D.D. The crystallization of rutile from titaniferous slags. J. S.Afr. Inst. Min. Metall., vol. 76, no. 2. Sep. 1975. pp. 20-24.

PEARTON, D.C.G., TAYLOR, J.D., FAURE, P.K., and STEELE, T.W. The determination of vanadium in silicate materials by atomic absorption spectrophotometry. Analyt. Chim. Ada, vol. 44. 1966. pp. 353-359.

B10. Magnesite and Magnesium Oxide

/. Reports

No. Title Year

1706 Concentration of magnesite from Apiesbomen, Buigersfort district 1975

• 2102D The recovery of magnesite from dump fines from the Strathmore Mine 1981

B11. Magnesium

I. Reports

No. Title Year

359 The separation and determination of calcium and magnesium in silicate material 1968

361 The spectrophotometric determination of small amounts of calcium and magnesium in glass sands and allied materials 1968 392 The spectrophotometric determination of small amounts of calcium and magnesium in glass sands and allied materials 1968

2002 The spectrochemical determination of phosphorus, magnesium, and iron in phosphate rocks and sulphuric acid leach liquors 1979

134 MINTEK PUBLICATIONS

B12. Manganese

/. Reports

No. Title Year

63 X-ray and spectrographic analyses of seven samples of manganese ores 1966

65 Samples of manganese dioxide for battery tests by the CSIR 1966

78 X-ra> investigation of four samples of manganese ore 1966

83 Qualitative X-ray examination of two samples of MnO2 ore 1966

97 X-ray diffraction analysis of six samples of manganese ore from Graskop, eastern Transvaal 1966

98 Qualitative X-ray analysis of manganese dioxide ore from Graskop 1966

108 An X-ray-diffraction method for the quantitative determination of nsutite (7~MnO2)

and cryptomelane (a-MnOJ in ores from the Gopani Mine, Transvaal 1966

111 The X-ray investigation of a sample of upgraded material from the Graskop wad deposit 1966

216 The determination of minor quantities of manganese in silicate materials 1967

288 Ramsdellite (MnO2) from Hotazel Mine, northern Cape Province 1968

1920 A mineralogical investigation of Mamatwan and Wessels manganese ores 1977

2094 The determination, by atomic-absorption spectrophotometry, of impurities in manganese

dioxide 1981

2131 The separation of trace elements in manganese dioxide 1981

• M60D The production of electrolytic manganese dioxide from furnace sludge 1982

• M64D Isotope-source neutron-activation analysis for the determination of manganese in bulk samples 1982 • M70 The preparation and certification of two reference materials of South African manganese ore 1983 2. Papers

CARTWRIGHT, A., and PAUL, R.L. A study of the mechanism of manganese dioxide deposition. MANGANESE DIOXIDE SYMPOSIUM, TOKYO, 1980. Schumm, B. Jnr, Joseph, H.M., and Kozawa, A. (compilers). Cleveland (U.S.A.), I.C. MnO2 Sample Office, 1981. vol. 2. pp. 290-304.

DE VILLIERS. J.P.R. The crystal structure of braunite with reference to its solid-solution behaviour. Am. Mineralogist, vol. 6C. 1975. pp. 1098-1104.

DE VILLIERS, J.P.R. The crystal structure of braunite n and its relation to bixbyite and braunite. Am. Mineralogist, vol. 65. 1980. pp. 756-765.

DE WAAL, S.A. Ramsdellite from the Hotazel Mine, northern Cape Province, South Africa. Econ. Geol., vol. 64, no. 2. 1969. pp. 221-222.

135 MINTEK PUBLICATIONS

KLEYENSTÜBER, A.S.E. A review of the geology and mining of the Kalahari manganese field. PROCEEDINGS, TWELFTH CONGRESS OF THE COUNCIL OF MINING AND METALLURGICAL INSTITUTIONS. Glen, H. W. fed.). Johannesburg, The South African Institute of Mining and Metallurgy, 1982. vol. 1. pp. 213-220.

RUSSELL, B.G. Flame-photometric determination of sodium and potassium in manganese ores. Analyst, Lond., vol. 91, no. 1085. Aug. 1966. pp. 511-519.

• TE RIELE, W.A.M. Electrowinning of manganese dioxide. VACATION SCHOOL: ELECTROMETTALURGY. Johannesburg, The South African Institute of Mining and Metallurgy, 1983. pp. 238-261.

3. Patent

Simultaneous recovery of zinc and manganese. S.Afr. Pat. 80/1590, 28th May, 1979.

B13. Niobium and Tantalum

I. Reports

No. Title Year

459 Determination of tantalum in rocks and minerals by paper-partition chromatography 1969

1010 The leaching, with hydrofluoric acid, of materials containing tantalum and niobium 1970

1154 The extraction and separation of niobium and tantalum by liquid-liquid extraction using

tri-n-butyl phosphate 1970

1178 Further leaching tests, with hydrofluoric acid, on a tantalite concentrate 1970

• 1241 The determination of impurities in niobium and tantalum fluorides 1971

1282 The determination of free hydrofluoric acid in the leach liquors from tantalum-niobium ores 1971 1514 The determination by X-ray-fluorescence spectrometry of minor amounts of niobium and tantalum in geological materials 1973

1611 The X-ray-fluorescence determination of percentage concentrations of niobium and tantalum in ores and minerals 1974

B14. Pegmatite

/. Reports

No. Title Year

21 The use of heavy-medium separation for the recovery of spodumene 1966

96 The mode of occurrence of beryl in grey gneiss along the contact with the Gesie pegmatite 1966

102 Micas of the Noumas pegmatite 1966

142 Micas from the Namaqualand pegmatite area 1966

136 MINTEK PUBLICATIONS

No. Title Year

190 Micas from the Namaqualand pegmatite area 1967

225 Test to recover tantalite-columbite from a bulk sample of tailing from the Noumas pegmatite by pneumatic tabling 1967

233 A chemical and mineralogical study of microlite from Noumas pegmatite [available only on loan from Mintek Library] 1967

258 Exploratory concentration tests by Warren Spring Laboratory on the use of the fluidized- bed concentrator for the recovery of spodumene 1967

262 Preliminary gravity concentration tests for the recovery of scheelite, wolframite, and cassiterite from the tailing dump at Boksputs in the Gordonia district 1967

266 Concentration tests for the recovery of lepidolite from tailing dumps at Helicon and Rubicon Mines by electrostatic separation and flotation 1968

473 Mineralogical examination of tantalite-bearing samples from the Warmbad district, South

West Africa 1968

482 Review of work on the treatment of pegmatites 1969

483 Summary of the mineralogical investigation of pegmatites 1969

494 A preliminary study of beryllium distribution of phyllosilicates from the Etiro pegmatite, Karibib, South West Africa 1966 496 A preliminary study of beryllium distribution in quartzes from the Etiro pegmatite, Karibib, South West Africa 1969

1308 Heavy-medium tests for the treatment of pegmatite ores and dump material in

Namaqualand 1971

1443 Gravity concentration tests on four samples from Tantalite Valley, S.W.A. 1972

1508 The selection of economically mineralized pegmatites according to their border-zone

characteristics 1973

1583 Preliminary tests on winnowing for the recovery of mica 1973

1733 A mineralogical investigation of weathered carbonatite from Salpeterkop 1975

1813 The economic potential of some pegmatites from the Kenhardt area in relation to the

trace-element content of their border zones 1976

1829 An investigation of weathered carbonatite from Salpeterkop 1976

• M42D The recovery of tantalite and cassiterite from a bulk sample of pegmatite 1982

137 MINTEK PUBLICATIONS

B15. Phosphates and Phosphorus Chemicals

/. Reports

No. Title Year

120 Exploratory tests on the recovery of apatite and magnetite from the farm Schiel 1967

302 Mineralogical examination of phosphate in pyroxenite from St. Agnesfontein, north- western Transvaal 1968

9S0 A mineralogical study of eight samples of phosphate ore from Steenkampskraal, Van Rhynsdorp, Cape Province 1970

965 The spectrophotometric determination of phosphate in leach residues and solutions 1970

1028 Exploratory heavy-liquid separation tests on a low-grade apatite concentrate 1970

1204 The flotation of phoscorite ores. Possible correlations between chemical variables in solution and metallurgical performance 1971

2002 The spectrochemical determination of phosphorus, magnesium, and iron in phosphate rocks and sulphuric acid leach liquors 1979

2014 The determination, by spark-source spectrometry, of chlorine and phosphorus in high- purity tungsten oxide 1979

2062 The reduction by computer of phosphate data obtained by spark-source mass spectrometry 1980

2. Papers

• DE VILLIERS, J.P.R., ORMROD, G.T. W., and COLE, A.E. On-stream analysis, by X-ray diffraction, of apatite-containing slurries. ICAM 81. PROCEEDINGS OF THE FIRST INTERNATIONAL CONGRESS ON APPLIED MINERALOGY. De Villiers, J.P.R., and Cawthorn, P.A. (eds.J. Johannesburg, The Geological Society of South Africa, 1983. pp. 435-442.

LOVELL, V.M. Froth characteristics in phosphate flotation. FLOTATION. A.M. GAUDIN MEMORIAL VOLUME. Fuerstenau, M.C. (ed.). New York, American Institute of Mining, Metallurgical and Petroleum Engineers Inc., 1976. vol. 1. pp. 597-621.

B16. Potassium Chemicals

I. Report

No. Title Year

298 The recovery of potassium from phlogopite 1968

B17. Rare Earths

/. Reports

138 MINTEK PUBLICATIONS

No. Title Year

457 The determination of rubidium and caesium in silicate materials by atomic-absorption spectrophotometry 1969

998 The determination of macroscopic amounts of total rare-earth oxides and thorium oxide 1970

1428 The separation and determination of trace and minor amounts of individual rare earths in silicates 1972

1467 The spectral analysis of solutions. I. The analysis of rare-earth minerals 1972

1904 Separation of rare earths from solutions of phosphoric acid 1977

1943 A review of the literature on the separation and determination of rare-earth elements 1978

1956 An improved ion-exchange separation of rare-earth elements for spectrographic analysis 1978

1991 The determination, by atomic-absorption spectrophotometry, of europium in phosphoric acid and in rare-earth oxides 1978 2010D A process for* the recovery of mixed rare-earth oxides from monazite 1979

2. Papers

BRENNER, I.B., WATSON, A.E., STEELE, T.W., JONES, E.A., and GONCALVES, M. Application of an argon-nitrogen inductively coupled radiofrequency plasma (ICP) to the analysis of geological and related materials for their rare earth contents. Spectrochim. Ada, vol. 36B, no. 8. 1981. pp. 785-797.

FESQ, H.W., KABLE, E.J.D., and GURNEY, J.J. Aspects of the geochemistry of kimberlites from the Premier Mine and other selected South African occurrences with particular reference to the rare earth elements. PHYSICS AND CHEMISTRY OF THE EARTH, Ahrens, L.H., Dawson, J.B., Duncan, A.R., and Erlank, A.J. (eds.). Oxford, Pergamon, 1975. vol. 9. pp. 687-707.

B18. Sodium Chemicals

/. Report

No. Title Year

1843 The treatment of Athlone Sewerage-plant effluent by the DESAL process 1976

B19. Tin

/. Reports

No. Title Year

5 The spectrophotometric determination of trace amounts of tin 1966

12 Exploratory tests on the concentration of tin ore from Kuils River, C.P. 1966

40 The spectrophotometric determination of tin in silicate materials 1966

139 M1NTEK PUBLICATIONS

No. Title Year

128 Exploratory concentration test for the recovery of cassiterite from Sandspruit No. 51, Bronkhorstspruit district 1967

• 239 The determination of tin in tungsten ores 1967

350 Concentration of cassiterite from two samples from Enkeldoorn, Bronkhorstspruit

district 1968

1579 The determination of tin in geochemical-survey samples 1973

1589 Preliminary investigations into the flotation of tin dioxide, cassiterite, and some related gangue minerals 1973 1742 The determination of tin in ores, residues, and concentrates by X-ray-fluorescence spectrometry 1975 2054 The determination, by X-ray spectrometry, of trace amounts of tin in titanium-bearing ores and concentrates and in siliceous materials 1980 2071 The determination, by X-ray-fluorescence spectrometry, of tin and tungsten in scheelite and cassitcrite ores and concentrates 1980

• M69 The determination, by X-ray-fluorescence spectrometry, of tin and tungsten in ores, concentrates, and residues of scheelite, wolframite, and cassiterite 1983

2. Papers

AMTHAUER, G., McIVER, J.R., and VILJOEN, E.A. 57Fe and u9Sn Mössbauer studies of natural tin-bearing garnets. Phys. Chem. Miner., vol. 4. 1979. pp. 235-244.

DE WAAL, S.A. The Bushveld granites in the Zaaiplaats area. Trans. Geol. Soc. S.Afr., vol. 75, pt 2. May-Aug. 1972. pp. 135-147.

McIVER, J.R., and MIHALIK, P. Stannian andradite from 'Davib Ost', South West Africa. Can. Mineralogist, vol. 13, no. 3. Aug. 1975. pp. 217-221. B20. Tungsten

1. Reports

No. Title Year

1710 The recovery of scheelite from Shongona, north-western Transvaal 1975

1817 The rapid determination by X-ray-fluorescence spectrometry of tungsten in tungsten ores and concentrates 1976

1875 The determination of tungsten and iron in ferrotungsten alloys by X-ray-fluorescence spectrometry 1977

2014 The determination, by spark-source spectrometry, of chlorine and phosphorus in high- purity tungsten oxide 1979

140 MINTEK PUBLICATIONS

No. Title Year

207'1 The determination, by X-ray-fluorescence spectrometry, of tin and tungsten in scheelite and cassiterite ores and concentrates 1980

• M69 The determination, by X-ray-fluorescence spectrometry, of tin and tungsten in ores, concentrates, and residues of scheelite, wolframite, and cassiterite 1983

3. Patent

Recovery for re-use of tungsten from tungsten carbide. S.Afr. Pat. 78/2623, 8th May, 1978.

