45th Lunar and Planetary Science Conference (2014) 2080.pdf DEUTERIUM/HYDROGEN RATIO MEASUREMENTS WITH LASER-INDUCED BREAKDOWN SPECTROSCOPY (LIBS). K. Ishibashi1, S. Kameda2, K. Kurosawa1, M. Kobayashi1, T. Arai1, S. Ohno1, K. Wa- da1, H. Senshu1, N. Namiki1, T. Matsui1, 1Planetary Exploration Research Center, Chiba Institute of Technology, 2- 17-1 Tsudanuma, Narashino, Chiba, Japan,
[email protected], 2Col. of Sci., Rikkyo Univ., 3-34-1 Nishi-Ikebukuro, Toshima-ku, Tokyo, Japan. Introduction: The deuterium/hydrogen ratio (D/H trometer at 656 nm is ~0.017 nm, which is high ratio) yields important information on origin and geo- enough to separate the centers of Hα and Dα emission logic history of the fluid, and fluid-rock interactions. line peaks. Spectra from fifty laser pulses were accu- In-situ measurement of D/H ratio is quite useful in mulated on each experimental run. The ambient pres- planetary explorations. sures of 1.0×105, 1.0×103 and 1.5×10-1 Pa and the laser We examine the possibility of measuring the D/H pulse energies of 100 and 200 mJ were tested. ratio with laser-induced breakdown spectroscopy Results and discussions: The examples of ac- (LIBS). LIBS is a rapid and convenient chemical anal- quired spectra are shown in Figures 1 to 5. In these ysis method, which is suitable for in-situ measure- plots the spectra are normalized by the Hα peak ments [e.g., 1]. Pulsed laser irradiation creates small heights. Figures 1, 2, and 3 are the spectra from 655.5 plasma on the sample surface, and the emission form to 657.0 nm for the 0/100-, 10/90-, and 50/50-D/H the plasma is observed spectroscopically [e.g., 2].