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Secondary Organic Aerosol from Chlorine-Initiated Oxidation of Isoprene Dongyu S
Secondary organic aerosol from chlorine-initiated oxidation of isoprene Dongyu S. Wang and Lea Hildebrandt Ruiz McKetta Department of Chemical Engineering, The University of Texas at Austin, Austin, TX 78756, USA 5 Correspondence to: Lea Hildebrandt Ruiz ([email protected]) Abstract. Recent studies have found concentrations of reactive chlorine species to be higher than expected, suggesting that atmospheric chlorine chemistry is more extensive than previously thought. Chlorine radicals can interact with HOx radicals and nitrogen oxides (NOx) to alter the oxidative capacity of the atmosphere. They are known to rapidly oxidize a wide range of volatile organic compounds (VOC) found in the atmosphere, yet little is known about secondary organic aerosol (SOA) 10 formation from chlorine-initiated photo-oxidation and its atmospheric implications. Environmental chamber experiments were carried out under low-NOx conditions with isoprene and chlorine as primary VOC and oxidant sources. Upon complete isoprene consumption, observed SOA yields ranged from 8 to 36 %, decreasing with extended photo-oxidation and SOA aging. Formation of particulate organochloride was observed. A High-Resolution Time-of-Flight Chemical Ionization Mass Spectrometer was used to determine the molecular composition of gas-phase species using iodide-water and hydronium-water 15 cluster ionization. Multi-generational chemistry was observed, including ions consistent with hydroperoxides, chloroalkyl hydroperoxides, isoprene-derived epoxydiol (IEPOX) and hypochlorous acid (HOCl), evident of secondary OH production and resulting chemistry from Cl-initiated reactions. This is the first reported study of SOA formation from chlorine-initiated oxidation of isoprene. Results suggest that tropospheric chlorine chemistry could contribute significantly to organic aerosol loading. -
Use of Chlorofluorocarbons in Hydrology : a Guidebook
USE OF CHLOROFLUOROCARBONS IN HYDROLOGY A Guidebook USE OF CHLOROFLUOROCARBONS IN HYDROLOGY A GUIDEBOOK 2005 Edition The following States are Members of the International Atomic Energy Agency: AFGHANISTAN GREECE PANAMA ALBANIA GUATEMALA PARAGUAY ALGERIA HAITI PERU ANGOLA HOLY SEE PHILIPPINES ARGENTINA HONDURAS POLAND ARMENIA HUNGARY PORTUGAL AUSTRALIA ICELAND QATAR AUSTRIA INDIA REPUBLIC OF MOLDOVA AZERBAIJAN INDONESIA ROMANIA BANGLADESH IRAN, ISLAMIC REPUBLIC OF RUSSIAN FEDERATION BELARUS IRAQ SAUDI ARABIA BELGIUM IRELAND SENEGAL BENIN ISRAEL SERBIA AND MONTENEGRO BOLIVIA ITALY SEYCHELLES BOSNIA AND HERZEGOVINA JAMAICA SIERRA LEONE BOTSWANA JAPAN BRAZIL JORDAN SINGAPORE BULGARIA KAZAKHSTAN SLOVAKIA BURKINA FASO KENYA SLOVENIA CAMEROON KOREA, REPUBLIC OF SOUTH AFRICA CANADA KUWAIT SPAIN CENTRAL AFRICAN KYRGYZSTAN SRI LANKA REPUBLIC LATVIA SUDAN CHAD LEBANON SWEDEN CHILE LIBERIA SWITZERLAND CHINA LIBYAN ARAB JAMAHIRIYA SYRIAN ARAB REPUBLIC COLOMBIA LIECHTENSTEIN TAJIKISTAN COSTA RICA LITHUANIA THAILAND CÔTE D’IVOIRE LUXEMBOURG THE FORMER YUGOSLAV CROATIA MADAGASCAR REPUBLIC OF MACEDONIA CUBA MALAYSIA TUNISIA CYPRUS MALI TURKEY CZECH REPUBLIC MALTA UGANDA DEMOCRATIC REPUBLIC MARSHALL ISLANDS UKRAINE OF THE CONGO MAURITANIA UNITED ARAB EMIRATES DENMARK MAURITIUS UNITED KINGDOM OF DOMINICAN REPUBLIC MEXICO GREAT BRITAIN AND ECUADOR MONACO NORTHERN IRELAND EGYPT MONGOLIA UNITED REPUBLIC EL SALVADOR MOROCCO ERITREA MYANMAR OF TANZANIA ESTONIA NAMIBIA UNITED STATES OF AMERICA ETHIOPIA NETHERLANDS URUGUAY FINLAND NEW ZEALAND UZBEKISTAN FRANCE NICARAGUA VENEZUELA GABON NIGER VIETNAM GEORGIA NIGERIA YEMEN GERMANY NORWAY ZAMBIA GHANA PAKISTAN ZIMBABWE The Agency’s Statute was approved on 23 October 1956 by the Conference on the Statute of the IAEA held at United Nations Headquarters, New York; it entered into force on 29 July 1957. The Headquarters of the Agency are situated in Vienna. -
CHAPTER12 Atmospheric Degradation of Halocarbon Substitutes
