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Phase Equilibria and Thermodynamic Properties of Minerals in the Beo
American Mineralogist, Volwne 71, pages 277-300, 1986 Phaseequilibria and thermodynamic properties of mineralsin the BeO-AlrO3-SiO2-H2O(BASH) system,with petrologicapplications Mlnx D. B.qnroN Department of Earth and SpaceSciences, University of California, Los Angeles,Los Angeles,California 90024 Ansrru,cr The phase relations and thermodynamic properties of behoite (Be(OH)r), bertrandite (BeoSirOr(OH)J, beryl (BerAlrSiuO,r),bromellite (BeO), chrysoberyl (BeAl,Oo), euclase (BeAlSiOo(OH)),and phenakite (BerSiOo)have been quantitatively evaluatedfrom a com- bination of new phase-equilibrium, solubility, calorimetric, and volumetric measurements and with data from the literature. The resulting thermodynamic model is consistentwith natural low-variance assemblagesand can be used to interpret many beryllium-mineral occurTences. Reversedhigh-pressure solid-media experimentslocated the positions of four reactions: BerAlrSiuO,,: BeAlrOo * BerSiOo+ 5SiO, (dry) 20BeAlSiOo(OH): 3BerAlrsi6or8+ TBeAlrOo+ 2BerSiOn+ l0HrO 4BeAlSiOo(OH)+ 2SiOr: BerAlrSiuO,,+ BeAlrOo+ 2H2O BerAlrSiuO,,+ 2AlrSiOs : 3BeAlrOa + 8SiO, (water saturated). Aqueous silica concentrationswere determined by reversedexperiments at I kbar for the following sevenreactions: 2BeO + H4SiO4: BerSiOo+ 2H2O 4BeO + 2HoSiOo: BeoSirO'(OH),+ 3HrO BeAlrOo* BerSiOo+ 5H4Sio4: Be3AlrSiuOr8+ loHro 3BeAlrOo+ 8H4SiO4: BerAlrSiuOrs+ 2AlrSiO5+ l6HrO 3BerSiOo+ 2AlrSiO5+ 7H4SiO4: 2BerAlrSiuOr8+ l4H2o aBeAlsioloH) + Bersio4 + 7H4sio4:2BerAlrsiuors + 14Hro 2BeAlrOo+ BerSiOo+ 3H4SiOo: 4BeAlSiOr(OH)+ 4HrO. -
LOW TEMPERATURE HYDROTHERMAL COPPER, NICKEL, and COBALT ARSENIDE and SULFIDE ORE FORMATION Nicholas Allin
Montana Tech Library Digital Commons @ Montana Tech Graduate Theses & Non-Theses Student Scholarship Spring 2019 EXPERIMENTAL INVESTIGATION OF THE THERMOCHEMICAL REDUCTION OF ARSENITE AND SULFATE: LOW TEMPERATURE HYDROTHERMAL COPPER, NICKEL, AND COBALT ARSENIDE AND SULFIDE ORE FORMATION Nicholas Allin Follow this and additional works at: https://digitalcommons.mtech.edu/grad_rsch Part of the Geotechnical Engineering Commons EXPERIMENTAL INVESTIGATION OF THE THERMOCHEMICAL REDUCTION OF ARSENITE AND SULFATE: LOW TEMPERATURE HYDROTHERMAL COPPER, NICKEL, AND COBALT ARSENIDE AND SULFIDE ORE FORMATION by Nicholas C. Allin A thesis submitted in partial fulfillment of the requirements for the degree of Masters in Geoscience: Geology Option Montana Technological University 2019 ii Abstract Experiments were conducted to determine the relative rates of reduction of aqueous sulfate and aqueous arsenite (As(OH)3,aq) using foils of copper, nickel, or cobalt as the reductant, at temperatures of 150ºC to 300ºC. At the highest temperature of 300°C, very limited sulfate reduction was observed with cobalt foil, but sulfate was reduced to sulfide by copper foil (precipitation of Cu2S (chalcocite)) and partly reduced by nickel foil (precipitation of NiS2 (vaesite) + NiSO4·xH2O). In the 300ºC arsenite reduction experiments, Cu3As (domeykite), Ni5As2, or CoAs (langisite) formed. In experiments where both sulfate and arsenite were present, some produced minerals were sulfarsenides, which contained both sulfide and arsenide, i.e. cobaltite (CoAsS). These experiments also produced large (~10 µm along longest axis) euhedral crystals of metal-sulfide that were either imbedded or grown upon a matrix of fine-grained metal-arsenides, or, in the case of cobalt, metal-sulfarsenide. Some experimental results did not show clear mineral formation, but instead demonstrated metal-arsenic alloying at the foil edges. -
Mineral Processing
