Fischer–Tropsch Synthesis As the Key for Decentralized Sustainable Kerosene Production †
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Techno-Economic Analysis of Synthetic Fuels Pathways Integrated with Light Water Reactors
INL/EXT-20-59775 Revision 0 Light Water Reactor Sustainability Program Techno-Economic Analysis of Synthetic Fuels Pathways Integrated with Light Water Reactors September 2020 U.S. Department of Energy Office of Nuclear Energy DISCLAIMER This information was prepared as an account of work sponsored by an agency of the U.S. Government. Neither the U.S. Government nor any agency thereof, nor any of their employees, makes any warranty, expressed or implied, or assumes any legal liability or responsibility for the accuracy, completeness, or usefulness, of any information, apparatus, product, or process disclosed, or represents that its use would not infringe privately owned rights. References herein to any specific commercial product, process, or service by trade name, trade mark, manufacturer, or otherwise, does not necessarily constitute or imply its endorsement, recommendation, or favoring by the U.S. Government or any agency thereof. The views and opinions of authors expressed herein do not necessarily state or reflect those of the U.S. Government or any agency thereof. INL/EXT-20-59775 Revision 0 Techno-Economic Analysis of Synthetic Fuels Pathways Integrated with Light Water Reactors L. Todd Knighton, Daniel S. Wendt (INL) Lesley Snowden-Swan, Jeromy Jenks, Shuyun Li, Steven Phillips, and Jalal Askander (PNNL) September 2020 Prepared for the U.S. Department of Energy Office of Nuclear Energy Page intentionally left blank EXECUTIVE SUMMARY Synthetic fuels (synfuels) and chemicals (synchems) are produced by synthesis from chemical building blocks rather than by conventional petroleum refining. Synthesis gas or syngas (carbon monoxide and hydrogen) is a common intermediate building block in the production of synfuels and synchems. -
Capture and Reuse of Carbon Dioxide (CO2) for a Plastics Circular Economy: a Review
processes Review Capture and Reuse of Carbon Dioxide (CO2) for a Plastics Circular Economy: A Review Laura Pires da Mata Costa 1 ,Débora Micheline Vaz de Miranda 1, Ana Carolina Couto de Oliveira 2, Luiz Falcon 3, Marina Stella Silva Pimenta 3, Ivan Guilherme Bessa 3,Sílvio Juarez Wouters 3,Márcio Henrique S. Andrade 3 and José Carlos Pinto 1,* 1 Programa de Engenharia Química/COPPE, Universidade Federal do Rio de Janeiro, Cidade Universitária, CP 68502, Rio de Janeiro 21941-972, Brazil; [email protected] (L.P.d.M.C.); [email protected] (D.M.V.d.M.) 2 Escola de Química, Universidade Federal do Rio de Janeiro, Cidade Universitária, CP 68525, Rio de Janeiro 21941-598, Brazil; [email protected] 3 Braskem S.A., Rua Marumbi, 1400, Campos Elíseos, Duque de Caxias 25221-000, Brazil; [email protected] (L.F.); [email protected] (M.S.S.P.); [email protected] (I.G.B.); [email protected] (S.J.W.); [email protected] (M.H.S.A.) * Correspondence: [email protected]; Tel.: +55-21-3938-8709 Abstract: Plastic production has been increasing at enormous rates. Particularly, the socioenvi- ronmental problems resulting from the linear economy model have been widely discussed, espe- cially regarding plastic pieces intended for single use and disposed improperly in the environment. Nonetheless, greenhouse gas emissions caused by inappropriate disposal or recycling and by the Citation: Pires da Mata Costa, L.; many production stages have not been discussed thoroughly. Regarding the manufacturing pro- Micheline Vaz de Miranda, D.; Couto cesses, carbon dioxide is produced mainly through heating of process streams and intrinsic chemical de Oliveira, A.C.; Falcon, L.; Stella transformations, explaining why first-generation petrochemical industries are among the top five Silva Pimenta, M.; Guilherme Bessa, most greenhouse gas (GHG)-polluting businesses. -
Comparative Evaluation of Semi-Synthetic Jet Fuels