B21. Zirconium (Non-nuclear)

1. Reports

No. Title Year

1808 Spectrophotometric determination (with pyrocatechol violet as chromogenic agent) of aluminium in zirconium metals and in the residues from anode sludges 1976 1861 The determination of some impurities in zirconium metal by instrumental neutron- activation analysis 1976

C1. Analytical Techniques

C1.1. Neutron Activation

/. Reports

No. Title Year

41 Table of the isomeric states of stable nuclides 1966

80 The resolution of photopeaks obtained from the products of stable nuclides irradiated

by neutrons 1966

152 The determination of beryllium by irradiation with gamma rays 1967

177 Compensating for flux variation in neutron-activation analysis 1967

236 The determination of some of the major constituents of ores and minerals by fast-neutron

activation analysis 1967

445 The use of californium-252 fission neutron sources 1969

474 The LAEA Conference on the Use of Nuclear Techniques in the Prospecting and

Development of Mineral Resources 1969

530 The measurement of 14MeV neutron fluxes from a neutron generator 1969

889 The simultaneous determination, by instrumental thermal-neutron activation analysis, of some selected trace elements likely to be present in lunar material 1969 891 Calibration of the 'Universal Voltronics' power supply for the neutron generator manufactured by Accelerators Incorporated 1969

141 MINTEK PUBLICATIONS

No. Title Year

967 Automatic timing of the neutron-generator counting station 1970

987 Rhythmic-activation analysis 1970

1005 Modifications to the Intertechnique 4000-channel analyser 1970

1013 The instrumental neutron-activation analysis of samples taken at different levels of the

E.R.P.M. Mine 1970

1476 A magnetic-tape-oriented system for data reduction in neutron-activation analysis 1972

1563 Neutron-activation analysis of samples from the Kimberley Reef conglomerate 1973

1636 Trace elements in diamonds from the Premier, Finsch, and Jagersfontein Mines, and their petrogenetic significance 1975 1638 The determination of trace elements in natural diamonds by instrumental neutron- activation analysis 1975 1639 The determination, by 14MeV neutron-activation analysis, of small amounts of oxygen and silicon in diamonds 1974

1652 The identification of diamonds from Premier, Finsch, and Jagersfontein Mines, by statistical analysis of data obtained from instrumental neutron-activation analysis 1975

1670 Neutron-activation analysis of routine mineral-processing samples 1974

1703 The geochemistry of some selected South African kimberlites and associated heavy minerals 1976 1873 The rapid reduction of gamma-ray spectra with a desk-top calculator 1977

1874 Activation analysis and classification to source of samples from the Kimberley Reef conglomerates 1977

1917 The instrumental neutron-activation analysis of granites from the Bushveld Complex 1978

1928 A liquid-nitrogen monitor for lithium-drifted germanium detectors 1977

2015 The preparation of synthetic standards for instrumental neutron-activation analysis 1979

2052 An investigation of the impurities in native gold by neutron-activation analysis 1980

2069 Automatic setting of the distance between sample and detector in gamma-ray

spectroscopy 1980

2085 A large-capacity sample changer for automated gamma-ray spectroscopy 1980

• M52 A high-speed, multi-input serial-interfacing system with simultaneous back-up recording on magnetic tape 1983 • M53 The development of an automatic sample-changer and control instumentation for isotope- source neutron-activation analysis 1983

142 MINTEK PUBLICATIONS

2. Papers

ANDEWEG, A.H. A large capacity sample changer for fully automated gamma ray spectroscopy. IEEE Trans. Nucl. ScL, vol. NS-27, no. 1. Feb. 1980. pp. 728-732.

BIBBY, D.M., and RASMUSSEN, S.E. Reactor neutron flux monitoring with iron foils. Radiochem. Radioanalyt. Lett., vol. 9, no. 1. 1972. pp. 1-8.

BIBBY, D.M., and RASMUSSEN, S.E. Performance of a counting head for an automatic sample changer. Radiochem. Radioanalyt. Lett., vol. 14, no. 1. 1973. pp. 9-15.

BIBBY, D.M., and SELLSCHOP, J.P.F. The determination of oxygen and silicon in diamonds by 14MeV activation analysis. J. Radioanalyt. Chem., vol. 22. 1974. pp. 103-111.

EDDY, B.T., WATTERSON, J.I.W., and ERASMUS, C.S. Preparation of synthetic standards for use in instrumental neutron activation analysis. Geostand. NewsL, vol. 4, no. 2. Oct. 1980. pp. 229-237.

ERASMUS, C.S., FESQ, H.W., KABLE, E.J.D., RASMUSSEN, S.E., and SELLSCHOP, J.P.F. The NIMROC samples as reference materials for neutron activation analysis. J. Radioanalyt. Chem., vol. 39. 1977. pp. 323-334.

ERASMUS, C.S., SARGEANT, J., SELLSCHOP, J.P.F., and WATTERSON, J.I.W. Multielement analysis of air and water pollutants in gold mines by thermal and epithermal neutron activation. METHODS AND STANDARDS FOR ENVIRONMENTAL MEASUREMENT, PROCEEDINGS OF THE8THIMR SYMPOSIUM. Kirchoff, W.H. fed). Washington, National Bureau of Standards, spec, pub. 464. pp. 129-136.

ERASMUS, C.S., SELLSCHOP, J.P.F., BIBBY, D.M., FESQ, H.W., KABLE, E.J.D., KEDDY, R.J., HAWKINS, D.M., MINGAY, D.W., RASMUSSEN, S.E., RENAN, M.J., and WATTERSON, J.I.W. Natural diamonds — major, minor and trace impurities in relation to source and physical properties. J. Radioanalyt. Chem., vol. 38. 1977. pp. 133-146.

FESQ, H.W., BIBBY, D.M., SELLSCHOP, J.P.F., and WATTERSON, J.I.W. The determination of trace-element impurities in natural diamonds by instrumental neutron-activation analysis. J. Radioanalyt. Chem., vol. 17. 1973. pp. 195-216.

GURNEY, J.J., FESQ, H.W., and KABLE, E.J.D. Clinopyroxene-ilmenite xenolites from kimberlites. LESOTHO KIMBERLITES. Nixon, P.H. (ed.J. Maseru, Lesotho National Development Corporation, 1973. pp. 238-254.

HAWKINS, D.M., and RASMUSSEN, S.E. Use of discriminant analysis for the classification of strata in sedimentary successions. Math. GeoL, vol. 5, no. 2. 1972. pp. 163-177.

KABLE, E.J.D., FESQ, H.W., and GURNEY, J.J. The significance of interelement relationships of some elements in South African kimberlites. PHYSICS AND CHEMISTRY OF THE EARTH. Ahrens, L.H., Dawson, J.B., Duncan, A.R., andErlank, A.J. (eds.). Oxford, Pergamon, 1975. vol. 9, pp. 709-734.

KNIGHT, A. Neutron activation analysis. S.Afr. Engr, vol. 58, no. 585. Feb. 1967. pp. 37, 39, 41.

RASMUSSEN, S.E., SELLSCHOP, J.P.F., FESQ, H.W., and HAWKINS, D.M. Characterization of sedimentary strata using trace element patterns. PROCEEDINGS TWELFTH INTERNA TIONAL SYMPOSIUM ON THE APPLICATION OF COMPUTERS AND MATHEMATICS IN THE MINERALS INDUSTR Y. Johnson, T.B., and Gentry, D. W. (eds.). Golden, Colorado School of Mines, 1974. pp. D41-D56.

143 MINTEK PUBLICATIONS

SELLSCHOP, J.P.F., BIBBY, D.M., ERASMUS, C.S., and MINGAY, D.W. Determination of impurities in diamond by nuclear methods. DIAMOND RESEARCH 1974. London, Industrial Diamond Information Bureau, 1974. pp. 43-50.

UKEN, E-A. Neutron-activation analysis. Miner. Sci. Engng, vol. 2, no. 2. Apr. 1970. pp. 24-34.

WATTERSON, J.I.W. Optimization of irradiation and decay times in nuclear activation analysis. J. Radioanalyt. Chem., vol. 26. 1975. pp. 135-150.

WATTERSON, J.I.W., ANDEWEG, A.H., and RAMAHLO, J. Isotope source neutron activation for the accurate analysis of kilogram samples of ores and rocks. J. Radioanalyt. Chem., vol. 71, no. 1-2. 1982. pp. 365-375.

WATTERSON, J.I. W., and HAWKINS, D.M. Multivariate techniques for the classification of granites. PROCEEDINGS TWELFTH INTERNATIONAL SYMPOSIUM ON THE APPLICATION OF COMPUTERS AND MA THEMA TICS IN THE MINERALS INDUSTR Y. Johnson, T.B., and Gentry, D. W. feds.). Colorado, Colorado School of Mines, 1974. pp. D57-D76.

WATTERSON, J.I.W., MALKIN, J.T., MNGADI, J.T., RAMJEE, B., and SELLSCHOP, J.P.F. A computer-based system for absolute neutron activation analysis. COMPUTERS IN ACTIVATION ANALYSIS AND GAMMA-RAY SPECTROSCOPY. Carpenter, B.S., D'Agostino. M.D., and Yule, H.P. (eds.). Springfield (U.S.A.), National Technical Information Service. 1979. pp. 238-252.

WATTERSON, J.I.W., MNGADI, J.T., and SELLSCHOP, J.P.F. The analysis of microscopic mineral grains by absolute (parametric) neutron activation. J. Radioanalyt. Chem., vol. 71, no. 1-2. 1982. pp. 377-399.

WATTERSON, J.I.W., MNGADI, T.J., and SELLSCHOP, J.P.F. Instrumental neutron-activation analysis of zircons from the Upper Witwatersrand System. ICAM81. PROCEEDINGS OF THE FIRST INTERNATIONAL CONGRESS ON APPLIED MINERALOGY. De Vil/iers, J.P.R., and Cawthorn, P.A. (eds.). Johannesburg, The Geological Society of South Africa, 1983. pp. 419-424.

ZANDERS, J.A.J., BIBBY, D.M., and RASMUSSEN, S.E. A simple automatic sample changer for the gamma-ray counting of reactor-irradiated samples. J. Phys. E: Scient. Instrum., vol. 6. 1973. pp. 973-975.

5. Special Publication

• 4 A manual of analytical methods used at Mintek. 1983. 315 pp.

C1. Analytical Techniques

C1.2. Techniques for the Determination of Elements That Are Not Classified Separately

1. Reports

No. Title Year

138 The determination of beryllium by atomic-absorption spectrophotometry 1967

173 The determination of beryllium by atomic-absorption spectrophotometry 1967

193 An investigation into the use of platinum ware for silicate analysis 1967

200 The spectrochemical analysis of silicate material by a plasma-jet source 1967

144 MINTEK PUBLICATIONS

No. Title Year

358 The determination of mercury at concentrations of parts per thousand million in geological samples 1968

486 Determination of strontium in ores by atomic-absorption and emission spectrophotometry 1969

499 The determination of molybdenum by atomic-absorption spectrophotometry 1969

524 The determination of minor amounts of molybdenum in soil samples 1969

537 Flame-photometric determination of lithium with the Techtron AA4 spectrophotometer 1969

1427 The pressed-fused disc — a technique for the preparation of ore samples to be analysed by X-ray fluorescence 1972 1503 Fast-neutron-activation analysis for the determination of oxygen in rock samples 1973

1571 The commissioning of a direct-reading spectrometer for the analysis of silicate rocks by the use of the graphite-pellet technique 1973

1599 The analysis of silicate rocks and metallurgical slags by X-ray-fluorescence spectrometry 1974

1656 The analysis of geological samples for trace elements by direct-reading emission spectrometry 1974 1834 The analysis of slag and silicate samples with a fully automatic sequential X-ray spectrometer 1976

2084 The analysis, by a fusion procedure and X-ray-fluorescence spectrometry, of silicates and slags 1980

• M67 The determination of total cyanide in solutions containing uranium and gold 1983

• M121 The determination of trace elements in coal by atomic-absorption spectroscopy 1983

2. Papers

BRENNER, I.B., WATSON, A.E., RUSSELL, G.M., and GONCALVES, G. A new approach to the determination of the major and minor constituents in silicate and phosphate rocks. Chem. Geol., vol. 28. 1980. pp. 321-330.

• JONES, E.A. Spectrophotometric determination of sulphate in sodium hydroxide solutions by flow- injection analysis. Analyt. Chim. Ada, no. 156. 1984. pp. 313-317.

RUSSELL, B.G., SPANGENBERG, J.D., and STEELE, T. W. An investigation into the use of platinum ware for silicate analysis. Talanta, vol. 16, no. 4. 1969. pp. 487-496.

C1. Analytical Techniques

C1.3. Techniques Not Included Elsewhere

/. Reports

145 MINTEK PUBLICATIONS

No. Title Year

158 Aerosol formation with a high-speed spinning surface 1967

264 A new detector unit for the Techtron model AA3 atomic-absorption spectrophotometer 1967

439 The determination of free acid in the presence of hydrolysable cations 1968

465 The determination of aminoid nitrogen in organic compounds by the Kjeldahl method 1969

502 The volumetric determination of chloride and bromide using mercurous perchlorate 1969

1049 Exchange visit to the Institut fur Spektrochemie und Angewandte Spektroskopie in

Dortmund, West Germany 1970

1106 Computerization of atomic-absorption data with the Olivetti Programma 101 1970

1163 The computer programming of atomic-absorption measurements on the Olivetti

Programma 101 1970

1172 A visit to Outokumpu Oy Research Laboratory in Finland 1970

1257 Aspects of the Seventh X-ray Analytical Conference, Durham, September 1970 1971

1305 The determination of total sulphur in the dust from nylon thread 1971

1556 The spectral analysis of solutions. 2. The analysis of leach liquors, concentrates, slags, and residues 1973 1581 The computer calculation, from fundamental parameters, of influence coefficients for X-ray spectrometry 1974 1592 The determination of line intensities in the presence of interfering spectra in dispersive X-ray-fluorescence spectrometry 1974

1607 The analysis of ion-exchange resins by X-ray fluorescence 1974

1621 Correction of matrix effects in the analysis of solutions by X-ray-fluorescence spectrometry 1974 1784 A single-standard calibration method for use in analysis by X-ray-fluorescence spectrometry 1976

1788 A computer programme for emission-spectrographic calculations 1976

1825 The full automation of a Philips 1220 X-ray spectrometer 1976

1873 The rapid reduction of gamma-ray spectra with a desk-top calculator 1977

1907 The application of the induction-coupled plasma system to spectral analysis 1977

1933 The determination of trace-elements by thin-film X-ray-fluorescence spectrometry, and its application to zirconium 1977 1936 The analysis of mineralogical and metallurgical materials. A guide to the analytical techniques and instrumentation available at the National Institute for Metallurgy 1978

1984 The commissioning of the AEI MS702 mass spectrometer 1978

146 M1NTEK PUBLICATIONS

No. Title Year

1992 The use of optical emission spectrometry for the determination of impurities in metals 1978

2006 An examination of procedures for the analysis of powders by atomic-absorption spectrophotometry 1979

2023 Atomic-absorption spectrophotometry with hydride generation: an improved technique 1979

2029 The commissioning of a 5 kW inductively coupled plasma unit for use with a 3,4 m Ebert spectrograph 1979 2039 The determination of free acid in the presence of hydrolysable cations 1980

2040 A solid-state constant-current power unit for the magnetic analyser of the MS792R mass spectrometer 1980

2044 The separation and determination of anions by ion chromatography 1980

2053 A study of the measurement, by electrothermal atomization and atomic-absorption spectrophotometry, of hydride-forming elements 1980

2060 The analysis, by atomic-absorption spectrophotometry, of activated charcoal 1980

2062 The reduction by computer of phosphate data obtained by spark-source mass spectrometry 1980

2075 The optimization of some of the conditions for analysis by spark-source mass spectrometry 1980

2107 The separation of some weak-acid anions by ion-exclusion chromatography 1981

2116 Optimum operation of a direct-reading spectrometer with excitation by a 5 k W inductively coupled plasma torch 1981

2117 Disc storage of the data obtained from photographic plates in spark-source mass spectrometry 1981

2132 The assessment of pellicular anion-exchange resins for the determination of anions by ion chromatography 1981

M24 Atomic-absorption programmes for the Hewlett Packard H.P. 975 programmable calculator 1982

M44 An on-line dilution system for spectrometry using an inductively coupled plasma source 1982

M49 A programme in BASIC for the appending of computer files 1982

M55 A new robust method for the treatment of analytical data 1982

M61 An atomic-absorption programme for the Apple II Plus computer 1982

• M80 The installation and commissioning of the Siemens SRS200 sequential X-ray-fluorescence spectrometer 1983 • M90 The automation of fusions with sodium peroxide in zirconium crucibles 1983

147 M1NTEK PUBLICATIONS

• M95 Modern applications of polarography and voltammetry to inorganic analysis 1983

• Ml 19 A versatile computer programme for data capture in multi-dement analysis by a sequential X-ray spectrometer 1983

• M125 Commissioning of the microphotometer used in spark-source mass specirometry 1983

2. Papers

AUSTEN, C.E., and STEELE, T.W. The computer calculation, from fundamental parameters, of influence coefficients for X-ray spectrometry. ADVANCES IN X-RAY ANALYSIS. Pickles, W.L., Barrett, S.C., Newkirk, J.B., and Rund, CO. feds.). London, Plenum Press, 1975. vol. 18. pp. 362-371.