CHAPTER12 AtmosphericDegradation of Halocarbon Substitutes Lead Author: R.A. Cox Co-authors: R. Atkinson G.K. Moortgat A.R. Ravishankara H.W. Sidebottom Contributors: G.D. Hayman C. Howard M. Kanakidou S .A. Penkett J. Rodriguez S. Solomon 0. Wild CHAPTER 12 ATMOSPHERIC DEGRADATION OF HALOCARBON SUBSTITUTES Contents SCIENTIFIC SUMMARY ......................................................................................................................................... 12.1 12.1 BACKGROUND ............................................................................................................................................... 12.3 12.2 ATMOSPHERIC LIFETIMES OF HFCS AND HCFCS ................................................................................. 12.3 12.2. 1 Tropospheric Loss Processes .............................................................................................................. 12.3 12.2.2 Stratospheric Loss Processes .............................................................................................................. 12.4 12.3 ATMOSPHERIC LIFETIMES OF OTHER CFC AND HALON SUBSTITUTES ......................................... 12.4 12.4 ATMOSPHERIC DEGRADATION OF SUBSTITUTES ................................................................................ 12.5 12.5 GAS PHASE DEGRADATION CHEMISTRY OF SUBSTITUTES .............................................................. 12.6 12.5.1 Reaction with NO .............................................................................................................................. -
Carbon Offset Impact Report 2019
Carbon Offset Impact Report 2019 Light for the World This document provides details on the social and community impacts linked to Light for the World’s carbon offsetting activity during 2019 May 2019 About CO2balance UK Ltd Established in 2003, CO2balance UK Ltd is a project developer of high impact, community focused, environmental projects that deliver quantifiable results data that aligns with corporate sustainable reporting indicators. Primarily African based, projects include bespoke CSR and Gold Standard carbon offset projects that provide social, health and community impacts. BACKGROUND This report is an Impact Report based on Light for the World’s carbon offsetting activity that was carried out during 2019. This was achieved through Light for the World working with CO2balance (project developer) and supporting its Uganda Borehole Rehabilitation project. The report outlines the positive impacts on the local communities in Uganda thanks to this offset activity. OVERVIEW • Reporting period covered – 2019 • Tonnes of carbon dioxide (CO2e) – 1,000 • Offset project supported – Uganda Borehole Rehabilitation Project CARBON OFFSET PROJECT – UGANDA BOREHOLE PROJECT The project is based around the rehabilitation of boreholes in Northern Uganda, supplying families with fresh clean water. As well as the natural health benefits, it means that families no longer have to boil the water, saving firewood and thereby preventing carbon emissions from being released. Access to safe drinking water is a serious issue in Africa effecting the health and well-being of local communities. A survey by the International Institute for Environment and Development (2009) revealed that there are an estimated 50,000 defective water supply installations (IIED 2009). -
Verification Program Manual and Mexico
SHARE: Join Our Email List CLIMATE ACTION NEWS December 2020 A note from our President Greetings, The climate community is hopeful and excited for a new era of climate policy, action, and diplomacy. The incoming Administration has already indicated a serious commitment to addressing the climate crisis, with key appointments and statements portending well for the future of U.S. climate action on the federal level. We are excited for the U.S. to not only rejoin the Paris Agreement, but to provide the example, the innovation, and the thought-leadership to achieve GHG reductions at the scale and urgency required. The Reserve is working to support and inform international efforts to scale up, mobilize, and strengthen the effectiveness of voluntary carbon markets across the globe. Even though COP has been postponed this year, experts around the world continue to discuss and deliberate critical issues to help craft key underlying decisions on how markets should function, how to apply usage of carbon offsets, and how to ensure the environmental integrity and financial value of offset projects and credits. In addition to participating in international discussions, the Reserve is working to expand our work in Mexico. We are updating the Mexico Ozone Depleting Substances Protocol to add several halocarbons, which are refrigerants with high global warming potentials. We are also continuing to work with communities and organizations across Mexico with outreach and education on implementing forest carbon projects, as well as drafting agricultural offset protocols for consideration by the Mexican Government. Thank you again for your climate action and leadership throughout the year. -