COMPARATIVE EVALUATION OF SEMI-SYNTHETIC JET FUELS FINAL REPORT Prepared for Coordinating Research Council, Inc. 3650 Mansell Road, Suite 140 Alpharetta, GA 30022 Universal Technology Corporation 1270 North Fairfield Road Dayton, OH 4432 Prepared by Clifford A. Moses Consultant New Braunfels, Texas CRC Project No. AV-2-04a Funded by U.S. Air Force Research Laboratories Contract F33415-02-D-2299 through Universal Technology Corporation September 2008 This page intentionally left blank for back-to-back printing COMPARATIVE EVALUATION OF SEMISYNTHETIC JET FUELS EXECUTIVE SUMMARY This report compares the properties and characteristics of five blends of individual synthetic paraffinic kerosenes with petroleum-based Jet A, Jet A-1 or JP-8 fuel to make semi-synthetic jet fuels (SSJF). The study was requested by the aviation fuel community to provide technical support for the acceptance of synthetic paraffinic kerosenes (SPK) derived from synthesis gas as blending streams up to 50%(v) in fuel specifications for aviation turbine fuel. The methodology for comparison was to be the properties and characteristics used in the original evaluation of the Sasol semi-synthetic jet fuel (SSJF) which has experienced 9 years of successful service since it was approved for use as commercial jet fuel by DEF STAN 91-91 in 1998. The SPK used by Sasol in the original SSJF was produced by a Fischer-Tropsch (F-T) process using synthesis gas derived from coal. The synthesis gases for the four new candidates were produced from natural gas. The details of the F-T process conditions and the downstream processing differed among the five SPK fuels. -
Implementation of Electrofuel Production at a Biogas Plant Case Study at Borås Energi & Miljö Master’S Thesis Within the Sustainable Energy Systems Programme
Biogas Digester Rawgas Gas upgrade Gas CO2 Biogas Organic waste Sabatier reactor Implementation of electrofuel production at a biogas plant Case study at Borås Energi & Miljö Master’s Thesis within the Sustainable Energy Systems programme TOBIAS JOHANNESSON Department of Energy and Environment Division of Physical Resource Theory Chalmers University of Technology Göteborg, Sweden 2016 FRT 2016:03 master’s thesis Implementation of electrofuel production at a biogas plant Case study at Borås Energi & Miljö Master’s Thesis within the Sustainable Energy Systems programme tobias johannesson supervisors: Stavros Papadokonstantakis & Camilla Ölander Examiner Maria Grahn Department of Energy and Environment Division of Physical Resource Theory chalmers university of technology Göteborg, Sweden 2016 Implementation of electrofuel production at a biogas plant Case study at Borås Energi & Miljö Master’s Thesis within the Sustainable Energy Systems programme TOBIAS JOHANNESSON FRT 2016:03 © TOBIAS JOHANNESSON, 2016 Department of Energy and Environment Division of Physical Resource Theory Chalmers University of Technology SE-412 96 Göteborg Sweden Telephone: + 46 (0)31-772 10 00 Cover: Schematic picture over a simplified biogas process with an implemented Sabatier reactor. Chalmers Reproservice Göteborg, Sweden 2016 Implementation of electrofuel production at a biogas plant Case study at Borås Energi & Miljö Master’s Thesis within the Sustainable Energy Systems programme TOBIAS JOHANNESSON Department of Energy and Environment Division of Physical Resource Theory Chalmers University of Technology Abstract One way to decrease the emissions of greenhouse gases is to use a renewable vehicle fuel, such as biogas. By separating methane from carbon dioxide in raw gas in a gas upgrading system, biogas is produced. -
Secure Fuels from Domestic Resources ______Profiles of Companies Engaged in Domestic Oil Shale and Tar Sands Resource and Technology Development
5th Edition Secure Fuels from Domestic Resources ______________________________________________________________________________ Profiles of Companies Engaged in Domestic Oil Shale and Tar Sands Resource and Technology Development Prepared by INTEK, Inc. For the U.S. Department of Energy • Office of Petroleum Reserves Naval Petroleum and Oil Shale Reserves Fifth Edition: September 2011 Note to Readers Regarding the Revised Edition (September 2011) This report was originally prepared for the U.S. Department of Energy in June 2007. The report and its contents have since been revised and updated to reflect changes and progress that have occurred in the domestic oil shale and tar sands industries since the first release and to include profiles of additional companies engaged in oil shale and tar sands resource and technology development. Each of the companies profiled in the original report has been extended