Mineral Processing Foundations of theory and practice of minerallurgy 1st English edition JAN DRZYMALA, C. Eng., Ph.D., D.Sc. Member of the Polish Mineral Processing Society Wroclaw University of Technology 2007 Translation: J. Drzymala, A. Swatek Reviewer: A. Luszczkiewicz Published as supplied by the author ©Copyright by Jan Drzymala, Wroclaw 2007 Computer typesetting: Danuta Szyszka Cover design: Danuta Szyszka Cover photo: Sebastian Bożek Oficyna Wydawnicza Politechniki Wrocławskiej Wybrzeze Wyspianskiego 27 50-370 Wroclaw Any part of this publication can be used in any form by any means provided that the usage is acknowledged by the citation: Drzymala, J., Mineral Processing, Foundations of theory and practice of minerallurgy, Oficyna Wydawnicza PWr., 2007, www.ig.pwr.wroc.pl/minproc ISBN 978-83-7493-362-9 Contents Introduction ....................................................................................................................9 Part I Introduction to mineral processing .....................................................................13 1. From the Big Bang to mineral processing................................................................14 1.1. The formation of matter ...................................................................................14 1.2. Elementary particles.........................................................................................16 1.3. Molecules .........................................................................................................18 1.4. Solids................................................................................................................19 -
High-Pressure Crystal Chemistry of Beryl (Beralrsi.Otr) and Euclase
American Mineralogist, Volume 71, pages 977-984, 1986 High-pressurecrystal chemistry of beryl (BerAlrSi.Otr) and euclase(BeAlSiO4OH) Rosnnr M. HaznN, ANonpw Y. Au, Llnnv W. FrNcnn GeophysicalLaboratory, CarnegieInstitution of Washington, 2801 Upton Street,N.W., Washington, D.C. 20008 Ansrnlcr Compressibilities and high-pressurecrystal structures of beryl and euclasehave beon determined by X-ray methods at severalpressures. Beryl (hexagonal,space group P6/mcc) has nearly isotropic compressibility; linear compressibilitiesperpendicular and parallel to the c axis ateB':1.72 + 0.04 x l0-a kbar-'and B,:2.10 + 0.09 x 10-akbar-'. The correspondingbulk modulus is 1.70 + 0.05 Mbar if the pressurederivative of the bulk modulus K'is assumedto be 4. Euclase(monoclinic, spacegroup P2r/a)has anisotropic compression,with maximum compressibrlity of 2.44 + 0.05 x l0-a kbar-l parallel to the unique monoclinic b axis, and minimum compressibility of 1.50 + 0.03 x 10-a kbar-' approximately parallel to [01]. The intermediate axis of compressionhas a magnitude of 1.96 + 0.05 x lO-akbar-'in the a-c plane.The bulk modulus of euclaseis 1.59 t 0.03 Mbar if K' is assumedto be 4. The bulk moduli ofBe, Al, and Si cation coordination polyhedrain beryl are all consistent with 1.7 Mbar, which is the crystal bulk modulus. Beryl compressionoccurs primarily by shorteningof cation-anion bond distances.In euclase,the 2.3-Mbar polyhedralbulk moduli are significantly greater than the observed 1.6-Mbar crystal modulus. Compression in euclase,particularly along the b crystallographicaxis, results from a combination of poly- hedral compressionand changesin interpolyhedral angles. -
List of New Mineral Names: with an Index of Authors
415 A (fifth) list of new mineral names: with an index of authors. 1 By L. J. S~v.scs~, M.A., F.G.S. Assistant in the ~Iineral Department of the,Brltish Museum. [Communicated June 7, 1910.] Aglaurito. R. Handmann, 1907. Zeita. Min. Geol. Stuttgart, col. i, p. 78. Orthoc]ase-felspar with a fine blue reflection forming a constituent of quartz-porphyry (Aglauritporphyr) from Teplitz, Bohemia. Named from ~,Xavpo~ ---- ~Xa&, bright. Alaito. K. A. ~Yenadkevi~, 1909. BuU. Acad. Sci. Saint-P6tersbourg, ser. 6, col. iii, p. 185 (A~am~s). Hydrate~l vanadic oxide, V205. H~O, forming blood=red, mossy growths with silky lustre. Founi] with turanite (q. v.) in thct neighbourhood of the Alai Mountains, Russian Central Asia. Alamosite. C. Palaehe and H. E. Merwin, 1909. Amer. Journ. Sci., ser. 4, col. xxvii, p. 899; Zeits. Kryst. Min., col. xlvi, p. 518. Lead recta-silicate, PbSiOs, occurring as snow-white, radially fibrous masses. Crystals are monoclinic, though apparently not isom0rphous with wol]astonite. From Alamos, Sonora, Mexico. Prepared artificially by S. Hilpert and P. Weiller, Ber. Deutsch. Chem. Ges., 1909, col. xlii, p. 2969. Aloisiite. L. Colomba, 1908. Rend. B. Accad. Lincei, Roma, set. 5, col. xvii, sere. 2, p. 233. A hydrated sub-silicate of calcium, ferrous iron, magnesium, sodium, and hydrogen, (R pp, R',), SiO,, occurring in an amorphous condition, intimately mixed with oalcinm carbonate, in a palagonite-tuff at Fort Portal, Uganda. Named in honour of H.R.H. Prince Luigi Amedeo of Savoy, Duke of Abruzzi. Aloisius or Aloysius is a Latin form of Luigi or I~ewis. -
