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Exploring with CuriosityChemCam and its Laser-Induced Remote Sensing for ChemistryLaser and Micro-Imaging

(meeting)

Mg

Si Roger C Wiens Al Ba ChemCam PI

Frontiers in Science Lectures Los Alamos – Albuquerque – Santa Fe – Taos (location) 3/16/2004 1 NASA (date)May, 2013 LA-UR-13-23209 Jean-Luc Lacour, CEA Goals

• Assess Mars’ biological potential by • Searching for organic carbon compounds, • Looking for the chemical building blocks of life, • Identify biologically relevant clues. • Characterize the geology of the landing region • Investigate Mars’ past habitability (including the role of water) • Characterize the human hazards on Mars , 2003 1997 MSL 2011

2 NASA/JPL-Caltech

Is Mars Like ?

• Starting 150 years ago, some astronomers thought they could see canals on Mars

Schiaparelli 3 Mariners 4, 6, 7 Missions

Mariner 4, 1965: Mars looks cratered and barren, like the

4 NASA Orbiter, 1971: Evidence of Water

5 NASA Viking Landers, 1976, Test for Life

6 NASA Biota Could Have Traveled From Earth to Mars

• NASA has > 100 meteorites from Mars that fell to Earth • Mars probably has a number of meteorites from Earth – Bacteria from Earth could have traveled in these rocks

NASA/JSC/Smithsonian 7 Fossilization How to Look for

• Concentration: where does water deposit material? – Lakebeds and especially river deltas – Coal- or oil-bearing stata on Earth • Preservation : mineralization = fossils – Sedimentary rocks, especially clay- bearing Coal R. Wiens, Carlsbad, NM • Environmental residues: how do microbes modify the environment? – methane

Atlas.nsw.gov.au 8 Rover ChemCam (Chemistry) Mastcam (Imaging) RAD (Radiation) MaHLI (Imaging) REMS (Weather)

DAN (Hydrogen)

APXS (Chemistry)

MARDI (Imaging) SAM CheMin (Isotopes) (Mineralogy) NASA/JPL-Caltech NASA/JPL-Caltech

Laser-Induced Breakdown Spectroscopy (LIBS)

Backpack LIBS for the IAEA

10 Sirven et al., JAAS ChemCam Instrument Schematic

IRAP, Toulouse, France

Los Alamos, USA 12 What Really Happens? LIBS Plasmas In Different

3”

14 LANL First Spectrum: Coronation

Field of view: ~ 6 cm Visible & Near Infrared Titanium Violet

Manganese

Ultraviolet

Calcium

Oxygen

Calcium

Carbon

Aluminum

Magnesium

Sodium

Iron

Lithium

Silicon

Sodium

Calcium

Oxygen

Calcium

Aluminum

Silicon

Titanium

Potassium

Silicon Iron

NASA/JPL-Caltech/LANL/IRAP/LPGN/IAS NASA/JPL-Caltech/LANL/IRAP/LPG-Nantes/IAS

16 NASA/JPL-Caltech/LANL/IRAP/LPG-Nantes/IAS

17 NASA/JPL-Caltech/LANL/IRAP/IAS

18 Mast Unit Installation

19 NASA/JPL-Caltech Mast Unit on ChemCam Mars

NASA/JPL-Caltech/MSSS Operating on Mars Drive

Investigate Eng. & Sci. Data

Downlink New Mosaic

Science Theme Group Selects Targets

Long-Term Lien List Engineers Build Guidance Command Sequences Sites

Mars River Delta

22 Crater Landing Site

Mount Sharp Sedimentary, 3 miles high

Landing Ellipse

90 miles

23 Mars Mission: Landing

• 900 kg is too heavy for MER-type air bag landing • MSL used a “sky crane” • Cables will lower it from a retro-rocket package • MSL lands on its 24 wheels Image: JPL

My Previous NASA Landing

NASA/JSC 25 26 First Image From Mars

27 NASA/JPL-Caltech NASA/JPL-Caltech

Landing on an Alluvial Fan

NASA/JPL-Caltech The conglomerate “” and loose, rounded pebbles

NASA/JPL-Caltech/MSSS View from

30 30, 9/6/2012 NASA/JPL-Caltech/U AZ Light-Toned Fractured

Hummocky

31

NASA/JPL-Caltech/Univ.of AZ %

High - Silica Mineral Grains

NASA/JPL

- Bathurst Caltech/ Univ.of

AZ

10 10 cm NASA/JPL

32 - Caltech/MSSS

NASA/JPL-Caltech/MSSS Heading into Yellowknife Bay Drill Results

• 20% of material is clay • Laid down in water • Water had normal pH • You could drink it!

