Draft Scope of the Risk Evaluation for Triphenyl Phosphate CASRN 115-86-6
Total Page:16
File Type:pdf, Size:1020Kb
Load more
Recommended publications
-
3R Toolkit for the MICE Industry
for the Meetings, Incentives, 3R Conventions & Toolkit Exhibitions Industry Supported by: CONTENTS 03 Introduction 04 Recommended 3R Practices Case Study on Singapore 09 International Building Week Case Study on Oracle 14 OpenWorld 19 Who to Contact ACKNOWLEDGEMENTS The MICE 3R Toolkit is an initiative of the MICE 3R taskforce comprising the National Environment Agency (NEA), the Singapore Tourism Board (STB) and members of the Singapore Association of Conference and Exhibition Organisers and Suppliers (SACEOS) to provide guidance on 3R initiatives for the MICE industry. A note of thanks to the following taskforce members for their invaluable contributions and support in producing this toolkit: Globibo Singapore Dr Felix Rimbach, Director of Research & Development Marina Bay Sands Pte Ltd Mr Kevin Teng, Executive Director of Sustainability Mr Roger Simons, Associate Director of Sustainability Reed Exhibitions Singapore Ms Louise Chua, Project Director of the Building & Energy Cluster Singapore Tourism Board Ms Keeva Lim, Lead Specialist of Conventions, Meetings & Incentive Travel Suntec Singapore Convention & Exhibition Centre Mr Daniel Ang, Senior Director of Operations Waste Management and Recycling Association of Singapore Mr Michael Ho, Vice Chairman Our thanks also go to Mr Paul Salinger, Vice President of Marketing of Oracle, and Ms Cressida Slote, Sustainability Project Manager of MeetGreen, for their assistance with the case study on Oracle OpenWorld. MICE 3R Toolkit 02 7.8 million tonnes of waste was generated in Singapore in 2016. If waste output continues to grow, more incineration plants will have to be built and Semakau Landfill will run out of space by 2035 or earlier. Resources such as water and energy are conserved when we reduce, reuse and recycle. -
Phosphorus Oxychloride CAS No
Product Safety Summary Phosphorus Oxychloride CAS No. 10025-87-3 This Product Safety Summary is intended to provide a general overview of the chemical substance. The information in the summary is basic information and is not intended to provide emergency response information, medical information or treatment information. The summary should not be used to provide in-depth safety and health information. In-depth safety and health information can be found in the Safety Data Sheet (SDS) for the chemical substance. Names Phosphorus oxychloride Phosphorus trichloride oxide Phosphoric trichloride POCl 3 Product Overview Solvay Novecare does not sell phosphorus oxychloride directly to consumers. Phosphorus oxychloride (POCl3) is used as a chemical intermediate to produce a variety of products which are used in several applications including manufacture of triarylphosphate esters which are used as flame retardants as well as an intermediate in the production of pharmaceutical, textile and agricultural chemicals. Phosphorus oxychloride is used in industrial applications and other processes where workplace exposures can occur. Consumer exposure does not occur as phosphorus oxychloride is not used in any commercially available product. Phosphorus oxychloride is dangerous to human health. Phosphorus oxychloride may be fatal if inhaled, highly toxic if swallowed, harmful if absorbed through skin and can cause severe burns which may result in scarring. Phosphorus oxychloride is consumed in manufacturing processes. POCl3 can make its way into the environment through unintentional releases (spills). POCl3 will not bioaccumulate but is not biodegradable. POCl3 in higher concentrations can be harmful to aquatic life due to formation of acids from the hydrolysis of POCl3. When released into the atmosphere, phosphorus oxychloride exists as vapor. -
OFR Staff Plan