Examples from NYF Pegmatites of the Třebíč Pluton, Czech Republic
Journal of Geosciences, 65 (2020), 153–172 DOI: 10.3190/jgeosci.307 Original paper Beryllium minerals as monitors of geochemical evolution from magmatic to hydrothermal stage; examples from NYF pegmatites of the Třebíč Pluton, Czech Republic Adam ZACHAŘ*, Milan NOVÁK, Radek ŠKODA Department of Geological Sciences, Faculty of Sciences, Masaryk University, Kotlářská 2, Brno 611 37, Czech Republic; [email protected] * Corresponding author Mineral assemblages of primary and secondary Be-minerals were examined in intraplutonic euxenite-type NYF peg- matites of the Třebíč Pluton, Moldanubian Zone occurring between Třebíč and Vladislav south of the Třebíč fault. Primary magmatic Be-minerals crystallized mainly in massive pegmatite (paragenetic type I) including common beryl I, helvite-danalite I, and a rare phenakite I. Rare primary hydrothermal beryl II and phenakite II occur in miarolitic pockets (paragenetic type II). Secondary hydrothermal Be-minerals replaced primary precursors or filled fractures and secondary cavities, or they are associated with ,,adularia” and quartz (paragenetic type III). They include minerals of bohseite-ba- venite series, less abundant beryl III, bazzite III, helvite-danalite III, milarite-agakhanovite-(Y) III, phenakite III, and datolite-hingganite-(Y) III. Chemical composition of the individual minerals is characterized by elevated contents of Na, Cs, Mg, Fe, Sc in beryl I and II; Na, Ca, Mg, Fe, Al in bazzite III; REE in milarite-agakhanovite-(Y) III; variations in Fe/Mn in helvite-danalite and high variation of Al in bohseite-bavenite series. Replacement reactions of primary Be- -minerals are commonly complex and the sequence of crystallization of secondary Be-minerals is not defined; minerals of bohseite-bavenite series are mostly the latest. -
Infrared and Raman Spectroscopic Characterization of the Carbonate Bear- Ing Silicate Mineral Aerinite - Implications for the Molecular Structure
This may be the author’s version of a work that was submitted/accepted for publication in the following source: Frost, Ray, Scholz, Ricardo, & Lopez Toro, Andres (2015) Infrared and Raman spectroscopic characterization of the carbonate bear- ing silicate mineral aerinite - Implications for the molecular structure. Journal of Molecular Structure, 1097, pp. 1-5. This file was downloaded from: https://eprints.qut.edu.au/84503/ c Consult author(s) regarding copyright matters This work is covered by copyright. Unless the document is being made available under a Creative Commons Licence, you must assume that re-use is limited to personal use and that permission from the copyright owner must be obtained for all other uses. If the docu- ment is available under a Creative Commons License (or other specified license) then refer to the Licence for details of permitted re-use. It is a condition of access that users recog- nise and abide by the legal requirements associated with these rights. If you believe that this work infringes copyright please provide details by email to [email protected] License: Creative Commons: Attribution-Noncommercial-No Derivative Works 2.5 Notice: Please note that this document may not be the Version of Record (i.e. published version) of the work. Author manuscript versions (as Sub- mitted for peer review or as Accepted for publication after peer review) can be identified by an absence of publisher branding and/or typeset appear- ance. If there is any doubt, please refer to the published source. https://doi.org/10.1016/j.molstruc.2015.05.008 Infrared and Raman spectroscopic characterization of the carbonate bearing silicate mineral aerinite – implications for the molecular structure Ray L. -