34 Calcium Sulfate Veins

35 SAM Instrument Results: Organics and

• Methane was not detected (~ 2 part per billion detection limit) • Organic molecules of the type indicative of life have not yet been detected • SAM found that argon, rather than , is the second most

abundant atmospheric gas, after CO2

SAM’s TLS uses infrared lasers and mirrors to measure the absorption of light by atmospheric gases

NASA/JPL-Caltech/Goddard How easy is it to find evidence for life on Earth 3.5 billion years ago?

Warrawoona Group Australia Grotzinger Cumberland This Week’s Drill Target Landing Ellipse

39 NASA/JPL-Caltech/Univ. of Arizona/USGS This boulder is the size of Curiosity

NASA/JPL-Caltech/MSSS

Mastcam image of ’s canyons and buttes Scarecrow Rover Climbs 3 Foot Boulder “JPL” Morse Code

42 Thank You!

43 NASA/JPL-Caltech/MSSS

Additional Slides

44 MAVEN 2013 The Future for Mars?

Insight 2016 • 2013…2016…2018…2020 • Humans? One-way trips? NASA

NASA

Mars-One NASA 2023

45 MAVEN 2013 The Future for Mars?

Insight 2016 • 2013…2016…2018…2020 • Humans? One-way trips? NASA Mars 2020 3030??

NASA

NASA

D. Spangler A successful human colony on Mars is still a long way off • So many things can go wrong! • Example from 1620: • Far in the future: Terraforming Mars?

46 W. Halsall How Do We Know A Meteorite is From Mars?

1. Inside it looks very much like a terrestrial rock compared with other meteorites 2. It’s age is much younger than the (which are all 4.5 billion years old) 3. Its oxygen isotopes define a trend that is distinct from terrestrial 4. Some of these meteorites contain pockets of gas identical to the Mars atmosphere

17O/16O Mars trend line

Plotted relative to mean ocean water, in parts per thousand enrichment

18O/16O 47 LIBS Minor & Trace Elements--Sr

Rover igneous calibration targets C. Fabre, manuscript

48 LIBS Sensitivies, ChemCam Configuration

Approximate detection limits 5-100 ppm at Mars atmospheric pressure

100-1000 ppm H He 0.1-3% Li Be B C N O F Ne Difficult Na Mg Al Si P S Cl Ar

K Ca Sc Ti V Cr Mn Fe Co Ni Cu Zn Ga Ge As Se Br Kr

Rb Sr Y Zr Nb Mo Ru Rh Pd Ag Cd In Sn Sb Te I Xe

Cs Ba La Hf Ta W Re Os Ir Pt Au Hg Tl Pb Bi

49 ChemCam Mast Unit : Optical Box

CAMERA (Remote Micro-Imager)

OPTICAL FIBER connector TELESCOPE To Body Unit LIBS laser beam focus and collection

LIBS LASER

SCHMIDT PLATE Image correction

GALILEAN

LIBS laser beam AUTOFOCUS expansion Target from Continuous Wave 1 to 7 m Laser diode 50 Model for Classification & Quantification

APXS Cross Future Calibration Test bench Instrument Selected λ calibration calibrations Response On Mars Standards

Current Standards Pre-delivery Instrument MVA λ calibration calibrations Response Prediction Model

Instrument Distance Abundance Mars Data λ calibration Response Correction Predictions

Uncertainties

51 Typical analysis sequence

6 Minutes, 2 W-hr Per Typical Analysis NASA/JPL-Caltech ChemCam Mars Calibration

1. Macusanite volcanic glass 2. Norite synthetic glass 3. Picrite synthetic glass 4. Shergottite synthetic glass 5. Graphite (C calibration) 6. Kaolinite-based ceramic 7. Nontronite-based ceramic 8. Nontronite-based ceramic 9. Nontronite-based ceramic 10. Titanium plate (diagnostics)

References:1-4: Fabre et al., 2011 6-9: Vaniman et al., 2012

53 Except No Apparent Coatings on Most Rocks Dust

~25 µm Constant Composition Depth

Grain Transition

Dust

54 Los Alamos Involvement in Curiosity

ChemCam Developed & Led By LANL

NASA/Cory Huston

NASA/JPL-Caltech

Plutonium for RTG CheMin LANL Science Co-lead is NASA/JPL-Caltech /MSSS from LANL Collaborators

56 NASA/JPL/Cornell