Staff Briefing Package Project Plan: Organohalogen Flame Retardant Chemicals Assessment July 1, 2020 CPSC Consumer Hotline and General Information: 1-800-638-CPSC (2772) CPSC's Web Site: http://www.cpsc.gov THIS DOCUMENT HAS NOT BEEN REVIEWED CLEARED FOR PUBLIC RELEASE OR ACCEPTED BY THE COMMISSION UNDER CPSA 6(b)(1) Acknowledgments The preparation, writing, and review of this report was supported by a team of staff. We acknowledge and thank team members for their significant contributions. Michael Babich, Ph.D., Directorate for Health Sciences Charles Bevington, M.P.H., Directorate for Health Sciences Xinrong Chen, Ph.D., D.A.B.T., Directorate for Health Sciences Eric Hooker, M.S., D.A.B.T., Directorate for Health Sciences Cynthia Gillham, M.S., Directorate for Economic Analysis John Gordon, Ph.D., Directorate for Health Sciences Kristina Hatlelid, Ph.D., M.P.H., Directorate for Health Sciences Barbara Little, Attorney, Office of the General Counsel Joanna Matheson, Ph.D., Directorate for Health Sciences ii THIS DOCUMENT HAS NOT BEEN REVIEWED CLEARED FOR PUBLIC RELEASE OR ACCEPTED BY THE COMMISSION UNDER CPSA 6(b)(1) Table of Contents Briefing Memo ............................................................................................................................... iv 1. Executive summary .............................................................................................................. 5 2. Introduction ......................................................................................................................... -
SDS) Is Provided for Compliance with Applicable Regulations of the Hazard Communication Standard of 2012 (HCS/HAZCOM 2012) Found in §29 CFR 1910.1200
Safety Data Sheet Section 1 – Identification of the Mixture and of the Company Product Identification Primary Identifier(s) Used on the Label Berryman TRANSMISSION & POWER STEERING SEALER Product Synonym(s) blend “PSTS” Product Number(s) 0712 and 0755 Relevant Identified Uses and Uses Advised Against Recommended Uses automatic transmission and power steering pump seal conditioner Uses Advised Against not for use in manual transmissions Manufacturer/Supplier Details Berryman Products, Inc. 3800 E Randol Mill Rd Arlington, TX 76011 (800) 433-1704 (USA/Canada) (817) 640-2376 (international) www.BerrymanProducts.com Emergency 2424----HourHour Telephone Number(s) ––– InfoTrac, Inc. (800) 535-5053 (USA/Canada) (352) 323-3500 (international) Section 2 – Hazards Identification Classification of the Substance or Mixture (29 CFR 1910.1200) Physical Hazards Health Hazards Eye Irritant – Category 2B Specific Target Organ Toxicity - Repeated Exposure – Category 2 (blood/blood system) Environmental Hazard - Chronic – Category 1 Allocation of Label Elements Chemical Identity Berryman TRANSMISSION & POWER STEERING SEALER Pictograms Signal Word WARNING Hazard Statements H320 – Causes eye irritation. H373 – May cause damage to blood/blood system through prolonged or repeated exposure. H410 – Very toxic to aquatic life with long-lasting effects. Safety Data Sheet ––– Page 111 of 999 Berryman Products, Inc. ––– part #s 0712 and 0755 Prevention Precautionary Statements P101 – Keep out of reach of children. P102 – Read label before use. P260 – Do not breathe fumes, gas, mist, vapor, or spray. P264 – Wash thoroughly with soap and water after handling. P273 – Avoid release to the environment. Response Precautionary Statements P314 – Get medical advice/attention if you feel unwell. P391 – Collect spillage. P305/P351/P338 – IF IN EYES: Rinse cautiously with water for several minutes. -
In Vivo Characterisation of the Toxicological Properties of Dphp, One of the Main Degradation Product of Aryl Phosphate Esters
bioRxiv preprint doi: https://doi.org/10.1101/2019.12.26.888057; this version posted December 27, 2019. The copyright holder for this preprint (which was not certified by peer review) is the author/funder. All rights reserved. No reuse allowed without permission. In vivo characterisation of the toxicological properties of DPhP, one of the main degradation product of aryl phosphate esters. Samia Ruby1*, Jesús Marín-Sáez2*, Aurélie Fildier3*, Audrey Buleté3, Myriam Abdallah1, Jessica Garcia4, Julie Deverchère1, Loïc Spinner3, Barbara Giroud3, Sébastien Ibanez5, Thierry Granjon5, Claire Bardel6,7, Béatrice Fervers1, Alain Puisieux1, Emmanuelle Vulliet3, Léa Payen1,4†, Arnaud M. Vigneron1† 1 Université de Lyon, Université Claude Bernard Lyon 1, INSERM 1052, CNRS 5286, Centre Lé on Bé rard, Cancer Research Center of Lyon, Equipe Labellisée Ligue contre le Cancer, Lyon, France. 