Gem Crystal Surface Features Spherical Cultured Pearls Aquamarine
Gems&Jeweller y Spring 2012 / Volume 21 / No. 1 Gem crystal Spherical Aquamarine- surface features cultured pearls coloured glass The Gemmological Association of Great Britain MARCUS MCCALLUM FGA PRECIOUS STONES, BEADS & PEARLS A wide range of precious and semi-precious stones, beads and freshwater pearls, personally selected from around the world. Unusual stones a speciality. ROOM 27-31, NEW HOUSE 67-68 HATTON GARDEN, LONDON EC1N 8JY TELEPHONE: +44(0)20 7405 2169 FACSIMILE: +44(0)20 7405 9385 email:[email protected] www.marcusmccallum.com Gems&Jewellery / Spring 2012 / Volume 21 / No. 1 Gem-A CalendarEditorial Gems&Jewellery Winds of change This year is turning in to a busy one for Gem-A. As reported in Gem-A News and Views (page Spring 40), we have a lease renewal on our Greville Street premises which will lead to a thorough refurbishment — something which those of you who know the building will agree is much needed. This will provide an excellent opportunity to reinvigorate both our onsite teaching facilities and the services we can offer members. How can we afford this you may ask, when only a very few years 12 ago the Association was in poor health financially? The fact is that over the last few years we have run a very tight ship knowing we had these costs looming. We have focused on what we are good Contents at and the things which are the core aspects of our business. This has led to the ceasing of loss- making operations, such as the laboratory, and an increase in students and thus revenue from our education, though it must be qualified that this increase is from overseas rather than the UK. -
Optical Properties of Common Rock-Forming Minerals
AppendixA __________ Optical Properties of Common Rock-Forming Minerals 325 Optical Properties of Common Rock-Forming Minerals J. B. Lyons, S. A. Morse, and R. E. Stoiber Distinguishing Characteristics Chemical XI. System and Indices Birefringence "Characteristically parallel, but Mineral Composition Best Cleavage Sign,2V and Relief and Color see Fig. 13-3. A. High Positive Relief Zircon ZrSiO. Tet. (+) 111=1.940 High biref. Small euhedral grains show (.055) parallel" extinction; may cause pleochroic haloes if enclosed in other minerals Sphene CaTiSiOs Mon. (110) (+) 30-50 13=1.895 High biref. Wedge-shaped grains; may (Titanite) to 1.935 (0.108-.135) show (110) cleavage or (100) Often or (221) parting; ZI\c=51 0; brownish in very high relief; r>v extreme. color CtJI\) 0) Gamet AsB2(SiO.la where Iso. High Grandite often Very pale pink commonest A = R2+ and B = RS + 1.7-1.9 weakly color; inclusions common. birefracting. Indices vary widely with composition. Crystals often euhedraL Uvarovite green, very rare. Staurolite H2FeAI.Si2O'2 Orth. (010) (+) 2V = 87 13=1.750 Low biref. Pleochroic colorless to golden (approximately) (.012) yellow; one good cleavage; twins cruciform or oblique; metamorphic. Olivine Series Mg2SiO. Orth. (+) 2V=85 13=1.651 High biref. Colorless (Fo) to yellow or pale to to (.035) brown (Fa); high relief. Fe2SiO. Orth. (-) 2V=47 13=1.865 High biref. Shagreen (mottled) surface; (.051) often cracked and altered to %II - serpentine. Poor (010) and (100) cleavages. Extinction par- ~ ~ alleL" l~4~ Tourmaline Na(Mg,Fe,Mn,Li,Alk Hex. (-) 111=1.636 Mod. biref. -
New Mineral Names*