ELLIS, P.J. The theoretical grain index, an index for use in the assessment of analyte segregation in powdered material. Powder Techno!., vol. 30, no. 2. Nov./Dec. 1981. pp. 225-236.

FRITZ, J.S., GJERDE, D.T., and POHLANDT, C. Ion chromatography. New York, Hiithig, 1982. 213 pp.

MOORE, G.L. Some candle! CHEMSA, vol. 8, no. 7. Jul. 1982. pp. 80-81.

MOORE, G.L., WATSON, A.E., and HUMPHRIES-CUFF, P. An on-line dilution system for ICP spectrometry. Spectrochim. Ada, vol. 37B, no. 9. 1982. p. 835.

POHLANDT, C. Determination of anions by ion chromatography. S.Afr. J. Chem., vol. 33, no. 3. 1980. pp. 87-91.

POHLANDT, C. Separation of some weak-acid anions by ion-exclusion chromatography. S.Afr. J. Chem., vol. 35, no. 3. 1982. pp. 96-100.

POHLANDT, C, and FRITZ, J.S. Extraction of metal ions from chloride solution with N,N- dioctylacetamide. Talanta, vol. 26. 1979. pp. 395-399.

POHLANDT, C, and FRITZ, J.S. Separation of metal ions on a new amide resin. J. Chromat., no. 176. 1979. pp. 189-197.

• SELLSCHOP, J.P.F., MADIBA, C.C.P., ANNEGARN, H.J., and ANDEWEG, A.H. Positron analysis as a quantitative technique in ion beam analysis. PROCEEDINGS OF THE SIXTH INTERNATIONAL CONFERENCE ON ION BEAM ANALYSIS. Siegbahn, K. fed.). Amsterdam, North-Holland, 1983. p. 836. Also in: Nucl. Instrum. MethodsPhys. Res., vol. 218, nos. 1-3. 15th Dec, 1983. pp. 23-28.

STEELE, T.W., and GUERIN, B.D. A new graphite rod for flameless atomic-absorption spectroscopy. Analyst, vol. 97, no. 1150. Jan. 1972. p. 77.

• WATSON, A.E. From Noah to know-how. Nucl. Active, no. 30. 1984. pp. 31-36.

4. Special Publications

2 Handbook of interference effects encountered in atomic-absorption spectrophotometry at the National Institute for Metallurgy. 1978. 137 pp.

• 4 A manual of analytical methods used at Mintek. 1983. 315 pp.

148 MINTEK PUBLICATIONS

C2. Comminution and Classification

/. Repons

No. Title Year

232 A comparison of open-circuit and closed-circuit grinding for the control of slime

formation 1967

416 Comminution kinetics: batch tests in small mills, and model development 1968

2113 Multivariable control of a milling circuit at East Driefontein Gold Mine 1981 M6 A comparative study of the effects of changes in liner patterns and mill speeds on rod- mill parameters 1982

2. Papers

BARKER, I.J., and KING, R.P. A real-time recursive filter applied to a milling circuit to estimate particle-size distributions. AUTOMATION IN MINING, MINERAL AND METAL PROCESSING. Lancaster, F.H. (ed.). Pretoria, South African Council for Automation and Computation, 1977. pp. 263-275.

BRAAE, M., GRAY, G.T., HULBERT, D.G., and WALSH, H.P. A microprocessor-based multivariable controller. PROCEEDINGS, TWELFTH CONGRESS OF THE COUNCIL OF MINING AND METALLURGICAL INSTITUTIONS. Glen, H.W. (ed.). Johannesburg, The South African Institute of Mining and Metallurgy, 1982. vol. 2. pp. 827-831.

GOSSMAN, G.I., HULBERT, D.G., KOUDSTAAL, J., BRAAE, M., and BUNCOMBE, A. The application of computer control to a gold-milling circuit at East Driefontein Gold Mine. PROCEEDINGS, TWELFTH CONGRESS OF THE COUNCIL OF MINING AND METALLURGICAL INSTITUTIONS. Glen, H. W. (ed.). Johannesburg, The South African Institute of Mining and Metallurgy, 1982. vol. 2. pp. 817-825.

GUEST, R.N. A laboratory investigation of the importance of the circulating load in the control of particle-size distribution. J. S.Afr. Mech. Engr, vol. 22, no. 2. Feb. 1972. pp. 46-51.

HOYER, D.I., and DAWSON, M.F. Some results of laboratory experiments on batch centrifugal ball milling. J. S.Afr. Inst. Min. Metall., vol. 82, no. 5. May 1982. pp. 125-133.

• HULBERT, D.G., and WOODBURN, E.T. Multivariable control of a wet-grinding circuit. AIChE J., vol. 29, no. 2. pp. 186-191.

KING, R.P. An analytical solution to ihe batch-comminution equation. J. S.Afr. Inst. Min. Metall., vol. 73, no. 4. Nov. 1972. pp. 127-131.

LIN, I. J., NADIV, S., and GRODZIAN, D. J.M. Changes in the state of solids and mechano-chemical reactions in prolonged comminution processes. Miner. Sci. Engng, vol. 7, no. 4. Oct. 1975. pp. 314-336.

LOVEDAY, B.K. An analysis of comminution kinetics in terms of size-distribution parameters. J. S.Afr. Inst. Min. Metall., vol. 68, no. 3. Oct. 1967. pp. 111-131.

LOVEDAY, B.K. Pilot-plant testing and scale-up of autogenous milling. GRINDING — THEORY AND PRACTICE. Johannesburg, The South African Institute of Mining and Metallurgy, Vacation School 8th-12th Aug., 1977. pp. 88-97.

149 MINTEK PUBLICATIONS

LOVEDAY, B.K. Control of milling circuit — definition of aims. GRINDING — THEORY AND PRACTICE. Johannesburg, The South African Institute of Mining and Metallurgy, Vacation School 8th-12th Aug., 1977. pp. 111-112.

LOVEDAY, B.K., and TOLMAY, A.T. The development of a mathematical model for large-scale mills. CHEMECA 70. Australian Institute of Chemical Engineers. Sydney, the Institute, 1972. pp. 141-151.

MOYS, M.H., and LOVEDAY, B.K. Autogenous-milling research at the South African National Institute for Metallurgy. PROCEEDINGS OF THE AUTOGENOUS GRINDING SEMINAR. Digne, M. fed.). Trondheim (Norway), Jan. 1980. pp. F2M-17.

STANLEY, G.G. Mechanisms in the autogenous mill and their mathematical representation. J. S.Afr. Inst. Min. Metall., vol. 75, no. 4. Nov. 1974. pp. 77-98.

STANLEY, G.G. Considerations in the application of autogenous milling. J. S.Afr. Inst. Min. Metall., vol. 76, spec, issue. Oct. 1975. pp. 52-55.

C3. Electrochemistry

1. Reports

No. Title Year

1693 Research at the National Institute for Metallurgy on the engineering aspects of copper electrowinning 1975 1754 A new three-dimensional anodic electrode for reduced power consumption during the electrowinning of metals 1975

1778 An apparatus for the automatic measurement of current efficiencies during the electrodeposition of nickel in chloride media 1976

1782 The application of air-sparging techniques to industrial electrodeposition of zinc from acidic zinc sulphate solutions 1976

1796 The mechanism of the electrodeposition and dissolution of nickel from chloride media 1976

1799 An electrochemical investigation of copper cementation on iron 1976 1800 An electrochemical investigation of the dissolution and passivation of platinum in acid solutions 1976

1804 The electrodeposition of nickel from ammoniacal solutions 1976

1844 An electrochemical and kinetic investigation of the behaviour of gold in chloride solutions. II. The anodic dissolution of gold 1976

1846 An electrochemical and kinetic investigation of the behaviour of gold in chloride solutions. III. The gold(Hl)/gold(i) reaction on platinum and the disproportionation of gold(l) 1976

1848 An electrochemical and kinetic investigation of the behaviour of gold in chloride solutions. I. The cathodic dissolution of gold 1976

1858 The kinetics and mechanism of the non-oxidative dissolution of some iron sulphides in aqueous acidic solutions 1976

150 MINTEK PUBLICATIONS

No. Title Year

1859 Increased current efficiency during electrodeposition of manganese from sulphate electrolytes 1976

1880 The electrochemical reduction of silver chloride and its application to the refining of silver 1977

1906 An automated instrument for measuring the effects of impurities on cathodic-current efficiency during the electrowinning of zinc 1977

1979 An electrochemical and kinetic investigation of the behaviour of gold in chloride solutr yns. IV. Results obtained from Phase 2 of the investigation 1978

2100 The anodic polarization of copper, tin, and copper-tin alloys in fluosilicate solutions 1981

2. Papers

• CARTWRIGHT, A. Fundamental aspects of electrocrystallization. VACATION SCHOOL: ELECTROMETALLURGY. Johannesburg, The South African Institute of Mining and Metallurgy, 1983. pp. 55-84.

• CUNLIFF, J. de B. Practical considerations in the electrowinning and electrorefining of metals. VACATION SCHOOL: ELECTROMETALLURGY. Johannesburg, The South African Institute of Mining and Metallurgy, 1983. pp. 123-149.

NICOL, M. J. The new electrochemistry and its part in a new technology. Probe 71-2. 1972. pp. 23-26.

NICOL, M. J. Mechanism of aqueous reduction of chalcopyrite by copper, iron and lead. Trans. Instn Min. Metall., vol. 84. 1975. pp. C206-C209.

• NICOL, M.J. An introduction to the basic concepts of electrochemistry. LECTURE/NOTES: SCHOOL OF PURE AND APPLIED ELECTROCHEMISTRY. Randburg, Council for Mineral Technology, 1979. pp. 1-23.

• NICOL, M.J. Application of electrochemical principles to problems in the metallurgical industry. LECTURE/NOTES: SCHOOL OF PURE AND APPLIED ELECTROCHEMISTRY. Randburg, Council for Mineral Technology, 1979. pp. 1-27.

NICOL, M.J. Anodic behaviour of gold. Part I — in acidic solutions. Gold Bull., vol. 13, no. 2. Apr. 1980. pp. 46-55.

NICOL, M.J. Anodic behaviour of gold. Part II — in alkaline solutions. Gold Bull., vol. 13, no. 3. Jul. 1980. pp. 105-111.

• NICOL, M.J. Overview of electrometallurgy. VACATION SCHOOL: ELECTROMETALLURGY. Johannesburg. The South African Institute of Mining and Metallurgy, 1983. pp. 4-10.

• NICOL, M.J. Current distribution in electrochemical reactions. VACATION SCHOOL: ELECTROMETALLURGY. Johannesburg, The South African Institute of Mining and Metallurgy, 1983. pp. 98-111.

NICOL, M.J., SCHALCH, E., BALESTRA, P.E.L., and HEGEDUS, H. A modern study of the kinetics and mechanism of the cementation of gold. J. S.Afr. Inst. Min. Metall., vol. 79, no. 7. Feb. 1979. pp. 191-198.

NICOL, M.J., and SCOTT, P.D. The kinetics and mechanism for the non-oxidative dissolution of some iron sulphides in aqueous acidic solutions. J. S.Afr. Inst. Min. Metall., vol. 79, no. 10. May 1979. pp. 298-305.

151 MINTEK PUBLICATIONS

PAUL, R.L. A circuit design for a motor-speed controller of high precision. Electrochim. Ada, vol. 23, no. 10. Oct. 1978. pp. 991-994.

• PAUL, R.L. Some guidelines to the design of an electrochemical experiment. LECTURE/NOTES: SCHOOL OF PURE AND APPLIED ELECTROCHEMISTRY. Randburg, Council for Mineral Technology, 1979. pp. 1-17.

• PAUL, R.L. A quantitative approach to mass transfer in electroanalytical chemistry. LECTURE/NOTES: SCHOOL OF PURE AND APPLIED ELECTROCHEMISTRY. Randburg, Council for Mineral Technology, 1979. pp. 18-33.

• PAUL, R.L. Fundamental aspects of electrode processes. VACATION SCHOOL: ELECTROMETALLURGY. Johannesburg, The South African Institute of Mining and Metallurgy, 1983. pp. 11-54.

PHILIP, H.I., and NICOL, M. J. Underpotential deposition and its relation to the anomalous deposition of metals in alloys. J. Electroanalyt. Chem., vol. 70. 1976. pp. 233-237.

POWER, G.P. An electrochemical method for the recycling of tungsten carbide and other hard metal carbides using a rotating drum anode. Chemistry in Australia, vol. 46, no. 7. 1979. pp. 303-307.

SAUNDERS, A.P., PHILIP. I., and MARTIN, J.P. An automated instrument for the determination of the effects of impurities on the cathodic current efficiency during the electrowinning of zinc. AUTOMATION IN MINING, MINERAL AND METAL PROCESSING. Lancaster, F.H. (ed.). Pretoria, South African Council for Automation and Computation, 1977. pp. 531-542.

SCHALCH, E., and NICOL, M.J. Electrochemical investigation of copper cementation on iron. Trans. Instn Min. Metall., vol. 87. Mar. 1978. pp. C16-C22.

SCOTT, P.D., and NICOL, M.J. The kinetics and mechanisms of the non-oxidative dissolution of metal sulphides. TRENDS IN ELECTROCHEMISTRY. Bockris, J.O.M., Rand, D.A.J., and Welch, B.J. (eds.). New York, Plenum Press, 1977. pp. 303-316.

VERBAAN, B., and MULLINDER, B. The simultaneous electrowinning, at high current efficiencies, of manganese dioxide and zinc from purified neutral zinc sulphate. Hydrometall., vol. 7. 1981. pp. 339-352.

C4. Flotation and Flocculation

C4.1. Engineering Studies

I. Reports

No. Title Year

996 An improved distributed-parameter model for the kinetics of mineral flotation 1970

1436 A computer programme for the simulation of the performance of a flotation plant. Revised report 1973 1517 Computer-controlled flotation plants in Canada and Finland 1973

1553 Characterization of the flotation properties of fluorspar from small-scale batch and pilot- plant tests 1973

1562 Application of a flotation model to an industrial plant 1973

152 MINTEK PUBLICATIONS

No. Title Year

1567 Estimation of the parameters in the distributed-constant flotation model 1974

1568 A computer programme for the estimation of parameters in flotation 1973

1573 A pilot-plant investigation of a flotation model 1974

1753 Full-scale flotation-plant data for modelling purposes 1975

1847 A pilot-plant investigation of a kinetic model for flotation 1976

2037 The removal of contaminants from recycled water in a mineral-flotation plant 1980

2126 The determination, by microwave techniques, of the interface between the pulp and

the froth 1981

M4 An instrument to detect the position of the froth-pulp interface during flotation 1982

MJ1 The application of split conditioning to the flotation of coarse particles 1982

• M78 An evaluation of the Leeds laboratory-scale flotation cell 1983

2. Papers

ENGELBRECHT, J.A., and WOODBURN, E.T. The effects of froth height, aeration rate, and gas precipitation on flotation. J. S.Afr. Inst. Min. Metall., vol. 76, spec, issue. Oct. 1975. pp. 125-132.

KING, R.P. Flotation research work of the NIM Research Group, and the Department of Chemical Engineering, University of Natal. J. S.Afr. Inst. Min. Metall., vol. 72, no. 9. Apr. 1972. pp. 235-345.

KING, R.P. Model for the design and control of flotation plants. APPLICA TION OF COMPUTER METHODS IN THE MINERAL INDUSTRY. Salamon, M.D.G., and Lancaster, F.H. feds.J. Johannesburg, The South African Institute of Mining and Metallurgy, 1973. pp. 341-350.

KING, R.P. On-line digital computer control of slurry conditioning in mineral flotation. Automatica, vol. 10, no. 1. Jan. 1974. pp. 5-14.