2 Department of Chemistry and Physics, Analytical Chemistry Area, University of Almería, Research Centre for Agricultural and Food Biotechnology (BITAL), Agrifood Campus of International Excellence ceiA3, Carretera de Sacramento s/n, E-04120 Almería, Spain 3 Université de Lyon, Institut des Sciences Analytiques, UMR 5280 CNRS, Université de Lyon, Université de Lyon 1, ENS-Lyon, 5 rue de la Doua, 69100 Villeurbanne, France 4 Université de Lyon, Université Claude Bernard Lyon 1, Hospices Civils de Lyon, Centre Hospitalier Lyon–Sud, Biochemistry, pharmacotoxicology, and molecular biology department, Pierre Bénite, France 5Université de Lyon, Université Claude Bernard Lyon 1, CNRS, Molecular and Supramolecular Chemistry and Biochemistry Institute ICBMS UMR 5246, F-69622 Lyon, France 6 Department of biostatistics, Hospices Civils de Lyon, Lyon, France 7 Université de Lyon, Université Lyon 1, CNRS, Laboratoire de Biométrie et Biologie Evolutive UMR 5558, F- 69622 Villeurbanne, France *These authors contribute equally to this work † To whom correspondence should be addressed: Léa Payen- Arnaud M. -
SDS for Taylor Mason's Hygrometer
SAFETY DATA SHEET Preparation Date: 3/11/2015 Revision Date: 3/11/2015 Revision Number: G1 Product identifier Product code: T2256 Product Name: TRIETHYL PHOSPHATE Other means of identification Synonyms: Ethyl phosphate TEP Triethoxyphosphine oxide Phosphoric acid, triethyl ester CAS #: 78-40-0 RTECS # TC7900000 CI#: Not available Recommended use of the chemical and restrictions on use Recommended use: Used as a catalyst in the production of acetic anhydride by the ketene process, as a desensitizing agent for peroxides, and as a solvent and plasticizer for cellulose acetate. Solvent; plasticizer for resins, plastics, gums; catalyst; lacquer remover. As a plasticizer, solvent, fire-retarding agent, anti-foaming agent As an ethylating agent, and as a raw material to prepare insecticides such as tetraethyl pyrophosphate. As ethylating agent; formation of polyesters which are used as insecticides.. Uses advised against No information available Supplier: Spectrum Chemicals and Laboratory Products, Inc. 14422 South San Pedro St. Gardena, CA 90248 (310) 516-8000 Order Online At: https://www.spectrumchemical.com Emergency telephone number Chemtrec 1-800-424-9300 Contact Person: Martin LaBenz (West Coast) Contact Person: Ibad Tirmiz (East Coast) 2. HAZARDS IDENTIFICATION Classification This chemical is considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200) Acute toxicity - Oral Category 4 Serious eye damage/eye irritation Category 2A Label elements Product code: T2256 Product name: TRIETHYL 1 / 12 PHOSPHATE Warning Hazard statements Harmful if swallowed Causes serious eye irritation Hazards not otherwise classified (HNOC) Not Applicable Other hazards Not available Precautionary Statements - Prevention Wash face, hands and any exposed skin thoroughly after handling Do not eat, drink or smoke when using this product Wear eye/face protection IF IN EYES: Rinse cautiously with water for several minutes. -
Persistent Organic Pollutants
PERSISTENT ORGANIC POLLUTANTS An Assessment Report on: DDT-Aldrin-Dieldrin-Endrin-Chlordane Heptachlor-Hexachlorobenzene Mirex-Toxaphene Polychlorinated Biphenyls Dioxins and Furans Prepared by: L. Ritter, K.R. Solomon, J. Forget Canadian Network of Toxicology Centres 620 Gordon Street Guelph ON Canada and M. Stemeroff and C.O'Leary Deloitte and Touche Consulting Group 98 Macdonell St., Guelph ON Canada For: The International Programme on Chemical Safety (IPCS) within the framework of the Inter-Organization Programme for the Sound Management of Chemicals (IOMC) This report is produced for the International Programme on Chemical Safety (IPCS). The work is carried out within the framework of the Inter-Organization Programme for the Sound Management of Chemicals (IOMC). The report does not necessarily represent the decisions or the stated policy of the United Nations Environment Programme, the International Labour Organisation, or the World Health Organization. The International Programme on Chemical Safety (IPCS) is a joint venture of the United Nations Environment Programme, the International Labour Organisation, and the World Health Organization. The main objective of the IPCS is to carry out and disseminate evaluations of the effects of chemicals on human health and the quality of the environment. Supporting activities include the development of epidemiological, experimental laboratory, and risk-assessment methods that could produce internationally comparable results, and the development of human resources in the field of chemical safety. Other activities carried out by the IPCS include the development of know-how for coping with chemical accidents, strengthening capabilities for prevention of an response to chemical accidents and their follow-up, coordination of laboratory testing and epidemiological studies, and promotion of research on the mechanisms of the biological action of chemicals. -
