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ICP-MS Multi-Element Standard Solution VI Safety data sheet according to Regulation (EC) No. 1907/2006 (REACH) ICP-MS Multi-Element Standard Solution VI 30 Elemente in 2 %iger Salpetersäure article number: 1L4K date of compilation: 08.07.2021 Version: 1.0 en SECTION 1: Identification of the substance/mixture and of the company/ undertaking 1.1 Product identifier Identification of the substance ICP-MS Multi-Element Standard Solution VI 30 Elemente in 2 %iger Salpetersäure Article number 1L4K Registration number (REACH) not relevant (mixture) 1.2 Relevant identified uses of the substance or mixture and uses advised against Relevant identified uses: Laboratory chemical Laboratory and analytical use Uses advised against: Do not use for products which come into contact with foodstuffs. Do not use for private purposes (household). 1.3 Details of the supplier of the safety data sheet Carl Roth GmbH + Co KG Schoemperlenstr. 3-5 D-76185 Karlsruhe Germany Telephone:+49 (0) 721 - 56 06 0 Telefax: +49 (0) 721 - 56 06 149 e-mail: [email protected] Website: www.carlroth.de Competent person responsible for the safety data :Department Health, Safety and Environment sheet: e-mail (competent person): [email protected] 1.4 Emergency telephone number SECTION 2: Hazards identification 2.1 Classification of the substance or mixture Classification according to Regulation (EC) No 1272/2008 (CLP) Section Hazard class Cat- Hazard class and Hazard egory category statement 2.16 Substance or mixture corrosive to metals 1 Met. Corr. 1 H290 3.2 Skin corrosion/irritation 2 Skin Irrit. 2 H315 3.3 Serious eye damage/eye irritation 2 Eye Irrit. 2 H319 3.6 Carcinogenicity 1B Carc. 1B H350 Supplemental hazard information Code Supplemental hazard information EUH208 contains Beryllium nitrate, nickel dinitrate. May produce an allergic reaction Malta (en) Page 1 / 22 Safety data sheet according to Regulation (EC) No. 1907/2006 (REACH) ICP-MS Multi-Element Standard Solution VI 30 Elemente in 2 %iger Salpetersäure article number: 1L4K For full text of abbreviations: see SECTION 16 2.2 Label elements Labelling according to Regulation (EC) No 1272/2008 (CLP) Signal word Danger Pictograms GHS05, GHS08 Hazard statements H290 May be corrosive to metals H315 Causes skin irritation H319 Causes serious eye irritation H350 May cause cancer Precautionary statements Precautionary statements - prevention P280 Wear protective gloves/eye protection Precautionary statements - response P302+P352 IF ON SKIN: Wash with plenty of water P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing For professional users only Supplemental hazard information EUH208 Contains Beryllium nitrate, nickel dinitrate. May produce an allergic reaction. Hazardous ingredients for labelling: Beryllium nitrate Labelling of packages where the contents do not exceed 125 ml Signal word: Danger Symbol(s) H350 May cause cancer. P280 Wear protective gloves/eye protection. EUH208 Contains Beryllium nitrate, nickel dinitrate. May produce an allergic reaction. contains: Beryllium nitrate Malta (en) Page 2 / 22 Safety data sheet according to Regulation (EC) No. 1907/2006 (REACH) ICP-MS Multi-Element Standard Solution VI 30 Elemente in 2 %iger Salpetersäure article number: 1L4K 2.3 Other hazards Results of PBT and vPvB assessment This mixture does not contain any substances that are assessed to be a PBT or a vPvB. SECTION 3: Composition/information on ingredients 3.1 Substances not relevant (mixture) 3.2 Mixtures Description of the mixture Name of sub- Identifier Wt% Classification acc. to Pictograms Notes stance GHS Nitric acid ...% CAS No 2 Ox. Liq. 2 / H272 B(a) 7697-37-2 Met. Corr. 1 / H290 GHS-HC Acute Tox. 3 / H331 IOELV EC No Skin Corr. 1A / H314 231-714-2 Eye Dam. 1 / H318 EUH071 Index No 007-004-00-1 REACH Reg. No 01-2119487297- 23-xxxx Beryllium nitrate CAS No 0,147 Acute Tox. 3 / H301 A(a) 13597-99-4 Acute Tox. 2 / H330 GHS-HC Skin Irrit. 2 / H315 IOELV EC No Eye Irrit. 2 / H319 237-062-5 Skin Sens. 1 / H317 Carc. 1B / H350i Index No STOT SE 3 / H335 004-002-00-2 STOT RE 1 / H372 Aquatic Chronic 2 / H411 nickel dinitrate CAS No 0,0031 Ox. Sol. 2 / H272 GHS-HC 13138-45-9 Acute Tox. 4 / H302 Acute Tox. 4 / H332 EC No Skin Irrit. 