Coke Oven Emissions from 1979-1983
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Petrographic and Vitrinite Reflectance Analyses of a Suite of High Volatile Bituminous Coal Samples from the United States and Venezuela
Petrographic and vitrinite reflectance analyses of a suite of high volatile bituminous coal samples from the United States and Venezuela Open-File Report 2008-1230 U.S. Department of the Interior U.S. Geological Survey U.S. Department of the Interior Dirk A. Kempthorne, Secretary U.S. Geological Survey Mark D. Myers, Director U.S. Geological Survey, Reston, Virginia 2008 For product and ordering information: World Wide Web: http://www.usgs.gov/pubprod Telephone: 1-888-ASK-USGS For more information on the USGS—the Federal source for science about the Earth, its natural and living resources, natural hazards, and the environment: World Wide Web: http://www.usgs.gov Telephone: 1-888-ASK-USGS Suggested citation: Hackley, P.C., Kolak, J.J., 2008, Petrographic and vitrinite reflectance analyses of a suite of high volatile bituminous coal samples from the United States and Venezuela: U.S. Geological Survey Open-File Report 2008-1230, 36 p., http://pubs.usgs.gov/of/2008/1230. Any use of trade, product, or firm names is for descriptive purposes only and does not imply endorsement by the U.S. Government. Although this report is in the public domain, permission must be secured from the individual copyright owners to reproduce any copyrighted material contained within this report. ii Contents Introduction ........................................................................................................................................................................1 Methods ..............................................................................................................................................................................1 -
An Empirical Study on Laboratory Coke Oven-Based Coal Blending for Coking with Tar Residue, Chemical Engineering Transactions, 71, 385-390 DOI:10.3303/CET1871065 386
385 A publication of CHEMICAL ENGINEERING TRANSACTIONS VOL. 71, 2018 The Italian Association of Chemical Engineering Online at www.aidic.it/cet Guest Editors: Xiantang Zhang, Songrong Qian, Jianmin Xu Copyright © 2018, AIDIC Servizi S.r.l. ISBN 978-88-95608-68-6; ISSN 2283-9216 DOI: 10.3303/CET1871065 An Empirical Study on Laboratory Coke Oven-based Coal Blending for Coking with Tar Residue Wenqiu Liu Hebei Energy College of Vocation and Technology, Tangshan 063004, China [email protected] Tar residue is the solid waste produced in coking plants or gas generators. Utilizing tar residue as additive in coal blending for coking is an effective approach for coal coking in our country, not only improving the yield and nature of coking products, but also realizing the recycling of tar residue. In this paper, tar residue is used as additive in coal blending for coking experiments, and combined with experiments on the crucible coke, small coke oven and industrial coke oven, the influences of the addition amount of tar residue on coke yield, coke reactivity and coke strength after reaction are further analyzed. As the experiment results reveal, compared to the experiment results of crucible coke and small coke ovens, the coke yield, coke reactivity and coke strength after reaction of industrial coke ovens are all bigger, leading to potential industrialization of coal blending for coking. Moreover, the influence of the amount of tar residue on the coal tar yield rate and gas yield is the same as that of coke reactivity and coke strength after reaction. 1. Introduction With the rapid development of economy, the fast growth of iron and steel industry has led China's coke industry to accomplish extraordinary achievements (Si et al., 2017). -
Update to the Developments of Hisarna an Ulcos Alternative Ironmaking Process Ir