Research on Ocean Acidification at the University of Malaya
ADVANCINGResearch SUSTAINABLE on DEVELOPMENTOcean A INcidification LMEs DURING CLIMATE at theCHANGE University of Malaya Emienour Muzalina Mustafa, Choon-Weng Lee & Siew-Moi Phang Institute of Ocean & Earth Sciences, University of Malaya, Kuala Lumpur, Malaysia OCEANS IN A CHANGING CLIMATE OCEAN ↑ CO 2 ACIDIFICATION HUMAN IMPACTS: OCEAN MARINE POLLUTION WARMING BIOTA EUTROPHICATION OVERFISHING OCEAN DE- OXYGENATION Fig. 5. The palaeohistorical record of ocean pH demonstrates that present levels are unseen in the last 20 million years (Turley et al., 2006). Fig. 1. Projected regional changes in ocean chemistry likely to be experienced by particularly vulnerable ecosystems and compared to global-scale surface ocean changes. Global ocean surface averages (bottom) are shown, from left to right: CO2 partial pressure, pH(SWS) and calcite and aragonite saturation. Editorial, Marine Pollution Bulletin 60(2010): 787-792 Fig. 2. Photos of representatives of calcifying groups thought to be vulnerable to ocean acidification from top left to bottom right: pteropod (Jeremy Young, NHM), benthic foraminifer (James Rae, UBristol), coccolithophore (Jeremy Young, NHM), blue mussel (Frédéric Gazeau, Villefranche), sea urchin (Helen Findlay, PML), brittlestar (Sam Dupont, UGothenburg), tropical coral (Malcolm Shick, UMaine), coralline algae (Armin Form, IFM-GEOMAR), cold water coral (Karen Hissmann, IFM-GEOMAR). COMMERCIAL SPECIES IN ASIA THAT MAY BE IMPACTED BY OCEAN ACIDIFICATION Climate change and the oceans – What does the future hold? Jelle Bijma a,⇑, Hans-O. Pörtner a, Chris Yesson b, Alex D. Rogers Marine Pollution Bulletin 74 (2013) 495–505 Atmospheric pCO2 levels (ppmv CO2) that would be required to cause pH changes in Change in diversity as a function of ocean surface waters pH reduction for organisms living near the Ischia CO2 vents. -
The Need for Fast Near-Term Climate Mitigation to Slow Feedbacks and Tipping Points
The Need for Fast Near-Term Climate Mitigation to Slow Feedbacks and Tipping Points Critical Role of Short-lived Super Climate Pollutants in the Climate Emergency Background Note DRAFT: 27 September 2021 Institute for Governance Center for Human Rights and & Sustainable Development (IGSD) Environment (CHRE/CEDHA) Lead authors Durwood Zaelke, Romina Picolotti, Kristin Campbell, & Gabrielle Dreyfus Contributing authors Trina Thorbjornsen, Laura Bloomer, Blake Hite, Kiran Ghosh, & Daniel Taillant Acknowledgements We thank readers for comments that have allowed us to continue to update and improve this note. About the Institute for Governance & About the Center for Human Rights and Sustainable Development (IGSD) Environment (CHRE/CEDHA) IGSD’s mission is to promote just and Originally founded in 1999 in Argentina, the sustainable societies and to protect the Center for Human Rights and Environment environment by advancing the understanding, (CHRE or CEDHA by its Spanish acronym) development, and implementation of effective aims to build a more harmonious relationship and accountable systems of governance for between the environment and people. Its work sustainable development. centers on promoting greater access to justice and to guarantee human rights for victims of As part of its work, IGSD is pursuing “fast- environmental degradation, or due to the non- action” climate mitigation strategies that will sustainable management of natural resources, result in significant reductions of climate and to prevent future violations. To this end, emissions to limit temperature increase and other CHRE fosters the creation of public policy that climate impacts in the near-term. The focus is on promotes inclusive socially and environmentally strategies to reduce non-CO2 climate pollutants, sustainable development, through community protect sinks, and enhance urban albedo with participation, public interest litigation, smart surfaces, as a complement to cuts in CO2. -