KING, R.P. Simulation of flotation plants. Trans. Soc. Min. EngrsAIME, vol. 258, no. 4. Dec. 1975. pp. 286-293.

KING, R.P. A pilot-plant investigation of a kinetic model for flotation. J. S.Afr. Inst. Min. Metall., vol. 78, no. 12. Jul. 1978. pp. 325-J38.

KING, R.P., HATTON, T.A., and HULBERT, D.G. Bubble loading during flotation. Trans. Instn Min. Metall., Sec. C. vol. 83, no. 811. Jun. 1974. pp. C112-C115.

LOVEDAY, B.K. Analysis of froth flotation kinetics. Trans. Instn Min. Metall., vol. 75, Sec. C. Sep. 1966. pp. 219-225.

LOVEDAY, B.K., and MARCHANT, G.R. Simulation of multicomponent flotation plants. APPLICA TION OF COMPUTER METHODS IN THE MINERAL INDUSTR Y. Salamon, M.D.G., and Lancaster, F.H. (eds.). Johannesburg, The South African Institute of Mining and Metallurgy, 1973. pp. 325-330.

153 MINTEK PUBLICATIONS

WOODBURN, E.T., KING, R.P., BUCHALTER, E.M., and PIPER, S.E. Integrated grinding and flotation control-computational problems in an optimum decision making model. A DECADE OF DIGITAL COMPUTING IN THE MINERAL INDUSTRY. Weiss, A. (ed.). New York, AIME, 1969. pp. 695-728.

WOODBURN, E.T., KING, R.P., and COLBORN, R.P. The effect of particle size distribution on the performance of a phosphate flotation process. Metal/. Trans., vol. 2, no. 11. Nov. 1971. pp. 3163-3174.

C4. Flotation and Flocculation

C4.2 Fundamental Studies

/. Reports

No. Title Year

42 The redox potential of solutions of potassium ethyl xanthate 1966

43 The effect of oxygen on the stability of solutions of potassium ethyl xanthate 1966

45 An apparatus used in the study of interactions between sulphide minerals, sulphydryl reagents and oxygen 1966 300 The mixed-collector system xanthate plus quaternary ammonium halide. A literature survey 1968

312 An investigaton of the influence of alkyl trimethyl ammonium halides on the stability of potassium ethyl xanthate in aqueous solution 1968

340 The detection of the formation of a bulk adduct between potassium ethyl xanthate and dodecyl trimethyl ammonium bromide in aqueous solution 1968

371 A preliminary investigation of cyanide-sulphydryl mixed-ligand complexes of mercuric ion 1968

437 The bathochromic shift of the 381 nm absorption peak in aqueous solutions of potassium ethyl xanthate containing dodecyltrimethyl ammonium bromine 1968

442 'n Ondersoek na die gebruik van die Hallimondbuis vir die kwantitatiewe bestudering van flottasieverskynsels met besondere verwysing na die kondisionering van apatiet en kalsiet 1968

443 The determination of anionic surface-active agents in dilute aqueous solution 1968

449 The determination of cationic surface-active agents in dilute aqueous solution 1968

464 The saturation pressure of nitrogen in determinations of surface areas 1969

498 An infrared investigation of the potassium alkyl xanthate and alkyl trimethyl ammonium bromide mixed-collector system 1969 504 The influence of preadsorbed oleate ions on the adsorption of water vapour by insoluble ionic crystals 1969

527 Quantitative aspects of the interaction between galena, xanthate, and oxygen at a pH value of 10 1969

154 MINTEK PUBLICATIONS

No. Title Year

533 Determination of the stoichiometry and stability constants of mercuryuu-cyanide- xanthate complexes. I. Low-concentration region 1969

870 Determination of the stoichiometry and stability constants of mercurydD-cyanide- xanthate complexes. II. High-concentration region 1970

1026 Small-scale flotation techniques 1970

1114 A study of the products of reaction between galena and aqueous xanthate solutions 1970

1125 Studies of the stability of xanthates and dixanthogen in aqueous solution, and the

chemistry of iron xanthates and cobalt xanthates 1971

1296 A review of reactions in the flotation system galena-xanthate-oxygen 1971

1340 The cadmium-cyanide-xamhate system 1971

1372 The electrical double-layer properties of kimberlite suspensions 1971

1402 A study of mineral-surface properties by the use of gas-adsorption measurements 1972

1403 The coagulation and flocculation of suspensions of kimberlite 1972

1414 The use of a closed recirculation apparatus in the study of the galena-oxygen-xanthate

system 1972

1439 The reaction of sulphide minerals with thiol compounds 1972

1447 A preliminary electrochemical investigation of the galena-xanthate-oxygen system in aqueous solution 1972 1479 Infrared studies c:" the adsorption of oleate species on mineral surfaces, with special reference to fluorite 1972

1490 The adsorption of krypton, nitrogen, and water vapour on sodium oleate 1972

1495 A method for the determination of elemental sulphur on the surface of sulphide minerals 1972

1785 Some thermodynamic aspects of systems relevant to the flotation of sphalerite 1976

1854 The interaction of pyrite, oxygen, and xanthate 1977

1896 The interaction of pyrite, oxygen, and xanthates 1977

1988 The effect of particles on the stability of flotation froths 1978

M29 Interactions between sulphide minerals and metal ions in the activation, deactivation, and depression of mixed-sulphide ores 1982 2. Papers ALLISON, S.A., and FINKELSTEIN, N.P. A study of the products of reaction between galena and aqueous xanthate solutions. Trans. Instn Min. Metall., vol. 80, no. 781. Dec. 1971. pp. C235-C239.

155 MINTEK PUBLICATIONS

ALLISON, S.A., GOOLD, L.A., NICOL, M.J., and GRANVILLE, A. The products of reaction between sulphide minerals and aqueous xanthate solutions, and a correlation of the products with electrode rest potentials. Me tall. Trans., vol. 3, no. 10. Oct. 1972. pp. 2613-2618.

ASHURST, K.G., FINKELSTEIN, N.P., and RICE, N.M. Studies of cyanide-xanthate mixed ligand complexes of mercury(il). J. Chem. Soc. (A), 1970. pp. 2303-2307.

• DIPPENAAR, A. The destabilization of froth by solids. I. The mechanism of film rupture. Int. J. Miner. Process., vol. 9. 1982. pp. 1-14.

• DIPPENAAR, A. The destabilization of froth by solids. II. The rate determining step. Int. J. Miner. Process., vol. 9. 1982. pp. 15-27.

FINKELSTEIN, N.P. Kinetic and thermodynamic aspects of the interaction between potassium ethyl xanthate and oxygen in aqueous solution. Trans. Instn Min. Metali., vol. 76, no. 724. Mar. 1967. pp. C51-C59.

FINKELSTEIN, N.P. The influence of alkyltrimethyl ammonium halides on the stability of potassium ethyl xanthate in aqueous solution. J. Appl. Chem., vol. 19. Mar. 1969. pp. 73-76.

FINKELSTEIN, N.P. Quantitative aspects of the role of oxygen in the interaction between xanthate and galena. Sepn Sci., vol. 5, no. 3. Jun. 1970. pp. 227-256.

FINKELSTEIN, N.P. The rate of decomposition of alkaline xanthate solutions. Colloid Polymer Sci., vol. 255. 1977. pp. 168-169.

FINKELSTEIN, N.P., and ALLISON, S.A. The chemistry of activation, deactivation and depression in the flotation of zinc sulphide: a review. FLOTATION. A.M. GAUDIN MEMORIAL VOLUME. Fuerstenau, M.C. fed.). New York, American Institute of Mining, Metallurgical and Petroleum Engineers Inc., 1976. vol. 1. pp. 313-457.

FINKELSTEIN, N.P., ALLISON, S.A., LOVELL, V.M., and STEWART, B.V. Natural and induced hydrophobicity in sulphide mineral systems. ADVANCES IN INTERFACIAL PHENOMENA OF PARTICULATE/SOLUTION/GAS SYSTEMS; APPLICATION TO FLOTATION RESEARCH. Somasundaran, P., and Grieves, R.B. (eds.). New York, AIChE, Chemical Engineering Progress Symposium Series no. 13, 1975.

FINKELSTEIN, N.P., and LOVELL, V.M. Fundamental studies of the flotation process: the work of the National Institute for Metallurgy. J. S.A/r. Inst. Min. Metall., vol. 72, no. 12. Jul. 1972. pp. 328-341.

FINKELSTEIN, N.P., and POLING, G.W. The role of dithiolates in the flotation of sulphide minerals. Miner. Sci. Engng, vol. 9, no. 4. Oct. 1977. pp. 177-197.

GAUDIN, A.M., and FINKELSTEIN, N.P. Interactions in the system galena-potassium ethyl xanthate- oxygen. Nature, Lond., vol. 207, no. 4995. Jul. 1965. pp. 389-391.

GIESEKKE, E.W. Spectroscopie studies on surface reactions between minerals and reagents in flotation systems. SURFACE SCIENCE AND ITS INDUSTRIAL IMPLICATIONS. Gries, W.H., andCrooke, M. (eds.). Pretoria, CSIR, 1981. pp. 229-236.

• GIESEKKE, E.W. A review of spectroscopie techniques applied to the study of interactions between minerals and reagents in flotation systems. Int. J. Miner. Process., vol. 11. 1983. pp. 19-56.

GRANVILLE, A., FINKELSTEIN, N.P., and ALLISON, S.A. Review of reactions in the flotation system galena-xanthate-oxygen. Trans. Instn Min. MetalL, vol. 81, no. 784. 1972. pp. C1-C30.

156 M1NTEK PUBLICATIONS

HALL, P.G., LOVELL, V.M., and FINKELSTEIN, N.P. Adsorption of water vapour on ionic solids containing preadsorbsd sodium oleate. Pan 1. Calcium fluoride. Trans. Farad. Soc, vol. 66, no. 570, pt 6. Jun. 1970. pp. 1520-1529.

HALL, P.G., LOVELL, V.M., and FINKELSTEIN, N.P. Adsorption of water vapour on ionic solids containing preadsorbed sodium oleate. Part 2. Calcium carbonate. Trans. Farad. Soc., vol. 66, no. 574, pt 10. Oct. 1970. pp. 2629-2635.

HARRIS, P.J. Surface chemistry in the flotation of minerals. SURFACE SCIENCE AND ITS INDUSTRIAL IMPLICATIONS. Gries, W.H., and Crooke, M. (eds.f. Pretoria, CSIR, 1981. pp. 221-228.

HARRIS, F.J., and FINKELSTEIN, N.P. Interactions berween sulphide minerals and xanthates. I. The formation of monothiocarbonate at galena and pyrite surfaces. Int. J. Miner. Proc, vol. 2, no. 1. 1975. pp. 77-100.

HARRIS, P. J., and FINKELSTEIN, N.P. The formation of monothiocarbonates during the reaction between xanthates and sulphide minerals in flotation systems. PROCEEDINGS ELEVENTH MINERAL PROCESSING CONGRESS. Ente Minerario Sardo. Cagliari, Instituto di Arte Mineraria. Special volume, 1975. pp. 35-57.

LOVELL, V.M. The determination of the surface area of minerals by the B.E.T. method: some associated problems. Powder Technol., vol. 12. 1975. pp. 71-76.

LOVELL, V.M. Froth characteristics in phosphate flotation. FLOTATION. A.M. GAUDIN MEMORIAL VOLUME. Fuerstenau, M.C. (ed.). New York, American Institute of Mining, Metallurgical and Petroleum Engineers Inc., 1976. vol. 1. pp. 597-621.

LOVELL, V.M., GOOLD, L.A., and FINKELSTEIN, N.P. Infrared studies of the adsorption of oleate species on calcium fluoride. Int. J. Miner. Process., vol. 1, no. 1. Jan. 1974. pp. 183-192.

LUSHER, J.A. The association of calcium ion with nickeliferous pyrrhotite. Surface ScL, vol. 5. 1966. pp. 252-254.

MACKENZIE, J.M.W. Zeta-poteniial studies in mineral processing: measurement techniques and applications. Miner. Sci. Engng, vol. 3, no. 3. Jul. 1971. pp. 75-43.

POHLANDT, C, COOK, E.B.T., and STEELE, T.W. Determination of small quantities of xanthate. Talanta, vol. 16, no. 8. 1969. pp. 1129-1135.

C5. Hydrometallurgy

C5.1. Fundamental Studies

/. Reports

No. Title Year

1012 The coordination numbers of cyanide complexes of zinc, cadmium, and mercury in aqueous solution 1970 1093 The calculation of the equilibrium distribution of metal-ion complexes in multicomponent aqueous systems 1970

1153 Eo/Eo diagrams. Their use in the estimation of unknown standard reduction potentials, with particular reference to the d10 electronic-configuration ions 1970

157 MINTEK PUBLICATIONS

1582 The construction and testing of a precision calorimeter 1973

1617 An electronic differential precision thermometer 1974

1626 Formation constants of zinc chlorocomplexes in perchlorate medium 1974

1629 The thermodynamics of the formation of complexes of silver with some substituted pyridines 1974 1712 The thermodynamics of the formation of chlorocomplexes of nickel and copper in perchlorate medium 1975

1764 Correlations of the free-energy and enthalpy changes of the dw metal ions Ag\ Hg2+, and Cd2+ with a variety of monodentate ligands 1975

1785 Some thermodynamic aspects of systems relevant to the flotation of sphalerite 1976

1799 An electrochemical investigation of copper cementation on iron 1976

1820 The thermodynamics of the formation of chlorocomplexes of iron(iii), cobalt(JJ), iron(ii),

man; anese(ii), and copper(li) in perchlorate medium 1976

1822 Stab .ity constants and linear free-energy relations for the platinum-group metals 1976

1828 7-picoline adducts of the nickel, copper, and zinc chelates of 2-thenoyItrifluoroacetone 1976

1839 A valence-bond study of dialkalis and alkali hydrides 1977

1889 Entropy relations in the formation of complexes of silvern), mercury(il), and cadmium(ll) with monodentate ligands 1977 1914 The thermodynamics of the formation of sulphate complexes of iron(Hi), cobalt(ii), manganese(ii), and copper(ii) in perchlorate medium 1977 1949 The kinetics of the leaching of zinc sulphide concentrates in acidic solutions containing ferric sulphate 1978

1951 Potentialities and limitations of four-parameter equations for the correlation of formation constants of metal-ion complexes in aqueous solution 1978

2038 Leaching of sphalerite in acidic ferric sulphate media in the absence of elemental oxygen 1980

2. Papers

ASHURST, K.G., FINKELSTEIN, N.P., and GOOLD, L.A. The coordination number of cyanide complexes of zinc, cadmium, and mercury in aqueous solution. J. Chem. Soc. (A), 1071. pp. 1899-1902.

ASHURST, K.G., and HANCOCK, R.D. Characterization of inner- and outer-sphere complexes by thermodynamics and absorption spectra. Part 1. Sulphato-complexes of the first-row transition elements. J. Chem. Soc, Dalton Trans., 1977. pp. 1701-1707.

ASHURST, K.G., and HANCOCK, R.D. The characterization of inner- and outer-sphere complexes by thermodynamics and absorption spectra. Part 2. Chloro-complexes of copper. J. Chem. Soc., Dalton Trans., 1981. pp. 245-250.

BOEYENS, J.C.A. Electrostatic calculation of bond energy. J. S.Afr. Chem. Inst., vol. 26, no. 3. 1973. pp. 94-105.

158 MINTEK PUBLICATIONS

BOEYENS, J.C.A., McDOUGALL, G. J., and SMIT, J.V.R. Crystallographic study of the ammonium- potassium 12-molybdophosphate ion-exchange system. J. Solid State Chem., vol. 18.1976. pp. 191-199.