Update to the Developments of Hisarna An Ulcos alternative ironmaking process Ir. Jan van der Stel , ir. Koen Meijer, ing. Cornelis Teerhuis, dr. Christiaan Zeijlstra, ir. Guus Keilman and ing. Maarten Ouwehand Tata Steel IJmuiden, The Netherlands Research, Development & Technology IEAGHG/IETS Iron and steel Industry CCUS and Process Integration Workshop Tokyo, Japan 4 – 7 November 2013 Confidential Content 1. HIsarna technology 2. HIsarna and CCS 3. HIsarna pilot plant 4. Campaign results 5. Conclusions 6. Forward plan 2 IEAGHG/IETS Iron and steel Industry CCUS and Process Integration Workshop , Tokyo, Japan, 4 – 7 November 2013. Confidential Ulcos IEAGHG/IETS Iron and steel Industry CCUS and Process Integration Workshop , Tokyo, Japan, 4 – 7 November 2013. Confidential 1. HIsarna technology Comparison with the BF route Blast furnace sinter Iron ore coke Liquid iron coal 4 IEAGHG/IETS Iron and steel Industry CCUS and Process Integration Workshop , Tokyo, Japan, 4 – 7 November 2013. Confidential 1. HIsarna technology Comparison with the BF route Blast furnace sinter Iron ore coke coal Direct use of coal and ore Liquid iron No coking and agglomeration 5 IEAGHG/IETS Iron and steel Industry CCUS and Process Integration Workshop , Tokyo, Japan, 4 – 7 November 2013. Confidential 1. HIsarna technology Top gas Oxygen Ore Oxygen Coal Slag Hot metal 6 IEAGHG/IETS Iron and steel Industry CCUS and Process Integration Workshop , Tokyo, Japan, 4 – 7 November 2013. Confidential 1.1. HIsarna technology Melting cyclone technology Melting and partial reduction of fine iron ores “2 Fe 2O3(s) + 2 CO(g) → 4 FeO(l) + 2 CO 2(g) ” • The cyclone product is a molten mixture of Fe 3O4 and FeO (~ 20 % reduced) • Pure oxygen is injected to generate the required melting temperature • The fines are separated from the gas by centrifugal flow of the gas IEAGHG/IETS Iron and steel Industry CCUS and Process Integration Workshop , Tokyo, Japan, 4 – 7 November 2013. -
Coal Characteristics
CCTR Indiana Center for Coal Technology Research COAL CHARACTERISTICS CCTR Basic Facts File # 8 Brian H. Bowen, Marty W. Irwin The Energy Center at Discovery Park Purdue University CCTR, Potter Center, 500 Central Drive West Lafayette, IN 47907-2022 http://www.purdue.edu/dp/energy/CCTR/ Email: [email protected] October 2008 1 Indiana Center for Coal Technology Research CCTR COAL FORMATION As geological processes apply pressure to peat over time, it is transformed successively into different types of coal Source: Kentucky Geological Survey http://images.google.com/imgres?imgurl=http://www.uky.edu/KGS/coal/images/peatcoal.gif&imgrefurl=http://www.uky.edu/KGS/coal/coalform.htm&h=354&w=579&sz= 20&hl=en&start=5&um=1&tbnid=NavOy9_5HD07pM:&tbnh=82&tbnw=134&prev=/images%3Fq%3Dcoal%2Bphotos%26svnum%3D10%26um%3D1%26hl%3Den%26sa%3DX 2 Indiana Center for Coal Technology Research CCTR COAL ANALYSIS Elemental analysis of coal gives empirical formulas such as: C137H97O9NS for Bituminous Coal C240H90O4NS for high-grade Anthracite Coal is divided into 4 ranks: (1) Anthracite (2) Bituminous (3) Sub-bituminous (4) Lignite Source: http://cc.msnscache.com/cache.aspx?q=4929705428518&lang=en-US&mkt=en-US&FORM=CVRE8 3 Indiana Center for Coal Technology Research CCTR BITUMINOUS COAL Bituminous Coal: Great pressure results in the creation of bituminous, or “soft” coal. This is the type most commonly used for electric power generation in the U.S. It has a higher heating value than either lignite or sub-bituminous, but less than that of anthracite. Bituminous coal -
Coal Tar Pitch – Its Past, Present and Future in Commercial Roofing by Joe Mellott
- 1 - Coal Tar Pitch – Its Past, Present and Future in Commercial Roofing By Joe Mellott Coal tar remains a desired and strong source of technology within the roofing industry, as innovative coal tar products significantly reduce associated health hazards and environmental impact. To help you better understand the role that coal tar continues to play in the commercial roofing market, this article will explore: • The history of coal tar • Its associated hazards • Hot and cold coal tar adhesive technologies • Modified coal tar pitch membrane technologies • Coal tar’s sustainability attributes A Brief History of Coal Tar In order to understand what coal tar pitch is, it’s important to understand its origins and refinement methods. Coal tar can be refined from a number of sources including coal, wood, peat, petroleum, and other organic materials. The tar is removed by burning or heating the base substance and selectively distilling fractions of the burned chemical. Distillation involves heating the substance to a point where different fractions of the substance