American Mineralogist, Volume 73, pages 1492-1499. 1988 NEW MINERAL NAMES* JOHN L. JAMBOR CANMET, 555 Booth Street, Ottawa, Ontario KIA OGI, Canada ERNST A. J. BURKE lnstituut voor Aardwetenschappen, Vrije Universitiete, De Boelelaan 1085, 1081 HV, Amsterdam, Netherlands T. SCOTT ERCIT, JOEL D. GRICE National Museum of Natural Sciences, Ottawa, Ontario KIA OM8, Canada Acuminite* prismatic to acicular crystals that are up to 10 mm long and 0.5 H. Pauly, O.Y. Petersen (1987) Acuminite, a new Sr-fluoride mm in diameter, elongate and striated [001], rhombic to hex- from Ivigtut, South Greenland. Neues Jahrb. Mineral. Mon., agonal in cross section, showing {l00} and {l10}. Perfect {100} 502-514. cleavage, conchoidal fracture, vitreous luster, H = 4, Dm'.. = 2.40(5) glcm3 (pycnometer), Dcale= 2.380 glcm3 for the ideal Wet-chemical analysis gave Li 0.0026, Ca 0.0185, Sr 37.04, formula, and Z = 4. Optically biaxial positive, a = 1.5328(4), (3 Al 11.86, F 33.52, OH (calc. from anion deficit) 6.82, H20 (calc. = 1.5340(4), 1.5378(4), 2 Vmoa,= 57(2)°, 2 Vcale= 59°; weak assuming 1 H20 in the formula) 7.80, sum 97.06 wt%, corre- 'Y = dispersion, r < v; Z = b, Y A c = -10°. X-ray structural study sponding to Sro98AIl.o2F.o7(OH)o.93H20. The mineral occurs as indicated monoclinic symmetry, space group C21c, a = 18.830(2), aggregates of crystals shaped like spear points and about I mm b= I 1.517(2), c= 5.190(I)A,{3 = 100.86(1)°. A Guinierpowder long. -
The Sheeprock Granite of West-Central Utah
CRYSTALLIZATION CONDITIONS FOR. A BE- AND Y-RICH GRANITE--THE SHEEPROCK GRANITE OF WEST-CENTRAL UTAH by Eric H. Christiansen Jack R. Rogers Li Ming Wu CONTRACT REPORT 91-6 APRIL 1991 UTAH GEOLOGICAL AND MI~T£RAL SURVEY 8 division of UTAH DEPARTME~TT OF NATURAL RESOURCES o THE PUBLICATION OF THIS PAPER IS MADE POSSmLE WITH MINERAL LEASE FUNDS A primary mission of the UGMS is to provide geologic information of Utah through publications. This Contract Report represents material that has not undergone policy, technical, or editorial review required for other UGMS publications. It provides Information that may be Interpretive or Incomplete and readers are to exercise some degree of caution in the use of the data. EHC-l INTRODUCTION The Sheeprock granite of west-central Utah is enriched and locally mineralized with beryllium and yttrium (Cohenour, 1959; Williams, 1954). Previous investigations of the whole rock geochemistry of the pluton suggested that it crystallized in situ, from its walls inward, concentrating incompatible elements like Be and Y in the core of the pluton (Christiansen et al., 1988). Magmatic concentrations of Y show a five-fold increase from rim to core of the pluton (13 to 63 ppm). Funkhouser-Marolf (1985) identified monazite (REE phosphate), xenotime (Y phosphate), and Nb-Fe-W-Y-Ta oxides as important hosts for Y. A pegmatitic occurrence of samarskite (an Y-Nb-Ta-Ti oxide) has also been reported (Cohenour, 1959). High Be concentrations are found in the pluton as well; concentrations range from 2 to 50 ppm in apparently un mineralized samples (Christiansen et al., 1988). -
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American Mineralogist, Volume 63, pages 664_676, l97g Multisyste_msanalysis of beryiliumminerar stabilities: the systemBeO-A[rOa_SiO2_H2O DoNer.n M. Bunr Department of Geology, Arizona State (Jniuersitv Tempe,Arizona8528I Abstract seven commonly associatedminerals in the systemBeo-Alror-Sior-Hro includechry- soberyl,phenakite, euclase,bertrandite, beryl, kaolinite,and qiuit . The phaserule implies that not more than six of theseminerals can coexistat an invariantpoint, and, with the addition of an aqueousphase, the associationconstitutes an (n * 4; ptrase(negative two d-egreesof freedom)multisystem. The apparentincompatibility of taotinite with phenakite allowsthe splitting of this unwieldymultisystem into two smaller(n + 3) phasemultisystems, which may belabeled (Kao) and (phe).Moiar volumedata, compuier program RrlcrroN, and naturalassemblages can then be usedto derivethe presumablystabie cJnfiguration of these multisystemson p"-minus an isothermal pHro diagram. n, p-r diagramprojected through theaqueous phase shouldhave the sametopology, and cansimilarlf be drawn. on the resultingdiagrams, three . invariant-butpoinis rabeled tchrl, tBr;;, and [etz] arestable in the.multisystem (Kao), and threedistinct identically-fuU"i.Opoint, u.. stablein rhe multisystem(Phe). An implicationof this topologyvia ihe "r.tu.tubl"-rtable correspon- dence,"is that the assemblagephenakite + euclase* beryl(* aqueousphase) has a finite i'I;ix, ii,l'J.?lT"t' ::ff,,,j :r;: :":.T' ? ts why" euclase is muchrarer than bertrandite. and its stabilityfield, especially