the opportunity to update its profile to reflect progress, current activities and future plans. Acknowledgements This report was prepared by INTEK, Inc. for the U.S. Department of Energy, Office of Petroleum Reserves, Naval Petroleum and Oil Shale Reserves (DOE/NPOSR) as a part of the AOC Petroleum Support Services, LLC (AOC- PSS) Contract Number DE-FE0000175 (Task 30). Mr. Khosrow Biglarbigi of INTEK, Inc. served as the Project Manager. AOC-PSS and INTEK, Inc. wish to acknowledge the efforts of representatives of the companies that provided information, drafted revised or reviewed company profiles, or addressed technical issues associated with their companies, technologies, and project efforts. Special recognition is also due to those who directly performed the work on this report. Mr. Peter M. Crawford, Director at INTEK, Inc., served as the principal author of the report. -
Verification of Shell GTL Fuel As CARB Alternative Diesel
Verification of Shell GTL Fuel as CARB Alternative Diesel Ralph A. Cherrillo, Mary Ann Dahlstrom, Anne T. Coleman – Shell Global Solutions (US) Inc. Richard H. Clark – Shell Global Solutions (UK) COPYRIGHT @ 2007 Shell Global Solutions (US) Inc. Outline • Introduction Future Fuel Demand GTL as a Future Fuel • GTL Demonstrations CARB Verification Testing Fleet Tests • GTL Outlook 2 Future Fuel Demand A Forecast of Global Automotive Fuel Demand Energy Demand (x1018 J ) ¾Significant uncertainty in Hydrogen Gaseous plateau of ‘conventional Fuels oil mountain’ 300 Gas Electricity 250 ¾Increased environmental pressures 200 Synthetic fuel and biofuels ¾Plethora of potential 150 Liquid vehicle-fuel solutions Fuels 100 Diesel / Gasoline ¾Common denominator ought to be cost 50 Heavy Oil effectiveness. 2000 2020 2040 2060 2080 2100 (Source: a WEC scenario) 3 GTL Fuel –Synthetic and Alternative Fuel GTL Fuel is one class of Synthetic fuels, which refers to liquids from: gas (GTL) coal (CTL) biomass (BTL) waste (WTL) Alternative Fuels comprise synthetic fuels, biofuels, and fuels such as water-fuel emulsions, ethanol-diesel blends 4 What is Gas to Liquids? GTL is a process that converts natural gas to clean fuels and high quality products via the Fischer-Tropsch process CO + 2H2 –(CH2)n – Natural Syngas Syngas Synthesis Hydrocracking • LPG Manufacture Synthesis Hydrocracking Gas Manufacture • Condensate CH4 • Naphtha • Gasoil • Base oils • Chemicals O H2O O22 Shell’s proprietary process: Shell Middle Distillate Synthesis (SMDS) 5 Why -- Shell GTL Fuel ¾ Strategic diversification of energy supply ¾ Compatible with existing infrastructure ¾ GTL provides a bridge to Biomass to Liquids and Coal to Liquids technologies ¾ Life cycle analysis: GTL vs. -
Oil Shale Tracing Federal Support for Oil Shale Development in the U.S
SUBSIDIZING OIL SHALE TRACING FEDERAL SUPPORT FOR OIL SHALE DEVELOPMENT IN THE U.S. www.taxpayer.net OIL SHALE SPECIMEN. Image Courtesy of United States Geological Survey OIL SHALE SPECIMEN. Image Courtesy of United States Geological Survey lthough the oil shale industry is still in reserves were created to ensure a military oil supply. its commercial infancy, it has a long his- In response, the Bureau of Mines program began A tory of government support that continues research into exploiting oil shale technology and in today. The Bureau of Land Management recently the 1960s private industry followed. But significant issued two new research, development and demon- action was limited until the 1970s, when in response stration leases and new federal regulations for com- to the gas shortages Congress intervened in oil shale mercial leases and royalty rates are expected any day. development, in hopes of creating a domestic fuel Before the federal government goes down that road alternative. Their unsuccessful attempt to spur large- it’s important to take a look back and ask whether we scale commercial development of oil shale and other should be throwing good money after bad. unconventional fossil fuels became a notorious waste Oil shale, or kerogen shale, is a sedimentary rock of federal funds. that contains liquid hydrocarbons that are released Since then federal support has continued in vari- when heated. Considered an oil precursor, kerogen ous forms. Although not a key part of the overall is fossil organic matter that has not had exposure energy policy agenda, federal subsidies continue to to high enough temperatures or been in the ground appear in legislation and administrative actions. -