DE VILLIERS, J.P.R., and BOEYENS, J.C.A. Crystal structure of a calcium sulphate-urea complex. J. Cryst. Mol. Struct., vol. 5. 1975. pp. 215-226.

ERASMUS, C.S., and BOEYENS, J.C.A. Crystal structure of the praseodymium /3-diketonate of 2,2,6,6-tetramethyl-3,5-heptanedione, Pr2(thd)6. Ada Crystallographica, vol. B26, pt 11. Nov. 1970. pp. 1843-1854.

ERASMUS, C.S., and BOEYENS, J.C.A. Crystal and molecular structure of tris (2,2,6,6-tetramethyI-3,5-heptanedionate) aquodysprosium(iii), Dy(thd)3H2O. J. Cryst. Mol. Struct., vol. 1. 1971. pp. 83-91.

FILMER, A.O. The non-oxidative dissolution of nickel mattes in aqueous acidic solutions. J. S.A/r. Inst. Min. Metall., vol. 81, no. 3. Mar. 1981. pp. 74-84.

FILMER, A.O., and BALESTRA, P.E.L. The non-oxidative dissolution of nickel concentrate in aqueous acidic solutions. J. S.Afr. Inst. Min. Metall., vol. 81, no. 1. Jan. 1981. pp. 26-32.

FILMER, A.O., and NICOL, M.J. The non-oxidative dissolution of nickel sulphides in aqueous acidic solutions. J. S.Afr. Inst. Min. Metall., vol. 80, no. 12. Dec. 1980. pp. 415-424.

FLEMING, C.A., GREEN, B.R., and ASHURST, K.G. The origin of the selectivity of oxines and oximes for copper(ll) over iron(lll). PROCEEDINGS INTERNATIONAL SOLVENT EXTRACTION CONFERENCE, ISEC 80. Association des Ingénieurs (eds.J. Liége, Université de Liége, 1980. vol. 2, p. 224.

FLEMING, C.A., and NICOL, M.J. The kinetics and mechanism of solvent extraction of Fe(iii) and Cu(ii) by oxine reagents. I. The aqueous-phase reaction between Fe(iii) and 8-hydroxy quinoline. J. Inorg. Nucl. Chem., vol. 42. 1980. pp. 1327-1334.

FLEMING, C.A., and NICOL, M.J. The kinetics and mechanism of solvent extraction of Fe(ill) and Cu(ii) by oxine reagents. II. The extraction of Fe(lll) into a toluene solution of 8-hydroxyquinoline. J. Inorg. Nucl. Chem., vol. 42. 1980. pp. 1335-1339.

GREEN, B.R., and HANCOCK, R.D. Recent advances in the development of resins for use in hydrometallurgy. PROCEEDINGS HYDROMETALLURGY81. London, Society of Chemical Industry, 1981. pp. E6/1-E6/13.

GREEN, B.R., and HANCOCK, R.D. The role of matrix effects on selectivity in ion-exchange resins. Hydrometall., vol. 6. 1981. pp. 353-363.

HANCOCK, R.D. Formation constants of silver(i)-ammonia complexes, and of the ammonium ion, at high free-ammonia concentrations. S.Afr. J. Chem., vol. 32, no. 2. 1979. pp. 49-51.

HANCOCK, R.D. Polar and steric effects on the stability of complexes of primary amines. J. Chem. Soc, Dalton Trans., no. 3. 1980. pp. 316-418.

HANCOCK, R.D., and EVERS, A. Formation constant of Pd(CH)^". Inorg. Chem., vol. 15. 1976. pp. 995-996.

HANCOCK, R.D., and FINKELSTEIN, N.P. 7T and ff-bonding in the stabilities of d10 metal-ion complexes in aqueous solution. Inorg. Nucl. Chem. Lett., vol. 7. 1971. pp. 477-484.

HANCOCK, R.D., FINKELSTEIN, N.P., and EVERS, A. Stabilities of the cyanide complexes of the monovalent group IB metal ions in aqueous solution. J. Inorg. Nucl. Chem., vol. 34. 1972. pp. 3474-3751.

159 MINTEK PUBLICATIONS

HANCOCK, R.D., FINKELSTEIN, N.P., and EVERS, A. Ligand-field theory and metal-ligand force constants. Inorg. Nucl. Chem. Lett., vol. 35. 1973. pp. 2558-2561.

HANCOCK, R.D., FINKELSTEIN, N.P., and EVERS, A. Linear free energy relationship in aqueous complex-formation reactions of the d10 metal ions. J. Inorg. Nucl. Chem., vol. 36. 1974. pp. 2539-2543.

HANCOCK, R.D., FINKELSTEIN, N.P., and EVERS, A. Some observations on a recent determination of the stability of the dicyanocuprated) ion. J. Inorg. Nucl. Chem., vol. 38. 1976. pp. 343-344.

HANCOCK, R.D., JACKSON, G., and EVERS, A. The affinity of lanthanoid(iU) ions for nitrogen- donor ligands in aqueous solution. J. Chem. Soc, Dalton Trans., pt 9. Sep. 1979. pp. 1384-1387.

HANCOCK, R.D., and MARSICANO, F. The chelate effect: a simple quantitative approach. J. Chem. Soc, Dalton Trans., no. 12. 1976. pp. 1096-1098.

HANCOCK, R.D., and MARSICANO, F. The linear free-energy relation in the thermodynamics of complex formation. Part 1. Correlations involving enthalpy changes on complex formation of silver(i) and mercury(H) with 'soft' donor ligands. J. Chem. Soc., Dalton Trans., 1976. pp. 1832-1837.

HANCOCK, R.D., and MARSICANO, F. Parametric correlation of formation constants in aqueous solution. Part 1. Ligands with small donor-atoms. Inorg. Chem., vol. 17, no. 3. 1978. pp. 560-564.

HANCOCK, R.D., and McDOUGALL, G.J. The role of electronic delocalization over the chelate ring in stabilizing complexes of 2,2'-bipyridyl. J. Chem. Soc, Dalton Trans., 1977. pp. 67-70.

HANCOCK, R.D., and McDOUGALL, G.J. The affinity of lead(H) for nitrogen-donor ligands. J. Coord. Chem., vol. 6. 1977. pp. 163-166.

HANCOCK, R.D., and McDOUGALL, G.J. Origin of macrocyclic enthalpy. J. Am. Chem. Soc, vol. 102, no. 21. 1980. pp. 6551-6553.

HANCOCK, R.D., McDOUGALL, G.J., MARSICANO, F., and BOEYENS, J.C.A. Empirical force- field calculations of strain-energy contributions to the thermodynamics of complex formation. Part III. The chelate effect in complexes of polyamines. Inorg. Chem., vol. 18, no. 10. 1979. pp. 2847-2852.

MARSICANO, F., and HANCOCX, R.D. A potentiometric and calorimetric study of the thermodynamics of formation of some of the complexes of the dw metal ions silver(l), mercury(ii), and cadmium(ii) with thiodiglycol, thiourea, and the sulphite ion. J. Coord. Chem., vol. 6. 1976. pp. 21-29.

MARSICANO, F., and HANCOCK, R.D. The linear free-energy relation in the thermodynamics of complex formation. Part 2. Analysis of the formation constants of complexes of the large metal ions silver(i), mercury(li), and cadmium(ii) with ligands having 'soft' and nitrogen-donor atoms. J. Chem. Soc, Dalton Trans., no. 3. 1978. pp. 228-234.

McDOUGALL, G.J., and HANCOCK, R.D. The N-M-N bond angle in the chelate ring of ethylenediamine. The crystal structure of tetra-aqua (ethylenediamine)nickel(H)) nitrate. J. Chem. Soc, Dalton Trans., no. 4. 1980. pp. 654-658.

McDOUGALL, G.J., HANCOCK, R.D., and BOEYENS, J.C.A. Empirical force-field calculations of strain-energy contributions to the thermodynamics of complex formation. Part 1: The difference in stability between complexes with five- and six-membered rings. J. Chem. Soc., Dalton Trans., no. 11. 1978. p. 1438.

MOODLEY, K.G., and NICOL, M.J. Kinetics of the reduction of platinum(iv) by tin(it) and copper(i) in aqueous chloride solutions. J. Chem. Soc., Dalton Trans., no. 3. Mar. 1977. pp. 239-243.

160 MINTEK PUBLICATIONS

NICOL, M. J. The kinetics of the oxidation of copperd) by hydrogen peroxide .in acidic chloride solutions. S.Afr. J. Chem., vol. 35, no. 3. 1982. pp. 77-79.

• NICOL, M.J. The non-oxidative leaching of oxides and sulphides: an electrochemical approach. HYDROMETALLURGY — RESEARCH, DEVELOPMENT AND PLANT PRACTICE. Osseo-Asare, K., and Miller, J.D. feds.). Warrendale (U.S.A.). The Metallurgical Society of AIME, 1982. pp. 177-195.

POPE, L.E., and BOEYENS, J.C.A. Crystal structures of S-benzylisothiouronium hexachloroplatinatetfV) and tetrachloroauratedii). J. Cryst. Mol. Struct., vol. 5, no. 1. 1975. pp. 47-58.

SCOTT, P.D., GLASSER, D., and NICOL, M.J. Thermal determination of the kinetics of the irondiu- tin(Il) redox reaction in chloride solution. J. Chem. Soc., Farad. Trans. I, vol. 71. no. 7. 1975. pp. 1413-1421.

SCOTT, P.D., and NICOL, M.J. Kinetics of the non-oxidative dissolution of galena in acidic chloride solutions. Trans. Instn Min. Metall., vol. 85. Mar. 1976. pp. C40-C44.

SCOTT, P.D., WILLIAMS, D.F., and GLASSER, D. The thermal determination of liquid phase kinetics. S.Afr. J. ScL, vol. 70, no. 1. 1974. pp. 10-12.

SMITH, R.P., and WOODBURN, E.T. Prediction of multicomponent ion exchange equilibria for the ternary system SOl' - NOf - Cl from data of binary systems. AIChE J., vol. 24, no. 4. Jul. 1978. pp. 577-588.

C5. Hydrometallurgy

C5.2. Processes and Equipment

1. Reports

No. Title Year

367 Felix Project: imperfect mixing in continuous leaching at Buffelsfontein uranium plant 1968

510 The performance of a clarifier subject to a low-intensity turbulence 1969

517 Radiotracer tests on the pachucas on the uranium plant at Western Reefs Mine 1969

898 The development of a computer programme for countercurrent operations involving liquid-solid separations 1970 2086 An automatic sampling probe for use in the carbon-in-pulp process 1980

2. Papers

COPELOWITZ, I., and LOVEDAY, B.K. An analysis of continuous resin contacting. Hydrometall., vol. 4. 1979. pp. 259-268.

FLEMING, C. A. Some aspects of the chemistry of carbon-in-pulp and resin-in-pulp processes. PAPERS PRESENTED AT THE SEMINAR ON CARBON-IN-PULP TECHNOLOGY FOR THE EXTRA CTION OF GOLD. Kalgoorlie (Australia), The Australasian Institute of Mining and Metallurgy, 1982. pp. 397-422.

• FLEMING, C.A. Recent developments in carbon-in-pulp technology in South Africa. HYDROMETALLURGY — RESEARCH, DEVELOPMENT AND PLANT PRACTICE. Osseo-Asare, K., and Miller, J.D. feds.J. Warrendale (U.S.A.), The Metallurgical Society of AIME, 1982. pp. 839-857.

161 MINTEK PUBLICATIONS

FLEMING, C.A., and NICOL, M.J. Alternative processes to filtration carbon-in-pulp and resin-in- pulp in the metallurgical industry. HYDROMETALLURGY 81: PROCEEDINGS OF A SOCIETY OF CHEMICAL INDUSTRY SYMPOSIUM HELD AT THE UNIVERSITY OF MANCHESTER, ENGLAND, 30 JUNES JULY 1981. London, the Society, 1981. pp. C2/1-C2/16.

FROST, F., and GLASSER, D. An apparatus for fractional ion-exchange separation. PROCEEDINGS CONFERENCE ON ION EXCHANGE IN THE PROCESS INDUSTRIES, LONDON, JULY 1969. London, Society for the Chemical Industry, 1970. pp. 188-194.

KING, R.P., WOODBURN, E.T., and TE RIELE, W. A.M. The dispersion of material in slowly moving fluids. Can. J. Chem. Engng, vol. 50, no. 1. Feb. 1972. pp. 3-8.

LAXEN, P.A. Carbon-in-pulp in South Africa. PAPERS PRESENTED AT THE SEMINAR ON CARBON-IN-PULP TECHNOLOGY FOR THE EXTRACTION OF GOLD. Kalgoorlie (Australia), The Australasian Institute of Mining and Metallurgy, 1982. pp. 17-41.

LOVEDAY, B.K. A model for the leaching of non-porous particles. J. S.Afr. Inst. Min. Metall., vol. 76, no. 2. Sep. 1975. pp. 16-19.

ORMROD, G.T. W. The control of aqueous ammonia concentrations by a thermal method. CHEMSA, Dec. 1975. pp. 284-286.

3. Patents

Improvements in and relating to the contacting of liquids and particulate solids. S.Afr. Pat. 69/5623, 28th Aug., 1970. (Also: S.W. Afr. Pat. 70/0100, 28th Aug., 1970.)

Contacting liquids and solids. S.W. Afr. Pat. 72/052, 5th May, 1971. (Also: Belg. Pat. 783.407, 12th May, 1972; Can. Pat. 978,722, 12th May, 1972; Fr. Pat. 72/17146, 12th May, 1972; Ital. Pat. 955.497, 31st May, 1972; Luxembourg Pat. 65.371, 16th May, 1972; U.S. Pat. 3,957,635, 8th May, 1972; W. Ger. Pat. P22 23 627.7 12th May, 1972.)

Solid/fluid contacting. S.Afr. Pat. 71/3139, 5th May, 1972. (Also: Bophuthatswana Pat. 71/3139, 5th May, 1972; Transkei Pat. 71/3139, 5th May, 1972; S.Afr. Pat. 71/3140, 5th May, 1972; Bophuthatswana Pat. 71/3140, 5th May, 1972; Transkei Pat. 71/3140, 5th May, 1972.)

Equipment for contacting liquids and solids. S.Afr. Pat. 72/4328, 23rd Jun., 1972. (Also: S. W. Afr. Pat. 73/064, 20th Jun., 1973; Venda Pat. 72/4328, 20th Jun., 1973.)

Improved method of measuring rates of dissolution. S.Afr. Pat. 72/8807, 13th Dec, 1972. (Also: S. W. Afr. Pat. 74/1, 8th Jan., 1974; Venda Pat. 72/8807, 13th Dec, 1972.)

The determination of mineral concentrations in slurries thereof. S.Afr. Pat. 75/6387, 8th Oct., 1975.

Extraction of dissolved compounds from slurries. S.Afr. Pat. 77/7475, 14th Dec, 1977. (Also: Venda Pat. 77/'>475, 14th Dec, 1977.)

Leaching process for metal sulphide containing materials. S.Afr. Pat. 80/0024, 24th Jan., 1979. (Also: Austral. Pat. 525900, 9th Dec, 1982; Can. Pat. 344311, 24th Jan., 1980; U.S. Pat. 4,274,931, 18th Jan., 1980.)

The leaching of sulphidic mattes containing non-ferrous metals and iron. Bophuthatswana Pat. 82/0021, 9th Feb., 1980. (Also: Belg. Pat. 887.544, 17th Feb., 1981; Botswana Pat. P381, 15th Dec, 1981; Peru Pat. 2653, 17th Feb., 1981; S. W. Afr. Pat. 81/0011, 3rd Feb., 1981; Sp. Pat. 499.463/9, 16th Feb., 1981; Zambia Pat. 16/81, 19th Feb., 1981; Zimbabwe Pat. 34/81, 12th Feb., 1981.)

