minerals Article Mineralogy of Silicate-Natrophosphate Immiscible y Inclusion in Elga IIE Iron Meteorite Victor V. Sharygin 1,2 1 V.S. Sobolev Institute of Geology and Mineralogy, Siberian Branch of the RAS, 3 Acad. Koptyuga pr., 630090 Novosibirsk, Russia;
[email protected] 2 ExtraTerra Consortium, Institute of Physics and Technology, Ural Federal University, 19 Mira str., 620002 Ekaterinburg, Russia The paper was presented at the 81st Annual Meeting of the Meteoritical Society in Moscow, Russia, y 22–27 July 2018. Received: 7 April 2020; Accepted: 11 May 2020; Published: 13 May 2020 Abstract: Rare type of silicate inclusions found in the Elga iron meteorite (group IIE) has a very specific mineral composition and shows silicate ( 90%)–natrophosphate ( 10%) liquid ≈ ≈ immiscibility due to meniscus-like isolation of Na-Ca-Mg-Fe phosphates. The 3 mm wide immiscible inclusion has been first studied in detail using optical microscopy, scanning electron microscopy, electron microprobe analysis and Raman spectroscopy. The silicate part of the inclusion contains fine-grained quartz-feldspar aggregate and mafic minerals. The relationships of feldspars indicate solid decay of initially homogenous K-Na-feldspar into albite and K-feldspar with decreasing of temperature. Some mafic minerals in the silicate part are exotic in composition: the dominant phase is an obertiite-subgroup oxyamphibole (amphibole supergroup), varying from ferri-obertiite 3+ 2+ NaNa2Mg3Fe Ti[Si8O22]O2 to hypothetical NaNa2Mg3Fe 0.5Ti1.5[Si8O22]O2; minor phases are the aenigmatite-subgroup mineral (sapphirine supergroup) with composition close to median value 2+ of the Na2Fe 5TiSi6O18O2-Na2Mg5TiSi6O18O2 join, orthopyroxene (enstatite), clinopyroxene of the diopside Ca(Mg,Fe)Si2O6–kosmochlor NaCrSi2O6-Na(Mg,Fe)0.5Ti0.5Si2O6 series and chromite.