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ES/ER/TM-96/R2 Toxicological Benchmarks for Screening Potential Contaminants of Concern for Effects on Aquatic Biota: 1996 Revision This document has been approved by the K-25 Site Technical Information Office for release to the public. Date: This report has been reproduced directly from the best available copy. Available to DOE and DOE contractors from the Office of Scientific an d Technical Information, P.O. Box 62, Oak Ridge, TN 37831; prices available from 423-576-8401 (fax 423-576-2865). Available to the public from the National Technical Information Service, U.S. Department of Commerce, 5285 Port Royal Rd., Springfield, VA 22161. ES/ER/TM-96/R2 Toxicological Benchmarks for Screening Potential Contaminants of Concern for Effects on Aquatic Biota: 1996 Revision G. W. Suter II C. L. Tsao Date Issued—June 1996 Prepared by Risk Assessment Program Health Sciences Research Division Oak Ridge, Tennessee 37831 Prepared for the U.S. Department of Energy Office of Environmental Management under budget and reporting code EW 20 LOCKHEED MARTIN ENERGY SYSTEMS, INC. managing the Environmental Management Activities at the Oak Ridge K-25 Site Paducah Gaseous Diffusion Plant Oak Ridge Y-12 Plant Portsmouth Gaseous Diffusion Plant Oak Ridge National Laboratory under contract DE-AC05-84OR21400 for the U.S. DEPARTMENT OF ENERGY AUTHOR AFFILIATIONS G. W. Suter II is a member of the Environmental Sciences Division, Oak Ridge Nationa l Laboratory, Oak Ridge, Tennessee. C. L. Tsao is affiliated with the School of the Environment, Duke University, Durham, North Carolina. iii PREFACE The purpose of this report is to present and analyze alternate toxicological benchmarks fo r screening chemicals for aquatic ecological effects. This work was performed under Work Breakdown Structure 1.4.12.2.3.04.05.04 (Activity Data Sheet 8304, “Technical Integration—Risk Assessment”). Publication of this document meets a milestone for the Environmental Restoration (ER) Risk Assessment Program. Since the prior edition of this report (Suter and Mabrey 1994), both the U.S. Environmental Protection Agency Office of Solid Waste and Emergency Response and EPA Region IV have developed sets of screening benchmarks for water. This report includes those values and updates the othe r benchmarks that were presented in the last edition. CONTENTS AUTHOR AFFILIATIONS ........................................................ iii PREFACE ...................................................................... v TABLES ....................................................................... ix ACRONYMS ................................................................... xi EXECUTIVE SUMMARY ........................................................ xiii 1. INTRODUCTION .............................................................. 1 2. METHODS FOR DERIVING BENCHMARKS ...................................... 1 2.1 TYPES OF BENCHMARKS ................................................ 1 2.2 WATER QUALITY CRITERIA ............................................. 2 2.3 TIER II VALUES ........................................................ 13 2.4 LOWEST CHRONIC VALUES ............................................ 14 2.5 ESTIMATED LOWEST CHRONIC VALUES ................................ 14 2.6 TEST EC20s ............................................................ 14 2.7 ESTIMATED TEST EC20s ................................................ 15 2.8 SENSITIVE SPECIES TEST EC20s ......................................... 15 2.9 POPULATION EC25s .................................................... 15 2.10 ECOTOX THRESHOLDS ................................................ 16 2.11 REGION IV SCREENING VALUES ....................................... 16 2.12 BACKGROUND CONCENTRATIONS .................................... 16 3. CHEMICAL-SPECIFIC INFORMATION ......................................... 22 3.1 INORGANICS .......................................................... 23 3.2 ORGANICS ............................................................ 27 4. APPLICATION OF BENCHMARKS ............................................. 34 5. REFERENCES ............................................................... 35 Appendix A DATA USED FOR TIER II CALCULATIONS ............................ A-1 Appendix B METHODS FOR DERIVATION OF TIER II VALUES ..................... B-1 Appendix C TABLE SHOWING CONCENTRATIONS ESTIMATED TO CAUSE A 20% REDUCTION IN THE RECRUIT ABUNDANCE OF LARGEMOUTH BASS, WITH UPPER AND LOWER 95% CONFIDENCE BOUNDS ........................... C-1 TABLES 1 Summary of conventional benchmarks for priority contaminants in fresh water ............ 3 2 Summary of alternative benchmarks for priority contaminants in fresh water based on levels of chronic effects ...................................................... 