Carbon Offset Impact Report - April 18
Carbon Offset Impact Report - April 18 [email protected] t. 01257 255 771 www.ikogroup.co.uk R E FO BR D IT A I S M BITUMINOUS MEMBRANES | COLD APPLIED LIQUIDS | HOT MELT H H T S R MASTIC ASPHALT | SINGLE-PLY | PITCHED ROOF SYSTEMS I A T I D R E INSULATION | STRUCTURAL WATERPROOFING & COMPOUNDS B IKO is a truly Global enterprise, with over 130 years of history, knowledge and innovation, distributing products to 96 countries around the globe with manufacturing plants in Canada, United States, United Kingdom, Belgium, Holland, France and Slovakia. The IKO Group IKO continues to remain committed to its family values of entrepreneurial spirit, craftsmanship and innovation in roofing, waterproofing and insulation that were the foundation of the business envisioned by IKO founder, Israel Koschitzky. Our Values INTEGRITY There are 6 main IKO Values that are core to the business SHARING KNOWLEDGE LONG-TERM (Sharing Knowledge, Integrity, Long-Term, Performance, AGILITY Humility and Agility), helping define IKO’s history and VALUES provide the blueprint for what IKO can achieve both today HUMILITY and in the future. PERFORMANCE www.ikogroup.co.uk/about-iko/iko-values IKO in the UK The IKO UK Group, comprising IKO PLC and IKO Polymeric, was established in 2000 and has grown both organically and through the successful acquisition and integration of well known, reputable brands including Ruberoid, Permanite, Marley Waterproofing, Hyload and Pure Asphalt. IKO PLC continues to grow within the traditional roofing and waterproofing industry as well as a number of different markets including PIR insulation and mastic asphalt solutions for highways and civil engineering projects. -
Halocarbon Scenarios, Ozone Depletion Potentials, and Global Warming Potentials
CHAPTER 8 Halocarbon Scenarios, Ozone Depletion Potentials, and Global Warming Potentials Lead Authors: J.S. Daniel G.J.M. Velders Coauthors: A.R. Douglass P.M.D. Forster D.A. Hauglustaine I.S.A. Isaksen L.J.M. Kuijpers A. McCulloch T.J. Wallington Contributors: P. Ashford S.A. Montzka P.A. Newman D.W. Waugh Final Release: February 2007 From Scientific Assessment of Ozone Depletion: 2006 CHAPTER 8 HALOCARBON SCENARIOS, OZONE DEPLETION POTENTIALS, AND GLOBAL WARMING POTENTIALS Contents SCIENTIFIC SUMMARY . 8.1 8.1 INTRODUCTION . 8.5 8.2 HALOCARBON LIFETIMES, OZONE DEPLETION POTENTIALS, AND GLOBAL WARMING POTENTIALS . 8.5 8.2.1 Introduction . 8.5 8.2.2 Ozone Depletion Potentials . 8.5 8.2.2.1 Atmospheric Lifetimes . 8.6 8.2.2.2 Fractional Release Factors . 8.6 8.2.2.3 Ozone Destruction Effectiveness . 8.7 8.2.2.4 ODP Values . 8.8 8.2.3 Direct Global Warming Potentials . 8.8 8.2.4 Degradation Products and Their Implications for ODPs and GWPs . 8.13 8.3 FUTURE HALOCARBON SOURCE GAS CONCENTRATIONS . .8.13 8.3.1 Introduction . 8.13 8.3.2 Baseline Scenario (A1) . 8.15 8.3.2.1 Emissions . 8.15 8.3.2.2 Mixing Ratios . 8.21 8.3.2.3 Equivalent Effective Stratospheric Chlorine . 8.25 8.3.3 Alternative Projections . 8.28 8.3.3.1 Emissions . 8.28 8.3.3.2 Mixing Ratios . 8.28 8.3.3.3 Equivalent Effective Stratospheric Chlorine . 8.30 8.3.4 Uncertainties in ODS Projections . 8.32 8.4 OTHER PROCESSES RELEVANT TO FUTURE OZONE EVOLUTION . -
An Algorithm to Detect Non-Background Signals in Greenhouse Gas Time Series from European Tall Tower and Mountain Stations
https://doi.org/10.5194/amt-2021-16 Preprint. Discussion started: 9 March 2021 c Author(s) 2021. CC BY 4.0 License. An algorithm to detect non-background signals in greenhouse gas time series from European tall tower and mountain stations Alex Resovsky1, Michel Ramonet1, Leonard Rivier1, Jerome Tarniewicz1, Philippe Ciais1, Martin 5 Steinbacher2, Ivan Mammarella3, Meelis Mölder4, Michal Heliasz4, Dagmar Kubistin5, Matthias Lindauer5, Jennifer Müller-Williams5, Sebastien Conil6, Richard Engelen7 1Laboratoire des Sciences du Climat et de l’Environnement, LSCE/IPSL, CEA-CNRS-UVSQ, Université Paris-Saclay, 91191 Gif-sur-Yvette, France 2Empa, Laboratory for Air Pollution/Environmental Technology, CH-8600 Duebendorf, Switzerland 10 3Institute for Atmospheric and Earth System Research/ Physics, University of Helsinki, Helsinki, Finland 4Lund University, 22100 Lund, Sweden 5Deutscher Wetterdienst, Meteorological