The Role of E-Fuels in the Transport System in Europe (2030–2050) (Literature Review)
A look into the role of e-fuels in the transport system in Europe (2030–2050) (literature review) Introduction As part of Concawe’s Low Carbon Pathways project, this In December 2015, Parties to the United Nations Framework Convention on Climate Change convened article presents a literature in Paris for the 21st Conference of Parties (COP21). The conference was an important step towards review on e-fuels, which aims to addressing the risks posed by climate change through an agreement to keep the global temperature build a better understanding of increase ‘well below 2°C above pre-industrial levels’ and drive efforts to limit it to 1.5°C above pre- e-fuel production technologies industrial levels. To achieve these goals, the European Union (EU) is exploring different mid-century and implications in terms of scenarios leading to a low-carbon EU economy by 2050. efficiency, greenhouse gas reduction, technology readiness level, environmental impact, In line with the EU’s low-emissions strategy, Concawe’s cross-sectoral Low Carbon Pathways (LCP) investment, costs and potential programme is exploring opportunities and challenges presented by different low-carbon technologies to demand. It is a summary of the achieve a significant reduction in carbon dioxide (CO2) emissions associated with both the manufacture exhaustive literature review and use of refined products in Europe over the medium (2030) and longer term (2050). which is due to be published by the end of 2019. In the scenarios considered by the Commission (P2X, COMBO, 1.5 TECH and 1.5 LIFE) e-fuels are presented as a potential cost-effective technology that could be used to achieve the objectives of the Paris Agreement, i.e. -
AD-MARTEM-OFFICIAL-2.Pdf
Odysseus II Space Contest The TEAM INTERSTELLAR Giulia Bassani & Nicola Timpano Liceo M. Curie Collegno Italy presents… Odysseus II Space Contest AD MARTEM “How to build an autonomous space station on Mars?” Odysseus II Space Contest EARTH MARS 23.44° YEAR 25,19° 365 days 686 days(667 sols) GRAVITY 9.81 m/s² 3.71 m/s² SOLAR LIGHT 24 h 40 m 1.37*10³ W/m² 6.1*10² W/m² 24 h ATMOSPHERE 1013 mbar 7.6 mbar 0.039% CO2 95% 78% N2 2.6% 0.4% H2O 0.03% 0.93% Ar 1.6% 20.9% O2 0.13% Odysseus II Space Contest Odysseus II Space Contest Geodesic Dome Semi-spherical structure made up of a network of beams lying on great circles (geodesics). It becomes proportionally more resistant with increasing size. In the picture→ Artistic view of our base made by us with 3D Studio Max. Resistant against the strong Martian sand-storms. This shape avoids the accumulation of sand and other debris on its surface. Odysseus II Space Contest Materials Multilayered-walls are built with regolith and water (obtained from the permafrost) using a 3D printer. If water freezes, the protection against the cosmic rays is improved. The Ad Martem Program Mission 1 – Cargo •Robotic 3D Printer •Nuclear reactor •Inflatable module Mission 2 – Setup Short human mission •Life Support System •Water and food •Rovers Mission 3 – Stay Human mission Odysseus II Space Contest The Main Base Made with Geogebra Odysseus II Space Contest Made with Geogebra The Main Base Odysseus II Space Contest No windows! Because they would let in the radiations. -
CO2-Based Synthetic Fuel: Assessment of Potential European Capacity and Environmental Performance
CO2-Based Synthetic Fuel: Assessment of Potential European Capacity and Environmental Performance Authors: Adam Christensen, Ph.D. Chelsea Petrenko, Ph.D. Copyright c 2017 This research was funded by European Climate Foundation and the International Council on Clean Trans- portation Final release, November 14, 2017 ii Contents 1 Executive Summary1 2 CO2-based synthetic fuels: Introduction6 2.1 Study Objectives........................................7 2.2 Scenarios............................................8 3 Economic Evaluation9 3.1 Basic Operation.........................................9 3.2 Methodology.......................................... 10 3.3 Literature Review........................................ 