Food Waste Reduction and Recycling Resource
Food Waste Reduction and Recycling Resource Kit CONTENTS INTRODUCTION HOW MUCH FOOD WASTE DO WE GENERATE? GROW FOOD 3 In 2018, Singapore generated 763 million kg of food waste. Food wastage happens when we buy, order or cook more than we can eat. BUY AND STORE FOOD PROPERLY 7 ORDER FOOD 12 REDISTRIBUTE FOOD 16 What’s the big deal? Singapore is a small country with limited space. At the current rate we are producing waste, Semakau Landfill will be filled up by 2035 if we do not take steps to reduce waste.1 The resources and labour RECYCLE FOOD WASTE used to produce the food also go to waste, along with hard-earned 20 money we use to buy food. ROLES & RESPONSIBILITIES ROLES & RESPONSIBILITIES 26 1 National Environment Agency – http://www.nea.gov.sg/energy-waste/waste-management/waste-statistics-and-overall-recycling MODULE 1: GROW FOOD LET’S NOT BE WASTEFUL BACKGROUND Together we can cultivate strong environmental ownership in schools and work towards a Zero Waste Nation. Growing food takes time, hard work and resources. Wasting food means we are wasting these resources! This kit aims to help schools get started. You will find resources, including instructions on how to make game sets, to encourage students to reduce food waste. THINGS YOU CAN DO Activity 1: Growing food takes time, hard work and resources Objective: To help students appreciate the time, resources and hard work required to grow food. FOOD MANAGEMENT CYCLE Duration: 20 minutes What you need: • Activity sheet (found on page 6). • 1 “paddy field” and 8 “rice stalks” with answers on the bottom of each stalk. -
UNITED STATES PATENT OFFICE 2,572,806 MANUEFACTURE of TETRAETHY, PYROPHOSPAATE John Sterling Harris, Richmond Heights, Mo., Assignor to Monsanto Chemical Company, St
Patented Oct. 23, 1951 2,572,806 UNITED STATES PATENT OFFICE 2,572,806 MANUEFACTURE OF TETRAETHY, PYROPHOSPAATE John Sterling Harris, Richmond Heights, Mo., assignor to Monsanto Chemical Company, St. Louis, Mo., a corporation of Delaware No Drawing. Application May 1, 1948, Serial No. 24,683 2 Claims, (C. 260-461) 2 This invention relates to compositions con enty known to the art. A still further object of taining increased amounts of tetraethyl pyro this invention is to provide biological toxicant phosphate, and more. particularly to a process compositions containing increased amounts of for the manufacture of tetraethyl pyrophosphate. tetraethyl pyrophosphate which poSSeSS over Compositions containing tetraethyl pyrophos 5. S00% greater biological activity for the combat phate are widely used as agricultural economic ing and control of pests such as aphids and mites poisons, particularly against many insects such than do the compositions containing tetraethyl as aphids and against many acarina such as the pyrophosphate which are presently known to red Spider mites, however, such compositions may the art. be used generally against the lower forms of life O In the practice of this invention, the mixtures which, in the past, have been combatted by the of reaction products from the processes of this use of nicotine or nicotine salts. Furthermore, invention contain substantially 40%, that is tetraethyl pyrophosphate has been found useful 38-45%, of tetraethyl pyrophosphate as con in the preparation of insectivoricide and rodenti trasted with the processes of the prior art which cide compositions. 5 yielded mixtures of the reaction productS con While the art has disclosed several methods for taining only 10-15% of the tetraethyl pyrophoS the preparation of tetraethyl pyrophosphate, phate. -
(VOC) and Organophosphate Flame Retardants (OPFR) in Building Materials