162 MINTEK PUBLICATIONS

Leaching of sulphidic mattes containing nonferrous metals. S.Afr. Pat. 81/0701, 18th Feb., 1980.

The leaching of zinc containing sulphide materials. S.Afr. Pat. 81/5009, 14th Apr., 1980. (Also: Bophuthatswana Pat. 81/0155, 24th Jul., 1981; S. W. Afr. Pat. 81/0092, 22nd Jul., 1981; Venda Pat. 81/0087, 27th JuL, 1981; Zimbabwe Pat. 195/81, 13th Aug., 1981.)

Selective ion exchange resins. S.Afr. Pat. 81/1394, 3rd Mar., 1981. (Also: Belg. Pat. 887,872,10th Mar., 1981; Bophuthatswana Pat. 81/0035,6th Mar., 1981; Chile Pat. 32906,10th Jun., 1982; S. W. Afr. Pat. 81/0022, 3rd Mar., 1981.)

Selective solvent extraction using organophosphorous and carboxylic acids. S.Afr. Pat. 82/3272, 12th May, 1982. (Also: Botswana Pat. P. 435,12th May, 1982; Venda Pat. 82/0039, !4th May, 1983; Zambia Pat. 3.V82, 27th May, 1982; Zimbabwe Pat. 98/82, 17th May, 1982.)

The contacting of liquids and slurries with solid extractants in discrete paniculate or granular form. S.Afr. Pat. 82/5561,2nd Aug., 1982. (Also: Botswana Pat. P. 429,2nd Aug., 1982; Swaziland Pat. RP/14/1983, 2nd Aug., 1982; Venda Pat. 82/0068, 10th Aug., 1982; Zimbabwe Pat. 166/82, 6th Aug., 1982.)

5. Technical bulletins

Continuous ion exchange in hydrometallurgy. Technical Bulletin no. 1. 1976. 16 pp. [Superseded by Technical Bulletin no. 2.]

The NIMCIX contactor. Continuous ion exchange in hydrometallurgy. Technical Bulletin no. 2. Aug. 1978. 10 pp. [Out of print.]

C5. Hydrometallurgy

C5.3. Reagents

/. Reports

No. Title Year

1793 The kinetics of mechanism of solvent extraction of copper by LIX 64N and KELEX 100 1976

1828 7-picoline adducts of the nickel, copper, and zinc chelates of 2-thenoyltrifluoroacetone 1976

1853 Chloromethylation of polystyrene resins 1977

1856 A study of model systems in anion exchange 1977

1897 A study of aggregation in the organic phase of solvent extraction systems and its influence

on the extraction process 1977

1935 The construction and testing of a small mixer-settler for use in the laboratory 1977

1947 The cation- and anion-exchange behaviour of various base-metal chlorides in polar organic solvents 1978 2. Papers BOEYENS, J.C.A., and HAEGELE, R. Oxygen as a di-^-peroxo bridge; synthesis and structure of benzyltrimethylammonium-di-pi-peroxohexachlorodiuranyl(Vi). Inorg. Chim. Acta, vol. 20. 1976. p. L7.

163 MINTEK PUBLICATIONS

BOEYENS, J.C.A., McDOUGALL, G. J„ and SMIT, J.V.R. Ciystallographic study of the ammonium- potassium 12-molybdophosphatw ion-exchange system. J. Solid State Chem., vol. 18. 1976. pp. 191-199.

FLEMING, CA. Origin of selectivity of oxines and oximes for copper(li) over iromui). Trans. Instn Min. Metall., vol. 85. Dec. 1976. pp. C211-C212.

FLEMING, CA. Origin of selectivity of oxines and oximes for copper(ll) over iron(Ui). Trans. Instn Min. Metall., vol. 88. Dec. 1979. pp. C253-C255.

FLEMING, CA., and HANCOCK, R.D. The mechanism in the poisoning of anion-exchange resins by cobalt cyanide. J. S.A/r. Inst. Min. Metall., vol. 79, no. 11. Jun. 1979. pp. 334-341.

FLEMING, C.A., HANCOCK, R.D., NICOL, M.J., and FINKELSTEIN, N.P. The kinetics of the extraction of copper by LIX64N and LIX63. Discussion Oi the rate law. INTERNATIONAL SOLVENT EXTRACTION CONFERENCE. Lucas, B.H., et al. (eds.). Montreal, Canadian Institute of Mining and Metallurgy, 1979. pp. 193-197.

FLEMING, C.A., and NICOL, M.J. A comparative study of kinetic models for the extraction of uranium by strong-base anion-exchange resins. J. S.Afr. Inst. Min. Metall., vol. 80, no. 2. Feb. 1980. pp. 89-99.

FLEMING, C.A., NICOL, M.J., HANCOCK, R.D., and FINKELSTEIN, N.P. The kinetics of the extraction of copper by LIX65N and the catalytic role of LIX63 in this reaction. J. Appl. Chem. BiotechnoL, vol. 28. 1978. pp. 443-452.

HAEGELE, R., and BOEYENS, J.C.A. Crystal structure of benzyltrimethylammonium /t2-peroxo- bisftrichlorodioxouranate(Vi)], a binuclear uranium complex containing dioxygen in a /trperoxo linkage. J. Chem. Soc, Dalton Trans., 1977. pp. 648-650.

MARSICANO, F., and HANCOCK, R.D. A potentiometric and calorimetric study of the thermodynamics of formation of some of the complexes of the dw metal ions silver(i), mercury(ii), and cadmium(ii) with thiodiglycol, thiourea, and the sulphide ion. J. Coord. Chem., vol. 6. 1976. pp. 21-29.

3. Patents

Improvements relating to resins. S.Afr. Pat. 76/5165, 23rd Aug., 1977.

Selective ion exchange media. S.Afr. Pat. 77/5398, 7th Sep., 1977. (Also: Austral. Pat. 39620/78, 7th Sep., 1978; Belg. Pat. 870,289, 7th Feb., 1978; Bophuthatswana Pat. 77/5398, 7th Sep., 1977; Br. Pat. 2 017 715B, 5th Sep., 1978; Can. Pat. 1,119,343, 8th Sep., 1978; Chile Pat. 31218, 7th Sep., 1978; Fr. Pat. 78.25747, 7th Sep., 1978; S. W. Afr. Pat. 78/0106, 5th Sep., 1978; U.S. Pat. 4,202,944, 7th Sep., 1978.)

Selective extractant for metal values. S.Afr. Pat. 78/1905, 4th Apr., 1978.

Selective ion exchange resins. S.Afr. Pat. 81/1394, 3rd Mar., 1981. (Also: Belg. Pat. 887,872, 10th Mar., 1981; Bophuthatswana Pat. 81/0035, 6th Mar., 1981; Chile Pat. 32906, 10th Jun., 1982; S. W. Afr. Pat. 81/0022, 3rd Mar., 1981.)

The measurement of the concentration of solid particles. S.Afr. Pat. 82/3383, 17th May, 1982. (Also: Botswana Pat. P.424, 17th May, 1982; Swaziland Pat. RP/10/1983, 17th May, 1982; VendaPat. 82/0040, 18th May, 1982; Zimbabwe Pat. 102/82, 19th May, 1982.)

164 MINTEK PUBLICATIONS

C6. Measurement and Control

/. Reports

No. Title Year

67 The application of silicon controlled rectifiers to instruments using half-cycle heating 1966

91 Half-cycle heating applied to an X-ray powoer camera 1966

477 Balanced-temperature analysers 1969

489 Thermal analysis. Overseas visit 1969

1267 The development of an electrodeless conductivity meter 1971

1526 Heat of solution as a control of aqueous-ammonia concentration 1973

1533 Fields of application for dispersive and non-dispersive X-ray-fluorescence instruments 1973

1591 The inductive measurement of conductivity in slags 1974

1640 A semi-automatic titrimeter for cyanide analysis 1974

1778 An apparatus for the automatic measurement of current efficiencies during the electrodeposition of nickel in chloride media 1976 1876 The determination, by ultrasonic measurement, of the mud level in a thickener and the resin level in an ion-exchange column 1977

1884 The use of capacitance probes for the determination of interfaces 1977

1939 An industrial microprocessor system 1978

1998 Electrode response to the addition of zinc during the cementation of gold 1979

2001 An assessment of vibrating viscometers on slurries 1979

2003 An electrodeless conductivity meter of improved sensitivity and reliability 1979

2059 Distributed computer control of industrial processes 1980

• 2096 A meter for the measurement of moisture in mill feed 1981

M28 The measurement of flow velocity distribution in fluids 1982

M31 Software for the design of multivariable control systems by use of the Inverse Nyquist Array 1982 M63 A general-purpose data logger 1982

• M68 The suitability of Doppler flowmeters for use in the minerals-processing industry 1983

• M98 Multivariable control and optimization of the operation of a milling circuit at East Driefontein Gold Mine 1983

165 MINTEK PUBUCATIONS

2. Papers

BRAAE, M., and HULBERT, D.G. A suite for the computer-aided design of control systems. Pulse, Jul. 1981. pp. 18-23.

• DANN, M.S. Variable turns ratio inductance transducer for measurement of translational displacement. J. Phys. E. Sci. Instrum., vol. 17, no. 3. Mar. 1984. pp. 184-185.

GRAY, G.T., and POTGIETER, J.H. Experience with the introduction of microprocessor systems into industry. Pulse, Jan. 1979. pp. 18-20.

GRAY, G.T., and RODD, M.G. The development of an extended macro-assembler for the production of microprocessor software. Trans. S.Afr. Inst. Elec. Engnrs, vol. 60, no. 7. Jul. 1978. pp. 201-205.

LEITNER, J.R. A microprocessor-based cross-correlation flowmeter. APPLICATION OF MICROPROCESSORS IN DEVICES FOR INSTRUMENTA TION AND A UTOMA TIC CONTROL. The Institute of Measurement and Control (eds.). London, the Chameleon, 1980. pp. 67-76. » LEITNER, J.R., and NAUDÉ, D.E.H. Slurry flow-rate measurement using correlation. Pulse, Sep. 1979. pp. 25-28.

ORMROD, G.T.W. The control of aqueous ammonia concentrations by a thermal method. Electron. Instrumn, vol. 6, no. 8. Aug. 1975. pp. 73, 77, 79.

ORMROD, G.T.W. The control of aqueous ammonia concentrations by a thermal method. CHEMSA, Dec. 1975. pp. 284-286.

ORMROD, G.T.W. Electrodeless conductivity meters in the measurement and control of the amount of lime in alkaline slurries. Pulse, Apr. 1979. pp. 16-18.

• ORMROD, G.T.W. The use of Doppler flowmeters for measuring slurry flows. Pulse, Feb. 1983. pp. 21-22.

ORMROD, G.T.W., and SOMMER, G. Analytical instrumentation for control of the leaching process. AUTOMATION IN MINING, MINERAL AND METAL PROCESSING. Lancaster, F.H. (ed.). Pretoria, South African Council for Automation and Computation, 1977. pp. 521-530.

SOMMER, G. Temperature measurement with thermocouples. Electron. Instrumn, vol. 2, no. 1. Apr. 1971. pp. 2-5.

SOMMER, G., and JOCHENS, P.R. Techniques of micro-thermal analysis based on a thermocouple as heating source and specimen holder. Miner. Sci. Engng, vol. 3, no. 1. Jan. 1971. pp. 3-16.

SOMMER, G., JOCHENS, P.R., and HOW AT, D.D. Solid state circuitry for a microdifferential thermal analyser. J. Phys. E; Scient. Instrum., vol. 1. 1968. pp. 1116-1118.

SOMMER, G., and MILLER, R.P. A hot stage microscope incorporating a differential thermal analysis unit. J. Scient. Instrum., vol. 43, no. 5. May 1966. pp. 293-297.

SOMMER, G., and SANDER, H.W. Balanced temperature analysers. 2ND INTERNATIONAL CONFERENCE ON THERMAL ANAL YSIS, 1968. Schwenker, R.F., and Gam, P.D. (eds.). New York, Academic Press, 1969. vol. 1. pp. 163-175.

• SOMMER, G., and STEWART, A.B. The introduction of advanced control equipment into mineral- processing operations. 4TH IF AC SYMPOSIUM ON A UTOMA TION IN MINING, MINERAL AND METAL PROCESSING. PREPRINTS. Westerlund, T. (ed.). Helsinki, Finnish Society of Automatic Control, 1983. pp. 197-202.

166 MINTEK PUBLICATIONS

ZANDERS, J.A.J. Single-ended differential instrumentation amplifier. Electron. Instntmn, vol. 4, no. 11. Mar. 1974. pp. 2-3.

ZANDERS, J.A.J. An electronic differential precision thermometer. Electron Instntmn, vol. 4, no. 12. Apr. 1974. pp. 24-25, 28.

3. Patents

Improvements relating to the controlling of processes. S.A/r. Pat. 73/1213,21st Feb., 1973. (Also: Venda Pat. 73/1213, 21st Feb., 1973.)

Improved method of measuring rates of dissolution. S.Afr. Pat. 71/8807, 13th Dec., 1972. (Also: S. W. Afr. Pat. 14/1, 8th Jan., 1974; Venda Pat. 72/8807, 13th Dec, 1972.)

The determination of mineral concentrations in slurries thereof. S.Afr. Pat. 75/6387, 8th Oct., 1975. C7. Mineralogy

C7.1. General

1, Reports

No. Title Year

25 Quantitative mineralogical examination of six samples of pulverized mine ores submitted by the Chemical Engineering Group, CSIR 1966

34 Qualitative electron-microprobe investigation of cobalt-gadolinium intermetallic compounds 1966

53 Differential thermal investigation of Moore-filter residues for the Anglo American Research Laboratory 1966

104 The infrared examination of microlite, muscovite, apatite in the presence of carbonate, asbestos, paragonite, and various uranium salts 1967

113 The identification, by means of the electron microprobe, of an opaque mineral from the Artonvilla Mine, Messina 1966

132 Mineralogical and spectrographic investigation of a mineral concentrate from Koster, western Transvaal 1967

260 The electron-microprobe investigation of two samples of magnetite catalyst from Sasol 1967

286 A mineralogical and petrographic study of the pre-Transvaal rocks in borehole K.I, Koster district, western Transvaal 1968

287 A preliminary examination of kieselghur from Witdraai, south of Postmasburg 1968

313 The qualitative investigation of inclusions in free-cutting steel with the electron microprobe 1968

943 An electron-microprobe investigation of chiastolite crystals 1970

1697 A petrographic and mineralogical investigation of silica samples from the farm Elandskraal 470 JQ, Rustenburg district 1975

167 MINTEK PUBLICATIONS

2. Papers

BUCHANAN, D.L., NOLAN, J., and VILJOEN, E.A. Determination of silica activity in Bushveld rocks. Contrib. Min. Pet., vol. 73. 1980. pp. 311-319.

CZAMANSKE, G.K., and MIHALIK, P. Oxidation during magnetic differentiation. Jinmoskia Complex, Oslo area, Norway: Part 1. The opaque oxides. J. Petrol., vol. 13, no. 3. 1972. pp. 493-509.

DE WAAL, S.A. Interference-folding of Bushveld Igneous Complex age in the Transvaal System north of Marble Hall, Transvaal. Johannesburg, The Geological Society of South Africa, spec. pub. 1,1970. pp. 283-298.

DE WAAL, S.A. The ferromangan-se deposit at Lisbos Falls, near Graskop, Transvaal, and its similarity to ferromanganese nodules of the ocean floor. Trans. Geol. Soc. S.Afr., vol. 80, pt 2.1977. pp. 131-136.