9 3 Summary of OSWER threshold values for aquatic life (EPA 1996) and Region IV screening values for freshwater surface water .......................... 17 A.1 Data and calculated results for derivation of Tier II values ........................... A-3 B.1 Factors for estimation of the Tier II values ....................................... B-6 C.1 Concentrations estimated to cause a 20% reduction in the recruit abundance of largemouth bass, with upper and lower 95% confidence bounds .................... C-3 ACRONYMS ACRs acute chronic ratios ARARs applicable or relevant and appropriate requirements CERCLA Comprehensive Environmental Response, Compensation, and Liability Act CV Chronic Value EC50 median effective concentration EPA U.S. Environmental Protection Agency ETs Ecotox Thresholds FACR Final Acute-Chronic Ratio FAV Final Acute Value FCV final chronic value GLWQI Great Lakes Water Quality Initiative GMAV genus mean acute value LC50 median lethal concentration LOEC Lowest Observed Effect Co MATC Maximum Acceptable Toxicant Concentration NAWQC National Ambient Water Quality Criteria NOEC No Observed Effect Concentration OSWER Office of Solid Waste and Emergency Response RI Remedial Investigation SACR secondary acute chronic ratio SAV Secondary Acute Values SCV Secondary Chronic Value SS sensitive species SVs screening values EXECUTIVE SUMMARY One of the initial stages in ecological risk assessment of hazardous waste sites is the screening of contaminants to determine which, if any, of them are worthy of further consideration; this process i s termed contaminant screening. Screening is performed by comparing concentrations in ambient media to benchmark concentrations that are either indicative of a high likelihood of significant effects (upper screening benchmarks) or of a very low likelihood of significant effects (lower screening benchmarks). Exceedance of an upper screening benchmark indicates that the c hemical in question is clearly of concern and remedial actions are likely to be needed. Exceedance of a lower screening benchmark indicates that a contaminant is of concern unless other information indicates that the data are unreliable or th e comparison is inappropriate. Chemicals with concentrations below the lower benchmark are not o f concern if the ambient data are judged to be adequate. This report presents potential screening benchmarks for protection of aquatic life fro m contaminants in water. Because there is no guidance for screening benchmarks, a set of alternativ e benchmarks is presented herein. The alternative benchmarks are based on different conceptua l approaches to estimating concentrations causing signifi cant effects. For the upper screening benchmark, there are the acute National Ambient Water Quality Criteria (NAWQC) and the Secondary Acute Values (SAV). The SAV concentrations are values estimated with 80% confidence not to exceed the unknown acute NAWQC for those chemicals with no NAWQC. The alternative chronic benchmarks are th e chronic NAWQC, the Secondary Chronic Value (SCV ), the lowest chronic values for fish and daphnids, the lowest EC20 for fish and daphnids from chronic toxicity tests, the estimated EC20 for a sensitive species, and the concentration estimated to cause a 20% reductio n in the recruit abundance of largemouth bass. It is recommended that ambient chemical concentrations be compared to all of these benchmarks. If NAWQC are exceeded, the chemicals must be contaminants of concern because the NAWQC ar e applicable or relevant and appropriate requirements (ARARs). If NAWQC are not exceeded, but other benchmarks are, contaminants should be selected on the basis of the number of benchmarks exceeded and the conservatism of the particular benchmark values, as discussed in the text. To the extent that toxicity data are available, this report presents the alternative benchmarks fo r chemicals that have been detected on the Oak Ridge Reservation. It also presents the data used t o calculate the benchmarks and the sources of the data. It compares the benchmarks and discusses their relative conservatism and utility. This report supersedes a prior aquatic benchmarks report (Suter and Mabrey 1994). It adds two new types of benchmarks. It also updates the benchmark values where appropriate, adds some ne w benchmark values, replaces secondary sources with primary sources, and provides more complet e documentation of the sources and derivation of all values. 1. INTRODUCTION An important early step in the assessment of ecological risks posed by a contaminated site is the screening of contaminants. In many cases, concentrations in water will be reported for more than 100 chemicals, most of which will be reported as undetecte d at some defined limit of detection. The

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