2 / H315 236-068-5 Eye Dam. 1 / H318 Resp. Sens. 1 / H334 Index No Skin Sens. 1 / H317 028-012-00-1 Muta. 2 / H341 Carc. 1A / H350i Repr. 1B / H360D STOT RE 1 / H372 Aquatic Acute 1 / H400 Aquatic Chronic 1 / H410 Silver nitrate CAS No 0,0016 Ox. Sol. 2 / H272 GHS-HC 7761-88-8 Met. Corr. 1 / H290 Skin Corr. 1B / H314 EC No Aquatic Acute 1 / H400 231-853-9 Aquatic Chronic 1 / H410 Index No 047-001-00-2 REACH Reg. No 01-2119513705- 43-xxxx Notes A(a): The name of substance is a general description. It is required that the correct name is stated on the label B(a): The classification refers to an aqueous solution Malta (en) Page 3 / 22 Safety data sheet according to Regulation (EC) No. 1907/2006 (REACH) ICP-MS Multi-Element Standard Solution VI 30 Elemente in 2 %iger Salpetersäure article number: 1L4K Notes GHS-HC: Harmonised classification (the classification of the substance corresponds to the entry in the list according to 1272/ 2008/EC, Annex VI) IOELV: Substance with a community indicative occupational exposure limit value Name of sub- Identifier Specific Conc. Limits M-Factors ATE Exposure stance route mg Nitric acid ...% CAS No Ox. Liq. 2; H272: C ≥ 99 % - >2,65 /l/4h inhalation: va- 7697-37-2 Ox. Liq. 3; H272: 65 % ≤ C < 99 % pour Skin Corr. 1A; H314: C ≥ 20 % EC No Skin Corr. 1B; H314: 5 % ≤ C < 20 % 231-714-2 Skin Irrit. 2; H315: 1 % ≤ C < 5 % Eye Dam. 1; H318: C ≥ 3 % Index No Eye Irrit. 2; H319: 1 % ≤ C < 3 % 007-004-00-1 mg Beryllium nitrate CAS No - - 100 /kg oral 13597-99-4 EC No 237-062-5 Index No 004-002-00-2 mg nickel dinitrate CAS No Skin Irrit. 2; H315: C ≥ 20 % - 1.620 /kg oral mg 13138-45-9 Skin Sens. 1; H317: C ≥ 0,01 % 1,5 /l/4h inhalation: dust/ STOT RE 1; H372: C ≥ 1 % mist EC No STOT RE 2; H373: 0,1 % ≤ C < 1 % 236-068-5 Index No 028-012-00-1 Silver nitrate CAS No - M-factor - 7761-88-8 (acute) = 100.0 EC No M-factor 231-853-9 (chronic) = 100.0 Index No 047-001-00-2 For full text of abbreviations: see SECTION 16 SECTION 4: First aid measures 4.1 Description of first aid measures General notes Take off contaminated clothing. Following inhalation Provide fresh air. In all cases of doubt, or when symptoms persist, seek medical advice. Following skin contact Rinse skin with water/shower. In case of skin irritation, consult a physician. Malta (en) Page 4 / 22 Safety data sheet according to Regulation (EC) No. 1907/2006 (REACH) ICP-MS Multi-Element Standard Solution VI 30 Elemente in 2 %iger Salpetersäure article number: 1L4K Following eye contact Irrigate copiously with clean, fresh water for at least 10 minutes, holding the eyelids apart. In case of eye irritation consult an ophthalmologist. Following ingestion In case of accident or unwellness, seek medical advice immediately (show directions for use or safety data sheet if possible). 4.2 Most important symptoms and effects, both acute and delayed Irritation, Dyspnoea, Corrosivity, Risk of blindness, Gastric perforation, Risk of serious damage to eyes, Allergic reactions 4.3 Indication of any immediate medical attention and special treatment needed none SECTION 5: Firefighting measures 5.1 Extinguishing media Suitable extinguishing media co-ordinate firefighting measures to the fire surroundings water spray, alcohol resistant foam, dry extinguishing powder, BC-powder, carbon dioxide (CO₂) Unsuitable extinguishing media water jet 5.2 Special hazards arising from the substance or mixture Non-combustible. Hazardous combustion products In case of fire may be liberated: Nitrogen oxides (NOx) 5.3 Advice for firefighters In case of fire and/or explosion do not breathe fumes. Fight fire with normal precautions from a reas- onable distance. Wear self-contained breathing apparatus. SECTION 6: Accidental release measures 6.1 Personal precautions, protective equipment and emergency procedures For non-emergency personnel Avoid contact with skin, eyes and clothes. Do not breathe vapour/spray. 6.2 Environmental precautions Keep away from drains, surface and ground water. Malta (en) Page 5 / 22 Safety data sheet according to Regulation (EC) No. 1907/2006 (REACH) ICP-MS Multi-Element Standard Solution VI 30 Elemente in 2 %iger Salpetersäure article number: 1L4K 6.3 Methods and material for containment and cleaning up Advice on how to contain a spill Covering of drains. Advice on how to clean up a spill Absorb with liquid-binding material (sand, diatomaceous earth, acid- or universal binding agents). Other information relating to spills and releases Place in appropriate containers for disposal. Ventilate affected area. 6.4 Reference to other sections Hazardous combustion products: see section 5. Personal protective equipment: see section 8. Incom- patible materials: see section 10. Disposal considerations: see section 13. SECTION 7: Handling and storage 7.1 Precautions for safe handling Avoid exposure. Advice on general occupational hygiene Wash hands before breaks and after work. Keep away from food, drink and animal feedingstuffs. 7.2 Conditions for safe storage, including any incompatibilities Keep container tightly closed. Incompatible substances or mixtures Observe hints for combined storage. Consideration of other advice: Specific designs for storage rooms or vessels Recommended storage temperature: 15 – 25 °C 7.3 Specific end use(s) No information available.
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