Hydrogeology and Water Quality of the West Valley Creek Basin, Chester County, Pennsylvania
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Hydrogeology and Water Quality of the West Valley Creek Basin, Chester County, Pennsylvania By Lisa A Senior, Ronald A. Sloto, and Andrew G. Reif U.S. GEOLOGICAL SURVEY Water-Resources Investigations Report 94-4137 Prepared in cooperation with the CHESTER COUNTY WATER RESOURCES AUTHORITY Lemoyne, Pennsylvania 1997 U.S. DEPARTMENT OF THE INTERIOR BRUCE BABBITT, Secretary U.S. GEOLOGICAL SURVEY Gordon P. Eaton, Director For additional information Copies of this report can be write to: purchased from: District Chief U.S. Geological Survey U. S. Geological Survey Branch of Information Services 840 Market Street Box 25286 Lemoyne, Pennsylvania 17043-1586 Denver, Colorado 80225-0286 CONTENTS Page Abstract................................................................................... 1 Introduction ...............................................................................3 Purpose and scope .................................................................... 3 Description of the study area ........................................................... 4 Well-numbering system................................................................ 7 Previous investigations................................................................ 7 Acknowledgments.................................................................... 8 Hydrogeology..............................................................................8 Geology ............................................................................. 8 Carbonate rocks................................................................ 10 Vintage Dolomite ......................................................... 10 Kinzers Formation ........................................................ 10 Ledger Dolomite.......................................................... 10 Elbrook Formation ........................................................ 12 Conestoga Limestone...................................................... 12 Noncarbonate rocks............................................................ 12 Leucocratic and intermediate felsic gneiss .................................... 12 Chickies Quartzite ........................................................ 12 Antietem Quartzite and Harpers Phyllite..................................... 12 Octoraro Phyllite.......................................................... 13 Wissahickon Formation.................................................... 13 Peters Creek Schist........................................................ 13 Hydrology.......................................................................... 13 Ground water.................................................................. 13 Water-bearing zones....................................................... 15 Aquifer and well characteristics............................................. 16 Hydraulic conductivity............................................... 16 Specific yield........................................................ 18 Specific capacity and well yield........................................ 18 Water levels .............................................................. 20 Depth to water ...................................................... 20 Fluctuations......................................................... 20 Regional flow............................................................. 26 Surface water .................................................................. 30 Ground-water/surf ace-water relations ............................................ 33 Water budget .................................................................. 40 Water use ................................................................ 40 Basin budget ............................................................. 42 Recharge................................................................. 45 Water quality..............................................................................46 Ground water ....................................................................... 49 CONTENTS Continued Page Water quality Continued Physical properties and field-determined constituents............................... 49 Major ions and constituents...................................................... 51 Metals and other trace constituents ............................................... 58 Radionuclides.................................................................. 60 Organic compounds ............................................................ 62 Volatile organic compounds ................................................ 62 Semivolatile organic compounds............................................ 63 Pesticides ................................................................ 64 Other organic compounds.................................................. 64 Surface water........................................................................ 65 Base flow...................................................................... 65 Physical properties and field-determined constituents ......................... 68 Major ions and constituents ................................................ 75 Metals and other trace constituents.......................................... 86 Streambed sediment............................................................ 90 Benthic invertebrate indices...................................................... 91 Relation between ground-water and surface-water quality ................................ 93 Summary.................................................................................98 References cited ..........................................................................100 ILLUSTRATIONS PLATES [In Pocket] Plate 1. Geology and location of selected wells and springs, West Valley Creek Basin, Chester County, Pennsylvania FIGURES Figures 1-3. Maps showing: 1. Location of the West Valley Creek Basin, Chester County, Pennsylvania ... .4 2. Physiographic provinces, southeastern Pennsylvania.....................5 3. Generalized geology of the West Valley Creek Basin, Pennsylvania, and location of streamflow-measurement stations ..................6 4. Structural cross-sections of Chester Valley, Pennsylvania ......................... 11 5. Water-bearing openings in noncarbonate and carbonate fractured-rock aquifers ..... 14 6. Geophysical logs for well CH-4147 completed in carbonate rock, West Valley Creek Basin, Pennsylvania.................................................... 17 7. Map showing location of observation wells and precipitation gages, West Valley Creek Basin, Pennsylvania ..............................................21 IV ILLUSTRATIONS-Continued Page Figures 8-10. Graphs showing: 8. Water-level fluctuations in observation wells completed in carbonate and noncarbonate rocks, West Valley Creek Basin, Pennsylvania, January 1990 - January 1992 ....................................22 9. Relation between precipitation and the water levels measured in well CH-249, West Valley Creek Basin, Pennsylvania, 1990-91...........23 10. Precipitation and water levels in well CH-3916, West Valley Creek Basin, Pennsylvania, 1990-91 .........................................24 11. Hydrograph of well CH-2738 and daily precipitation, March 10-April 6,1992, West Valley Creek Basin, Pennsylvania ...................................25 12-13. Maps showing: 12. Generalized regional ground-water flow directions, West Valley Creek Basin, Pennsylvania .....................................27 13. Altitude and configuration of the water-table determined from water levels measured May-June 1984, and in the fall of 1983,1987,1990, and 1992, West Valley Creek Basin, Pennsylvania .................28 14-17. Graphs showing: 14. Daily mean discharge at streamflow-measurement stations 01480887, [Westl Valley Creek at Ravine Road near Downingtown, and 01480870, East Branch Brandywine Creek below Downingtown, Pennsylvania, 1990-91 .........................................31 15. Instantaneous discharge at 15-minute intervals at streamflow- measurement stations 01480887, [Westl Valley Creek at Ravine Road near Downingtown, and 01480870, East Branch Brandywine Creek below Downingtown, Pennsylvania, October and December, 1990 ...................................32 16. Base flow and streamflow, at streamflow-measurement station 01480887, [Westl Valley Creek at Ravine Road near Downingtown, Pennsylvania, 1990-91 .........................................33 17. Base flow at streamflow-measurement station 01480887, [Westl Valley Creek at Ravine Road near Downingtown and ground-water levels in a well (CH-249) completed in carbonate rocks, West Valley Creek Basin, Pennsylvania, 1990-91..............................35 18. Map showing location of discharge-measurement sites (October 1990 and 1991) and reconnaissance water-quality-measurement sites (August 1990), West Valley Creek Basin, Pennsylvania ...................................37 19-21. Graphs showing: 19. Base flow and exported sewer flow for the West Valley Creek Basin, Pennsylvania, 1990-91 .........................................45 20. Relation between concentrations of sodium and chloride in ground water in the West Valley Creek Basin, Pennsylvania ...............54 21. Distribution of concentrations of nitrite plus nitrate as nitrogen in ground water in the West Valley Creek Basin, Pennsylvania, grouped by lithology: 1) gneiss and quartzite; 2) carbonate rock; 3) phyllite and schist ..........................................56 ILLUSTRATIONS Continued Page Figures 22. Piper diagrams