become volatile. The fractions are then collected by condensing the fraction at a specific temperature. A base substance can be split into any number of fractions through distillation. A good example of industrial distillation is the oil refining process. Through distillation, crude oil can be separated into fractions that include gasoline, jet fuel, motor oil bases, and other specialty chemicals. Fractionation or distillation is a tried-and-true method for breaking a substance into different parts of its composition. One of the first uses of coal tar was in the maritime industry. Trees stumps were burned and the tar fractions were collected through distillation of the tar. -
Spherical Graphite Produced by Waste Semi-Coke with Enhanced Properties As
Electronic Supplementary Material (ESI) for Sustainable Energy & Fuels. This journal is © The Royal Society of Chemistry 2019 Spherical graphite produced by waste semi-coke with enhanced properties as anode material for Li-ion batteries Ming Shi, Zige Tai, Na Li, Kunyang Zou, Yuanzhen Chen, Junjie Sun, Yongning Liu* State Key Laboratory for Mechanical Behavior of Materials, School of Material Science and Engineering, Xi’an Jiaotong University, Xi’an 710049, PR China *Corresponding author E-mail address: [email protected] Fax: +86 29 8266 3453; Tel: +86 29 8266 4602 Fig. 1 N2 absorption/desorption profiles of (a) pristine semi-coke (SC); (b) synthetic graphite without Si (PG); and (c) synthetic graphite with 10% Si at 2300 °C (SG). Table 1 The percentage of impurity of pristine SC and SG (10% Si at 2300 °C). Content percentage / wt % samples B Si Al Ca Fe K Na Mg SC <0.1 4.25 5.5 3.3 0.8 0.3 0.09 <0.1 SG <0.1 1.01 1.9 0.1 <0.1 0.02 0.03 <0.1 Table 2 The SG capacity values with that of similar materials published in the literature. Materials Specific Capacity Rate capability Cyclic retention Ref. [mA h g-1] [mA h g-1] Spherical graphite produced 347.06 at 0.05C 329.8 at 0.1C; 317.4 at 97.7% at 0.5C after This by waste semi-coke 0.5 C and 262.3 at 1C 700 cycles work Iron‐catalyzed graphitic 306 at 0.1C 150 at rate of 2C Over 90 % after 200 1 materials from biomass cycles Carbonaceous composites 312 at 0.2C 149 at 1 C; 78 at 5C - 2 prepared by the mixture of graphite, cokes, and petroleum pitch. -
Lecture 32: Coke Production
NPTEL – Chemical – Chemical Technology II Lecture 32: Coke production 32.1 Introduction Coal is used as fuel for electric power generation, industrial heating and steam generation, domestic heating, rail roads and for coal processing. Coal composition is denoted by rank. Rank increases with the carbon content and decreases with increasing oxygen content. Many of the products made by hydrogenation, oxidation, hydrolysis or fluorination are important for industrial use. Stable, low cost, petroleum and natural gas supplies has arose interest in some of the coal products as upgraded fuels to reduce air pollution as well as to take advantage of greater ease of handling of the liquid or gaseous material and to utilize existing facilities such as pipelines and furnaces. 32.2 Coking of coal Raw material is Bituminous coal. It appears to have specific internal surfaces in the range of 30 to 100m2/g. Generally one ton of bituminous coal produces 1400 lb of coke. 10 gallons of tar. Chemical reaction:- 4(C3H4)n nC6H6 + 5nC + 3nH2 + nCH4 Coal Benzene Coke Lighter hydrocarbon Joint initiative of IITs and IISc – Funded by MHRD Page 1 of 9 NPTEL – Chemical – Chemical Technology II Process flow sheet: Illustrated in Figure. Figure 32.1 Flow sheet of coking of coal 32.3 Functional role of each unit (Figure 32.1): (a) Coal crusher and screening: At first Bituminous coal is crushed and screened to a certain size. Preheating of coal (at 150-250˚C) is done to reduce coking time without loss of coal quality. Briquetting increases strength of coke produced and to make non - coking or poorly coking coals to be used as metallurgical coke. -
Projectprofile