10 3.4 Financial Model......................................... 12 3.4.1 Fundamental Economic Parameters.......................... 12 3.4.2 Capital Costs...................................... 12 3.4.3 Feedstock Prices.................................... 14 Electricity........................................ 14 CO2 ........................................... 15 3.4.4 Exogenous Market Prices............................... 15 Diesel Fuel....................................... 15 3.4.5 Deployment....................................... 16 3.5 Results.............................................. 16 3.5.1 Policy Scenario 1.................................... 17 3.5.2 Policy Scenario 2.................................... 17 3.5.3 Policy Scenario 3.................................... 19 3.5.4 Policy Scenario 4................................... -
Power to Gas – Bridging Renewable Electricity to the Transport Sector
POWER TO GAS – BRIDGING RENEWABLE ELECTRICITY TO THE TRANSPORT SECTOR Abstract Globally, transport accounts for a significant part of the total energy utilization and is heavily dominated by fossil fuels. The main challenge is how the greenhouse gas emissions in road transport can be addressed. Moreover, the use of fossil fuels in road transport makes most countries or regions dependent on those with oil and/or gas assets. With that said, the question arises of what can be done to reduce the levels of greenhouse gas emissions and furthermore reduce dependency on oil? One angle is to study what source of energy is used. Biomass is considered to be an important energy contributor in future transport and has been a reliable energy source for a long time. However, it is commonly known that biomass alone cannot sustain the energy needs in the transport sector by far. This work presents an alternative where renewable electricity could play a significant role in road transport within a relatively short time period. Today the amount of electricity used in road transport is negligible but has a potential to contribute substantially. It is suggested that the electricity should be stored, or “packaged” in a chemical manner, as a way of conserving the electrical energy. One way of doing so is to chemically synthesize fuels. It has been investigated how a fossil free transport system could be designed, to reach high levels of self- sufficiency. According to the studies, renewable electricity could have the single most important role in such a system. Among the synthetic fuels, synthetic methane (also called synthetic biogas) is the main focus of the thesis. -
Fisher–Tropsh Synthesis Technology Evolution - Anna Matuszewska Et Al
IOP Conference Series: Materials Science and Engineering PAPER • OPEN ACCESS Recent citations Fisher–Tropsh synthesis technology evolution - Anna Matuszewska et al To cite this article: N I Loseva et al 2019 IOP Conf. Ser.: Mater. Sci. Eng. 663 012067 View the article online for updates and enhancements. This content was downloaded from IP address 170.106.40.40 on 25/09/2021 at 21:27 ETSaP 2019 IOP Publishing IOP Conf. Series: Materials Science and Engineering 663 (2019) 012067 doi:10.1088/1757-899X/663/1/012067 Fisher–Tropsh synthesis technology evolution N I Loseva, I I Niyazbakiev and A V Silman Tyumen Industrial University, 38, Volodarsky St., Tyumen, 625000, Russia E-mail: [email protected] Abstract. the article considers the development stages of technologies for producing hydrocarbons based on syngas. XTL technology is based on the Fischer–Tropsch process. Carbon-containing substances in any aggregate state can be used as a raw material of XTL technology, which will affect the chemistry and process parameters. Currently, interest in these technologies has increased in connection with the advent of scientific and technological innovations. The latest generation of XTL technology has already entered the industrial production phase. The article presents the results of a comparative analysis of XTL technology of different generations, the main indicators of which were the state of raw materials, the type of reactor devices, the chemical composition of the catalytic systems and the resulting product. The advantages of the technology proposed by INFRA Technology Company involving an innovative reactor design for a high-performance multifunctional catalyst, are shown.