DE WAAL, S.A. Carbon dioxide and water from metamorphic reactions as agents for sulphide pnd spinel precipitation of mafic magmas. Trans. Geol. Soc. S.Afr., vol. 80, pt. 3. 1977. pp. 193-196.

DE WAAL, S.A. The alteration and possible reasons for the refractory nature of chromitite from the Marico occurrence, western Transvaal. Trans. Geol. Soc. S.Afr., vol. 80. pt 3. 1977. pp. 235-239.

DE WAAL, S.A., and CALK, L.C. The sulphides in the garnet pyroxenite xenoliths from Salt Lake Crater, Ohio. /. Petrol., vol. 16, no. 1. Feb. 1975. pp. 134-153.

FRICK, C, and VILJOEN, E.A. The De Hoek meteorite: a plessitic octahedrite from South Africa. S.Afr. J. ScL, vol. 69. 1973. pp. 310-312.

FRICK, C., and VILJOEN, E.A. The Etosha meteorite: a medium octahedrite from South West Africa. S.Afr. J. ScL, vol. 69. 1973. pp. 345-348.

WILLEMSE, J.W., and VILJOEN, E.A. The fate of argillaceous material in the gabbroic magma of the Bushveld Igneous Complex. Johannesburg, The Geological Society of South Africa, spec. pub. 1, 1970. pp. 336-366.

C7. Mineralogy

C7.2. Techniques

1. Reports

No. Title Year

103 Techniques for the examination of inorganic compounds on an infrared spectrograph 1966

105 Report on overseas visit 1966

268 A power-failure safety device and operational aid for the electron microprobe 1968

2058 An elementary introduction to image analysis — a new field of interest at the National Institute for Metallurgy 1980

2. Papers

GASPARRINI, E. Electron-microprobe quantitative analysis by energy-dispersive spectrometry. PROCEEDINGS, ELECTRON MICROSCOPY SOCIETY OF SOUTHERN AFRICA, PRETORIA CONFERENCE. Durban, the Society, 1975. vol. 5. pp. 121-122.

168 MINTEK PUBLICATIONS

GASPARRINI, E. The energy-dispersive spectrometer: a new tool of investigation for the earth scientist. Miner. Sci. Engng, vol. 8, no. 1. Jan. 1976. pp. 3-22.

HIEMSTRA, S.A. Photomicrography. Miner. Set. Engng, vol. 1, no. 2. Jul. 1969. pp. 34-50.

• HIEMSTRA, S.A. The iridescent coating of polished sections, and its application to ore microscopy and image analysis. ICAM81. PROCEEDINGS OF THE FIRST INTERNA TIONAL CONGRESS ON APPLIED MINERALOGY. De Villiers, J.P.R., and Cawthorn, P.A. (eds.). Johannesburg, The Geological Society of South Africa, 1983. pp. 479-483.

JOHNSON, J.A., and VILJOEN, E.A. The effects of the sample surface on quantitative electron- microprobe analyses. ELECTRON MICROSCOPY SOCIETY OF SOUTHERN AFRICA — PROCEEDINGS. Durban, the Society, 1980. vol. 10. pp. 21-22.

LIEBENBERG, W.R. Mineralogy and the metallurgist. Miner. Sci. Engng, vol. 2, no. 4. Oct. 1970. pp. 3-23.

• LOMBAARD, T., and HIEMSTRA, S.A. Development of an apparatus for the magnetohydrostatic separation of minerals. ICAM81. PROCEEDINGS OF THE FIRST INTERNATIONAL CONGRESS ON APPLIED MINERALOGY. De Villiers, J.P.R., and Cawthorn, P.A. feds.). Johannesburg, The Geological Society of South Africa, 1983. pp. 485-489.

MIHALIK, P. The electron microprobe X-ray analysis. S.Afr. Chem. Process., vol. 2, no. 2. Apr.- May 1967. pp. 37-42.

MIHALIK, P. An aid for the alignment, positioning, and checking of the beam in the electron microprobe. Lab. Practice, vol. 19, no. 3. Mar. 1970. p. 288.

MIHALIK, P., and HIEMSTRA, S.A. Apparatus permitting visual observation during the vacuum- deposition of thin films. Lab. Practice, vol. 21, no. 4. Jan. 1972. pp. 29-30.

• OOSTHUYZEN, E.J. The application of automatic image analysis to mineralogy and extractive metallurgy. ICAM 81. PROCEEDINGS OF THE FIRST INTERNATIONAL CONGRESS ON APPLIED MINERALOGY. De Villiers, J.P.R., and Cawthorn, P.A. (eds.). Johannesburg, The Geological Society of South Africa, 1983. pp. 449-464.

• VILJOEN, E.A., and JOHNSON, J.A. Microbeam techniques in applied mineralogy. ICAM 81. PROCEEDINGS OF THE FIRST INTERNATIONAL CONGRESS ON APPLIED MINERALOGY. De Villiers, J.P.R., and Cawthorn, P.A. (eds.). Johannesburg, The Geological Society of South Africa, 1983. pp. 499-506.

VILJOEN, E.A., JOHNSON, J.A., and HAIG, L. Some factors governing the quality of quantitative electron-microprobe analysis. ELECTRON MICROSCOPY SOCIETY OF SOUTH AFRICA — PROCEEDINGS. Durban, the Society, 1980. vol. 10. pp. 19-20.

VON RAHDEN, H.V.R. A modified halide-disc holder for infrared spectrometry. J. Scient. Instrum., vol. 44. 1167. p. 168. C8. Ore-dressing (Excluding Flotation and Comminution)

1. Reports

No. Title Year

518 The prediction of gravity or inertial separation efficiencies from heavy-liquid tests and Tromp-type efficiency curves. An improved method 1969

169 MINTEK PUBLICATIONS

No. Title Year

2076 Wet high-intensity magnetic separation. Laboratory tests conducted in 1978 and 1979 1980

2082 A survey of the literature on gravity separation 1980

• 2108D Evaluation of a grinding aid in batch grinding, classification, and gravity concentration 1981

• M77 Analysis of the results of a marked-ball test in relation to theories of ball wear in rotary mills 1983 • M97 Reduction in metal consumption by the use of alternating lines of higher and lower lifter bars in a rod mill 1983

• M101 The potentiality of heat-treated balls in the grinding of gold ores 1983

• Ml 16 Abrasive and impactive wear of high-chromium cast-iron grinding balls 1984

• Ml 17 An assessment of the merits of various types of balls in the milling of ores 1983

2. Papers • BARKER, I. J., and HULBERT, D.G. Dynamic behaviour in the control of milling circuits. 4THIFAC SYMPOSIUM ON AUTOMATION IN MINING, MINERAL AND METAL PROCESSING. PREPRINTS. Westerland, T. fed.). Helsinki, Finnish Society of Automatic Control, 1983. pp. 101-115.

CORRANS, I.J. A development in the application of wet high-intensity magnetic separation. FINE PARTICLES PROCESSING. Somasundaran, P. New York, American Institute of Mining, Metallurgical and Petroleum Engineers Inc., 1980. vol. 2. pp. 1294-1309.

GOOLD, L.A., LIN, I.J., LOVELL, V.M., and FINKELSTEIN, N.P. Oil-levitation extraction: a variation of flotation. J. S.Afr. Inst. Min. Metall., vol. 76, spec, issue. Oct. 1975. pp. 132-134.

KELEGHAN, W.T.H. Some potential applications of wet high-intensity magnetic separation. J. S.Afr. Inst. Min. Metall., vol. 76, spec, issue. Oct. 1975. pp. 108-110.

KELEGHAN, W.T.H. WHIMS for low-grade uranium. Nucl. Active, no. 16. Jan. 1977. pp. 3-5.

LEVIN, J. Mixing and sampling procedures used at the National Institute for Metallurgy, South Africa. SAMPLING IN THE MINERAL AND METALLURGICAL PROCESSING INDUSTRIES. Institution of Mining and Metallurgy. London, the Institution, 1973. pp. 28-37.

LIN, I.J., and FINKELSTEIN, N.P. The application of magnetohydrostatic separation to metallurgical processes. J. S.Afr. Inst. Metall., vol. 76, spec, issue. Oct. 1975. pp. 111-112.

LOVED AY, B.K. The prediction of gravity or inertia! separation efficiencies from heavy-liquid tests and Tromp-type efficiency curves. An improved method. Trans. Instn Min. Metal/., vol. 79, no. 763. Jun. 1970. pp. C137-C1O.

MOYS, M.H. The control of autogenous and semi-autogenous mills: the relation between measurements of bearing pressure and parameters describing the mill load. J. S.Afr. Inst. Min. Metall., vol. 80, no. 11. Nov. 1980. pp. 401-408.

OVERBEEK, P.W. An assessment of the efficiency of the Dryflo concentrator by the use of specific gravity markers. J. S.Afr. Inst. Min. Metall., vol. 76, spec, issue. Oct. 1975. pp. 120-122.

• VERMEULEN, L.A., HOW AT, D.D., and GOUGH, C.L.M. Theories of ball wear and the results of a marked-ball test in ball milling. J. S.Afr. Inst. Min. Metall., vol. 83, no. 8. Aug. 1983. pp. 189-197.

170 MINTEK PUBLICATIONS

3. Patent

Relating to magnetic separators. S.A/r. Pat. 78/1467, 14th Mar., 1978. (Also: Austral. Pat. 519,775, 9th Mar., 1979; Br. Pat. 2 016 304, 28th Feb., 1979; Can. Pat. 322,854, 6th Mar., 1979; U.S. Pat. 4,260,477, 5th Mar., 1979; Venda Pat. 78/1467, 14th Mar., 1978.)

C9. Pyrometallurgy

/. Report

No. Title Year

1521 The dissipation of electrical power in the burden of a submerged-arc furnace 1973

2. Papers

CHANNON, W.P., URQUHART, R.C., and HOW AT, D.D. The mode of current transfer between electrode and slag in the submerged-arc furnace. J. S.Afr. Inst. Min. Metall., vol. 75, no. 1. Aug. 1974. pp. 4-7.

• CURR, T.R., BARCZA, N.A., MASKE, K.U., and MOONEY, J.F. The design and operation of transferred-arc plasma systems for pyrometallurgical applications. 6TH INTERNATIONAL SYMPOSIUM ON PLASMA CHEMISTRY. Boulos, M.I., andMunz, R.J. feds.). Sherbrooke (Canada), Université de Sherbrooke, 1983. vol. 1. pp. 175-180.

HAINES, A.K., KING, R.P., and WOODBURN, E.T. The interrelationship between bubble motion and solids mixing in a gas-fluidized bed. AIChE, vol. 18, no. 3. May 1972. pp. 591-599.

URQUHART, R.C., JOCHENS, P.R., and HOW AT, D.D. The dissipp'ion of electrical power in the burden of a submerged-arc furnace. 31ST ELECTRIC FURNACE CONFERENCE PROCEEDINGS. Metallurgical Society ofAIME. New York, AIME, 1973. vol. 31. pp. 29-48.

3. Patent

• Treatment of insoluble iron- ontaining materials to recover metal values therefrom. S.Afr. Pat. 82/1779. 17th Mar., 1982. (Also: Bophuthatswana Pat. P.417, 30th Mar., 1982; Swaziland Pat. RP/14/1983,17th Mar., 1982; Venda Pat. 82/0019, 24th Mar., 1982; Zimbabwe Pat. 66/82, 2nd Apr., 1982.)

C10. Reference Materials

I. Reports

No. Title Year

331 A literature survey of the preparation of standard rock samples 1968

332 Collection and preparation of standard rock samples 1968

1322 The preparation and analysis of minerals for use as reference material 1971

1351 Preliminary report on the analysis of the six NIMROC geochemical standard samples 1972

1552 The preparation and analysis of minerals for use as reference matei ial. Progress report no. 2 1973

171 MINTEK PUBLICATIONS

1609 An interlaboratory analysis of two ferrochromium slags 1974

1649 The establishment of preferred values for a series of fluorspar samples 1974

1696 The preparation and certification of a reference sample of a precious metal ore 1975

1719 An evaluation of the X-ray-fluorescence analysis of rocks and silicates under routine conditions 1975 1762 The determination, by instrumental neutron-activation analysis, of some elements in the NIMROC standard reference materials 1975

1803 The preparation and analysis of minerals for use as reference material. Progress report no. 3 1976

1807 The establishment of preferred values for a series of rare-earth samples 1976

1945 Analyses of the NIMROC reference samples for minor and trace elements 1978

1965 Analyses, by several laboratories, of three ferromanganese slags 1978

1972 The preparation and certification of a reference sample of high-carbon ferrochromium 1978

1976 The preparation and certification of two samples of chromium ore 1978

1977 The preparation and certification of a reference sample of hematite ore 1978

1978 The preparation and certification of a reference sample of magnetite ore 1978

2016 Analysis of the NIMROC reference samples for major elements 1979

2042 The preparation and analysis of minerals for use as reference material. Progress report no. 4 1980 2083 The determination, by anodic-stripping voltammetry, of zinc and lead in six NIMROC reference materials 1980

2089 An investigation of the confidence limits of the Gastwirth median 1980

2115 Estimation of material variation in powdered materials 1981

2121 Five robust indicators of central value 1981

2127 The preparation of a reference material of South African zirconium concentrate from

Richards Bay 1981

M2 The preparation of two reference materials of South African fluorspar 1981

Ml6 The preparation and certification of ten uranium reference materials 1982

M47 The separation of trace elements from iron, and the analysis of iron-rich ores for use as reference materials 1982 M70 The preparation and certification of two reference materials of South African manganese ore 1983 M84 The preparation and certification of a uranium reference material 1983

172 MINTEK PUBLICATIONS

No. Title Year

• M104 The preparation and analysis of reference materials, and the provision of recommended values. Progress report No. 5 1983

2. Papers

EDDY, B.T. Instrumental neutron-activation analysis of uranium reference materials. Geostand. NewsL, vol. 6, no. 1. Apr. 1982. pp. 83-89.

ELLIS, P.J., COPELOWITZ, I., and STEELE, T.W. The estimation of the mode by the dominant cluster method. Geostand. NewsL, vol. 1, no. 2. Oct. 1977. pp. 123-130.

STEELE, T.W., and HANSEN, R.G. Major element data (1966-1978) for the six 'NIMROC' reference samples. Geostand. NewsL, vol. 3, no. 2. Oct. 1979. pp. 135-172.

STEELE, T.W., WILSON, A., GOUDVIS, R., ELLIS, P.J., and RADFORD, A.J. Trace element data (1966-1977) for the six NIMROC reference samples. Geostand. NewsL, vol. 2, no. 1. Apr. 1978. pp. 71-106.

STOCH, H., STEELE, T.W., and RANKIN, R.S. The preparation and certification of two samples of chromium ore. Geostand. NewsL, vol. 3, no. 1. Apr. 1979. pp. 25-45.

C11. Simulation and Control — Fundamental Studies

/. Reports

No. Title Year

327 Information theory and the design of experiments 1968

1025 An introduction to stochastic differential equations. Abbreviated lecture notes 1971

2009 A review of the activities of the NIM Measurement and Control Engineering Research Group 1979

2. Papers

BRAAE, M., and RUTHERFORD, D.A. Fuzzy relations in a control setting. Kybernetes, vol. 7. 1978. pp. 185-188.

BRAAE, M., and RUTHERFORD, D.A. Selection of parameters for a fuzzy logic controller, huzzy Sets and Systems, vol. 2. 1979. pp. 185-199.

BRAAE, M., and RUTHERFORD, D.A. Theoretical and linguistic aspects of the fuzzy logic controller. Automatica, vol. 15, no. 5. Sep. 1979. pp. 553-577.