Observatory Hohenpeissenberg, 82383 Hohenpeissenberg, Germany 6DRD/OPE, Andra, Bure, 55290, France 7European Center for Medium-Range Weather Forecasts, Shinfield Park, Reading, UK 15 Correspondence to: Alex Resovsky ([email protected]) Abstract. We present a statistical framework for near real-time signal processing to identify regional signals in CO2 time series recorded at stations which are normally uninfluenced by local processes. A curve-fitting function is first applied to the de- trended time series to derive a harmonic describing the annual CO2 cycle. We then combine a polynomial fit to the data with a short-term residual filter to estimate the smoothed cycle and define a seasonally-adjusted noise component, equal to two 20 standard deviations of the smoothed cycle about the annual cycle. Spikes in the smoothed daily data which rise above this 2σ threshold are classified as anomalies. -
Ocean Acidification Due to Increasing Atmospheric Carbon Dioxide
Ocean acidification due to increasing atmospheric carbon dioxide Policy document 12/05 June 2005 ISBN 0 85403 617 2 This report can be found at www.royalsoc.ac.uk ISBN 0 85403 617 2 © The Royal Society 2005 Requests to reproduce all or part of this document should be submitted to: Science Policy Section The Royal Society 6-9 Carlton House Terrace London SW1Y 5AG email [email protected] Copy edited and typeset by The Clyvedon Press Ltd, Cardiff, UK ii | June 2005 | The Royal Society Ocean acidification due to increasing atmospheric carbon dioxide Ocean acidification due to increasing atmospheric carbon dioxide Contents Page Summary vi 1 Introduction 1 1.1 Background to the report 1 1.2 The oceans and carbon dioxide: acidification 1 1.3 Acidification and the surface oceans 2 1.4 Ocean life and acidification 2 1.5 Interaction with the Earth systems 2 1.6 Adaptation to and mitigation of ocean acidification 2 1.7 Artificial deep ocean storage of carbon dioxide 3 1.8 Conduct of the study 3 2 Effects of atmospheric CO2 enhancement on ocean chemistry 5 2.1 Introduction 5 2.2 The impact of increasing CO2 on the chemistry of ocean waters 5 2.2.1 The oceans and the carbon cycle 5 2.2.2 The oceans and carbon dioxide 6 2.2.3 The oceans as a carbonate buffer 6 2.3 Natural variation in pH of the oceans 6 2.4 Factors affecting CO2 uptake by the oceans 7 2.5 How oceans have responded to changes in atmospheric CO2 in the past 7 2.6 Change in ocean chemistry due to increases in atmospheric CO2 from human activities 9 2.6.1 Change to the oceans -
Taskforce on Scaling Voluntary Carbon Markets: Consultation Document
NOVEMBER 2020 TASKFORCE ON SCALING VOLUNTARY CARBON MARKETS CONSULTATION DOCUMENT REPORT FRONT-PIECE ABOUT THE TASKFORCE The Taskforce on Scaling Voluntary Carbon Markets is a private sector-led initiative working to scale an effective and efficient voluntary carbon market to help meet the goals of the Paris Agreement. The Taskforce was initiated by Mark Carney, UN Special Envoy for Climate Action and Finance Advisor to UK Prime Minister Boris Johnson for the 26th UN Climate Change Conference of the Parties (COP26); is chaired by Bill Winters, Group Chief Executive, Standard Chartered; and sponsored by the Institute of International Finance (IIF) under the leadership of IIF President and CEO, Tim Adams. Annette Nazareth, a partner at Davis Polk and former Commissioner of the US Securities and Exchange Commission, serves as the Operating Lead for the Taskforce. McKinsey & Company provides knowledge and advisory support. The Taskforce’s more than 50 members represent buyers and sellers of carbon credits, standard setters, the financial sector and market infrastructure providers. The Taskforce’s unique value proposition has been to bring all parts of the value chain to work intensively together and to provide recommended actions for the most pressing pain-points facing voluntary carbon markets. The Taskforce is also supported by a highly engaged Consultation Group, composed of subject- matter experts from more than 80 institutions, who contribute additional perspective to the recommendations. ABOUT THE REPORT This report was developed by the Taskforce on Scaling Voluntary Carbon Markets, drawing on multiple sources, including a research collaboration with McKinsey & Company, which is providing knowledge and advisory support to the IIF.