EPSILON CARBON PRIVATE LIMITED ECPL CoalTar Distillation -300,000tpa Karnataka ProjectProfile General TheEpsilon CarbonprivateLimited is aspiring to emergeasadynamiccompanyin India in the field of coal tar processing for manufacture ofvarious value added products. The proposed green-field Coal tar distillation plant coupledwith solidpitchmeltingunitisproposedtosetupwith Coal tar processing capacity of 300,000tpaat Toranagallu in Bellary district of Karnataka. Process Description: The coal tar are separated by distillation process. Coal tar containing several chemical compounds with major being Coal tar pitch,Naphthalene,Wash Oil, Light Oil, Phenol Oil & Anthracene oil. Following are major manufacturing of process & Products: 1. Coal Tar pitch (Binder Grade Pitch) 2. Zero QI /Impregnated Pitch 3. Naphthalene &Naphthalene sulfonate formaldehyde (NSF) 4. Oils- Carbon Black Oil (CBO) ,Light oil, Phenol oil, Wash oil , Anthracene oil By Products: 5. Sodium Phenolate 6. Ammonical water 1. Binder Grade Pitch: Soft Pitch from the bottom of pitch column is sent to pitch column for further processing to modified pitch to increase QI content and blended with required high QI pitch to produce binder grade pitch for aluminum industry. 2. Impregnated Pitch : Blending of coal tar and wash oil in specific ratio, dehydration up to 180℃ to separate moisture content in coal tar. The dehydrated mixture is transferred to settling tank for reduction of QI. (Settling tank provide draw-off valve for QI sampling). QI value less material transfer to further distillation (Removal of Oils) to produce Impregnated Pitch. Project Profile for 300,000 tpa Coal Tar Distillation plant EPSILON CARBON PRIVATE LIMITED ECPL CoalTar Distillation -300,000tpa Karnataka ProjectProfile 3. Carbon Black Oil(CBO): Blending of Soft Pitch from the bottom of pitch column and Anthracene oil in specific ratio with required specific gravity to produce carbon black oil for tyre industry. -
THE GUIDE to SOLID FUELS This Leaflet Will Tell You All You Need To
THE GUIDE TO SOLID FUELS This leaflet will tell you all you need to know about: • The different solid fuels available and their suitability for the various types of appliances • Smoke control legislation • Buying solid fuel • Hints on getting the best from your fuel and appliance Choice of Fuel There are a great many different solid fuels for sale. Your choice will be based on a number of criteria, the most important of which will be the type of appliance you will be burning the fuel on and whether or not you live in a smoke control area (see page 4). Fuels for open fires Housecoal The most traditional fuel for open fires is housecoal. It is available in various sizes e.g. Large Cobbles, Cobbles, Trebles and Doubles. The larger sizes are usually a little more expensive than Doubles size. Housecoal comes from mines in Britain and other parts of the world, most notably Columbia and Indonesia. The coal may be sold by the name of the colliery it comes from e.g. Daw Mill, the port of entry e.g. Merseyport or a merchant’s own brand name, e.g. Stirling. Coal merchants also frequently sell the coal by grade – 1, 2 and 3 or A, B and C; 1 and A being the best quality. Wood Wood and logs can be burnt on open fires. They should be well-seasoned and preferably have a low resin content. You should not use any wood that has any kind of coating on the surface e.g. varnish or paint, as harmful gases may be emitted on burning. -
A Life Cycle Analysis of Deploying Coking Technology to Utilize Low-Rank Coal in China
sustainability Article A Life Cycle Analysis of Deploying Coking Technology to Utilize Low-Rank Coal in China Yan Li 1, Guoshun Wang 1, Zhaohao Li 2, Jiahai Yuan 3 , Dan Gao 2,* and Heng Zhang 2 1 School of Business, Central South University, Changsha 410083, China; [email protected] (Y.L.); [email protected] (G.W.) 2 School of Energy, Power and Mechanical Engineering, North China Electric Power University, Beijing 102206, China; [email protected] (Z.L.); [email protected] (H.Z.) 3 School of Economics and Management, North China Electric Power University, Beijing 102206, China; [email protected] * Correspondence: [email protected] Received: 12 May 2020; Accepted: 10 June 2020; Published: 15 June 2020 Abstract: At present, the excess capacity in China’s coke industry can be deployed to utilize some low-rank coal, replacing coking coal with potential economic gains, energy efficiency, and environmental benefits. This study presents a life cycle analysis to model these potential benefits by comparing a metallurgical coke technical pathway with technical pathways of