KING, R.P. Some problems in chemical reactor analysis with stochastic features. / & EC Fundamentals, vol. 9, no. 1. Feb. 1970. pp. 190-191.

KING, R.P. Continuous flow system with stochastic transfer functions. II. Solution by the associated Kolmogorov equation. Chem. Engng Sci., vol. 26, no. 5. May 1971. pp. 729-737.

173 MINTEK PUBLICATIONS

KING, R.P. Continuous flow systems with stochastic transfer functions. III. Stationary operation with chemical reaction. PROCEEDINGS AND INTERNATIONAL SYMPOSIUM ON CHEMICAL REACTION ENGINEERING. Amsterdam, Elsevier Publishing Co., 1972. pp. B4-35-B4-46.

KING, R.P. Applications of stochastic differential equations to chemical engineering problems — an introductory review. Chem. Engng Commun., vol. 1, no. 4. Nov. 1974. pp. 221-237.

KING, R.P., GLASSER, D., and STONE, S.L. The optimal catalyst-concentration profile for bifunctional catalysts. Journal of Optimization Theory and Application, vol. 10, no. 2. Aug. 1972. pp. 94-108.

KING, R.P., WOODBURN, E.T., COLBORN, R.P., EDWARDS, R., and SMITH, W.E. Dynamic testing of mineral processing equipment using radioisotopes. NUCLEAR TECHNIQUES AND MINERAL RESOURCES. International Atomic Energy Agency. Vienna, the Agency, 1969. pp. 117-127.

PAYNTER, J.C., LOVEDAY, B.K., and ROBINSON, C.G. Optimization studies on the design of r> processing plant for a large mining venture. APPLICA TION OF COMPUTER METHODS IN THE MINERAL INDUSTRY. Salomon, M.D.G., and Lancaster, F.H. (edsj. Johannesburg, The South African Institute of Mining and Metallurgy, 1973. pp. 171-176. *

D1. Selection of Materials and Optimization

/. Reports

No. Title Year

1860 A preliminary investigation of materials of construction for ore hoppers 1976

1908 An analysis of the replies to a questionnaire on materials of construction for ore hoppers 1977

2110 The investigation of a fracture on one side of a skip bridle in a mine shaft 1981

• M6S A preliminary survey of the corrosivity of water in fold mines 1983

• M66 A review of corrosion inhibitors: theory and practice 1983

2. Papers

• HIGGINSON, A. Recent advances in corrosion-science research in Great Britain. Some impressions of the 24th Corrosion Science Symposium. Corrosion and Coatings, vol. 11, no. 1. 1984. pp. 25, 27, 33.

• HIGGINSON, A., and WHITE, R.T. A preliminary survey of the corrosivity of water in South African gold mines. J. S.Afr. Inst. Min. Metall., vol. 83, no. 6. Jun. 1983. pp. 133-141.

HOW AT, D.D. Spotlight on wear and abrasion in industry. J. S.Afr. Inst. Min. Metall., vol. 81, no. 6. Jun. 1981. pp. 200-202.

HOW AT, D.D., and ENRIGHT, D.P. The performance, wear characteristics, and failures of austenitic manganese-steel castings used in crushing and rod milling. J. S.Afr. Inst. Min. Metall., vol. 80, no. 2. Feb. 1980. pp. 63-81.

ÜLVAN, E., and KOURSARIS, A. Metal formability in bulk deformation processes. J. Metals, vo!. 35, no. 12. Dec. 1983. pp. 20-26.

174 MINTEK PUBLICATIONS

E1. Costs and Commodities

/. Reports

No. Title Year

109 The possibility of establishing a local cost index for the estimation of metallurgical and

chemical plant 1967

884 Review of information on the mineral industry of Mocambique 1970

1310 South African costs of industrial equipment for the metallurgical industry 1971

1529 South African costs of equipment for the metallurgical industry (1972) 1973

1559 A cost assessment of the production of elemental sulphur by chlorination roasting 1973

1644 Prospects for the recovery of minerals from the sea 1974

1741 South African costs of equipment for the metallurgical industry (1975) 1975

1750 A review of the present and future development of sulphur production in South Africa 1975

• M120 South African costs of equipment for the metallurgical industry (1983) 1983

2. Papers

GRANVILLE, A. The recovery of deep-sea minerals: problems and prospects. Miner. Sci. Engng, vol. 7, no. 3. Jul. 1975. pp. 170-188.

ROBINSON, R.E. The utilization and conservation of mineral resources. S.A/r. J. Sd., vol. 68, no. 4. Apr. 1972. pp. 105-110.

VAN RENSBURG, W.C.J. Changing patterns in the World's supply of minerals. Miner. Sci. Engng, vol. 6, no. 3. Jul. 1974. pp. 142-153.

E2. Manpower

/. Report

No. Title Year

1483 The South African manpower requirements in extractive metallurgy 1972

2. Papers

JOCHENS, P.R. Metallurgical-engineering curricula and syllabuses at South African universities and technikons. Konfersnsie oor Ingenieursmannekragontwikkeling vir die 2lste Eeu. Pretoria, University of Pretoria, 5th Nov., 1980. vol. 2. pp. 3N-3N/8.

ROBINSON, R.E. Would you encourage your son to undertake a mining career? Coal, Gold Base Miner., vol. 19, no. 3. May 1971. pp. 19-27.

175 MINTEK PUBLICATIONS

E3. Mintek and lts Predecessor (NIM)

i. Report

No. Title Year

1867 NIM decennial review (1966 to 1976) 1977

2. Papers

CLARKE, P.J. The National Institute for Metallurgy, South Africa. StahlundEisen, vol. 97, no. 18. 8th Sep., 1977. pp. 895-899.

CLARKE, P.J. A new centre for metallurgical rese^cn — the National Institute for Metallurgy in Randburg. Afrika-Post, vol. 24, no. 11. Nov. 1977. pp. 337-340. (In German.)

CLARKE, P.J. Recent progress of the National Institute for Metallurgy. Meiall, vol. 32, no. 3. Mar. 1978. pp. 288-289. (In German.)

CLARKE, P.J. South Africa's National Institute for Metallurgy. Int. J. Miner. Processing, vol. 6, no. 4. Feb. 1980. pp. 341-347.

GLEN, H. W. Spotlight on the Council for Mineral Technology (Mintek). J. S.Afr. Inst. Min. Metall., vol. 8, no. 12. Dec. 1981. pp. 352-353.

LASCHINGER, J.E. Focus on vital role of the National Institute for Metallurgy. S.Afr. Engr, vol. 59, no. 602. Jul. 1968. pp. 24-29.

LASCHINGER, J.E. The National Institute for Metallurgy. S.Afr. Min. Engng, J., vol. 81. 24th Mar., 1969. pp. 279-287.

E4. Miscellaneous

/. Reports

No. Title Year

18 The 8th Commonwealth Mining and Metallurgical Congress — Australasia — 27th February to 15th April, 1965. Visits to various places in Australia and Tasmania 1966

66 The study of propagation modes effective in around-the-World radio-wave propagation in the 15-Mc/s to 30-Mc/s band 1966

1812 List of unrestricted NIM reports and papers published during the first decade of NIM's existence (1966 to 1975) [superseded by Report 1894] 1976

1894 List of unrestricted NIM publications issued from 1966 to 1977 [superseded by Report 1970] 1977

1970 List of unrestricted NIM publications issued from 1966 to 1978 [superseded by Report 2013] 1978

2013 List of unrestricted NIM publications issued from 1966 to 1979 [superseded by Report 2067] 1979

176 MINTEK PUBLICATIONS

No. Title Year

2067 List of unrestricted NIM publications issued from 1966 to 1980 [superseded by Report M8S] 1980

2130 The organizing of conferences 1981

Ml ICAM 81 1981

• M85 List of unrestricted Mintek publications issued from 1966 to 1982 [superseded by Special Publication 6] 1983

2. Papers

ALBERTS, L. Closing address. INFACON 80. PROCEEDINGS OF THE SECOND INTERNATIONAL FERRO-ALLOYS CONGRESS. Lausanne, Institut des Producteurs de Ferro- Alliages d'Europe Occidentals, 1981. pp. 436-443.

ALBERTS, L. Research management by objectives. J. S.Afr. last. Min. Metall., vol. 82, no. 6. Jun. 1982. pp. 157-159.

ALBERTS, L. Scientific and technological infrastructure in relation to the security of investments and mineral supplies. PROCEEDINGS, TWELFTH CONGRESS OF THE COUNCIL OF MINING AND METALLURGICAL INSTITUTIONS. Glen, H. W. (ed.). Johannesburg, The South African Institute of Mining and Metallurgy, 1982. vol. 2. pp. 665-671.

BATRA, K., SEE, J.B., and KING, T.B. Flow behaviour of liquid metals on solid substrates. Metal Sci., vol. 11, no. 5. May 1977. pp. 145-151.

BROOKES, H.C., and PAUL, R.L. Densities and excess volumes of fused halides. Z. Naturforsch., vol. 30a. 1975. pp. 64-68.

CLARKE, P.J. Mineral expansion — spotlight on research. Processing, vol. 1, no. 1. 1980. pp. 15-16,21.

ENGLISH, R.B., HAINES, R.J., and STEEN, N.D.C.T. Synthesis and molecular structure of [Rh4(^-PPh2)4(^-CO)2(CO)4J, an edge-bridged tetrahedral cluster of rhodium. S.Afr. J. Chem., vol. 3^, no. 3. 1981. pp. 88-89.

FINN, C.W.P. Spotlight on INFACON 80. J. S.Afr. Inst. Min. Metall., vol. 81, no. 5. May 1981. pp. 13c-138.

GLEN, H.W. Technical English — a 'dead' language. J. S.Afr. Inst. Min. Metall., vol. 79, no. 13. Aug. 1979. pp. 382-385.

GLEN, H.W. User attitudes to scientific editing: just change the was'% and were's. J. Res. Commun. Studies, vol. 3. 1981. pp. 221-227.

GLEN, H.W. (ed.). PROCEEDINGS, TWELFTH CONGRESS OF THE COUNCIL OF MINING AND METALLURGICAL INSTITUTIONS. Johannesburg, The South African Institute of Mining and Metallurgy, 1982. 2 vols., 1060 pp.

HAINES, R.J., and STEEN, N.D.C.T. Synthesis and molecular stucture of [Rh3(^-PPh2)3(/i-Cl)2(/i- CO)(CO)3], a unique triangular rhodium cluster derivative. J. Chem. Soc, Chem. Commun. 057. 1981. pp. 407-408.

177 MINTEK PUBLICATIONS

HA1NES, R.J., STEEN, N.D.C.T., and ENGLISH, R.B. Synthesis and molecular structure of [Rh3(/t-PPh2)3(CO,)], an edge-bridged triangular cluster of rhodium. J. Organometall. Chem., no. 209. 1981. pp. C34-C36.

HAINES, R.J., STEEN, N.D.T.C., and ENGLISH, R.B. Synthesis and X-ray crystal and molecular structure of [[RhFe(/i-PPh,)r(/i-CO)(CO),j2], an unusual tetranuclear compound with a straight-chain structure. J. Chem. Soc, Chem. Commun. 144. 1981. pp. 587-588.

HAINES, R.J., STEEN, N.D.C.T., LAING, M., and SOMMERVILLE, P. A non-closed tetranuclear metal cluster derivative of rhodium and iron: synthesis and molecular structures. J. Organometall. Chem., no. 198. 1980. pp. C72-C74.

JOCHENS, P.R. Technology transfer between a State-sponsored research institute and industry. PROCEEDINGS OF THE SYMPOSIUM ON TECHNOLOGY TRANSFER. South African Council for Scientific and Industrial Research. Pretoria, CSIR, 1974. pp. 38-52.

JOCHENS, P.R. The energy requirements of the mining and metallurgical industry in South Africa. J. S.Afr. Inst. Min. Metall., vol. 80, no. 9. Sep. 1980. pp. 331-343.

JOCHENS, P.R. Highlights of current metallurgical research and development in the South African precious-metals and ferro-alloy industries. CIMME Bull., vol. 25, no. 1. Mar. 1981. pp. 15-28.

JOCHENS, P.R. optimum versus maximum recovery of gold. J. S.Afr. Inst. Min. Metall., vol. 81, no. 7. Jul. 1981. pp. 229.

JOCHENS, P.R. Project management in the metallurgical industry. J. S.Afr. Inst. Min. Metall., vol. 81, no. 8. Aug. 1981. pp. 252, 254.

KNIGHT, A. Nuclear power reactors in Britain. S.Afr. Engr, vol. 57, no. 582. Nov. 1966. pp. 57-61.

NAKANI, B.S., and GIESEKKE, E.W. A study of lanthanide p-toluene sulphonic acid complexes in solution. Polyhedron, vol. 1, no. 3. 1982. pp. 253-256.

PAUL, R.L., and BROOKS, H.C. Energies of mixing of molten silver bromide-alkali bromide system. Inorg. Nucl. Chem. Lett., vol. 8, no. 7. 1972. pp. 629-631.

PAUL, R.L., and BROOKS, H.C. Binary silver bromide-alkali bromide melts. Calculated and measured energies of mixing. Inorg. Chem., vol. 13, no. 3. 1974. pp. 683-690.

PLUMMER, V. Computerized information systems and services. AN INTRODUCTORY COURSE FOR INFORMATION WORKERS. Pretoria, CSIR, 1979. pp. 91-108.

ROBINSON, R.E. The fifth James Moir memorial lecture. S.Afr. Chem. Process., Jun.-Jul. 1967. pp. CP72-CP84.

ROBINSON, R.E. The case for national research in mineral processing. J. S.Afr. Inst. Min. Metall., vol. 76, no. 3. Oct. 1975. pp. 196-213.

ROBINSON, R.E. Metallurgical problems in the utilization of South Africa's resources. RESOURCES OF Si 'HERN AFRICA TODAY AND TOMORROW. Baker, G. (ed.). Johannesburg, Associated Scientific and Technical Societies of Southern Africa, 1976. pp. 308-318. 4. Special Publications

1 Notebook of experiments in extractive metallurgy for high schools. 1975. 42 pp. [Out of print.]

• 3 A guide to the presentation of papers. Jul. 1983. (First printed 1979.) 19 pp.

• 5 A guide to the preparation of slides for technical presentations. 1983. 19 pp.

178 MINTEK PUBLICATIONS

8. PERIODICAL PUBLICATIONS

Copies of A from volume 8, number 4 (1376) onwards are available from Mintek, Private Bag X3015, Randburg, 2125 South Africa.

Copies of the latest issues of B and C are available from the above-mentioned address free of charge and on request.

A. Minerals Science and Engineering

This periodical was published quarterly from January 1969 to October 1980. It was a review journal devoted to the origin, occurrences, winning, properties, anil uses of minerals.

B. Annual Report

This is issued (in English and Afrikaans) and appears each year in March.

C. Mintek Research Digest

This leaflet contains summaries of some of the work being done and of the recently issued unrestricted reports. It is published approximately every two months.

179 MINTEK PUBLICATIONS

9. MISCELLANEOUS PUB'.ICATIONS

These publications, which are of an ephemeral nature, are not issued once they have lost their relevance. The publications listed here are available at present. Those which have been included since the last issue of this list (Report M85) are marked*.

Requests should be addressed to Mintek, Private Bag X3015, Randburg, 2125 South Africa.

A. General Brochure

• Mineral and process chemistry (18 pp.)

B. Careers Brochures

1. Careers at Mintek (22 pp.) 2. Loopbane by Mintek (22 pp.) [Afrikaans version of 1 above] • 3. A career in rnetallurgy/'n Loopbaan in metallurgie (4 pp.) • 4. Loopbaan-vooruitsigte/Career prospects (4 pp.)

180