Identification of volatile organic compounds (VOC) and organophosphate flame retardants (OPFR) in building materials Daniel Duberg 2017-05-29 Exam project, 15 HP, Chemistry Supervisor: Thanh Wang, Josefin Persson Examiner: Tuulia Hyötyläinen Abstract Humans today spend most of their time in various indoor settings such as housing, schools and workplaces. The quality of the indoor environment is therefore of great significance for our wellbeing. However, it has been suggested that the indoor environment contains over 6000 organic compounds, such as various volatile organic compounds (VOC). Around 500 of these compounds is believed to be due to emissions from different surrounding building materials such as insulation, plastic film, sealants and flooring. This study targeted building materials from three low energy preschools that were sampled and analyzed for emissions of VOCs and nine different organophosphate flame retardant compounds (OPFR) using a gas chromatograph coupled to a mass spectrometer (GC/MS). Low energy buildings are buildings that is particularly air tight to be so energy efficient as possible. The study uses a qualitative approach and therefore mainly identifies possible contribution from building materials to indoor environment. More than 100 different VOCs was identified and the most noticeable were meta-, ortho- and para-xylene, toluene, n-hexane and propylene glycol, all but the last compound is associated with hazardous health effects. The building materials that emitted the largest amounts of VOCs was sealants and adhesives. Linoleum flooring and acrylic was also large emitters. Tris(1-chloro-2-propyl) phosphate (TCIPP) were identified in all samples and all nine targeted OPFR compounds were identified in the various material samples and dust samples. -
Interagency Committee on Chemical Management
DECEMBER 14, 2018 INTERAGENCY COMMITTEE ON CHEMICAL MANAGEMENT EXECUTIVE ORDER NO. 13-17 REPORT TO THE GOVERNOR WALKE, PETER Table of Contents Executive Summary ...................................................................................................................... 2 I. Introduction .......................................................................................................................... 3 II. Recommended Statutory Amendments or Regulatory Changes to Existing Recordkeeping and Reporting Requirements that are Required to Facilitate Assessment of Risks to Human Health and the Environment Posed by Chemical Use in the State ............................................................................................................................ 5 III. Summary of Chemical Use in the State Based on Reported Chemical Inventories....... 8 IV. Summary of Identified Risks to Human Health and the Environment from Reported Chemical Inventories ........................................................................................................... 9 V. Summary of any change under Federal Statute or Rule affecting the Regulation of Chemicals in the State ....................................................................................................... 12 VI. Recommended Legislative or Regulatory Action to Reduce Risks to Human Health and the Environment from Regulated and Unregulated Chemicals of Emerging Concern .............................................................................................................................. -
Love Your Food
LOVE YOUR FOOD A Handy Guide to Reducing Food Wastage and Saving Money CONTENTS 1 Love Your Food Find out how much food waste is generated in Singapore, and why it ’s a problem. Love Your Cooking 6 Learn how to prepare meals without wastage, and discover great recipes for leftovers. 7 Tips for cooking at home 8 Recipes using leftovers Love Your Groceries 18 Useful tips for grocery shopping as well as storing food. 19 Tips for grocery shopping 20 Tips for storing food 21 Food storage chart 22 Love Your Makan Sessions How to reduce food wastage when eating out or throwing a party. 23 Tips for eating out 24 Tips for parties and events 25 Love Your Ofce Pantry Learn how to manage the food in your office pantry and reduce food wastage. 27 Love Your Kitchen Hacks A collection of smart ways to get more out of the food in your kitchen. 30 Love Your Celebrations Celebrate festive occasions without wasting food. 33 Love Your Community Learn how excess food can be used to help the needy. 35 Be A Winner, Not A Food Binner! A fun family game that rewards your family for reducing food wastage. LOVE YOUR FOOD 3 LET’S ENJOY FOOD, NOT WASTE IT. In Singapore, we love food. But sometimes, we order, cook or buy more than we need. This leads to food wastage. Every year, Singapore generates around 800 million kg of food waste! 800 equivalent million kg to >1,500 Olympic-size swimming pools equivalent to bowls of food per person 2 per day Food waste refers to all unconsumed food substances that are disposed of or recycled.