gasification coke integrated with different chemical productions. The results show that producing gasification coke is a feasible technical pathway for the transformation and development of the coke industry. However, its economic feasibility depends on the price of cokes and coals. The gasification coke production has higher energy consumption and CO2 emissions because of its lower coke yield. Generally speaking, using gasification coke to produce F-T oils has higher economic benefits than producing methanol, but has lower energy efficiency and higher carbon emissions. Keywords: coal coking; life cycle analysis; gasification coke; metallurgical coke; low-rank coal 1. -
Fuel Which May Not Be Burned in the Low Smoke Zone
Cork Low Smoke Fuel Zone Fuel which may not be burned in the low smoke zone Bituminous (Smoky) coal Often labelled “Polish”, “Columbian”, “Texan”, “Russian” or “House” coal. This is sometimes labelled “Premium” coal, but many low smoke brands also carry the “Premium” tag. If it doesn’t say “Low smoke” on the bag, don’t burn it in the low smoke zone. “Singles”, “Doubles” and “slack” are usually bituminous, and may not be burned, except for low smoke singles. Bituminous coal when burned emits many toxic substances, which have been linked to heart attack, stroke, cancer, asthma and many other heart and lung ailments. Timber effect sheeting or treated timber Scrap Chipboard (particle board), plywood, Oriented Strand Board (OSB), Medium Density Fibreboard (MDF), or any other material that has been made using glues, resins, etc. Chipboard (particle board) Plywood In addition to being harmful to the environment, these can release harmful substances into your home when burned. You should not burn broken furniture, or any other timber which has been treated with preservative, paint, varnish, lacquer or polish. These may not be burned in any domestic fire, Oriented Strand Board Medium Density Fibre in or outside the low smoke zone. (OSB) Board (MDF) Household waste Plastics, Tetra-paks, Styrofoam cartons and wrappers, polythene, etc. Burning of household waste has a detrimental effect on the environment inside and outside the home. It releases carcinogenic substances called dioxins. These may not be burned in any domestic fire, inside or outside the low smoke zone. Types of fuel which may be burned in the low smoke zone Anthracite A naturally low smoke, hard, shiny coal. -
High Quality Graphite Electrode Products
HIGH QUALITY GRAPHITE ELECTRODE PRODUCTS GrafTech International is a leading manufacturer of high quality graphite electrode products essential to the production of Electric Arc Furnace (or EAF) steel and other ferrous and non-ferrous metals. We have a broad portfolio of competitive graphite electrode manufacturing facilities, including three of the highest capacity facilities in the world. We are the only large scale graphite electrode producer that is substantially vertically integrated into petroleum needle coke, a key raw material for graphite electrode manufacturing. This unique position provides competitive advantages in product quality and cost. MAXIMIZING STEEL PRODUCTIVITY THROUGH TECHNOLOGY AND SERVICE LEADERSHIP Founded in 1886, we have over 130 years of experience in the research and development (or R&D) of graphite and carbon based solutions, and our intellectual property portfolio is extensive. We currently have graphite electrode manufacturing facilities in Calais, France, Pamplona, Spain, Monterrey, Mexico and St. Marys, Pennsylvania. Our customers include major steel producers and other ferrous and non ferrous metal producers in Europe, the Middle East and Africa (or EMEA), the Americas and Asia Pacific (or APAC), which sell their products into the automotive, construction, appliance, machinery, equipment and transportation industries. Our vision is to provide highly engineered graphite electrode services, solutions and products to EAF operators. Based on the high quality of our graphite electrodes, reliability of our petroleum needle coke supply and our excellent customer service, we believe that we are viewed as a preferred supplier by the global EAF steel producer market. GRAFTECH SERVICE AND SOLUTIONS We consider sustained customer satisfaction as a key measure of product and service performance.